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IIT-JEE 2011 Paper2 Solutions English

IIT-JEE 2011 Paper2 Solutions English

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Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
Date : 11-04-2011 Duration : 3 Hours Max. Marks : 240
PAPER - 2
QUESTIONS AND SOLUTIONS OF IIT-JEE 2011
INSTRUCTIONS
A. General :
1. The question paper CODE is printed on the right hand top corner of this sheet and on the backpage of this booklet.2. No additional sheets will be provided for rough work.3. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers andelectronic gadgets are NOT allowed.4. Write your name and registration number in the space provided on the back page of this booklet.5. The answer sheet, a machine-gradable Optical Response Sheet (ORS), is provided separately.6. DO NOT TAMPER WITH/MUTILATE THE ORS OR THE BOOKLET.7. Do not break the seals of the question-paper booklet before being instructed to do so by theinvigilators.8. This Question Paper contains having 60 questions.9. On breaking the seals, please check that all the questions are legible.
B. Filling the Right Part of the ORS:
10. The ORS also has a CODE printed on its Left and Right parts.11. Make sure the CODE on the ORS is the same as that on this booklet.
If the codes do notmatch, ask for a change of the booklet.
12. Write your Name, Registration No. and the name of centre and sign with pen in the boxesprovided.
Do not write them anywhere else
. Darken the appropriate bubble
UNDER
eachdigit of your Registration No. with a
good quality HB pencil.C. Question paper format and Marking Scheme:
13. The question paper consists of
3 parts
(Chemistry, Physics and Mathematics). Each partconsists of
four sections
.14. In
Section I
(Total Marks: 24), for each question you will be awarded 3 marks it you darkenONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened.In all other cases,
minus one (-1) mark
will be awarded.15. In
Section II
(Total Marks: 16), for each queshon you will be awarded
4 marks
if you darken ALLthe bubble(s) corresponding to the correct answer(s)
ONLY
and
zero marks
otherwise. Thereare
no negative marks
in this section.16. In
Section Ill
(Total Marks: 24), for each question you will be awarded 4 marks if you darken
ONLY
the bubble corresponding to the correct answer and zero marks otherwise. There are
nonegative marks
in this section.17. In
Section IV
(Total Marks: 16), for each question you will be awarded 2 marks for each row inwhich you have darkened
ALL
the bubble(s) corresponding to the correct answer(s)
ONLY
and
zero marks
otherwise. Thus, each question in this section carries
a maximum of 8 marks
.There are
no negative marks
in this section.
Write your Name registration number and sign in the space provided on the backpage of this booklet.
DO NOT BREAK THE SEALS WITHOUT BEINGINSTRUCTED TO DO SO BY THE INVIGILATOR
 
J10411Page # 2Useful Data :
R = 8.314 JK
1
mol
1
or 8.206
× 10
2
L atm K
1
mol
1
1 F = 96500 C mol
1
h = 6.626
× 10
34
Js1 eV = 1.602
× 10
19
Jc = 3.0
× 10
8
m s
1
N
A
= 6.022
× 10
23
 
J10411Page # 3
PART-II
SECTION
I (Total Marks : 24)
(Single Correct Answer Type)This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and(D) out of which ONLY ONE is correct.1.
Oxidation states of the metal in the minerals haematite and magnetite, respectively, are :(A) II, III in haematite and III in magnetite (B) II, III in haematite and II in magnetite(C) II in haematite and II, III in magnetite (D) III in haematite and II, III in magnetite
Ans.
(D)
Sol.
In haematite(Fe
2
O
3
), Fe is present (III) oxidation state and in magnetite (Fe
3
O
4
) Fe is present in (II) and(III) oxidation state.
2.
Among the following complexes (K
P),
K
3
[Fe(CN)
6
] (K), [Co(NH
3
)
6
]Cl
3
(L), Na
3
[Co(oxalate)
3
] (M), [Ni(H
2
O)
6
]Cl
2
(N), K
2
[Pt(CN)
4
] (O) and[Zn(H
2
O)
6
](NO
3
)
2
(P)the diamagnetic complexes are :(A) K, L, M, N (B) K, M, O, P (C) L, M, O, P (D) L, M, N, O
Ans.
(C)
Sol.
K
[Fe(CN)
6
]
3
: 3d
5
electron configuration after pairing of electrons for d
2
sp
3
hybridisation it contains oneunapaired electrons.L
[Co(NH
3
)
6
]
3+
: 3d
6
electron configuration, d
2
sp
3
, diamagnetic.M
[Co(ox)
3
]
3
: 3d
6
electron configuration, d
2
sp
3
, diamagnetic.N
[Ni(H
2
O)
6
]
2+
: 3d
8
electron configuration, sp
3
d
2
, with two unpared electrons ; paramagnetic.O
[Pt(CN)
4
]
2
: 5d
8
electron configuration, dsp
2
diamagnetic.P
[Zn(H
2
O)
6
]
2+
: 3d
10
electron configuration, sp
3
d
2
diamagnetic.
3.
Passing H
2
S gas into a mixture of Mn
2+
, Ni
2+
, Cu
2+
and Hg
2+
ions in an acidified aqueous solution precipitates:(A) CuS and HgS (B) MnS and CuS (C) MnS and NiS (D) NiS and HgS
Ans.
(A)
Sol.
In presence of acidic medium, ionisation of H
2
S is supressed so less number of S
2
ions are produced. Soonly those sulphides are precipitated which have low solubility product (K
SP
) value, For example CuS andHgS.
4.
Consider the following cell reaction :2Fe (s) + O
2
(g) + 4H
+
(aq)
 
2Fe
2+
(aq) + 2H
2
O (l) E
º = 1.67 V
At [Fe
2+
] = 10
3
M, P (O
2
) = 0.1 atm and pH = 3, the cell potential at 25
ºC is :
(A) 1.47 V (B) 1.77 V (C) 1.87 V (D) 1.57 V
Ans.
(D)
CHEMISTRY

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