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PPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMI

CHEMISTRY
FORM 4
MODULE 1
PPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMI

INTRODUCTION TO CHEMISTRY,
THE STRUCTURE OF THE ATOM,
CHEMICAL FORMULAE AND
EQUATIONS

MINISTRY OF EDUCATION MALAYSIA


1. You are given this formula:

Number of Particles
X=
Avogadro Cons tan t
What is X ?

A Molar mass
B Molar volume
C Number of moles

2. You are given the molecular formula of glucose: C6H12O6

The molecular formula of glucose shows the

A actual mass of glucose


B formula of a glucose molecule that exists in solid state
C actual number of each atom of the elements in a glucose molecule
D ratio for the number of atoms of each type of element in a glucose
molecule

3. Molar mass of a substance is the mass

A of one mole of the substance


B of one atom of the substance
C of 6.023 x 10 24 particles of the substance

4. The diagram shows the symbol of an atom.

Nucleon number A
Proton number Z X

The isotopes of hydrogen are 1 H , 2 3


1H H
and .
1 1
What is isotopes?

A Different atoms with the same number of electron, protons and neutrons.
B Different atoms with the same number of electrons but different number
of protons.
C Different atoms with the same number of neutrons but different number
of protons.
D Different atoms with the same number of protons but different number of
neutrons.
5. The value of Avogadro constant is 6.023 x 1023 mol-1

What is Avogadro constant?


A The number of neutrons in an atom.
B The mass in one mole of a substance
C The number of protons and electrons of an atom.
D The number of particles in one mole of a substance

6. ‘ 1 mole of any gas occupies 24 dm3 at room conditions’ is the definition of

A molarity
B molar mass
C molar volume

7. ‘An amount of substance that contains as many particles as the number of


atoms in exactly 12 g of carbon-12’

Which of the following terms explains the above statement?

A mole
B molar mass
C relative atomic mass
D relative molecular mass

8. The equation below shows the reaction between magnesium and oxygen

2 Mg (s) + O2 (g) 2 MgO(s)

Number 2 represents

A mass
B volume
C number of moles
D number of particles

9. Which of the following statements is true about matter?

A Matter has mass only.


B Matter has mass and occupies space.
C Matter is the smallest particle of an element.

2
10. Which of the following is not true about molar mass?

A the mass of 6.02 x 10 23 particles


B the mass of NA number of particles
C the mass of one mole of the substances
D the mass of one gram of the substances

11. An atom is a neutral particle. It contains the same number of

A protons and neutrons.


B protons and electrons.
C neutrons and electrons.

12. The diagram shows the heating curve of solid naphthalene.

temperature/oC

Q
R

P
time/min
Which of the following points shows the melting process of naphthalene?

A At point P
B From point P to point Q
C From point Q to point R
D From point R to point S

13.
CaCO3 (s) + HCI (aq) CaCI2(aq) + CO2 (g) + H2O(l)

What is (are) the reactant (s) for the above chemical equation?

A CaCO3 only
B CO2 and H2O
C CaCO3 and HCl
D CaCI2, H2O and CO2

3
14. The diagram shows the electron arrangement of atom X

How many valence electrons are there in the atom X?

A 2
B 5
C 7

15. The table shows the relative masses of the three subatomic particles.

Subatomic Relative mass


Proton 1
Electron 1
1840
Neutron 1

Which of the subatomic particles has the least mass?

A Proton
B Neutron
C Electron

16. The table shows the simplest ratio of elements P and Q

Element P Q
Simplest ratio 1 3

What is the empirical formula of this substance?

A PQ
B P3Q
C PQ3
D P2Q3

4
17. The diagram shows the changes in the state of a substance from P to Q under pro

Process X

P Q

What is process X ?

A Melting
B Freezing
C Sublimation
D Condensation

18. What is the number of molecules in one mole of carbon dioxide gas, CO2?
[NA = 6.02 x 1023 ]

A 6.02 ×10 23
2
B 1 x 6.02 x 1023
C 2 x 6.02 x 1023
D 3 x 6.02 x 1023

19. The number of electrons and the number of neutrons of atom X are 4 and 5
respectively.
What is the proton number and nucleon number of atom X?

Proton Nucleon
number number
A 4 9
B 4 5
C 9 4
D 1 9

5
20. The table shows the relative atomic masses of copper and oxygen.

Elements Copper Oxygen


Relative atomic mass 64 16

How many times is copper atom heavier than oxygen atom?

A 0.25
B 4
C 48
D 80

23
21. The symbol of sodium atom can be written as 11 Na

The nucleus of this sodium atom contains

A. 11 protons and 12 neutrons


B. 11 neutrons and 12 protons
C. 11 protons and 12 electrons
D. 12 neutrons and 11 electrons

22. The table below shows the proton number and the number of electrons of four
different particles.

Particle Proton number Number of electrons


P 8 8
Q 12 10
R 17 17
S 17 18

Which of the particles are ions?

A P and Q
B P and R
C Q and R
D Q and S

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23. The table below shows the number of protons of four atoms W, X, Y and Z.

Atom Number of protons


W 3
X 16
Y 17
Z 19

Which of the atoms have the same number of valence electrons?

A W and Z
B X and Z
C X and Y
D Y and Z

24. Calculate the number of moles of 16 g of Copper.


[ Relative atomic mass : Cu , 64 ]

A 0.25
B 0.75
C 2.50
D 7.50

25. An experiment is carried out to determine the empirical formula of oxide of metal
X.
The data below shows the result of the experiment.

Mass of crucible and lid = 139.50g


Mass of crucible, lid and metal X = 148.31g
Mass of crucible, lid and oxide of metal X = 150.48g

What is the empirical formula of oxide of metal X?


[ Relative atomic mass: O,16 ; X, 65 ]

A XO
B XO2
C X2O
D X2O3

7
26 What is the relative formula mass of hydrated copper(II) sulphate , CuSO4.5H2O?
[ Relative atomic mass : H , 1 ; O , 16 ; S , 32 ; Cu,64 ]

A 160
B 186
C 250
D 818

27. An oxide of metal X contains 6.9 g of metal X and 4.6 g of oxygen.


What is the empirical formula of oxide of metal X ?
[ Relative atomic mass: O, 16 ; X, 24 ]

A XO
B XO2
C X2O
D X2O3

28. The equation shows the reaction between calcium carbonate and nitric acid.

CaCO3(s) + 2HNO3 (aq ) Ca(NO3) 2(aq ) + H2O(l) + O2(g)

What is the volume of carbon dioxide gas released when 5 g of calcium carbonate
reacts completely?
[ Relative atomic mass: Ca,40 ; C,12 ; O,16 ; H ,1 ; one mole of any gas occupies
24 dm3 at room conditions]

A 1.2 dm3
B 2.4 dm3
C 12 dm3
D 24 dm3

29. What is the number of moles of 560 cm3 of carbon dioxide gas at STP?
[Given that number of mole of gas = volume ÷ molar volume ;
molar volume : 22.4 dm3 mol -1 at STP ]

A 0.025 mol
B 0.25 mol
C 2.5 mol
D 25 mol

8
30. The diagram shows the set-up of apparatus used to investigate diffusion in a solid
gel.

Gel

Potassium manganate(VII) cystal

After a few days, the entire solid gel turned purple.


What can we deduce from the above investigation?

A Potassium manganate(VII) dissolves in the gel.


B Potassium manganate(VII) is less dense than the gel.
C Potassium manganate(VII) reacts with the gel to produce purple
colour
D Potassium manganate(VII) particles diffuse through spaces
between the gel particles.

31. The equation shows the reaction between carbon and oxygen gas.

C (s) + O2 ( g) CO2 (g)

What is the mass of carbon dioxide gas released when 12 g of carbon reacts
completely in the reaction?
[ Relative atomic mass: C, 12 : O, 16 ]

A 12 g
B 28 g
C 32 g
D 44 g

9
32. The diagram shows two balloons P and Q.

1.5 mol of 2.5 mol of


carbon oxygen
dioxide

P Q

Balloon P is filled with 1.5 moles of carbon dioxide gas whereas balloon Q is
filled with 2.5 moles of oxygen gas.
What is the mass of carbon dioxide and oxygen ?
[ Relative atomic mass: C,12: O,16 ]

carbon dioxide oxygen


A 22 g 16 g
B 42 g 40 g
C 44 g 32 g
D 66 g 80 g

10
33. You are given a chemical equation:

2 Mg (s) + O2 (g) 2MgO(s)

Write three information based on the chemical equation.

i) ………………………………………………………………………………………..…

ii) ……………………………………………………………………………………….….

iii) ………………………………………………………………………………………….

34. The figure shows the relationship between the number of particles, the number of
moles and the mass of a substance.

÷ NA x Molar mass
Number of Number of Mass
particles moles
x NA ÷ Molar mass

Based on the above figure write the formulae to determine :

i) number of moles =

ii) mass of a substance =

iii) Number of particles =

11
35. A crystal of copper(II) sulphate is placed at the bottom of a beaker filled with water. The
beaker is left aside until the water turns blue.

After 1 day
Water
Blue solution of
Copper (II) copper (II)
sulphate sulphate, CuSO4
crystal

Name the process occurred. Explain your answer.

Name of process : …………………………………………………………………………….

Explanation : …………………………………………………………………………….

..……………………………………………………………………………………………………..

……………………………………………………………………………………………………….

……………………………………………………………………………………………………….

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36. The figure shows the heating curve of solid naphthalene.

temperature/oC

Q
R

P
time/min

Describe the changes in term of the movement and the forces of attraction of
naphthalene particles from point

(a) P to Q:

1. Movement: ………………………………………………………………..…

………………………………………………………………………………..

2. Forces of attraction:…………………………………………………..…...

……………………………………………………………………………………...

(b) R to S:
1. Movement: ……………………………………………………………..…

……………………………………………………………………….……..

2. Forces of attraction:……………………………………………………...

…………………………………………………………………..………….

13
Listen carefully to the text read by the teacher. Answer questions 37 and 38.

37. The smallest particle of an element that can participate in a chemical reaction is
called

A ion
B atom
C element
D molecule

38. A negatively-charged and positively-charged particles are called

A ions
B atoms
C elements
D molecules

Listen carefully to the text read by the teacher. Answer questions 39 and 40

39. Which of the following is not true about chemical equation?

A It can be written in words only.


B It shows the state of substances.
C It can be written in words or symbols.
D It is a shorthand description of a chemical reaction.

40. What are the states of matter that involved in a chemical reaction?

i) ………………………………………………………………………...

ii) ……………………………………………………………………….

iii) …………………………………………………….………………….

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PPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMI

CHEMISTRY
FORM 4
MODULE 2
PPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMI

PERIODIC TABLE OF ELEMENTS,


CHEMICAL BONDS

MINISTRY OF EDUCATION MALAYSIA


1 In the Periodic Table, the horizontal row of elements is known as the

A group
B family
C period
D series

2 The term ampotheric means

A alkali in nature.
B basic in nature.
C acidic in nature.
D both acidic and alkali in nature.

A measurement of the strength of an atom in its molecule to attract


electrons towards its nucleus.

3 Which of the following referred to the statement above?

A Electropositivity
B Electronegativity
C Electrical conductivity
D Electropositivity

4 What is an anion?

A A neutral particle.
B A positively-charged particle.
C A negatively-charged particle.

5 What is the type of chemical bond in sodium chloride, NaCl?

A Ionic bond.
B Single bond.
C Double bond.
D Covalent bond.

3
6 One hydrogen atom combines with another hydrogen atom to form a covalent
molecule by

A sharing electrons.
B accepting electron.
C donating electron.
D exchanging electrons.

7 Group 18 elements are known as

A halogens.
B noble gases.
C alkali metals.
D alkali earth metals

8 All the following elements are in group 17 except

A iodine.
B fluorine.
C chlorine.
D caesium

9 Elements in the Modern Periodic Table are arranged according to their

A boiling point.
B atomic mass.
C proton number.
D nucleon number.

10 Which of the following is true?

Noble gases Uses


A Neon To detect pipes leakage.
B Argon To fill photographic flash lamps.
C Helium To fill up balloons and airships.
D Krypton To fill light bulbs.

11 Which of the following scientists proposed the Law of Octaves ?

A Lothar Meyer
B John Newlands
C Dmitri Mendeleev
D Johann W. Dobereiner

4
12 Which of the following is true about the special properties of transition elements ?

I low density.
II act as catalysts.
III form complex ions.
IV form coloured compounds.

A I and II
B I and III
C I , III , and IV
D II , III , and IV

13 Which of the following is the property of ionic compounds?

A High melting point.


B Does not dissolve in water.
C Can conduct electricity.
D Dissolve in organic solvents.

14 An atom that receives an electron forms

A a cation.
B an anion.
C an ionic bond.
D a covalent bond.

15 Where is 23
X located in the Periodic Table?
11

Group Period
A 1 3
B 2 3
C 1 4
D 2 4

16 The type of chemical bond in an oxygen molecule is

A single covalent bond.


B double covalent bond.
C triple covalent bond.

5
17 Which of the following chemical formulae represents an ionic compound?

A CO2
B H2O
C K2O
D SO2

18 Which of the following pairs of elements will form a compound by sharing


electrons?

A Sodium and chlorine.


B Hydrogen and chlorine.
C Potassium and oxygen.
D Magnesium and oxygen.

19 Which of the following has the same number of electrons as neon?


[ Proton number : F, 9 ; Na , 11 ; Cl, 17 ; O , 8 ; Ne , 10 ]

A F
B O2-
C Cl-
D Na

20 Which of the following substances when dissolves in water, has the highest
electrical conductivity?

A Vinegar
B Ammonia
C Carbon dioxide
D Potassium oxide

21 Element Y with proton number 19 reacts with water to form gas X.


What is gas X ?

A Oxygen
B Hydrogen
C Carbon dioxide
D Nitrogen dioxide

6
22 Element A has proton number 20.
What is the position element A in the Periodic Table?

Group Period
A 1 3
B 2 3
C 1 4
D 2 4

23 Which of the following statements is true about element chlorine?

A Chlorine is more reactive than fluorine.


B Chlorine is more reactive than bromine.
C Chlorine is more electronegative than fluorine.
D Atomic size for chlorine is larger than bromine.

24 Which of the following statements is not true about sodium metal?

A Sodium is more reactive than lithium.


B Atomic size of sodium is larger than lithium.
C Sodium reacts with oxygen to form white solid.
D Tendency of sodium atom to release electron is higher than
potassium atom.

25 The electron arrangement of atom P is 2.8.8.1.


Which of the following is true about P?

I P reacts vigorously with water.


II P is more electropositive than sodium.
III P burns in air to produce white P oxides.
IV P reacts with chlorine gas to form yellow P chlorides.

A I , II, and III


B I, III, and IV
C II , III, and IV
D I, II, III, and IV

7
26 Which of the following substances has high melting point?

I Ethanol
II Sodium chloride
III Lead(II) bromide
IV Tetrachloromethane

A I and II only
B I and III only
C II and III only
D III and IV only

27 The proton number of element M is 8.


Which of the following is true about element M?

A M atom forms M2+ ion.


B M2+ ion achieves octet electron arrangement.
C Carbon atom combines with atom M to form a compound with chemical
formula CM2.
D Sodium atom combines with atom M to form a compound with chemical
formula NaM.

28 An element M reacts with oxygen to form a covalent compound, MO2. What is the
electron arrangement of atom M?

A 2.4
B 2.6
C 2.8.2
D 2.8.8.1

29 Which of the following compounds contain only covalent bonds?

A K2O
B CO2
C CO2
D K2O

8
30 Table shows the proton number of four atoms, P, Q, R and S.

Atom P Q R S
Proton number 17 8 11 6

Which of the following chemical formulae is correct?

A PQ
B SP
C RP2
D R2Q

31 Element P has an electron arrangement of 2.8.1.


Element R has an electron arrangement of 2.6.
Which of the following is true about the compound formed between elements P
and R?

Type of compound Chemical formula


A Ionic compound PR
B Ionic compound P2R
C Covalent compound PR
D Covalent compound P2R

9
Question 32 to 34.
Write the answers in the spaces provided.

32 Based on the information given below, describe the formation of ionic bond in
sodium chloride, NaCl.

1. Sodium atom with ……….. 2.8.1 …………. .electron to


achieve ……….. electron ……………
2. Chlorine atom with …………… 2.8.7 ……………. electron to
achieve ……………. electron ………...
3. Sodium ion and ……………. ion formed are …………. to one
another by ………….. force.

The formation of sodium chloride,

1. ……………………………………………………………………………

……………………………………………………………………………

2. .…………………………………………………………………………..

……………………………………………………………………………

3. ……………………………………………………………………………

….……………………………………………………………………………

10
33 Diagram shows the electron arrangements of hydrogen atom and chlorine atom.

Hydrogen atom Chlorine atom Hydrogen chloride


- 1 valence - 7 valence - share electrons
electron electrons - covalent bond
- needs one - needs one
more electron more electron
to achieve to achieve
duplet octet
electron electron
arrangement arrangement

Based on the information given below, describe the formation of covalent bond in
hydrogen chloride.

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

11
34 The table below shows the properties of ionic compounds and covalent
compounds.

Properties Ionic Covalent


compound compound
Melting point High Low
Conduct electricity in molten and Yes No
aqueous
Solubility in water Yes No

Based on the table describe three differences between ionic compounds


and covalent compounds.

………...............................................................................................................

…………………………………………………………………………………………

…………………………………………………………………………………………

…………………………………………………………………………………………

…………………………………………………………………………………………

…………………………………………………………………………………………

…………………………………………………………………………………………

…………………………………………………………………………………………

Listen carefully to the text read by the teacher. Answer the questions 35
and 36 that follows.

35 Why do the ionic compounds have high melting and boiling points?

………...............................................................................................................

12
36 What is another property for the ionic compounds?

………...............................................................................................................

Listen carefully to the text read by the teacher. Answer the questions 37, 38,
39 and 40 that follows.

37 What happen when a piece of sodium is placed in the water?

………...............................................................................................................

38 State the changes of universal indicator when added to the solution.

………...............................................................................................................

39 Name the gas released during the reaction.

………...............................................................................................................

40 Name the product formed.

………...............................................................................................................

13
PPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMI

CHEMISTRY
FORM 4
MODULE 3
PPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMI

ELECTROCHEMISTRY

MINISTRY OF EDUCATION MALAYSIA


1 The diagram shows a type of cell that consists of batteries, electrolyte and two
electrodes.

Battery

Carbon electrodes

Electrolyte

Name the cell.

A Electrode cell
B Electrolyte cell
C Electrolytic cell
D Electrolysis cell

2 An electrode which is connected to the positive terminal of the source of electricity


in an electrolytic cell is called

A anion
B cation
C anode
D cathode

3
3 The diagram shows the decomposition of molten lead(II) bromide into its
constituent elements when an electric current passes through it.

Carbon electrodes

Molten lead(II) bromide

Heat

What is the process called?

A Extraction
B Purification
C Electrolysis
D Electroplating

4
4 The diagram shows an experiment to prevent the iron ring from rusting.

Copper
strip Iron coated
Iron CuSO4 with copper
ring solution

Name the process involved.

A Extraction
B Purification
C Electroplating
D Neutralization

5 What is meant by electrolytes?

A Substances that can conduct electricity in any state but are not chemically
changed.
B Substances that can conduct electricity in solid or molten but are not
chemically changed.
C Substances that can conduct electricity in aqueous solution only and
undergo chemical changes.
D Substances that can conduct electricity either in molten state or in aqueous
solution and undergo chemical changes.

6 Ion that is attracted to the positive terminal during electrolysis is known as

A anion
B proton
C cation
D electron

5
7 Which of the following substances undergoes electrolysis?

A Molten sulphur
B Glucose solution
C Molten lead metal
D Sodium chloride solution

8 Which of the following is not a factor that affects the electrolysis of an aqueous
solution?

A Position of ions in electrochemical series


B Types of electrodes
C Presence of catalyst
D Concentration of ions

9 What is the change of energy that occurs in a voltaic cell?

A Electrical energy to potential energy.


B Potential energy to chemical energy.
C Electrical energy to chemical energy.
D Chemical energy to electrical energy.

10 Which of the following pairs of electrodes are inert?

A Copper and carbon.


B Carbon and platinum.
C Copper and magnesium.
D Platinum and magnesium.

11 What are the ions that present in copper(II) sulphate solution?

A Copper(II) ion and sulphate ion.


B Copper(II) ion and hydrogen ion.
C Copper(II) ion, hydrogen ion, sulphate ion and oxide ion.
D Copper(II) ion, hydrogen ion, sulphate ion and hydroxide ion.

6
12 What are the ions that present in the molten lead(II) bromide?

A Lead(II) ion and bromide ion only.


B Lead(II) ion, hydrogen ion and bromide ion only.
C Lead(II) ion, hydroxide ion and bromide ion only.
D Lead(II) ion, hydrogen ion, hydroxide ion and bromide ion.

13 The electrochemical series can be constructed based on

A the ability of a metal to displace another metal from its salt solution.
B the availability of an element in many organic substances.
C the ability of an element to exist in more than one oxidation number.

14 The table shows the differences between electrolytic cell and voltaic cell.
Choose the false statement.

Characteristic Electrolytic cell Voltaic cell


A Energy changes Electrical energy→ chemical Chemical energy → electrical
energy energy
B Flow of electrons From negative to positive From positive to negative
electrodes. electrodes.
C Types of Same or different types of Two different types of metals.
electrodes metals or graphite
electrodes.

7
15 Diagram shows the electrolysis of molten lead(II) bromide.

Carbon electrodes

Molten lead(II) bromide

heat

What are the observations at the anode and cathode?

Anode Cathode
A Colourless gas is given Grey solid is deposited
off
B Brown gas is given off Colourless gas is given off
C Brown gas is given off Grey solid is deposited
D Grey solid is deposited Bromine gas is given off

16 The diagram shows the set-up of apparatus for the electrolysis of concentrated
iron(III) chloride solution using carbon electrodes.

X Y Concentrated iron(III) chloride solution


Carbon electrodes

What are the products formed at test tubes X and Y during the electrolysis?

X Y
A Chlorine gas Hydrogen gas
B Hydrogen gas Oxygen gas
C Chlorine gas Iron metal
D Hydrogen gas Chlorine gas

8
17 Which of the following voltaic cells shows the correct direction of electron flow?

A C

Magnesium Copper Aluminium


Tin

Dilute
hydrochloric
acid

B D

Lead Zinc Iron Zinc

Dilute
hydrochloric
acid

18 The diagram shows a part of the electrochemical series.

Ca Mg Al Zn Fe

Electropositivity decreases

Based on the electrochemical series, which of the following pairs of the terminals is
correct?

Negative terminal Positive terminal


A Aluminium Iron
B Zinc Magnesium
C Aluminium Magnesium
D Iron Zinc

9
19 Which of the following pairs of metals that gives the highest voltage in a voltaic
cell?

A Zinc and iron.


B Tin and lead.
C Copper and tin.
D Silver and magnesium.

20 The diagram shows an experiment of the electrolysis of molten lead(II) bromide.

Carbon electrodes

Molten lead(II) bromide

heat

Which of the statements is true?

A Solid lead(II) bromide is a


molecule.
B Molten lead(II) bromide is a molecule.
C Solid lead(II) bromide contains freely moving ions.
D Molten lead(II) bromide contains freely moving
ions.

10
21 The diagram shows an electrolysis of sodium chloride solution.

+ −

Carbon Sodium chloride


electrodes solution

What are the ions that are attracted to the cathode?

A Sodium ion , Na+ and chloride


ion, Cl-
B Sodium ion, Na+ and hydrogen
ion, H+
C Chloride ion, Cl- and hydroxide
ion, OH-
D Hydrogen ion, H+ and hydroxide
ion, OH-

22 Q is a metal that can displace lead from lead(II) nitrate solution.


Which of the following metals cannot displace Q from its salt solution?

A Iron.
B Silver.
C Aluminium.
D Magnesium.

23 Which of the following compounds could be used as an electrolyte in


electroplating of iron spoon with silver?

A Silver nitrate solution.


B Iron(II) chloride solution.
C Copper(II) sulphate solution.
D Dilute hydrochloric acid.

11
24 Sodium chloride does not conduct electricity in solid state because

A it has a high density.


B it has a high melting point.
C the sodium ions and the chloride ions are only present in molten state.
D the sodium ions and the chloride ions are held in a fixed position in the crystal
lattice.

25 In the diagram below, the electrons flow from the zinc electrode to the copper
electrode because

e e

Zinc Copper

Dilute sulphuric acid

A copper is more reactive than zinc.


B sulphuric acid contains free electrons.
C zinc is more electropositive than copper.
D there is more electrons at the zinc electrode.

12
26 The diagram shows a Daniell cell using magnesium and lead as electrodes.

Magnesium electrode Lead electrode

Porous pot
Magnesium sulphate solution Lead(II) nitrate solution

Which of the following represents the half-equation at lead electrode?


A 2H+ + 2e Æ H2
B Pb Æ Pb2+ + 2e
C Pb2+ + 2e Æ Pb
D Mg2+ + 2e Æ Mg

27 The diagram below shows the set-up of apparatus to coat an iron spoon with
copper.

Copper strip Iron spoon

Aqueous copper(II) sulphate solution

What can be observed at the anode and cathode after 30 minutes?

Anode Cathode
A Copper strip becomes thinner Gas bubbles are released
B Copper strip becomes thicker Brown solid is formed
C Copper strip becomes thinner Brown solid is formed
D Copper strip becomes thicker Gas bubbles are released

13
28 A solution of sodium nitrate is electrolysed by using carbon electrodes.
Which of the following statements shows the reaction that occur at the beginning
of the electrolysis?

A Nitrate ions are discharged at the anode.


B Sodium ions are discharged at the cathode.
C Hydrogen ions receive electrons at the
anode.
D Hydrogen ions receive electrons at the
cathode.

29 The diagram shows four simple voltaic cells.

Which of the cells shows the highest potential difference?

A C

Aluminium
Copper
Copper

Dilute
hydrochloric
acid
B D

Zinc Copper Lead Copper

Dilute
hydrochloric
acid

14
30 The table shows pairs of metals and the results obtained when they are used as
electrodes in chemical cells.

Pair of Voltage/V Negative terminal


Metal
P/Q 0.78 P
R/Q 2.72 R
S/R 0.72 R
S/P 1.22 S

The electrochemical series formed in descending order is

A P, Q, R, S
B S, R, P, Q
C R, P, Q, S
D R, S, P, Q

31 The tables show the ions present in aqueous silver nitrate, AgNO3 and the ions
that are attracted to the cathode and the anode during the electrolysis.

Electrolyte Silver nitrate solution


Ions present Ag+, NO3−, H+, OH−

Electrode Cathode Anode


Ions attracted Ag+, H+ NO3−, OH−

Based on the tables,


(a) explain the electrolysis of aqueous silver nitrate, AgNO3, using
carbon electrodes.

…………….……………………………………………………………………………

…………………………………………………………………………………………

…………………………………………………………………………………………

(b) name the products at the cathode and anode.

…………………………………………………………………………………………

15
32 The diagram shows a simple voltaic cell.

Metal X Metal Y

Electrolyte

Based on the diagram, describe the structure of the simple voltaic cell.

………………………………………………………………………………………………….

………………………………………………………………………………………………….

………………………………………………………………………………………………….

………………………………………………………………………………………………….

Listen carefully to the text read by the teacher. Answer questions 33


and 34.

33 Name the ore that contains aluminium oxide.

A Galena
B Bauxite
C Hematite
D Casiterite

34 What is the function of adding cryolite to aluminium oxide?

A To melt the ore.


B To act as the anode.
C To act as the cathode.
D To lower the melting point of aluminium oxide.

16
Listen carefully to the text read by the teacher. Answer questions 35 and 36.

35 What is electrochemical series?

A An arrangement of metals based on its reactivity with oxygen.


B An arrangement of metals based on its reactivity with hydrogen.
C An arrangement of metals based on the tendency of each metal atom to
accept electrons.
D An arrangement of metals based on the tendency of each metal atom to
donate electrons.

36 Which of the following is true about the electrochemical series?

A It can be used to determine the standard cell voltage.


B It is based on the tendency of a metal atom to accept electron.
C The metal which is situated at a higher position in the series will be the negative
terminal.
D The greater the tendency of a metal atom to accept electron the higher it is in the
series.

17
PPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMI

CHEMISTRY
FORM 4
MODULE 4
PPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMI

ACIDS AND BASES


& SALTS

MINISTRY OF EDUCATION MALAYSIA


1 What is meant by ‘strong acid’?

A Acid that partially ionized to produce low concentration of hydrogen ions


B Acid that partially ionized to produce high concentration of hydrogen ions
C Acid that completely ionized to produce low concentration of hydrogen ions
D Acid that completely ionized to produce high concentration of hydrogen
ions.

2 The equation below represents a reaction between acid and alkali.

Acid + alkali salt + water

What is the name of this reaction?

A Titration.
B Precipitation.
C Fermentation.
D Neutralisation.

3 The diagram shows a flow chart to identify substance P.

Substance P

Test for Test for Test for


gases anions cations

What is the type of analysis used to identify substance P?

A Qualitative analysis
B Quantitative analysis
C Psychometric analysis
D Spectrometry analysis

3
4 What is salt?

A A mixture formed when an acid is added to a metal or an ammonium compound.


B A mixture formed when an alkali is added to a metal or an ammonium compound.
C A compound formed when the hydrogen ion of an acid is replaced by a metal ion or
an ammonium ion.
D A compound formed when the hydroxide ion of an alkali is replaced by a metal ion or
an ammonium ion.

5 An indicator is added to an alkali and acid solution respectively.


Which of the following is correct?

Indicator Colour in alkali Colour in acid


A Phenolphthalein colourless pink
B Phenolphthalein pink colourless
C Methyl orange red yellow
D Methyl orange red orange

6 Which of the following is not a monoprotic acid?

A Nitric acid
B Sulphuric acid
C Hydrochloric acid
D Methanoic acid

4
7 The diagram below shows changes that occur before and after water is added to
a chemical substance.

-
CH3COOH H+ CH3COO

H+
+
CH3COOH H
CH3COOH

CH3COO
- H+
CH3COOH

Before adding water After adding water

Name the substance.

A Acid.
B Salt
C Base.
D Alkali.

8 Which of the following is an insoluble salt?

A Silver nitrate
B Lead(II) sulphate
C Sodium carbonate
D Copper(II) chloride

9 Neutralisation process is used in various fields in our daily life.


Which of the following statements is false?

A Vinegar is used to prevent coagulation of latex


B An antacid is used to neutralise excess acid in the stomach.
C Acidic soil is treated with powdered lime, lime stone or ashes of burnt wood
D Toothpaste is used to neutralise the acid produced by bacteria in our mouth.

10 Which of the following is the physical characteristic of crystals?

A Crystals of the same substance have same size.


B Crystals of the same substance have different shapes.
C Crystals have same angles between two neighbouring surfaces.
D Crystals have flat surfaces, straight edges and sharp angles.

5
11 The diagram shows the pH values of five different solutions.

V W X Y

pH = 1 pH = 4 pH = 8 pH = 12

Which of the solutions has the highest concentration of hydrogen ions?

A V
B W
C X
D Y

12 The diagram shows types of particles in a solution.

NH4+ OH-
-
OH
NH4 + NH3
NH4+
NH3 OH-

The solution is a

A weak acid
B strong acid
C weak alkali
D strong alkali

6
13 The table shows the concentration and pH value of sodium hydroxide solution,
NaOH in test tube P, Q, R and S.

Test Concentration of NaOH pH value


tube solution (mol dm-3)
P 0.0001 10
Q 0.001 11
R 0.01 12
S 0.1 13

Which of the following statements is true?

A When the concentration of sodium hydroxide solution increases, the concentration


of hydrogen ions decreases.
B When the concentration of sodium hydroxide solution increases, the concentration
of hydroxide ions decreases.
C When the concentration of sodium hydroxide solution increases, the concentration
of hydrogen ions also increases.
D When the concentration of sodium hydroxide solution increases, the concentration
of hydroxide ions also increases.

14 The diagram shows the titration of sodium hydroxide solution with dilute
hydrochloric acid.

Burette

Dilute hydrochloric acid

NaOH solution + phenolphthalein

What is the function of phenolphthalein?

A To determine the amount of the product.


B To determine the degree of ionization of an acid.
C To determine the degree of ionization of an alkali.
D To determine the end point of neutralisation reaction.

7
15 The diagram shows the results when electricity is passed through two solutions
R and S.

Carbon
Solution R electrod Solution S

Bulb does not light up Bulb lights up

Based on the observations, solution R and solution S are

Solution R Solution S
A Sodium hydroxide in water. Sodium hydroxide in methyl benzene.
B Ammonia in propanon. Ammonia in methyl benzene.
C Hydrochloric acid in water. Hydrochloric acid in propanon.
D Ethanoic acid in methyl benzene. Ethanoic acid in water.

16 Which of the following ions forms a white precipitate which will dissolve in excess
sodium hydroxide solution and ammonia solution?

A Zn2+
B Ca2+
C Al3+
D Pb2+

17 Which of the following is used to prepare lead (II) sulphate?

A Add lead metal to sodium sulphate.


B Add lead(II) nitrate to potassium sulphate.
C Add lead(II) chloride to sodium sulphate
D Add lead(II) carbonate to potassium sulphate.

8
18 The equations below show the reaction used to prepare insoluble salt.

AgNO3 + KCl AgCl + KNO3


CaCl2 + Na2CO3 CaCO3 + 2NaCl

Which of the following pairs is insoluble salt?

A AgCl and NaCl


B AgCl and CaCO3
C KNO3 and NaCl
D KNO3 and CaCO3

19 Which of the following salts is prepared by titration method?

A Copper(II) nitrate
B Lead(I) nitrate
C Magnesium nitrate
D Potassium nitrate

20 The equation below shows the neutralisation reaction between hydrochloric acid
and sodium hydroxide solution.

HCl + NaOH Æ NaCl + H2O

What is the concentration of 50 cm3 hydrochloric acid, HCl needed to neutralise


50 cm3 of 0.5 mol dm-3 sodium hydroxide, NaOH solution?

A 0.25 mol dm
B 0.50 mol dm
C 0.75 mol dm
D 1.00 mol dm

9
21 The equation below shows the reaction between sodium and oxygen.

4Na + O2 Æ 2Na2O

What is the mass of sodium oxide formed when 2.3g of sodium reacts
completely with oxygen?
[Relative atomic mass : Na, 23 ; O, 16]

A 1.55g
B 3.10g
C 4.65g
D 6.20g

22 What is the volume of 0.1 mol dm-3 nitric acid required to neutralise completely
25.0 cm3 of 0.1 mol dm-3 sodium hydroxide solution?

A 10.0 cm3
B 25.0 cm3
C 30.0 cm3
D 45.0 cm3

23 What is the concentration of hydrogen ion in 0.10 mol dm-3 nitric acid?

A 0.05 mol dm-3


B 0.10 mol dm-3
C 0.15 mol dm-3
D 0.20 mol dm-3

10
24 The table below shows the information in a qualitative analysis.

Reagent Observation Result


Sodium hydroxide • White Zn2+
solution until excess precipitate Al3+
• Dissolve in Pb2+
excess
Aqueous ammonia • White Al3+
until excess precipitate Pb2+
• Does not
dissolve in
excess
Potassium iodide • Yellow Pb2+
solution precipitate

A solution may contain Pb2+ ions, Zn2+ ions or Al3+ ions.


Explain the chemical test to confirm the presence of ions Pb2+ , Zn2+ and Al3+ .

Answer:

………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
……………………………………………………………………………………………………...
……………………………………………………………………………………………………...
……………………………………………………………………………………………………...

11
25 The equation below shows the reaction when zinc nitrate is heated strongly.

2Zn(NO3)2 2ZnO + 4NO2 + O2

State three observations when zinc nitrate is heated strongly.

Answer:

………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………

26 The diagram shows the heating process of zinc carbonate.

Zinc carbonate

Heat
Lime water

State two observations for the heating of zinc carbonate.

Answer:

………………………………………………………………………………………………………
………………………………………………………………………………………………………

12
27 The diagram below shows the flow chart for the chemical test of Fe2+ ions and
Fe3+ ions.

Test I
Potassium
Solution Light blue Fe2+ ions
hexacyanoferrate(II)
contains precipitate
K4Fe(CN)6
Fe2+ ions
or Fe3+
ions. Dark blue
Fe3+ ions
precipitate

Test II
Potassium
Solution thiocyanate No change Fe2+ ions
contains KSCN
Fe2+ ions
or Fe3+ Blood red
ions. Fe3+
solution

Based on the flow chart, explain how to differentiate Fe2+ ions and Fe3+ ions.

Answer:

………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………
………………………………………………………………………………………………………

13
Listen carefully to the text read by the teacher. Answer questions 28 and 29.

28 State one common use of salt.

……………………………………………………………………………………………………

29 State one effect when we take excess salt in our food?

……………………………………………………………………………………………………

Listen carefully to the text read by the teacher. Answer questions 30, 31, and 32.

30 Name a substance that can be used to overcome the gastric problem.

……………………………………………………………………………………………………

31 What can be used to reduce pain caused by bee sting?

……………………………………………………………………………………………………

32 State the other use of neutralisation.

……………………………………………………………………………………………………

14
PPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMI

CHEMISTRY
FORM 4
MODULE 5
PPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMIPPSMI

MANUFACTURED SUBSTANCES IN
INDUSTRY

MINISTRY OF EDUCATION MALAYSIA


1. The diagram shows the formation of a large molecule by joining together all the sub-
units in process X.

Large molecule

Sub-units

What is proses X?

A Freezing
B Refraction
C Polymerisation
D Depolymerisation

2. What is Contact Process?

A An industrial process for the manufacture of ammonia


B An industrial process for the manufacture of nitric acid
C An industrial process for the manufacture of sulphuric acid
D An industrial process for the manufacture of hydrochloric acid

3. What is a composite material?

A A mixture of elements and has metallic properties


B A long chain molecule formed by joining together many small repeating units
C A material with more superior properties that formed by combining two or
more different substances

3
4. What is an alloy?

A An alloy is a mixture of two or more ions with a certain fixed composition.


B An alloy is a mixture of two or more atoms with a certain fixed composition.
C An alloy is a mixture of two or more elements with a certain fixed
composition.
D An alloy is a mixture of two or more molecules with a certain fixed
composition

5. Name the industrial process that produce ammonia?

A Haber process
B Contact process
C Ostwald process

6. Which of the following is not the property of ammonia?

A Colourless gas
B Soluble in water
C Changes moist blue litmus paper to red
D Changes moist red litmus paper to blue

7. Which of the following are the uses of ammonia in daily life?

I To manufacture nitric acid


II To manufacture explosives
III To manufacture sulphuric acid
IV To manufacture nitrogenous fertilizers

A III and IV
B I, II and III
C I, II and IV
D I, II, III and IV

4
8. Polymer X is used to make safety glass, lens and reflectors. Its monomer is
methylmethacrylate.
What is the name of polimer X?

A Nylon
B Perspex
C Polythene
D Polypropene

9. The chemical equation below shows the reaction of the manufacture of sulphuric acid
in stage II.

SO2(g) + O2(g) SO3(g)

What is the optimum conditions for the reaction in stage II

Temperature/°C Catalyst Pressure/ atm


A 450 Iron 1
B 450 Iron 10
C 450 Vanadium(V) oxide 1
D 450 Vanadium(V) oxide 10

10. The diagram shows the arrangement of atoms in alloy X.

Tin

Copper

Alloy X

What is the name of alloy X?

A Steel
B Brass
C Bronze
D Duralumin

5
11.Which of the following is not true about the uses of sulphuric acid?

A Leather tanning
B Manufacture of paint
C Production of margerine
D Manufacture of detergents

12. Which of the following is not the aim of making alloy?

A To prevent rusting
B To minimize corrosion
C To improve physical appearance
D To lower the melting of the metal

13. Which of the following pairs is not true?

Process Catalyst
A Manufacture of sulphuric acid Vanadium(V) oxide
B Manufacture of ammonia Copper(II) sulphate
C Manufacture of nitric acid Platinum
D Manufacture of margerine Nickel

14. Which of the following information is true?

Type of glass Properties


• Low melting point
A Lead crystal glass
• High density
• High melting point
B Soda lime glass
• Reflects light rays
• Low melting point
C Borosilicate glass
• High refractive index
• Low melting point
D Fused silicate glass • More resistant to
chemical

6
15. The diagram shows an experiment to investigate the rate of corrosion of iron nail,
steel nail and stainless steel nail.

Jelly solution + potassium hexacyanoferrate(III)

Iron nail Steel nail Stainless steel nail

The manipulated variable in the experiment is

A type of nails
B rate of corrosion
C condition of experiment

7
16. The diagram shows the structure of polymer P

H Cl H Cl H Cl H Cl

C C C C C C C C

H H H H H H H H

Which of the following is the monomer of polymer P?

A H Cl C Cl H H

C C C C C H

H H H H
H Cl H
B H Cl D

C C C H
H C C H

H H
H H

17. Which of the following statements explains the reason of why steel is harder and
stronger than iron?

A The orderly arrangement of atoms in steel enables the layer of atoms to slide on
one another
B The defects in the arrangement of atom in steel allows the layer of atoms to
slide on one another
C The presence of foreign atoms disturbs the orderly arrangement of atom in
steel thus reduces the layer of atoms from sliding on one another

8
18. What is the percentage of nitrogen by mass in ammonium sulphate, (NH4)2SO4?
[Relative Atomic Mass : H,1; N,14; O, 16; S, 32]

A 4.71 %
B 10.60 %
C 21.21 %
D 28.00 %

19. Fertilizer ammonium sulphate can be prepared by reacting ammonia with sulhuric
acid.
Which of the following balanced chemical equation is correct?

A NH3 + HSO4 → NH4SO4


B 2NH3 + H2SO4 → (NH4)2SO4
C NH3 + H2SO4 → (NH4)2SO4
D 2NH3 + HSO4 → (NH4)2SO4

9
20. The following shows the composition, properties and uses of alloy X.

Alloy X

Composition Properties Uses

• luster • Making of souvenirs


• 96% tin
• shiny •
• 3% copper
• strong
• 1% antimony

What is alloy X?

A Steel
B Brass
C Pewter
D Stainless steel

10
21. The diagram shows the environmental pollution caused by sulphur dioxide.

SO2
SO2 SO2
O2 Acid rain
O2
Acid rain

SO2

(a) State two types of pollution.

1 : ………………………………………………………………………..…………………

2 : ………………………………………………………………………………..…………

(b) State one effect caused by each pollution in (a)

1: …………………………………………………………………………...………………

2: …………………………………………………………………………………...………

11
(c) Explain the formation of acid rain. You may used the keywords below.

SO2 – factories.
Burning petrol – SO2.
SO2 – water and oxygen – acid rain.

………………………………………………………………………………………………

……………………………………………………………………………...………………

………………………………………………………………………………………………

22. The diagram shows the manufacturing of ammonia in an industry.

Reactor

Mixture: N2 + H2
N2
gas Temperature: 450 OC
NH3
Pressure: 200 atm
H2
gas Catalyst: Iron

Based on the diagram in the manufacturing of ammonia, NH3 , answer the following
questions.

(a) What are the raw materials used?

…..…………………………………………………………………………………………

12
(b) Describe the manufacturing of ammonia and state the conditions involved.

……………………….………………..………………………..…………………………

…….……………………………..……………………….……………………...…………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………...……

………………………………………………………………………………………………

(c) Write the chemical equation involved.

…………………………………………………………………………………...…………

13
23. The table below shows three stages involved in the manufacturing of sulphuric acid.

Stage Reactant Product

I Sulphur and oxygen Sulphur dioxide

II Sulphur dioxide and oxygen Sulphur trioxide

Sulphur trioxide and concentrated sulphuric acid Oleum


II
Oleum and water Sulphuric acid

Explain the manufacturing of sulphuric acid. Your explanation should start with stage
I until you finally get the sulphuric acid.

………………………………………………………………………………………..…………

………………………………………………………………………………………..…………

………………………………………………………………………………………..…………

……………………………………………………………………………..……………………

……………………………………………………………………………………..……………

Listen carefully to the text read by the teacher. Answer questions 24, 25 and 26.

24. What is the pH of natural rain water and the pH of acid rain?

………………………………………………………………………………………………

25. Name the gas that caused acid rain

…….…………………………………………………………………..………………………

26. How is acid rain formed?

….………………………………………………………………………………..……………

….…………………………………………………………………………………..…………

14
Listen carefully to the text read by the teacher. Answer questions 27, 28 and 29.

27. Polymer is made up of


………………………………………………………………………………..………………

28. State two examples of natural polymer


………………………. ……………………………………………..……………………....

29. Man-made polymers are known as


…………………………………………………………………………………………...…..

Listen carefully to the text read by the teacher. Answer questions 30, 31 and 32.

30. State three examples of ceramic.

………………………………………………………………………………………………
.………………………………………………………………………………………..……
………………………………………………………………………………………………

31. Ceramics are made of

………………………………………………………………………………………………..

32. State two properties of ceramic.

………………………………...……………………………………………..………………

…………………………………………..…………………………………………...………

15

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