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Table Of Contents

1-2 CLASSIFICATION OF LIGAND SUBSTITUTION MECHANISMS
1-3 OPERATIONAL TESTS OF MECHANISM
1-4 SUMMARY OF MECHANISTIC CLASSIFICATIONS
1-5 CORRELATION OF CLASSIFICATION SCHEMES
1-6 PROSPECTUS
2-1 MODEL FOR SQUARE-PLANAR SUBSTITUTIONS
2-2 RATE LAW AND STEREOCHEMISTRY
2-3 EFFECT OF LIGANDS IN THE COMPLEX ON THE RATE
2-4 EFFECT OF THE ENTERING GROUP ON THE RATE
0.53 50 3.9 50 0.090 30 1.45 20 very large very large 0.19 100
2-5 SOLVENT EFFECTS
2-6 EFFECT OF CHARGE ON THE COMPLEX
2-7 THERMODYNAMIC PARAMETERS
2-8 EVALUATION OF THE MODEL AND EVIDENCE FOR AN A PROCESS
2-9 SUMMARY O F Pt(l1) SUBSTITUTION REACTIONS
2-10 OTHER CENTRAL METAL ATOMS
3-2 RATE LAWS AND RELATED MATTERS
3-3 STERIC EFFECTS IN Co(1ll) REACTIONS
3-4 THE ROLE OF THE LEAVING GROUP
3-5 EFFECTS OF CHARGE AND CHELATION
3-6 BASE HYDROLYSIS OF Co(lll) COMPLEXES
3-7 THE EFFECTS OF NONLABILE LIGANDS
3-8 Co(ll1) STEREOCHEMISTRY
3-9 REACTIONS IN NONAQUEOUS SOLVENTS
3-10 EVIDENCE FOR Id PROCESSES
3-14 ACID HYDROLYSIS AND ANATION OF Cr(ll1) AND Rh(lll) COMPLEXES
3-15 Cr(lll) AND RELATED BASE HYDROLYSIS REACTIONS
3-16 MECHANISMS EMPLOYED BY OTHER OCTAHEDRAL COMPLEXES
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Langford_Lsp

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Published by: anakdamit on Apr 12, 2011
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04/02/2012

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