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AIEEE 2011 Sample/Guess Paper-3

AIEEE 2011 Sample/Guess Paper-3

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Published by Aditya Kumar
AIEEE 2011 Sample/Guess Paper
AIEEE 2011 Sample/Guess Paper

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Published by: Aditya Kumar on Apr 17, 2011
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04/21/2011

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Part
1: CHEMISTRY
Useful Data :Atomic Mass : H = 1, C = 12, N = 14, O = 16, Na = 23, S = 32, Cl = 35.5, K = 39, Ca=40,Mn = 55, Fe = 56, Cu = 63.5, Br=80, I = 127.SECTION
I
Straight Objective Type
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B),(C) and (D), out of which ONLY ONE is correct.
1.
Identify the end product in the given sequence :
      
h / Br
2
X
        
.alcKOH
Y
    
NBS
Z
(a) 1
bromo cyclopentene (b) 2
bromo cyclopentene(c) 3
bromo cyclopentene (d) 4
bromo cyclopentene
2.
The enol form of cyclo hexane
1, 3, 5
trione represented by :(a)
OHOHHO
(b)
OHOHOH
(c)
OHOHHO
(d)
OHOHHO
3.
A hydrocarbon P on photochlorination gives a mixture containing only one monochloroand two dichloro derivatives. 3.6 gm of P occupies 1.12 litre at NTP. The hydrocarbon Pis:(a) n
pentane (b) 2,2,3,3
tetra methyl butane(c) 2
methyl butane (d) 2,2
dimethyl propane
4.
To prepare 3
ethyl
3
pentanol the reagents needed are :(a) ethylmethyl ketone and ethylmagnesium bromide followed by hydrolysis.(b) diethyl ketone and methylmagnesium bromide followed by hydrolysis.(c) diethyl ketone and ethylmagnesium bromide followed by hydrolysis.(d) ethylmethyl ketone and propylmagnesium bromide followed hydrolysis.

Space for rough work

 
 
 
SECTION
II
 Multiple Correct Answer Type
This section contains 5 multiple correct answer(s) type questions. Each question has 4choices (A), (B), (C) and (D), out of which ONE OR MORE is/are correct.
5.
Which of the following statements is correct :(a) The substituents get lower number in comparison to the functional group.(b) The IUPAC name of acid amides is alkanamide.(c) The IUPAC name of alkenes ends with the suffix
ene.(d) The IUPAC name of isocynide ends with suffix
nitrile
6.
8 ml of a hydrocarbon requires 40 ml of dioxygen for complete oxidation under similarconditions. Hydrocarbon cannot be(a) propene (b) propyne(c) propane (d) cyclopropane
7.
Which of the following statement(s) is/are incorrect :(a) Hydrogen atoms of acetylene are neutral while that of ethylene are acidic.(b) In S
N2
bond formation and bond breaking takes place in one step.(c) The rate of reaction in S
N1
depends upon the concentration of substrate and attackingreagent.(d) The nuclear reactions of benzene are the example of neucleophilic substitutionreactions.
8.
Which of the following is a dissymmetric compound(a)
COOH
 
OH
 
H
 
CH
3
(b)
COOH
 
OH
 
H
 
H
 
HO
 
COOH
 
(+) form
 
(c)
COOH
 
OH
 
OH
 
H
 
H
 
COOH
 
(d)
COOH
 
H
 
OH
 
HO
 
H
 
COOH
 
(
) form
 
9.
For the reaction shown below if the concentration of KCN is increased four times, the rateof the reaction will not be changed by :
MeMeCl + KCN
       
MeOH.aq
 MeMeCN + KCl
(a) 2 times (b) 4 times(c) 16 times (d) unchanged

Space for rough work

 
 
 
SECTION
III
 
 Matrix Match Type
This section contains 2 questions. Each question contains statements given in twocolumns, which have to be matched. The statements in
Column I
are labeled A, B, C andD, while the statements in
Column II
are labelled p, q, r, s and t. Any given statement in
Column I
can have correct matching with
ONE OR MORE
statement(s) in
Column II
.The appropriate bubbles corresponding to the answers to these questions have to bedarkened as illustrated in the following example:If the correct matches are A
 – 
p, s and t; B
 – 
q and r; C
 – 
p and q; and D
 – 
s and t; thenthe correct darkening of bubbles will look like the following:
pqr spqr spqr spqr s
ABCDpqrs
tttt
t
10.Column-I Column-II
(A) Nucleophile (p) R
4
N
+
(B) Electrophile (q)RN
+
C
 
(C) Neither electrophile nor nucleophile (r) SO
3
(D) Both nucleophile as well as electrophile (s) CH
2
=O
11.Column-I Column-II
(A)pent
3
en
1
yne(p) Homocyclic(B)N, N
dimethylethanamine(q) Hetrocyclic(C) Ethynylcyclohexene (r) Alkenyne(D) Oxirane (s) Aliphatic

Space for rough work

 

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