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AIEEE Chemistry

AIEEE Chemistry

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Published by Raja Pramod

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Published by: Raja Pramod on May 24, 2011
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12/29/2012

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  S  A   K  S   H   I
CHEMISTRY
1.Silver Mirror test is given by which oneof the following Compounds?1) Formaldehyde2)Benzophenone3)Actaldehyde4)Acetone
Ans:
1 or 32.A5.2 molal aqueous solution of methylalcohol, CH
3
OH, is supplied. What is themole fraction of methyl alcohol in thesolution?1)0.0862)0.0503)0.1004) 0.190
Ans:
13.Trichloroacchetaldehyde was su-bjectedto Cannizzaro's reaction by using NaOH.The mixture of the products containssodium tri-chloroacetate and anothercom-pound. The other compound is?1) 2, 2, 2 - Trichloropropanol2)Chloroform3) 2, 2, 2 - Trichloroethanol4)Trichloromethanol
Ans:
34.The rate of a chemical reaction doublesfor every 10°C rise of temperature. If thetemperature is raised by 50°C, the rate of the reaction increases by about?1)32 times2)64 times3) 10 times4) 24 times
Ans:
1
Sol:
r
2
= r
2
.2
n
Where n =
T/105.'a' and 'b' are Vander Waal's constant forgases. Chlorine is more easily liquefiedthan ethane because1)a for C
l
2
<a for C
2
H
6
but b for Cl
2
>b for C
2
H
6
2)a for C
l
2
>a for C
2
H
6
but b for Cl
2
<b for C
2
H
6
3)a and b for C
l
2
>a and b for C
2
H
6
4)a and b for C
l
2
< a and b for C
2
H
6
Ans:
2
Sol:
Inter molecular forces andmolecular weight is more for C
l
2
, henceC
l
2
has high boiling point than C
2
H
6
But the size of molecule C
2
H
6
is greatherthan C
l
2
hence for C
2
H
6
b is greater thanC
l
2
6.The entrophy change involved in theisothermal reversible expan-sion of 2moles of an ideal gas from a volume of 10dm
3
to a volume of 100dm
3
at 27°C is:1) 32.3 J mol
–1
K
–1
2) 42.3 J mol
–1
K
–1
3) 38.3 J mol
–1
K
–1
4) 35.8 J mol
–1
K
–1
Ans:
3
Sol :
S = 2.303nRlog (V
2
 /V
1
)7.Avessel at 1000K contains CO
2
with apressure of 0.5 atm. Some of the CO
2
isconverted into CO on the addition of graphite. If the total pressure atequilibrium is 0.8 atm, the value of K is?1) 0.3 atm2)0.18 atm3) 1.8 atm4)3 atm
Ans:
3
Sol :
at eq.pressure 0.5 x –2xP
T
= 0.5 + x = 0.8So,
K
p
= 1.88.Agas absorbs a photon of 355 nm andemits at two wave-lengths. If one of theemissions is at 680 nm, the other is?1) 743 nm2) 518 nm3) 1035 nm4) 325 nm
Ans:
1
Sol:
E
T
= E
1
+ E
2
9.In a face centred cubic lattice, atom Aoccupies the corner positions and atom Boccupies the face centre positions. If oneatom of B is missing from one of theface centred points, the formula of thecompound is?1) A
2
B
3
2) A
2
B
5
3) A
2
B4) AB
2
Ans:
2
Sol:
After removing atoms, formula isAB
5/2
i.e. A
2
B
5
10.Among the following the maximumcovalent character is shown by thecompound?1) A
l
C
l
3
2) MgC
l
2
3) FeC
l
2
4) SnC
l
2
Ans:
1
Sol:
According to Fajan's rule1)Polarisiation
α
charge on cations2).In turn polarisation
α
covalentcharacterA
l
C
l
3
is most covalent11.Which one of the following orderspresents the correct sequence of theincreasing basic nature of the givenoxides?1) Na
2
O < K
2
O < MgO < A
l
2
O
3
2) K
2
O < Na
2
O< A
l
2
O
3
< MgO3) A
l
2
O
3
< MgO < Na
2
O < K
2
O4) MgO < K
2
O < A
l
2
O
3
< Na
2
O
Ans:
3
Sol:
As electropositive characterincreases basic nature metal oxidesincreasesA
l
2
O
3
< MgO < Na
2
O < K
2
O12.The Structure of IF
7
is?1) Octahedral2) Pentagonal bipyramid3) Square Pyramid4) trigonal bipyramid
Ans:
2
Sol:
IF
7
exhibits Pentagonal bip-yramidal shape13.Identify the compound that exhibitstautomerism1)2-Pentanone2)Phenol3)2 - Butene4)Lactic acid
Ans:
1
Sol:
2- Pentanone2- Pentanone present in the liquid statehence it exhibits tauto-merism(C
6
H
5
O
11
is solid MP= 42°C)14.Phenol is heated with a solution of mixture of KBr and KBrO
3
. The majorproduct obtained in the above reactionis:1)4 - Bromophenol2) 2, 4, 6 - Tribromophenol3) 2 - Bromophenol4)3 - Bromophenol
Ans:
2
Sol:
In aqueous medium phenol with Br
2
gives tribomo phenol15.Ethylene glycol is used as an antifreezein a cold climate. Mass of ethyleneglycol which should be added to 4 kg of water to prevent it from freezing at – 6°Cwill be :(K
for water = 1.86 KKgmol
–1
, and molar mass of ethyleneglycol = 62g mol
–1
)1)400.0g2)304.60 g3)804032 g4)204.30 g
Ans:
3
Sol:
T
= i.K
.m16.The degree of dissociation (
α
) of a weak 
2 2 2 3
OH|CH C CH CH CH
=
3 2 2 3
O||CH C CH CH CH
3 2 2 3
O||CH C CH CH CH
3 2 2 23 2 2 2
AC,MgC,FeC,SnC
+ + + +
l l l l l
T 1 2
hchchci.e.
= +λ λ λ 
( ) ( ) ( )
2
CO g C s CO g
+
C C H C H C2 2 6 2 6 2
aabutbb
> >
ll
FFFFFFFI
 
AIEEE - 2011 SOLUTIONS
PaperCode 'S'
OHBrBrBr

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