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Aipmt Prelims 2011 Brilliant tutorials

Aipmt Prelims 2011 Brilliant tutorials

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Published by saurav gupta
Aipmt Prelims 2011 Brilliant tutorials
Aipmt Prelims 2011 Brilliant tutorials

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Published by: saurav gupta on Jun 20, 2011
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CBSE PLUS 1
Brilliant Tutorials Pvt. Ltd. CBSE PLUS/PM/PD/Pre(Obj)/Qns/Ans ’11 - 1
CBSE PM/PD 2011CHEMISTRY 1.
Considering the state of hybridization of carbon atoms, find out the moleculeamong the following which is linear?
(1)
CH
3
— CH = CH — CH
3
 
(2)
CH
3
— C
C — CH
3
 
(3)
CH
2
= CH — CH
2
— C
CH
(4)
CH
3
— CH
2
— CH
2
— CH
3
 
Sol.:
 
1 2 3 433
HCH C C C
is a linear molecule as C
2
and C
3
are sp hybridized.
Correct choice : (2)
 
2.
In the following reactions,(a)
+
+
H /Heat3 3Major MinorProduct Product
CH CH CH CH A B
3
CH
OH
 (b)
 +
HBr,darkin absence of peroxideMajor MinorProduct Product
A C D
 the major products (A) and (C) are respectively:
(1)
 
=
2 2 3
CH C CH CH
3
CH
and
2 2 3
CH CH CH CH
3
CH
Br
 
(2)
 
3 3
CH C CH CH
=
3
CH
and
3 2 3
CH C CH CH
3
CH
Br
 (3)
 
3 3
CH C CH CH
=
3
CH
and
3 3
CH CH CH CH
3
CH
Br
 
(4)
 
=
2 2 3
CH C CH CH
3
CH
and
3 2 3
CH C CH CH
3
CH
Br
 
 
2 CBSE PLUS
 
Brilliant Tutorials Pvt. Ltd. CBSE PLUS/PM/PD/Pre(Obj)/Qns/Ans ’11 - 2
 
Sol.:
 
3 3
CH CH CH CH
3
CH
OH
+
H
2
H O
3 3
CH CH CH CH
3
CH
H
=
3 3
CH C CH CH
3
CH
(A)
major product
+
3 2
CH CH CH CH
=
3
CH
(B)
minor product
=
3 3
CH C CH CH
3
CH
HBr,dark
absence of 
peroxide
3 2 3
CH C CH CH
3
CH
Br
(C)
major
 
Correct choice : (2)
 
3.
Standard electrode potential of three metals X, Y and Z are — 1.2 V, + 0.5 V and— 3.0 V respectively. The reducing power of these metals will be:
(1)
Y > Z > X 
(2)
Y > X > Z
(3)
Z > X > Y 
(4)
X > Y > Z
Sol.:
Reducing power of the metal is inversely proportional to the reduction potential of the metal.Z > X > Y 
Correct choice : (3)4.
The total number of atomic orbitals in fourth energy level of an atom is:
(1)
8
(2)
16
(3)
32
(4)
4
Sol.:
4th energy level has one s, three p, five d and seven f orbitals.Total = 1 + 3 + 5 + 7 = 16
Correct choice : (2)
 
5.
Which of the following has the minimum bond length?
(1)
 
+
2
O
(2)
 
2
O
 
(3)
 
22
O
(4)
O
2
 
Sol.:
Minimum length is related to maximum bond orderSpecies Bond order
2
O
+
(2.5)
2
O
(1.5)
22
O
(1.0)
2
O
(2.0)
Correct choice : (1)
 
CBSE PLUS 3
Brilliant Tutorials Pvt. Ltd. CBSE PLUS/PM/PD/Pre(Obj)/Qns/Ans ’11 - 3
6.
If x is amount of adsorbate and m is amount of adsorbent, which of the following relations is
not
related to adsorption process?
(1)
 
xm
= f(p) at constant T
(2)
 
xm
= f(T) at constant p
(3)
p = f(T) at constant
xm
(4)
 
xm
= p
×
T
Sol.:
 
xm
= f(T) at constant p is wrongly related.It must be as
x 1m T
 
=
   
 
Correct choice : (2)7.
A buffer solution is prepared in which the concentration of NH
3
is 0.30 M and theconcentration of 
+
4
NH
is 0.20 M. If the equilibrium constant, K 
b
for NH
3
equals1.8
×
10
—5
, what is the pH of this solution? (log 2.7 = 0.43)
(1)
9.08
(2)
9.43
(3)
11.72
(4)
8.73
Sol.:
 
b
[salt]pOH pK lo[base]
= +
 
( )
5
0.2log 1.8 10 log0.3
= × +
 = 4.57Hence pH = 14
4.57 = 9.43
Correct choice : (2)8.
The electrode potentials for
+ +
+ 
2(aq) (aq)
Cu e Cu
and
+
+ 
(aq) (s)
Cu e Cu
are+ 0.15 V and + 0.50 V respectively. The value of 
+
2
oCu /Cu
E
will be:
(1)
0.500 V 
(2)
0.325 V 
(3)
0.650 V 
(4)
0.150 V 
Sol.:
 
o2(aq)1(aq)
Cu e Cu ; G 1 F ( 0.15)
++
+ = × × +
 
o(s)(aq)2
Cu e Cu ; G 1 F( 0.50)
+
+ = × +
 
o o o2(s)1 23(aq)
Cu 2e Cu ; G G G
+
+ = +
 
oo o3
G nFE 2FE
= =
 Hence
o
E 0.325
=
 
Correct choice : (2
)
 

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