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APPSC Polytechnic Lectuers exam Chemistry Subject Paper held on 19th May 2011

APPSC Polytechnic Lectuers exam Chemistry Subject Paper held on 19th May 2011

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1.
Uraniumis
a.
memberof
(1)
transitionseries-(2)actinideseries
(3)III-period
(4)VI-period
2._
Manganeseshowsoxidationstatesfrom+2to+7.Themostoxidisingstateknownin
7.
solubonis
.(1)
+7
(2)+4
(3)+3
(4)+2
8.The
follOwing
polysaccherideis
composed
of
l3-g1ycosidic
bonds:
(1)
Starch
(2)
Glycogen
(3)
Dextrin
I
B.
(4)
Cellulose
-
4.
Thereactiongiven
by
twoormorepeptidelinkages
1s
(1)
Biuret
test
(2)Ninhydrintest
(3)Xanthoproteic
test
(4)Pauly's
test~
6.
Oneofthefollowinghormonesisanamino
acid
derivative:(1)Epinephrine(2)Norepinephrine
(3)
Thyroxine
(4)All
of
them
(3)
PGLJ922
6.
Vlhich
gas
is
adsorbedmoreandeasily
by
charcoal?
(I)CO
(2)
N2
(3)
NH3
(4)II2
TheLlf2ofa
nldioactiveelement
u,
20
years,Mter100years,one
gram
ofciteelement
\ri!!
reduce
to
1
32
gm
(2)
1
4
gm
(3)
1
8
gtn
(4)
1
16
gill
Totalnumberofisomers
of
G
4
HIOO
will
be
(1)
4
(2)5
(3)7
(4-)
6
o.
Which
oneofthefollowing
has
all
tbe
effects,namely
inductive,
mesomeric
and
~:
hyperconjugative
?
(1)
(2)
CH
a
01CHaCH
=
CHOCHa
II
o
(3)CH
2
CH'"OH
2
(4)CH
2
==
on-
CB
=
CH
z
 
·r·--------------------
¥
'P.Gb/922
10.Thecoordinationnumberofcopper
in
the15.complexformed
by
.addingexcessofammonia
incoppersulphate
solution
is
(l)
4
(2)
3,(3)
2
~"-
0<
t4)
6
11.Thehybridisationof
Niin
Ni(CO)4is
(1)
sp
(2)
2
s,p
(3)
spa
(4)
dsp
2
~
tz,
The
complex,[Ni(CN
l!12-
has
(1)
linearstrucrure3)
square
planarstrucnrc:(4)octahedralstructure13.~
Ammoniumionis
"~r-~
.
'"
-(1)
aconjugateacid~
2)
acon;ugate
base
3
nei·:tcr
a:l
cad
nora
J".,
e
i
(4)
The
str~ch
oftheaciddependsonthe
(1)
numberof
nyfu-ogen
aznnspres:en..
ill
me
molecule
(4)_
c.oru:cntrationofhydrogenions
furnished
by
ionisation16.Thetypeofbends
pr~ent_inCuS04.
5H
2
0
are
-r
(1)'"
electrovalent,
covalent
and
co-ordinate
(2)electrovalentandcovalent(3}
electrovalent
andco-ordinate
(4)/
covalentanc
CO-i)n;linate
17.
Inhiplecoem
btr.:::ri..=
ens;
1
-
..
18.Inatriple
bond
there
is
sbaringof
(1)3electrons
(2)
4,
electrons
>-
_->
 
"
~
(5)
PGL/922
20.Whichofthefollowingisthestrongestbase?25.Innuclearreactions,heavywaterisusedas
(1)
enolisation
of
ketogroupoffructoseand
"
then,its
transformationintoaldehydegroupinpresenceofOH-whichis
(1)
Be(OH)2
(2)
Mg(OH)2
(3)
Al(oH)3
(4)
Si(oH)4
21.Whichofthefollowingisaweakelectrolyte?
L)
net
HB.
3
HI
(4)
RF
22.For
exothermic
reaction
(1)
.:'lH""
+ve
(2)
dH
=
-ve
~
(3)
LUi
=
0
I
(4)
None
oftheabove23.Theprocess
in
whichheatisneitherailowed27.toenternorallowedtoleavethesystemis
(l)
Isothermal
2:
A
crabatie_
L
orie(4)Isobaric24.Forafirstorderreaction
tl/2
=6.93
min.
28.Whatistherateconstantvalue
(min-I).?
(1)
0·1"
(2)2
(3)10
(4)1
(1)
Decomposer(2)Absorber
(3)
Moderator
(4)
Promoter
"
!ifri
,.
1'""
26.
Ketones'donotreduceToBen'sreagent,butfructosewithaketogroupreduces
it.
It
isat;.nbu1.lldto
presentin
Tollen'sreagent
(2)-CI-IOH
group
whichis
rusooxidisedto
keto
group(3)Bothstatement.arocorrect
(4)
Noneofthestatementsiscorrect
Which
is
a
non-reducing
sugar?
(1)Cellobiose
.,
...,
(2)Sucmse
(3)Lactose
(4)Maltose
Whichpolysaccharidehas0':-(1""-76)glycosidelinkage
?.~,
(1)
Amylose
i!?
I
(2)
Cellulose
(3)
Amylopectin
~
~
(4)
Allofthese
,_
...

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