Professional Documents
Culture Documents
E/plating
Iron ring Silver AgNO3 Electrode Half equation Products Observation Cathode (-) Ag+ + e Ag Ag Anode (+) Ag++ e
molten
ELECTROLYSIS
Electrolyte Purification Electrode Ions presence Moving of ions Half equation Products Observation Cathode (+) Anode (-) Br- , Pb2+ Br2BrBr2 + 2e Bromine gas Brown gas released Pb2+ Pb2+ + 2e Lead Pb Compound that CONDUCT ELECTRICITY in MOLTEN or AQUEOUS STATE undergoes CHEMICAL CHANGES CuSO Electrode Half equation Products Observation POSITION in ECS Carbon CONCENTRATION Cathode (-) Cu2+ + 2e Cu atom Brown solid deposited Cu Cu Anode (+) Cu2+ + 2e Impure Cu pure Cu
Aqueous
TYPE of ELECTRODE Carbon 1.0 mol dm-3 CuCl2 Cu electrode Cu electrode CuCl2 OH-, ClION PRESENCE MOVING OF ION half Equation (Selected ions to discharged) PRODUCT OBSERVATION
Cu2+ , H+ Cathode
Position in E.C.S
Cu2+ , H+ Cathode
Position in E.C.S
OH-, ClAnode
Position in E.C.S
Cu2+ , H+ Cathode
Position in E.C.S
ION PRESENCE MOVING OF ION half Equation (Selected ions to discharged) PRODUCT OBSERVATION
Cu
4OHO2 + 4e
2H2O +
Cu
Cu2+ + 2e
Cu
Cu
2Cl-
Cl2 + 2e
Blue colour of copper (II) chloride solution turn to colourless. Explain why? -Because concentration of Cu2+ ions decreases
Blue colour of copper (II) chloride solution turn to colourless. Explain why? -Because concentration of Cu2+ ions decreases
Blue colour of copper (II) chloride solution remain unchanged. Explain why ? because rate Cu2+ change to Cu is same with rate Cu change to Cu2+
Abe Ki te
Electrolysis product
Confirmatory test Put a damp blue litmus paper into test tube, the litmus paper turn to red and bleach it Put a damp blue litmus paper into test tube, the litmus paper turn to red and bleach it Add starch solution into test tube, the starch solution turn to dark blue Put a glowing wooden splinter into test tube, the glowing wooden splinter will light up
Chlorine gas
e-
<
Ki te-
Bromine gas
Iodine
<
Oxygen gas
-consist of electrolyte - consist of anode and cathode - electron flow from anode to cathode
similarities
Electrolytic cell Difference s Two or different electrode Used to produce chemical reaction Elect to chem. -ve terminal +ve terminal +ve terminal to ve terminal Made of Electric current Energy change Cathode Anode Flow of electron
Voltaic cell
Normally observe at anode in electrolysis (positive terminal) Electrolysis product Almost all metal (except Cu metal) Cu metal Observation Grey solid formed Brown solid formed Colourless gas released Confirmatory test Put a lighted wooden splinter into test tube, a pop sound is produced
Two different electrode Produced from chemical reaction Chem. To Elect +ve terminal -ve terminal -ve terminal to +ve terminal
Hydrogen gas