Asumiendo

FLUJOS MOLARES
Componentes
Acido acetico
Acido propanoico
Acido butanoico
Acido metanoico
total

F (Kmol/h)

Clave Ligero(LK)
Clave Pesado(HK)

Acido propanoico
Acido butanoico

COMPOSICION
Componentes
Acido acetico
Acido propanoico
Acido butanoico
Acido metanoico

fraccion molar
Destilado (D)
0.2469
0.7333
0.0198
0
1.0000

Alimentacion (F) Kmol/h

100
300
400
200

1000
Destilado (D) Kmol/h
100
297
8
0
405

fraccion molar
Residuo (W)
0.0000
0.0050
0.6588
0.3361
1.0000

Residuo (W) Kmol/h

0
3
392
200
595

COLUMNA DE DESTILACION MULTICOMPONENTES

TEMPERATURA DE BURBUJA
RESIDUO
componente
C1
C2
C3
C4
C5
Acido Acetico
53.27
-6304.5
-4.2985
8.8865E-18
Acido propanoico
54.552
-7149.4
-4.2769
1.1843E-18
Acido n-butanoico
93.815
-9942.2
-9.8019
9.3124E-18
Acido metanoico
50.323
-5378.2
-4.203
3.4697E-06
Fuente Perry Chemical Engineers Handbook (7ed)
Temperatura (K)

404.5

componente
Acido Acetico
Acido propanoico
Acido n-butanoico
Acido metanoico

zi

Entonces

K
Ki-K

0
0.00504202
0.65882353
0.33613445
1

Presion (Kpa)
Pvap(Kpa)
150.334663
73.8496383
34.1805939
234.602306

Ki

*xi
1.483687763
4.398246063
0
0.728839263
2.160572122 0.010893641
0.337336234
1 0.658823529
2.315344738
6.863611154 2.307096186
2.976813357

DESTILADO

componente
C1
C2
C3
Acido Acetico
53.27
-6304.5
Acido propanoico
54.552
-7149.4
Acido n-butanoico
93.815
-9942.2
Acido metanoico
50.323
-5378.2
Fuente Perry Chemical Engineers Handbook (7ed)
411

componente
Acido Acetico
Acido propanoico
Acido n-butanoico
Acido metanoico

zi

Entonces

K
Ki-K

temp promedio
temp =(Tb+Tr)/2
componente
Acido Acetico
Acido propanoico
Acido n-butanoico
Acido metanoico

101.325

0.33592969
0.00140654

TEMPERATURA DE ROCIO

Temperatura (K)

6
6
6
2

0.24691358
0.73333333
0.01975309
0
1

C4
-4.2985
-4.2769
-9.8019
-4.203

8.8865E-18
1.1843E-18
9.3124E-18
3.4697E-06

Presion (Kpa)
Pvap(Kpa)
180.321081
91.2769197
43.3026755
275.76743

C5
6
6
6
2

101.325

Ki

yi/
1.779630701
4.164201838 0.059294335
0.900833157
2.107881758 0.347900602
0.427364179
1 0.019753086
2.721612928
6.36836932
0
0.426948024

0.42694802
0.00041616
407.75

C1

presion(Kpa)
C2

53.27
54.552
93.815
50.323

C3
-6304.5
-7149.4
-9942.2
-5378.2

101.3
C4

-4.2985
-4.2769
-9.8019
-4.203

C5
8.8865E-18
1.1843E-18
9.3124E-18
3.4697E-06

6
6
6
2

componente
Acido Acetico
Acido propanoico
Acido n-butanoico
Acido metanoico
=

zi
0.1
0.3
0.4
0.2
1
1.332773

Pvap(Kpa)
164.779521
82.182097
38.5182917
254.523371

jxZjF/(j-)
Ki

1.626648775
4.277955056 0.145252652
0.811274403
2.133586233 0.799282334
0.3802398
1 -1.2020206
2.512570298
6.607857195 0.250530871
SUMA
-0.00695474

NTES
Pvap (Kpa)
150.3346626
73.84963832
34.18059391
234.6023056

Pvap (Kpa)
180.3210808
91.27691968
43.30267547
275.7674299

Pvap (Kpa)
164.7795209
82.18209698
38.51829174
254.5233712

jxXjD/(j-)
0.358648525
1.953801261
-0.059359042
0
2.253090743

tem promedio