S GD V T LNG SN TRNG THPT HU LNG ========o0o===== ===

THI TH I HC, CAO NG - NM 2010-2011. Mn thi: HO HC; Khi: A, B. Thi gian lm bi: 90 pht, khng k thi gian pht . ( thi c 06 trang; 50 cu trc nghim). =======o0o======

M : 231 H v tn:...S bo danh: Cho bit khi lng nguyn t (theo vC) ca cc nguyn t: H = 1; C =12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba = 137. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40). Cu 1. Hp cht X cu to bi C, H, O c phn t khi 74. X c tnh cht sau: + Tc dng vi Na gii phng H2, nhng khng tc dng vi dung dch NaOH. + Tham gia phn ng trng gng + Tc dng vi H2 to ra ancol, ancol ny ha tan c Cu(OH)2. Vy cng thc cu to ca X l: A. CH3-CH2-CH(OH)-CHO B. CH3- CH(OH)-CHO C. CH3-CH2-CO-CH2OH D. HO-CH2-CH2-CHO Cu 2. Khi lng ca mt on mch t nilon-6,6 l 27346 vC v ca mt on mch t capron l 17176 vC. S lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l: A. 121 v 114. B. 121 v 152 . C . 113 v 114. D. 113 v 152. Cu 3. Thy phn cc cht sau trong mi trng kim: CH3CHCl2(1); CH3COOCH=CHCH3(2); CH3COOC(CH3)=CH2(3); CH3CH2CCl3(4); CH3COO-CH2-OOCCH3(5); HCOOC2H5(6). Nhm cc cht sau khi thy phn c sn phm tham gia phn ng trng gng l: A. (1); (2); (3); (5) B. (1); (4); (5); (6) C. (1); (2); (3); (6) D. (1); (2); (5); (6) Cu 4. tc dng ht vi 4,64gam hn hp gm FeO, Fe3O4, Fe2O3 cn dng va 160ml dung dch HCl 1M. Nu kh hon ton 4,64 gam hn hp trn bng kh CO nhit cao th khi lng Fe thu c l: A. 4,36g B. 3,63g C. 3,36g D. 4,63g Cu 5. t chy hon ton 1,72 gam hn hp X gm anehit acrylic v mt anehit no n chc A cn 2,296 lt oxi ( ktc). Cho ton b sn phm chy hp th hon ton vo nc vi trong d c 8,5 gam kt ta. Cng thc cu to ca A l: A. C2H5CHO B. C3H7CHO C. HCHO D. CH3CHO Cu 6. Cho dung dch X cha 1 mol Ba(HCO3)2 tc dng vi dung dch Y cha 3 mol KHSO4 ( cc dung dch u long) thu c kt ta T, kh CO2 v dung dch Z. Cc ion c trong dung dch Z bao gm: A. K+, CO32B. K+, H+, SO42C. K+, CO32-, SO42- D. K+, H+, SO42-, Ba2+. Cu 7. Hp cht X l dn xut ca benzen c cng thc phn t C 8H10O2. X tc dng vi NaOH theo t l mol 1:1. Mt khc cho X tc dng vi Na th s mol H2 thu c ng bng s mol ca X phn ng. Nu tch mt phn t H2O t X th to ra sn phm c kh nng trng hp to polime. S cng thc cu to ph hp ca X l: A. 7 B. 2 C. 9 D. 6 Trang 1 /6 M 231

Cu 8. Cho cc ancol sau: CH3CH2OH(1); CH3CH(OH)CH3(2); CH3CH2CH(OH)CH2CH3 (3); CH3CH(OH)C(CH3)3(4). Dy gm cc ancol khi tch nc ch cho mt anken duy nht l: A. (1), (2) B. (1), (2), (3) C. (1), (2) ,(4) D. (1), (2), (3), (4) 2+ Cu 9. Cho a mol Mg, b mol Zn tc dng vi dung dch cha c mol Cu v d mol Ag+. Bit a < c + d/2. iu kin ca b ( so vi a, c, d) thu c mt dung dch cha 3 ion kim loi. A. b < c-a+d/2 B. b < c-a C. b > c-a D. b < c+ d/2 Cu 10. X phng ha hon ton 9,7 gam hn hp hai este no n chc X, Y cn 100ml dung dch NaOH 1,50M. Sau phn ng, c cn dung dch thu c hn hp hai ru ng ng k tip v mt mui duy nht. Cng thc cu to thu gon ca hai este l: A. C2H5COOCH3 v C2H5COOCH2CH3 B. HCOOCH3 v HCOOCH2CH3 C. CH3COOCH3 v CH3COOCH2CH3. D. HCOOCH3 v HCOOCH2CH2CH3 Cu 11. Th tch dung dch Ba(OH)2 0,025M cn cho vo 100ml dung dch hn hp HNO3 v HCl c pH= 1, thu c dung dch c pH= 2 l: A. 0,224 lt B. 0,336 lt C. 0,15 lt D. 0,448 lt Cu 12. C 3 dung dch mui: X, Y, Z ng vi 3 gc axit khc nhau, tha mn iu kin sau: X + Y c kh thot ra Y + Z c kt ta xut hin X + Z va c kt ta va c kh thot ra. X, Y, Z ln lt l: A. Na2SO4, Na2SO3, Ba(HCO3)2 B. Ba(HCO3)2, NaHSO4, Na2SO3. C. NaHSO4, Na2SO4, Ba(HCO3)2 . D. NaHSO4, Na2SO3, Ba(HCO3)2. Cu 13. Ankan C6H14 tc dng vi clo theo t l mol 1:1 thu c hai ng phn monoclo. Tn ca ankan l: A. 3-metylpentan B. 2,3- imetylbutan C. 2,2-imetylbutan D. isopentan Cu 14. C 4 l mt nhn ng cc dung dch: CH 3NH2; CH3COOH; C2H5OH; C6H5NH2, phn bit ngi ta dng: A. H2O, dung dch brom B. Na2CO3, dung dch brom C. Qu tm, H2O D. Na2CO3, qu tm Cu 15. C 4 cht kh X, Y, Z, T trong : - X lm mt mu dung dch nc brom, khng lm c nc vi trong. - Y khng lm mt mu dung dch nc brom, c lm c nc vi trong. - Z c lm mt mu dung dch nc brom, c lm c nc vi trong. - T khng lm mt mu dung dch nc brom, khng lm c nc vi trong. X, Y, Z, T ln lt l: A. NO2, CO2, SO2, H2S B. H2S, SO2, CO2, NO2 C. H2S, CO2, SO2, NO2. D. SO2, CO2, NO2, H2S Cu 16. Khi cho Ba(OH)2 d vo dung dch cha FeCl2, CuSO4, AlCl3 thu c kt ta. Nung kt ta trong khng kh n khi lng khng i, thu c cht rn X. Trong cht rn X c cha: A. FeO, CuO, BaSO4 B.Fe2O3, CuO, BaSO4 C. Fe2O3, CuO, Al2O3. D.FeO, CuO, Al2O3 Cu 17. C ti a bao nhiu phn ng xy ra khi cho cc ng phn mch h ca C2H4O2 tc dng ln lt vi Na, NaOH v tham gia phn ng trng bc: Trang 2 /6 M 231

A. 6 B. 5 C. 4 D. 3 Cu 18. C 9,98 gam caosu buna-S, phn ng va vi dung dch cha 8 gam Br 2/CCl4. T l ca mt xch buta-1,3-ddien vi stiren l: A. 2:3 B. 1:1 C. 5:7 D. 3:4 Cu 19. Cho dng kh CO i qua m gam hn hp Cu, CuO, Fe, Fe xOy, thu c 12,31 gam cht rn gm nhiu cht, kh thot ra sau phn ng c dn vo dung dch Ca(OH) 2 d c 5 gam kt ta. Gi tr ca m l: A. 12,14g B. 13,14g C. 12,11g D. 13,11g Cu 20. Oxit cao nht ca mt nguyn t R thuc nhm VA, c t l khi lng ca . Nguyn t R l: A. Stibi B. Asen C. Nit D. Photpho Cu 21. . Cho glixezol tc dng vi hn hp 3 axit: CH3COOH, C2H5COOH, HCOOH. S loi trieste ti a c th to thnh: A. 15 B. 9 C. 18 D. 12 Cu 22. Cho 4,35gam anehit A tc dng vi lng d dung dch AgNO 3/NH3, thu c 32,4 gam bc. Vy A l: A. OHC-CHO B. CH3CH2CHO C. H-CHO D. OHC-CH2CH2-CHO Cu 23. C bao nhiu phn ng trong cc phn ng sau u thy to ra kt ta, sau kt ta c th b ha tan ht: (1) AlCl3 + NaOH; (2) AlCl3 + NH3 + H2O;(3) CO2 + Ca(OH)2; (4) NaAlO2 +HCl +H2O; (5) NaAlO2 +CO2 +H2O; (6) ZnCl2 + NaOH; (7) ZnCl2 + NH3 + H2O; (8) CuCl2 + NH3 + H2O; (9) FeCl3 + NH3 + H2O A. 6 phn ng B. 5 phn ng C. 7 phn ng D. 8 phn ng Cu 24. Thuc th phn bit cc cht rn: Al, Al2O3, Fe2O3, K2O l: A. Dung dch HCl B. Dung dch HNO3 C. H2O D. Dung dch H2SO4 c Cu 25. C hai ng nghim, mt ng nghim ng dung dch Na 2SO4, mt ng nghim ng dung dch Na2CO3. Ch dng mt ha cht trong s cc ha cht sau: Dung dch HCl, dung dch BaCl2, dung dch NaHSO4, dung dch AlCl3 th s ha cht c th phn bit hai dung dch trn l: A.4 B. 1 C..3 D. 2 Cu 26. Cc hn hp sau u c t l mol 1:1. Hn hp khng tan ht trong nc l: A. Na + Al B. Na + Al2O3 C. Na2O + Al D. Na2O + Al2O3. Cu 27. Hai este A, B l dn xut ca benzen c cng thc phn t l: C 9H8O2; A v B u cng hp vi brom theo t l mol l 1:1. A tc dng vi xt cho mt mui v mt anehit. B tc dng vi xt d cho hai mui v nc, cc mui c khi lng phn t ln hn khi lng phn t ca natri axetat. Cng thc cu to ca A, B c th l: A. C6H5COOCH=CH2 v CH2=CH-COOC6H5 . B. HCOOC6H4CH=CH2 v HCOOCH=CH-C6H5. C. HOOC-C6H4-CH=CH2 v CH2=CH COOC6H5 D.C6H5COOCH=CH2 v C6H5-CH=CH-COOH. Cu 28. Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l: A. 9,4. B. 9,6. C. 10,8. D. 8,2. Trang 3 /6 M 231
mR : mO = 3, 5 :10

Cu 29. un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li 0,448 lt hn hp kh Z ( ktc) c t khi so vi O2 l 0,5. Khi lng bnh dung dch brom tng l A. 1,32 gam. B. 1,20 gam. C. 1,04 gam. D. 1,64 gam. Cu 30. Trn 200ml dung dch NaOH 1M vi 100ml dung dch HCl xM thu c dung dch A. Cho dung dch A vo 200 ml dung dch AlCl3 0,5M thu c 1,56 gam kt ta. Hy chn gi tr ng ca x A. 1M B. 1,4M C. 0,6M D. 2,8M Cu 31. X l mt este n chc, c t khi hi i vi CH4 l 5,5. Nu em un 2,2 gam este X vi dung dch NaOH d, thu c 2,05 gam mui. Cng thc cu to thu gon ca X l: A. HCOOCH2CH2CH3. B. CH3COOC2H5 C. HCOOCH(CH3)2. D. C2H5COOCH3 Cu 32. Cho phng trnh ion thu gn: aZn + bNO3- +cOH- dZnO22- + eNH3 + gH2O Tng cc h s( cc s nguyn ti gin) ca cc cht tham gia phn ng ( a+ b+ c) l: A. 12 B. 9 C. 10 D. 11 Cu 33. Cho hn hp bt gm 2,7 gam Al v 5,6 gam Fe vo 550 ml dung dch AgNO3 1M. Sau khi cc phn ng xy ra hon ton, thu c m gam cht rn. Gi tr ca m l: A. 32,4g B. 64,8g C. 59,4 g D. 54,0g Cu 34. Cho cc dung dch sau: HCl, Ca(OH)2, Na2CO3, NaCl. Cc dung dch c th lm mm nc cng tm thi l: A. Ca(OH)2, Na2CO3 B. Ca(OH)2, NaCl C. Ca(OH)2, NaCl D. HCl, Na2CO3 Cu 35. Cho 6,72 lt kh CO2 (ktc) hp th ht vo 500ml dung dch NaOH 0,1M v Ca(OH)2 0,4M thu c m gam kt ta. Gi tr ca m l: A. 10g B. 20g C. 15g D. 25g Cu 36. t chy hon ton mt amin no n chc, mch h thu c CO 2 v H2O theo t l khi lng 44: 27. S ng phn amin trn l: A. 5 B. 4 C. 3 D. 8 X1 X2 X3 X1 Na. Cc cht X1, X2, X3 ln lt l: Cu 37. Cho s : Na A. Na2O, NaBr, NaCl B. Na2SO4, NaOH, NaCl C.NaCl, NaOH, NaClO D. Na2O, NaOH, Na2CO3 22Cu 38. Dung dch A cha cc ion: CO3 ; SO3 ; SO42-, 0,1 mol HCO3- v 0,3 mol Na+. Thm V lt dung dch Ba(OH)2 1M vo A th thu c lng kt ta l ln nht. Gi tr nh nht ca V l: A. 0,20 B. 0,15 C. 0,30 D. 0,25 Cu 39. Polime no sau y c iu ch bng phn ng ng trng hp: A. PE B. Cao su buna-S C. PVC D. Nilon-6,6 Cu 40.t chy hon ton hn hp hai ancol ng dng c cng s mol nh nhau, ta thu c s mol CO2 v hi nc c t l mol 62. Cng thc hai ancol l: A. CH4O v C2H6O2. C. C2H6O2 v C4H10O2
nCO2 : nH 2O = 3 : 4

. Bit khi lng phn t 1 trong 2 cht l B. C2H6O v C3H8O D. CH4O v C3H8O

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II. PHN RING [ 10 cu ] Th sinh ch c lm 1 trong 2 phn ( phn A hoc B). A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41. Dung dch D c to ra do ha tan kh NO2 vo dung dch xt c d. Cho bt kim loi nhm vo dung dch D c 4,48 lt hn hp kh K gm hai kh ( ktc) thot ra, trong c mt kh c mi khai c trng. T khi ca K so vi He bng 2,375. Thnh phn phn trm th tch mi kh trong hn hp K l: A. 30%; 70% B. 40%; 60% C. 35%; 65% D. 50%; 50% Cu 42. Mui A c cng thc l C3H10O3N2, ly 3,66 gam A phn ng ht vi 75ml dd KOH 0,5M. C cn dd sau phn ng th c phn hi v phn cht rn, trong phn hi c 1 cht hu c bc 3, trong phn rn ch l cht v c. Khi lng cht rn l: A. 5,76 g. B. 3,45 g. C. 3,03 g. D. 4,71 g. Cu 43. A( C3H6O3) + KOH Mui + Etylen glycol. Vy cng thc cu to ca A l: A. H-COO-CH2-CH2-OH B. HO-CH2-COO-CH3 C. CH3-COO-CH2-OH D. CH3-CHOH-COOH Cu 44. Cho s phn ng: Thuc sng khng khi X Y Sobitol. X , Y ln lt l A. saccaroz, glucoz. B. tinh bt, glucoz. C. xenluloz, fructoz. D. xenluloz, glucoz. Cu 45. Cho m gam alanin tc dng ht vi 300ml dung dch HCl 1M thu c dung dch A. Dung dich A tc dng va vi 500ml dung dch NaOH 1M. Gi tr ca m l: A. 8,9g B. 13,35g C. 17,8g D. 20,025g Cu 46. Ho tan m gam hn hp gm Cu v Fe3O4 trong dung dch HCl d, sau phn ng cn li 4,16 gam cht rn khng tan v dung dch X. C cn dung dch X thu c 30,96 gam cht rn khan. Gi tr ca m l: A. 35,12. B. 27,72. C. 51,835. D. 21,92 Cu 47. Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l A. CH2=CH-CH2-CH3. B. CH3-CH=CH-CH3. C. CH2=CH2. D. CH2=C(CH3)2. Cu 48. phn bit phenol, benzen, stiren, anilin ngi ta s dng cc thuc th l: A. Dung dch NaOH, dung dch brom B. Dung dch brom, qu tm C. Dung dch HCl, qu tm D. Qu tm, dung dich brom Cu 49. Trong phn t hp cht hu c X ( C4H10O3) ch cha chc ancol. Bit Y ha tan c Cu(OH)2 cho dung dch mu xanh da tri. S cng thc cu to ca X l: A. 4 B. 5 C. 2 D. 3 Cu 50. Ho tan hon ton hn hp gm( 0,54 gam Al; 1,12 gam Fe; 1,92 gam Cu) trong 500 ml dung dch HNO3 aM thu c dung dch E v kh NO duy nht bay ln. Dung dch E ho tan va 0,88 gam bt Cu. Gi tr ca a l: A. 1 B. 0,75 C. 0,5 D. 1,25 B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)

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Cu 51. Cho ba kim loi: M, R, X . Bit E0 ca 2 cp oxi ho - kh M2+/M = -0,76V v R2+/R = +0,34V; khi cho X vo dung dch mui ca R th c phn ng xy ra cn khi cho X vo dung dch mui ca M th khng xy ra phn ng; E0 ca pin M-X = +0,63V th E0 ca pin X-R bng A. 0,47V. B. 0,21V. C. 1,05V. D. 1,10V. Cu 52. tch c CH3COOH t hn hp CH3COOH v C2H5OH ta dng ha cht no sau y: A. H2SO4 c B. CuO(t0) v AgNO3/NH3 d C. Na v dung dch HCl D. Ca(OH)2 v dung dch H2SO4 Cu 53. Thnh phn chnh ca supephotphat kp l: A. Ca3(PO4)2.CaF2. B. NH4H2PO4 C. Ca(H2PO4)2 D. Ca(H2PO4)2.CaSO4 Cu 54. Trong cc trng hp sau trng hp no khng xy ra n mn in ha: A.Nhng thanh Cu trong dung dch Fe2(SO4)3 c nh mt vi git dung dch H2SO4 B. Nhng thanh Zn trong dung dch H2SO4 c nh vi git dung dch CuSO4. C. S han g ca gang thp trong t nhin D. S n mn v tu trong nc bin. Cu 55. Hn hp X nng 9 gam gm Fe3O4 v Cu. Cho X vo HCl d thy cn 1,6 gam Cu khng tan. Khi lng Fe3O4 trong X l: A. 7,4g B. 2,32g C. 5,8g D. 3,48g Cu 56. Khi cng brom theo t l mol 1:1 vo buta-1,3-ien. S sn phm cng ibrom ti a thu c l: A. 2 B. 4 C. 5 D. 3 Cu 57. un 19,8 gam hn hp hai ancol n chc l ng ng k tip vi H2SO4 c 1400C. Bit hiu sut phn ng t 80%, sau phn ng thu c 12,96 gam hn hp ete. Hai ancol l: A.C2H5OH v C3H7OH B. C3H5OH v C4H7OH C. CH3OH v C2H5OH D. C3H7OH v C4H9OH Cu 58. Nhit phn hon ton 54,8 gam hn hp Fe(NO3)2 v Cu(NO3)2 trong iu kin khng c khng kh thu c 24 gam hn hp cht rn A v hn hp kh X. Sc t t kh X vo dung dch NaOH d n khi phn ng hon ton thu c dung dch Y. Khi lng mui c trong dung dch Y l: A. 34g B. 30,8g C. 46,2g D. 49,4g Cu 59. Thy phn hon ton 1 mol pentapeptit X thu c 3 mol glixin, 1 mol alanin, 1 mol valin. Mt khc khi thy phn khng hon ton X th trong hn hp sau phn ng thy c cc ipeptit Ala-Gly, Gly-Ala, Gly-Val, v tripeptit Gly-Gly-Ala. Vy cu trc bc mt ca X l: A. Gly-Gly-Ala-Gly-Val B. Gly-Val-Gly-Gly-Ala C. Val-Gly-Gly-Ala-Gly D. Gly-Gly-Ala-Val-Gly Cu 60. Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3-C(CH3)=CH-CH3, CH2=CH-CH2-CH=CH2. S cht c ng phn hnh hc l A. 4. B. 1 C. 3. D. 2.

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