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aieeechem05

aieeechem05

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Published by Lokesh Kumar

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Published by: Lokesh Kumar on Sep 28, 2011
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12/27/2012

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FIITJEE
 
Ltd. ICES House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi - 110016, Ph : 26515949, 26569493, Fax : 26513942 
 
 –1–
FIITJEE
SOLUTION TO AIEEE-2005
 
CHEMISTRY
76. Which of the following oxides is amphoteric in character?(1) CaO (2) CO
2
 (3) SiO
2
(4) SnO
2
 
76. (4)
CaO
 →
basicSiO
2
& CO
2
 
 →
acidicSnO
2
 
 →
amphoteric77. Which one of the following species is diamagnetic in nature?(1)
2
He
+
(2) H
2
 (3)
2
H
+
(4)
2
H
 
77. (2)
H
2
σ
1s
2
 
σ
*
1s
0
, no unpaired so diamagnetic78. If 
α
is the degree of dissociation of Na
2
SO
4
, the vant Hoff’s factor (i) used for calculating the molecular mass is(1) 1 +
α
(2) 1 -
α
 (3) 1 + 2
α
(4) 1 – 2
α
 
78. (3)
Na
2
SO
4
2Na
+
+ SO
4-2
 1 -
α
2
α
 
α
 Total moles = 1+2
α
 79. The oxidation state of Cr in [Cr(NH
3
)
4
Cl
2
]
+
is(1) +3 (2) +2(3) +1 (4) 0
79. (1)
(Cr(NH
3
)
4
Cl
2
)
+
 X + 4
×
0 + 2
×
-1 = 1X = +380. Hydrogen bomb is based on the principle of (1) Nuclear fission (2) Natural radioactivity(3) Nuclear fusion (4) Artificial radioactivity
80. (3)
81. An ionic compound has a unit cell consisting of A ions at the corners of a cube and Bions on the centres of the faces of the cube. The empirical formula for this compoundwould be(1) AB (2) A
2
B(3) AB
3
(4) A
3
B
81. (3)
A =
18 = 18
×
 (Corner)
www.myengg.comThe Engineering Universewww.myengg.comThe Engineering Universe
 
 
FIITJEE
 
Ltd. ICES House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi - 110016, Ph : 26515949, 26569493, Fax : 26513942 
 
 –2–
 
1B632
= × =
 (Face centre)
AB
3
 82. For a spontaneous reaction the G
, equilibrium constant (K) and
ocell
E will berespectively(1) -ve, >1, +ve (2) +ve, >1, -ve(3) -ve, <1, -ve (4) -ve, >1, -ve
82. (1)
83. Which of the following is a polyamide?(1) Teflon (3) Nylon 66(3) Terylene (4) Bakelite
83 (2)
AmideNylon66
 
NOH 84. Which one of the following types of drugs reduces fever?(1) Analgesic (2) Antipyretic(3) Antibiotic (4) Tranquiliser 
84. (2)
85. Due to the presence of an unpaired electron, free radicals are:(1) Chemically reactive (2) Chemically inactive(3) Anions (4) Cations
85. (1)
86. Lattice energy of an ionic compounds depends upon(1) Charge on the ion only (2) Size of the ion only(3) Packing of ions only (4) Charge on the ion and size of the ion
86. (4)
87. The highest electrical conductivity of the following aqueous solutions is of (1) 0.1 M acetic acid (2) 0.1 M chloroacetic acid(3) 0.1 M fluoroacetic acid (4) 0.1 M difluoroacetic acid
87. (4)
88. Aluminium oxide may be electrolysed at
o
1000C to furnish aluminium metal (Atomicmass = 27 amu; 1 Faraday = 96,500 Coulombs). The cathode reaction is
3o
Al3eAl
+
+
 To prepare 5.12 kg of aluminium metal by this method would require(1)
7
5.4910C
×
of electricity (2)
7
1.8310
×
C of electricity(3)
4
5.4910C
×
of electricity (4)
1
5.4910C
×
of electricity
88. (1)
Q =
5
mFZ5.1210965003M27
× × ×=
 = 5.49
×
10
7
C
www.myengg.comThe Engineering Universewww.myengg.comThe Engineering Universe
 
 
FIITJEE
 
Ltd. ICES House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi - 110016, Ph : 26515949, 26569493, Fax : 26513942 
 
 –3–
89. Consider an endothermic reaction, XY
 
with the activation energies E
b
and E
 for the backward and forward reactions, respectively. In general(1) E
b
< E
 (2) E
b
> E
 (3) E
b
= E
 (4) There is no definite relation between E
b
and E
89. (1)
H = E
– E
b
 For 
H
 
= Positive, E
b
< E
 90. Consider the reaction:
223
N3H2NH
+
carried out at constant temperature andpressure. If HandU
are the enthalpy and internal energy changes for thereaction, which of the following expressions is true?(1) H0
=
(2) HU
= ∆
 (3)HU
< ∆
(4)HU
> ∆
 
90. (3)
H =
U +
nRT
n = -2
H =
U – 2RT
H <
U91. Which one of the following statements is NOT true about the effect of an increase intemperature on the distribution of molecular speeds in a gas?(1) The most probable speed increases(2) The fraction of the molecules with the most probable speed increases(3) The distribution becomes broader (4) The area under the distribution curve remains the same as under the lower temperature
91. (2)
Most probable velocity increase and fraction of molecule possessing most probablevelocity decreases.92. The volume of a colloidal particle, V
C
as compared to the volume of a solute particlein a true solution V
S
, could be(1)
CS
V1V
(2)
23CS
V10V
 (3)
3CS
V10V
(4)
3CS
V10V
 
92. (4)
93. The solubility product of a salt having general formula MX
2
, in water is:
12
410.
×
Theconcentration of M
2+
ions in the aqueous solution of the salt is(1)
6
2.010M
×
(2)
4
1.010M
×
 (3)
4
1.610M
×
(4)
10
4.010M
×
 
93. (2)
MX
2
M
+2
+ 2X
-
 S 2SK
sp
= 4s
3
 
sp43
K,S1104
= = ×
 
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