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Iit Jee 2004 Chem

# Iit Jee 2004 Chem

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FIITJEE
Ltd. ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Term.), New Delhi - 16, Ph : 2686 5182, 26965626, 2685 4102, 26515949 Fax : 26513942

FFIIII T TJJEEEE

SSoolluuttiioonnssttoo I  I  I  J  J  E E E E – – 2 20000 4 4 M aaiinnssP Paa p pee
CChheemmiisstt y y

Time: 2 hours Note:
Question number 1 to 10 carries
2 marks
each and 11 to 20 carries
4 marks
each.1. For the given reactionA + B
→
ProductsFollowing data were givenInitial conc. (m/L). Initial conc. (m/L) Initial rate [mL
-1
s
-1
][A] [B]0.1 0.1 0.050.2 0.1 0.10.1 0.2 0.05a) Write the rate equation. b) Calculate the rate constant.
Sol.
a) Let the order w.r.t A & B are x any y respectivelyr = K[A]
x
[B]
y
0.05 = K[0.1]
x
[0.1]
y
0.1 = K[0.2]
x
[0.1]
y
or 2 = [2]
x
x =10.05 = K[0.1]
x
[0.1]
y
0.05 = K[0.1]
x
[0.2]
y
1 = [2]
y
y=0 b) rate equation = r = K[A] [B]
0
0.1 = K[0.2]K = 0.5 Sec
-1
2. 100 ml of a liquid contained in an isolated container at a pressure of 1 bar. The pressure is steeply increasedto 100 bar. The volume of the liquid is decreased by 1 ml at this constant pressure. Find the
H &
U.
Sol.

H =0,
q
p
=
U-WW = PdV= 100
×
1 atmmL= 10
-2
KJ =
U3. Draw the shape of XeF
4
and OSF
4
according to VSEPR theory. Show the lone pair of electrons on thecentral atom
Sol.
FFFFXe
(square planar)(sp
3
d
2
)
FOFSFF
(Trigonal bipyramidal)(sp
3
d)

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FIITJEE
Ltd. ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Term.), New Delhi - 16, Ph : 2686 5182, 26965626, 2685 4102, 26515949 Fax : 26513942

IIT-JEE 2004-M-2
4. The structure of D-Glucose is as follows
CHOHOHHOHHOHOHHOH
a) Draw the structure of L Glucose. b) Give the reaction of L Glucose with Tollens reagent.
Sol.
CHOHOHHOHHOHHOHOH
(Lglucose)
HOHHOHHOHHOHOHO
-
O
32
Ag(NH)
+

5. a) Draw New mann`s projection for the less stable staggered form of butane. b) Relatively less stability of the staggered form is due toi) Torsional strain.ii) Vander Waal’s strain.iii) Combination of the above two.
Sol.
a)
CH
3
HH.H.CH
3
.H
b) Less stability is due to Vander Waal’s strain6. Arrange the following oxides in the increasing order of Bronsted basicity.
273223
ClO,BaO,SO,CO,BO

Sol.

273223
ClOSOCOBOBaO
< < < <
7. AlF
3
is insoluble in anhydrous HF but when little KF is added to the compound it becomes soluble. Onaddition of BF
3
,AlF
3
is precipitated. Write the balanced chemical equations.
Sol
. 3KF + AlF
3

→
3
AlF
6

3
AlF
6
+ 3BF
3

→
AlF
3
+ 3KBF
4
8. The crystal AB (rock salt structure) has molecular weight 6.023 y amu. where y is an arbitrary number inamu.. If the minimum distance between cation & anion is
1/3
ynmand the observed density is
3
20Kg/m.Find thea) density in
3
Kg/mand b) type of defect
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FIITJEE
Ltd. ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Term.), New Delhi - 16, Ph : 2686 5182, 26965626, 2685 4102, 26515949 Fax : 26513942

IIT-JEE 2004-M-3
Sol.
a) Density
2327
46.023y6.023108y10
× ×=× × × ×
[Since a = 2y
1/3
]
33
510g/m
= ×

3
5Kg/m
=
b) Since the (density) calculated < density observed, it means the defect is metal excess defect.9. Which of the following is more acidic and why? NH
3+
NH
3+
F
,

Sol.
NH
3+
F
is more acidic due to – inductive effect of fluorine10. 7-bromo-1,3,5-cycloheptatriene exists as ionic species in aqueous solution while 5-bromo-1,3cyclopentadiene doesn’t ionise even in presence of
Ag(aq),
+
Explain.
Sol.
Aromatic Ion(highly stable)
Agaq.
→
Br
Br
Ag

Antiaromatic Ion(highly unstable)
11. a) The schrodinger wave equation for hydrogen atoms is
Ψ
2s
=
3/2r/a1/200
112eaa4(2)
π
Where a
0
is Bohr’s radius. Let the radial node in 2s be at r
0
. Then find r in terms of a
0
. b) A base ball having mass 100 g moves with velocity 100 m/sec. Find out the value of wave length of  base ball.c)
7234926
XY.
αβ

Find out atomic number, mass number of Y and identify it.
Sol.
a)
22s
ψ
= probability of finding electrons at any place
∴Ψ
2
= 0 at node
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