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Table Of Contents

1.1 BASIC CONCEPTS
1.2 THE HISTORY OF THE CONCEPT OF THE MACROMOLECULE
1.3 CLASSIFICATION OF POLYMERS
1.4 STRUCTURE AND PROPERTIES OF POLYMERS
1.4.1 Poly(ethylene)
1.4.3 Poly(methyl methacrylate)
1.4.4 Poly(styrene)
1.4.5 Poly(vinyl chloride), PVC
1.4.6 The Nylons
1.4.7 Epoxy Resins
1.4.8 Phenol-Formaldehyde Polymers
1.4.9 Amino Resins
1.4.10 Poly(tetrafluoroethylene), PTFE
1.4.11 Polyurethanes
1.4.12 Poly(ether ether ketone)
1.4.13 Silicones
1.4.14 Naturally Occurring Polymers
1.4.15 Cellulose
1.4.16 Starch
1.4.17 Natural Rubber
1.4.18 Proteins
1.4.19 Poly(3-hydroxybutyrate)
2.1CHAIN POLYMERISATION
2.1.1Initiation
2.1.2Propagation
2.1.3Termination
2.1.4Other Reactions
2.2ARRANGEMENT OF MONOMER UNITS
2.3KINETICS OF CHAIN POLYMERISATION
2.4AUTOACCELERATION
2.5PRACTICAL METHODS OF CHAIN POLYMERISATION
2.5.1Bulk Polymerisation
2.5.2Solution Polymerisation
2.5.3Suspension Polymerisation
2.5.4Emulsion Polymerisation
2.5.5The Loop Process
2.6OTHER CHAIN POLYMERISATION MECHANISMS
2.7STEP POLYMERISATION
2.8STEP POLYMERISATION WITH POLYFUNCTIONAL MONOMERS
2.9COPOLYMERISATION
3.1POLYMER STEREOCHEMISTRY
3.2POLYMER CRYSTALLINITY
3.2.1Orientation and Crystallisation
3.2.2The Crystalline Melting Point
3.2.3Polyblends
3.3THERMAL AND MECHANICAL PROPERTIES
3.3.1The Glass Transition Temperature, T
3.3.2The Effect of Plasticisers
3.3.4The Effect of Polymer Stereochemistry on T
3.3.6Other Thermal Transitions
4.2 PHENOL–FORMALDEHYDE RESINS
4.3 UNSATURATED POLYESTER RESINS
4.4 POLYURETHANES
5.1INTRODUCTION
5.2DISSOLUTION OF POLYMERS
5.3SOLUBILITY PARAMETERS
5.4SIMPLE LIQUID MIXTURES AND RAOULT’S LAW
5.5ENTROPY OF MIXING
5.6REAL MOLECULES IN DILUTE SOLUTION
5.7SHAPES OF POLYMER MOLECULES IN SOLUTION
5.8REPTATION MODEL OF MOLECULAR MOTION
5.9WATER-SOLUBLE POLYMERS
5.10USES OF HIGH-VISCOSITY POLYMER SOLUTIONS
5.11POLYMER MELTS
Methods of Determining Relative Molar Mass
6.1INTRODUCTION
6.2MOLAR MASSES FROM COLLIGATIVE PROPERTIES
6.2.1Vapour Phase Osmometry
6.3LIGHT SCATTERING
6.3.1Experimental Determination
6.4VISCOSITY METHODS OF DETERMINING RELATIVE MOLAR MASS
6.5END GROUP ANALYSIS
6.6GEL PERMEATION CHROMATOGRAPHY
Mechanical Properties of Polymers
7.1INTRODUCTION
7.2STRESS,STRAIN,AND YOUNG’S MODULUS
7.3BRITTLE AND TOUGH FRACTURE
7.4TYPES OF STRENGTH
7.5THE INFLUENCE OF SURFACES
7.6VISCOELASTICITY
7.7CREEP AND STRESS RELAXATION
7.8COLD DRAWING
7.9DYNAMIC TESTS
7.10TIME/TEMPERATURE RELATIONSHIP
7.11RUBBERLIKE ELASTICITY
7.12REINFORCED POLYMERS
8.2BEHAVIOUR OF POLYMERS IN FIRES
8.2.1The Behaviour of Individual Polymers
8.3ASSESSMENT OF COMBUSTION BEHAVIOUR
8.4IMPROVEMENT OF STABILITY OF POLYMERS IN FIRES
8.5WEATHERING OF POLYMERS
8.6PROTECTION OF POLYMERS FROM PHOTO-OXIDATION
8.7BIOLOGICAL DEGRADATION OF POLYMERS
8.8EXPLOITATION OF POLYMER DEGRADATION
9.1INTRODUCTION
9.2ORGANIC DENDRIMERS
9.3SUPRAMOLECULAR DENDRIMERS
9.4SHAPES AND CONFORMATIONS OF DENDRIMERS
9.5DENDRIMER MICELLES
9.6CHARACTERIZATION OF DENDRIMERS
9.6.1Mass Spectroscopy
9.6.2Gel Permeation Chromatography
9.6.3High-Performance Liquid Chromatography
9.6.4NMR Spectroscopy
9.6.5X-Ray Diffraction
9.6.6Titration
9.6.7Small Angle Neutron Scattering
9.6.8Atomic Force Microscopy
9.7APPLICATIONS OF DENDRIMERS
9.8MEGAMERS
FURTHER READING
Special Topics in Polymer Chemistry
10.1INTRODUCTION
10.2POLYMERS IN MEDICINE
10.3IONOMERS
10.4ELECTRONICALLY CONDUCTING POLYMERS
10.5INTERPENETRATING POLYMER NETWORKS
10.6INORGANIC POLYMERS
10.7POLYMER LIQUID CRYSTALS
10.8POLYMERS FOR FOOD PACKAGING
11.1INTRODUCTION
11.2POLLUTION BY POLYMERS
11.3THE NATURE OF THE PROBLEM
11.4POLYMERS AND ENERGY
11.5RECYCLING OF POLYMERS
11.6DEGRADABLE POLYMERS
Bibliography
Subject Index
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The Chemistry of Polymers, 3rd Ed

The Chemistry of Polymers, 3rd Ed

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Published by: brainsurgeon on Oct 10, 2011
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