CONFIDENTIAL *

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JABATAfI
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JABATAfI
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STPM 2009
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JABATANPELAJARANNEGERf. (2 hours) -ANPELAJARANNEGERISEMBILAN
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JABA TANPELAJARANNEGER/ JABA TANPELAJARANNEGERISEMB/LAN
JABAT AN PELAJARAN NEGERl SEMBILAN
PERCUBAAN BERSAMA
SIJIL TINGGI PERSEKOLAHAN MALAYSIA
2009
Instructions to candidates:
DO NOT OPEN TIDS QUESTION PAPER UNTIL YOU
ARE TOLD TO DO SO.
Answer all questions in Section A. Write your answers in the
spaces provided
Answer any four questions in Section B. Write your answers on
your own test pad Begin each answer on a fresh sheet of paper.
Answers should be illustrated by large and clearly labeled
diagrams wherever suitable.
Arrange your answers in numerical order and tie the answer
sheets to this question paper.
For examiner's use
1
2
3
4
5
6
7
8
9
10
Total
This question paper consists of 11 printed pages
STPM TRIAL 96212 CONFIDENTIAL *

Section A [40 marks]

Answer all questions in this section

1. (a) The mass spectrum of a compound , X is shown below















(i) If the molecular formula of X is C
3
H
8
O , draw two possible structural
isomers of X







[2]

(ii) Based on the mass spectrum given, identify the compound X. Give
your reason

.



..
[2]





Relative abundance










15 17 28 29 31 45 60 m/e
1. b) The diagram below shows four electron transitions in the hydrogen atom
















(i) Skecth the line spectrum formed as a result of these four transitions





[2]

(ii) In which region of the electromagnetic spectrum are these lines formed?

..
[1]

(iii) By using the Rhyberg equation, calculate the frequency of the light emitted
when an electron occupying the energy level n=3 drops to n=1.
[Rhyberg constant for H atom = 1.097 x 10
7
m
-1
]








[3]




Energy

n=5
n=4

n=3

n=2



n=1
2 (a) The following cell was set up between a zinc half-cell and an unknown metal, M
half-cell. The standard e.m.f of the cell is 1.56 V. The zinc electrode is the anode in this
cell.




(i) Give the name of a suitable substance to be used as the salt bridge.

[1]

(ii) Write the cell diagram (cell notation) for the above cell.

[1]

(iii) State the direction of electron flow through the voltmeter.

.. [1]

(iv) Use the Data Booklet to calculate the standard electrode potential of the
system:

M
+
(aq) + e
-
M(s)









[2 ]



M(s)
M
+
(1.0 moldm
-3
)
zinc rod
Zinc sulphate solution
(1.0 moldm
-3
)
(b)




In an electrolysis experiment, two electrolytic cells A and B are connected in
series as shown above. Cell A consists of copper electrodes immersed in an
aqueous copper(II) sulphate solution. Cell B consists of electrodes of metal X
immersed in an aqueous solution containing X
n+
ions.
When a current of 0.50 A is allowed to pass through the two cells for 20.0 min,
the masses of copper and X deposited in cell A and cell B are 0.197 g and
0.672 g respectively. [Relative atomic mass: Cu, 63.5, X, 108]

(i) Calculate the quantity of electricity that passed through the two cells.




[1 ]

(ii) Calculate the quantity of electricity that is required to deposit 1.00 mol of
copper and 1.00 mol of X.

Copper:




X:




[3]

(iii) Based on the results obtained in (ii) above, state the charge of the X
n+
ion.



copper
electrodes
Electrodes of
metal X
copper(II)
sulphate
solution
solution containig
X
n+
ions
cell A cell B
3 (a) Write the formula of the oxides of Period 3 elements of the Periodic Table in
the boxes provided. Give only one formula for each element.


Element Na Mg Al Si S Cl
Formula of
oxide


[3]

(b) Write equations for the reactions of aluminium oxide with the following reagents:

(i) aqueous sodium hydroxide

....

(ii) aqueous hydrochloric acid

...................................
[2]

(c) Strontium, Sr is an element in Group 2 of the Periodic Table.

(i) Write a balanced equation for the action of heat on strontium nitrate

..

(ii) Both magnesium nitrate and strontium nitrate will decompose on heating. Which
of the two will decompose at a lower temperature?

.

(iii) Explain why your answer to (c) (ii) decomposes at a lower temperature.



.

.
[4]

(d) Arrange the solubility of Group 2 sulphates in descending order .

.
[1]

4. The compound 1-chloro-2-phenylethene is a monomer from which an addition
polymer can be obtained.

(a) Draw the displayed structural formula showing two repeating units of
of this addition polymer.






[1]

(b) Write an equation and state conditions for the reaction between
1-chloro-2-phenylethene and hydrogen .

Equation:..

Conditions .

[2]

(c) Chloroethene reacts with hydrogen chloride to produce compound A. On heating
A with aqueous sodium hydroxide, compound B is formed. B gives an orange
precipitate with 2,4 dinitrophenylhydrazine

(i) suggest the structural formulae for A and B in the boxes below:

A







B


(ii) Write the name of the reaction mechanism by which A is formed

..
[3]




(d) When chloroethene reacts with bromine in tetrachloromethane, the product is
a mixture of two isomers.
Draw the structures of the two isomers.









[2]

(e) Toluene reacts with ethanoyl chloride in the presence of anhydrous
aluminium chloride as a catalyst.
Write an equation for this reaction


...[1]






Section B [60marks]

Answer any four questions in this section

5 (a) Define (i) standard enthalpy change of atomization.
(ii) standard enthalpy change of formation [2]

(b) The table below provides information on energy changes that take place in the
formation of copper (II) oxide.

Enthalpy changes H ( kJmol
-1
)
Cu(s) + O
2
(g) CuO(s) -155.2
Cu(s) Cu(g) +339.3
O
2
(g) O (g) +249.0
Cu(g) Cu
+
(g) + e +750.0
Cu
+
(g) Cu
2+
(g) + e +2000.0
O(g) + e O
-
(g) -140.0
O
-
(g) + e O
2-
(g) +786.0


i) Draw the Born Haber cycle for copper (II) oxide in the form of an enthalpy
level diagram.
(ii) Use the enthalpy level diagram and the values given in the table above to
calculate the lattice energy of copper (II) oxide. [7]

(c) Explain the following observations:
(i) Molten aluminium chloride is a non - electrolyte but an aqueous solution of
aluminium chloride is a strong electrolyte.
(ii) Aluminium chloride dissolves easily in an organic solvent but aluminium
fluoride does not dissolve in the same organic solvent. [6]


6. (a) Define (i) pH and (ii) buffer solution [2]

(b) Calculate the pH of
(i) 0.100 mol dm
-3
of aqueous ethanoic acid solution
(ii) a buffer solution formed by dissolving 16.4 g of sodium ethanoate in 750
cm
3
of water and then adding to 250 cm
3
of 0.100 mol dm
-3
ethanoic acid
[K
a
for ethanoic acid= 1.75 x 10
-5
mol dm
-3
] [6 ]

(c) The partition coefficient for a solute Q between ether and water is 12.50.
(i) By referring to solute Q, ether and water, explain what is meant by the term
partition law.
(ii) Under what conditions is the partition law true?
(iii) 8.00 g of Q was dissolved in 25.0 cm
3
of water. Q was then extracted firstly
with 25.0 cm
3
of ether and secondly with two portions of 12.5 cm
3
of ether.
Determine in each case the mass of Q that remains in the aqueous layer.
[7 ]

7. (a) 0.500 g of solid aluminium chloride was heated to 200
0
C at a pressure of
1.00 x 10
5

Pa. The volume of vapour formed at this temperature and pressure was
found to be 73.6 cm
3
. Calculate the relative molecular mass of the vapour at this
temperature and pressure. Draw a displayed formula to show the types of
bonding in the molecules of the vapour. [4]

(b) Explain with the help of equations why an aqueous solution of aluminium
sulphate has a pH of 4.8 [3]

(c) Carbon and silicon are the first two elements in Group 14 of the Periodic Table.
Carbon dioxide is a gas that dissolves in, and reacts with water. Silicon(IV) oxide
is a solid that is insoluble in, and is unreactive towards water. The tetrachlorides
of carbon and silicon are both liquids, one of which reacts with water and the
other does not.
Explain the differences in physical and chemical properties of these four
compounds described by these statements, writing balanced equations for all
reactions that occur. [8]
8. (a) How do the chloride, bromide and iodide ions differ in their reactions with
(i) silver nitrate solution, followed by aqueous ammonia
(ii) concentrated sulphuric acid
In each case, suggest the products of the reaction and write equations where
appropriate. [9]

(b) What do you understand by the term transition element? State two
properties of iron or its compounds that typify it as a transition element. [3]

(c) Describe and explain what happens when an aqueous solution containing Cu
2+

ions is added gradually with dilute aqueous ammonia followed by an aqueous
solution of [EDTA]
4-
[3]

9. (a) Phenylmethanol and 4-methylphenol are structural isomers with the same
molecular formula. State clearly how these two compounds will react with each
of the following reagents, and write balanced equations for the reactions
involved.
(i) aqueous sodium hydroxide at room temperature
(ii) aqueous bromine at room temperature [6]

(b) The reaction scheme below shows two different organic compounds P
and Q having the same molecular formula C
3
H
6
Cl
2
reacting with aqueous
potassium hydroxide to form compounds R and S respectively. R and S are then
treated with 2,4 dinitrophenylhydrazine and in both cases an orange precipitate is
formed. However only R gives a yellow precipitate when heated with iodine in
sodium hydroxide solution.













(i) Write the structure formula of the group responsible for the positive test with
- 2.4-dinitrophenylhydrazine
- iodine in sodium hydroxide solution
(ii) Draw the structural formulas of compounds R and S .
(iii) Suggest a chemical test to distinguish between R and S
(iv) Draw the structural formulas of P and Q
(v) Write equations for the reactions of both P and Q with aqueous KOH solution [9]
Q
R C
3
H
6
O
S C
3
H
6
O
Orange Precipitate
Orange Precipitate Yellow Precipitate
P
KOH(aq)
2,4-dinitro phenylhydrazine 2,4 -dinitrophenylhydrazine
KOH(aq)
I
2
/ OH
-

10. (a) A compound, A, has the molecular formula, C
3
H
4
OCl
2
. Compound A is a
colourless liquid that fumes in moist air. It reacts with water to form compound
B, C
3
H
5
O
2
Cl. B is optically active. When A is refluxed with aqueous sodium
hydroxide and then acidified, compound C, C
3
H
6
O
3
, is obtained.

(i) Identify A, B and C. Give reasons for your answers.
(ii) Draw the structural formula of the compound formed in the reaction
between 2-propanol with A. Write a balanced equation for this reaction [8]

(b) Pentyl 4-metoxycinnamate, L, can absorb ultraviolet rays and is used in the
production of skin cream. Its structural formula is as follows.









(i) State the type of isomerism that is shown by molecule L and draw the structures
of these isomers.
(ii) Draw the structural formulas of the products formed when L is heated with
aqueous sodium hydroxide solution.
(iii) L can be synthesised in the laboratory from the compound shown below. Name
the reactant used and the conditions necessary for this synthesis.





[7]














CH
3
O
O CH
2
(CH
2
)
3
CH
3
O
CH=CH C
Mol ec ul e L






CH
3
O
CH=CHCOOH