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Chem_P2

Chem_P2

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Published by: sherry_christy on Nov 07, 2011
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08/05/2013

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SULIT*SECTION A [40 marks]1(a) (i) Write ground state electron configuration for copper(II) ion.
Tulis konfigurasi elektron asas untuk ion kuprum(II).
……………………………………………………………………………...........[1 m](ii)Specify in what group and in what period in the periodic table of an elementwith the electron configuration of [Ar]3d
8
4s
2
is found.
 Nyatakan dalam apakumpulan dan kala dalam jadual berkala untuk satu unsur dengankonfigurasi elektron [Ar]3d 
8
4s
2
.
…………………………………………………………………………………………..………………………………………………………………………………………….[2 m](iii)How does the size change when an atom is converted to an anion? Explain.
 Bagaimana saiz berubah apabila satu atom bertukar menjadi anion? Jelaskan.
…………………………………………………………………………………………..…………………………………………………………………………………………..…………………………………………………………………………………………..…………………………………………………………………………………………..[3 m](b) Consider the reaction: BF
3
+ NH
3
F
3
B←NH
3
. Describe the changes inhybridization (if any) of the B and N atoms as a result of this reaction.
 Pertimbangkantindakbalas: BF 
3
+ NH 
3
3
 B←NH 
3
. Nyatakan perubahan dalam penghibridan(sekiranya ada) untuk atom B dan atom N akibat dari tindakbalas ini.
……………………………………………………………………………………………..……………………………………………………………………………………………..……………………………………………………………………………………………..……………………………………………………………………………………………..[4 m]962/2*Kertas soalan ini SULIT sehingga peperiksaan ini tamat. SULIT*22
 
SULIT*2(a) A mixture of 
H
21
2
and
B
8135
2
was analysed in a mass spectrometer. The massspectrum was found to contain the following lines:
Satu campuran
H
21
2
dan
B
8135
2
dianalisis dalam satu spektrometer jisim. Spektrum jisim didapati mengandungi garisan- garisan berikut:
LineIIIIIIIVVRelativemass248183162(i)Give the formulae of the particles that produce the lines, I to IV
. Beri formulauntuk zarah yang menyebabkan garisan I sehingga IV.
…………………………………………………………………………………………..…………………………………………………………………………………………..…………………………………………………………………………………………..………………………………………………………………………………………….…………………………………………………………………………………………..[2 m](ii) Explain how the particles of line IV are produced.
 Jelaskan bagaimana garisan IV terbentuk.
…………………………………………………………………………………………..…………………………………………………………………………………………..…………………………………………………………………………………………..…………………………………………………………………………………………..[1 m]962/2*Kertas soalan ini SULIT sehingga peperiksaan ini tamat. SULIT*33
 
SULIT*2(b) Bromine is formed by the reaction between bromate(V)ions and bromide ions andacid. BrO
3-
(aq) + 5Br 
-
(aq) + 6H
+
(aq) → 3Br 
2
(aq) + 3H
2
O(l). The results of someexperiments on the reaction are shown below:
 Bromin dibentuk daripada tindakbalasantara ion bromate(V) dan ion bromide serta asid. BrO
3-
(aq) + 5Br 
-
(aq) + 6H 
+
(aq) →3Br 
2
(aq) + 3H 
2
O(l). Hasil tindakbalas dari beberapa eksperimen adalah sepertiditunjukkan di bawah:
ExperimentConcentration/moldm
-3
Initialrate/moldm
-3
s
-1
BrO
3-
Br 
-
H
+
10.100.100.101.2 x 10
-3
20.100.300.103.6 x 10
-3
30.200.100.102.4 x 10
-3
40.200.100.209.6 x 10
-3
(i) Write the rate law for the reaction.
Tulis hukum kadar untuk tindakbalas di atas.
………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………[4 m](ii) State the overall order of reaction.
 Nyatakan tertib tindak balas keseluruhan.
………………………………………………………………………………………………[1 m](iii) Find the value of the rate constant.
Cari nilai pemalar kadar 
.……………………………………………………………………………………………..……………………………………………………………………………………………..……………………………………………………………………………………………..[2 m]962/2*Kertas soalan ini SULIT sehingga peperiksaan ini tamat. SULIT*44

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