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HCI Chem H2 Paper 1 Question Paper

HCI Chem H2 Paper 1 Question Paper

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HWA CHONG INSTITUTION
C2 PRELIMINARY EXAMINATIONHigher 2 CHEMISTRY 9746PAPER 120 Sept 2007 1 hour 
Do not open this booklet until you are told to do so.
INSTRUCTIONS TO CANDIDATES
1. Check that there are
17
printed pages in this question booklet.2. Fill in your particulars on the optical mark sheet. Enter your NRIC number or FINnumber and shade accordingly.3. There are
forty
questions in this paper. Answer 
ALL
questions. For each question,there are four possible answers,
A
,
B
,
C
and
D
. Choose the
one
you consider correctand record your choice in
soft pencil
on the
Optical Mark Sheet
provided.4. After the examination, you are required to submit only the optical mark sheet.
INFORMATION FOR CANDIDATES
Each correct answer will score one mark. Marks will not be deducted for wrong answers.A
Data Booklet 
is provided. You may use a calculator.Any rough working should be done in this booklet.This question booklet consists of 
17
printed pages
 
C2 Prelim 2007 9746/01/HCI
2
Section A1
Which of the following is a possible configuration of a stable M
3+
ion in the ground state?
A
1s
2
2s
2
2p
3
B
1s
2
2s
2
2p
6
3s
2
3p
1
C
1s
2
2s
2
2p
6
3s
2
3p
6
3d
2
D
1s
2
2s
2
2p
6
3s
2
3p
6
3d
2
4s
2
 
2
Wines often contain a small amount of sulphur dioxide that is added as a preservative.The sulphur dioxide content of a wine is found by the following method:A 50 cm
3
sample of white wine is reacted with 40.0 cm
3
of 0.01 mol dm
3
of excessaqueous iodine. The sulphur dioxide in the wine is oxidized to sulphate, SO
42
, in theprocess. The unreacted iodine requires exactly 23.60 cm
3
of 0.02 mol dm
3
sodiumthiosulphate for complete reaction. Determine the concentration of sulphur dioxide,in mol dm
3
, in the wine.
A
1.64 x 10
3
B
3.28 x 10
3
C
4.72 x 10
3
D
9.44 x 10
3
 
3
In which of the following pairs of compounds(i) does the first compound have a larger bond angle about the central atom thanthe second compound and,(ii) is the second compound more polar than the first compound?
A
CO
2
, BeC
l
2
B
I
C
l
F
2
,
C
l
O
2
C
SO
2
, HCN
D
BC
l
3
, NO
2
 
4
Three vessels containing 90 cm
3
of iodine fumes, 4 dm
3
of argon and 0.01 m
3
of water vapour respectively at 150
o
C and 101 kPa were connected together. The connectedvessels were allowed to cool to room temperature. What was the final pressure in theconnected vessel?
A
20.2 kPa
C
28.7 kPa
B
71.1 kPa
D
70.7 kPa
 
C2 Prelim 2007 9746/01/HCI
3
 
5
Which graph correctly describes the behaviour of fixed masses of the ideal gases
L
and
M
 where the number of moles of 
L
is greater than number of moles of 
M
?
A B
 
C D
 
6
Figure 1 shows the first eight ionisation energies of an element
G
while Figure 2 showsthe boiling points of eight consecutive elements (including
G
).With reference to Figure 2, which of the options,
A
,
B
,
C
or 
D
corresponds to the boilingpoint of element
G
?
VT0ML
constant V
Figure 1 Figure 2
   I  o  n   i  s  a   t   i  o  n   E  n  e  r  g  y   /   k   J  m  o   l
     −
    B  o   i   l   i  n  g   P  o   i  n   t   /
  o
   C
Number of electronsAtomic Number 
ABCD
V
1
constant T
ML0V
1
0ML
constant T
VT
constant P
ML0

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