Series SOS/2 Code No. 56/2/1 ws a. Roll No. Candidates must write the Code on aaa : the title page of the answer-book. , Tani as oF AR YRAGT & PVT wR Hae fered | « Please check that this question paper contains 12 printed pages. * Code number given on the right hand side of the question paper should be written on the title page of the answer-book by the candidate. ¢ Please check that this question paper contains 30 questions. ¢ Please write down the Serial Number of the question before attempting it. * 15 minutes time has been allotted to read this question paper. The question paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the students will read the question paper only and will not write any answer on the answer script during this period. ° gua cia a a ff we yew A ier ye 12 71 owe Fo afet wa at sik feu me ats FRR aT on satya S qe-gs H fed | ° opm sie a a fh ww wt F380 We gra wa wr at fram YR we a wee, Wer aT maim sae fers | ° yee a ost & faa 15 fee wo a Rea tl ee aw oe le 7 10.15 44 fen TT | 10.15 ae a 10.30 3S aH OM tae yet BT VST sik wa osaft & dhe 3 sacgia wa aR Te feet | CHEMISTRY (Theory) warm fear (dare) Time allowed : 3 hours Maximum Marks : 70 Frat wat : 370s Sina sie : 70 56/2/1 1 P.T.O.Bt General Instructions : @ All questions are compulsory. (ii) Marks for each question are indicated against it. (iii) Questions number 1 to 8 are very short-answer questions and carry 1 mark each. (iv) Questions number 9 to 18 are short-answer questions and carry 2 marks each. (v) Questions number 19 to 27 are also short-answer questions and carry 3 marks each. (vi) Questions number 28 to 30 are long-answer questions and carry 5 marks each. (vii) Use Log Tables, if necessary. Use of calculators is not allowed. arart Fae : @ wet wer ort F 1 (ii) arte Tet ae sie wale Te eI (ii) eer 1 a 8 am afer yaaa Tet F | wee eT fee 1 ee | (iv) Werte 9 F 18 we y-sae eT Bree TET & fee 2 sie FI (vy) Fee 19 327 TH Ht ay-saa Fert E | ade Ter & fore 3 sis FI (vi) ser-Her 28 4 30 Ge-sada wer 1 ele wet & fee 5 ate B 1 (vii) sreRamagER ait aac ar walt at 1 degeledt & svahr at orate we 2) 1. What is meant by an ‘intrinsic semiconductor’ ? * ‘sie (As) arefarers’ 3 ae cred @ 7 2. State Henry’s law about partial pressure of a gas in a mixture. fret from 4 ate & aifns aa & ak Feat ar fram fear | 3. What do you understand by ‘denticity of a ligand’ ? we fers af efaar Bara ear wae @ 7 4, Which will react faster in S,2 displacement, 1-bromopentane or 2-bromopentane, and why ? Sy2 fre t fe FS sh afe ast S afi son, Late art aatited, sit ait 2 56/2/15. Give the IUPAC name of the following compound : a CH, — C = C - CH,OH !ot CH, Br frfafad afr a anéaied. (TUPAC) am afar : CH, - C = C - CH,OH l I CH, Br 6. Write the structure of the following compound : 3-oxopentanal. 1 frafatad airs at denn fase: 3-stedtiete 1 7. Why is an alkylamine more basic than ammonia ? 1 amifrar at ater ua Tenet siftre arta wit ate? 8. What is meant by a ‘broad spectrum antibiotic’ ? 1 ‘faega Bagh vfasfae’ & ar ard ze ? 9. Differentiate between molarity and molality of a solution. Explain how molarity value of a solution can be converted into its molality. 2, we fae at Ata sit aera # stat aifse | fet fae & AreRa AA at saat tae FSS seer ST wea zg, FEET I 10. A 0-561 m solution of an unknown electrolyte depresses the freezing point of water by 2-93° C. What is Van’t Hoff factor for this electrolyte ? The freezing point depression constant (K,). for water is 1-86° C kg mol”. 2 Gh said fagi-smes ST 0-561 m fae Fa % fenia Bt 2-98° C Haft am 2 | fags & fag ave ae (Van't Hoff) ae AA FT a ? ae % fay fenis ara feris (Kp 186° C kg mol? 2 | 11. Determine the values of equilibrium constant (K,) and AG° for the following reaction : 2 Ni (s) + 2 Ag* (aq) —> Ni (aq) + 2 Ag(s), E° = 1-05 V (F = 96500 C) frafafan aftten & ferme ara feria (K,) at AG? & art at oftaferd afar : Ni (s) + 2 Ag* (aq) —> Ni®* (aq) + 2 Ag(s), E° = 1-05 V (F = 96500 C) 56/2/1 3 P.T.O.