thi Ha Phn tch Ln 1 K44

thi Ha Phn tch Ln 1 (Dnh cho sinh vin ngnh Ha K44 Thi gian 90) s 21 Cu 1: Trnh by phng php trc quang xc nh nng dung dch Fe3+ theo phng php ng chun hc vi dung dch Fe3+ dng ng chun nng 0,1mg/ml cng cc ha cht v cc dng c cn thit. Gii thch tt c cc iu kin nu c. Ly chnh xc 5,0ml dung dch Fe3+ cha bit nng pha vo bnh nh mc dung tch 200ml sau ly 4,0ml dung dch va pha em to phc vi axit sunfosalixilic trong mi trng pH thch hp to phc mu vng trong bnh nh mc dung tch 50ml, o mt quang ti bc sng thch hp nhn c gi tr A = 0,2.10. Tnh nng dung dch Fe3+ trong dung dch ban u (g/l) trong h s tt phn t ca phc mu ny bng 1,8.105 v cuvet dng o mt quang c chiu dy 1cm. Cu 2: Trnh by phng php chun xc nh nng NaCl bng dung dch chun AgNO3 0.1N bng phng php Morth v phng php ch th hp ph Fluorexin hc. Gii thch tt c cc iu kin nu c. Tnh nng K2CrO4 cn thit kt ta gch Ag2CrO4 xut hin ti ng im tng ng, trc v sau im tng ng vi sai s cho php 0,1%. Coi nng NaCl khong 0,1N v s thay i th tch l khng ng k bit TAgCl = 10-10 ,TAg2CrO4 = 10-12. Cu 3: Chun 15,0ml dung dch FeCl2 bng dung dch chun K2Cr2O7 0,07N trong mi trng thch hp thy tiu tn ht 12,7ml. Tnh nng dung dch FeCl2 (g/l) v TK2Cr2O7/Fe2+. Cho bit Fe=56, Cl=35,5; K=39; Cr=55;O=16 Cu1. Cho cc cht ch th oxh - kh sau : Axit phenylantranilic (E0 = 1,08v); Diphenylamin (Eo = 0,76v) v Feroin (Eo = 1,1v) Hy tnh cc gi tr in th ca dung dch ti im tng ng, bc nhy in th v tm cht ch th thch hp c kh nng xc nh c im dng chun vi sai s +- 0,1% khi chun 50ml dung dch FeSO4 0,1N bng K2Cr2O7 0,1 N trong mi trng H2SO4 lun lun n nh ti pH = 0 Cho bit EoCrO72-/2Cr3+ = 1,36V ; Eo Fe3+/Fe2+ = 0,77v Cu 2. Ha tan 5,35 gam NH4Cl vo 500ml dd NH3 0,1M (coi th tch gi nguyn ). Tnh pH ca dung dch thu c bit K NH3 = 1,8.10-5 v N = 14, Cl = 35,5 ; H = 1 Cu3. a/ Trnh by phng php Morh chun NaCl bng AgNO3. Hy cho bit iu kin v nng K2CrO4 v mi trng pH php chun dng ti ng im tng ng v sai s t +-0,1% (gi s nh phn 100ml dung dch NaCl bng AgNO3 cng nng 0,1N) b/ Khi chun 25,00ml dung dch NaCl tn ht 23,00ml dung dch AgNO3 nng 0,1N hy tnh nng gam/l ca NaCl Cu4. Cho 250ml dung dch cha 50mg mt cht X, s dng dung mi bezen thc hin qu trnh chit bit rng X c h s phn b gia nc v bezen l 80. Tnh th tch bezen cn dng sau ln chit th nht c 99% cht X c chuyn vo pha hu c. Nu mi ln chit dng 50ml bezen v mun t hiu sut chit nh trn th phi chit bao nhiu ln. Cu5. Trnh by phng php in phn dung dch CuSO4 trong mi trng axit H2SO4 + HNO3 S phn cc gy nh hng n qu trnh in phn nh th no v cc cch loi b chng. Mt dng in nh hng nh th no n qu trnh in phn thi Ha Phn Tch nh Lng y l thi Ha Phn Tch nh Lng dnh cho Sinh Vin Ha 2006, mi tham kho: thi mn Phn Tch nh Lng Lp Ha 2006, 26/06/2008 Thi gian: 120 pht (khng tnh 5 pht c )

Cu 1. (2 im) Acid tartaric, H2C4H4O6 (M = 150.087), l mt acid yu 2 chc c pKa1=3.0 v pKa2 = 4.4. Cn nh lng acid ny trong mt mu cha khong 80% acid tartatric bng dung dch NaOH 0.1M xc nh im cui bng mt ch th mu. Hy thit lp quy trnh phn tch hm lng acid tartaric trong mu ny. (Thit lp iu kin chun , ung cong chun , chn cht ch th, lng cn mu, th tch nh mc, cng thc nh lng...) Cu 2. (3.5 im) Chun dung dch NaOH bng cht chun gc potassium hydrogen phthalate (KHP), pKa1 = 2.93; pKa2 = 5.41; uc thc hin bng cch cn trc tip mt lng xc nh KHP rn thay v ht mt th tch xc nh KHP 0.1000N vo erlen. Quy trnh ny c th mc sai s t nhiu ngun gy sai s khc nhau. Hy phn nh (c gii thch) cc trng hp sau y, ngun gy sai s l sai s ngu nhin, sai s h thng hay khng gy sai s. Nu c gy sai s th d on nng NaOH xc nh uc nh th no so vi nng NaOH khng mc sai s. Phn ng chun nh sau C8H4O42 + H2OC8H5O4 + OH (a) Cn dng ly KHP khng uc hiu chun ph hp v khi lng cn lun lch m 0.15g. (b) Ch th s dng trong phn ng chun lun i mu gia pH 3 v 4. (c) C bt kh kt trong u buret lc bt u chun nhng mt i lc kt thc chun . (d) KHP s dng trong cc ln chun lp uc cn ring trong cc erlen khc nhau v ch chnh zero lc cn erlen th nht. (e) Khng sy kh KHP trc khi dng. (f) Khng sy kh NaOH trc khi dng. (g) Quy trnh chun yu cu pha long KHP bng nc n 25 mL nhng phn tch vin l pha long n 35 mL 1 trong s mu chun lp. Cu 3. (3.5 im) Hm lng Fe trong mt mu thin thch uc xc nh bng chun oxyha kh vi KMnO4. Ha tan 0.4185-g mu trong acid v dng ct Walden kh nh lng Fe3+ v Fe2+. Chun bng KMnO4 0.02500 M, vi hn hp bo v Zymmerman, tn 41.27 mL. Cho , [H+] = 2N Hy nu cu to v cch s dng ct Walden: Vit cc phng trnh phn ng. V ung cong chun . Tnh % theo khi lng Fe2O3 trong mu thin thch. .