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Table Of Contents

2.1.1.1. From Radical Addition of Fluorinated Transfer Agents to
2.1.1.2. From Telomerisation Reaction
2.1.1.2.1. Telomerisation of Fluoromonomers with Hydrogenated
2.1.1.2.2. Telomerisation of Hydrogenated Monomers with Fluorinated
2.1.1.2.2.1. Telomerisation of 1,3-Butadiene with Perfluoroalkyl Iodides
2.1.1.2.2.2. Telomerisation of Acrylamide with Fluorinated Transfer Agents
2.1.1.2.2.2.1. Telomerisation of Acrylamide with Fluorinated Mercaptan or
2.1.1.2.2.2.2. Telomerisation of Tris(hydroxymethyl) Acrylamide with
2.1.1.2.2.3. Telomerisation of Acrylic Acid with CTFE Telomers. Inter-
2.1.1.2.3. Telomerisation of Fluoromonomers with Fluorinated Transfer
2.1.1.3. By Dead-End Polymerisation of Fluoromonomers from
2.1.1.4. By Chemical Changes and Coupling
2.1.1.4.1. Chemical Changes of Non-fluorinated Polymers
2.1.1.4.1.1. Synthesis of RF-b-Polydimethylsiloxane. The Daikin Com-
2.1.1.4.2. Coupling of (Fluoro)telomers by Esterification. In addition to these
2.1.2.1. Introduction
2.1.2.3. From Atom Transfer Radical Polymerisation (ATRP)
2.1.2.3.2. From Telomeric Initiators Reactivated by a C–I Cleavable
2.1.2.3.3. Initiators that Possess a C–Br Cleavable Bond. One example of
2.1.2.3.4. From Initiators Possessing a C–Cl Cleavable Bond. Examples of
2.1.2.3.5. Synthesis of Block Copolymers by Stepwise ATRP Processes. This
2.1.2.3.5.1. Synthesis of Aliphatic Fluorinated A–B Copolymers. Betts
2.1.2.3.5.2. Synthesis of Aromatic Fluorinated A–B Copolymers. Aro-
2.1.2.4.1. Synthesis of Fluorinated Block Copolymers by Iodine-Transfer
2.1.2.4.1.2. Stepwise Cotelomerisation. Various examples of direct cote-
2.1.2.4.1.3. Iodine Transfer Polymerisation of Fluoroalkenes. Various
2.1.2.4.3. Block Copolymers from the RAFT Process
2.1.2.4.3.2. Synthesis of Fluorinated Block Copolymers by RATF. Poly-
2.1.2.4.4. Block Copolymers from the MADIX Process. Recently, the Rhodia
2.1.2.5. From Fluorinated Tetraphenyl Ethanes
2.1.3. Synthesis of Diblock Copolymers by Combination of Different Systems
2.1.3.2. Coupling of Non-living/Living Radical Methods
2.1.4. Preparation of Fluorodiblock Copolymers by Living Methods Other
2.1.4.1. Cationic Methods
2.1.4.2. Sequential Cationic Polymerisation of (Fluoro)vinyl Ethers
2.1.4.3. Ring-Opening Polymerisation of Cyclic Amides Esters
2.1.4.4. Anionic Methods
2.1.4.5. By Ring-Opening Metathesis Polymerisation (ROMP)
2.1.4.6. By Group-Transfer Polymerisation
2.1.5. Synthesis of Fluorinated Diblock Copolymers by Condensation
2.1.6. Conclusion
2.2.1.2.1. SynthesisofModelsofF-TriblocksfromRadicalMonoadditions. As
2.2.2. Synthesis of F-Triblocks by Controlled Radical Polymerisation
2.2.2.1. By Sequential ATRP of (Fluoro)monomers
2.2.2.2. Synthesis of Fluorinated A–B–A by Iodine Transfer Polymerisation
2.2.2.3. Synthesis of F-Triblock Copolymers by RAFT and MADIX
2.2.2.4. Conclusion
2.2.3. Synthesis of Fluorotriblock Copolymers by Combining Different
2.2.3.1. Synthesis of Triblock Copolymers by Coupling Condensation
2.2.3.2. Condensation of Telomers
2.2.3.3.1. From ATRP of Hydrogenated Monomers Initiated by Telechelic
2.2.3.3.1.1. Telomers that Possess C–I Cleavable Bonds. a,v-Diiodi-
2.2.3.3.1.2. Telomers Containing C–Br Cleavable Bonds. On the other
2.2.3.3.2. By Coupling Condensation/ATRP of Fluoromonomers. In 2002,
2.2.3.4. Miscellaneous
2.2.4.1. Cationic Polymerisation
2.2.4.1.1. From the Cationic Polymerisation of Oxazoline. Water-soluble
2.2.4.1.2. From the Ring Opening Polymerisation of Oxygen-Containing Cyclic
2.2.4.2. Anionic Polymerisation
2.2.4.3. From Metathesis
2.2.4.4. Conclusion
2.2.5. Synthesis of Fluorinated Triblock Copolymers by Condensation
2.2.6. Conclusion
2.3.1. Syntheses Involved in the First Series
2.3.1.1. First Generation from Kim [329, 330]
2.3.2. Second Generation from Investigations Carried Out in Our Laboratory
2.3.2.2. Fourth Generation from Specific Polymer’s Research [339]
2.3.3. Synthesis of Fluorosiloxanes Containing Perfluoropolyethers (PFPE) for
2.3.4. Synthesis and Procedures of the Third Series
2.3.5. Conclusion
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Well Architectured Fluoropolymers

Well Architectured Fluoropolymers

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Published by: muttonyang on Jan 29, 2012
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11/10/2012

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