MSDS

Abbreviated Material Safety Data Sheets (MSDSs)
The abbreviated MSDSs provided for each compound listed i n the f o l l o w i n g Table o f Contents contain only the basic chemical, physical, and toxicological data needed to answer Pre-Lab questions and t o prepare Tables o f Reactants and Products for the experiments i n Experimental Organic Chemistry: A Miniscale and Microscale Approach, 3 rd Ed. Should you w i s h more complete
information regarding the chemicals with which you are working, consult a source containing the full MSDS. Information provided regarding first-aid procedures generally describes only the initial steps that should be taken should an accident occur.
Disclaimer
Neither the authors, The University of Texas at Austin, nor Thomson Learning, Inc., assumes responsibility for the accuracy of any of the data provided in the abbreviated Material Safety Data Sheets.
Acetamide
CAS No. 60-35-5 PS solid Color colorless Odor distinct FP 174 BP 221 MP 8082 d 1.159 VP 10 @ 105 VD N/A Sol 200%
Types of Hazard/Exposure Fire
Acute Hazards/Symptoms Slight fire hazard.
Prevention Avoid heat, sparks, flames. Ventilation, local exhaust. Protective gloves and clothing.
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam. Remove from exposure immediately, get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately; if vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Irritation, drowsiness, fatigue, nausea, acidosis and skin eruptions. Irritation.
Skin
Eyes
Irritation, corneal damage.
Safety goggles.
Ingestion
Drowsiness, fatigue, nausea, acidosis and skin eruptions.
Do not eat or drink in the laboratory.
Carcinogenicity Abbreviations:
Suspected carcinogen.
Mutagenicity
For more detailed information consult the Material Safety Data Sheet for this compound. CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
4-Acetamidobenzenesulfonamide
CAS No. 121-61-9 PS solid Color off-white Odor N/A FP N/A BP N/A MP 219 d N/A VP N/A VD N/A Sol slightly soluble
Acute Hazards/Symptoms Flammable, emits toxic fumes under fire conditions. May be harmful if inhaled. May be irritating to the skin.
First Aid/Fire Water spray, carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Inhalation Skin
Eyes
Dust, vapor, or mist may be irritating to the eyes.
Safety goggles. .
Ingestion
May be harmful if swallowed.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
For more detailed information consult the Material Safety Data Sheet for this compound. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density (g/mL); Sol = solubility in water; N/A = not available or not applicable.
4-Acetamidobenzenesulfonyl Chloride
CAS No. 121-60-8 PS solid Color tan Odor acetic acidlike FP N/A BP N/A MP 145 148 d N/A VP N/A VD N/A Sol decomposes
Acute Hazards/Symptoms Moderate fire hazard.
Prevention No flames, no sparks, no contact with hot surfaces. Ventilation, local exhaust. Protective gloves and clothing.
First Aid/Fire Carbon dioxide, dry chemical powder, or foam. Remove from exposure immediately; get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, and get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
Corrosive material, chemical burns, coughing, wheezing, laryngitis, headache, and vomiting. Corrosive material, chemical burns.
Skin
Eyes
Corrosive material, chemical burns.
Safety goggles.
Ingestion
Corrosive material, convulsions, muscle Do not eat or drink in weakness, and symptoms as described the laboratory. in acute ingestion.
Carcinogenicity
Mutagenicity
For more detailed information consult the Material Safety Data Sheet for this compound. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
Acetanilide
CAS No. 103-84-4 PS solid Color white Odor odorless FP 169 BP 304 MP 114 d 1.219 VP 1@ 114 VD 4.7 Sol 0.5%
Prevention Avoid heat, sparks, flames. Ventilation, local exhaust.
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam Remove from exposure immediately; get immediate medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs keep head lower than hips, get medical attention, if needed.
Inhalation
Irritation, eczematous skin eruptions, poisoning as in ingestion.
Skin
Irritation, contact dermatitis, skin eruptions due to systemic poisoning
Protective gloves and clothing.
Eyes
Irritation
Safety goggles.
Ingestion
Nausea, vomiting, sweating, gastric irritation, chills, brown-black urine, skin rash, hypotension, methemoglobinemia. Severe cases: hypothermia, and circulatory or respiratory failure. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Possible mutagen.
Acetic Acid
CAS No. 64-19-7 PS liquid Color colorless Odor vinegary FP 39 BP 118 MP N/A d VP VD Sol soluble
1.049 11.8 @ 2.07 20
Acute Hazards/Symptoms Moderate fire hazard., vapors or gases may ignite at distant ignition sources.
Prevention No flames, no sparks, no contact with hot surfaces. Ventilation, local exhaust.
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam, alcohol resistant foam Remove from exposure immediately; get immediate medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. Give large amounts of water or milk and allow vomiting to occur; when vomiting occurs, keep head lower than hips. Possible mutagen.
Inhalation
Irritation, pharyngeal edema, chronic bronchitis, coughing, shortness of breath, laryngitis, pulmonary edema, and hypotension
Skin
Irritation, pain, erythema, blisters, Protective gloves and burns and superficial destruction of the clothing. skin; readily absorbed through the skin. Irritation, lacrimation, corneal erosion, Safety goggles. opacification, iritis, and possibly loss of sight
Eyes
Ingestion
Severe ulceronecrotic lesions, stricture Do not eat or drink in of the esophagus, perforation of the the laboratory. esophagus and pylorus, diarrhea, shock, vomiting, abdominal spasms, thirst, rapid and weak pulse, slow and shallow breathing, laryngitis, bronchitis, pulmonary edema. Not a known carcinogen. Mutagenicity
Carcinogenicity
Acetic Anhydride
CAS No. 108-24-7 PS liquid Color colorless Odor vinegary FP 54 BP 138140 MP -73 d 1.082 VP 10 @ 36 VD 3.52 Sol reacts
Acute Hazards/Symptoms
Prevention
First Aid/Fire Carbon dioxide, regular dry chemical, alcohol resistant foam Remove from exposure immediately; get immediate medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately; give large amounts of water or milk, and allow vomiting to occur; when vomiting occurs keep head lower than hips. Not a known mutagen.
Moderate fire hazard., vapors or gases No flames, no sparks, may ignite at distant ignition sources, no contact with hot contact with water or moist air may surfaces. generate flammable and/or toxic gases. Severe irritation, cough, choking, wheezing, chest pain, and pulmonary edema, which may be fatal. Irritation, white, wrinkled skin, blisters, and severe burns. Ventilation, local exhaust.
Inhalation
Skin
Eyes
Pain, lacrimation, photophobia, and blurred vision. Corneal and conjunctival edema, iritis, corneal erosion, and opacity may be delayed effects.
Safety goggles.
Ingestion
Severe burns of the mouth, esophagus, Do not eat or drink in and stomach with pain, difficulty the laboratory. swallowing, nausea, vomiting, and diarrhea.
Carcinogenicity
Not a known carcinogen
Mutagenicity
Acetone
CAS No. 67-64-1 PS liquid Color colorless Odor minty, sweet FP -17 BP 56 MP -94 d 0.791 VP 180 @ 20 VD 2.0 Sol soluble
Acute Hazards/Symptoms SEVERE fire hazard., vapors or gases may ignite at distant ignition sources. Irritation, dryness of the mouth and throat, restlessness, anorexia, vomiting, slow, irregular respiration, slow, weak pulse, liver and kidney damage, central nervous system depression with weakness of the legs, headache, nausea and a general feeling of malaise.
Prevention No flames, no sparks, no contact with hot sources Ventilation, local exhaust.
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water Remove from exposure immediately; get medical attention.
Inhalation
Skin
Irritation, cellular damage to the outer Protective gloves and layers of the epithelium with edema clothing. and hyperemia, small amounts may be absorbed through intact skin. Irritation, corneal epithelial, conjunctival, stinging sensation, and damage to eyes. Safety goggles.
Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. If vomiting occurs, keep head lower than hips.
Eyes
Ingestion
Fruity odor of the breath and mucous membrane, gastroenteric irritation, flushed cheeks, shallow respiration, latent period followed by restlessness, diarrhea, nausea and vomiting. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Possible mutagen.
p-Acetophenetidide (Phenacetin)
CAS No. 62-44-2 PS crystalline powder Color white Odor odorless FP N/A BP decomposes MP 134 135 d N/A VP N/A VD N/A Sol 1 g/1310 mL
Acute Hazards/Symptoms Slightly flammable.
Prevention No open flames.
First Aid/Fire Water spray, dry chemical, alcohol foam, or carbon dioxide.
Inhalation Skin
Cyanosis, dizziness, respiratory depression. Possibly a mild irritant.
Local exhaust or Remove to fresh air. Get breathing protection. medical attention. Protective gloves and clothing. Immediately flush skin with plenty of soap and water for at least 15 min. while removing contaminated clothing and shoes. Get medical attention. Immediately flush eyes with plenty of water for at least 15 min., lifting lower and upper eyelids occasionally. Get medical attention immediately. Induce vomiting immediately as directed by medical personnel. Call a physician immediately. Not a known mutagen.
Eyes
Possibly irritating to eye tissues.
Safety goggles.
Ingestion
Moderately toxic, causes cyanosis, Do not eat or drink dizziness, respiratory depression. Cardiac in the laboratory. arrest may occur. May result in liver and kidney damage. Possible carcinogen. Mutagenicity
Carcinogenicity
Acetophenone
CAS No. 98-86-2 PS liquid Color colorless Odor floral FP 82 BP 203 MP 19-20 d VP VD Sol 0.55% @ 20
1.030 1 @ 15 4.14
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam Remove from exposure immediately, get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. If vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Irritation, coughing and central nervous system depression with headache, dizziness, and narcosis. Irritation, redness, pain, and mild burns.
Skin
Eyes
Severe reaction with only transient optical irregularity of the corneal epithelium.
Safety goggles.
Ingestion
Sore throat, abdominal pain, nausea Do not eat or drink in and central nervous system depression the laboratory. with headache, dizziness, and narcosis.
Carcinogenicity
Mutagenicity
Adipic Acid
CAS No. 124-04-9 PS crystalline solid Color white Odor FP BP 337 MP 150 152 d 1.360 VP 1 @ 159.5 VD 5.04 Sol 1.4 g/ 100 mL
odorless 196
Types of Hazard/Exposure Fire Inhalation
Acute Hazards/Symptoms Combustible. Cough. Labored breathing. Sore throat.
Prevention No open flames. Local exhaust or breathing protection.
First Aid/Fire Powder, water spray, foam, carbon dioxide. Fresh air, rest. Refer for medical attention.
Skin
Redness.
Protective gloves Remove contaminated and clothing. clothes. Rinse skin with plenty of water or shower. Safety goggles. First rinse with plenty of water for several minutes; remove contact lenses if possible; seek medical attention. Rinse mouth. Rest. Refer for medical attention.
Eyes
Redness and pain.
Ingestion
N/A
Do not eat or drink in the laboratory. Mutagenicity
Carcinogenicity
Not a known mutagen.
Alumina
CAS No. 1344-28-1 PS solid Color white Odor odorless FP N/A BP 2980 MP 2053 2072 d 3.965 @ 25 VP 1@ 2158 VD N/A Sol insoluble
Acute Hazards/Symptoms Negligible fire hazard. N/A
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately, get medical attention.
Inhalation
Coughing, shortness of breath, Ventilation, local respiratory tract irritation due to exhaust. mechanical action, and exacerbation of symptoms in persons with impaired pulmonary function. Irritant dermatitis, pruritis. Protective gloves and clothing.
Skin
Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Eyes
Irritation, redness, and possibly swelling of the conjunctiva.
Safety goggles.
Ingestion
N/A
Carcinogenicity
Possible carcinogen
Mutagenicity
Aluminum Chloride
CAS No. 7446-70-0 PS solid Color white Odor pungent FP N/A BP N/A MP 190 @ 1900 d 2.44 @ 25 VP 1@ 100 VD N/A Sol reacts
Prevention
First Aid/Fire Carbon dioxide, regular dry chemical. Remove from exposure immediately, get medical attention immediately.
Inhalation
Forms corrosive hydrochloric acid on contact with moisture, coughing, choking, pain in the nose, mouth and throat and burns of the mucous membranes. Symptoms may include tightness in the chest, frothy sputum, cyanosis, and dizziness. Severe irritation, pain, and possibly burns.
Ventilation, local exhaust.
Skin
Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately, continue to wash eyes with water. Give water or milk; if vomiting occurs, keep head lower than hips; get medical attention immediately.
Eyes
Redness, pain, blurred vision, and corneal burns.
Safety goggles.
Ingestion
Burning pain in the mouth and throat, Do not eat or drink in severe burns of the mucous the laboratory. membranes, discoloration of the tissues, swallowing and speech may be difficult, vomiting, diarrhea, hemolysis, kidney damage, and liver damage with jaundice. Not a known carcinogen. Mutagenicity
Carcinogenicity
Possible mutagen.
4-Aminobenzoic Acid
CAS No. 150-13-0 PS solid Color white Odor N/A FP N/A BP N/A MP 188189 d 1.374 VP N/A VD N/A Sol 5.39 g/L
Acute Hazards/Symptoms Emits toxic fumes under fire conditions. May be harmful if inhaled. Irritating to respiratory system. Do not breathe in dust. Causes skin irritation. May cause sensitization by skin contact. Causes eye irritation
Prevention No open flames or sparks. Ventilation, local exhaust.
First Aid/Fire Water spray, Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Seek medical advice. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water lifting upper and lower lids occasionally. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Inhalation
Skin
Protective gloves and clothing. Safety goggles.
Eyes
Ingestion
Harmful if swallowed.
Carcinogenicity
Mutagenicity
Ammonium Hydroxide
CAS No. 1336-21-6 PS liquid Color colorless Odor pungent, sharp FP N/A BP 36 MP N/A d 0.90 VP 115 @ 20 VD 1.2 Sol soluble
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately; get immediate medical attention.
Inhalation
Irritation, swelling of the lips, Ventilation, local restlessness, runny nose, headache, exhaust. salivation, nausea, vomiting, difficulty in speaking, decreased respiratory function, and inflammation, or edema of the larynx. Severe pain, stinging sensation, severe Protective gloves and burns and vesiculation, and possibly clothing. brownish stains.
Skin
Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Do not induce vomiting; give large amounts of water or milk; when vomiting occurs keep head lower than hips; get medical attention immediately. Not a known mutagen.
Eyes
Severe pain, loss of corneal epithelium Safety goggles. despite irrigation, swelling of the eyelids, and increased intraocular pressure. Corneal anesthesia is possible, allowing damage to occur before warning discomfort is felt. Immediate pain, circumoral burns, corrosion of the mucous membranes, profuse salivation, inability to swallow or speak. Shock with marked hypotension, weak and rapid pulse, shallow respiration, and clammy skin may occur. Not a known carcinogen. Do not eat or drink in the laboratory.
Ingestion
Carcinogenicity
Mutagenicity
Aniline
CAS No. 62-53-3 PS liquid Color colorless Odor fishy FP 70 BP 184 MP N/A d 1.022 VP 0.6 @ 20 VD 3.2 Sol 3.5%
First Aid/Fire Regular dry chemical, carbon dioxide, regular foam, alcohol resistant foam Remove from exposure immediately; get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately; if vomiting occurs, keep head lower than hips; get medical attention immediately.
Inhalation
May cause effects as described under ingestion.
Skin
Irritation, sensitization dermatitis, Protective gloves and readily absorbed through the skin, and clothing. a small amount absorbed from clothes or shoes may cause toxic symptoms as described in acute ingestion. Redness, pain, and possible corneal damage. Safety goggles.
Eyes
Ingestion
Headache, nausea, vomiting, chest or Do not eat or drink in abdominal pain, dryness of the throat, the laboratory. cyanosis, lips, tongue and mucous membranes may be navy blue to black and the skin may appear slate gray, central nervous system effects may include confusion, irritability, vertigo, numbness of extremities, pain in joints, and drowsiness. Aniline crosses the placental barrier and exposure during pregnancy may affect the fetus. Possible carcinogen. Mutagenicity
Carcinogenicity
Possible mutagen.
trans-p-Anisalacetophenone
CAS No. 959-33-1 PS solid Color yellow Odor N/A FP N/A BP N/A MP 7376 d N/A VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms Flammable. Emits toxic fumes under fire conditions. Irritant, may be harmful if inhaled. Irritant, may be harmful to the skin.
First Aid/Fire Water spray, carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advise. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Inhalation Skin
Eyes
Vapor or mist is irritating to the eyes, may be harmful.
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
p-Anisaldehyde
CAS No. 123-11-5 PS liquid Color colorless Odor floral FP 116 BP 118 121 MP -1 d 1.119 1.123 VP 133.5 @ 73 VD 4.7 Sol slightly soluble
Prevention Avoid heat, flames, sparks Ventilation, local exhaust. Protective gloves and clothing.
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
N/A
Skin
Irritation.
Eyes
N/A
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Anisole
CAS No. 100-66-3 PS liquid Color Odor FP 43 BP 155 MP N/A d 0.9961 VP 10 @ 42.2 VD 3.7 Sol insoluble
colorless licoricelike
Acute Hazards/Symptoms Moderate fire hazard., vapors or gases may ignite at distant ignition sources Irritation, dizziness, or suffocation
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips, get medical attention, if needed. Not a known mutagen.
Inhalation
Skin
Irritation
Eyes
Irritation
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Azobenzene
CAS No. 103-33-3 PS solid Color orange Odor N/A FP >143 BP 293 MP 69 d 1.203 VP 1@ 103 VD N/A Sol insoluble
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately; if vomiting occurs, keep head lower than hips; get medical attention. Not a known mutagen.
Inhalation
Coughing, shortness of breath, dizziness, dullness, bluish skin, and faintness. Irritation, possibly absorbed through intact skin with dizziness, dullness, bluish skin and faintness, all symptoms of methemoglobenimia. Irritation, redness, and pain.
Skin
Eyes
Safety goggles.
Ingestion
Abdominal pain, dizziness, dullness, bluish skin, faintness, and methemoglobinemia.
Carcinogenicity
Possible carcinogen.
Mutagenicity
1,1Azobis(cyclohexanecarbonitrile)
CAS No. 2094-98-6 PS solid Color white Odor N/A FP N/A BP N/A MP 115118 d N/A VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms Flammable. Capable of creating a dust explosion. Container explosion may occur under fire conditions. Emits toxic fumes under fire conditions. May be harmful if inhaled. Irritating to respiratory system. Prolonged exposure can cause nausea, headache, and vomiting. Irritating to the skin.
First Aid/Fire Smother with dry sand, limestone, or clay. A Class D extinguisher may be used. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Inhalation
Skin
Eyes
Irritating to the eyes.
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Benzaldehyde
CAS No. 100-52-7 PS liquid Color colorless Odor almondlike FP 63 BP 178 MP -26 d 1.0415 @ 10 VP 1@ 26.2 VD 3.65 Sol 0.29%
Acute Hazards/Symptoms Moderate fire hazard., vapors or gases may ignite at distant ignition sources. Sore throat, and coughing, central nervous system depression with nausea, vomiting, headache, lightheadedness. irritation, redness, pain, weak local anesthesia, possible absorption through the skin. Irritation, lacrimation, redness, pain, and eye injury.
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately; if vomiting occurs, keep head lower than hips; get medical attention immediately. Not a known mutagen.
Inhalation
Skin
Eyes
Safety goggles.
Ingestion
Sore throat, central nervous system depression, nausea, vomiting, abdominal pain, headache, dizziness, dullness, convulsions, and respiratory failure. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Benzamide
CAS No. 55-21-0 PS solid Color colorless Odor N/A FP 180 BP 288 MP 130 d 1.341 VP N/A VD N/A Sol 1.35%
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs keep head lower than hips, get medical attention, if needed. Not a known mutagen.
Inhalation
N/A
Skin
N/A
Eyes
N/A
Safety goggles.
Ingestion
Headache, shortness of breath, dullness, drowsiness, nausea, vomiting, and central nervous system depression. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Benzanilide
CAS No. 93-98-1 PS solid Color colorless Odor N/A FP BP N/A 117119 MP N/A d 1.315 VP N/A VD N/A Sol insoluble
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs keep head lower than hips, get medical attention, if needed. Not a known mutagen.
Inhalation
N/A
Skin
May be absorbed through the skin
Eyes
Irritation
Safety goggles.
Ingestion
N/A
Carcinogenicity
Mutagenicity
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
Benzenesulfonyl Chloride
CAS No. 98-09-9 PS liquid Color colorless Odor N/A FP 132 BP 251 252 dec MP 14.5 d 1.4 VP 1.3 @ 20 VD N/A Sol reacts
Acute Hazards/Symptoms Negligible fire hazard., slight explosion hazard Acidic corrosive action: sore throat, coughing, choking, weakness and labored breathing, tightness in the chest, dizziness, cyanosis, and low blood pressure. Redness, pain, and serious burns. N/A
Prevention
First Aid/Fire Regular dry chemical, regular foam, water Remove from exposure immediately; get medical attention immediately.
Skin
Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately; give large amounts of water or milk, allow vomiting to occur; when vomiting occurs, keep head lower than hips; get medical attention immediately. Not a known mutagen.
Eyes
Irritation, burns, and permanent corneal damage.
Safety goggles.
Ingestion
Severe burning pain in the mouth, Do not eat or drink in throat and abdomen, nausea, vomiting, the laboratory. diarrhea, sudden drop in blood pressure.
Carcinogenicity
Mutagenicity
Benzilic Acid
CAS No. 76-93-7 PS powder Color white Odor N/A FP N/A BP 187 MP 150153 d N/A VP N/A VD N/A Sol 1.758 g/L
Acute Hazards/Symptoms Emits toxic fumes under fire conditions. Harmful by inhalation.
First Aid/Fire Water spray, Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Seek medical advice. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water lifting upper and lower lids occasionally. Seek medical advice. If swallowed, wash out mouth with water. Call a physician. Not a known mutagen
Inhalation
Skin
May cause skin irritation.
Eyes
May cause eye irritation.
Ingestion
Carcinogenicity
Mutagenicity
Benzoic Acid
CAS No. 65-85-0 PS solid Color white Odor varying sharp FP 121 BP 249 MP 122 d VP VD 4.2 Sol 2.9% @ 20
1.2659 1 @ 96 @ 15
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam Remove from exposure immediately, get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several minutes, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips, get medical attention, if needed. Not a known mutagen.
Inhalation
Irritation, sore throat, and coughing
Skin
Irritation and redness
Eyes
Irritation and redness
Safety goggles.
Ingestion
Sore throat, gastric pain, nausea, vomiting, and allergic reactions
Carcinogenicity
Mutagenicity
Benzoyl Chloride
CAS No. 98-88-4 PS liquid Color Odor FP 68 BP 197 MP N/A d VP VD Sol decomposes
colorless pungent
1.211 1 @ 32 4.88
Prevention No flames, no sparks, no contact with hot surfaces.
First Aid/Fire Carbon dioxide, regular dry chemical
Inhalation
Irritation, burns, sore throat, coughing, Ventilation, local labored breathing, pulmonary edema, exhaust. liver and kidney damage.
Remove from exposure immediately; keep warm and at rest, get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, and continue to wash eyes with water. If person conscious, give water or milk; if vomiting occurs, keep head lower than hips; get medical attention immediately.
Skin
Irritation, redness, pain, and burns.
Eyes
Irritation, redness, pain, blurred vision, Safety goggles. and severe eye burns.
Ingestion
Immediate pain and severe burns of mucous membranes of the mouth and throat and gastrointestinal tract, nausea, vomiting, abdominal pain, diarrhea, and central nervous system depression. Possible carcinogen.
Carcinogenicity
Mutagenicity
Benzyl Bromide
CAS No. 100-39-0 PS liquid Color colorless Odor N/A FP 86 BP 198199 MP -3 -1 d VP 1.439 0.242 @17 VD 5.8 Sol insoluble
Acute Hazards/Symptoms Water hydrolyzes material liberating acidic gas that in contact with metal surfaces can generate flammable and/or explosive hydrogen gas. Emits toxic fumes under fire conditions. Do not breathe vapor. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache nausea and vomiting. Target organ; central nervous system. Do not get on skin. Material is extremely destructive to tissue of the upper mucous membranes. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache nausea and vomiting. Do not get in eyes. Lachrymator.
Prevention Avoid heat, sparks, flames.
First Aid/Fire Carbon dioxide, dry chemical powder or appropriate foam. Do not use water. Remove to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed, wash out mouth with water provided person is conscious. Call a physician. Not a known mutagen
Inhalation
Skin
Eyes
Safety goggles.
Ingestion
Harmful if swallowed. Symptoms may Do not eat or drink in include burning sensation, coughing, the laboratory. wheezing, laryngitis, shortness of breath, headache nausea and vomiting.
Carcinogenicity
Mutagenicity
Benzyltriphenylphosphonium Chloride
CAS No. 1100-88-5 PS solid Color off-white Odor faint FP >299 BP N/A MP 300 d 1.18 @ 25 VP N/A VD N/A Sol moderately soluble
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several minutes, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately; if vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Skin
Absorption through skin: depression, diarrhea or irritability.
Eyes
Irritation, death in animals.
Safety goggles.
Ingestion
Depression, labored breathing, Do not eat or drink in diarrhea; kidneys, liver, and lungs may the laboratory. be affected.
Carcinogenicity
Mutagenicity
Bicyclo[2.2.1]hept-5-en-cis-endo-2,3-dicarboxylic Acid
CAS No. 3853-88-1 PS solid Color colorless Odor N/A FP N/A BP N/A MP 191 193 d N/A VP N/A VD N/A Sol slightly soluble
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.*
Inhalation
Irritation*
Skin
Irritation*
Eyes
Irritation*
Safety goggles.
Ingestion
N/A
Carcinogenicity
Not a known carcinogen.*
Mutagenicity
*Toxicological information for the listed chemical is not available. Information given pertains to cyclohexane-cis1,2-dicarboxylic acid and is intended to be used for comparison of a similar compound. Other effects may result from contact, inhalation, or ingestion. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
Bicyclo[2.2.1]hept-5-en-endo-2,3-dicarboxylic Anhydride
CAS No. 129-64-6 PS solid Color white Odor N/A FP N/A BP N/A MP 164 165 d 1.417 VP N/A VD N/A Sol reacts
Acute Hazards/Symptoms SEVERE fire hazard.
First Aid/Fire Regular dry chemical, sand, earth, regular foam. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
Irritation, runny or stuffy nose, wheezing, asthmatic symptoms, central nervous system depression, headache, nausea, and vomiting. Irritation, absorption through skin may cause central nervous system depression, headache, nausea, and vomiting. Symptoms as given in acute skin contact.
Skin
Eyes
Safety goggles.
Ingestion
Symptoms as given in acute inhalation. Do not eat or drink in the laboratory.
Carcinogenicity
Mutagenicity
Borane-THF Solution
CAS No. 14044-65-6 PS liquid Color Odor FP -17 BP >69 MP N/A d 0.898 VP N/A VD N/A Sol reacts
colorless irritating
Acute Hazards/Symptoms Severe fire hazard.
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs keep head lower than hips, get medical attention, if needed. Not a known mutagen.
Inhalation
Irritation, headache, nausea, and vomiting. Irritation.
Skin
Eyes
Irritation.
Safety goggles.
Ingestion
Headache, nausea, and vomiting.
Carcinogenicity
Mutagenicity
Bromine
CAS No. 7726-95-6 PS liquid Color Odor FP N/A BP 59 MP N/A d 3.12 VP VD Sol 4%
brown to irritating red
175 @ 7.14 20
Acute Hazards/Symptoms Negligible fire hazard., may ignite or explode on contact with combustible materials. Irritation, copious mucous secretion, coughing, nosebleeds, and headache. Delayed symptoms: nausea, diarrhea and abdominal pains, pulmonary edema, pneumonitis or pneumonia. Cooling sensation, burning sensation, redness, pain, brown discoloration, blisters, discharging pustules, destructive burns and deep-seated ulcers. Redness, pain, blurred vision, burns, lacrimation, photophobia, loss of vision
Prevention
First Aid/Fire
Avoid contact with Regular dry chemical, combustible materials carbon dioxide, regular foam Ventilation, local exhaust. Remove from exposure immediately; get immediate medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, and continue to wash eyes with water. Contact physician immediately; give large amounts of water or milk and allow vomiting to occur; when vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Skin
Eyes
Safety goggles.
Ingestion
Burns of the mouth, throat and Do not eat or drink in stomach, brown discoloration and the laboratory. corrosion of the tongue and mucous membranes, sore throat, and vomiting.
Carcinogenicity
Mutagenicity
4-Bromoacetanilide
CAS No. 103-88-8 PS solid Color offwhite Odor N/A FP N/A BP N/A MP 167169 d 1.717 VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms Flammable. Emits toxic fumes under fire conditions. May be irritating if inhaled.
Inhalation
Skin
Irritating to the skin.
Eyes
Vapor or mist is irritating to the eyes.
Safety goggles.
Ingestion
Toxic, harmful if swallowed.
Carcinogenicity
Mutagenicity
Bromobenzene
CAS No. 108-86-1 PS liquid Color colorless Odor pleasant FP 51 BP 156 MP N/A d 1.49 VP VD Sol 0.045%
3 @ 20 5.41
Acute Hazards/Symptoms Moderate fire hazard., vapors or gases may ignite at distant ignition sources. Irritation, headache, sore throat, coughing, shortness of breath, nausea, vomiting, and dizziness. Irritation, redness, abdominal pain, nausea, vomiting, diarrhea, headache, dullness, and central nervous system effects. Irritation, redness, and pain.
Prevention
First Aid/Fire
No heat, no flames, no Alcohol resistant foam, sparks carbon dioxide, regular dry chemical, water. Ventilation, local exhaust. Protective gloves and clothing. Remove from exposure immediately, get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs keep head lower than hips, get medical attention, if needed. Not a known mutagen.
Inhalation
Skin
Eyes
Safety goggles.
Ingestion
Headache, abdominal pain, gastrointestinal irritation, nausea, vomiting, diarrhea, dizziness, and central nervous system effects. Not a known carcinogen.
Carcinogenicity
Mutagenicity
1-Bromobutane
CAS No. 109-65-9 PS liquid Color colorless Odor N/A FP 22 BP 99-101 MP N/A d 1.3 VP 150 @ 25 VD 4.7 Sol insoluble
Acute Hazards/Symptoms SEVERE fire hazard.
Prevention No open flames, no sparks, no contact with hot surfaces. Vapors or gases may ignite at distant ignition sources. Ventilation, local exhaust. Protective gloves and clothing.
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam
Inhalation
Irritation of mucous membranes, narcosis Irritation, burns
Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry. Thoroughly wash skin with water. Get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention. If vomiting occurs keep head lower than hips. Get medical attention immediately. Not a known mutagen.
Skin
Eyes
Irritation
Safety goggles.
Ingestion
Gastrointestinal disturbances, possibly Do not eat or drink in narcosis. the laboratory.
Carcinogenicity
Mutagenicity
1-Bromoethylbenzene
CAS No. 585-71-7 PS liquid Color colorless Odor N/A FP 81 BP MP d 94 @ 16 49.550.5 1.356 torr Prevention Avoid heat, sparks, flames. Ventilation, local exhaust. VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms Combustible
First Aid/Fire Water spray, carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen.
Inhalation
Skin
Eyes
Irritating to respiratory system. Vapor or mist is irritating to the mucous membranes and respiratory tract. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting. Harmful if absorbed through skin. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting. Vapor or mist is irritating to the eyes.
Safety goggles.
Ingestion
Harmful if swallowed. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache nausea and vomiting. Not a known carcinogen.
Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advise. If swallowed wash out mouth with water. Call a physician.
Carcinogenicity
Mutagenicity
2-Bromohexane
CAS No. 111-25-1 PS liquid Color colorless Odor N/A FP 135 BP 154158 MP -85 d 1.176 VP <10 VD 5.7 Sol insoluble
Acute Hazards/Symptoms Combustible. Emits toxic fumes under fire conditions.* May be harmful if inhaled. Irritating to respiratory system.* Irritating to the skin.*
Inhalation Skin
Eyes
Irritating to the eyes.*
Safety goggles.
Ingestion
May be harmful if swallowed.*
Do not eat, drink, or smoke during work.
Carcinogenicity
Mutagenicity
* Toxicological information for the listed chemical is not available. Information given pertains to 1-bromohexane and is intended to be used for comparison of a similar compound. Other effects may result from contact, inhalation, or ingestion. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density (g/mL); Sol = solubility in water; N/A = not available or not applicable.
2-Bromonitrobenzene
CAS No. 577-19-5 PS solid Color yellow Odor distinct FP >110 BP 261 MP 4042 d 1.62 VP N/A VD 7.0 Sol almost insoluble
Acute Hazards/Symptoms Slight fire hazard. Irritation. If sufficient amounts are absorbed, methemoglobinemia may occur.
Prevention Avoid heat, flames, and sparks. Ventilation, local exhaust.
First Aid/Fire Regular dry chemical, regular foam, water Remove from exposure immediately, get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Skin
Irritation. Skin absorption may occur Protective gloves and and may result in methemoglobinemia clothing. as detailed in ingestion. Irritation Safety goggles.
Eyes
Ingestion
Nausea and vomiting, abdominal pain, Do not eat or drink in coma, and paralysis. the laboratory.
Carcinogenicity
Mutagenicity
4-Bromonitrobenzene
CAS No. 586-78-7 PS solid Color off-white Odor N/A FP BP MP 125127 d 1.934 VP N/A VD N/A Sol insoluble
N/A 255256
Acute Hazards/Symptoms Slight fire hazard. Irritation and possibly conditions detailed in inhalation Irritation, skin absorption may occur and may result in conditions detailed in inhalation. Irritation
First Aid/Fire Regular dry chemical, regular foam, water Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Skin
Eyes
Safety goggles.
Ingestion
Nausea and vomiting, abdominal pain, Do not eat or drink in confusion, irritability, tremor, memory the laboratory. loss, anorexia, emaciation, headache, slurred speech, conjunctivitis Not a known carcinogen. Mutagenicity
Carcinogenicity
4-Bromophenol
CAS No. 106-41-2 PS solid Color white to off-white Odor N/A FP BP MP 6468 d 1.840 @ 15 VP negligible VD N/A Sol >10%
N/A 235236
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention. If vomiting occurs, keep head lower than hips, get medical attention, if needed. Not a known mutagen.
Inhalation
Irritation
Skin
Irritation, depigmentation
Eyes
Irritation
Safety goggles.
Ingestion
Rapidly absorbed from the gastroenteric tract, nausea and vomiting, abdominal pain.
Carcinogenicity
Mutagenicity
1-Bromopropane
CAS No. 106-94-5 PS liquid Color colorless Odor N/A FP 22 BP 71 MP -110 d 1.353 VP 100 @18 VD 4.25 Sol 0.25 g/100 mL:
Acute Hazards/Symptoms Flammable liquid and vapor.
Prevention NO open flames or sparks. Local exhaust.
First Aid/Fire Dry chemical, alcohol foam or carbon dioxide. Water may be ineffective. Remove to fresh air. If breathing is difficult, give oxygen. Get medical attention. Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention. Give large amounts of water to drink. Get medical attention. Possible mutagen.
Inhalation
Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath. A central nervous system depressant. Causes irritation to skin. Symptoms include redness, itching, and pain.
Skin
Protective gloves and clothing..
Eyes
Causes irritation, redness, and pain.
Safety goggles.
Ingestion
Causes irritation to the gastrointestinal Do not eat or drink in tract. Symptoms may include nausea, the laboratory. vomiting and diarrhea. Not a known carcinogen. Mutagenicity
Carcinogenicity
4-Bromo-2-chloroacetanilide
CAS No. 3460-23-9 PS solid Color colorless Odor N/A FP N/A BP N/A MP 151 d N/A VP N/A VD N/A Sol insoluble
Types of Hazard/Exposure Fire Inhalation Skin
Prevention No flames, no sparks, no contact with hot surfaces Ventilation, local exhaust.
First Aid/Fire
Eyes
Ingestion
Regular dry chemical, carbon dioxide, water, regular foam. Irritation, may be harmful.* Remove from exposure immediately, get medical attention. Irritation, may be harmful if absorbed Protective gloves and Remove contaminated through skin.* clothing. clothes and jewelry, thoroughly wash skin with water. Irritation.* Safety goggles. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Irritation, may be harmful.* Do not eat or drink in If vomiting occurs, keep the laboratory. head lower than hips; get medical attention, if needed. Not a known carcinogen.* Mutagenicity Not a known mutagen.*
Carcinogenicity
*Toxicological information for the listed chemical is not available. Information given pertains to 2-chloroacetanilide and is intended to be used for comparison of a similar compound. Other effects may result from contact, inhalation, or ingestion. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
4-Bromo-2-chloroaniline
CAS No. 38762-41-3 PS solid Color colorless Odor N/A FP N/A BP N/A MP 7072 d N/A VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms Low fire hazard.
First Aid/Fire Water spray, carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Seek medical advice. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water lifting upper and lower lids occasionally. Seek medical advice. If swallowed, wash out mouth with water. Not a known mutagen
Inhalation
Harmful if inhaled.
Skin
Harmful if in contact with skin.
Eyes
Harmful to eyes.
Ingestion
Carcinogenicity
4-Bromo-2-chloro-6-iodoaniline
CAS No. 147-82-0 PS liquid Color beige Odor N/A FP N/A BP 300 MP 120122 d N/A VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms Emits toxic fumes under fire conditions. *
First Aid/Fire
Inhalation Skin
Eyes
Ingestion
Water spray, carbon dioxide, dry chemical powder or appropriate foam. Highly Toxic if inhaled. * Ventilation, local Remove to fresh air. If exhaust. breathing is difficult, give oxygen. Toxic if absorbed through skin. Causes Protective gloves and Immediately flush skin skin irritation. * clothing. with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Harmful to the eyes. * Safety goggles. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. Highly toxic if swallowed. * Do not eat or drink in If swallowed, wash out the laboratory. mouth with water. Call a physician. Carcinogen * Mutagenicity Not a known mutagen.*
Carcinogenicity
* Toxicological information for the listed chemical is not available. Information given pertains to 2,4,6tribromoaniline and is intended to be used for comparison of a similar compound. Other effects may result from contact, inhalation, or ingestion. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density (g/mL); Sol = solubility in water; N/A = not available or not applicable.
1-Bromo-3-chloro-5-iodobenzene
CAS No. 13101-40-1 PS solid Color colorless Odor N/A FP N/A BP N/A MP 85.8 d N/A VP N/A VD N/A Sol insoluble
Prevention
First Aid/Fire
Skin
Eyes
Ingestion
Regular dry chemical, carbon dioxide, water, regular foam. Remove from exposure immediately, artificial respiration if needed; get medical attention. Irritation, possibly corrosion.* Protective gloves and Remove contaminated clothing. clothes and jewelry, thoroughly wash skin with water. Lacrimation, irritation, and possibly Safety goggles. Thoroughly wash eyes corrosion.* with water for several min, remove contact lenses if possible, and seek medical attention immediately. N/A Do not eat or drink in If vomiting occurs, keep head lower than hips; get the laboratory. medical attention, if needed. Not a known carcinogen.* Mutagenicity Not a known mutagen.*
No flames, no sparks, no contact with hot surfaces Respiratory tract effects, central nervous Ventilation, local system, effects, and possibly corrosion.* exhaust.
Carcinogenicity
*Toxicological information for the listed chemical is not available. Information given pertains to 1,3,5-tribromobenzene and is intended to be used for comparison of a similar compound. Other effects may result from contact, inhalation, or ingestion. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
2-Bromo-2-methylbutane
CAS No. 507-36-8 PS liquid Color colorless Odor N/A FP 4 BP 107 MP N/A d 1.182 VP N/A VD N/A Sol N/A
Types of Acute Hazards/Symptoms Hazard/Exposure Fire Severe fire hazard; vapors may ignite at distant ignition sources. Inhalation Skin May be harmful. Irritation, may be harmful if absorbed through skin. Irritation, may be harmful.
Prevention No flames, no sparks, no contact with hot surfaces. Ventilation, local exhaust. Protective gloves and clothing. Safety goggles.
First Aid/Fire Carbon dioxide, dry chemical powder, foam, water. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Eyes
Ingestion
May be harmful.
Carcinogenicity
Mutagenicity
1-Butanol
CAS No. 71-36-3 PS liquid Color colorless Odor irritating FP 29 BP 117 MP N/A d 0.81 VP VD Sol 7.7%
6.5 2.55 @ 25
Acute Hazards/Symptoms SEVERE fire hazard., vapors or gases may ignite at distant ignition sources. 25 ppm: irritation. At 50 ppm: sore throat, coughing, nausea, and central nervous system depression with headache and dizziness. irritation with redness and dryness, may be absorbed through skin
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry. Thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediatly. Contact physician immediately. If vomiting occurs, keep head lower than hips; get medical attention immediately. Possible mutagen.
Inhalation
Skin
Eyes
moderate temporary injury
Safety goggles.
Ingestion
abdominal pain, nausea, vomiting, and Do not eat or drink in diarrhea. High doses: complete the laboratory. paralysis, reduction of body temperature and respiration.
Carcinogenicity
Mutagenicity
2-Butanol
CAS No. 78-92-2 PS liquid Color colorless Odor strong, pleasant FP 24 BP 94 MP -115 d 0.81 VP 13 @ 20 VD 2.6 Sol 15 g/ 100 mL.
Acute Hazards/Symptoms Flammable.
Prevention
First Aid/Fire
No flames, no sparks, Foam, powder, alcoholno contact with hot resistant foam, water sufaces spray, carbon dioxide. Local exhaust. Fresh air, rest. Refer for medical attention.
Inhalation Skin
Dizziness. Drowsiness. Headache. Dry skin.
Protective gloves and Remove contaminated clothing.. clothes. Rinse skin with plenty of water or shower. Safety goggles. First rinse with plenty of water for several minutes; remove contact lenses if possible; seek medical attention.
Eyes
Redness. Pain. Blurred vision.
Ingestion
Dizziness. Drowsiness. Headache.
Do not eat or drink in Rinse mouth. Give plenty the laboratory. of water to drink. Refer for medical attention. Mutagenicity Not a known mutagen.
Carcinogenicity
2-Butanone
CAS No. 78-93-3 PS liquid Color colorless Odor sharp, mintlike FP -9 BP 80 MP -86 d .805 VP 78 @ 20 VD 2.5 Sol 29 g/ 100 mL
Acute Hazards/Symptoms Highly flammable.
Prevention No flames, no sparks, no contact with hot sufaces
First Aid/Fire Powder, AFFF, foam, carbon dioxide. Fresh air, rest. Refer for medical attention. Remove contaminated clothes. Rinse skin with plenty of water or shower. First rinse with plenty of water for several minutes; remove contact lenses if easily possible; seek medical attention. Rinse mouth. Give plenty of water to drink. Refer for medical attention. Possible mutagen.
Inhalation
Cough. Dizziness. Dullness. Headache. Local exhaust. Nausea. Shortness of breath. Unconsciousness. Vomiting. MAY BE ABSORBED! Redness. Protective gloves and clothing. Safety goggles.
Skin
Eyes
Redness. Pain.
Ingestion
Dizziness. Drowsiness. Headache.
Carcinogenicity
Mutagenicity
3-Buten-2-one
CAS No. 78-94-4 PS liquid Color colorless Odor irritating FP -6 BP 81 MP N/A d 0.842 VP 120 @ 34 VD 1.3 Sol soluble
Acute Hazards/Symptoms SEVERE fire hazard., vapors or gases may ignite at distant ignition sources. Coughing, choking, pain, burns, pulmonary edema, tightness in the chest, cyanosis, dizziness, low blood pressure; central nervous system depression, headache, nausea, and vomiting. Irritation, pain, burns; absorption through the skin may cause central nervous system depression, headache, dizziness, nausea, vomiting. Irritation, pain, and burns.
Prevention No flames, no sparks, no contact with hot sufaces Ventilation, local exhaust.
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water Remove from exposure immediately; keep warm and at rest; get medical attention immediately.
Inhalation
Skin
Remove contaminated clothes and jewelry, thoroughly wash skin with water, and get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, and continue to was eyes with water until medical help arrives. Give water or milk; if vomiting occurs, keep head lower than hips; get medical attention immediately. Not a known mutagen.
Eyes
Safety goggles.
Ingestion
Immediate pain and severe burns, discoloration of the tissues, swallowing and speech may be difficult or impossible, and shock.
Carcinogenicity
Mutagenicity
n-Butyl Acetate
CAS No. 123-86-4 PS liquid Color colorless Odor mild, fruity FP 26 BP 126 MP -77 d .8826 VP 15 @ 25 VD 4.0 Sol ca. 0.7%
Types of Acute Hazards/Symptoms Hazard/Exposure Fire Highly flammable.
Prevention No flames, no sparks, no contact with hot sufaces Local exhaust or breathing protection. Protective gloves and clothing. Safety goggles.
First Aid/Fire Powder, AFFF, foam, carbon dioxide. Fresh air, rest. Refer for medical attention. Remove contaminated clothes. Rinse skin with plenty of water or shower. First rinse with plenty of water for several minutes; remove contact lenses if easily possible; seek medical attention. Rinse mouth. Do not induce vomiting. Rest. Refer for medical attention. Not a known mutagen.
Inhalation Skin
Cough. Dizziness. Dullness. Headache. Nausea. Dry skin. Redness.
Eyes
Redness. Pain.
Ingestion
N/A
Carcinogenicity
Mutagenicity
tert-Butyl Peroxybenzoate
CAS No. 614-45-9 PS liquid Color colorless to light yellow Odor N/A FP 93 BP 7576 @ 0.2 torr MP 8 d 1.021 VP 3.36 @ 50 VD 6.7 Sol insoluble
Acute Hazards/Symptoms Flammable. Contact may cause fire, may accelerate fires. Emits toxic fumes under fire conditions. May be harmful if inhaled. May be harmful if absorbed through skin.
Prevention
First Aid/Fire
Eyes
May be harmful to the eyes.
Ingestion
No open flames or Carbon dioxide, dry sparks. No Smoking. chemical powder or appropriate foam. Ventilation, local Remove to fresh air. If exhaust. breathing is difficult, give oxygen. Protective gloves and Immediately flush skin clothing. with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Safety goggles. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. Do not eat or drink in If swallowed wash out the laboratory. mouth with water. Call a physician. Mutagenicity Not a known mutagen.
Carcinogenicity
n-Butylbenzene
CAS No. 104-51-8 PS liquid Color colorless Odor mild aromatic FP 54 BP 182183 MP -88 d 0.86 VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms Combustible and flammable liquid. Emits toxic fumes under fire conditions. May be harmful by inhalation. Do not breathe vapor.
First Aid/Fire Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Seek medical advice. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water lifting upper and lower lids occasionally. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Skin
May be harmful absorbed through skin. May cause eye irritation.
Eyes
Ingestion
Carcinogenicity
Mutagenicity
sec-Butylbenzene
CAS No. 135-98-8 PS liquid Color colorless Odor mild aromatic FP 45 BP 173174 MP -75 d 0.863 VP 4 VD N/A Sol N/A
Acute Hazards/Symptoms Flammable. Emits toxic fumes under fire conditions. Harmful if inhaled. Irritating to respiratory system. Irritating to the skin.
Inhalation Skin
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
tert-Butylbenzene
CAS No. 98-06-6 PS liquid Color colorless Odor mild aromatic FP 34 BP 169 MP -58 d VP VD 0.867 4.79 3.16 @ @ 37.7 169 Sol insoluble
Acute Hazards/Symptoms Flammable. Emits toxic fumes under fire conditions.
First Aid/Fire Carbon dioxide, dry chemical powder or appropriate foam. Water may cool, but not extinguish. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Inhalation
May be harmful if inhaled.
Skin
May be harmful if absorbed through skin.
Eyes
May be harmful to the eyes.
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Calcium Chloride
CAS No. 10043-52-4 PS solid Color colorless Odor N/A FP N/A BP >1600 MP 782 d 2.15 @ 25 VP N/A VD N/A Sol 74.5% @ 20
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
Irritation, coughing, and shortness of breath. Severe irritation, erythema, blistering, exfoliation, and ulceration.
Ventilation, local exhaust. Protective gloves and clothing.
Skin
Eyes
Irritation, redness, pain, and superficial Safety goggles. injury.
Ingestion
Abdominal spasms, nausea, gastrointestinal tract or cardiovascular irregularities.
Carcinogenicity
Mutagenicity
Calcium Hypochlorite
CAS No. 7778-54-3 PS Color granular offwhite powder Odor N/A FP N/A BP N/A MP 100 d 2.350 VP N/A VD N/A Sol decomposes
Acute Hazards/Symptoms Contact with other material may cause fire. Contact with combustible material may cause fire. Contact with water liberates a toxic gas. Emits toxic fumes under fire conditions. Harmful if inhaled. Irritating to respiratory system. Do not breathe in dust. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Causes skin irritation. Causes burns.
Prevention No open flames or sparks.
First Aid/Fire Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Seek medical advice.
Inhalation
Skin
Eyes
Causes severe eye irritation.
Ingestion
Harmful if swallowed. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Not a known carcinogen.
Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water lifting upper and lower lids occasionally. Seek medical advice. If swallowed wash out mouth with water. Call a physician.
Carcinogenicity
Mutagenicity
Carbon, Decolorizing
CAS No. 7440-44-0 PS solid Color black Odor odorless FP N/A BP N/A MP N/A d 1.82. 1 VP 1@ 3586 VD N/A Sol insoluble
Acute Hazards/Symptoms Severe fire hazard., may ignite on exposure to air. Mucous membrane irritation
Prevention No flames, no sparks, no contact with hot sufaces Ventilation, local exhaust. Protective gloves and clothing.
First Aid/Fire Regular dry chemical, sand, earth, regular foam, water Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
Skin
N/A
Eyes
Irritation
Safety goggles.
Ingestion
N/A
Carcinogenicity
Mutagenicity
Carvone
CAS No. 2244-16-8 PS liquid Color Odor FP 98 BP 230 MP N/A d 0.9608 VP N/A VD N/A Sol insoluble
colorless spice-like
Prevention No flames, no sparks, no contact with hot sufaces. Ventilation, local exhaust. Protective gloves and clothing.
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
Irritation.
Skin
Erythema, skin absorption may occur.
Eyes
Irritation.
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Carvone 2,4-Dinitrophenylhydrazone
CAS No. 1567-89-1 PS solid Color red Odor N/A FP N/A BP N/A MP 126128 d N/A VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms Non-flammable. Emits toxic fumes under fire conditions. May be harmful if inhaled. Very irritating to respiratory system. Irritating to the skin.
Inhalation Skin
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Celite
CAS No. 61790-53-2 PS solid Color Odor FP N/A BP 2230 MP 1700 d 1.9 2.35 VP none VD N/A Sol insoluble
white to odorless off-white
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately, get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
Physical discomfort of the upper respiratory tract, coughing, silicosis. Mechanical irritation.
Skin
Eyes
Mechanical irritation.
Safety goggles.
Ingestion
Chemically and biologically inert on ingestion.
Carcinogenicity
Mutagenicity
Ceric Ammonium Nitrate

CAS No. 16774-21-3 PS solid Color Odor FP N/A BP N/A MP N/A d N/A VP N/A VD Sol
yellow to odorless red
N/A 142.6% @ 25
Acute Hazards/Symptoms Negligible fire hazard., may ignite or explode on contact with combustible materials. Severe irritation, sore throat, coughing, and shortness of breath. Irritation, redness, and pain.
Prevention Avoid contact with Water combustible materials Ventilation, local exhaust. Protective gloves and clothing.
First Aid/Fire
Inhalation
Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Skin
Eyes
Irritation, redness, and pain.
Safety goggles.
Ingestion
Burning sensation, abdominal pain, nausea, vomiting, and diarrhea.
Carcinogenicity
Mutagenicity
4-Chlorobenzaldehyde
CAS No. 104-88-1 PS solid Color white Odor N/A FP 87 BP 213214 MP 45 d 1.196 @ 61 VP N/A VD N/A Sol slightly soluble
Prevention No flames, no sparks, no contact with hot sufaces.
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. If vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Irritation, tracheobronchitis, Ventilation, local pulmonary edema, bronchopneumonia, exhaust. and bronchospasms. Irritation, erythema, swelling, nerve irritation, hyperemia, and pigmentation. Strong irritation. Protective gloves and clothing.
Skin
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
4-Chloroacetanilide
CAS No. 539-03-7 PS powder Color white Odor N/A FP N/A BP 331.3 332.4 @ 740 MP 177179 d 1.385 VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms Low fire hazard. Emits toxic fumes under fire conditions. Irritant if inhaled.
Prevention No open flames or sparks. Ventilation, local exhaust. Protective gloves and clothing. Safety goggles.
Inhalation
Skin
Irritant to skin.
Eyes
Irritant to eyes.
Ingestion
Carcinogenicity
Mutagenicity
Chloroacetyl Chloride
CAS No. 79-04-9 PS liquid Color colorless Odor N/A FP N/A BP 105106 MP -22 d 1.418 VP 60 VD 3.9 Sol decomposes
Acute Hazards/Symptoms Emits toxic fumes under fire conditions. Toxic. Corrosive. Lachrymator. Toxic by inhalation. Inhalation may result in spasm, inflammation, and edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Harmful if in contact with skin. Causes burns.
First Aid/Fire Dry chemical, foam, or carbon dioxide. Remove to fresh air. If breathing is difficult, give oxygen.
Skin
Eyes
Harmful to the eyes.
Safety goggles.
Ingestion
Toxic if swallowed. Exposure to and/or consumption of alcohol may increase toxic effects. Exposure can cause, burning sensation, wheezing, laryngitis, shortness of breath, headache, coughing, nausea, and vomiting. Not a known carcinogen.
Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician.
Carcinogenicity
Mutagenicity
Chlorobenzene
CAS No. 108-90-7 PS liquid Color colorless Odor almondlike FP 28 BP 132 MP -45 d 1.107 VP 11.8 @ 25 VD 3.9 Sol insoluble
Prevention
First Aid/Fire Powder, water spray, foam, carbon dioxide.
Flammable. Gives off irritating or toxic No flames, no fumes (or gases) in a fire. sparks, no contact with hot sufaces. Drowsiness. Headache. Nausea. Uconsciousness. Redness. Roughness.
Inhalation
Ventilation, local Fresh air, rest. Refer for exhaust., or medical attention. breathing protection. Protective gloves and clothing. First rinse with plenty of water, then remove contaminated clothes and rinse again. Refer for medical attention. First rinse with plenty of water for several minutes; remove contact lenses if possible; seek medical attention. Rinse mouth. Refer for medical attention. Possible mutagen.
Skin
Eyes
Redness.
Safety goggles.
Ingestion
Abdominal pain.
Carcinogenicity
2-Chlorobenzoic acid
CAS No. 118-91-2 PS solid Color white Odor N/A FP 173 BP 285 MP 138140 d VP VD 1.54 0.189 N/A @101 Sol slightly soluble
Acute Hazards/Symptoms Flammable. Emits toxic fumes under fire conditions. May be irritating if inhaled.
Inhalation
Skin
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
4-Chlorobenzoic Acid
CAS No. 74-11-3 PS solid Color colorless Odor N/A FP 238 BP N/A MP 239-241 d 1.541 @ 24 VP N/A VD N/A Sol soluble
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention. If vomiting occurs, keep head lower than hips, get medical attention, if needed. Not a known mutagen.
Inhalation
Irritation
Skin
Irritation, absoption may occur
Eyes
Irritation
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
4-Chlorobenzyl Alcohol
CAS No. 873-76-7 PS solid Color white Odor N/A FP N/A BP 234 MP 7072 d N/A VP N/A VD N/A Sol poorly soluble
First Aid/Fire Carbon dioxide, dry chemical powder, foam, water. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
May be harmful.
Skin
Irritation, may be harmful if absorbed through skin.
Eyes
Irritation.
Safety goggles.
Ingestion
May be harmful.
Carcinogenicity
Mutagenicity
1-Chlorobutane
CAS No. 109-69-3 PS liquid Color Odor FP -9 BP 78 MP -123 d 0.89 VP 80 @20 VD 3.2 Sol insoluble
colorless unpleasant
Prevention
First Aid/Fire Powder, AFFF, foam, carbon dioxide. Fresh air, rest. Refer for medical attention. Remove contaminated clothes. Rinse skin with plenty of water or shower. First rinse with plenty of water for several minutes; remove contact lenses if possible; seek medical attention. Rinse mouth. Refer for medical attention. Possible mutagen.
Highly flammable. Gives off irritating No flames, no sparks, or toxic fumes (or gases) in a fire. no contact with hot sufaces. Cough. Drowsiness. Sore throat. Redness. Local exhaust. Protective gloves and clothing. Safety goggles.
Inhalation Skin
Eyes
Redness.
Ingestion
Abdominal cramps. Nausea.
Carcinogenicity
-Chloro-2,6-dimethylacetanilide
Acute Hazards/Symptoms Flammable, emits toxic fumes under fire conditions. Irritating, may be harmful if inhaled. Irritating, may be harmful if absorbed through the skin.
First Aid/Fire Dry chemical, foam, or carbon dioxide. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Eyes
Irritating, may be harmful to the eyes. Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
2-Chloro-2-methylbutane
CAS No. 594-36-5 PS liquid Color colorless Odor N/A FP -9 BP 8586 MP -73 d 0.866 VP N/A VD N/A Sol slightly soluble
Acute Hazards/Symptoms SEVERE fire hazard. Vapors or gases may ignite at distant ignition sources. Irritation, narcotic
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
Skin
Irritation, central nervous system depression
Eyes
Irritation
Safety goggles.
Ingestion
Narcotic
Carcinogenicity
Mutagenicity
Chloroform
CAS No. 67-66-3 PS liquid Color colorless Odor sweet FP N/A BP 60.5 61.5 MP -63 d 1.492 VP VD Sol 0.82% @ 20
160 @ 4.12 20
Acute Hazards/Symptoms Negligible fire hazard. Irritation, central nervous system depression may be preceded by excitation and inebriation, dizziness, headache, fatigue, salivation, nausea, and vomiting. Inflammation, destruction of the epithelium, moderate necrosis; some absorption possible, resulting in weight loss and degenerative kidney changes. Burning pain, lacrimation, redness, damage to corneal epithelium. N/A
Prevention
First Aid/Fire Regular dry chemical, regular foam, water. Remove from exposure immediately, get medical attention.
Skin
Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed.
Eyes
Safety goggles.
Ingestion
Burning of the mouth, throat, esophagus, and stomach, nausea, vomiting, diarrhea, cyanosis, muscle cramps, irregular respiration, respiratory failure, and liver damage. Suspect carcinogen.
Carcinogenicity
Mutagenicity
Possible mutagen.
Chloroplatinic Acid
CAS No. 16941-121 PS solid Color Odor FP BP 115 MP 60 d 2.43 VP N/A VD 18 Sol very soluble
brownish- odorless N/A yellow
Acute Hazards/Symptoms Not considered to be a fire hazard.
Prevention
First Aid/Fire
Keep away from steel Water spray, carbon and other common dioxide, or dry powder. metals. Ventilation, local Remove to fresh air. If not exhaust., or breathing breathing, give artificial protection. respiration. If breathing is difficult, give oxygen. Get medical attention.
Inhalation
Exposure can cause severe allergies affecting the nose, skin and lungs. Irritation and even ulcers can develop in the nose. May cause platinosis. Symptoms include wheezing, coughing, tightness of the chest, shortness of breath, cyanosis, and pronounced asthmatic symptoms.
Skin
May cause platinosis; symptoms may Protective gloves and include severe irritation, eczema, clothing. urticaria, itching, and dermatitis. May cause skin allergy.
Immediately flush skin with plenty of soap and water. Remove contaminated clothing and shoes. Get medical attention. Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Eyes
May cause irritation, itching, and conjunctival vasodilation.
Safety goggles.
Ingestion
May cause vomiting and bloody diarrhea.
Do not eat or drink in Induce vomiting the laboratory. immediately as directed by medical personnel. Get medical attention. Mutagenicity Possible mutagen.
Carcinogenicity
Chlorosulfonic Acid
CAS No. 7790-94-5 PS liquid Color colorless Odor pungent FP N/A BP 158 MP N/A d VP VD Sol reacts
1.753 1 @ 20 4.02
Acute Hazards/Symptoms Negligible fire hazard., reacts violently N/A with water. Severe mucous membrane irritation, coughing, choking, headache, dizziness and weakness. Severe irritation, pain, burns, and brownish or yellowish stains
Prevention
First Aid/Fire Carbon dioxide, regular dry chemical. Remove from exposure immediately; get immediate medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible; seek medical attention immediately, and continue to wash eyes with water. Contact physician immediately; give large amounts of water or milk; allow vomiting to occur; when vomiting occurs, keep head lower than hips. Not a known mutagen.
Skin
Eyes
Corneal and conjunctival edema, iritis, Safety goggles. corneal erosion and opacity, pain, blurred vision, and photophobia.
Ingestion
Severe burning pain in the mouth, Do not eat or drink in throat and abdomen, nausea, vomiting, the laboratory. diarrhea, and bloody stools.
Carcinogenicity
Mutagenicity
Chromic Anhydride
CAS No. 1333-82-0 PS solid Color dark red Odor FP BP MP 197 d 2.7 VP N/A VD N/A Sol 63 g/100 mL
odorless N/A decomposes
Acute Hazards/Symptoms Not combustible but enhances combustion of other substances. Many reactions may cause fire or explosion. Cough. Labored breathing. Shortness of breath. Sore throat. Wheezing.
Prevention No contact with combustible substances and reducing agents.
Inhalation
Avoid inhalation of Fresh air, rest. Refer for fine dust and mist. medical attention. Ventilation (not if powder), local exhaust. Protective gloves and clothing. Safety goggles. Remove contaminated clothes. Rinse skin with plenty of water or shower. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Skin
Redness. Skin burns. Pain.
Eyes
Redness. Pain. Permanent loss of vision. Severe deep burns.
Ingestion
Abdominal cramps.
Do not eat or drink Rinse mouth. Do not in the laboratory. induce vomiting. Give plenty of water to drink. Refer for medical attention. Mutagenicity Possible mutagen.
Carcinogenicity
Known carcinogen.
Cinnamaldehyde
CAS No. 104-55-2 PS Color Odor FP 71 BP 248 MP -80 d 1.05 VP 0.03 @ 25 VD 4.6 Sol slightly soluble
oily liquid yellowish cinnamon
Acute Hazards/Symptoms Combustible liquid. Fire hazard when exposed to heat or flame.
Prevention No flames, no sparks, no contact with hot sufaces.
First Aid/Fire Dry chemical, foam, or carbon dioxide. Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Remove any contaminated clothing. Wash skin with soap or mild detergent and water for at least 15 minutes. Get medical attention if irritation develops or persists. Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. If swallowed, do not induce vomiting. Give large quantities of water. Get medical attention. Possible mutagen.
Inhalation
Causes irritation to the respiratory tract. Ventilation, local Symptoms may include coughing or exhaust. shortness of breath.
Skin
Causes irritation to skin. Symptoms Protective gloves include redness, itching, and pain. May and clothing. cause allergic reaction in sensitive individuals.
Eyes
Safety goggles.
Ingestion
May cause vomiting and bloody diarrhea.
Carcinogenicity
Mutagenicity
trans-Cinnamic Acid
CAS No. 140-10-3 PS solid Color white Odor N/A FP N/A BP 300 MP 132135 d 1.248 VP N/A VD N/A Sol 0.446 g/L
Inhalation Skin
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
N-Cinnamyl-m-nitroaniline
CAS No. 22774-96-5 PS solid Color N/A Odor N/A FP N/A BP N/A MP 115 d N/A VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms NA*
First Aid/Fire Water spray, carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician. N/A*
Inhalation Skin
NA* NA*
Eyes
NA*
Safety goggles.
Ingestion
NA*
Carcinogenicity
N/A*
Mutagenicity
* Toxicological information for the listed chemical is not available; refer to aniline and m-nitroaniline. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density (g/mL); Sol = solubility in water; N/A = not available or not applicable.
N-Cinnamylidene-m-nitroaniline
CAS No. 22856-77-5 PS solid Color N/A Odor N/A FP N/A BP N/A MP 92 d N/A VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms NA*
First Aid/Fire Water spray, carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician. NA*
Inhalation Skin
NA* NA*
Eyes
NA*
Safety goggles.
Ingestion
NA*
Carcinogenicity
NA*
Mutagenicity
* Toxicological information for the listed chemical is not available; refer to cinnamaldehyde and m-nitroaniline. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density (g/mL); Sol = solubility in water; N/A = not available or not applicable.
Citral
CAS No. 5392-40-5 PS liquid Color colorless Odor sharp lemonlike FP 90 BP 207 MP N/A d 0.88 VP N/A VD N/A Sol insoluble in water
Acute Hazards/Symptoms Not considered a fire hazard.
Prevention
First Aid/Fire
Keep away from open Carbon dioxide, dry flames and sparks. chemical, Universal-Type Foam. Ventilation or local exhaust. Remove from the exposure to fresh air. Contact a physician as necessary.
Inhalation
May be irritating if inhaled.
Skin
May be irritating to skin.
Protective gloves and Remove any contaminated clothing. clothing or shoes. Wash affected areas thoroughly with soap and water for at least 15 minutes. Contact a physician as necessary. Safety goggles. Flush immediately with clean water for at least 15 minutes. Contact a physician immediately.
Eyes
May be irritating to eyes.
Ingestion
Do not eat or drink in Give water to dilute. the laboratory.. Contact a physician immediately. Mutagenicity Not a known mutagen.
Carcinogenicity
Cupric Acetate
CAS No. 6046-93-1 PS solid Color green Odor N/A FP N/A BP N/A MP 250 (dec) d 1.882 VP N/A VD 6.9 Sol 7.2%
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam. Remove from exposure immediately; get medical attention.
Inhalation
Sore throat, coughing, shortness of Ventilation, local breath, digestive disorders, fever, and exhaust. illness similar to the common cold, with sensations of chills and stuffiness of the head. Redness, pain, and irritation. Protective gloves and clothing.
Skin
Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Not a known mutagen.
Eyes
Redness, pain, blurred vision, possibly conjunctivitis, corneal ulcerations, and turbidity.
Safety goggles.
Ingestion
Sore throat, salivation, abdominal pain, vomiting, diarrhea, and hemorrhagic gastritis. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Cupric Sulfate
CAS No. 7758-98-7 PS solid Color blue, (pentahydrate) Odor N/A FP N/A BP N/A MP 200 d 3.603 VP N/A VD N/A Sol 14.3% @ 0
Prevention
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam Remove from exposure immediately; get medical attention.
Inhalation
Sore throat, coughing, shortness of Ventilation, local breath, chest pain, a metallic taste, exhaust. spasm, inflammation, edema of larynx and bronchi, headache, nausea, chemical pneumonitis, pulmonary edema, and laryngitis. Corrosive to mucous membranes. Redness, pain, itching, papulovesicular and eczematoid lesions, and corrosive to skin. Protective gloves and clothing..
Skin
Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Give water or milk; if vomiting occurs, keep head lower than hips; seek immediate medical attention. Possible mutagen.
Eyes
Irritation, redness, pain, blurred Safety goggles. vision, and corrosive to eyes. Copper deposition in the cornea.
Ingestion
Sore throat, gastroenteric pain, blue discoloration of gums and tongue, hepatic cirrhesis, brain damage, demyelination.
Carcinogenicity
Mutagenicity
Cyclododecanol
CAS No. 1724-39-6 PS solid Color white Odor N/A FP N/A BP MP d 0.961 VP N/A VD N/A Sol slightly
125 @ 7778 12 torr
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
No specific data available, possibly central nervous system depression. Irritation, possibly skin absorption and allergic dermatitis.
Skin
Eyes
Irritation.
Safety goggles.
Ingestion
No specific data available, possibly central nervous system depression.
Carcinogenicity
Mutagenicity
Cyclododecanone
CAS No. 830-13-7 PS solid Color white Odor N/A FP 118 BP 106 MP 60 d 0.906 VP 0.8 @ 20 VD Sol
N/A 45 ppm @ 20
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam Remove from exposure immediately, get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
No signs of toxicity reported.
Skin
Irritation.
Eyes
Irritation.
Safety goggles.
Ingestion
N/A
Carcinogenicity
Mutagenicity
Cyclohexane
CAS No. 110-82-7 PS liquid Color colorless Odor sweet FP -18 BP 80.7 MP 6.5 d 0.779 VP 95 @ 20 VD 2.90 Sol insoluble
Prevention
First Aid/Fire Regular dry chemical, carbon dioxide, water for cooling, regular foam. Remove from exposure immediately; get medical attention.
SEVERE fire hazard., moderate No flames, no sparks, explosion hazard, vapors or gases may no contact with hot ignite at distant ignition sources. sufaces. Irritation, central nervous system depression with headache, dizziness, dullness, nausea, vomiting, degenerative changes in the heart, lungs, liver, kidneys, and brain. Irritation, redness, and dryness. Ventilation, local exhaust.
Inhalation
Skin
Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Possible mutagen.
Eyes
Irritation, tearing, redness, and conjunctivitis.
Safety goggles.
Ingestion
Central nervous system depression; aspiration may result in chemical pneumonitis.
Carcinogenicity
Mutagenicity
Cyclohexane-cis-1,2-dicarboxylic Acid
CAS No. 610-09-3 PS solid Color white Odor N/A FP N/A BP N/A MP 193 195 d N/A VP N/A VD N/A Sol slightly soluble
Inhalation
Irritation.
Skin
Irritation.
Eyes
Irritation.
Safety goggles.
Ingestion
N/A
Carcinogenicity
Mutagenicity
cis-1,2-Cyclohexanediol
CAS No. 1792-81-0 PS solid Color white Odor N/A FP N/A BP 117@14 MP 99-101 d 1.183 VP N/A VD N/A Sol soluble
Acute Hazards/Symptoms Fire possible at elevated temperatures or by contact with an ignition source. Emits toxic fumes under fire conditions. Irritant to respiratory system
First Aid/Fire Water spray, carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water, lifting upper and lower lids occasionally. Seek medical advice. If swallowed, wash out mouth with water. Call a physician. Not a known mutagen.
Inhalation
Skin
Irritant to skin.
Eyes
Irritant to eyes.
Ingestion
Carcinogenicity
Mutagenicity
Cyclohexanol
CAS No. 108-93-0 PS liquid Color colorless Odor pungent FP 67 BP 160 MP 2022 d 0.948 VP 1.0 @ 21 VD 3.5 Sol soluble
Prevention No flames, no sparks, no contact with hot sufaces. Ventilation, local exhaust.
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam, alcohol resistant foam. Remove from exposure immediately; get immediate medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get immediate medical attention.
Inhalation
Irritation, central nervous system depression, dizziness, drowsiness, headache, nausea, and vomiting.
Skin
Irritation, defatting of the skin, Protective gloves and absorption may lead to central nervous clothing. system depression, headache, dizziness, drowsiness, nausea, and vomiting. Irritation, redness, pain. Safety goggles.
Eyes
Ingestion
Irritation, coughing, abdominal pain, diarrhea, central nervous system depression, headache, weakness, dizziness, drowsiness, nausea, and vomiting. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Possible mutagen.
Cyclohexanone
CAS No. 108-94-1 PS liquid Color colorless Odor minty, sweet FP 46 BP 155 MP -47 d VP VD 3.4 Sol slightly soluble
0.947 2 @ 20
Acute Hazards/Symptoms Moderate fire hazard., vapors or gases may ignite at distant ignition sources. Irritation, changes in the sense of smell, respiratory system changes, narcosis, central nervous system depression, headache, dizziness, lethargy, and unconsciousness.
Prevention No flames, no sparks, no contact with hot sufaces. Ventilation, local exhaust.
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical. Remove from exposure immediately, get medical attention.
Inhalation
Skin
Irritation, burns, labored breathing, Protective gloves and hypnotic signs, defatting, clothing. dermatitis,and peritoneal and intestinal congestion. Irritation, pain, redness, lacrimation, and corneal injury. Safety goggles.
Eyes
Ingestion
Coughing, central nervous system depression, dullness, gastrointestinal irritation, and unconsciousness.
Carcinogenicity
Mutagenicity
Cyclohexanone Semicarbazone
CAS No. 1589-61-3 PS solid Color colorless Odor NA FP NA BP NA MP 167 d 1.223 VP NA VD NA Sol 6 g/L
Acute Hazards/Symptoms Flammable, emits toxic fumes under fire conditions.* May be harmful if inhaled.* May be irritating to the skin.*
First Aid/Fire Water spray, carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.*
Inhalation Skin
Eyes
Dust, vapor, or mist may be irritating to the eyes.*
Safety goggles.
Ingestion
Carcinogenicity
Not a known carcinogen. *
Mutagenicity
* Toxicological information for the listed chemical is not available. Information given pertains to acetone semicarbazone and is intended to be used for comparison of a similar compound. Other effects may result from contact, inhalation, or ingestion. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density (g/mL); Sol = solubility in water; N/A = not available or not applicable.
Cyclohexene
CAS No. 110-83-8 PS liquid Color colorless Odor sweet FP -20 BP 82 MP -104 d 0.8102 VP 67 @ 20 VD 2.8 Sol insoluble
Acute Hazards/Symptoms SEVERE fire hazard., vapors or gases may ignite at distant ignition sources.
Prevention NO flames, NO sparks, NO contact with hot surfaces. Ventilation, local exhaust.
First Aid/Fire Carbon dioxide, regular dry chemical, water.
Inhalation
Irritation, central nervous system depression, headache, dizziness, drowsiness, labored breathing, and kidney and liver damage. Defatting of the skin, redness, and burning sensation.
Remove from exposure immediately, keep warm and at rest. get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; contact physician immediately. Not a known mutagen.
Skin
Eyes
Redness and irritation.
Safety goggles.
Ingestion
Nausea, labored breathing, central Do not eat or drink in nervous system involvement, the laboratory. pulmonary aspiration, and pneumonia.
Carcinogenicity
Mutagenicity
4-Cyclohexene-cis-1,2-dicarboxylic Acid
CAS No. 935-79-5 PS solid Color colorless Odor N/A FP N/A BP N/A MP 103 104 d N/A VP N/A VD Sol
N/A partially soluble
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed.
Inhalation
Sore throat and coughing.*
Skin
Irritation.*
Eyes
Redness, pain, and irritation.*
Safety goggles.
Ingestion
Irritation of the throat and abdominal spasms.*
Carcinogenicity
Mutagenicity
Not a known mutagen.*
*Toxicological information for the listed chemical is not available. Information given pertains to phthalic acid and is intended to be used for comparison of a similar compound. Other effects may result from contact, inhalation, or ingestion. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
1,3-Cyclopentadiene
CAS No. 542-92-7 PS liquid Color Odor FP 25 BP 40 MP N/A d 0.8021 VP 249 @ 12 VD 2.3 Sol insoluble
colorless petroleum odor
Acute Hazards/Symptoms SEVERE fire hazard., vapors or gases may ignite at distant ignition sources. Irritation, headache, dizziness, dullness, and central nervous system effects. Irritation, local redness
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam Remove from exposure; get medical attention Remove contaminated clothes and jewelry. Thoroughly wash skin with water. Seek medical attention if needed. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips. Get medical attention if needed. Not a known mutagen.
Inhalation
Skin
Eyes
Irritation, redness, pain
Safety goggles.
Ingestion
Abdominal pain, nausea
Carcinogenicity
Mutagenicity
Decanedioyl Dichloride
CAS No. 111-19-3 PS liquid Color colorless Odor FP BP MP N/A d 1.121 VP N/A VD N/A Sol decomposes
pungent >110 168 @ 12 torr odor
First Aid/Fire Carbon dioxide, regular dry chemical Remove from exposure immediately, keep warm and at rest get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, and continue to wash eyes with water. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Irritation, coughing, choking, pain, burns, pulmonary edema, and tightness in the chest.
Skin
Irritation, pain, burns
Eyes
Irritation, pain, burns
Safety goggles.
Ingestion
Pain, severe burns, discoloration of the tissues, and swallowing and speech may be difficult or impossible.
Carcinogenicity
Mutagenicity
Dibasic Potassium Phosphate

CAS No. 7758-11-4 PS crystals or powder Color white Odor odorless FP N/A BP N/A MP >465 d N/A VP VD Sol 150 g/100 mL
N/A N/A
Acute Hazards/Symptoms Not considered a fire hazard.
Prevention Avoid open flames and sparks. Ventilation, local exhaust., or breathing protection. Protective gloves and clothing.
First Aid/Fire Use any means suitable for extinguishing surrounding fire. Remove to fresh air. Get medical attention for any breathing difficulty. Wash exposed area with soap and water. Get medical advice if irritation develops. Wash thoroughly with running water. Get medical advice if irritation develops. If swallowed, give several glasses of water to drink to dilute. If large amounts were swallowed or symptoms occur, get medical advice. Not a known mutagen.
Inhalation
Not expected to be a health hazard.
Skin
No adverse effects expected.
Eyes
No adverse effects expected but dust Safety goggles. may cause mechanical irritation.
Ingestion
Symptoms may include vomiting, lethargy, diarrhea, blood chemistry effects, cardiac effects and central nervous system effects.
Carcinogenicity
Mutagenicity
o-Dichlorobenzene
CAS No. 95-50-1 PS viscous liquid Color Odor FP 66 BP 180 MP -17 d VP VD 5.1 Sol practically insoluble
pale odorless yellow
1.006 1.2 torr @ 20
Acute Hazards/Symptoms Combustible.
Inhalation
Cough. Drowsiness. Sore throat. Unconsciousness.
Ventilation, local Fresh air, rest. Refer for exhaust., or medical attention. breathing protection. Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention. First rinse with plenty of water for several minutes; remove contact lenses if easily possible. Seek medical attention. Rinse mouth. Refer for medical attention. Possible mutagen.
Skin
Redness. Burning sensation. Symptoms Protective gloves may be delayed. Blisters. and clothing.
Eyes
Redness. Pain.
Safety goggles.
Ingestion
Burning sensation. Diarrhea. Nausea. Vomiting. Not a known carcinogen.
Carcinogenicity
1,2-Dichlorobutane
CAS No. 616-21-7 PS liquid Color colorless Odor N/A FP 26 BP 125 MP N/A d 1.112 VP 28 VD N/A Sol insoluble
Prevention
First Aid/Fire Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Seek medical advice.
Flammable liquid. Emits toxic fumes No flames, no sparks, under fire conditions. Vapor may no contact with hot travel considerable distance to ignition surfaces. source and flash back. Avoid breathing vapor. Harmful if Ventilation, local inhaled. Symptoms of exposure may exhaust. include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Causes skin irritation. May be harmful if absorbed through skin. Protective gloves and clothing.
Inhalation
Skin
Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water lifting upper and lower lids occasionally. Seek medical advice. If swallowed wash out mouth with water.
Eyes
Causes eye irritation.
Safety goggles.
Ingestion
Harmful if swallowed. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.
Carcinogenicity
Mutagenicity
1,3-Dichlorobutane
CAS No. 1190-22-3 PS liquid Color colorless Odor N/A FP 30 BP 134 MP N/A d 1.115 VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms Flammable liquid. Emits toxic fumes under fire conditions. Vapor may travel considerable distance to ignition source and flash back. Avoid breathing vapor. Harmful if inhaled. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Harmful if absorbed through skin.
First Aid/Fire Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Seek medical advice. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water lifting upper and lower lids occasionally. Seek medical advice. If swallowed wash out mouth with water.
Inhalation
Skin
Eyes
Lachrymator. Causes eye irritation.
Ingestion
Carcinogenicity
Mutagenicity
1,4-Dichlorobutane
CAS No. 110-56-5 PS liquid Color colorless Odor NA FP 39 BP 161163 MP -38 d 1.160 VP NA VD NA Sol insoluble
Acute Hazards/Symptoms Flammable liquid. Emits toxic fumes under fire conditions. Vapor may travel considerable distance to ignition source and flash back. May be harmful if inhaled.
First Aid/Fire Water spray, Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Seek medical advice. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water lifting upper and lower lids occasionally. Seek medical advice. If swallowed wash out mouth with water. Not a known mutagen.
Inhalation
Skin
May be harmful if absorbed through skin. May cause eye irritation.
Eyes
Ingestion
Carcinogenicity
Dichloromethane
CAS No. 75-09-2 PS liquid Color colorless Odor sweet FP none BP 40 MP -97 d VP VD 2.9 Sol 1.32% @ 20
1.325 400 @ 24
Prevention Avoid heat, flames, sparks
First Aid/Fire Carbon dioxide, regular dry chemical, and water. Remove from exposure immediately; get medical attention.
Irritation, lightheadedness, dizziness, Ventilation, local tingling, numbness of the extremities, exhaust. sensation of heat, sensation of fullness in the head, drunkenness, mental confusion, nausea, headache, and fatigue. Irritation, possibly burns, skin absorption may occur causing effects detailed in inhalation. Pain, and extreme irritation. Protective gloves and clothing.
Skin
Eyes
Safety goggles.
Ingestion
Rapid, then slowed respiration, Do not eat or drink in gastrointestinal ulceration and the laboratory. hemorrhage, and unconsciousness, central nervous system depression, and liver and kidney damage. Known carcinogen. Mutagenicity
Carcinogenicity
Possible mutagen.
Dicyclopentadiene
CAS No. 77-73-6 PS solid Color colorless Odor pungent FP 32 BP 164 172 dec MP 32-35 d 0.979 @ 20 VP 1.4 @ 20 VD 4.6 Sol insoluble
Acute Hazards/Symptoms Severe fire hazard., vapors or gases may ignite at distant ignition sources.
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact a physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Irritation of mucous membranes and Ventilation, local upper respiratory tract, headache, exhaust. vomiting, nausea, dizziness, sneezing, coughing, and narcotic effects. Severe irritation and redness. Protective gloves and clothing.
Skin
Eyes
Irritation, smarting, redness, and pain. Safety goggles.
Ingestion
Abdominal pain, nausea, and focal hemorrhage of the kidney, intestine, stomach, bladder, and lung.
Carcinogenicity
Mutagenicity
Diethylamine
CAS No. 109-89-7 PS liquid Color Odor colorless fish-like FP -29 BP 55 MP -50 d 0.707 VP 731 VD 2.5 Sol soluble
Acute Hazards/Symptoms Flammable. Emits toxic fumes under fire conditions. Vapor may travel considerable distance to source of ignition and flashback. Container may explode under fire conditions. Toxic. Corrosive. Lachrymator. Toxic by inhalation. Inhalation may result in spasm, inflammation, and edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Harmful if in contact with skin. Causes burns.
First Aid/Fire Dry chemical, foam, or carbon dioxide.
Inhalation
Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician.
Skin
Eyes
Safety goggles.
Ingestion
Toxic if swallowed. Exposure to and/or Do not eat or drink in consumption of alcohol may increase the laboratory. toxic effects. Exposure can cause, burning sensation, wheezing, laryngitis, shortness of breath, headache, coughing, nausea, and vomiting. Not a known carcinogen. Mutagenicity
Carcinogenicity
Diethyl Benzylphosphonate
CAS No. 1080-32-6 PS liquid Color colorless Odor N/A FP 109 BP 106 108 MP N/A d 1.095 VP N/A VD N/A Sol insoluble
First Aid/Fire Carbon dioxide, regular chemical powder, foam, water Remove from exposure immediately, get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
May be harmful.
Skin
Eyes
Irritation.
Safety goggles.
Ingestion
May be harmful.
Carcinogenicity
Mutagenicity
Diethyl Ether
CAS No. 60-29-7 PS liquid Color colorless Odor sweet FP -40 BP 35 MP -116 d 0.7 VP 442 @ 20 VD 2.6 Sol 6.9%
Prevention
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately.
Severe fire hazard., severe explosion No flames, no sparks, hazard, may form explosive peroxides, no contact with hot vapors or gases may ignite at distant surfaces. ignition sources. Central nervous system depression with drowsiness, dizziness, nausea, headache, and lowering of the pulse and body temperature. Irritation, defatting, and drying of the skin. Ventilation, local exhaust.
Inhalation
Skin
Eyes
Painful inflammation.
Safety goggles.
Ingestion
Central nervous system depression Do not eat or drink in with nausea, vomiting, drowsiness, the laboratory. dizziness; stomach may become promptly distended, which may hinder breathing Not a known carcinogen. Mutagenicity
Carcinogenicity
Possible mutagen.
N,N-Diethyl-2,6-dimethylacetanilide
CAS No. 137-58-6 PS solid Color white Odor N/A FP 71.1 BP 180182 @4 MP 6669 d N/A VP N/A VD N/A Sol insoluble
Prevention
First Aid/Fire
Flammable, emits toxic fumes under Avoid heat, fire conditions. flames. Harmful if inhaled. Ventilation, exhaust. Harmful if absorbed through the skin.
Eyes
May be irritating to the eyes.
Ingestion
sparks, Dry chemical, foam, or carbon dioxide. local Remove to fresh air. If breathing is difficult, give oxygen. Protective gloves and Immediately flush skin clothing. with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Safety goggles. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. Do not eat or drink in If swallowed wash out the laboratory. mouth with water. Call a physician. Mutagenicity Not a known mutagen.
Carcinogenicity
Diethylene Glycol
CAS No. 111-46-6 PS viscous liquid Color colorless Odor odorless FP 124 BP 245 MP -6.5 d 1.12 VP 1@ 91.8 VD 3.66 Sol infinitely soluble
First Aid/Fire Powder, alcohol-resistant foam, water in large amounts, carbon dioxide. Remove from exposure immediately; fresh air, rest. Remove contaminated clothes. Rinse and then wash skin with water and soap. First rinse with plenty of water for several minutes; remove contact lenses if easily possible; seek medical attention. Rinse mouth. Give a slurry of activated charcoal in water to drink. Refer for medical attention. Possible mutagen.
Inhalation
Cough. Dizziness.
Skin
Redness.
Eyes
Redness.
Safety goggles.
Ingestion
Abdominal pain. Nausea. Vomiting. Dizziness. Drowsiness. Unconsciousness. Confusion.
Carcinogenicity
Mutagenicity
Dimethyl Fumarate
CAS No. 624-49-7 PS solid Color colorless to white Odor odorless FP N/A BP 192 193 MP 104107 d 1.37 VP N/A VD N/A Sol almost insoluble
First Aid/Fire Regular dry chemical, carbon dioxide, regular foam. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
Irritation, coughing, and dyspnea.
Skin
Irritation and redness.
Eyes
Irritation.
Safety goggles.
Ingestion
Relatively non-toxic; large amounts may cause sore throat, vomiting, and abdominal pain.
Carcinogenicity
Mutagenicity
Dimethyl Maleate
CAS No. 624-48-6 PS liquid Color colorless Odor N/A FP 91 BP 204 205 MP N/A d 1.152 VP 1@ 45.7 VD 4.97 Sol insoluble
First Aid/Fire Regular dry chemical, carbon dioxide, regular foam. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Irritation, coughing, and dyspnea.
Skin
Eyes
Irritation, redness, pain, and corneal erosion.
Safety goggles.
Ingestion
Sore throat, abdominal pain, and vomiting.
Carcinogenicity
Mutagenicity
Dimethyl Sulfoxide
CAS No. 67-68-5 PS liquid Color colorless Odor N/A FP 87 BP 189 MP 18.4 d VP 1.100 0.42 VD 2.7 Sol miscible
Acute Hazards/Symptoms Combustible liquid. Emits toxic fumes under fire conditions. Can react violently with several reagents. When heated above boiling point, formaldehyde, methyl mercaptan, and sulfur dioxide are evolved. May be harmful if inhaled.
First Aid/Fire Water spray, Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Seek medical advice. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water lifting upper and lower lids occasionally. Seek medical advice. If swallowed wash out mouth with water. Not a known mutagen.
Inhalation
Skin
Eyes
Readily absorbed through skin. Avoid Protective gloves and contact with DMSO solutions clothing. containing toxic material. DMSO may carry such materials into the body. Causes eye irritation. Safety goggles.
Ingestion
Carcinogenicity
2,6-Dimethylaniline
CAS No. 87-62-7 PS liquid Color Odor pale yellow N/A FP 91 BP 214@739 MP 1012 d VP 0.984 <0.01 VD N/A Sol N/A
Acute Hazards/Symptoms Combustible. Emits toxic fumes under fire conditions. Container may explode under fire conditions. Highly Toxic. Toxic by inhalation. Toxic if in contact with skin.
First Aid/Fire Water spray, Dry chemical, foam, or carbon dioxide. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advise. If swallowed wash out mouth with water provided person is conscious. Call a physician. Not a known mutagen.
Eyes
Safety goggles.
Ingestion
Toxic if swallowed.
Carcinogenicity
Possible cancinogen.
Mutagenicity
2-(2,4-Dimethylbenzoyl)benzoic Acid
CAS No. 577-56-0 PS powder Color white Odor odorless FP N/A BP N/A MP 116118 d N/A VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms Emits toxic fumes under fire conditions.* May be harmful if inhaled.* May irritate the skin.*
First Aid/Fire Water spray, dry chemical, foam, or carbon dioxide. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Eyes
May irritate the eyes.*
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
* Toxicological information for the listed chemical is not available. Information given pertains to 2-acetylbenzoic acid and is intended to be used for comparison of a similar compound. Other effects may result from contact, inhalation, or ingestion. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density (g/mL); Sol = solubility in water; N/A = not available or not applicable.
N,N-Dimethylformamide
CAS No. 68-12-2 PS liquid Color colorless Odor pungent, fishy FP 58 BP 153 MP -61 d 0.94 VP VD Sol miscible
2.7 torr 2.5 @ 20
Acute Hazards/Symptoms Flammable. Gives off irritating or toxic fumes (or gases) in a fire.
Prevention
First Aid/Fire
No flames, no sparks, Powder, alcohol-resistant no contact with hot foam, water spray, carbon surfaces. No contact dioxide. with oxidizing agents. Ventilation, local exhaust., or breathing protection. Protective gloves and clothing. Fresh air, rest. Artificial respiration if indicated. Refer for medical attention. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention. First rinse with plenty of water for several minutes; remove contact lenses if easily possible; seek medical attention. Rinse mouth. Refer for medical attention.
Inhalation
Abdominal pain. Diarrhea. Nausea. Vomiting. Nervous agitation. Facial flushing. Alcohol intolerance. MAY BE ABSORBED! Dry skin. Redness. Roughness.
Skin
Eyes
Redness. Pain.
Safety goggles.
Ingestion
Abdominal pain. Diarrhea. Nausea. Vomiting. Nervous agitation. Facial flushing. Alcohol intolerance. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Possible mutagen.
4,4-Dimethyl-2-cyclohexen-1-one
CAS No. 1073-13-8 PS liquid Color colorless Odor N/A FP 64 BP 72 73.5 MP N/A d 0.944 VP N/A VD N/A Sol poorly soluble
First Aid/Fire Carbon dioxide, regular chemical powder, foam, water Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Possiblemutagen.
Inhalation
May be harmful
Skin
Irritation, may be harmful if absorbed through skin
Eyes
Irritation
Safety goggles.
Ingestion
May be harmful
Carcinogenicity
Mutagenicity
2,6-Dimethylnitrobenzene
CAS No. 81-20-9 PS liquid Color Odor light yellow N/A FP 87 BP 225 MP 1416 d 1.112 VP N/A VD N/A Sol insoluble
Prevention
First Aid/Fire
Combustible liquid. Emits toxic fumes Avoid heat, sparks, under fire conditions. flames.
Inhalation Skin
Eyes
Ingestion
Water spray, carbon dioxide, dry chemical powder or appropriate foam. Highly toxic if inhaled. Ventilation, local Remove to fresh air. If exhaust. breathing is difficult, give oxygen. Toxic if absorbed through skin. Causes Protective gloves and Immediately flush skin skin irritation. clothing. with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Harmful to the eyes. Safety goggles. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. May be fatal if swallowed. Do not eat, drink, or If swallowed wash out smoke during work. mouth with water. Call a physician. Not a known carcinogen. Mutagenicity Not a known mutagen.
Carcinogenicity
1,3-Dinitrobenzene
CAS No. 99-65-0 PS powder Color orange Odor N/A FP N/A BP 297 MP 8890 d 1.368 VP N/A VD N/A Sol 0.808 g/L
Acute Hazards/Symptoms May be shock sensitive. Emits toxic fumes under fire conditions. Capable of creating a dust explosion. May explode when heated. Highly Toxic by inhalation, danger of cumulative effect, risk of irreversible effects.
First Aid/Fire Water spray, Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Seek medical advice. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water lifting upper and lower lids occasionally. Seek medical advice. If swallowed wash out mouth with water. Call a physician.
Inhalation
Skin
May be fatal if absorbed through skin. Protective gloves and Causes cyanosis, which may be clothing. delayed 24 hours. Causes eye irritation. Safety goggles.
Eyes
Ingestion
Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Possible mutagen.
3,5-Dinitrobenzoic Acid
CAS No. 99-34-3 PS solid Color white Odor N/A FP N/A BP N/A MP 205207 d N/A VP N/A VD N/A Sol 0.11.0%
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam Remove from exposure immediately, get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention. If vomiting occurs, keep head lower than hips, get medical attention, if needed. Not a known mutagen.
Inhalation
Irritation
Skin
Irritation
Eyes
Irritation
Safety goggles.
Ingestion
N/A
Carcinogenicity
Mutagenicity
3,5-Dinitrobenzoyl Chloride
CAS No. 99-33-2 PS solid Color yellow Odor pungent FP N/A BP 196 MP 6971 d 1.33 VP VD Sol decomposes
912 7.6 @ 196 8.0
First Aid/Fire Regular dry chemical, regular foam. Remove from exposure immediately, get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, get medical attention immediatly, continue washing with water. Contact physician immediately; give large amounts of water or milk, allow vomiting to occur; when vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Spasm, inflammation, and edema of the larynx and bronchi, chemical pneumonitis, and pulmonary edema. Corrosive
Skin
Eyes
Corrosive
Safety goggles.
Ingestion
Corrosive
Carcinogenicity
Mutagenicity
2,4-Dinitrophenylhydrazine
CAS No. 119-26-6 PS solid Color orange Odor N/A FP 209 BP N/A MP N/A d N/A VP N/A VD N/A Sol 0.1-1%
Acute Hazards/Symptoms Severe fire hazard., severe explosion hazard. Irritation, cyanosis, nausea, central nervous system effects with tremors, excitability, and convulsions. Irritation, skin absorption may occur. Sensitization dermatitis may occur in previously exposed persons. If sufficient amounts are absorbed, systemic toxicity may occur as detailed in acute inhalation. Irritation .
Prevention
First Aid/Fire
Avoid friction, shock, Flood with water, if no and heat water is available use dry chemical or earth. Ventilation, local exhaust. Protective gloves and clothing. Remove from exposure immediately, get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water.
Inhalation
Skin
Eyes
Safety goggles.
Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention. If vomiting occurs, keep head lower than hips, get medical attention, if needed. Possible mutagen.
Ingestion
Systemic toxicity may occur as detailed in acute inhalation.
Carcinogenicity
Mutagenicity
1,4-Dioxane
CAS No. 123-91-1 PS liquid Color colorless Odor sweet FP 12 BP 100102 MP 11.8 d 1.034 VP 40 VD 3 Sol soluble
Acute Hazards/Symptoms Flammable, may form explosive peroxides. Harmful to respiratory system
Prevention Avoid heat, sparks, flames. Ventilation, local exhaust. Protective gloves and clothing. Safety goggles.
First Aid/Fire Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water, lifting upper and lower lids occasionally. Seek medical advice. If swallowed, wash out mouth with water. Call a physician.
Skin
Irritant to skin.
Eyes
Irritant to eyes.
Ingestion
Harmful if swallowed. Symptoms Do not eat or drink in include nausea, vomiting, anorexia, the laboratory. weakness, dizziness, vertigo, headache and sweating. Probable carcinogen Mutagenicity
Carcinogenicity
Diphenyl Ether
CAS No. 101-84-8 PS solid Color Odor FP 115 BP 259 MP 2630 d 1.073 VP 0.0213 @ 20 VD 5.8 Sol 0.0021%
colorless unpleasant
First Aid/Fire Regular dry chemical, carbon dioxide. Water or foam may cause frothing. Remove from exposure immediately, get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
Irritation, nausea.
Skin
Irritation.
Eyes
Irritation.
Safety goggles.
Ingestion
Nausea, vomiting, sore throat, abdominal pain, and diarrhea .
Carcinogenicity
Mutagenicity
Diphenylacetylene
CAS No. 501-65-5 PS solid Color white Odor N/A FP BP MP 5961 d N/A VP N/A VD N/A Sol insoluble
N/A 170 @ 19
First Aid/Fire Carbon dioxide, regular chemical powder, foam, water. Remove from exposure immediately, get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
May be harmful.
Skin
Eyes
Irritation.
Safety goggles.
Ingestion
May be harmfu.l
Carcinogenicity
Mutagenicity
Disodium Hydrogen Phosphate

CAS No. 7558-79-4 PS granular solid Color colorless Odor odorless FP N/A BP N/A MP 48.1 d 1.7 VP N/A VD N/A Sol soluble
Acute Hazards/Symptoms Not considered to be a fire hazard. N/A
Prevention
First Aid/Fire Use any means suitable for extinguishing surrounding fire. Remove to fresh air. Get medical attention for any breathing difficulty. Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention if irritation develops. Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists. Give large amounts of water to drink. Get medical attention.
Inhalation
May cause irritation to the respiratory tract. Symptoms may include coughing and shortness of breath. May cause irritation with redness and pain.
Ventilation, local exhaust., or breathing protection. Protective gloves and clothing.
Skin
Eyes
May cause irritation, redness and pain. Safety goggles.
Ingestion
Symptoms may include vomiting, lethargy, diarrhea, blood chemistry effects, heart disturbances and central nervous system effects. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Dry Ice
CAS No. 124-38-9 PS solid Color white Odor none FP none BP -79 MP -78.5 d VP VD Sol 1.6%
1.56 569 @ 1.52 @ -79 -82
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire Remove from exposure immediately; get medical attention.
Inhalation
Acidic taste, headache, vertigo, nausea, Ventilation, local labored breathing, weakness, exhaust. drowsiness, mental confusion, increase in blood pressure, pulse, and respiratory rate, visual disturbances, profuse perspiration, general feeling of discomfort, and loss of consciousness. Frostbite with redness, tingling, pain, numbness, hard and white skin, and blisters. Protective gloves and clothing.
Skin
Remove contaminated clothes and jewelry, thoroughly wash skin with water, warm affected areas with warm water, and get medical help if needed. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, continue to wash eyes with water until medical help arrives. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Eyes
Stinging, frostbite, redness, pain, and blurred vision.
Safety goggles.
Ingestion
Frostbite.
Carcinogenicity
Mutagenicity
Ethanol
CAS No. 64-17-5 PS liquid Color colorless Odor alcoholic FP 13 BP 78 MP N/A d VP VD Sol soluble
0.7893 40 torr 1.59 @ 19
Acute Hazards/Symptoms Severe fire hazard., vapors or gases may ignite at distant ignition sources. Irritation, central nervous system depression with headache, stupor, fatigue, dizziness, drowsiness, dullness, lassitude, and loss of appetite may occur. Redness, burning, contact dermatitis, skin absorption may occur.
Inhalation
Skin
Eyes
Immediate burning, stinging, reflex closure of the lids, tearing, and temporary injury of the corneal epithelium.
Safety goggles.
Ingestion
Emotional lability, decreased Do not eat or drink in inhibitions, exhilaration, boastfulness, the laboratory. belligerency, visual impairment, muscular incoordination, sensory disturbances, dilated pupils, rapid pulse, nausea, vomiting, sweating, drowsiness, and stupor. Not a known carcinogen. Mutagenicity
Carcinogenicity
Possible mutagen.
Ethyl Acetate
CAS No. 141-78-6 PS liquid Color colorless Odor fruity FP -3 BP 76.5 77.5 MP -84 d 0.902 VP 73 @ 20 VD 3 Sol 8.7%
Inhalation
Irritation, headache, coughing, dizziness, drowsiness, shortness of breath, narcotic effects, and unconsciousness. Irritation, redness, and defatting action on the skin.
Skin
Eyes
Irritation, redness, pain, and lacrimation.
Safety goggles.
Ingestion
Sore throat, abdominal pain, diarrhea, central nervous system depression, dizziness, headache, fatigue, drowsiness, and unconsciousness.
Carcinogenicity
Mutagenicity
Ethyl 4-Aminobenzoate
CAS No. 94-09-7 PS solid Color white Odor odorless FP N/A BP N/A MP 88-90 d 1.11 VP VD N/A N/A Sol slightly soluble
Acute Hazards/Symptoms Noncombustible. Emits toxic fumes under fire conditions. May be harmful if inhaled. Irritating to the skin.
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advise. If swallowed wash out mouth with water provided person is conscious .Call a physician. Not a known mutagen.
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Ethylbenzene
CAS No. 100-41-4 PS liquid Color colorless Odor distinct FP 22 BP 136 MP N/A d VP VD 3.7 Sol 0.015%
0.8670 7.1 @ 20
Acute Hazards/Symptoms SEVERE fire hazard., vapors or gases may ignite at distant ignition sources.
First Aid/Fire Regular dry chemical, carbon dioxide, water for cooling, regular foam. Remove from exposure immediately; get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hip. Possible mutagen.
Inhalation
Severe irritation, cough, fatigue, depression, dizziness, and headache.
Skin
Irritation, inflammation, 1st or 2nd degree burns; absorption through skin may cause systemic toxicity.
Eyes
Irritation and lacrimation.
Safety goggles.
Ingestion
Abdominal pain, nausea, vomiting, aspiration with extensive edema and hemorrhage of lung tissue.
Carcinogenicity
Mutagenicity
Ferric Chloride
CAS No. 10025-77-1 PS solid Color yellow Odor unpleasant FP N/A BP 280 285 MP 37 d 1.82 VP 1 VD N/A Sol 91.9% @ 20
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately, get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, continue to wash eyes with water until medical help arrives. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Severe respiratory tract irritation, sore throat, cough, and labored breathing. Severe irritation, pain, and burns.
Skin
Eyes
Redness, pain, blurred vision, lacrimation, corneal injury and burns.
Safety goggles.
Ingestion
Abdominal pain, prolonged vomiting, Do not eat or drink in watery and then tarry diarrhea, intense the laboratory. dehydration, shock, cyanosis, rapid respiration, drowsiness, and dilated pupils. Not a known carcinogen. Mutagenicity
Carcinogenicity
Ferrous Ammonium Sulfate

CAS No. 10045-89-3 PS Color Odor odorless FP N/A BP N/A MP d VP N/A VD >1 Sol 26.9 g/100 mL
crystals pale bluegreen
110-112 1.86
Prevention No open flames or sparks. Ventilation, local exhaust. Protective gloves and clothing.
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove to fresh air. Get medical attention. Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention. Induce vomiting immediately as directed by medical personnel. Get medical attention.
Inhalation
Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath. Causes irritation to skin. Symptoms include redness, itching, and pain.
Skin
Eyes
Safety goggles..
Ingestion
Causes irritation to the gastrointestinal Do not eat or drink in tract. Symptoms may include nausea, the laboratory. vomiting and diarrhea. Low toxicity in small quantities but larger dosages may cause nausea, vomiting, diarrhea, and black stool. Pink urine discoloration is a strong indicator of iron poisoning. Not a known carcinogen. Mutagenicity
Carcinogenicity
Fluorene
CAS No. 86-73-7 PS solid Color colorless to white Odor N/A FP N/A BP 298 MP 114116 d 1.202 VP 10 @ 146 VD N/A Sol 0.2 ppm
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention. If vomiting occurs, keep head lower than hips, get medical attention, if needed. Not a known mutagen.
Inhalation
Irritation.
Skin
Irritation.
Eyes
Irritation.
Safety goggles.
Ingestion
Irritation.
Carcinogenicity
Mutagenicity
9-Fluorenone
CAS No. 486-25-9 PS solid Color yellow Odor N/A FP 163 BP 342 MP 8083 d 1.13 VP N/A VD N/A Sol insoluble
First Aid/Fire Carbon dioxide, regular chemical powder, foam, water. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
May be harmful.
Skin
Irritation, tumors, and may be harmful if absorbed through skin.
Eyes
Irritation.
Safety goggles.
Ingestion
May be harmful.
Carcinogenicity
Mutagenicity
Fluorescein
CAS No. 2321-07-5 PS powder Color orangebrown Odor N/A FP N/A BP N/A MP 320 d N/A VP N/A VD N/A Sol 0.05g/100g
Acute Hazards/Symptoms Emits toxic fumes under fire conditions May be harmful if inhaled.
First Aid/Fire Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Seek medical advice. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water lifting upper and lower lids occasionally. Seek medical advice. If swallowed wash out mouth with water. Not a known mutagen.
Skin
Eyes
Ingestion
Carcinogenicity
Formic Acid
CAS No. 64-18-6 PS liquid Color colorless Odor pungent FP 69 BP 100.8 MP 8.5 d 1.2 VP 23 @ 20 VD 1.6 Sol miscible
First Aid/Fire Regular dry chemical, carbon dioxide, regular foam, alcohol resistant foam. Remove from exposure immediately, keep warm and at rest, get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, and get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, and continue to wash eyes with water until medical help arrives. Contact a physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Possible mutagen.
Inhalation
Irritation, throat discomfort, lightheadedness, nausea, cough, rhinitis, nasal discharge, corrosion, dyspnea, bronchitis, pulmonary edema, shock, and death. Irritation, redness, pain, corrosion, subsequent dermatitis, second degree burns, blistering, vesiculation, keloid formation, and absorbed through the skin producing severe toxic effects.
Skin
Eyes
Irritation, lacrimation, acute Safety goggles. inflammation of the eyes, conjunctivitis, keratitis, pain, redness, blurred vision, burns, tissue damage, and permanent corneal scarring.
Ingestion
Burning sensation in the mouth, salivation, corrosion of the glottis, esophagus, and stomach, abdominal pain, nausea, diarrhea, and difficulty breathing. Not a known carcinogen.
Carcinogenicity
Mutagenicity
D-Fructose
CAS No. 57-48-7
PS solid
Color Odor colorless odorless
FP N/A
BP N/A
MP 119122
d 1.60
VP N/A
VD N/A
Sol soluble
Acute Hazards/Symptoms Emits toxic fumes under fire conditions. May be harmful if inhaled.
Inhalation
Skin
Eyes
Ingestion
Carcinogenicity
Mutagenicity
2-Furaldehyde
CAS No. 98-01-1 PS liquid Color light yellow Odor N/A FP 58 BP 162 MP -36 d 1.160 VP 1.7 VD 3.31 Sol 77.833 g/L
Acute Hazards/Symptoms Combustible liquid. Emits toxic fumes under fire conditions. Toxic by inhalation. Do not breathe vapor. May cause sensitization by inhalation. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache nausea and vomiting. May cause nervous system disturbances. Toxic in contact with skin. Causes burns and may cause sensitization with contact. May cause allergic reactions and photosensitivity. Irrritant and causes burns.
First Aid/Fire Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Seek medical attention.
Skin
Eyes
Safety goggles.
Ingestion
Toxic if swallowed. Symptoms may Do not eat or drink in include burning sensation, coughing, the laboratory. wheezing, laryngitis, shortness of breath, headache nausea and vomiting. May cause nervous system disturbances. Possible carcinogen Mutagenicity
Carcinogenicity
2-Furaldehyde Semicarbazone
CAS No. 2411-74-7 PS solid Color Odor off-white odorless FP N/A BP N/A MP 202 d N/A VP N/A VD Sol N/A poorly soluble First Aid/Fire Water spray, carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.*
Acute Hazards/Symptoms Flammable, emits toxic fumes under fire conditions.* May be harmful if inhaled.* May be irritating to the skin.*
Inhalation Skin
Eyes
Dust, vapor, or mist may be irritating to the eyes.*
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
* Toxicological information for the listed chemical is not available. Information given pertains to acetone semicarbazone and is intended to be used for comparison of a similar compound. Other effects may result from contact, inhalation, or ingestion. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density (g/mL); Sol = solubility in water; N/A = not available or not applicable.
D-Glucose
CAS No. 50-99-7
PS crystals or powder
Color colorless or white
Odor odorless
FP N/A
BP N/A
MP 83
d 1.56
VP
VD
Sol 1 g/1.1 mL
N/A N/A
Prevention No open flames or sparks. Ventilation, local exhaust., or breathing protection. Protective gloves and clothing. Safety goggles.
First Aid/Fire Use any means suitable for extinguishing surrounding fire. Not expected to require first aid measures. Not expected to require first aid measures. Wash thoroughly with running water. Get medical advice if irritation develops. Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice. Not a known mutagen.
Inhalation
No adverse health effects expected from inhalation. Not expected to be a health hazard from skin exposure. No adverse effects expected but dust may cause mechanical irritation.
Skin Eyes
Ingestion
Extremely large oral dosages may produce gastrointestinal disturbances.
Carcinogenicity
Mutagenicity
tris-[3-(Heptafluoropropylhydroxymethylene)-(+)-camphorato]europium
CAS No. 34788-82-4 PS solid Color yellow Odor N/A FP N/A BP N/A MP 156158 d N/A VP N/A VD N/A Sol N/A
Acute Hazards/Symptoms Flammable. Emits toxic fumes under fire conditions. May be harmful if inhaled. May irritate skin.
Inhalation Skin
Eyes
Vapor or mist may be harmful to the eyes.
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Heptane
CAS No. 142-82-5 PS liquid Color colorless Odor mild, gasolinelike FP -4 BP 91 MP -91 d 0.697 VP 40 torr @ 20 VD 3.5 Sol insoluble
Acute Hazards/Symptoms Severe fire hazard
Prevention
First Aid/Fire
No flames, no sparks, Powder, AFFF, foam, no contact with hot carbon dioxide. NO water. surfaces. Ventilation, local exhaust. Protective gloves and clothing. Fresh air, rest. Refer for medical attention. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention. Wear protective gloves and clothing. when administering first aid. First rinse with plenty of water for several minutes; remove contact lenses if easily possible; seek medical attention. Rinse mouth. Do not induce vomiting. Rest. Refer for medical attention. Possible mutagen.
Inhalation Skin
Dullness. Headache. Dry skin.
Eyes
Redness. Pain.
Safety goggles.
Ingestion
Abdominal cramps. Burning sensation. Nausea. Vomiting.
Carcinogenicity
Mutagenicity
Hexane
CAS No. 110-54-3, 107-83-5 PS liquid Color Odor colorless hydrocarbonlike FP -7 BP 69 MP -95 d 0.660 VP 125 VD 3 Sol slightly soluble
Acute Hazards/Symptoms Severe fire hazard; vapor may travel considerable distance to ignition source and flash back. Toxic by inhalation. Vapor is irritating to the upper respiratory track. Symptoms may include headache, dizziness, and nausea. May cause skin irritation.
First Aid/Fire
Skin
Eyes
May causes eye irritation.
Ingestion
Toxic by ingestion. Symptoms may include headache, dizziness and nausea. Not a known carcinogen.
Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Seek medical advice. Protective gloves Immediately flush skin and clothing. with soap and copious amounts of water for at least 15 minutes. Safety goggles. Immediately flush eyes with copious amounts of water, lifting upper and lower lids occasionally. Seek medical advice. Do not eat or drink If swallowed, wash out in the laboratory. mouth with water. Mutagenicity Not a known mutagen.
Carcinogenicity
1,6-Hexanediamine
CAS No. 6055-52-3 PS solid Color colorless Odor fishy FP BP MP 4142 d N/A VP VD Sol soluble
N/A 204205
N/A N/A
Prevention Avoid heat, flames, and sparks Ventilation, local exhaust. Protective gloves and clothing.
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam Remove from exposure immediately; get medical attention Remove contaminated clothes and jewelry; thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediatly. If vomiting occurs, keep head lower than hips; get medical attention if needed. Not a known mutagen.
Inhalation
Irritation
Skin
Irritation
Eyes
Irritation
Safety goggles.
Ingestion
Not available
Carcinogenicity
Mutagenicity
1-Hexene
CAS No. 592-41-6 PS liquid Color colorless Odor faint, pleasant FP -26 BP 63 MP -140 d 0.67 VP 310 torr @ 20 VD 3.0 Sol negligible
Prevention No flames, no sparks, no contact with hot surfaces. Ventilation, local exhaust. Protective gloves and clothing..
First Aid/Fire Powder, AFFF, foam, carbon dioxide. Fresh air, rest. Refer for medical attention. Remove contaminated clothes. Rinse and then wash skin with water or shower. Refer for medical attention. First rinse with plenty of water for several minutes; remove contact lenses if possible; seek medical attention. Rinse mouth. Do not induce vomiting. Refer for medical attention. Not a known mutagen.
Inhalation Skin
Cough. Dizziness. Drowsiness. Sore throat. Unconsciousness. Vomiting. Dry skin. Redness.
Eyes
Redness.
Safety goggles.
Ingestion
Cough. Dizziness. Drowsiness. Sore throat. Unconsciousness. Vomiting.
Carcinogenicity
Mutagenicity
Hydrobromic Acid, Concentrated

CAS No. 10035-10-6 PS liquid Color colorless to yellow Odor irritating FP N/A BP 74 @ 100 torr MP N/A d 1.5 VP N/A VD 2.8 Sol miscible
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately; get medical attention immediately.
Inhalation
Irritation, coughing, choking, burns of Ventilation, local the mucous membranes, headache, exhaust. nausea, pulmonary edema, tightness in the chest, dizziness, and weak, rapid pulse. Severe pain, burns, and brownish or yellowish stains Protective gloves and clothing.
Skin
Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention, and continue to wash eyes with water until medical help arrives. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Not a known mutagen.
Eyes
Pain, lacrimation, photophobia, burns, Safety goggles. and blindness
Ingestion
Immediate pain, difficulty or inability to swallow or speak, respiratory distress, thirst, nausea, vomiting, diarrhea, weak, rapid pulse, and shallow respiration. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Hydrochloric Acid Solutions (9-37%)

CAS No. 7647-01-0 (Hydrogen Chloride) PS liquid Color colorless or yellow Odor irritating FP N/A BP 65.5 110 MP N/A d 1.07 1.18 VP 30 @ 20 VD 1.3 Sol soluble
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately; keep warm and at rest, get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention, continue to wash eyes with water. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Possible mutagen.
Inhalation
Burning of the throat, coughing, choking, inflammation, ulceration of the nose, throat or larynx, bronchitis, pneumonia, palpitations, and headache. Severe irritation, inflammation, ulceration, necrosis, chemical burns, shock, rapid pulse, sweating, and collapse. Severe irritation, conjunctivitis, corneal necrosis, and burns with impairment or permanent loss of vision.
Skin
Eyes
Safety goggles.
Ingestion
Burns of the mouth, throat, esophagus Do not eat or drink in and stomach, pain, uneasiness, nausea, the laboratory. salivation, vomiting, diarrhea, chills, shock and intense thirst.
Carcinogenicity
Mutagenicity
Hydrogen Peroxide (30%)

CAS No. 7722-84-1 PS liquid Color colorless Odor pungent FP N/A BP 126 MP -40 d 1.11 VP 23.3 @ 20 VD 1 Sol 100%
Acute Hazards/Symptoms Negligible fire hazard.; may ignite or explode on contact with combustible materials. Irritation, sore throat, coughing, shortness of breath, systemic poisoning, headache, dizziness, vomiting, diarrhea, and numbness. Irritation, tingling and whitening of the skin, erythema or vesicle formation, severe burns, ulceration.
Prevention
First Aid/Fire
Avoid contact with Water combustible materials
Inhalation
Remove from exposure immediately; keep warm and at rest; get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, and get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, continue to wash eyes with water until medical help arrives. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Possible mutagen.
Skin
Eyes
Redness, stinging, tearing, blurred vision, severe corneal or conjunctival ulceration, blindness.
Safety goggles.
Ingestion
Irritation and injury to the mouth and Do not eat or drink in throat, distention of the esophagus and the laboratory. stomach, and stomach and chest pains.
Carcinogenicity
Mutagenicity
Hydroxylamine Hydrochloride
CAS No. 5470-11-1 PS crystals Color colorless Odor odorless FP N/A BP N/A MP 152 d 1.67 VP N/A VD N/A Sol 83 g/100 mL
Acute Hazards/Symptoms Not combustible. Gives off irritating or toxic fumes (or gases) in a fire. Blue lips or fingernails. Blue skin. Headache. Dizziness. Nausea. Confusion. Convulsions. Unconsciousness. Redness. Pain. N/A
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately; keep warm and at rest; get medical attention immediately. Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention. First rinse with plenty of water for several minutes; remove contact lenses if easily possible; seek medical attention. Rinse mouth. Give a slurry of activated charcoal in water to drink. Refer for medical attention. Possible mutagen.
Inhalation
Ventilation, local exhaust., or breathing protection.
Skin
Eyes
Redness. Pain.
Safety goggles.
Ingestion
Blue lips or finger nails. Blue skin. Headache. Dizziness. Nausea. Confusion. Convulsions. Unconsciousness. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Iodine
CAS No. 7553-56-2 PS solid Color purple to black Odor pungent FP N/A BP 184.4 MP 113.5 d 4.93 VP 0.305 @ 25 VD 8.8 Sol 0.03% @ 20
Acute Hazards/Symptoms Negligible fire hazard., may ignite or explode on contact with combustible materials. Severe irritation of the mucous membranes, severe cough, headache, and feeling of tightness in the chest. Brown discoloration of the skin with marked erythema, desquamation, and vesiculation with weeping and crusting. Burning sensation, irritation, and lacrimation.
Prevention
First Aid/Fire
Avoid contact with Use extinguishing agents combustible materials appropriate for surrounding fire. Ventilation, local exhaust. Remove from exposure immediately; keep warm and at rest; get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical help immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, continue to wash eyes with water until medical help arrives. Contact physician immediately. Give milk then starch solution; if vomiting occurs, keep head lower than hips.
Inhalation
Skin
Eyes
Safety goggles.
Ingestion
Inflammation and corrosion of the gastrointestinal tract, brown discoloration of the lips and mucous membranes, a burning sensation, nausea, severe vomiting, diarrhea, intense thirst, metallic taste, fever, delirium, and stupor. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Possible mutagen.
Iodine Monochloride
CAS No. 7790-99-0 PS solid Color red Odor pungent FP N/A BP N/A MP 27.2 d 3.240 VP N/A VD N/A Sol decomposes
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately; keep warm and at rest; get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, and get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Sore throat, coughing, labored breathing, fatigue, respiratory irritation, and pulmonary edema. Irritation and burns.
Skin
Eyes
Potent lacrimator, burning, and corneal Safety goggles. injury.
Ingestion
Sore throat, labored breathing, gastrointestinal irritation, abdominal pain, nausea, and vomiting.
Carcinogenicity
Mutagenicity
Isobutylbenzene
CAS No. 538-93-2 PS liquid Color colorless Odor mild aromatic FP 54 BP 173 MP -51 d 0.853 VP 4.22 VD N/A Sol insoluble
Acute Hazards/Symptoms Combustible and flammable.
Inhalation
May be harmful if inhaled.
Skin
Eyes
Ingestion
Carcinogenicity
Mutagenicity
(-)-Isopinocampheol
CAS No. 25465-65-0 PS solid Color white Odor N/A FP 93 BP 219 MP 5255 d N/A VP N/A VD N/A Sol N/A
Inhalation
Irritation.
Skin
Irritation.
Eyes
Irritation.
Safety goggles.
Ingestion
N/A
Carcinogenicity
Mutagenicity
Isopropylbenzene
CAS No. 98-82-8 PS liquid Color colorless Odor aromatic FP 31 BP 152.4 MP -962 d 0.862 VP 3.2 @ 20 VD 4.2 Sol insoluble
Types of Acute Hazards/Symptoms Hazard/Exposure Fire Highly flammable.
First Aid/Fire Powder, AFFF, foam, carbon dioxide. Fresh air, rest. Halfupright position. Refer for medical attention. Remove contaminated clothes. Rinse and then wash skin with water and soap. First rinse with plenty of water for several minutes; remove contact lenses if possible; seek medical attention. Rinse mouth. Do not induce vomiting. Refer for medical attention. Possible mutagen.
Inhalation
Ataxia. Cough. Dizziness. Drowsiness. Ventilation, local Headache. Sore throat. Unconsciousness. exhaust. Dry skin Protective gloves and clothing.
Skin
Eyes
Redness. Pain
Safety goggles.
Ingestion
Ataxia. Cough. Dizziness. Drowsiness. Do not eat or drink in Headache. Sore throat. Unconsciousness. the laboratory.
Carcinogenicity
Mutagenicity
Isopropylxylenes
CAS No. N/A PS liquid Color colorless Odor mild aromatic FP N/A BP 193216 MP N/A d 0.85 VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms Combustible liquid. May be harmful if inhaled. Irritating to respiratory system. Prolonged exposure can cause nausea, headache, and vomiting. Irritating to the skin. May cause drying, cracking and redness.
First Aid/Fire Dry chemical, foam, or carbon dioxide. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Skin
Eyes
Irritating to the eyes. May cause redness and stinging.
Safety goggles.
Ingestion
May be harmful if swallowed. May cause irritation to the gastrointestinal tract. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Lead Acetate
CAS No. 301-04-2 PS solid Color white Odor pungent FP N/A BP N/A MP 280 d 3.25 VP N/A VD N/A Sol 44.3%
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately, keep warm and at rest, get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. If vomiting occurs, keep head lower than hips. Get medical attention. Not a known mutagen.
Inhalation
Metallic taste, thirst, a burning sensation in the mouth and throat, excessive salivation, abdominal pain, vomiting, fatigue, sleep disturbances, dullness. Irritation.
Skin
Eyes
Irritation.
Safety goggles.
Ingestion
Symptoms as described in inhalation.
Carcinogenicity
Mutagenicity
Magnesium
CAS No. 7439-95-4 PS solid Color white Odor odorless FP N/A BP 1107 MP 649 d 1.7 @ 5 VP 1@ 621 VD N/A Sol reacts
First Aid/Fire Regular dry chemical, sand, lime, soda ash. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
Burning sensation, coughing, wheezing, laryngitis, headache. Severe local lesions if particles perforate the skin or gain access through cuts. Formation of hydrogen bubbles.
Skin
Eyes
Safety goggles.
Ingestion
Gastrointestinal irritation, nausea, vomiting, chills, fever, muscle and joint pain, anorexia, abdominal pain, and diarrhea. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Maleic Anhydride
CAS No. 108-31-6 PS solid Color colorless Odor irritating FP 103 BP 200 MP 5456 d VP VD 3.4 Sol reacts
1.314 1 @ 44 @ 60
Acute Hazards/Symptoms Slight fire hazard. Irritation; fumes cause: burning sensation in the throat, coughing, and vomiting. Irritation, inflammation, blistering, burns, and possibly absorbed through skin.
First Aid/Fire Alcohol resistant foam, carbon dioxide. Remove from exposure immediately; keep warm and at rest, get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, and get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, and continue to wash eyes with water until medical help arrives. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Possible mutagen.
Skin
Eyes
Irritation, severe burns; fumes cause conjunctivitis, corneal damage or edema, photophobia, double vision, and lacrimation.
Safety goggles.
Ingestion
Corrosion, sore throat, abdominal pain, nausea, and vomiting.
Carcinogenicity
Mutagenicity
Mercuric Oxide
CAS No. 21908-53-2 PS powder Color orangered or orangeyellow Odor odorless FP N/A BP N/A MP 500 d 11.14 VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms Substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition. Upon heating it decomposes to form oxygen, which increases the flammability of combustibles.
First Aid/Fire Use any means suitable for extinguishing surrounding fire.
Inhalation
Causes irritation to the respiratory Ventilation, local tract. Symptoms include sore throat, exhaust. coughing, pain, tightness in chest, breathing difficulties, shortness of breath and headache. Pneumonitis may develop. Can be absorbed through inhalation with symptoms to parallel ingestion. Causes irritation. Symptoms include redness and pain. May cause burns. May cause sensitization. Can be absorbed through the skin with symptoms to parallel ingestion. Protective gloves and clothing.
Remove to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately.
Skin
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. Induce vomiting immediately as directed by medical personnel. Get medical attention immediately.
Eyes
Causes irritation and burns to eyes. Symptoms include redness, pain, blurred vision; may cause serious and permanent eye damage.
Safety goggles.
Ingestion
Highly toxic! Average lethal dose for Do not eat or drink in inorganic mercury salts is about 1 the laboratory. gram. May cause burning of the mouth and pharynx, abdominal pain, vomiting, corrosive ulceration, bloody diarrhea. Not a known carcinogen. Mutagenicity
Carcinogenicity
Possible mutagen.
Methanol
CAS No. 67-56-1 PS liquid Color colorless Odor alcohollike FP 11 BP 64.6 64.7 MP -98 d 0.7914 VP 97.25 @ 20 VD 1.11 Sol soluble
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs keep head lower than hips, get medical attention, if needed. Possible mutagen.
Inhalation
Irritation, coughing, unsteady gait, Ventilation, local twitching, constipation, numbness and exhaust. shooting pains in the hands and forearms. Irritation, skin absorption may lead to Protective gloves and metabolic acidosis and effects on the clothing. eyes and central nervous system given in acute ingestion. Irritation, violent inflammation of the conjunctiva, and epithelial defects on the cornea. Safety goggles.
Skin
Eyes
Ingestion
Inebriation, drowsiness, coughing, Do not eat or drink in headache, dullness, weakness, vertigo, the laboratory. dizziness, nausea, vomiting, occasional diarrhea, and blindness. Not a known carcinogen. Mutagenicity
Carcinogenicity
Methyl Acetoacetate
CAS No. 105-45-3 PS liquid Color colorless Odor sweet FP 69 BP 169170 MP -80 d 1.076 VP N/A VD 4 Sol soluble
Acute Hazards/Symptoms Combustible liquid. Irritating to respiratory system.
First Aid/Fire
Skin
Eyes
Can cause blindness.
Ingestion
Carbon dioxide, dry chemical powder or appropriate foam. Ventilation, local Remove to fresh air. If exhaust. breathing is difficult, give oxygen. Seek medical advice. Protective gloves and Immediately flush skin clothing. with soap and copious amounts of water for at least 15 minutes. Safety goggles. Immediately flush eyes with copious amounts of water, lifting upper and lower lids occasionally. Seek medical advice. Do not eat or drink in If swallowed, wash out the laboratory. mouth with water. Call a physician. Mutagenicity Not a known mutagen.
Carcinogenicity
Methyl Benzoate
CAS No. 93-58-3 PS liquid Color colorless Odor fruity FP 82 BP 198 199 MP -12 d VP VD Sol 0.016%
1.094 1 @ 39 4.68
Acute Hazards/Symptoms Moderate fire hazard., vapors or gases may ignite at distant ignition sources. Irritation, sore throat, and coughing.
Inhalation
Skin
Irritation.
Eyes
Redness, pain, and irritation.
Safety goggles.
Ingestion
Abdominal pain, vomiting, diarrhea, and depression.
Carcinogenicity
Mutagenicity
Methyl Iodide
CAS No. 74-88-4 PS liquid Color colorless Odor acrid FP N/A BP 42 MP -66.1 d 2.28 VP 400 @ 25 VD 4.9 Sol 14 g/100 mL
Types of Acute Hazards/Symptoms Hazard/Exposure Fire Not considered to be a fire hazard. Fire may produce poisonous or irritating gases. Inhalation Inhalation of vapors can irritate the respiratory tract. Overexposure may produce symptoms of vertigo, delirium and mental disturbances. Other symptoms may include slurred speech, drowsiness, coughing, nausea and vomiting. Skin
First Aid/Fire Dry chemical, foam, carbon dioxide, or water spray. Remove to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately.
Causes irritation, rash and blister Protective gloves and formation. Prolonged contact can cause clothing. skin burns. Can be absorbed through skin with toxic effects.
Eyes
Vapors can cause irritation. Splashes may cause severe irritation with eye damage.
Safety goggles.
Ingestion
Ingestion may damage the gastrointestinal tract. Severe intoxication can occur with symptoms of central nervous system depression.
Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, immediately. Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. Induce vomiting immediately as directed by medical personnel. Get medical attention immediately. Possible mutagen.
Mutagenicity
For more detailed information consult the Material Safety Data Sheet for this compound. CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
Methyl Isobutyrate
CAS No. 547-63-7 PS liquid Color colorless Odor fruity FP 3 BP 90 MP N/A d 0.891 VP N/A VD N/A Sol slightly soluble
Acute Hazards/Symptoms Flammable liquid. May be harmful by inhalation.
First Aid/Fire
Skin
Eyes
Ingestion
Carbon dioxide, dry chemical powder or appropriate foam. Ventilation, local Remove to fresh air. If exhaust. breathing is difficult, give oxygen. Seek medical advice. Protective gloves and Immediately flush skin clothing. with soap and copious amounts of water for at least 15 minutes. Safety goggles. Immediately flush eyes with copious amounts of water, lifting upper and lower lids occasionally. Seek medical advice. Do not eat or drink in If swallowed, wash out the laboratory. mouth with water. Call a physician. Mutagenicity Not a known mutagen.
Carcinogenicity
3-Methylbenzoic Acid
CAS No. 99-94-5 PS solid Color white Odor odorless FP N/A BP 274275 MP 180182 d 1.27 VP N/A VD N/A Sol 0.33 g/L
Acute Hazards/Symptoms Flammable. Emits toxic fumes under fire conditions. Harmful if inhaled. Irritating to respiratory system. Irritant.
Inhalation Skin
Eyes
Vapor or mist may be irritating to the eyes.
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
(+/-)- -Methylbenzylamine
CAS No. 618-36-0 PS liquid Color colorless Odor N/A FP 79 BP 185 @ 756 torr MP -65 d 0.940 VP N/A VD N/A Sol poorly soluble
Acute Hazards/Symptoms Emits toxic fumes under fire conditions. Extremely destructive to tissue of the mucous membranes and upper respiratory tract. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache nausea and vomiting. Harmful if absorbed through skin. Extremely destructive to tissue of skin. Causes burns. Harmful to the eyes.
First Aid/Fire Water spray, carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen.
Inhalation
Skin
Eyes
Safety goggles.
Ingestion
Harmful if swallowed. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache nausea and vomiting. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Methylcyclohexane
CAS No. 108-87-2 PS liquid Color colorless Odor sweet FP -3 BP 101 MP -126 -126.3 d 0.77 VP 37 @ 20 VD 3.4 Sol insoluble
Prevention
First Aid/Fire Regular dry chemical, carbon dioxide, water for cooling, regular foam. Remove from exposure immediately, keep warm and at rest, get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Not a known mutagen.
Severe fire hazard., moderate explosion No flames, no sparks, no contact with hot hazard, vapors or gases may ignite at surfaces. distant ignition sources. Irritation, light-headedness, drowsiness, Ventilation, local lacrimation, salivation, labored exhaust. breathing, diarrhea, and liver and kidney damage. Irritation, hardening, ulceration, and defatting. Protective gloves and clothing.
Inhalation
Skin
Eyes
Conjunctival congestion.
Safety goggles.
Ingestion
Irritation, lethargy, severe diarrhea, liver and kidney damage, and circulatory collapse.
Carcinogenicity
Mutagenicity
2-Methylpropanal
CAS No. 78-84-2 PS liquid Color colorless Odor pungent FP -25 BP 6364 MP -65 d 0.7938 VP 66 @ 25 VD 2.5 Sol slightly soluble
Acute Hazards/Symptoms Severe fire hazard., vapors or gases may ignite at distant ignition sources. Irritation, central nervous system depression, and symptoms similar to alcohol intoxication. Irritation, burns, lethal amounts may be absorbed through skin.
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water Remove from exposure immediately, get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. If vomiting occurs, keep head lower than hips; get medical attention immediately. Not a known mutagen.
Inhalation
Skin
Eyes
Lacrimation, irritation, burns.
Safety goggles.
Ingestion
Central nervous system depression and Do not eat or drink in symptoms similar to alcohol the laboratory. intoxication.
Carcinogenicity
Mutagenicity
Methyltrioctylammonium Chloride
CAS No. 5137-55-3 PS viscous liquid Color colorless to pale orange Odor N/A FP 109 BP N/A MP N/A d 0.884 VP N/A VD N/A Sol partially soluble
Acute Hazards/Symptoms Emits toxic fumes under fire conditions. Harmful by inhalation. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Harmful if absorbed through skin.
Prevention Avoid heat, sparks, flames. Ventilation, local exhaust
First Aid/Fire Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Seek medical advice. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water lifting upper and lower lids occasionally. Seek medical advice. If swallowed, wash out mouth with water. Call a physician.
Skin
Eyes
Ingestion
Carcinogenicity
Mutagenicity
2-Methyl-2-butanol
CAS No. 75-85-4 PS liquid Color colorless Odor distinct FP 21 BP 102 MP -12 d 0.805 VP 10 @ 17.2 VD 3.0 Sol slightly soluble
Acute Hazards/Symptoms SEVERE fire hazard. Vapors or gases may ignite at distant ignition sources.
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water for cooling Remove from exposure immediately, keep warm and at rest, artificial respiration if needed; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water.
Inhalation
Headache, dizziness, nausea, vomiting, Ventilation, local diarrhea, coughing, shortness of breath, exhaust. excitement and delirium.
Skin
Irritation. May be absorbed through the Protective gloves and skin, causing headache, dizziness, clothing. nausea, vomiting, flushing, rapid pulse and respiration, drop in blood pressure, and unconsciousness. Conjunctivitis, double vision and irritation. May be absorbed, causing headache, dizziness, cough, shortness of breath, vomiting, excitement and delirium. Nausea, vomiting, diarrhea, headache, shortness of breath, cough, dizziness, excitement and delirium followed by coma. Safety goggles.
Eyes
Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention. Contact physician immediately. If vomiting occurs, keep head lower than hips; get medical attention immediately. Not a known mutagen.
Ingestion
Carcinogenicity
Mutagenicity
2-Methyl-1-butene
CAS No. 563-46-2 PS liquid Color Odor FP BP 31-32 MP N/A d 0.6504 VP N/A VD 2.4 Sol insoluble
colorless unpleasant <-7
Acute Hazards/Symptoms SEVERE fire hazard. Vapors or gases may ignite at distant ignition sources.
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water for cooling Remove from exposure immediately, keep warm and at rest, artificial respiration if needed; get medical attention immediatly. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. If vomiting occurs, keep head lower than hips; Not a known mutagen.
Inhalation
Irritation, central nervous system depression, asphyxia
Skin
Irritation
Eyes
Irritation
Safety goggles.
Ingestion
Irritation to the gastrointestinal tract; aspiration into the lungs may cause death due to chemical pneumonitis.
Carcinogenicity
Mutagenicity
2-Methyl-2-butene
CAS No. 513-35-9 PS liquid Color Odor FP BP 3738 MP -134 d 0.663 VP N/A VD 2.4 Sol slightly soluble
colorless unpleasant -20
Acute Hazards/Symptoms SEVERE fire hazard. Vapors or gases may ignite at distant ignition sources
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water for cooling. Remove from exposure immediately, keep warm and at rest; get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
Irritation, central nervous system Ventilation, local depression with dizziness, exhaust. disorientation, headache, vomiting and nausea; respiratory and cardiac depression, burning sensation. Erythema Protective gloves and clothing.
Skin
Eyes
Irritation
Safety goggles.
Ingestion
Diarrhea and central nervous system depression with labored breathing and respiratory failure. Aspiration may result in chemical pneumonitis. Not a known carcinogen.
Carcinogenicity
Mutagenicity
2-Methyl-3-butyn-2-ol
CAS No. 115-19-5 PS liquid Color colorless Odor N/A FP 25 BP 104 MP 2.6 d 0.868 VP N/A VD N/A Sol miscible
Acute Hazards/Symptoms Flammable liquid and vapor.
Prevention No flames, no sparks, no contact with hot surfaces. Ventilation, local exhaust. Protective gloves and clothing. Safety goggles.
First Aid/Fire Carbon dioxide or dry chemical powder. Do not use water. Remove to fresh air. Flush with water. Use soap if no burns have occured. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Requires antidote. Contact a physician. Possible mutagen.
Inhalation Skin
Causes irritation to respiratory tract and mucous membranes. Can irritate skin.
Eyes
Can irritate eyes.
Ingestion
Causes irritation to mucous membranes. Not a known carcinogen.
Carcinogenicity
2-Methyl-3-heptanol
CAS No. 14979-39-6 PS liquid Color colorless Odor N/A FP 54 BP 9899 @ 75 torr MP N/A d VP 0.827 N/A VD N/A Sol slightly soluble
Acute Hazards/Symptoms Combustible. Flammable.*
First Aid/Fire
Inhalation
Skin
Eyes
Ingestion
Carbon dioxide, dry chemical powder or appropriate foam. May be harmful if inhaled. Irritating to Ventilation, local Remove to fresh air. If respiratory system.* exhaust. breathing is difficult, give oxygen. Irritating to the skin.* Protective gloves and Immediately flush skin clothing. with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Irritating to the eyes.* Safety goggles. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. May be harmful if swallowed.* Do not eat or drink in If swallowed, wash out the laboratory. mouth with water. Call a physician. Not a known carcinogen. Mutagenicity Not a known mutagen.
Carcinogenicity
* Toxicological information for the listed chemical is not available. Information given pertains to 4methyl-3-heptanol and is intended to be used for comparison of a similar compound. Other effects may result from contact, inhalation, or ingestion. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density (g/mL); Sol = solubility in water; N/A = not available or not applicable.
4-Methyl-2-pentanol
CAS No. 108-11-2 PS liquid Color colorless Odor sweet FP 41 BP 132 MP -90 d 0.802 VP 2.8 @ 20 VD 3.53 Sol 1.7% @ 20
Acute Hazards/Symptoms Moderate fire hazard.; vapors or gases may ignite at distant ignition sources.
First Aid/Fire Regular dry chemical, carbon dioxide, regular foam, alcohol resistant foam Remove from exposure immediately; get immediate medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water.
Inhalation
Irritation, sore throat, coughing, Ventilation, local headache, shortness of breath, and exhaust. central nervous system depression with weakness, nausea, vomiting and fatigue. Irritation with redness and pain, absorbed through the skin and may cause central nervous system depression with weakness, dizziness, drowsiness, nausea, vomiting and fatigue. Redness, pain, and blurred vision. Protective gloves and clothing.
Skin
Eyes
Safety goggles.
Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips, get immediate medical attention. Not a known mutagen.
Ingestion
Abdominal pain, vomiting, diarrhea, Do not eat or drink in and central nervous system depression. the laboratory.
Carcinogenicity
Mutagenicity
2-Methyl-1-pentene
CAS No. 763-29-1 PS liquid Color colorless Odor N/A FP -9 BP 62 MP -136 d 0.682 VP 325 @ 37.7 VD N/A Sol insoluble
Types of Acute Hazards/Symptoms Hazard/Exposure Fire Severe fire hazard.
First Aid/Fire Carbon dioxide, regular chemical powder, foam, water for cooling. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
May be harmful.
Skin
Eyes
Irritation.
Safety goggles.
Ingestion
May be harmful.
Carcinogenicity
Mutagenicity
4-Methyl-1-pentene
CAS No. 691-37-2 PS liquid Color colorless Odor N/A FP -7 BP 5354 MP N/A d VP VD 2.9 Sol N/A
0.6642 424 @ 38
First Aid/Fire Regular dry chemical, carbon dioxide, water for cooling, regular foam Remove from exposure immediately; get medical attention.
Inhalation
Irritation and may cause central nervous system depression with vomiting, dyspnea, cyanosis, vertigo, incoordination, and loss of consciousness. Irritation
Skin
Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention. Get medical attention immediately. Not a known mutagen.
Eyes
Irritation
Safety goggles.
Ingestion
No specific data available; central Do not eat or drink in nervous system depression may occur. the laboratory. Not a known carcinogen. Mutagenicity
Carcinogenicity
4-Methyl-2-pentene
CAS No. 4461-48-7 PS liquid Color N/A Odor N/A FP <-7 BP 5659 MP N/A d 0.669 VP N/A VD 2.90 Sol insoluble
Prevention
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam. Remove from exposure immediately; get medical attention
Severe fire hazard., vapors or gases may No flames, no sparks, ignite at distant ignition sources. no contact with hot surfaces. Irritation, possible narcotic and may Ventilation, local cause central nervous system depression exhaust. with vomiting, dyspnea, cyanosis, vertigo, incoordination, loss of consciousness, and even death at high concentrations. Irritation. Protective gloves and clothing.
Inhalation
Skin
Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several minutes, remove contact lenses if possible, and seek medical attention immediately. Get medical attention immediately Not a known mutagen.
Eyes
Irritation.
Safety goggles.
Ingestion
No specific data available; central nervous system depression may occur. Not a known carcinogen.
Carcinogenicity
2-Methyl-1-propanol
CAS No. 78-83-1 PS liquid Color clear Odor sweet and musty FP 28 BP 108 MP -108 d 0.803 VP 8.8 @ 20 VD 2.6 Sol 9.5 g/100 mL water
Acute Hazards/Symptoms Flammable liquid and vapor
First Aid/Fire Dry chemical, foam or carbon dioxide. Remove to fresh air. If breathing is difficult, give oxygen. Call a physician.
Inhalation
Causes irritation to respiratory tract. Effects from overexposure include headache, dizziness, muscle weakness, drowsiness, incoordination, confusion, and coma. Skin contact causes irritation, redness, and pain. May be absorbed through the skin; symptoms of absorption may be similar to those from ingestion.
Skin
Remove any contaminated clothing. Wash skin with soap or mild detergent and water for at least 15 minutes. Get medical attention if irritation develops or persists. Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. Induce vomiting immediately as directed by medical personnel. Possible mutagen.
Eyes
Vapors cause irritation, redness, and blurred vision. Splashes may cause severe irritation or eye damage.
Safety goggles.
Ingestion
Ingestion may cause nausea, vomiting, and diarrhea.
Carcinogenicity
Mutagenicity
2-Methyl-2-propanol
CAS No. 75-65-0 PS liquid Color colorless Odor N/A FP 11 BP 83 MP 2526 d 0.775 VP 44 VD 2.5 Sol N/A
Acute Hazards/Symptoms Flammable. Emits toxic fumes under fire conditions. May be irritating if inhaled. Irritating to the skin.
Inhalation Skin
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Naphthalene
CAS No. 91-20-3 PS N/A Color N/A Odor mothballlike FP N/A BP 218 MP 80.5 d 0.963 VP N/A VD 4.4 Sol N/A
Prevention
First Aid/Fire Regular dry chemical, sand, earth, regular foam, water Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention immediately.
Severe fire hazard.; explosion possible. No flames, no sparks, no contact with hot surfaces. Irritation, headache, nausea, vomiting, Ventilation, local abdominal cramps, diarrhea, edema, exhaust. perspiration, and confusion. Irritation and severe dermatitis. Protective gloves and clothing.
Inhalation
Skin
Eyes
Irritation, conjunctivitis, injury to the cornea, cataracts, and diminished visual acuity.
Safety goggles.
Ingestion
Abdominal cramps, nausea, vomiting, Do not eat or drink in diarrhea, headache, profuse the laboratory. perspiration, bladder irritation, hemolytic anemia, hemoglobinuria, convulsions, liver injury with jaundice and acute renal failure. Possible carcinogen. Mutagenicity
Carcinogenicity
2-Naphthalenesulfonic Acid
CAS No. 120-18-3 PS solid Color colorless Odor N/A FP N/A BP N/A MP d 124125 1.441 Prevention Avoid heat, sparks, flames. Ventilation, local exhaust. VP N/A VD N/A Sol slightly soluble
Acute Hazards/Symptoms Reacts violently with water. Emits toxic fumes under fire conditions. May accelerate combustion. Contact with other material may cause fire. Harmful if inhaled. . Inhalation may result in spasm, inflammation, and edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Harmful if absorbed through skin. Irritating to the skin. Causes burns. May cause allergic skin reaction.
First Aid/Fire Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen.
Inhalation
Skin
Eyes
Ingestion
Protective gloves and Immediately flush skin clothing. with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Harmful to the eyes. Extremely Safety goggles. Immediately flush eyes destructive to tissue in eyes. with copious amounts of water lifting upper and lower lids often. Seek medical advice. May be fatal if swallowed. . Exposure Do not eat, drink, or If swallowed wash out can cause, burning sensation, wheezing, smoke during work. mouth with water. Call a laryngitis, shortness of breath, physician. headache, coughing, nausea, and vomiting. Carcinogen Mutagenicity Not a known mutagen.
Carcinogenicity
1-Naphthol
CAS No. 90-15-3 PS crystalline powder Color white Odor phenolic FP N/A BP 278 280 MP 9596 d 1.10 VP 1 @ 94 VD 4.5 Sol very slightly soluble
Prevention No flames, no sparks, no contact with hot surfaces. Ventilation, local exhaust., or breathing protection.
First Aid/Fire Water spray, dry chemical, alcohol foam, or carbon dioxide. Remove to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. Induce vomiting immediately as directed by medical personnel. Get medical attention. Possible mutagen.
Inhalation
Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath. Inhalation may result in symptoms and problems similar to ingestion.
Skin
May cause severe irritation, redness, Protective gloves and and pain. May be absorbed through the clothing.. skin with symptoms paralleling ingestion and causing kidney damage. Local action may cause peeling of the skin which may be followed by persistent pigmentation. Causes irritation, redness, pain, and injury to the cornea and lens of the eyes. Safety goggles.
Eyes
Ingestion
Large doses may cause crampy abdominal pain, nausea, vomiting, sweating, intense thirst, cyanosis.
Carcinogenicity
Mutagenicity
2-Naphthol
CAS No. 135-19-3 PS solid Color white Odor distinct mothballlike FP 153 BP 285-286 MP 122-123 d 1.2 VP 3.6 @ 130 VD 4.97 Sol slightly soluble
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical. Remove from exposure immediately, keep warm and at rest, get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, and continue to wash eyes. Contact physician immediately. If vomiting occurs, keep head lower than hips; get medical attention. Not a known mutagen.
Inhalation
Sweating, intense thirst, nausea, vomiting, diarrhea, hyperactivity, stupor, hypotension, hyperapnea, and abdominal pain. Blanching, erythema, tissue destruction, may be absorbed to cause effect as given under inhalation.
Skin
Eyes
Safety goggles.
Ingestion
May cause effects as given under inhalation.
Carcinogenicity
Mutagenicity
1-Naphthyl Isocyanate
CAS No. 86-84-0 PS liquid Color colorless Odor faint FP 109 BP 267 @ 760 torr MP N/A d 1.177 VP N/A VD 5.8 Sol decomposes
First Aid/Fire Regular dry chemical, carbon dioxide, regular foam Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, and continue to wash eyes with water. If vomiting occurs keep head lower than hips, get medical attention, if needed. Not a known mutagen.
Inhalation
Irritation, coughing, chest pains, Ventilation, local difficulty breathing, allergic respiratory exhaust. reaction, and unconsciousness. Allergic skin reaction, irritation, pain, and possibly burns. Protective gloves and clothing.
Skin
Eyes
Irritation, pain, and burn .
Safety goggles.
Ingestion
Bile stasis and the cessation of bile flow.
Carcinogenicity
Mutagenicity
Nitric Acid, Concentrated

CAS No. 7697-37-2 PS liquid Color colorless to yellow Odor distinct FP N/A BP 100 MP N/A d 1.36 1.41 VP 45 @ 25 VD 1 Sol soluble
Acute Hazards/Symptoms Negligible fire hazard., may ignite or explode on contact with combustible materials.
Prevention
First Aid/Fire
Avoid contact with Regular dry chemical, combustible materials soda ash, water. Remove from exposure immediately, keep warm and at rest, get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical help immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention, and continue to wash eyes with water. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Severe respiratory irritation, coughing, Ventilation, local choking, yellowish burns of the exhaust. mucous membranes, headache, and nausea. Severe pain, burns, yellowish stains. Protective gloves and clothing.
Skin
Eyes
Pain, lacrimation, photophobia, burns, Safety goggles. blindness.
Ingestion
Corrosion of the mucous membranes of the mouth, throat and esophagus, immediate pain and difficulty or inability to swallow or speak, vomiting, and diarrhea. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Nitric Acid, Fuming

CAS No. Nitric Acid 7697-37-2 Nitrogen Dioxide 10102-44-0 PS liquid Color yellow to red Odor N/A FP N/A BP 100 MP N/A d 1.4 VP 62 torr @ 25 VD 1 Sol miscible
Acute Hazards/Symptoms Negligible fire hazard., may ignite or explode on contact with combustible materials. Nitric Acid: coughing, headache, dizziness, and weakness. Delayed symptoms: dryness of the throat and nose, and chest pain or tightness. Nitrogen Dioxide: usually no symptoms at time of exposure. Delayed symptoms: fatigue, uneasiness, restlessness, and cough. Nitric Acid: immediate severe and penetrating burns, staining the skin yellow or yellowish-brown. Nitrogen Dioxide: severe irritation, pain, yellow-brown discoloration, and burns.
Prevention
First Aid/Fire
Avoid contact with Regular dry chemical, combustible materials soda ash, water. Ventilation, local exhaust. Remove from exposure immediately; keep warm and at rest; get medical attention immediately.
Inhalation
Skin
Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min., remove contact lenses if possible, seek medical attention immediately, and continue to wash eyes with water. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Not a known mutagen.
Eyes
Nitric Acid: pain, photophobia, Safety goggles. tearing, edema, corneal ulceration, and severe burns. Nitrogen Dioxide: severe irritation with redness, pain, blurred vision, edema of the eyelids, corneal ulceration, and burns. Nitric Acid: immediate pain in the mouth, throat, and stomach, nausea, vomiting, and diarrhea. Nitrogen Dioxide: acid taste, nausea, and vomiting. Not a known carcinogen. Do not eat or drink in the laboratory.
Ingestion
Carcinogenicity
Mutagenicity
3-Nitroaniline
CAS No. 99-09-2 PS solid Color yellow Odor N/A FP N/A BP 304 MP 112114 d 1.43 VP N/A VD N/A Sol 0.089 g/L
Acute Hazards/Symptoms Emits toxic fumes under fire conditions. Harmful by inhalation. May cause cyanosis; onset may be delayed 2-4 hours.
First Aid/Fire Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Seek medical advice. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water lifting upper and lower lids occasionally. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Skin
May be fatal if absorbed through skin. Protective gloves and clothing. Causes eye irritation. Safety goggles.
Eyes
Ingestion
May cause cyanosis; onset may be delayed for 24 hours.
Carcinogenicity
Mutagenicity
4-Nitroaniline
CAS No. 100-01-6 PS solid Color pale yellow Odor N/A FP 164 BP 260 @ 100 torr MP 149151 d 1.424 VP N/A VD N/A Sol slightly soluble
Acute Hazards/Symptoms Emits toxic fumes under fire conditions. Exposure can cause, headache, unconsciousness, coughing, chest pains, difficulty breathing, nausea, cyanosis, ataxia, diarrhea, and vomiting. Toxic if in contact with skin.
First Aid/Fire Water spray, dry chemical, foam, or carbon dioxide. Remove to fresh air. If breathing is difficult, give oxygen.
Skin
Eyes
Safety goggles.
Ingestion
Toxic if swallowed. Exposure to and/or consumption of alcohol may increase toxic effects. Exposure can cause, headache, unconsciousness, coughing, chest pains, difficulty breathing, nausea, cyanosis, ataxia, diarrhea, and vomiting. Not a known carcinogen.
Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advise. If swallowed wash out mouth with water provided person is conscious .Call a physician.
Carcinogenicity
Mutagenicity
Nitrobenzene
CAS No. 98-95-3 PS oily liquid Color pale yellow Odor almond-like FP 88 BP 211 MP -5.7 d 1.2 VP 1@ 44.4 VD 4.3 Sol practically insoluble
Types of Acute Hazards/Symptoms Hazard/Exposure Fire Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Inhalation Blue lips or fingernails. Blue skin. Dizziness. Headache. Nausea. Unconsciousness. Weakness. MAY BE ABSORBED! Blue lips or fingernails. Blue skin.
First Aid/Fire Powder, alcohol-resistant foam, water spray, carbon dioxide. Fresh air, rest. Refer for medical attention. Remove contaminated clothes. Rinse and then wash skin with water or shower. Refer for medical attention. First rinse with plenty of water for several minutes; remove contact lenses if easily possible; seek medical attention. Rinse mouth. Induce vomiting. Rest. Refer for medical attention. Possible mutagen.
Skin
Eyes
Vapors cause eye irritation. Splashes cause severe irritation, possible corneal burns and eye damage.
Safety goggles.
Ingestion
May cause headache, shallow respiration, Do not eat or drink in dizziness, vomiting, weakness, and the laboratory. blood pressure falls. Possible carcinogen. Mutagenicity
Carcinogenicity
Norbornene
CAS No. 498-66-8 PS solid Color N/A Odor sharp FP -14 BP 96 MP 4446 d N/A VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms Severe fire hazard., vapors or gases may ignite at distant ignition sources. Irritation.
First Aid/Fire Regular dry chemical, sand, earth, regular foam, water Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
Skin
Irritation.
Eyes
Irritation.
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
exo-Norborneol
CAS No. 497-37-0 PS solid Color white Odor N/A FP N/A BP 176 177 MP 124-126 d N/A VP N/A VD N/A Sol slightly soluble
First Aid/Fire Carbon dioxide, regular chemical powder, foam, water. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
May be harmful.
Skin
Eyes
Irritation.
Safety goggles.
Ingestion
May be harmful.
Carcinogenicity
Mutagenicity
Nylon-6,10
CAS No. 9008-66-6 PS solid Color white Odor N/A FP N/A BP N/A MP N/A d 1.040 VP N/A VD N/A Sol insoluble
First Aid/Fire Water spray, carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Seek medical advice. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water lifting upper and lower lids occasionally. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Inhalation
May be harmful by inhalation. Do not Ventilation, local breathe vapor. exhaust.
Skin
Eyes
Ingestion
Carcinogenicity
Mutagenicity
Petroleum ether 30-60

CAS No. 68476-50-6 PS liquid Color Odor FP colorless hydrocarbon -46 BP 3040 MP N/A d N/A VP N/A VD N/A Sol insoluble
Acute Hazards/Symptoms Severe fire hazard; vapor may travel considerable distance to ignition source and flash back, container explosion may occur under fire conditions. May be harmful if inhaled. Vapor is irritating to the upper respiratory track.
First Aid/Fire Carbon dioxide, dry chemical powder or appropriate foam.
Inhalation
Skin
Eyes
May causes eye irritation.
Ingestion
May be harmful if swallowed. Symptoms of exposure may include CNS depression and diarrhea. Not a known carcinogen.
Remove to fresh air. If breathing is difficult, give oxygen. Seek medical advice. Protective gloves and Immediately flush skin clothing. with soap and copious amounts of water for at least 15 minutes. Safety goggles. Immediately flush eyes with copious amounts of water lifting upper and lower lids occasionally. Seek medical advice. Do not eat or drink in If swallowed, wash out the laboratory. mouth with water. Seek medical attention. Mutagenicity Not a known mutagen.
Carcinogenicity
Phenol
CAS No. 108-95-2 PS solid Color colorless or white Odor tar-like FP 79 BP 182 MP 4042 d VP VD Sol 6.7%
1.071 0.35 @ 3.24 25
Acute Hazards/Symptoms Moderate fire hazard., vapors or gases may ignite at distant ignition sources. Severe irritation of the mucous membranes, profuse sweating, headache, intense thirst, nausea, vomiting, abdominal pain, and diarrhea. Local anesthesia, skin necrosis, painless burns due to damage to nerve endings, readily absorbed through the skin causing symptoms given in inhalation.
First Aid/Fire Regular dry chemical, regular foam, alcohol resistant foam. Remove from exposure immediately; keep warm and at rest, get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, and continue to wash eyes with water. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips.
Inhalation
Skin
Eyes
Severe irritation, redness, pain, blurred Safety goggles. vision, severe blindness, and loss of the eye.
Ingestion
Burning of the mouth and throat, Do not eat or drink in abdominal pain, pale face, contracted the laboratory. or dilated pupils, circulatory collapse, tachypnea, paralysis, convulsions, coma, jaundice, necrosis of mouth and gastrointestinal tract. Not a known carcinogen. Mutagenicity
Carcinogenicity
Possible mutagen.
Phenolphthalein
CAS No. 77-09-8 PS solid Color colorless Odor N/A FP N/A BP N/A MP 261 d 1.3 VP N/A VD N/A Sol soluble
Inhalation
Skin
Eyes
Safety goggles.
Ingestion
Possible carcinogen
Mutagenicity
For more detailed information consult the Material Safety Data Sheet for this compound. CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density (g/mL); Sol = solubility in water; N/A = not available or not applicable.
Phenylhydrazine
CAS No. PS Color colorless Odor faint aromatic FP 88 BP 243.5 MP 19 d 1.1 VP 1@ 71.8 VD 3.7 Sol slightly soluble in hot water
100-63-0 liquid
Types of Acute Hazards/Symptoms Hazard/Exposure Fire Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Inhalation Skin Coughing. Labored breathing. Sore throat. Cyanosis. MAY BE ABSORBED! Dry skin. Redness. Pain.
First Aid/Fire Water spray, alcoholresistant foam, powder, carbon dioxide. Fresh air, rest. Refer for medical attention. Remove contaminated clothes. Rinse skin with plenty of water or shower. Seek medical attention. First rinse with plenty of water for several minutes; remove contact lenses if easily possible; seek medical attention. Rest. Refer for medical attention. Possible mutagen.
Eyes
Redness. Pain.
Safety goggles.
Ingestion
Abdominal pain. Diarrhea. Nausea. Vomiting. Weakness. Vertigo. Not a known carcinogen.
Carcinogenicity
Phenylhydrazine hydrochloride
CAS No. 59-88-1 PS solid Color white Odor N/A FP N/A BP N/A MP 250 d N/A VP N/A VD N/A Sol soluble
First Aid/Fire Water spray, carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water, lifting upper and lower lids often. Seek medical advice. If swallowed, wash out mouth with water. Call a physician. Not a known mutagen.
Inhalation
Skin
Eyes
Safety goggles.
Ingestion
Carcinogen
Mutagenicity
For more detailed information consult the Material Safety Data Sheet for this compound. CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density (g/mL); Sol = solubility in water; N/A = not available or not applicable.
Phenyl Isocyanate
CAS No. 103-71-9 PS liquid Color colorless Odor N/A FP 51 BP 6264 MP -30 d 1.093 VP 2.8 VD N/A Sol decomposes
Acute Hazards/Symptoms Flammable. Combustible. Emits toxic fumes under fire conditions. Very toxic if inhaled. May cause sensitization. Very toxic in contact with skin. May cause sensitization. Causes burns.
Prevention Avoid heat, sparks, flames. Ventilation, local exhaust Protective gloves and clothing.
First Aid/Fire Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Eyes
Lachrymator. Vapor or mist is irritating to the eyes.
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Phenylmagnesium Bromide
CAS No. 100-58-3 PS solid Color white Odor N/A FP -17 BP N/A MP N/A d 1.14 VP N/A VD N/A Sol decomposes
Acute Hazards/Symptoms Highly flammable. Emits toxic fumes under fire conditions. Ignites on contact with water. Harmful if inhaled. Very irritating to respiratory system. Caustic will burn skin.
First Aid/Fire Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Eyes
Vapor or mist burns eyes.
Safety goggles.
Ingestion
Carcinogenicity
Probable carcinogen
Mutagenicity
Phthalic Anhydride
CAS No. 85-44-9 PS solid Color white Odor N/A FP N/A BP 284 MP 131133 d VP 1.494 <0.01 VD 5.1 Sol decomposes
Acute Hazards/Symptoms Flammable. Emits toxic fumes under fire conditions. May be harmful if inhaled. Irritating to respiratory system. Irritating to the skin.
Inhalation Skin
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Picric Acid
CAS No. 88-89-1 PS Color Odor odorless FP 150 BP explodes above 300 MP 122 d 1.77 VP N/A VD N/A Sol moderate (110%)
crystalline yellow solid
Acute Hazards/Symptoms Flammable solid. Dangerous fire hazard. when exposed to heat or flame.
First Aid/Fire Fight fire from protected location or maximum possible distance. Do not use carbon dioxide or halogenated extinguishing agents. Remove to fresh air. If breathing is difficult, give oxygen. Get medical attention. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Keep contaminated clothing wet after removing. Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. If swallowed, do not induce vomiting. Give large quantities of water. Get medical attention. Possible mutagen.
Inhalation
Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath. Systemic poisoning can cause headache, dizziness, nausea, vomiting, abdominal pain and diarrhea. Causes irritation to skin. Symptoms include redness, itching, and pain. May cause allergic skin reactions. May be absorbed through the skin with possible systemic effects.
Skin
Eyes
Fume is irritating to the eyes. Splashes can cause eye injury.
Safety goggles.
Ingestion
Causes irritation to the gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea. Other symptoms may parallel those from inhalation. Not a known carcinogen.
Carcinogenicity
Mutagenicity
(+)- -Pinene
CAS No. 7785-70-8 PS liquid Color Odor FP 32 BP 154 156 MP N/A d 0.857 0.862 VP N/A VD N/A Sol insoluble
colorless petroleumlike
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water for cooling. Remove from exposure immediately; get medical attention.
Inhalation
Irritation, destruction to tissue, burning sensation, coughing, wheezing, shortness of breath, dizziness, headache, nausea, and vomiting. Irritation, dermal eruptions, and may be absorbed through skin and cause effects as detailed in inhalation. Irritation and burning sensation.
Skin
Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Eyes
Safety goggles.
Ingestion
Effects as detailed in inhalation.
Carcinogenicity
Mutagenicity
Polystyrene
CAS No. 9003-53-6 PS solid Color colorless to white Odor odorless FP 345 360 BP N/A MP 86-91 d 1.04 1.13 VP N/A VD N/A Sol insoluble
Inhalation
Irritation and coughing.
Skin
N/A
Eyes
Irritation.
Safety goggles.
Ingestion
Irritation.
Carcinogenicity
Mutagenicity
Potassium Bromide
CAS No. 7758-02-3 PS solid Color white Odor odorless FP N/A BP 1435 MP 734 d VP 2.750 <0.01 VD N/A Sol soluble
Acute Hazards/Symptoms Non-flammable. Emits toxic fumes under fire conditions. May be harmful if inhaled. Irritating to respiratory system. Irritating to the skin. NA
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Potassium tert-Butoxide
CAS No. 865-47-4 PS solid Color white Odor N/A FP N/A BP N/A MP 256 to 258 (dec) d 1.850 VP 1@ 220 VD N/A Sol N/A
Acute Hazards/Symptoms Flammable. Emits toxic fumes under fire conditions. Harmful if inhaled. Very irritating to respiratory system. Caustic, may burn skin.
Inhalation Skin
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Potassium Carbonate
CAS No. 584-08-7 PS solid Color colorless or white Odor odorless FP N/A BP decomposes MP 891 d 2.29 VP N/A VD N/A Sol 112% @ 20
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately; get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, continue to wash eyes with water. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Irritation, coughing, choking, pain, burns of the mucous membranes, and pulmonary edema.
Skin
Severe pain, burns, and brownish stains. Protective gloves and clothing.
Eyes
Pain, burns, edema, corneal opacification, permanent opacity, and blindness.
Safety goggles.
Ingestion
Immediate pain, corrosion of the mucous Do not eat or drink membranes, shortness of breath, in the laboratory. laryngitis, headache, nausea, vomiting, profuse salivation, and difficulty or inability to swallow or speak. Not a known carcinogen. Mutagenicity
Carcinogenicity
Potassium Chloride
CAS No. 7447-40-7 PS solid Color white Odor N/A FP N/A BP 1420 MP 770 d 1.984 VP N/A VD N/A Sol soluble
Acute Hazards/Symptoms Non-flammable. Emits toxic fumes under fire conditions. May be harmful if inhaled. Irritating to respiratory system. Irritating to the skin.
First Aid/Fire Water spray, carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water, lifting upper and lower lids often. Seek medical advice. If swallowed, wash out mouth with water. Call a physician. Not a known mutagen.
Inhalation Skin
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Potassium Ferricyanide
CAS No. 13746-66-2 PS solid Color orange Odor N/A FP N/A BP N/A MP N/A d 1.850 VP N/A VD N/A Sol soluble
Acute Hazards/Symptoms Non-flammable. Emits toxic fumes under fire conditions. Harmful if inhaled. Very irritating to respiratory system. Irritating to the skin. NA
Prevention
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Potassium Fluoride
CAS No. 7789-233 PS solid Color white Odor N/A FP N/A BP 1505 MP 860 d 2.480 VP N/A VD 2 Sol soluble
Acute Hazards/Symptoms Non-flammable. Emits toxic fumes under fire conditions. May be harmful if inhaled. Very irritating to respiratory system. Irritating to the skin. NA
Prevention
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Potassium Hydroxide
CAS No. 1310-58-3 PS solid Color off-white Odor odorless FP N/A BP 1316 MP 360 d 2.044 VP 1.0 @ 719 VD N/A Sol 52%
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately; get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, continue to wash eyes with water. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Irritation, coughing, choking, pain, burns of the mucous membranes, and tightness in the chest.
Skin
Severe pain, burns, and brownish stains. Protective gloves and clothing.
Eyes
Pain, burns, edema, destruction of epithelium, permanent opacity, and blindness.
Safety goggles.
Ingestion
Immediate pain, corrosion of the mucous Do not eat or drink membranes, profuse salivation, and in the laboratory. difficulty or inability to swallow or speak.
Carcinogenicity
Mutagenicity
Potassium Iodide
CAS No. 7681-11-0 PS solid Color colorless to white Odor odorless FP N/A BP 1330 MP 681 d 3.13 @ 15 VP 1@ 745 VD N/A Sol 127.5%
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately, get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. Give milk then starch solution; if vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Irritation, coughing, and chest discomfort.
Skin
Pimples, boils, hives, blisters, black and Protective gloves blue spots. and clothing.
Eyes
Irritation, redness, pain, corrosive.
Safety goggles.
Ingestion
Gastrointestinal upset, nausea, and vomiting.
Carcinogenicity
Mutagenicity
Potassium Permanganate
CAS No. 7722-64-7 PS solid Color N/A Odor N/A FP N/A BP N/A MP N/A d N/A VP N/A VD N/A Sol soluble
Acute Hazards/Symptoms Negligible fire hazard., may ignite or explode on contact with combustible materials. Irritation, labored breathing, choking, pain in the nose, mouth and throat, and burns of the mucous membranes. Burns, redness, and pain.
Prevention Avoid contact with combustible materials. Ventilation, local exhaust.
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately, keep warm and at rest; get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Possible mutagen.
Inhalation
Skin
Eyes
Burns, redness, pain, lacrimation, and blurred vision.
Safety goggles.
Ingestion
Inflammation, nausea, vomiting, and difficulty speaking or swallowing. Overexposure can cause anemia and kidney damage.
Carcinogenicity
Mutagenicity
1-Propanol
CAS No. 71-23-8 PS liquid Color clear Odor alcohol FP 23 BP 97 MP -127 d 0.804 VP 21 @ 25 VD 2.07 Sol infinitely soluble
Acute Hazards/Symptoms Severe fire hazard. Vapors or gases may ignite at distant ignition sources.
First Aid/Fire Water spray, dry chemical, alcohol foam, or carbon dioxide. Remove to fresh air. If breathing is difficult, give oxygen. Call a physician.
Inhalation
Vapors have a mild narcotic effect and Ventilation, local act as an upper respiratory tract irritant. exhaust. Symptoms may include irritation of the eyes, nose, and throat, drowsiness, headache, and uncoordination. Defatting agent. May cause skin Protective gloves and irritation. Skin absorption may occur clothing. with symptoms paralleling those from inhalation exposure.
Skin
In case of contact, immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician. Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. Give large amounts of water to drink. Get medical attention. Possible mutagen.
Eyes
Vapors are irritating to the eyes. Splashes may cause severe irritation, with stinging, tearing, redness and pain.
Safety goggles.
Ingestion
May cause nausea, vomiting, drowsiness, gastrointestinal pain, cramps and diarrhea. Not a known carcinogen.
Carcinogenicity
Mutagenicity
2-Propanol
CAS No. 67-63-0 PS liquid Color colorless Odor alcoholic FP 12 BP 82.4 MP -89.5 d 0.7855 VP 40 @ 24 VD 2.1 Sol soluble
Acute Hazards/Symptoms Severe fire hazard. Vapors or gases may ignite at distant ignition sources. Irritation, chest tightness, wheezing, and large amounts may cause symptoms similar to acute ingestion.
First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water Remove from exposure immediately, get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention. If vomiting occurs keep head lower than hips, get medical attention, if needed.
Inhalation
Skin
Irritation, contact dermatitis, and large Protective gloves and amounts may result in symptoms clothing. similar to acute ingestion. Irritation, transitory injury, conjunctivitis, iritis, and corneal opacity. Safety goggles.
Eyes
Ingestion
Abdominal pain, nausea, vomiting, and hemorrhage, hypoglycemia, tenderness and edema of muscles, and arrhythmias, vomiting with aspiration may cause aspiration pneumonia. Central nervous system depression may occur with headache and dizziness. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Propylene Glycol
CAS No. PS Color clear Odor odorless FP 23 BP 99 MP -59 d 1.0361 VP 0.129 @ 25 VD 2.6 Sol miscible
57-55-6 oily liquid
Acute Hazards/Symptoms Can support combustion.
First Aid/Fire Dry chemical, foam, water or carbon dioxide. Remove to fresh air. Not expected to require firstaid measures. Remove any contaminated clothing. Wash skin with soap and water for at least 15 minutes. Get medical attention if irritation develops or persists. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Call a physician if irritation persists. Not expected to require first aid measures. Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice. Possible mutagen.
Inhalation
No adverse health effects via inhalation. Mild irritant and defatting agent, especially on prolonged contact.
Skin
Eyes
May cause transitory stinging and tearing.
Safety goggles.
Ingestion
Relatively non-toxic. Ingestion of Do not eat or drink in sizable amount (over 100ml) may the laboratory. cause some gastrointestinal upset and temporary central nervous system depression. Effects appear more severe in individuals with kidney problems. Not a known carcinogen. Mutagenicity
Carcinogenicity
Pyridine
CAS No. 110-86-1 PS liquid Color colorless Odor N/A FP 20 BP 115 116 Types of Hazard/Exposure Fire Acute Hazards/Symptoms Severe fire hazard., vapors or gases may ignite at distant ignition sources. Prevention No flames, no sparks, no contact with hot surfaces. Ventilation, local exhaust. First Aid/Fire Alcohol resistant foam, carbon dioxide, regular dry chemical, water for cooling. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Possible mutagen. MP N/A d 0.978 VP 18 @ 20 VD 2.72 Sol soluble
Inhalation
Irritation, unpleasant taste in the mouth, narcosis, dizziness, drowsiness, and headache.
Skin
Redness, irritation, burns, Protective gloves and photosensitivity and sensitization clothing. reactions, and subdermal hemorrhages. Irritation and corneal damage. Safety goggles.
Eyes
Ingestion
Nausea, fatigue, mental depression, vomiting, and diarrhea.
Carcinogenicity
Mutagenicity
Resorcinol
CAS No. 108-46-3 PS solid Color white Odor N/A FP 170 BP 280 MP 110113 d VP 1.327 1 VD 3.8 Sol 220%
Inhalation Skin
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
p-Rosaniline Hydrochloride (Basic Fuchsin)

CAS No. 569-61-9 PS solid Color green Odor N/A FP N/A BP N/A MP 250 d 1.22 VP N/A VD N/A Sol 0.1-0.5 g/100 mL
Acute Hazards/Symptoms Flammable. Emits toxic fumes under fire conditions. Irritant, may be harmful if inhaled.
First Aid/Fire Water spray, carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advise. If swallowed wash out mouth with water. Call a physician. Possible mutagen
Inhalation
Skin
Irritant, may be harmful to the skin.
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Possible carcinogen
Mutagenicity
Salicylamide
CAS No. 65-45-2 PS solid Color white Odor N/A FP N/A BP 181.5 @ 14 torr MP 140144 d 1.351 VP N/A VD N/A Sol 2.511 g/L
Inhalation Skin
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Salicylic Acid
CAS No. 69-72-7 PS fine crystals Color white Odor odorless to slight phenolic FP 157 BP 211 MP 157 159 d 1.44 VP VD Sol 1 g/460 mL
1 torr @ 4.8 114
First Aid/Fire Carbon dioxide, water spray, powder. Fresh air, rest. Refer for medical attention. Remove contaminated clothes. Rinse and then wash skin with water and soap. First rinse with plenty of water for several minutes; remove contact lenses if easily possible; seek medical attention. Rinse mouth. Induce vomiting. Refer for medical attention. Possible mutagen.
Inhalation Skin
Cough. Sore throat. Redness.
Eyes
Redness, pain.
Safety goggles.
Ingestion
Nausea, vomiting, ear ringing.
Carcinogenicity
Mutagenicity
Semicarbazide Hydrochloride
CAS No. 563-41-7 PS solid Color white Odor N/A FP N/A BP N/A MP N/A d N/A VP N/A VD N/A Sol soluble
First Aid/Fire Carbon dioxide, regular dry chemical. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. Give large amounts of water or activated charcoal slurry; when vomiting occurs, keep head lower than hips. Possible mutagen.
Inhalation
Nausea, vomiting, fever, headache, hypotension, weakness, and fatigue. Irritation.
Skin
Eyes
Redness and irritation
Safety goggles.
Ingestion
Nausea, vomiting, sore throat, abdominal pain, and diarrhea.
Carcinogenicity
Mutagenicity
Silicon Dioxide
CAS No. 112926-00-8 PS solid Color white Odor odorless FP N/A BP N/A MP N/A d 2.6 VP N/A VD N/A Sol N/A
Acute Hazards/Symptoms Non-flammable. Emits toxic fumes under fire conditions. Harmful if inhaled. Irritating to respiratory system. Irritating to the skin. N/A
Prevention
Eyes
Dust is irritating to the eyes.
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Silver Nitrate
CAS No. 7761-88-8 PS liquid Color colorless Odor N/A FP N/A BP 440 MP 212 d 4.352 VP N/A VD N/A Sol soluble
Acute Hazards/Symptoms Negligible fire hazard., may ignite or explode on contact with combustible materials. Irritation, sore throat, coughing and shortness of breath, headache, nausea, vomiting.
Prevention
First Aid/Fire
Avoid contact with Use extinguishing agents combustible materials appropriate for surrounding fire. Ventilation, local exhaust. Remove from exposure immediately, keep warm and at rest, and get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical help immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, continue to wash eyes with water. Contact physician immediately. Give salt water; if vomiting occurs, keep head lower than hips. Possible mutagen.
Inhalation
Skin
Irritation, redness, pain, ulceration, and discoloration.
Eyes
Irritation, redness, pain, burns, discoloration, and blindness.
Safety goggles.
Ingestion
Burning mouth and throat, salivation, violent abdominal pain and rigidity, diarrhea, headache, nausea, vomiting, and cyanosis. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Sodium
CAS No. 7440-23-5 PS metal Color light, silvery white Odor odorless FP 115 BP 881.7 MP 97.8 d 0.968 VP 1.2 @ 400 VD Sol
0.003 decomposes violently in water First Aid/Fire
Prevention
Flammable solid, water reactive. Can Avoid open flames or react vigorously with water, steam, sparks. Keep from acids to release flammable/explosive water. hydrogen. Dangerous in presence of oxidants. May ignite spontaneously in moist air or oxygen. May re-ignite after fire is extinguished. Inhalation produces damaging effects on the mucous membranes and upper respiratory tract. Symptoms may include irritation of the nose and throat, and labored breathing. Ventilation, local exhaust.
Use dry soda ash, dry salt, sand, graphite powder or metal-fire-extinguishing dry powder such as Met-LX. Do not use water, foam, carbon dioxide, dry chemical, or chlorinated fire extinguishers. If inhaled, remove to fresh air. Get medical attention immediately.
Inhalation
Skin
Corrosive, can cause serious burns due Protective gloves and to almost immediate reaction with clothing. water, especially on moist skin. If metal ignites, very deep burns and tissue destruction can occur.
Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. If swallowed, do not induce vomiting. Give large quantities of water. Get medical attention immediately. Not a known mutagen.
Eyes
Corrosive. May cause redness, pain, blurred vision, and damage from severe alkali burns.
Safety goggles.
Ingestion
Extremely dangerous, corrosive Do not eat or drink in material. Will react immediately with the laboratory. saliva to cause serious burns and possible local combustion.
Carcinogenicity
Mutagenicity
Sodium Acetate
CAS No. 127-09-3 PS solid Color N/A Odor N/A FP N/A BP N/A MP 324 decomposes d 1.528 VP N/A VD N/A Sol soluble
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam Remove from exposure immediately, get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Possible mutagen.
Inhalation
Irritation, coughing, and shortness of Ventilation, local breath exhaust. Irritation Protective gloves and clothing.
Skin
Eyes
Irritation
Safety goggles.
Ingestion
Abdominal pain and vomiting
Carcinogenicity
Mutagenicity
Sodium Acetate, Trihydrate

CAS No. 6131-90-4 PS solid Color N/A Odor odorless FP N/A BP 123 MP 58 d 1.45 VP N/A VD N/A Sol 76.2% @ 0
Inhalation
Irritation, coughing, and shortness of breath. Irritation.
Skin
Eyes
Irritation.
Safety goggles.
Ingestion
Abdominal pain and vomiting.
Carcinogenicity
Mutagenicity
Sodium Bicarbonate
CAS No. 144-55-8 PS solid Color white Odor odorless FP N/A BP N/A MP 300 d 2.159 VP N/A VD N/A Sol 10%
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Possible mutagen.
Inhalation
Irritation, sore throat, and coughing.
Skin
Irritation.
Eyes
Safety goggles.
Ingestion
Irritation of the mouth, esophagus, and Do not eat or drink in stomach. Alkalosis. the laboratory.
Carcinogenicity
Mutagenicity
Sodium Bisulfite
CAS No. 7631-90-5 PS solid Color white Odor N/A FP N/A BP MP d VP N/A VD N/A Sol soluble
decomposes decomposes 1.32 Prevention N/A
Acute Hazards/Symptoms Negligible fire hazard.
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately; get medical attention.
Inhalation
Irritation, sore throat, coughing, and shortness of breath. Irritation, corrosion.
Skin
Protective gloves and Remove contaminated clothing. clothes and jewelry, thoroughly wash skin with water. Safety goggles. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips.
Eyes
Irritation, corrosion, and grayness and irregularity of the corneal epithelium.
Ingestion
Irritation of the stomach, abdominal Do not eat or drink in pain, and nausea. Those with the laboratory. preexisting respiratory conditions may experience hypersensitivity: symptoms include bronchospasm, gastrointestinal disturbances, hypotension, and shock. Not a known carcinogen. Mutagenicity
Carcinogenicity
Sodium Borohydride
CAS No. 16940-66-2 PS solid Color Odor FP BP N/A MP d VP N/A VD 1.3 Sol 55% @ 25
white, odorless 318 off-white
300400 1.07 decomposes 4 Prevention
First Aid/Fire
No flames, no sparks, Regular dry chemical, no contact with hot sand, lime, soda ash surfaces. Remove from exposure immediately; keep warm and at rest, get medical attention immediately.
Inhalation
Severe irritation, sore throat, coughing, Ventilation, local shortness of breath, and headache exhaust.
Skin
Chemical and thermal burns, fatal systemic poisoning due to skin absorption
Protective gloves and Remove contaminated clothing.. clothes and jewelry, thoroughly wash skin with water, and get medical attention immediately. Safety goggles. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, and continue to wash eyes with water.
Eyes
Severe irritation and chemical and thermal burns
Ingestion
Sore throat, abdominal pain, diarrhea, headache, dizziness, and corrosion of the gastric mucosa.
Do not eat or drink in Contact physician the laboratory. immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Mutagenicity Not a known mutagen.
Carcinogenicity
Sodium Bromide
CAS No. 7647-15-6 PS solid Color white Odor odorless FP N/A BP 1390 MP 755 d 3.210 VP 1@ 806 VD N/A Sol 116% @ 50
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately. Get medical attention. Remove contaminated clothing, jewelry, and shoes immediately. Thoroughly wash with water. Thoroughly wash eyes with water for several minutes, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips. Get medical attention. Possible mutagen.
Inhalation
Irritation, rashes (especially acne, furunculosis). Irritation, rashes (especially acne, furunculosis).
Skin
Eyes
N/A
Safety goggles.
Ingestion
Immediate abdominal pain, nausea, vomiting, kidney damage, systemic poisoning, paralysis, and coma. Not a known carcinogen.
Carcinogenicity
Mutagenicity
Sodium Carbonate
CAS No. 497-19-8 PS Color Odor FP N/A BP decomposes MP 851 d 2.536 VP N/A VD N/A Sol 7.1% @ 0
crystal- colorless odorless line to white powder, crystals
Prevention N/A
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, continue to wash eyes with water.
Inhalation
Irritation, coughing, and shortness of breath. Irritation and redness
Skin
Eyes
Severe irritation, redness, pain, and blurred vision
Safety goggles.
Ingestion
Corrosion of the gastric mucosa, sore throat, gastrointestinal disturbances, nausea, vomiting, abdominal pain, and diarrhea.
Do not eat or drink Contact physician in the laboratory. immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Mutagenicity Not a known mutagen.
Carcinogenicity
Sodium Chlorate
CAS No. 7775-09-9 PS solid Color white Odor N/A FP N/A BP decomposes MP 248261 d 2.49 VP N/A VD N/A Sol 79g/100mL @0
Acute Hazards/Symptoms Negligible fire hazard., may ignite or explode on contact with combustible materials. Irritation with sore throat, coughing, headache, dizziness, and faintness. Irritation.
Prevention
First Aid/Fire
Avoid contact Use extinguishing agents with combustible appropriate for materials surrounding fire. Ventilation, local Remove from exposure exhaust. immediately, get medical attention. Protective gloves Remove contaminated and clothing. clothes and jewelry, thoroughly wash skin with water. Safety goggles. Thoroughly wash eyes with water for several minutes, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. If vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Skin
Eyes
Irritation.
Ingestion
Irritation of the gastrointestinal mucosa, abdominal pain, nausea, vomiting, and diarrhea.
Carcinogenicity
Mutagenicity
Sodium Chloride
CAS No. 7647-14-5 PS crystalline powde Color colorless to white Odor FP BP 1413 MP 801 d 2.165 VP N/A VD N/A Sol 35.7% @ 0
odorless N/A
Prevention N/A
First Aid/Fire Use extinguishing agents appropriate for surrounding fire.
Inhalation
Coughing, dryness, and sore throat.
Ventilation, local Remove from exposure exhaust. immediately, get medical attention. Protective gloves Remove contaminated and clothing. clothes and jewelry, thoroughly wash skin with water. Safety goggles. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Skin
Irritation
Eyes
Redness, pain, irritation and a stinging sensation
Ingestion
Dryness of mucous membranes, a violent Do not eat or inflammatory reaction in the drink in the gastrointestinal tract, and ulceration if very laboratory. large doses are taken. Not a known carcinogen. Mutagenicity
Carcinogenicity
Sodium Citrate, Dihydrate

CAS No. 6132-04-3 PS solid Color white Odor N/A FP N/A BP N/A MP >300 d N/A VP N/A VD N/A Sol soluble
Acute Hazards/Symptoms Flammable. Emits toxic fumes under fire conditions. May be harmful if inhaled. Irritating to respiratory system. Irritating to the skin.
Inhalation Skin
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Sodium Dichromate, Dihydrate

CAS No. 7789-12-0 PS solid Color red to orange Odor N/A FP N/A BP N/A MP 91 d 2.350 VP N/A VD N/A Sol soluble
Acute Hazards/Symptoms Flammable. Emits toxic fumes under fire conditions. Vigorously supports combustion. Harmful if inhaled, toxic.
Inhalation Skin
Irritating to the skin, may cause burns. Protective gloves and May be toxic clothing.
Eyes
Irritating to the eyes. May be toxic
Safety goggles.
Ingestion
Carcinogenicity
Carcinogenic
Mutagenicity
Sodium Hydroxide
CAS No. 1310-73-2 PS solid Color white Odor odorless FP N/A BP 1390 MP 318 d 2.130 VP 100 @ 1111 VD >1 Sol soluble
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately, keep warm and at rest; get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention, continue to wash eyes with water. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips. Not a known mutagen.
Inhalation
Irritation, sore throat, burning sensation, laryngitis, coughing, destruction of mucous membranes, headache, nausea, vomiting, and delayed pulmonary edema. Redness, cutaneous burns, and skin fissures.
Skin
Eyes
Disintegration and sloughing of conjunctival and corneal epithelium, corneal opacification, edema, ulceration, and blindness.
Safety goggles.
Ingestion
Corrosion of the lips, mouth, tongue and pharynx, severe esophageal and abdominal pain, and vomiting.
Carcinogenicity
Mutagenicity
Sodium Hypochlorite
CAS No. 7681-52-9 PS liquid Color yellow, green Odor chlorinelike FP N/A BP N/A MP N/A d 1.097 VP 17.5 @ 20 VD N/A Sol 100%
Acute Hazards/Symptoms Negligible fire hazard., may ignite or explode on contact with combustible materials. Severe burns, severe bronchial irritation, sore throat, blistering, coughing, nausea, and labored breathing. Redness, pain, blistering, itchy eczema, and chemical burns.
Prevention
First Aid/Fire
Avoid contact with Use extinguishing agents combustible materials appropriate for surrounding fire. Ventilation, local exhaust. Remove from exposure immediately; get medical attention immediately. Remove contaminated clothes and jewelry, thoroughly wash skin with water, and get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention, and continue to wash eyes with water. Contact physician immediately. Do not induce vomiting; give milk; if vomiting occurs, keep head lower than hips. Possible mutagen.
Inhalation
Skin
Eyes
Severe pain, hemorrhages, corneal opacification, edema, ulceration, and blindness.
Safety goggles.
Ingestion
Inflammation of the mouth and Do not eat or drink in digestive system, circulatory collapse, the laboratory. confusion, delirium, and drop in blood pressure.
Carcinogenicity
Mutagenicity
Sodium Iodide
CAS No. 7681-82-5 PS crystals, powder Color colorless to white Odor odorless FP N/A BP 1304 MP 661 d 3.67 VP 1@ 767 VD N/A Sol 184%
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed. Not a known mutagen.
Inhalation
Irritation. Prolonged exposure may produce iodism in sensitive individuals. Irritation.
Skin
Eyes
Irritation.
Safety goggles.
Ingestion
Enlargement of salivary glands or lymph glands.
Carcinogenicity
Mutagenicity
Sodium Lead Alloy

CAS No. 1274044-2 PS solid Color gray Odor N/A FP N/A BP N/A MP N/A d N/A VP N/A VD N/A Sol decomposes
Prevention
First Aid/Fire Use approved class D extinguisher or smother with dry sand; do not use water or CO2. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Extremely flammable, reacts violently No open flames or with water, liberating extremely sparks, protect from flammable gasses. moisture. Harmful if inhaled. Very irritating to respiratory system, causes burns. Very caustic, causes burns. Ventilation, local exhaust. Protective gloves and clothing.
Inhalation Skin
Eyes
Vapor or mist very caustic to the eyes. Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Sodium Nitrite
CAS No. PS Color
to yellow
Odor
FP N/A
BP N/A
MP 271
d 2.168 @0
VP N/A
VD N/A
Sol 82% @ 15
7632-00-0 solid
colorless odorless
Types of Hazard/Exposure
Fire
Acute Hazards/Symptoms Negligible fire hazard., may ignite or explode on contact with combustible materials.
Prevention
First Aid/Fire
Avoid contact with Use extinguishing agents combustible materials appropriate for surrounding fire. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; turn head to side, and get medical attention immediately.
Inhalation
Irritation, sore throat, and shortness of Ventilation, local breath. exhaust. Redness and irritation. Protective gloves and clothing.
Skin
Eyes
Irritation and dilation of pupils.
Safety goggles.
Ingestion
Gastrointestinal irritation with nausea, Do not eat or drink in vomiting, diarrhea, and abdominal the laboratory. pains, dizziness, confusion, and lethargy.
Carcinogenicity
Mutagenicity
Possible mutagen.
Sodium Nitroprusside
CAS No. 1375538-9 PS solid Color dark red Odor N/A FP N/A BP N/A MP N/A d 1.720 VP N/A VD N/A Sol soluble
Acute Hazards/Symptoms Noncombustible. Emits toxic fumes under fire conditions. Highly toxic, may be fatal if inhaled. Highly toxic, may be fatal if absorbed through skin.
First Aid/Fire Use extinguishing media appropriate to surrounding fire. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advise. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Eyes
Vapor or mist is highly toxic.
Safety goggles.
Ingestion
Highly toxic, may be fatal if swallowed.
Carcinogenicity
Mutagenicity
Sodium Sulfate
CAS No. 7757-82-6 PS crystals, powder Color white Odor odorless FP N/A BP N/A MP 884 d 2.671 VP N/A VD N/A Sol 17% @ 20
Prevention
First Aid/Fire Use extinguishing agents appropriate for surrounding fire. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. If vomiting occurs, keep head lower than hips.
Inhalation
Irritation.
Skin
Irritation.
Eyes
Irritation.
Safety goggles.
Ingestion
Diarrhea, fluid loss, blood in stools, and hypotension.
Carcinogenicity
Known carcinogen.
Mutagenicity
Known mutagen.
(E)-Stilbene
CAS No. 103-30-0 PS solid Color colorless Odor N/A FP BP N/A 305307 MP 122125 d 0.970 VP N/A VD N/A Sol almost insoluble
Acute Hazards/Symptoms Slight fire hazard. N/A Irritation.
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam. Remove from exposure immediately. Get medical attention. Remove contaminated clothing, jewelry, and shoes immediately. Thoroughly wash with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek immediate medical attention. If vomiting occurs, keep head lower than hips. Get medical attention. Possible mutagen.
Eyes
Irritation, itching, lacrimation.
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
(Z)-Stilbene
CAS No. 645-49-8 PS liquid Color pale yellow Odor N/A FP >110 BP 82-84 MP -5 d 1.02 VP N/A VD N/A Sol insoluble
First Aid/Fire Carbon dioxide, regular chemical powder, foam, water. Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek immediate medical attention. If vomiting occurs, keep head lower than hips; get medical attention, if needed.
Inhalation
May be harmful.
Skin
Eyes
Irritation.
Safety goggles.
Ingestion
May be harmful.
Carcinogenicity
Mutagenicity
d,l-Stilbene Dibromide
Acute Hazards/Symptoms Emits toxic fumes under fire conditions.* May be harmful if inhaled. Vapor is irritating to respiratory system. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.* May cause skin irritation.*
Prevention Avoid flames, sparks, and contact with hot surfaces Ventilation, local exhaust.
First Aid/Fire Water spray, dry chemical, foam, or carbon dioxide. Remove from exposure immediately, artificial respiration if needed; get medical attention.
Skin
Eyes
Lachrymator. Vapor or mist is irritating to the eyes.*
Safety goggles.
Ingestion
May be harmful if swallowed. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.* Not a known carcinogen.*
Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advise. If swallowed, wash out mouth with water. Call a physician.
Carcinogenicity
Mutagenicity
Not a known carcinogen*
*Toxicological information for the listed chemical is not available. Information given pertains to meso-stilbene dibromide and is intended to be used for comparison of a similar compound. Other effects may result from contact, inhalation, or ingestion. Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density (g/mL); Sol = solubility in water; N/A = not available or not applicable.
meso-Stilbene Dibromide
Acute Hazards/Symptoms Emits toxic fumes under fire conditions. May be harmful if inhaled. Vapor is irritating to respiratory system. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. May cause skin irritation.
Prevention Avoid flames, sparks, and contact with hot surfaces Ventilation, local exhaust.
First Aid/Fire Water spray, dry chemical, foam, or carbon dioxide. Remove from exposure immediately, artificial respiration if needed; get medical attention.
Skin
Eyes
Lachrymator. Vapor or mist is irritating to the eyes.
Safety goggles.
Ingestion
May be harmful if swallowed. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Not a known carcinogen
Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advise. If swallowed, wash out mouth with water. Call a physician.
Carcinogenicity
Mutagenicity
Styrene
CAS No. 100-42-5 PS liquid Color colorless Odor varying FP 31 BP 145146 MP -31 d 0.909 VP 10 @ 31 VD 3.6 Sol 0.02%
Prevention
First Aid/Fire Regular dry chemical, carbon dioxide, water for cooling, regular foam.
SEVERE fire hazard., vapors or gases may No flames, no ignite at distant ignition sources. sparks, no contact with hot surfaces. Irritation, headache, fatigue, difficulty in concentrating, central nervous system depression, nausea, weakness, dizziness, and inertia.
Inhalation
Ventilation, local Remove from exposure exhaust. immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed.
Skin
Irritation, redness, cracking, inflammation, Protective gloves defatting and degreasing of the skin; and clothing. absorption may result in symptoms given in inhalation. Irritation, redness, pain, lacrimation, Safety goggles. blurred vision, and slight reversible corneal damage.
Eyes
Ingestion
Irritation of the mouth, throat, and Do not eat or gastrointestinal tract, and symptoms given drink in the in inhalation. laboratory.
Carcinogenicity
Suspected carcinogen.
Mutagenicity
Known mutagen.
Succinic Acid
CAS No. 110-15-6 PS solid Color white Odor N/A FP N/A BP 235 MP 187190 d VP 1.55 0.009 VD N/A Sol 56.5 g/L
Acute Hazards/Symptoms Flammable. Emits toxic fumes under fire conditions. Irritating if inhaled, may be toxic. Irritating to the skin, may be harmful.
Inhalation Skin
Eyes
Vapor or mist is severely irritating to the eyes.
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Sucrose
CAS No. 57-50-1 PS crystals Color N/A Odor characteristic caramel FP N/A BP N/A MP 160 186 d 1.59 VP N/A VD Sol
N/A 1.5 g/0.5 mL
Prevention N/A
Inhalation
Not expected to be a health hazard. Nuisance dust. Inhalation of high concentrations may cause coughing and upper respiratory tract irritation. No adverse effects expected. No adverse effects expected but dust may cause mechanical irritation.
Ventilation, local Remove to fresh air. Get exhaust. medical attention for any breathing difficulty. Protective gloves Not expected to require and clothing. first-aid measures. Safety goggles. Wash thoroughly with running water. Get medical advice if irritation develops. If large amounts were swallowed, give water to drink and get medical advice.
Skin Eyes
Ingestion
Extremely large oral dosages may produce gastrointestinal disturbances.
Carcinogenicity
Mutagenicity
Possible mutagen.
Sulfanilamide
CAS No. 63-74-1 PS solid Color white Odor FP BP N/A MP 165 167 d 1.08 VP N/A VD N/A Sol 7.5%
odorless N/A
Prevention N/A
Inhalation
Harmful.
Ventilation, local Remove from exposure exhaust. immediately; get medical attention. Protective gloves Remove contaminated and clothing. clothes and jewelry, thoroughly wash skin with water. Safety goggles. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. Give sodium bicarbonate solution; if vomiting occurs, keep head lower than hips.
Skin
Irritation.
Eyes
Irritation.
Ingestion
Cyanosis, anorexia, vomiting, dizziness, and drowsiness.
Carcinogenicity
Mutagenicity
Possible mutagen.
3-Sulfolene
CAS No. 77-79-2 PS crystals Color offwhite Odor N/A FP 109 BP N/A MP 6566 d N/A VP N/A VD N/A Sol soluble
First Aid/Fire Carbon dioxide, regular chemical powder, foam, water Remove from exposure immediately; get medical attention. Remove contaminated clothes and jewelry, thoroughly wash skin with water. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed.
Inhalation
May be harmful
Skin
Irritation, may be harmful if absorbed through skin
Eyes
Irritation
Safety goggles.
Ingestion
May be harmful
Carcinogenicity
Mutagenicity
Sulfuric Acid, Fuming

CAS No. Sulfuric acid 7664-93-9 Sulfur trioxide 7446-11-9 PS liquid Color yellow Odor pungent FP N/A BP 100 MP N/A d 1.84 VP 1 VD <0.3 Sol reacts violently
Prevention N/A
Inhalation
Sore throat, labored breathing, coughing, Ventilation, local Remove from exposure choking, chronic respiratory tract exhaust. immediately, keep warm damage, and chronic bronchitis. and at rest, get medical attention immediately. Severe irritation, pain, and burns. Protective gloves Remove contaminated and clothing. clothes and jewelry, thoroughly wash skin with water, and get medical attention immediately. Safety goggles. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, and continue to wash eyes with water. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips.
Skin
Eyes
Severe damage and blindness.
Ingestion
Serious burns of the mouth and esophagus, pain in the abdomen, vomiting, and diarrhea.
Carcinogenicity
Known carcinogen.
Mutagenicity
Sulfuric Acid Solutions

CAS No. 7664-93-9 PS liquid Color colorless Odor N/A FP N/A BP 100 MP N/A d 1.84 VP 1 VD <0.3 Sol soluble
Acute Hazards/Symptoms Negligible fire hazard., may ignite or explode on contact with combustible materials. Irritation, shallower and more rapid breathing, sneezing, a burning or tickling sensation in the nose and throat, and cough. Second and third degree skin burns, necrosis, charring, and shock.
Prevention
First Aid/Fire
Avoid contact Use extinguishing agents with combustible appropriate for materials surrounding fire. Ventilation, local Remove from exposure exhaust. immediately, keep warm and at rest, get medical attention immediately. Protective gloves Remove contaminated and clothing. clothes and jewelry, thoroughly wash skin with water, and get medical attention immediately. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, and continue to wash eyes with water. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips.
Inhalation
Skin
Eyes
Burning or stinging sensation, lacrimation, Safety goggles. blurred vision, and conjunctival congestion.
Ingestion
Burning pain in the mouth, throat, esophagus and abdomen, nausea, and vomiting.
Carcinogenicity
Known carcinogen.
Mutagenicity
Sulfuryl Chloride
CAS No. 7791-255 PS liquid Color colorless to pale yellow Odor sharp FP none BP 6870 MP -54 d 1.680 VP 100 @ 17.8 VD 4.65 Sol decomposes
Acute Hazards/Symptoms Flammable, reacts violently with water. Emits toxic and extremely flammable fumes under fire conditions. Extremely destructive to mucous membranes, may be fatal if inhaled.
First Aid/Fire Extinguish with dry chemical extinguisher; do not use water. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Not a known mutagen.
Inhalation
Skin
Causes burns, may be fatal if absorbed Protective gloves and through skin. clothing.
Eyes
Vapor or mist is very damaging to the Safety goggles. eyes.
Ingestion
May be fatal if swallowed.
Carcinogenicity
Mutagenicity
L-Tartaric
acid
MP d 170172 1.760 Prevention Avoid heat, sparks, flames. Ventilation, local exhaust. VP N/A VD N/A Sol soluble
CAS No. 87-69-4
PS solid
Color white
Odor N/A
FP 150
BP N/A
Acute Hazards/Symptoms Fire possible at elevated temperatures or by contact with an ignition source. Emits toxic fumes under fire conditions. Irritant to respiratory system
First Aid/Fire Water spray, Carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Immediately flush eyes with copious amounts of water lifting upper and lower lids occasionally. Seek medical advice. If swallowed wash out mouth with water. Not a known mutagen.
Inhalation
Skin
Irritant to skin.
Eyes
Irritant to eyes.
Ingestion
Carcinogenicity
Tetrachloroethylene
CAS No. 127-18-4 PS liqui d Color none Odor N/A FP None BP 121 MP -22 d 1.623 VP 19 VD 5.83 Sol 0.165 g/L
Acute Hazards/Symptoms Noncombustible. Emits toxic fumes under fire conditions. Harmful if inhaled. Harmful if absorbed through skin. N/A
Prevention
First Aid/Fire
Eyes
Ingestion
Use extinguishing media appropriate to surrounding materials. Ventilation, local Remove to fresh air. If exhaust. breathing is difficult, give oxygen. Protective gloves and Immediately flush skin clothing. with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Safety goggles. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. Do not eat or drink in If swallowed wash out the laboratory. mouth with water. Call a physician. Mutagenicity Not a known mutagen.
Carcinogenicity
Kn own carcinogen.
Thionyl Chloride
CAS No. 7719-09-7 PS Color clear, pale yellow Odor FP BP 76 MP -105 d 1.64 VP 100 @ 21 VD N/A Sol decomposes
pungent N/A
Types of Hazard/Exposur e Fire
Prevention
First Aid/Fire
Not considered to be a fire hazard. May react N/A violently with water or moist air. Can liberate flammable hydrogen gas when in contact with metal and moisture.
Use extinguishing agents appropriate for surrounding fire.
Inhalation
Corrosive. Extremely destructive to tissues of Ventilation, local Remove to fresh air. Get the mucous membranes and upper respiratory exhaust. medical attention immediately. tract. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting. Corrosive. Liquid contact may cause blistering burns, irritation, and pain. Vapors may be severely irritating to the skin. Protective gloves Wipe off excess material from and clothing. skin then immediately flush skin with water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. If swallowed, do not induce vomiting. Give large quantities of water. Get medical attention immediately.
Skin
Eyes
Corrosive! Vapors are irritating and may cause Safety goggles. damage to the eyes. Contact may cause severe burns and permanent eye damage.
Ingestion
Corrosive. May cause burning pain in throat, abdominal pain, nausea, and vomiting.
Carcinogenicity Not a known carcinogen.
Mutagenicity
For more detailed information consult the Material Safety Data Sheet for this compound. ations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
Tin
CAS No. PS Color silvery Odor FP BP 2507 MP 231.9 d 7.31 VP 1@ 1609 VD N/A Sol insoluble
7440-31-5 granules or flakes Types of Hazard/Exposure Fire
odorless N/A
Acute Hazards/Symptoms Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Prevention No open flames.
First Aid/Fire Dry sand, graphite, dolomite, sodium chloride. Never use water, halogenated agents, or class A, B, or C extinguishers.
Inhalation
No adverse effects expected but dust may cause mechanical irritation.
Ventilation, local Not expected to require exhaust. first-aid measures. Remove to fresh air. Get medical attention for any breathing difficulty. Protective gloves Not expected to require and clothing. first aid measures. Wash exposed area with soap and water. Get medical advice if irritation develops. Safety goggles. Wash thoroughly with running water. Get medical advice if irritation develops. Induce vomiting immediately as directed by medical personnel.
Skin
No adverse effects expected. May cause mild irritation and redness.
Eyes
No adverse effects expected but dust may cause mechanical irritation.
Ingestion
Large doses may cause nausea, vomiting, and diarrhea.
Carcinogenicity
Mutagenicity
Tin (II) Chloride

CAS No. 7772-99-8 PS solid Color off-white Odor N/A FP N/A BP 652 MP 246 d 3.950 VP N/A VD N/A Sol decomposes
Acute Hazards/Symptoms Nonflammable.
Prevention No open flames or sparks, protect from moisture. Ventilation, local exhaust. Protective gloves and clothing.
First Aid/Fire Media appropriate for surrounding fire. Extinguish with dry chemical powder. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed, wash out mouth with water provided person is conscious. Call a physician. Not a known mutagen.
Inhalation Skin
Extremely destructive to mucous membranes and lungs. Corrosive, causes burns.
Eyes
Extremely destructive to the eyes.
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Toluene
CAS No. 108-88-3 PS liquid Color colorless Odor distinct FP 4 BP 110.6 MP -93 d 0.865 VP 22 @ 20 VD 3.2 Sol 0.05% @ 20
First Aid/Fire Regular dry chemical, carbon dioxide, water for cooling, regular foam
Inhalation
Fatigue, weakness, confusion, headache, nausea, and drowsiness. Irritation and drying.
Ventilation, local Remove from exposure exhaust. immediately; get medical attention. Protective gloves Remove contaminated and clothing. clothes and jewelry, thoroughly wash skin with water. Safety goggles. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. Contact physician immediately. If vomiting occurs keep, head lower than hips.
Skin
Eyes
Irritation and corneal burns.
Ingestion
Abdominal spasms, systemic effects given Do not eat or in inhalation, coughing, and gagging. drink in the laboratory.
Carcinogenicity
Mutagenicity
Possible mutagen.
p-Toluidine
CAS No. 106-49-0 PS solid Color Odor colorless fish-like FP 88 BP 200 MP 4446 d 0.973 VP N/A VD 3.9 Sol 0.664 g/L
First Aid/Fire Water spray, carbon dioxide, dry chemical powder or appropriate foam. Remove to fresh air. If breathing is difficult, give oxygen. Immediately flush skin with soap and copious amounts of water for at least 15 minutes. Remove contaminated clothing. Immediately flush eyes with copious amounts of water lifting upper and lower lids often. Seek medical advice. If swallowed wash out mouth with water. Call a physician. Possible mutagen
Inhalation Skin
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Possible carcinogen
Mutagenicity
Triethylene Glycol
CAS No. 112-27-6 PS liquid Color colorless Odor N/A FP 165 BP 285 MP -7 d VP 1.125 <0.01 VD 5.2 Sol soluble
Inhalation Skin
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Trimyristin
CAS No. 555-45-3 PS liquid Color colorless Odor N/A FP >110 BP N/A MP 5658 d VP VD 1.080 <0.01 8.95 Sol Insoluble
Inhalation Skin
Eyes
Safety goggles.
Ingestion
Carcinogenicity
Mutagenicity
Triphenylmethanol
CAS No. 76-84-6 PS solid Color colorless to offwhite Odor N/A FP N/A BP 380 MP 164 d 1.1999 VP N/A VD N/A Sol insoluble
First Aid/Fire Regular dry chemical, carbon dioxide, water, regular foam.
Inhalation
May be harmful.
Ventilation, local Remove from exposure exhaust. immediately; get medical attention. Protective gloves Remove contaminated and clothing. clothes and jewelry, thoroughly wash skin with water. Safety goggles. Thoroughly wash eyes with water for several min, remove contact lenses if possible, and seek medical attention immediately. If vomiting occurs, keep head lower than hips; get medical attention, if needed.
Skin
May be harmful.
Eyes
Irritation.
Ingestion
May be harmful.
Carcinogenicity
Mutagenicity
Urea
CAS No. 57-13-6 PS crystals or powder Color white Odor ammonialike FP BP MP 135 d 1.32 VP N/A VD N/A Sol N/A
N/A Decomposes
Acute Hazards/Symptoms Not considered to be a fire hazard. N/A
Prevention
First Aid/Fire Use any means suitable for extinguishing surrounding fire. Remove to fresh air. If breathing is difficult, give oxygen. Get medical attention.
Inhalation
Causes irritation to the respiratory tract. Ventilation, local Symptoms may include coughing, exhaust. shortness of breath. May be absorbed into the bloodstream with symptoms similar to ingestion. Causes irritation to skin. Symptoms include redness, itching, and pain.
Skin
Protective gloves and Immediately flush skin clothing. with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention if symptoms occur. Safety goggles. Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Eyes
Ingestion
Causes irritation to the gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea. May also cause headache, confusion and electrolyte depletion.
Do not eat or drink in Induce vomiting the laboratory. immediately as directed by medical personnel. Get medical attention.
Carcinogenicity
Mutagenicity
Possible mutagen.
m-Xylene
CAS No. 108-38-3 PS liquid Color clear Odor aromatic FP 26 BP 138 MP -48 d 0.86 VP 9 @ 20 VD 3.7 Sol insoluble
First Aid/Fire Dry chemical, foam or carbon dioxide. If inhaled, remove to fresh air. If breathing is difficult, give oxygen. Call a physician.
Inhalation
Inhalation of vapors may be irritating Ventilation, local to the nose and throat. Inhalation of exhaust. high concentrations may result in nausea, vomiting, headache, ringing in the ears, and severe breathing difficulties that may be delayed in onset.. Skin contact results in loss of natural Protective gloves and oils and often results in a characteristic clothing. dermatitis. May be absorbed through the skin.
Skin
Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. Aspiration hazard. If swallowed, do not induce vomiting. Give large quantities of water. Get medical attention immediately. If vomiting occurs, keep head below hips.
Eyes
Vapors cause eye irritation. Splashes Safety goggles. cause severe irritation, possible corneal burns and eye damage.
Ingestion
Ingestion causes burning sensation in Do not eat or drink in mouth and stomach, nausea, vomiting the laboratory. and salivation.
Carcinogenicity
Mutagenicity
Possible mutagen.
p-Xylene
CAS No. 106-42-3 PS liquid Color clear Odor aromatic FP 27.2 BP 138 MP d VP VD Sol insoluble
1314 0.86
9 torr @ 3.7 20
First Aid/Fire Dry chemical, foam or carbon dioxide.. If inhaled, remove to fresh air. If breathing is difficult, give oxygen. Call a physician.
Inhalation
Inhalation of vapors may be irritating to Ventilation, local the nose and throat. Inhalation of high exhaust. concentrations may result in nausea, vomiting, headache, ringing in the ears, and severe breathing difficulties that may be delayed in onset. Skin contact results in loss of natural Protective gloves oils and often results in a characteristic and clothing. dermatitis. May be absorbed through the skin.
Skin
Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Eyes
Vapors cause eye irritation. Splashes cause severe irritation, possible corneal burns and eye damage.
Safety goggles.
Ingestion
Ingestion causes burning sensation in mouth and stomach, nausea, vomiting and salivation..
Do not eat, drink, or Aspiration hazard. If smoke during work. swallowed, do not induce vomiting. Give large quantities of water; if vomiting occurs, keep head below hips. Get medical attention immediately.
Carcinogenicity
Mutagenicity
Possible mutagen.
Xylenes
CAS No. 1330-20-7 PS liquid Color clear Odor aromatic FP 9 BP 137140 MP -25 d 0.86 VP VD Sol insoluble
8 @ 20 3.7
Prevention
First Aid/Fire
No flames, no Dry chemical, foam or sparks, no contact carbon dioxide. with hot surfaces. If inhaled, remove to fresh air. If breathing is difficult, give oxygen. Call a physician.
Inhalation
Inhalation of vapors may be irritating to the Ventilation, local nose and throat. exhaust., or breathing protection.
Skin
Skin contact results in loss of natural oils Protective gloves Immediately flush skin with and often results in a characteristic and clothing. plenty of soap and water for dermatitis. May be absorbed through skin. at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Vapors cause eye irritation. Splashes cause Safety goggles. severe irritation, possible corneal burns and eye damage. Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately.
Eyes
Ingestion
Ingestion causes burning sensation in mouth Do not eat or drink Aspiration hazard. If and stomach, nausea, vomiting and in the laboratory swallowed, do not induce salivation. Minute amounts aspirated into vomiting. Give large the lungs can produce a severe hemorrhagic quantities of water. If pneumonitis with severe pulmonary injury vomiting occurs, keep head or death. below hips.
Carcinogenicity
Mutagenicity
Possible mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound. ations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (C); BP = boiling point (C) @ 760 torr unless otherwise stated; MP = melting point (C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (C); VD = vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
Zinc Chloride
CAS No. 7646-85-7 PS crystals Color white Odor FP BP 732 MP 293 d 2.91 VP 1 VD N/A Sol 432%
odorless N/A
Prevention N/A
Inhalation
Irritation, metallic taste, lacrimation, sore throat, hoarseness, chest pain, soreness, nausea, abdominal pain, and vomiting. Irritation, redness, pain, papular and primary dermatitis, chemical burns, boils, and ulceration.
Ventilation, local Remove from exposure exhaust. immediately, keep warm and at rest, get medical attention immediately. Protective gloves Remove contaminated and clothing. clothes and jewelry, thoroughly wash skin with water, get medical attention immediately. Safety goggles. Thoroughly wash eyes with water for several min, remove contact lenses if possible, seek medical attention immediately, and continue to wash eyes with water. Contact physician immediately. Give water or milk; if vomiting occurs, keep head lower than hips.
Skin
Eyes
Irritation, pain, redness, blurred vision, corneal burns, ulceration, conjunctivitis, dermatitis, and iritis.
Ingestion
Irritation of mucous membranes, corrosion, Do not eat or swollen lips, sore throat, chest pain, drink in the nausea, vomiting, and bloody diarrhea. laboratory.
Carcinogenicity
Mutagenicity
Possible mutagen.

MSDS

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Abbreviated Material Safety Data Sheets (MSDSs)

Types of Hazard/Exposure Fire

Acute Hazards/Symptoms Slight fire hazard.

Irritation, drowsiness, fatigue, nausea, acidosis and skin eruptions. Irritation.

Irritation, corneal damage.

Drowsiness, fatigue, nausea, acidosis and skin eruptions.

Do not eat or drink in the laboratory.

Types of Hazard/Exposure Fire

Dust, vapor, or mist may be irritating to the eyes.

May be harmful if swallowed.

Do not eat or drink in the laboratory.

Not a known carcinogen.

Types of Hazard/Exposure Fire

Acute Hazards/Symptoms Moderate fire hazard.

Corrosive material, chemical burns.

Not a known carcinogen.

Types of Hazard/Exposure Fire

Acute Hazards/Symptoms Slight fire hazard.

Prevention Avoid heat, sparks, flames. Ventilation, local exhaust.

Irritation, eczematous skin eruptions, poisoning as in ingestion.

Irritation, contact dermatitis, skin eruptions due to systemic poisoning

Protective gloves and clothing.

Do not eat or drink in the laboratory.

1.049 11.8 @ 2.07 20

Types of Hazard/Exposure Fire

Types of Hazard/Exposure Fire

Protective gloves and clothing.

Not a known carcinogen

Types of Hazard/Exposure Fire

Do not eat or drink in the laboratory.

Types of Hazard/Exposure Fire

Acute Hazards/Symptoms Slightly flammable.

Prevention No open flames.

Cyanosis, dizziness, respiratory depression. Possibly a mild irritant.

Possibly irritating to eye tissues.

Types of Hazard/Exposure Fire

Acute Hazards/Symptoms Moderate fire hazard.

Not a known carcinogen.

Types of Hazard/Exposure Fire Inhalation

Acute Hazards/Symptoms Combustible. Cough. Labored breathing. Sore throat.

Prevention No open flames. Local exhaust or breathing protection.

Redness and pain.

Do not eat or drink in the laboratory. Mutagenicity

Not a known carcinogen.

Not a known mutagen.

Types of Hazard/Exposure Fire

Acute Hazards/Symptoms Negligible fire hazard. N/A

Irritation, redness, and possibly swelling of the conjunctiva.

Do not eat or drink in the laboratory.

Types of Hazard/Exposure Fire

Acute Hazards/Symptoms Negligible fire hazard. N/A

Ventilation, local exhaust.

Protective gloves and clothing.

Redness, pain, blurred vision, and corneal burns.

Types of Hazard/Exposure Fire

Prevention No open flames or sparks. Ventilation, local exhaust.

Protective gloves and clothing. Safety goggles.

Do not eat or drink in the laboratory.

Not a known carcinogen.

Types of Hazard/Exposure Fire

Acute Hazards/Symptoms Negligible fire hazard. N/A

Types of Hazard/Exposure Fire

May cause effects as described under ingestion.