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OFFICE OF CIVIL DEFENSE OFFICE 0' THE SECRETARY OF THE ARMY WASHINGTON, 0. C. 2310 OCO CONTRACT OANC 2D-67-C-C 133I ODWORK UNIT 3311C
*
ThIs *Md
11w111Uted
Reproduced by the CLEAR ING HOUSE for Iecderaf Scicrnijc & Technjia Informiation Springfield
Vaj. 22151
D C8 i s
* SRISTANF03ED
RESEARCH INSTITUTE:
FIrnl Raport
July I9
Detachobit Summery
By: F. E. WALKER
PfJut for, OFFICF OF CIVIL DEFENSE OFFICE OF THE SECRETARY OF THE ARMY WASHINGTON. D. C. 20310 OCD CONTRACT DAHC 20-67-C-0138 OCO WORK UNIT 3311C
SRI Projo
MU 6300-620
This documwt hu been @mved fo Pubk rado en4 mWe ditvLiuton IsurnMlni. In
OCO REVIEW NOTICE Tht non ta ben ,loe in the nley does not sfnty the wcmftwta of ot Cvil D*eImeeW approved for wA1iDtItn. Approval reflect the views and vol 1 of the Office of Civil Detee.
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DETACHABLE SUW4ARY
Method Developed The study effort was directed toward developing a method for rapidly estimating to what exteat petroleum refineries would be affected in the event of a nuclear attack on the United States. The method developed en-
ables the user to estimate the repair requirements, and the corresponding production capabilities, of petroleum refineries after blast damage from overpressures of 0.5, 1, 5, and 10 psi. Thus, it is possible to predict
what a given level oi repair effort will buy in terms of petroleum products, when it is known which refinery is hit, and with what overpressure. The estimating method %,.s used during the study to produce the following major conclusions: 0 After 0.3-0.5 psi, a refinery can produce the same proportion of products but at about 70 percent of the initial capacity. This
reflects the assumptton that at this overpressure refinery capacity is directly related to remaining cooling tower capacity. * After 1.0 psi, a refinery temporarily shuts down, but with minor emergency repair to process controls, it can operate at about 50 percent of initial capacity, a After 1.5 psi, a refinery is totally shut down, primarily because of process control damage by roof collapse in each of the numerous individual refining process control rooms. Vulnerability at
higher overpressures is summarized in Section IV. The physical items needed for refinery repair after blast damage are: S-1
i-
0 Material. by type
Repair labor requirewnts were developed by Atudy of the average
The require-
ments are shown graphically in Figure 2, as best-fit curves of data from average refineries, indicating a range of man-dayg for a given initial refinery capacity at a specified overpr.ssure level, Thin report dis-
cusses how the repair requitements are developed and describes all the elements that are covered. Analysis of conclusions indicates that repair
costs calculated by the method developed are consistenit with overall avorage costs of building new refineries.
Repair Decision After blast damage to petroleum refineries, certain decisions must be made before repairs to restore production are begun. The decisions
will hinge on what products are needed and what repair effort is available. Reclaiming refinery capability for light fuel products such as gasolines, jet fuels, and diesel fuels (most likely to be in d'omand during a period of postattack repair) will require decisions in three areas and will be governed by what products are most needed, and what minirmum grades will meet users' demands. 0 The three decision areas are:
a The stage to which the repair is to be made 0 The substitution of an alternative crude oil for the refinery's 'normal" supply Reclaiming rejinery capability for producing specialty products, such as asphalts and lubes, will require decisions on where to produce these products, for example, whether to: S-2
Ig
300
CAP4 AC~ REQUIRE4EiroPR.A APT E r".~ IFT$TO~ RE I, e OfrJL.Asr OVEREJ ~r EFN.R. 8- 3 SSUE LEVELS
I!
m Fully repair the specialty refinery
* Partially repair the specialty refinery, the comparable specialty
* * m *
Application of the Mothod The following sequence esmes, for the repair of petroloam refining proc-
Repair thu crude oil topping processing unit Repair processing unite that convert heavy petroluum fractions to gasoline-type products Repair processing units which upgrade gasolines Repair all other processing units producing nonfuels
C V
ure 2 (based on average refineries) and determine, for any refinery capacity at a specified level of blast overpressure, the level of repair effort in sian-days that is required to restore the refinery to 100 percent production. For example:
A 24,000 B/D refinery is expected to require 60,rOO to 90,000 man-days of repair labor to return capacity after 10 psi overpressure Also, for any refinery product, by type of refinery, the reader is it to 100 percent of initial
given tables and charts from which to determine the amount of a product (as a percent of initial refinery capacity) that can be produced after
S-4
For exmmplP
Before blast damage, Ka-iollne constitutes 50 percent of initial total products from a small fuel refinery, After 10 pai
overpressure a 24,000 H/D small fuel rfinery hao tho produc-
~030
30
----
"
0000.
I@ 0
20
I
20
.,
40
l
50 so
-_ I
?a
Jo
11
so
MA0-OAYS iN Ts," &W WkDhMAGED COWOiTfOh bi 0 PEINCUT O*IAATfOI AFTER 6.3-04 ps NI IC PO IRCENT OPEKAATIOS AFTER IC m.
FIGURE 3
GASOLINE YIELD RESULTING FROM REPAIR EFFORT AT SELECTED SLAST OVERPRESSURES SMALL FUEL REFINERY. 24.00 SLAHRELS PER DAY CAPACITY
S-5
Results of sensitivity analysts on refinery sites show that for refineries of tIe sam typo, but of different sizes, the stages f repair
effort (Repair Stages A, B, C, and D) are proportional to the correspondIng repair stages of the averago size refinery.
This means that, for any refinery type, an estimator can simply caluulate the ratio of the Individual repair atage to the cuulative rep&ir
stage for the average size refinery of a particular type, apply that rtth_
Then, to find the repair requirement for Stage A for a small fuel refinery of a different size:
A
Ratio of A.I+C+"
u
Thus:
0.36 x 285,00,0 and 335,000 = 103,000 to 120,000 mandays for Repair Stage A
Following
S-6
.4
systou may necesttate upplying a refinery with an alternatLve ertad oil. The "normal" crude oil input to fuel and complete processing re-
of three zepropentative
ittg a refinery with ot of the other two of the three major U.S. crude
oil types rathei than with what this study judged to be that refinery'# is illustrated by the followit tsxamplea
with its norisal crudq oil and alternative crude oils has the production capability shown 1ielow.
Stage
A 8 C D
Crude Oil
44 62 79 100
Crude Otis
25-2ft 28-33 31-37 33-42
Sum.mtry of Results The method for estimating production capabilities and requiroments of refinerles after a nuclear attack is summarized in Tables 1, 2, and 3. Table I gives, for each type of refinery, the product percentages
available when the refinery is undamaged (0 psi), and at two levels of low overpressure: the range of 0.3-0.5 psi, with no repair effort, and Table 1
can be used for any sixe refinery of the type specified; it gives the normal product mix and shows the imumdiate effect of damage in the low overpressure ranges, where refineries are still operable.
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8-10
At overpressures of 1.5 psi or greater, repair to refineries becomes necessary for them to operate. Table 2 gives product percentages after
each of the four repair stages for an average size refinery of each type, thus showing the incremental production that each repair stage affords. Table 3 gives the man-days of repair effort required at each repair stage and for each level of overpresoure for an average size refinery of each type. The only data the estimator has to supply are readily available from industry published periodicals, journals, or reference msterial:2 * a Refinery type and initial capacity in B/D Type of crude oil used, including both the "normal" crude oil supply and an alternative (supplied in the report) It is recognized that in a postattack environment the relative demand for individual products will not be the same as before an attack. Because.
refining processes produce a combination of products, a relatively high demand for one product creates a surplus of "other" products.
Management
and planning must consider uses for, or ways to dispose of, these other surplus products. For example, kerosene and diesel type products normally In a postattack condition
if the demand for gasoline and residual fuel rises so that the demand for kerosene and diesel products drops to one-fourth of the total products, a surplus of kerosene and diesel equivalent to one-twelfth of the total products would occur. Even with reduced total products of 6 million bar-
rels per day (slightly more than 50 percent of current production) this
!S-li
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Finul R#port
Jl
By: F. E, WALKER
Prepard tor.
OFFICE OF CIVIL DEFENSE OFFICE OF THE SECRETARY OF THE ARMY WASHINGTON. D. C. 20310 OCD CONTRACT DAHC 20-67-C-0136 OCD WORK UNIT 3311C SRI Project MU 6300-620
This doamnwt ho ban apm~ for pubdic rum$ ud ole; is dlobution Is unlicnited. OCO REVIEW NOTICE This rtpo h bus rwd in the Offi of CM ODfhww und reproved for puWlattio. Approe dms aotslgnIfy tha tw ntmu neaomily r thevwum v n poliaie of thu Office of Ckil Dsnse. d
CONTENTS
I II III
1
7 19 21 25 28 29 33 35 39 39 41 43 43 47 47 50 52 54 61 64 66 69 69 70 72 74 76
INDUSTRY DESCRIPTORS .................... Crude Oils . . . . . . . . . . . . . . . . . . . . . . . . . Refinery Types ........... ....................... Processing ......... ......................... . Equipment ......................... Products .......... .......................... . .............. .. Validity of inlustry Descriptors ....
IV
...................
..
Cooling Tower ........ ....................... . Controls .......... ......................... . Fired Heater ......... ........................ ... Tanks . . . ........ .... ... .......................... V ...................... REFIERY REPAIR ........ Repair Stages ........ ....................... Quantity of Production in Repaired Refineries ........ Quality of Products After Repair .... .............. Labor .......... ........................... Crafts. ............. ........................... Repair Materials ........ ...................... Operational Materials ...... ................... VI USING THE MSThOD ........ ...................... . . . .. . . . .
Determine Refinery Size and Type .... .............. .. .. ................. Determine Crude Oil Supply ..... Estimate Production Capability ..... ............... .. Estimate Repair Requirements ..... ................ .. Estimate Production Capability by Repair Stage ....... ...
ii
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...
CNTENTS
APPENDIXES
A B C D EQUIPMENT SIZES AND NUMERS. ................ 87 137
.
PRODUCT YIELD FROM CRUDE OILS AFTER LOW BLAST OVERPRESSURE PRODUCT YIELD FROM CRUDE OILS AT FOUR STAGES OF REPAIR REPAIR REQUIREMENTS AT FOUR REPAIR STAGES AFTER BLAST OVERPRESSURE ....................... ........................... ........................... .. .
.
1
iv
ILLUSTRATIONS
3
.
asoline Yield Resulting from Repair Effort at Selected Blast Overpressures: Small Fuel Refinery; 24,000 Barrels per Day Capacity ..... ................... . Complete Processing
.
. .
11
..
.......................
.
.
31 45
5 6
Individual Refinery Labor Requirements to Restore 100 Percent Capacity after Selected Blast Overpressure Levels . . Cost to Restore Refineries to 100 Percent Capacity after 10 psi Blast Overpressure, Compared with New Refinery Con......................... struction Cost ........
59
63
Labor Requirements to Restore 100 Percent Refinery Capacity after Specified Blast Overpressure Levels .... ......... Product Yield versus Repair Effort, Undamaged and after 1.0 psi Overpressure: Large Fuel Refinery; 165,000 Barrels per Day Capacity ....... ..................... .... Product Yield versus Repair Effort at Selected Blast Overpressures: Large Fuel Refinery; 78,000 Barrels per Day Capacity ..............................
75
78
10
79
11
Product Yield versus Repair Effort at Selected Blast Overpressures: Small Fuel Refinery; 24,000 Barrels per Day Capacity ...... ...... ......................... Product Yield versus Repair Effort at Selected Blast Overpressures: Complete Processing Refinery; 194,000 Barrels per Day Capacity ...... .... .....................
80
12
81
13
Product Yield versus Repair Effort at Selected Blast Overpressures: Asphalt Refinery; 12,000 Barrels per Day Capacity ...... ... ......................... ....
82
I
IONS
IO
4.
14
Product Yield versus Repair Effort lt Selected Blast Overpressuree: Asphalt nd Lube Refienery; 7,000 Barrels p*r
Day Capacity .
. . .
. .
83
84
15
Product Yield versus Repair Effort at Selected Blast Overpreaures: Lube Refinery; 4,000 Barrels per Day Capacity
I
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TABLES
I 2
Initial Capacity and Partial Production Capability after 0.3-0.5 psi and 1,0 psi Blast Overprmur* ........
Production Capability by Repair Stage after 1.5 psi or Orester Blast Overprosr . .. ........ .. .
14
15
. . . ...............
. .
16
4 5 6 7
Refinery Categorization
. .
27 30 34
Refinery Processing Unit Capacity Indices .... Refining Equipment Included in Processing Units
. .
. . .......
49
Refinery Production Capability by Repair Stage with "Normal" and Alternative Crude Oils ..... ................ .... ...... 51 56 58 62 67 71 71
9 10 11 12 13 14 15
Parameter Values for Labor Requirement Model .... Repair Requirements, by Refinery Type . Repair Cost after 10 psi Overpressure .. Operational Supplies ......
............ ..........
.................. ....
.
Determining Refinery Type from Processing Combinations Normal and Alternative Crude Oils, by Refinery Type
Refinery Production Capability with Selected Crude Oils after 0-1 psi Blast Overpressure ... ............. .... Equipment Sizes and Numbers:
Unit ..........................
73
A-1
-2
-3
-4
........................... vii
109
/
TABLES - 5 - 6 aod Numbers: CokIng Processing Unit . Equipmnt Sizes and Numbers: Catalytic Cracking Procastink Unit . . . . . . . . . . . . . . . . .
E ipment SiYe
1'
4
IIlI . 113
and Numbers:
. . .
. . . . . . . .
Equipment Sizes and Numbers: Equipent Sizes and Numbers: Equipment Sizes and Numbers: easing Unit ... .................... Equipment Sizes and Numbers:
Unit .
. . .
Polymerization Processing
117
Unit . . . . . . . . . . . . . . . . . . . . . . . . . .
119 121
Equipment Sizes and Numbers: Vacuum Distillation Proceasing Unit ........ ...................... .... Equipment Sizes and Numbers: Lube and Specialties Processing Unit . . . . . . . . . . . . . . . . . . . .. .
Equipment Sizes and Numbers: Asphalt Processing Unit
125 127
129
-15
Equipment Sizes and Numbers: Light 011 Treating Processing Unit ..... ... ...................... .... Equipment Sizes and Numbers: cialties Processing Unit ..... Naphthenic Lube and Spe................ .... .....
-16 -17 B- 1
-
Equipment Sizes and Numbers: Pipe Supports and Utilities ....... .......................
Product Yield from Crude Oils after Low Blast Overpressure: Large Fuel Refinery ... ............. .... Product Yield from Crude Oils after Low Blast Overpressure: Small Fuel Refinery ... ............. .... Product Yield from Crude Oils after Low Blast Overpressure: Complete Processing Refinery . ........ ..
143
viii
TABLES
B- 4 - 5 - a CI
Product Yield fro% Crude Oil# after Low Blast Overpresure: Asphalt Refinery . . . .... . Product Yield from Crude Oils after Low Blast Overpressure: Asphalt and Lube Refinery ...... . . Product Yield from Crude Oils after Low Blast Overpressure: Luba Refinery ....
. . . ........
144
.
145
146
Product Yield from Crude Oils at Four Rep0air Stages: Large Fuel Refinery ..... . . .... Product Yield from Crude Oils at Four Repair Stages: Small Fuel Refinery ........ ............. .... Product Yield from Crude Oils at Four Repair Stages; Complete Processing Refinery ..... ......... .. Product Yield from Crude Oils at Four Repair Stages: Asphalt Refinery ......... ................ .... Product Yield from Crude Oils at Four Repair Stages: Asphalt and Lube Refinery . ............. Product Yield from Crude Oils at Four Repair Stages: Lube Refinery ......... ......... ......... ..... Repair Requirements after Blast Overpressure, Four Repair Stages: Large Fuel Refinery, 78,000 B/D Capacity . . . Repair Requirements after Blast Overpressure, Four Repair Stages: Large Fuel Refinery, 150,000 B/D Capacity . . . Repair Requirements after Blast Overpreasure, Four Repair Stages: Small Fuel Refinery, 24,000 B/D Capacity . . . Repair Requirements after Blast Overpressure, Four Repair Stages: Complete Processing Refinery, 194,000 B/D Capacity ......... ........................ .... Repair Requirements after Blast Overprossure, Four Repair Stages: Asphalt Refinery, 12,000 B/D Capacity ...... Repair Requirements after Blast Overpressure, Four Repair Stages: Asphalt Refinery, 14,000 B/) Capacity ..... ix
152
- 2 - 3 - 4
-
5 6
156
D- 1
-
3 4
5 6
nn_
_nn_
_nn
D- 7
Repair Requireents after Blast Overpressure, Four Repair Stages: Asphalt and Lube Winery, 1,000 8/0 Capacity . . . . . . . . . . . . . . . . . . . . . . . Repair Requiremats after Blast Overpressure, Four Repair . .. Stages: Lube Refinery, 4,000 B/T Capacity . . Repair Requirements after Blast Overpreasure, Four Repair Stages: Lube Refinery, 27,000 B/D Capacity ......
. a - 9
f
x
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IN'rDUCTION
The U.S. petroleum refining industry is regarded as critical to the continued national viability. lau. refining "pa-ctty is In the event of damage by attack, petrowith em-
phamis on restoration of a petroleus refining level required for that viability. To plan the recovery of the petroleum refining industry, it
is essential to be able to estimate (1) the extent of damage by blast overpressure levels, (2) the capability of individual reftneries to produce products as they stand or with increments of repair effort, and (3) the repair effort needed.
Objective The overall purpose of this study was to describe individual U.S. refineries and their normal modes of operation and derive a mana for estimating refinery production capability and the repair effort needed after exposure to selected blast overpressures. Specifically, this study was aimed at developing a means for esti-
mating the capability of refinerias to produce petroleum products after exposure to blast: * * * a o With no repair After partial repair After full repair By product group By overpressure level
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Scope_ and Meod
The U.S. petroleum refining industry is =ade up of 267 refineriem Over 100
_ _
which process more than 200 different types of crude oils.
individual refining processes, and at least 50-100 types of equipment are used by these refineries to produce well over 1,000 different products. Analysis and grouping of the pertinent factors related to these aspects of the U.S. petroleum refining industry represented a major effort in this study. To develop a procedure for estimating production
capabilities and repair requirements after a nuclear attack, it was necessary to bring industry descriptors down to a meaningful number. These reductions are described below. The 267 refineries are represented by six types: - Large fuel*
- Small fuel*
- Complete processing
- Asphalt
6 percent of U.S.
capacity
The 200+ crude oils are represented by three major types of crude oil from the largest producing oil fields and three specialty crude oils:
Largest
- 10'-15' API asphaltic 10-150 API asphaltic and lube API lube Specialty I
- 30-45
Large fuel and small fuel refineries are differentiated by included processes. 2
@ The more than 100 individual refining processes are represented ny the 16 most used a The 50-100 types of equipmnt within processes are represented by 25 items most vital to process operation, most susceptible to blast damage, and requiring largest labor input for repair * The 1,000+ products are represented by seven groups, aorerding to common characteristics The reduction process is summarized graphically in Figure 1.
INFUIT
PRiOEU
REULT
CRUDE OILS
REFINERIES
3 M1144"
6 Tyes
PROCESSES 100+
16 MOM Used
BLAST EFFECTS
EOUIPMENT -10O
PRODUCTS low0+
OUMP U
Ra~ee
26 It tm
FIGURE 1
To abstract the petroleum refining industry to this extent, of course necessary to make many simplifying assumptions. pointed out throughout the report, where appropriate.
it
was
These are
The data used in this study reflect the most recent Information available. The topics addressed are described below.
Processing
The petroleum processing characteristics of CONUS crude oil refineries are considered. A representative "norma crude oil and alterna-
tive crude oils for processing are selected on the basis of production records and refining characteristics. Refineries in Alaska, Hawaii, U.S. protectorates, or areas contiguous to the United States are Omitted. These latter areas could prove to
Blast Effects
Levels of refinery damage are characterized in terms of blast overpressure. This damage mechanism is better understood than other damage d
mechanisms and, in addition, overpressure provides a direct link with the nuclear environment. Although other damage mechonisms of wind, dhermal ef-
fects, electromagnetic pulse, or the secondary effects of debris-missile or fire are recognized to be important, their coverage is beyond the scope of this study. Repair Requirements The analysis Is based on the major requirementi for the rebuilding of the essential parts of a petroleum refinery after debris has been cleared and the area determined safe for repair work. Major requirements include
labor of reconstruction, principal skills or crafts, and corresponding needs for equipment and supplies. Essential parts of a refinery Include
Capacities and Yields Accepted abbreviated methods l are used in estimating refining ca-
pacities and product yields from selected crude oils after various blast overpressures. The capacities and yields are expressed as B/D (barrels
per day) or In terms of initial capacity under conditions of no damage. The capacitlies and yields nd the repair requirements are expressed as
[
F
the Civil Defense Technical Office at Stanford Research Institute. project manager was Richard B. Bothun, Manager, the principal Investigator was Frank E. Walker.
The
provided by Lyle Schump, Rae Wong, and Pamela Kruzic. was under the supervision of George D. Evaluation Department. Hopkins,
Director, Operations
Direction and guidance for this study were provided by Michael Pachuta of OCD. Additional information on refinery components was pro-
vided by Carl A. Trexel, Jr., Senior Industrial Economist and Viona R. Duncan, Research Assistant, both of the Energy and Resources Economics Department.
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Method Developed The study effort was directed toward developing a method for rapidly
estimating to what extent petroleum refineries would be affected in the event of a nuclear attack on the United States. The method developed
enables the user to estimate the repair requirements, and the corresponding production capabilities, of petroleum refineries after blast damage from overpressutes of 0.5, 1, 5, and 10 psi. Thus, it is pos-
sible to predict what a given level of repair effort will buy in terms of petroleum products, when it is known which refinery is hit, and with what overpressure. The estimating method was used during the study to produce the following major conclusions: * After 0.3-0.5 psi, a refinery can produce the same proportion of products but at about 70 percent of the initial capacity. This
reflects the assumption that at this overpressure refinery capacity is directly related to remaining cooling tower capacity. " After 1.0 psi, a refinery temporarily shuts down, but with minor emergency repair to process controls, it can operate at about 50 percent of initial capacity. " After 1.5 psi, a refinery is total', shut down, primarily because of process control damage by roof collapse in each of the numerous individual refining process control rooms. Vulnerability at
higher overpressures is summarized in Section IV. The physical items needed for refinery repair after blast damage are:
0 4
Labor in
terms of man-days
Equipment, by type
&
Material,
by type
Repair labor requirements were developed by study of the average size refinery of each type at each selected overpresaure. The requirements are
shown graphielly in Piguro 2, *# best-fit curves of data from average refineries, indicating a range of man-days for a given initial refinery capacity at a specified overpressure level. This report discusses how the
repair requirements are developed and describes all the elements that are covered. Analysis of conclusions indicates that repair costs calculated
by the method developed are consistent with overall average costs of buildIng new refineries.
Repair Decision After blast damage to petroleum refineries, certain decisions must be made before repairs to restore production are begun. The decisions
will hinge on what products are needed and what repair effort is available. Reclaiming refinery capability for light fuel products such as gasolines, jet fuels, and diesel fuels (most likely to be in demand during a
period of postattack repair) will require decisions in three areas and will will be governed by what products are most needed, meet users' " " " demands. and what minimum grades
The order of repairing refinery processes The stage to which the repair is to be made for the refinery's
Reclaiming refinery capability for producing specialty products, such as asphalts and lubes, will require decisions on where to produce these
5|
?OOL
LVEL
toDo
*2 I
200
REINR
FIGURE 2
LABOR REQUIREMENTS TO RESTORE 100 PER~CENT REFINERY CAPACITY AFTER SPECIFIED BLAST OVERPRESSURE LEVELS
9I
mV
products,
a Fully repair the specialty refinery * Partially repair the specialty refinery, the comparable specialty processing units of fuel, and the complete procasming refineries a RepAir the comparable portion of the lual and the complete proc-
Repair Stage A B
Repair Effort Repair the crude oil topping processing unit Repair processing units that convert heavy petroleum fractions to gasoline-type products
C D
Repair processing units which upgrade gasolines Repair all other processing units producing nonfuels
Using this sequence of repair stages, the reader can refer to Figure 2 (based on average refineries) and determine, for any refinery capacity at a specified level of blast overpreesure, the level of repair effort in man-days that is tion. required to restore the refinery to 100 percent produc-
For example: A 24,000 S/D refinery is expected to require 60,000 to 90,000 man-days of repair labor to return it capacity aLter 10 psi overpressure Also, for any refinery product, by type of refinery, the reader is to 100 percent of initial
given tables and charts from which to determine the amount of a product (as a percent of initial refinery capacity) .0 that can be produced after
For example:
Before blast damage, gasoline constitutes 50 percent of initial total products from a small fuel refinery. After 10 pal
Cumulative
Repair Stage A B C D Repair Effort, Man-Days 28,000 61,000 76,000 77,000 Percent of Initial Total Products 15% 29 40 50
0asoline Production
Percent of Initial Oasoline Production 30% 58 80 100
0-3-OS
t.f, t[k1. ~
tot Ia too,, No
-. 3
I
I
to
FIGURE 3 IN
AT SELECTEC
-00060
:-A
:TA1 AI
REFINERY
411
MPfIk
fRV~kATA0
-1P
11
OU
This means that, for any refinery type, an eatiAtor can simply calculate the ratio of the individual repair stage to the cumulative stage for the average sixe refinery of a particular type, repair
to the repair requirement estimated for repair to 100 percent capability (total of Repair Stages A, B, C, and D) of that refinery size, and derive repair requirements for the other repair stages. a simple exaaple, below. This is illustrated by
Given:
Repair Stage A = 286,000 man-days Repair to 100 percent capacity (A+1 C+D)
77,000 man-days
Ratio
Then,
A.B4C+D
-A
0.36
90,000 B/D small fuel refinery Repair to 100 percent capacity = 285,000 to 335,000 man-days (A+84C+D)
(given above)
0.36 X 285,000 and 335,000 = 103,000 to 120,000 mandays for Repair Stage A
Each refinery has its own "normal" input of crude oil. an attack, conditions at producing oil 12 fields or in
Following
the transportation
fineries is considered to be one of the three "major" U.S. crude oil types; "normal" input to specialty refineries is considered to be one
ing a refinery with one of the other two of the throe major U.S. crude
oil typea rather thaa with what this study judged to be that refinery's
normal" supply of crude oil illustrated by the following example: A 24,000 B/D small fuel refinery, after 10 psi overpressure, with its normal crude oil and alternative crude oils has the production capability shown below,
Total Production as Percent of Initial Capacity Repair Stage A B C D Normal Crude Oil 44 62 79 100 Alternative Crude Oils 25-28% 28-33 31-37 33-42
Summary of Results The method for estimating production capabilities and requirements of refineries after a nuclear attack is sumarized in Tables 1, 2, adn
available when the refinery Is undamaged (0 psi), and at two levels of low overpressure: the range of 0.3-0.5 psi, with no repair effort, and
1 ppi, with only emergency repairs to the crude topping unit. can be used for any size refinery of the type specified; it
Table 1
gives the
normal product mix and shows the immediate effect of damage in the low overpressure ranges, where refineries are still operable.
13
80 m.s
FS
.-
..
4~4Pe
400
~~
3a
r4
Vlot
VU
4'0
f4
too.~ m
r4
in m * Me.F04
ko 4 P4
r04
*.
4 .
PO4
P4
00
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14
14
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ini W)W
4 -
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44
151
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14 m
AM
4t4N
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<Mop
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aI
At overpressure# of 1.5 psi or greater, repair to refineries beeomes necessary for them to operate, Table 2 gives product percentages after
each of the four repair stages for an average size refinery of each type, thus showing the incremental production that each repair stage affords. Table 3 gives the man-days of repair effort required at each repair
stage and for each level of overpressure for an average size refinery
of each type,
The only data the estimator has to supply are readily available from industry published periodicals, journals, or reference material:a " " Refiaery type and initial capacity in B/D Type of crude oil used, including both the "normal" crude oil supply and an alternative (supplied in the report) It is recoonized that in a postattack environment the relative demand for individual products will not be the saw as before an attack. Because
refining processes produce a combination of products, a relatively high demand for one product creates a surplus of "other" products. Management
and planning must consider uses for, or ways to dispose of, these other surplus products. For example, kerosene and diesel type products normally In a postattack condition
if the demand for gasoline and residual fuel rises so that the demand for kerosene and diesel products drops to one-fourth of the total products, a surplus of kerosene and diesel equivalent to one-twelfth of the total products would occur. Even with reduced total products of 6 million bar-
rels per day (slightly more than 50 percent of current production) this represents a surplus of 1/12X 6,000,000 . 500,000 B/D. The surplus prodA few potential
products, reprocessing of surplus products to make required products, or re-injecting surplus products into underground storage.
17I
17
inn ........nn. n
III
IMMDSTRY DESCRIPMRS~
In the United States today there are 267 crude oil refineriesa'" which use many different processes and modifications of these processes. They refine crude oil, or mixtures of crude cils, from at least 200 different oil fields.2 The product markets they serve are as varied as the
U.S. economy is diversified, As a result of these factors, no two refineries are exactly alike. There are, however, some overall similarities. The contribution of this
study is in anslyzing the components of the U.S. petroleum refining industry, abstracting the similarities, as3embling representative types to make it possible to apply estimating factors and carrying out the calcuThis section details the bases and as-
sumptions used to arrive at the initial production capabilities in the industry. This study approaches the analysis from the standpoint that the effect of nuclear blast on refineries is similar for similar types of refineries and that these effects can be related to refinery type and capacity. In Simplifying assumptions are made and relationships are developed areas:
the following 6 * *
19
rA
/7
a particular type of crude oil into salable products that meet the qualf:
In general,
changing the structure of those parts under various conditions of temPuerture and pressure (using catalysa wheie necessary), and recombining
and treating those parts with chemicals and additives to meet a product isix demand, Many of the procm4ses used to separate the crude arc fairly standard throughout the industry. oil into its parts
Normally,
the separatlon
boil above a given temperature, at a particular pressure, are separated from those that boil below that temperature at that pressuze. Sequential
initial processing steps and in the preparation of products intermediate to structural change. Refinery processes and equipment are chosen, sized, arranged, and interrelated according to the crude oil that is available and the prod.. uct market that the refinery serves. has postulated an average refinery. For each refinery type, he author
equipment sized to operate at capacity and produce the product mix representative of that refinery type when using a "normal" crude oil represented by the predominant U.S. crude oil.
It is recognized that, within a particular refinery type, the crude oils input to individual refineries will differ. Some refineries procHowever, it
is assumed that there are compensating differences in the included processing equipment product mixes. to permit refineries It is of one type to produce similar
20
materially change the postttack refinery repair requirements or production capabilities from those shown for the average refinries. Substitution of alterntative crude oils in each of the postulated refineries will influence the product mix, depending on the characteristics of the alternative crude oils ment. Thea result is
and the refinery processing equip-
mix volumes do not coincide with product market demand) and a resultant refinery throughput decrease because of individual process limitations. For example, a refinery specializing in the heavier products, such as
asphalts, also produces gasoline; a refinery that is producing light products (gasoline, kerosene, and diesel) also simultaneously produces higher-boiling fuel oil materials. If the amounts of fuel oil produced
by the latter exceed the demand in that refinery's market area, the overall operation of that refinery is unbalanced: fuel oil will accumu-
late, and eventually storage problems will force the refinery to shut down. Similar problems would occur with light products, if refineries
use alternative crude oils lighter than they are designed to process. For example, the use of a light crude in a rofinery specializing in heavy products, such as asphalt, would create a light products storage problem. To balance its operations, a refinery would have to include
a degree of cracking and related processing to convert enough of the haavier fuel oils into the lighter products to met market demands. Such factors have been taken into consideration in the development and equipping of refineries.
Crude Oils At the well-heads or in the producing oil fields, small amounts of gas and light gasolines are removed from crude oils. The remaining major
portion of the crude oil then goes on to become input to a petroleum refinery. The crude oil that reaches the refinery is still a complex
21
mixture, ranging from light hydrocarbons that can be used in gasoline to the hoaviest hydrocarbons, which can only be used la asphalts., Thd composition of ctrude oil from some
producing fields Is
distinct,
uila
purposes"-
o
4
i"
refining characteristics that require specialited refining processed. However, most of the ctude oilu fvou the producitng fieldt, are btenderl
with similar crude oils from the man* locality during the delivery to a refinery. H imany The characteristics of the blended crude oil stream may in
respects be similar to characteristics of the crude oil that conatitutes the largest field volume in the blend. In this study, the norml crude oil supply to the major portion of petroleum refining compares to the largest voluze of U.S. crude oil pro-
diuced; alternative supply available compares to the next largest volumes produced. In the Gu.f Coast area, crude oils from the largest producing fields
there are fewer large fields, but all the crudes are somewhat heavier than those from the Gulf 20.300 API). (in the range of 10"-40' API, clustering around
separated fields with some moderately heavy (20*-30o API) and some light (30'-40* API) crude ols.9'"'51
6 Publisbed production voluwsn "
from the
fields include about 42 percent of the total U.S. production of crude oil. The percentages from these larSest volume oil fields grouped by
I
I
im mmm m m
!2
~
.-Producing Fields
Gulf Coast area West Coast area Mideont inent area
Oravit
Monte,
AlPT*
10-200
201-30,
4% 4# 2*
30-40"
22% 1 3
40+1
5%
I%t
Total
1%
10%
26%
5%
crude oil production most representative Is that from the Gulf Coast area. This crude oil was selected as being comparable to the "normal"
crude supplied to the largest part of U.S. petroleum refining industry, the fuel and complete processing refineries. Crude oils selected as
being comparable to alternative crude* available to thesc refineries were: 20 " -250 * API West Coast area
The 200-25* API Midcontinent crude (2 percent of U.S. production) was selected over the 306-40" API Midcontinent crude (3 percent of U.S. production) , because, under postattack conditions, the widospread geographical locations of fields in the latter gravity range group could limit the availability of that crude oil to the refineries. These considerations apply principally to the larger refineries, which produce a complete range of products or mainly fuels. Smaller
t In the lo-15
API range.
23
specialty refineries mormalky use only crude oils segregated specifically for their uie. A process similar to that described abkjvo resulted in a
selection of three representative specialty crudo oils, again with the consideration that a crude oil comparable to only one of these would represent that specialty refinery's "nor~l' supply. oils selected were as followa The specialty crude
.in*Coparable
Oil
Usable alternative crude oils for specialty refineries are the tMre largest production crude@ selected for fuel and complete procesing refineries. This Is shown in sumary form as follows:
Crude Oil 30"-40 20*-25" 200-25* lO-10l5 10-15* 300-45* API API API API API API Gulf West Coast Videontinr nt asphaltic asphaltic and lube lube
Asphalt A A A N
Lube A A A
Note:
N - comparable to "normal" crude oil supply, A = comparable to alternative crude oil supply. Underlying the selection of representative types of crude oilm was
the assuaption that in the event that "normal" crude oils were unavailable after an attack, crude oils comparable to the other categories would be available. Because an attack might disrupt a refinery's
24
'normal"
Refinery
Types
of
Refinorls may Uv grouped by simlloriteo in size and In typoe products produced. pee ing units, Similar typos of products imply similar types of and thlb in
prise about 94 percent of the nation's crude oil refining capacity. priamary purpose of the remaining 6 percent is products, asphalt or lubo,
or a combination of these.
and degree of completeness in the line of products. In general, the small refineries include only the simple processes, such as skiming or topping, fuel and asphalt products, and produce many products. of products, ore important. The details necessary for categorizing refineries are available in published trade journalsa The categorization selected for this study In using Nelson's categorization and produce a limited number of type of
Conversely, the large refineries are complex Both characteristics, refinery size and types
system, each refinery's processing characteristics were investigated separately, rather than with refineries grouped by large company ownership. Peacetime operations by large multireftnery companies frequently
include shipments of intermediate or partially finished oil products between owned refineries. cease, eries. In the event of attack, these shipments may
changing somwhat the processing characteristics of some refinFor this reason, the categorization used in this study, reflecting
25
I
conditions after blast daae, may differ slightly from the usual peace-
time categorization.
categories that give recognition to both the types of products and the
refinery size:
# Large fuel
0 small fuel
# Complete processing
, Aap ul1
SAsphalt and lube a Luba This grouping reflects the use of particular refining processes in the manufacture of particular products. In developing the six categories,
each refiuery, with its production capacities, is iduntifled according to five types of processes in combinations.
* Alkylation (manufacture of aviation gasolines)
* Polymerization (manufacture of gasolines from light gases) a Lube products * Coke * Asphalt Table 4 summarizes the six refinery types by combinations of process types, and details the capacities, number of refineries, and average capacity for each type. All large fuel refineries include alkylation processing, while conbinations of the other four selected processes are fairly well distributed. The large fuel refineries account for the largest part of U.S. refining-about one-half of the total U.S. capacity--but this category includes Capacity of the
large fuel refineries averages 78,000 B/D, with the largest capacity at 241,000 B/D and the smallest at 36,000 B/D. 26
W -
.2 .4 .O .0.2 .
**27
About one-half of the number of small fuel refineries average only ab f: 5,400 B/D capacity and do not Include any of the five major re'ig proceaes listed above.
Most of the other half of the small fuel The total number of
ies, but the total small fuel capacity is only one-fourth of the total U.S. capacity. The average capacity of the small fuel refineries approxi-
mates 24,000 B/D, with a capacity range from 185,000 B/D to 700 B/D. In the complete processing refinery category, processing Is fairly evenly distributed among the combinations of the five selected processes. Capacity approximates one-fifth of total U.S. capacity and is contained in only 12 refineries--less than 5 percent of the total number of U.S. refinerivs. 194,000 B/D, The average capacity of this type of refinery is about with a range from 419,000 to 34,000 B/D.
The remaining three types of refineries include the small specialty refineries: asphalt, asphalt and lube, and lube. None of them have
alkylation processing, but each has either asphalt or lube processing, or' both, depending on their primary product line. Capacities of the
three types together comprise only 6 percent of the U.S. total refining capacity. Capacities range from a high of 35,000 B/D to a low of less
Processing Within the refinery, the crude oil is fractionated into parts, the parts processed to change fractionated further, ket demand. rapidly, their structures, and the resulting products
recombined,
Technology in
the structure-change
28
I I !II
!I
. L.
tails the 16 process types, This study considers that the processing unit in major use in eoach type of atructure-change Is represents ive of that protess. For exaaple,
Orthoflow Fluid catalytic oracking is seloctod as representative of all catalytic cracking. Table 5 shows both the choice of the individual
process within each process type and the index of capacity of each of these 16 processes, in terms of crude topping capacity for each of the six refinery categories. Because sequential processing, racycling, and necessary in normal
refining operations, the total of the processing unit capanity indices exceeds 100 for all refineries. The sequences and relative capacities (capacity indices) of processes are illustrated in Figure 4, a simplified flow diagram of a conplete processing type of refinery. This shows the respective locations
and capacities of the principal types of processes in the overall refining process flow.
Equipment The study took into consideration that, ideally, all equipment in a petroleum refinery is needed during the normal day-to-day operations. However, emergency refining operations, such as could exist in a postattack period, may be performed with some pieces of equipment out of service. To estimate accurately both a refinery's postattack production
capability and repair requirement, it is essential to know three factors: the operational criticality, the blast vulnerability, and the repair requirements for each piece of equipment in each refining process.
29
41
141
bC
10
CO I%
41
.4
r4
44A
la
~.i ~
30
TRAT NO
'All
1
LYI4SNIC
04
ZATW
am "
P,.m~~~~T
*Ud
mo
uwUe
or w
0.RCSECPAIIS ROUT:CMLT
40
To~31
O;prational Coi
of each piece of equipment affects the production capability of the corresponding process unit and of tho refinery. The equipmnt whose re-
ducad or elisinsted operation causes the greatest degradation of refinery production capability is o Blast Vulnerability For the equipment that is critical to refining operations, it is aloo necessary to know its vulnerability to overpressure. Information most concern.
on both the overpressure level that causes damage and the extent of the dansge is needed. The equipment that is extensively damaged at low
Repair Rtequirements
For the equipment that is both critical to refining operations, and vulnerable to blast overpressure# it is necessary to know what is required to repair and restore It to operation, Emphasis is placed on the
r,
Selection of Itoms
.1quipent
The refinery control rooms are examples of equipment of concern in all three categories, is Equipment that may be critical to low overpressure, is to operation but
relatively invulnerable
tively small amunt of repair effort, these are heat excheangors and pumps.
of less concern.
32
is
eomparable
to that used in the chemical processes,) Twenty-five repromentative items of equipment applicable to the various refinery processing units were moloetad on the following bases: 9 Criticality of equipamnt to process unit operation # Vulnerability of equipent to blast damage * Noeaity for a large amount of labor and multiple skills to repair the equipment Table 6 details the selected items of equipment and indicates their inclusion in the 15 types of processing units. Although a particular piece of equipment performs a specific function regardless of its location in a process unit or its inclusion in a particular refinery category, its size and therefore its reclamation requirement is a direct function of both the processing requirement and refinery capacity. Each of the included pieces of equipment arc indiCal-
culation methods and bases of equipment sizing are detailed in Appendix A. Products Equipment developed in today's industry needs specialized fuel and lubricant products. Those specialized needs designate characteristics,
requirements, or specifications for petroleum products, so the equipment can meet performance standards considered to be normal or acceptable. As a result, the total number of petroleum products, fied by specification, is well over 1,000. However, separately identimany large groups
of products are made in the same kinds of processing units and serve similar markets with only slight differences in specifications.
33
~~ bt$
XW w W N A
) AN
.4 4 P P N
.~tqJAOUItO1
D U#4
qu
.10"IN
.4
.QNa1J1~41
OiNNN
a WOND
Wal
44
soil Quo
40
bt1T AN bc
Ja;qjp
bc x
P( .4
mN mUNmN
N4
$0"OU00 Jamol
:gag&~ UTIOCI
NNN N
xNN N 34 10*v xN
b cWxm)Cxx0 XN
4xxA
NN3.
UA N
b N4
0 .4
.4 41
46.
U. 1A
Q*1
*UO
34
This study asxu*ed that all product* can be grouped into seven cutogories,
*
a
oil
Asphalt Coke
a 0
Gasoline includes all ty"%of motor and aviation gasolines, sene includes napthas, solvents, and jet fuels. of fuel for diesel use. oils,
Kero-
Fuel oil includes all types of residual fuels for both stationary Asphalt includes roofing asphalt Coke is used primarily for fuel in the altmzinum industry, and for
boiler and seagoing vessel boiler us*. and all types of paving and road oils. for stationary boilers, for electrodes barbecue briquettes.
Product specifications cannot be met in postattack production quantitles required using simple "batch-still" or simple "pipe-still" distillation equipment. Modern refining equipment and methcds must be available.
Validity of Industry Decriptors Wfore attempting to estimate production after damage and repair effort, tive descriptors chosen for the petroleum refining Industry were tested now stands. In total, the
selected descriptors give results that are representative of U.S. petroleum refining. The designated types of refineries, their respective processing
units and pieces of equipment--weighted by the relative capacities of these types in the United States, and using the "normal" crude oils sele-ted for each refinery type--were analyzed by the accepted abbreviated methods of estimating production, by product. This yielded a calculated product mix production, as shown by the follod-
35
calculdu
of
mines Data4
tureau
_Product
Gasoline Kerosene and diesel
Yield
_ < .. M,)
40% 30
44% 20
Lub6
Fuel oil Asphalt
2
12 a
84
7 4
Coke
3 100%
24
Other*
Total
6
100%
Inclusion of still gas with fuel oil in the abbreviated calculation method accounts for the only large discrepancy. separately, under "Other." In some instances, it may be desirable to estimate postattack production capabilities of individual refineries whose crude oil and processing cqipment differ appreciably from the averages selected. On the Bureau of Mines data show this
4
basis that all refineries of one type produce similar product mlixs, product changes resulting from change of crude oil characteristics (I.e., degrees API gravity) may be roughly approximated by applying ratios derived from the average refinery of that type. This is illustrated by
gasoline production capabilities of a large fuel type refinery with change of crude oil: Crude Oil, Gasoline Production,
API Gravity
* Noral" Alternative Approximate decrease 300-40" 20*-25* 120
Undamaged (%
54% 8-10 44 t
finished products. limited capacity of fuel oil equipment and proct Large decrease reflects essing equipment used for converting heavy oils to lighter products.
36
Than, tor a particular large fuel refinery that usually is supplied with a crge oil of '"1" dsgrees API and wut be supplied with alternative crude oil of "1"
-
-10
With Initial gasoline productic.n capability at 54 percent, the reduced production using the alternative crude oil of approximate 54 X (1 - 0.7) = 16%
-
Similar approximations may be made for other products. In this illustration the large decrease of gasoline with use of a heavier crude oil is bused on the refinery Initially having all processing With
units sized to operate at full capacity with the "normal" crude. heavier crudes, capacity.
heavy oil processing capacity of course would not drop as for as the 16 percent. study. The deterainatlon of the decrease would require further
S371
I
IV HFIflRY VUJRMILITY The vulnerability of petroleum refinery equipment to blast domeg e
drawn Zr published vourcoa,8# 1 0 indicates that cooling towers, control rooms, fired heaters. and tanks--essential items in nearly all types of petrolaum processing--are susceptible to blast damage at low overpressures. Cooling Tower A cooling tower is the essential part of a water cooling system.
-I
Cooled water from a l.rge basin or reservoir at the foot of a cooling tower is pumped to the individual refinery processing units, cools various hydrocarbon streams in beat exchangers. is where it
water returns to the top of the cooling tower, it sprayed over baffles. Atmospheric evaporation,
convection air currents or with forced draft fans, cool the water as It drains back to the basin or reservoir. Characteristically, thuse water cooling towers are lightweight. To
function, they must have ntmerous water and air flow baffles with sufficient open space for large quantities of air to enter, exaust. flow through, and
The only strength required by such a tower, other then that is that needed to support its
baffles to properly channel air flows and water flows, piping to return the warmed water to the top, distribute it, fans.
1
,11 ,la
III
Construction materials here must withstand a constant war moist atmospheric condition.
and
Published sourcesOPIO indicate that those cooling towers are susceptiblo to blast damage at about 0.3-0.5 psi overpressuro. A large
cooling tower 90 ft wide, 76 ft high, and 325 ft loug is damaged at about 0.3 psi. At this uverpressure, the corrugated asbestos louvers
on the windward side will shatter and their fragments will be blown into the interstices of the tower, with little or no damage to the internal parts of the structure. A small cooling tower of three cells, each
20 ft wide, 20 ft long, and 15 ft high, is damaged at about 0.5 psi to 1.0 psi, 10 when corrugated asbestos louvers on the blast-loaded side shatter and are blown into the interstices of the tower; probability of failure is I percent at 0.5 psi, 50 percent at 0.75 psi, and 99 percent at 1.0 psi. For this study, the outer louvers were assumed to break at about
0.3 to 0.5 psi overpressure, because petroleum refineries normally use large cooling towers. The loss of the louvers decreases the efficiency
of the tower to about 70 percent but does not completely shut down the
refinery.
Higher overpressures result in greater damage. At about 1.5 psi
overpressure, approximately 25 percent of the interior baffles are destroyed, 10 reducing cooling tower efficiency to about 50 percent.
9
At
Before rebuilding, water could temporarily be cooled on an emergency basis, if other refinery equipment still operable required cool water, by spraying the circulating warmed water over the surface of the collecting basin or on thm mass of debris that may remain. This would accomp-
40
,o
A i
Controls
The electrical controls of a processing unit (manual switches and remote-operated electrical switches for motor operated equipment) are a part of its control system. These controls, or switchgear, are cherecteristically housed in rooms with structural tool roofs. Published datall
indicate that the atool type roofs of switchgear rooms collapse at 1,0 psi, causing damage to the switchgear. In the central instrument control room are the various instruments required for adequate indication and control of process conditions. Characteristically, these instruments are glass-fronted and some may contain jewel-bearing wheatstone bridge galvanometers. A low overpres-
sure level of about 0.5 psi will break the glass fronts and possibly damage the jewel-bearing parts, rendering the instruments unusable. The instrument control equipment of a process unit is normally housed in rooms with either a structural steel roof or a precast concrete roof. This study assumed that the steel roof is used on the
older, less expensive, and less complex process units, i.e., the crude topping, vacuum flaahing, light oil treating, and asphalt process units. Published data9 indicate that structural steel roofs on instrument control rooms survive a 1.0 psi overpressure because outer windows have broken, relieving the roof pressure. However, it was assumed that instru-
ments are damaged from flying shattered glass particles at 1.0 psi. The concrete roof is found in instrument control rooms in complex process units or in process units requiring "double-dock" structures. Published data9 indicate that control rooms with concrete roofs suffer frame deformation at 1.0 psi and that the roofs of all control rooms collapse at 1.5 psi overpressure.
41
Control systems, from the instrument to the equipment that is controlled, normally consist of preopure-controlled pnou.ratic sysWOO or low energy electrical systems. The pneumatic systems are susceptible to the electrical systems are us-
Those conditions of
instrument damago can be expected after collapse of the control room roof. Thus, it is considered that at 1.0 psi the crude topping, vacuum flashing, light Jtl treating, and asphalt proeessing units would bu shut down because of damage to their control rooms. It is recognized that
emphasis would be placed on repair of the crude topping unit sufficiently to permit production of at least some products. Because the crude topping
process is moderately simple in operation, it can operate to some degree with partial manual control. The author has assumed that sufficient
emergency repair could be made to the crude topping unit to permit it to operate at 50 percent of initial capacity. The vacuum flashing, light oil treating, and asphalt processes would remain shut down until scheduled postattack repair could be made. Until
these units are repaired, the fuels, complete processing, md lube refineries could not operate at more than 50 percent of initial capacity; some products do not meet normal specifications. However, the asphalt
and asphalt and lube refineries suffer greater capacity reduction because the process units of their principal product, asphalt, are Ehut down. At 1.5 psi overpressure, all refinery processing is shut dow cause of damage to -,ntral systems. be-
42
i,
Fired loater The application of hoot in petroleum processing is primarily by means of a tirad heater. Characteristically, this is an insulated brickalong its inner surfaces. 1
'
1e
At
about 2.0 pai overpreasure, the insulated brickwork breaks and pieces fall to th4 buttom of the box, dsmgtng th@ burners and redirecting the flow of heat in the fire box.9 This allows excessive channeling of hot
1lu* ganes to one part of the firebox, with resultant overheating and equipment failure. after 2.11 psi. It is assumed that tLe fired heater is unusable
Tanks The fourth item of refinery equipmrnt that suffers damage at low blast overpressure is tankage, for storage of crude oil, products, and finished products. Adequate intermediate
to maintaining proper relative throughputs among processing units within a refinery. pressure. Blast damage to tanks occurc over a wide range of overHowever, the damage effects that could stop refining opera-
tions occur at overpressures above 1.5 psi, where operations are already stopped because of control house roof collapse. The roofs of cone roof tanks collapso tank after about 1 psi overpressure,9 and sink to the bottom of the
although the tank may still be used For either a cone roof or a
floating roof type of tank, the overpressure level that will cause damage that stops storage operation will vary with the relative amount o
0 liquid in the tank. 9 . 1
lift a half-filled tank, while about 6.5 psi overpressure will rupture and uplift a tan)4 0.9 filled. Under normal operating conditions, reThus, tankage is con-
43
Based on the above, the pattern of continued production capability after low overprvosure is as follows:
of Initial Capacity
Fuel,
Complete Procansing Overpressure <0.3 0.3-0.5 Cooling tower, glass-fronted Instruments 1.0 Control instruments and switchgear All processes, be50 Daswo To and Lube Refinorien 100% 70
15-22
1.5
cause of damage to
control rooms
Figure 5 suimarixes the complete range of blast dainnge effects from 0.3 to 20 psi, drawn from published literaturo9* 1 0 for each of the se-
44
44ji46 h a d A
44)
~;i
-Ir
ijh~i'ii
~I
-
Iij
--.--
of
1
w
a*
00
wU
45
REFINERY IEPAIR
After a refinery is subjected to blast overpressures of 1.5 psi or greater, there will be equipment to be repaired in many process units; even under normal conditions, the magnituda o repair effort would be
such that only a few proceus units could be repaired simultaneously. Thus, it cart b assumed that the repair of process units will take place Selection of the sequence of refining unit repair
in sequential stages.
will be determined by which products to produce and in what volume, or conversely, the selection of the sequence will determine producto, volumes, and quality of product. This study selected the repair sequence according to the logic that: * It is aost important to restore enough operating capability to produce some engine fuels--gasoline, kerosene (includinb -t
fuels), and diesel--regardlems of individual product quality. * Next in importance is to increase the volume of those fuels. * Next in importance is to improve fuel quality. * Last in importance is the production of nonfuels. Repair Stages On this basis, the repair sequence selected consists essentially of four major stages: Repair Stage A - Repair the crude topping unit Repair Stage B - Repair the processing units used in cracking processes Repair Stage C - Repair the processing units used in upgrading products Repair Stage D - Repair all other processing units 47
Thin sequence applies principally to fuwls and complete processing rofineries. In the postattack period tere will be some need for lubc aid
asphalt products, oven though their volumes are expected to be small with respect to the demand for fuels. To permit production of tuese, the re-
pair of specialty refineries differs from the nequonce above enough for specialty products to be produced in conJunction w!th whstevr fuels these refinerio can produce.
The sequence of proceasing unit repair for each refinery type is summarized in Table 7.
Oue underlying principle used in establishing vatimating factors for repair is that the repair effort will be completed only to the degree necessary to permit refining unit operation, but that for the particular equipment repaired, the repair must be complete. The repaired equipment
or system would be virtually identical to the proattack system condition, and all equipment that forms a part of the process unit's operation must be repaired before that process unit can operate. paired procosA unit goes back on stream, (When a completely re-
increment of product processed in this unit.) While following this principle means complete reclamation of most parts of the repaired refining process unit (fired beaters, control houses.
fractionation columns, and so forth), it excludes repair not mecesery to refining unit operation at that time (spare equipment, unneeded steel structural work, paintiug, and the like). Repair requirements data were drawn from published sources.9 10 In
48
I..K
da
ko
cd U4 U4
u
96
4,
raw stooko nf gasolinv, kerosene, diesel, and residual products at the percentages appropriate to the crude oil are sized to process supply. All procesuing unit With a oJor changw in
crude oil supply, one of the subsequent processing units may b-osm the
finery production capability can be limited by the capacity of one particular proccsing unit. Further, if the capacity of that processing effects, total refinery capability
A 185,000 0/0 refinery may be designed to operate on a crude oil that normally has a maximum of 15 percent of raw product, The processing units for prodtct P are sited accordingly at 0.15 X 165,000 = 24,750 BiD. If the crude oil is changed to P.
one with 45 percent of P, the processing of P is still limited to 24,750 B/D. 0.45 This limits crude oil throughput to 24.750/
165,GO0 B/D. If the capacity of the process units for product P have been reduced to one-half of normal (from blast damage), oil the crude
Table 8 compares, at each repair stage, the product yields from the six selected types of refineries, using the selected tnormal" crude oils and the product yields that could be expected from crude oils comparable to the selected alternative crude oils. 50
"'.
00
in
-4
W~ 4
444
4)
4m -4
Itot4
In,
aD' m 0V r )C -44
-,
... to
4J
r'to
41
40
M IA
-4
4
44
1.4-4
..
ot
04
04P4
0404P-4
-440
9 4' N
4'
'
4 v
04'
144 -4
4 4 4.0
f*U M
404 U
( 4'
-4 0 00 0
~4 ~
* 4 0
rA V3 C~~' -
~
.4
..
'
ur
41
&
UA'
'
The limits placed on production capability by the use of alternative crude oils are pronounced in the asphalt and the asphalt and lube refinerios. This limited capability refle,,ts the emphasis on only light fuel
products coupled with the volume limitatiors of repaired and r perable processes, as well as the difference in crude oil supply. The refinery Z
normally uses heavy crude oils to produce mainly asphalt-type products and has limited process capacity to produce gasoline. In Repair Stage A, the crude topping process unit Is repaired and some light fuel products can be produced, If the refinery must time ian
alternative crude oil that contains a large percentage of a gasolinetype raw product, the refinery throughput is limited by the gasoline processing capacity. As successive repair stages B, C, and D are com-
pleted, more of the crude oil is converted into a gasoline-type product. However, the gasoline processing units remain the limiting capacity factor, so that the resultant total throughput never achieves production levels equalling initial refinery capacity. If gasoline could be blended into kerosene and diesel, the throughput would be expected to increase with increased repair completed. The
Quality of Products After Repair Products that can be produced after the early stages (A and B) of
refinery repair will not necessarily be "on-grade" (meet today's specifications). Under postattack conditions after low overpressure (0.3-
0.5 psi), it is assumed that refineries can operate with balanced operating conditions: capacities of process units within a refinery re-
main proportional to preattack capacities, and products receive adequate processing to reet specificttions.
52
light oil
capacity.
After 1.5 psi or higher overproasutres, however, all refinery processing units are shut down, Making repairs in sequential stages tempo. It is assumed that in the
early repair stages, raw gasoline stock (and other fuel stocks) can be produced, but other process units to upgrade the gasoline and keep it "on-grade" are temporarily inoperable. As a result, gAsoline (and other fuels) are expected tv be of lower quality than that normally produced, This study took into considwration that in the postattack period the short term operability of engines is of much importance. While the
light oil treating process units are shut down, fuel specifications cannot be met, so that short term operation of engines must take precedence over possible degradation of engine life over the long term. The study also recognized that engines can operate on fuels other than those for which they were designed. Tests have been made of this,
and in many instances results have been satisfactory with the acceptance of a decreased efficiency and a potential increase of maintenance. The
degree of decreased efficiency and the degree of increased maintenance that could be tolerated would reflect the urgency of the need for the work of the engines and for the refineries' production. Investigation
of these trade-offs is beyond the scope of this study, so a refinery product is considered usable as long as it is within its normal boiling range.
I
153
Labor
Model Formulation
Th. labor effort required to repair a particular piece of equipoent after blast damiage in, in general, a function of both the complexity of
that equipment and its vulnerability to damage, an wall as a function of its size and type. To adequately relate the required repair labor to the
equipment condition after blast overproesure, the labor Is expressed as a function of: " Overpressure level " Lowest overpressure level to cause equipment damage " Maximum labor to ccrmpletely repair the equipment " Equipment site For the purpose of estimating labor requirements, a mathematical
model developed by URS Systems Corporation was selected.'
This model
combines a basic model or mathematical function describing the repair labor required for a particular size of equiptaent with a scaling model describing the effects o:_ ;quipment size. The basic model is:
R =L where
.'.
R = repair effort (man-days) I.= maximum repair effort (man-days) p = overpressure (psi) x = lowest overpressure (50 percent probability estimate) at which damage is observed, psi k a constant for given equipment y = a constant for given equipment
The constants k and y give an expression that best fits existing data for repair requirements of each type of equipment. The base of the
1.0
This basic riodol, however, de3critbes the repair effort for only one equipment size. Because a petroleum refinary may have many different-
sited pieces of equipment of the same type, it is necessary to scale the labor requirem6nts to the particular equipment olse. the scaling factor: This is donn with
where
o C C b
a a constant for a given equipment component = capacity or size of equipment component being investigated = capacity or size of equipment component standard a constant for a given equipment component.
The constants m and b are selected for each type of equipment to yield appropriate scaling for types of repair that could change with equipment size (welding a seam on a large or on a small tank), or remain the same without regard to size (replace instrument gauges). At the overpressure
levels at which damage effects change, these constants will change value, The combined model used in this study is:
L R =L
-k (p-x +
bI
where R equipment.
Table 9 lists the seven parameters (L, 3, x, y, m, b, C0 ) for the labor requirement model for each of the selected 25 types of equipment. equipment These are applied to the size characteristics of each piece of to estimate the labor required for repair after blast overpressures of 0.5, 1, 5, and 10 psi.
55
tf
ci
C; a. '0 z * . a.a .0
0. A
-'AMA
Ro
*I
0.--
o0
t.o.#A
a a
e0
-.-
.0 a
005
O0- 0OO
0C4M
00
OC0.0
3 01
16 u
56
on repair requirement, the capacities of the refinery typos--large fuel, asphalt, and lube--were varied and the rovultant ropair roqirenents
Vdwturmined,
The rcsult
and for the three capacity variation# are summarized in Table 10.
results indieate that the initial capacity or size of a refinery in the predominant influence in determining the repair requirement, Refinery
repair needed after blast damage is within a given rango, regardless of the type of refinery. This is illustrated in Figure 6.
An example of the application of the seven parameters (Table 9) to selected refinery equipment is as follows:
Refinery type Refinery capacity Processing unit Equipment Number Volume, each
Small fuel 24,000 B/D Crude topping Fired heaters 2 15,000 cu ft 10 psi
Overpressure
-1.5(10-0.9)1.
10(500
p..
fired heaters.
1[
57
ton
8~
0o
000000
00
'41
too 0~C 00
t a a -
-4
a
s-4N-4~
13
rW
q41tfi
TYPI
CAPACITY, IA*RIJ PER DAY ?1.=00 IO000 24,= t4lo 1,,w 14,ow low OVERPREMUns LEVEL
7o
LAROE FUEL LAN0G FUEL SMALL FUEL COMPLEYE PROCIMING AiPHALT AI4ALT A.PHALT AND LUDE
to ow
LUM LUN
.0
smO -
4w0 -5P6
I*-
400
50
too
15
200
REFINERY CAPACITY IN THOUSANDS Of BARRELS PER DAY FIGURE 6 INDIVIDUAL REFINERY LABOR REQUIREMENTS TO RESTORE 100 PERCENT CAPACITY AFTER SELECTED BLAST OVERPRESSURE LEVELS 59
tJ,
1 '.
refiinry.
light the fact that in that type of relinory, the crude topping unit rIquirei one-third of Doeatts equipwmnt equipment, the total repair effort after 10 pai.
of the differi4
vulnerabilities of dif erent plec*s of in the amount of labor needed to rapair that to reastoro 100 percent capaclevel, is The re-
ity of a refinery is not a linear function of blast ovorpressure However, the amount of labor after a specific overprosure level to the amount of aquipment in a refinery.
roughly proportional
pair labor requirement can be expressed as a range of labor required for a given initial refinery capacity and blast ovarprossuro level. ure 6 illustrates this grephically. Any 24,000 JB/D refinery is For example; require between about Fig-
expected to
60,000 and 90,000 man-days of repair labor after 10 psi overpressure. The range increues with increasing overpreasure. sure levels, At very low overpres-
towers and storage tanks) and the range of repair effort Since specialized equipment in different process units is
damaged at
higher overpressures, there is a wider range of repair effort at any given refinery capacity, depending on the type of refinery and the equipment included. The consistency of the calculated labor requirements may be visualized by comparing them tith new refinery construction costs. rough approximation, the current labor rate is For a
60
On theou
blast is
betwca
tite repoir
cost aftor 10 psi and full reflaury costs Includes design engineering,
qipant damagod but conaidarad not alwalutoly vussntial to joediate
opordtion (I.*., oparv aqulpment), and the cost of the equipment pieces
riot yat damaged at 10 psl ovarprvmoure.
ror ouch piece of ref i1ary vquipsmnt that has been considaed to be
damagd by blest overpresoure, putblithed aource&0110 have detailed the individual craft# or skills that would e entailed, the equipmont that
thoe caft
woldrequire,
Wh~ile thr
conceivable that one craft could quickly learn the techniques of a similar craft to circumvent skill or craft shortages.
and
line.
Group
I
Included Current Crat or Skill Mason, rigger, carpenter Welder, boilermaker, pipefit;tor Crafts for control instruments
, :Mutal
61
V*
t *
VU
ooaI
U,-o
MO
(VA;
~1
1$
l v TO
~cc
C;4
V
-41
cc 4u
w~ -a I
roU
J .~
tA q
44'4
41
.-
62
*-i
& CALCULATED REFINERY REPAIR CC" AFTER 10 PO OVERPRESSURE No. TYPE CAPACITY, BARRELS PER DAY I LAAGE FUEL 7a1000
2
S" --'3 4
*
-
LARG E fL
Ibo0oc0I0
24,00 114*0
14,000 4,000
7 B $100
UE2,0
was
n.o
A .
S7
fI
$1
7
,
4
0
51l
1 FIGURE 7
I
10
100
COST TO RESTORE REFINERIES TO 100 PERCENT CAPACITY AFTER 10 PSI BLAST OVERPRESSURE, COMPARED WITH NEW REFINERY CONSTRUCTION COST
63
.__I:
try repair after the various overpressure levels can be summarized as follows:
Comeents Outer louvers broken Glass fronts broken Structures deformed and "soft" equipment damaged Equipment displaced from foundation
5-10
Equipment relocation
10 and higher
Repair Materials The materials required for repair of refineries are readily classified by type. However, the quantities of materials will vary with the
blast overpressure levels the type of equipment being repaired, and the size of that equipment. The characteristics of equipment (see Appendix A)
are given in dimensions such that the required quantities of materials for repair may be calculated when necessary. For example, the amount of
brick required for a fired heater may be estimated as follows: # * * Simplest configuration- cube of NH" ft on each side Brick wall thickness- 1 ft One internal 'ire-bridgewall, 2 ft thick, 3/4 of wall height
64
"
"
M 6.0 WS
X 4" X 8" I
0.037 cu ft
3
Number of brick
0.037 cu ft
In each instance, the supply points and suppliers of materials may be found in published supplier listings.
14
In the event that equipment is beyond repair, the refinery has the alternatives of: * Cannibalization - the situation of taking repairable equipment from a processing unit that is shut down a Replacement
-
buying new equipment and completely rebuilding the processing units needed
65
I
Cannibalization
The equipment characteristics data (see Appendix A) have been presented in such a way as to make them usable for making connibalization decisions. For example, if it is found necessary to obtain a pump, it is possible to refer to the list of representative equipment of proc-
ease# that are shut down, verify approximate pump size and operational
characteristics, and, with proper authorization, cannlbalix is appropriate. Replacement The suppliers of each of the many types of equipment may be found
4 by reference to published supplier lists.1
one that
suppliers of equipment, there are possible instances in which equipment could be manufactured by companies that are not in that particular line of business, but who have the inherent manufacturing capability. For
example, pressure vessels could be manufactured by shipbuilding companies. In the postattack period, the time lapse between equipment order placement and delivery will be related to both the extent of damage to the supply industry and the use of an appropriate priority procedure. It is conceivable that in spite of some damage to supplier industries, the use of priorities could result in delivery times less than those under normal preattack conditions.
hetypesnof mterials
p The types of materials required for the operation of petroleum re-
fining processes have been identified with the classification of the product with which each is used. This information, together with an
approximation of the number of supply sources, Is summarized in Tablo 12. Sulfur and sulfur dioxide constitute a part of the supplies to nearly all refineries. The characteristics of the remaining supply
material will vary according to the refining processes and crude oils 66
IA
0 0 "0#j IV 0) M4 v D.0 0 0ac4J 4. k w4 " D I 4
a 4
4
4)
m
,.
~4
4J
04 )
4V
4) 0
)4
4J
(A
4'
44
41
4)4
4
.4 v4 tVm4
414)
!4u ... ,. . ae
0u so 0 0 4104 6l
k0
04
06
w
-4
4-
a9
4)0
co 4)
a
4
4
tl
.4J
-a
P4
X m
P4
ao04 P
-A4
-4:54
-4
-4
0. E-4 4 0)
4
C4I
~F-4
P4
.4 .44 L,0
x u
67
used.
Vsrlous strengths or conce.ntrtions of sulfuric acid are used, The inhibitors used
will be determined by the products produced, the processes used, and the crude oils supplied. Catalysts will depend on the processes used and
possibly on royalty or patent agreements. In general, most of the operational supplies can ba obtained from any of several manufacturers, itora. Exceptions are sulfuric acid and inhib-
type gasolines (alkylation process) and in the treatment of the light oils to maintain quality specifications. Shortage of sulfuric acid high octane gasolines could curtail the production of aviation and and reduce the quality of light oil products. Inhibitors are added to the light oil products to retard or limit possible degradation of the products before use. could create product quality problems. Although additives as a group have many suppliers, the gasoline additives TEL (tetra ethyl lead) and ThL (tetra methyl lead), which are used to increase gasoline octane rating, have a limited number of suppliers. Shortage of TEL or MM would reduce the octane rating of gasoShortage of inhibitors
68
ii i
68iii i i
iii
VI
This section describes how to ume the tables and figures presented
to estimate production capability and repair effort in blast-dmaged rofineries. An example is carried through the procedure for illustration. At Watson, California, the Atlantic Richfield refinery receives 1.0 psi blast overpressure. Knowing which refinery is hit, with what overpresaure, the method of estimating production capability and repair effort is: & * a Determine refinery size and type Determine crude oil supply Estimate initial production capability and remaining capability with no repair # Estimate repair requirements by repair stages 9 Estinate production capability by repair stages (Figures 10-15) (Figure 8) (Table 15) (Table 13) (Table 14)
Example:
With the estimation of postattack refinery repair efforts and production capabilities, the necessity for making several decisions before These decisions are dis-
cussed, and bases on which to make the decisions are indicated at appropriate points in the discussion. Determine Refinery Size and Type From published sources, 2 determine the initial capacity and the type of refinery, based on the listed combination of production capabilities from the following five processes (see 'Refinery Types" in Section III):
69
ii
Alkylation
* Polymerization * Lubo
a Coking
a Asphalt ad Gai Jouraal2 shows te oxample refinery to be a 16,0O0
4
The Oil
HAiD refinery with production capacities for: . @ * a Alkylation Polymerisation Coking Asphalt -
available to refineries have been groupod as discussed The "normal" crude oil and alternative crude oils are
a fuel refinery is considered to ue a crude oil comparable to 300-400 API Gulf Coast crude oil as its "normal" supply. Table 14 shows which
alternative crude oils are considered usable for each refinery type,
in the event that crude oil supplies or delivery systems have been diarupted by the nuclear attack. From this table, the "normal" crude oil
supply to the example refinery is seen to be comparable to 30-400 API Gulf crude oil; alternatives are comparable to 200-25* API West Coast and 200-250 API Midcontinent crude oils.
i
n
70
$14
"
W40
0.44
P4 ad
P 4) to
10
I:
41
14 6J
V4 th "40 V4
v4 '".4
4
0 6
0
0.v44
04 0
64'n
0.4
0~ 4.Iu
dc
4.UO "4
tion 111, has been taken into account in Appendix H in calculating refinery partial production capability, both With alternative crude oils and after overpretsurts of 0.3-0. repair. Table 15 aumarizas, for the six refinery types, refinery capacities for no-aal operations at initial cApcity and partial production and 1.0 psi with only minor emergency
capabilities aftor damage from 0.3-0,5 psi and 1.0 psi overpressure, with "normal" and alternutive crude oils. Whether the refinery has its "nor-
mal" supply of crude oil or has to operate on either of the alternative crude oils will be determined by conditions after a nuclear attack. From Table 15, production from the example refinery after 1.0 psi 50 percent of initial capacity with "nor-
mal" crude oil and 15-19 percent of initial capacity with alternative crude oils. By using the product percentages shown in Appendix B, the
Initial Capacity of "Normal" Crude Product Gasoline Kerosene Diesel Lube Percent 54% 15 14 ............. 75 89,100 24,700 23,100
Production Capability after 1.0 psi "Normal" Crude Alternative Crude Percent 26% 8 7 z/5 42,900 13,200 11,600 Percent 4- 6% 2 2- 3 B/D 6,6009,900 3,300 3,3005,000
Fuel oil
Asphalt Coke
13
.... 4
21,500
6,600
7
........ 2
11,600
3,300
7
0- 1
11,600
01,700
Total
100%
165,000
50%
82,600
15-19%
34,80031,400
72
L#A
P4
.4
P4
41
090
V4 x
~I
UO~i'Ii
i
. .......
73
It is possible that a nuclear attack will influence thv crude oil supply. if it it teasaery to supply this example refinery with a
heavior than norual alternative crude oil, the Sasoline production will
decressa. With a crude oil comparable to the selected alternatives, Instead of being
42,90
Planning dacoions regarding the use of rrude oil* the relative need for productu,
38.300 O/D of gasoline would be gained by use of tha light crude oil ever the heavy.
capucity is in
Table D-1 details effort by repair stage for an average This is scaled up to the example re-
78,000 B/iD large fuel refinery. finery size of 165,000 B/D as:
Repair Requirement
in Man-Days
Average Refinery, 78,000 B/D Repair Stage A B C D Cumulative Repair Requiremnt 54,062 97,955 126,238 127,699 Ratio to Full Repair 0.42 0.77 0.99 1.00
Example Refinery, 165,000 B/I) Corresponding Cumulative Repair Requirement 101,000"- 118,000 t 185,000 -216,000 238,000 -277,000 240,000 -280,000
74
ot
40
I
~.I
FIG RE 8CAP~cTv
I3005
AC1TY 6~F~EAENTSF
~PeiA
-100I,~
~Q,~EC,
1 .RFN
11J0E
sot
Ir
etimate Production Capobility by Repair Stage How much production each increment of repair effort will buy can be determined by estimating the production capability for each repair stage.
~This
in done by combining the data of Appendix B and Appendix C. This study assumed that refinery production capability will continue
at the levels achieved with only emergency repair (to units damaged at low overpresaures) until scheduled repair effort is made. Each repair
stage completed will then permit a production increase corresponding to restored production in those process units damaged at higher overpremsures. Table B-1, in Appendix B, indicates that after 1.0 psi overpressure, sufficient emergency repairs can be made to permit production of gasoline equal to 26 percent of the initial refinery capacity, Table C-1 shows that this production capability is not surpassed until Repair Stages A, B, and C have been completed. Combining these data for "normal" crude
oil yields the result: Gasoline Yield as a Percent Repair Stage of Initial Capacity Production After Production Overpressure 1.5 psi* After 1.0 psi
A B
C
13% 22
33
26 %t
26t
33
54
54
1.0 psi.
On this basis, the gasoline production from the example refinery after
76
7
Cumulative
Repair Stage A B C D Repair Effort in Man-Days 101,000-118,000 155,000-216,000 238,000-277,000 240,000-280,000
Gasoline
Production Percent 26% 26 33 54 B/D 42,900 42,900 54,500 89,100
In other words,
will buy an
increment of 2,000-3,000 man-days of repair effort will buy an additional large increment of 34,600 BD (54,500 B/D-89,000 B/D). Similar relation-
ships are developed for kerosene and diesel products and are shown in Figure 9. These form a part of the base of decisions on planning of reBy comparing the product yields resulting from effort ex-
pair effort.
pended on several refineries requiring repair, the estimator may develop a basis for deciding where the least repair effort will gain the maximum quantities of the products needed. This is illustrated by the Figures 10-15 that demonstrate the product yields from "normal" crudes for average-sized refineries of each type after selected overpressures. From these, basic decisions may be made
after it is known which products are needed most and how much labor is
available. * Examples are:
If gasoline is in great demand and sufficient labor is available, completion of repairs through Repair Stage D gives the best results (see Figures 10-12).
If kerosene and diesel are in great demand, it is not advantageous to repair an asphalt, or an asphalt and lube refinery beyond Repair Stage C (see Figures 13 and 14).
If
repair labor is
limited,
77
5 __
GASOLINE 50 70.0
40 O
w 10 0 4 - 11 10D0 000
20
TU3BIE
UE
a
20
0 _. U E. I _ I I I . 1 0 0
REAR 350
AE
so 00 no - 2UN0
4M00 40
20
W0
c0
60a
I 10
I 3w
mm I
50
' IGUR PODUC 3UTI
-0
UNT
STAE I
REA
EPIRSAG
P~
OVRPE3CE FIUR95RDC0IL
FE .0PS N EAREFR.UNAAE ESU AGEFULREIEREP650 ARREAS P0 0.AY CAACT LAG ULRFNR; 78 50 BRESPRDYCPCT
20RPESUE
O)W so -40,000
40
GASOLINE
46,000
t1
1'0
510
10.0 Pw
5001>
~3
20
280.000 20,00W
15,000
10
. 300 '..
. 0
I 400 "
. 40
50
1 ..
,000 0
10 :
40 -
KEROSENETURBINE FUEL
35,000
30 6
320 o 10 w 0.3-60 c10,000
I.
psi
15,000 "
100
0 so 100 16) 200 2 3W 3W 400 4W 50D
DIESEL 40 ",-0 30 -
20.000
cA.
100
150
200
260
30
000
THOUSAND MAN-DAYS (a) (bI UNDAMAGED CO NDITION 70 PERCENT OPERATION AFTER 0.3-0. . I
10
PRODUCT YIELD VERSUS REPAIR EFFORT AT SELECTED BLAST OVERPRESSURES. LARGE FUEL REFINEFY; 78,0010 BARRELS PER DAY CAPACITY
79
M(14
14JMD
20'M
60
1 I
i 6A 1.0000
l000
1 2
)t
KEROANE-
,0 -TURBINE
0
so_ 1
FUEL
-0
Icoco;
-
12000
00
to
20 30W 30
40
50
s!o
70
100
DIESEL
40
10,00
,o.'
0
.. ~o
_ O,,O--REPAIR STAGE 0 I
"10
1o.0 pw
10 O
0
bA
W) W)
40 THOUSAND MAN-DAYS
UNDAMAGED
70 -10
s0
20
1O
RONDITISAC
FIGURE 11
PRODUCT YIELD VERSUS REPAIR EFFORT AT SELECTED BLAST OVERPRESSURES: SMALl FUEL REFINERY; 24,(OX) BARRELS PER DAY CAPACITY (al 80
-i
-ji40
so-GASOLINE
pi0,0I
"A
40 IW.I0.3 -o
30
-so.000
g
60,00
10
0 60
100
I KEROSENE-
20
"
300
5W
00
700
000
0 1000
TURBINE FUEL
'000
60,0 0
2040=O0f
03-05
5.0, ,00
i P.
20.000
100
D I DIESEL 40
2W I
3 00
I
400
I I
GOD I
-
700
I
00
1000
10.000
30
REPAIR STAGE 0
eco0
~-0
100
200
300
(a) Val (cl
400
0o
6o0
700
100
900
0ooo
70 PERCENT OPERATION AFTER 0.3-0.5 pi 50 PERCENT OPERATION AFTER 1.0 pal UNTIL STAGE C REPAIR
FIGURE
12
PRODUCT YIELD VERSUS REPAIR EFFORT AT SELECTED BLAST OVERPRESSURES: COMPLETE PROCESSING REFINERY; 194,000 BARRELS PER DAY CAPACITY 81
r.
GAIOLINI 10 4 - ' ! II lo
iE
2M
W1 1 I1
30
I
40
I
oj-
MNE
- mO
400 -,
10
20
30
40
so
REPAIR STAGI A
to
E-I00
0 ,$
to
THOU
0
AN-OAYS
400
W k)O
0 PERCENT OPERATIONl AFTER P[KfT OKRATW AFTER 1.0P0 UNTIL STAGE A REPAIR
FIGURE 13
82
Il U~AMAGO CONIVI!
ThOUSJEG M*OAY
20
T2I
-
GASOLINE 1
. : I10 ).
20
....
' 26
10
W ~l
.5
1.0
10
100 ow
1,=
.,
0
lo
10
5
o
10
ICT
Is
T T
20
21
2
14 Is tI
5 0IESTTEL 1
11
-0-00-
FIGURE
1F,...S.L,,.
_ __
Is40
00
THOUSA~NDMAN-DAYSA:I
PiREFRTO
14 PROOICT YIELDEN()
AT ELE
DBATOEPESRS
_T
GASOLINE
00
0.
ItO
so
1 0
....
._
les0
1300
osoo
1o
.. I. IS
._ I 30
20 460
--
REPAIR STAGE A
REPAIR STAGU3E S
REPAIR STAGE C -
10 am0 II0
1400
ao I
l30ca-0.3-0. 1.064-
FIGUR 15
20 POUT-
9
EDVRU
STGA N SI ETE I 2
Ioo
SM VRRESR
20
1EN
0 ~ 70
AAED C N0Y
APAITY
Is
ATER
tWJ 70 PERCIENT OPERATION AFTER 1.0 pWUNTIL STAGE S9 REPAIR FIGURE 15 PRODUJCT YIELD VERSUS REPAIR EFFORT AT SELECTED BLAST OVERPRESSURES: LUSE REFINERY; 4,000 BARRELS PER DAY CAPACITY 84
be maoro advantageous not to repair the specialty refineries, but instead to use the repair effort in the fuel and complete proc-
easning refineries.
Assuming gasoline as the product in greatest dond, Figure 13 shuwg ht to reatore an average asphalt refinery to 100 percent of initial capacity after 1.0 psi would require 11,000 mn-days, and an increment of 1,320 B/D of gasoline Would result. Application of the 11,0O0 ton-doys,
instead, to any repair stage for a large fuel refinery, would yle-'d more gssoli~ie, The increments of repair labor and gasoline production caps-
Repair Stage A B C D
Labor in O00's of Man-Days Increment Cumulative 101-118 84- 98 53- 61 2- 3 101-118 185-216 238-277 240-280
Gasoline Production in 000's of B/D Increment Capability 42.9 0. 11.6 34.6 42.9 42.9 54.5 89.1
seen that if the example refinery has repair labor sufficient only to complete stages A, B, and C, it would be advantageous for gasoline supply to apply the 2,000-3,000 man-days of repair labor to the example refinery, instead of to an asphalt refinery. The asphalt refinery gaso-
line would only go up to 1,200 BiD instead of 1,320 B/D, a decrease of 120 B/D (Figure 13). However, the example refinery gasoline would in-
crease by 34,600 B/D (from 54,500 to 89,100 B/D), giving a net gain in gasoline of 34,480 B/D. In general, for the fuel and complete processing refineries, Repair Stages A and B result in distinct increments of gasoline, kerosene, and diesel production. However, when further repair is planned, it should
85
be noted that the combined labor *f Repair Stages C and D makes a significant production increase over that from Repair Stag. C effort alone. This results from the emphasis on light fuCls production (i.e., line). gaso-
I
4
heavy components of crude oils that normally produce fuel oils and as-
phalt are removed from the gaspline producing processes, so that these
processes have a lighter petroleum fraction that can produce a greater amount of gasoline. diesel production. Relationships of this nature may also be developed, as required, using alternative crude oils. It is recognized that many variations of refineries exist. In some Similar relationships are evident for kerosene and
instance, a refinery that is being investigated may vary by a large degree from the average six types considered in this study. In this event,
in Appendix A.
applied to the modified sizes and numbers to yield corrected equipment repair. It is also recognized that the sequence of repair stages and the repair of process units in each stage can vary, depending on which products are in demand in the postattack period, Repair effort has been It Is
necessary for the estimator to recalculate production capabilities with each sequence selected. It is also necessary for the estimator to select
an alternative sequence of repair and calculate the products that could be produced with the operable equipment at each repair stage. The sumDe-
mary of this effort for this study is shown in Appendixes B and C. tails of this effort have not been included.
88
APPendix A
BEQUIPA
Appendix A EQUIPMENT SIZES AND "MBERS The equipment that would be necessary for each processing unit within each type of refinery is detailed in Tables A-1 through A-17. These data are used to develop reproaentative processing units and refinery categories, based on equipment data that reflect known or calculable vulnerability and blast damage reclamation requirements. These equipment data are used in determining refinery vulnerability to low overpressure levels and resultant product capacities and the reclamation requirements and correlated production capacities after higher blast overpressures (see Sections IV and V of the main text). Refinery Equipment Selected items of refinery processing equipment that represent an overall average of that type of equipment in the petroleum refining industry are described in terms of general characteristics. For re-
fineries that include equipment that does not match the average given, the specific comparable characteristics of individual refinery equipment may be substituted. Although a particular type of equipment performs a
specific function regardless of the refinery category, its size and therefore its reclamation requirements are direct functions of the refinery capacity and processing requirements. All pieces of equipment
are individually sized for each processing unit in each refinery category. Individual equipment numbers and sizes for each processing unit Units of size measurement are kept consistent with
89
Although these units of aie in moRm instnces are not the usual ones encountered in petroleum refining, they can be easily converted, if desired.
Control Rom
Ilu some inas ances the control room roofs will be of steel construction that has been calculated to be damaed after 1.0 psi, instead of reinforced concrete construction which has been calculated to collapse after 1.5 psi overpressure. of older refineries, The steel construction is characteristic simpler processing units not or those refineries
f
d
smaller refineries,
where construction was strongly influenced by minimum investment principles. This steel control house roof could be anticipated in the proc-
ess units of the following types of refineries: " " " " Crude oil topping Vacuum flashing Light oil treating Asphalt
Of these, the first process is essential to all processing of crude oil; the second to separation of stocks for aidbarrel and asphalt production and for feed preparation for cracking; the third is essential to all light products being on-grade; and the last is essential only to asphalt and road oil production. Emergency repairs to some of these as needed, Repairs would
be in the above sequence, but only to the extent that they would then match the remaining refinery capacity. The size of a particular processing unit control room is a function of both the capacity and the complexity of the processing unit. Larger
capacity units tend to have a greater number of ana more precise instruMent controls, and more cvmplex units require a greater number of control 90
points.
V where
Ct cu ft (minimum
.
2,000 cu ft)
For each of 16 selected types of proca.ing units, the corresponding values of the complexity "a" are an follows:
Constant "a"
(cu ft
Procssaing Unit Crude topping Thermal cracking Thermal reforming Vis breaking Coking Catalytic cracking Catalytic reforming Polymerization per B/D) 0.374 0.746 0.746 0.746 1.667 0.900 0.746 0.900 Processing Unit A5.ylation Hydrogen treating Vacuum flashing Vacuum distillation Lube and specialties Asphalt Light oil treating Naphthenic lube and specialties Example:
Const.ant "a
(cu ft
per B/D) 1.667 0.900 0.374 0.900 3.122 0.571 0.374
2.565
for a 90,000 B/D crude topping processing unit, control room size = 90,000 BD X 0.374 CU ft B/l = 33,660 cu ft
Fired Heater Many designs of firea heaters are in operation in various refinerieg. In addition to size variations, there are variations in burner location (fLoor, sides, ends, or top); in heat recovery (successive pnsses, steam generation, or waste heat reeovery); and in construction
91
mounted burners was selected as a representative fired heater. volua approximates 0.8 cu ft per 9/D capacity of the heater.
(cu; it)
40,000
30,000 50,000 ,
fuel
Asphalt
Asphalt and lube Lube
20,000
20,000 20,000
In
Fractionation Column (Distillation Towers) Separation of petroleum into two or more parts is accouplished in fractionation columns by the different boiling temperatures of those parts. The heated petroleum enters the fractionation column where the
liquid part (which has a higher boiling temperature) flows downward, and the vapor part (which has a lower boiling temperature) flows upward. For adequate separation of the petroleum parts there must be Intimate contacting of liquid and vapor throughout the height of the colunn. Actual design of any one fractionation coluo reflects the complex
relationships of the characteristics of the petroleum materials entering and leaving the tower, This study made simplifying assumptions and
calculated the size of each column separately as a function of quantity of petroleum separated, type of separation, and the percentage that remains as a liquid. This relationship is:
92
I'
1.
,-,
aao
b= x a
whoro
D a column diameter in ft
R = fraction of residual liquid c = column input in B/,
2.
Height required for one unit of intimate mixing (one "tray") is 22 in.
3.
ai as shown
Separation Type Stripping Primary fractionation Secondary fractionation Splitting Super fractionation
70-100
Extraction Columns These are vessels used for separation of portions of petroleum liq-
essentially the same as the distillation towers with which they are used.
Cooling Tower Extraction of heat is requisite to the operation of every refinery. This is usually accomplished by heat exchange with water and water evaporation, although air cooling systems with radiation exchanger coils with fans are also used. Deciding factors are equipment economies,
93
!I
This study considers as representative equipment tho extraction of heat1 by cooling towers using induced draft fans for evaporative cooling of a circulating water system. The basic system Ir of a module construction
The outer surface hna louvra with a volume approximating 18,000 cu ft. of redwood or cemant-asbestoo, and the inner framework includes baffles and splash docks as needd for adequate evaporation, tive as required for refinery cooling. Modules are addiCooling capacity required i& considerod to be 4.0 cu ft of cooling tower volume per B/D throoghput capacity of each processing unit,
Reactor Those vessels in which petroleum fractions change structurally are characteristically termed reactors. present. teristics. In most Instances a catalyst is
These vessels are in two groups, based on operational claracOne group includes those that normally operate at high temThese would
be of thick-walled construction and are expected to be relatively insensitive to blast conditions. as "cracking" reactors. In the study, this group was riferred to
t~vely low pressure and does not require as great a structural strength for normal operation. Examples are alIkylation process reactors. This
reactor total throughput, which includes reactor fresh feed plus recycled material. This relationship is:
v = 0.1725 X c,
where v = reactor volume in cu ft c = processing unit capacity in B/D.
Regenerator In some catAlytic processed the catalyst to regenerated, or returned to Its active state, by Lransferring At from the reactor to a separate regeneration vessel, where it is properly processed by steam, air, and so forth. This study also related sizes of these vessels to This relatiunship is:
0. 580 X
where
v c
-
Minimum regenerator volume in considered to be 600 cu ft. Pressure Vessels At several points in every processing unit, pressure vessels are needed for segregation of liquid and vapor phases, elimination of water, or separation of waste material. walled steel construction. Presaure vessels are normally of heavy
sensitive to blast, they may be displaced from their footings or foundations by blast. Differentiation is made between vertical and horizontal
vessels, because of differing difficulties in handling during reclamation. Thus, this study considered only the numbers of pressure vessels of the-se two types that would be representative of each processing unit. Pipe Support Economics of modern refining dictate conditions of ease of piping maintenance and simple flow modifications consistent with ease of operations. These factors have resulted in much of the process unit piping The amount of overhead pipe
95
Thc linear tnet of overhead rape support may be expre osd as a fuiction of provceising Utlit capacity as:
AX c#
where
Atpport ./)
Tht 16 velacted typos of processing units and the coresponding values of their complexity constant "a" are:
Processing Unit
Crude topping ';hermal cracking Thermal reforming Via breaking Coking Catalytic cracking Catalytic reforming Polymerization
a/D)
0.0049 0.0143 0.0143 0.0143 0.0490 0.0200 0.0143 0.0200
Processing Unit
Alkylation Hydrogen treating Vacuum flashing Vacuum distillation Lube and specialties Asphalt Light oil treating Naphthenic lube and specialties
B/0)
0.0490 0.0200 0.0049 0.0200 0.1250 0.0093 0.0049 0,0806
Example:
for a 90,000 B/D crude topping processing unit, piLre support 80,000 B/D X 0.0049 9
-
is
441 ft
Pipe supports are also used in the moving of intermediate products between processing units. This study weighted Lhe complexity of the a refinery and estimated the pipe supports between process units In the same manner as that for individual process units, but using the refinery capacity as throughput. Exceptions exist at either end of the scale; a minimum of 400 ft of pipe support is estizated units included in
96
for the smallest lube refinery, and a maximum of 2,000 feet for any refinery, no matter how large.
Tankage Tankage is one of the major items of Investment in a petroleum reIn Rddition, tunkagQ
reclamtion roqulrswnt's. At the input to a refinery for the crude oil topping unit alone, a minimum of four large tanks are required: one being filled from the
supply system, one full and ready to use, one supplying the crude topping unit, and one empty ready to be filled. If there is a secondary crudu
oil supply, additional tanks Are required, as they are for each proceasing unit; the movement of intermediate products from one processing unit to
the next normally requires segregation and blending of products end storage or residence time to accommodate process unit shutdowns for repairs. Seldom can only one tank be used between processing units as a surge vessel. If this is done, a shutdown of one unit forces the next procAt the point of product
completion, much storage is needed--products are delivered to their respective markets in large quantities, and enough storage Is needed to satisfy required shipment schedules. The tankage volume requirement in terms of each processing unit
+ b,
a = 0.807 b = 0.842
97
I
Example: tor a 80,000 B/D crude topping unit,
13.2 X 100 Cu ft
tank&$* required
Reclamation effort after blast da"ge will vary with the type of tank. This study considered three typed of tankapt: Sm* roof taks for those mterial. that are relatively
uovolatils * Floating roof tanks. for those materials that could pa-tentisily vaporize Spherical (and sami-spherical) tank* for those materials that
must be stored under pressure. Each representative procossing unit was examined and the appropriate amount of each typo of tankage designated.
Tho pump roquirements for each representative processing unit were Investigated. The requirements include pumps that are needed for proc-
easing reasons within the process unit and pumps required for feed to the unit and for delivery of products from the unit to storage. raquirements are expressed as: Pump
GPM X TDIR gallons per minute total dynamic head (in It)
Tables A-1 through A-17 list capacity in each process unit. is 10,000.
the number of pumps required at each The zitlmiz capacity (GPM X TIH) value
98
Pump Urive; Klectric Motor. and Steam Turbine* Pump drives are frequently divided into two groups,
electric drive, is subject to olactric power failure
One group,
normally in
and is
and unachodu1ed
thurtoll.
etwa
at* shutoff.
ice
is
in process units.
8toam drive
that
charge to a
Within each group, each pump drive was sized for horsepower requiremont at 8C0 percent ufficiency:
GP
80
3,960
1040'
and the number of pump drives within standard power ratings available were dotailed.
Centrifugal Blowers In some catalytic processes, the regeneration of catalyst is accomplished by passage of large quantities of air through the catalyst in a regeneration vessel at relatively low pressure. Blowers and their
required drivers for this service are sized, based on the relationship of 0.112 HP per B/D of catalytic cracking process plant capacity.
Heat Exchangers Heat exchwigers are treated in a manner similar to pressure vessels. Studies have sown them to be relatively insensitive to low blast overpressure effects, but they may be displaced from their footings or
foundations.
Filters
These are relatively small in number, but they are included because they are requisite to product finishing in some instances and because they are vulnerable to damage at low bl*st overpressure. They are esseh-
tially a fabric-covered rotating cylindrical drum with valving arrangements to permit vacuum and pressure to be applied from within at different points during rotation. This study assumed that a representative
Instrument Cubicles In large size and complex processing units, refiners have found it expedient to have a portion of the control instrumentation located in an instrument cubicle near the operating equipment, rather than in the central control room. This study assumed that a cubicle consists of a small Al-
though the cubicles represent only a small investm'nt, the contained instruments are a part of the control system of a processing unit, and
they are vulnerable to damage at low blast overpressure (glass front breakage, instrument damage, or wiring breakage).
Utilities Equipment necessary to bring in energy from outside also considered. ae refinery is
Invectments, but they are vulnerable to l.ow blast over'pressure damage. The fuel gas flows through a met-r and v pressure regulator valve, both of which are normally unprotected. meter and one regulator valve. Every refinery requires at least one
1I
100
I
ms 3
alse:tri,
This study
asum' -.at every refinery requires at least one transformer, and large i refin .a require at least three transformers to operate, on the above bases, the equipment that would be necessary for each processing unit within each category of refinery is detailed in Tablas A-I through A-17.
101
1.
Capaci-
ties for operating time only (excluding down time) would be higher by a factor approximating 100/95. Z. Single units of equipment are shown with only the sie~ of the single unit in the "Size" column (the numeral 1 in the "ZXwnbers" column is omitted); modular types of equipment have only a number in the *Numbers" column, showing the equivalent number of modules. The
slse module is reflected in the value of C. shown in Table 9. Fractional modules in the case of cooling towers reflect combined use of a cooling tower by more than one processing unit. The num-
ber of fractional modules shown for any one process unit is that unit's minimum requirement (i.e., a crude topping process unit in a 24,000 B/I) refinery requires 5.3 of the selected size cooling tower modules (see Table A-l).
102
Iar_
Equlpul. Contrnl uocuse, steel rf. Control bou~s, Fired haster Fractionation coltmn canar. rf. Unit of MUsaurs 1,000 fta 1,000 ftt 1,000 fte 1,000 ft 1,000 1,000 1,000 1,000 1,000 1,000 it 5 ft 3 ft ftM ftO tt,
s
"i*1
No,
ouol
Sine 57
Small ''j
No. $IBM
P
V.. St 73
No,
Sit* 30,0
3 4 8
3 1 4 a
40 30 39 3.5
2 2 4
15
3 1 4 a
s0 44 50.4 4.5
22.3
1.1
17.0
33
5.3
43
Reactor, cbuhuical Legenhrator Prtssure vessel, horiz. Pressure vessel, vert. Pipe support Store" taak. come rf. fltg. rt.
4 8 380
1
4 8 740 30,000
2 4 120 3,000
4 8 960 40,500
15,600
Storage tank,
N X TD , 1,Ooo O X TDH* 1,00 ONw X TI* Electric motor Hp up Hp Hp Hp ip Hp No. Xo. No.
160
300
12 28 4 6 14 4 6 14
so 90 s0 25 30 W0 25 30
12 28 4 6 14 4 6 14
4 a 14 2 3 7 2 3 7
90 50 s0 30 15 '0 30 15 20
a 40 4 20 4 20
Steam turbine
72
72
36
72
Table A.-1
MAMI8 CAUL4 TW0INZ P2RWMIN0G UNIT
,1
tqulpmnt bz RetIrr
TIMI
TI
ajd Capaziq
As
Euo
Promoto
194,_____ OW
a"
1060
3sw~y B 15
22.3
140
Sig* 73
A 4.3 9.6
6.3
N.
f1Z4 6o
No.
3 11
7.4
2,0 2 1.5
4.1
10 2
2
3 1
4
50 44
50.4
7
3.2
10
13.5
1.1
4.5
0.7 0.9
0.8 1.0
0.3
0.4
1.3
43
2.6
3.1
1.6
0.91
6.1
1 2 70 1,290
1 2 s0 1,500
1 2 40 660
1 2 20 51a
1 2 140 3,43U
90 30 60 30 15 20 30 15
8 40 4 20 4 20
2 3 7
90 40 d0 30 15 20 30 15
2 3 7
100 50 70 30 15 20 30 15
2 10
60 30 20 3 20 1c
2 3 7 5
30 20 20 10
2 3 7
3 125 60 2
3 2
3 7 10 2 5
20
72
4
18
20
4
it 1f is
4
1
40
1i LM.V..4wA4 4' .
INO
_________________________
Typ
2T7,000
disf No. ime
'"V
No.
Pro?%alue
U
Si*A No. B
No,
lime
No,
20 9.4 is 11
2 7.7 a 4.6
7 31 24 1
2. 5, 4. 1,
Fractiolattih eolin
txtraction columi Cooling taor Reactor, cracking asaatol., cbemical Roge ratar P'rosaut veis-al, horti,
3.2
1
6.1
0.67
2.6
0.45
Prourtb
Visasi,
vert.
rf. rf.
No.
it 1,000 ft0 1,000 ft
3
12
110 1,330 620
12
400 2,550 1,200
3
40 130 t0
3
10 750 450
3
20 1 50
1,000 ft' ,000 GPM X Tm 1, OWONP X TWO 1.000 ON X TDH* Hp up Hp Hp up Kp Hp No. *o. No. 4 4 1 1 1 24 24 6 6 6 8 20 4 10 4 10 280 30 10 10 100 10 a 20 4 10 4 10 550 55 175 20 175 20 2 5 220 25 60 10 60 10 250 5 90 250 30 250 30 2 5 15 20 50 10 50 10
WCsccric motor
Stmea turbine
Contrifugal blower
Meat axchager Filter lrAtriant cubicle
6)1
" -a-I. . I
-.-
TrE
ft"
No.
tx
lm
No,
li8
"I
1;; No
_,
site
2
7.7 31
2.0
3,4
2
013
92.0
3'.0
a 9.3
6 4.0
24 it
4,3 1,3
5 1.5
2,5 O.
3.2
.67
2.6
0.48
0.53
0.27
0.079
0.53
3
40 I!'0 so I0 750 450
3
20 100 50
3
20 120 60
3
20 50 30
3
20 20 10
3
40 120 60
220 25 60 10 60 10
2 5
2 5
150 20 80 10 50 10
&
10 20 50 t0 so 10
2 5
90 10 30 10 30 10
2 5
30 10 10 5 10 3
2 5
180 30 s0 10 50 10
Table A-3
1iQ01 PTZT U AXtV MAW ThEA, RUOMINiO PLO ZUIo
"0t 1 FuetIIesil
U5ai go, flu No. imse No, 8
No,
Si*
Mo,
Cootrol bouse,
Tired heater
concr. rf.
2.0
1.5 3.1 0.5 0.2
2
2,4 6,9 0,19 0,3 7.8 14 2,4 0,6
2,0
0.19 0.4 0,1
1,000 fta 1,00 ft 1,000 1,000 1,000 1,000 1,000 1,000 ft. 3 t fts it3 ft 3 ft
3
Fractionation column
0,41
0,78
2.2
0.0532
Reactor, chelical Regen rstor Pressure vessel, horiz. Pressure vessel, vert. Pipe support
1,000 fts
1,000 ft 1,000 fts 1,000 OG X TDM* ,000 PM X Til* 1,000 ON X TDH* up up Hp up up Np up No. No. No. I 5 2 4
3
40
?0
80
50
800
390
10
10
70 10 20 5 20 5
2 4
140 20 40 10 40 10
2 '
2 4 3
30 20 10
Electric motor
Stea
turbine
10
4'
KU AND
MZU
UNIT
_________________ __it,____
li
WO. *O,
flip
Ito,
size
No ,
,a
0.23 0.8 0.
1.5 3 Os 0.2
2.2
0.02
0.061
0.031
0.02
0.42
2
120 600 390
2
20 10 10 20 10 10
2
20 10 10
a
20 10 10
2
20 s0 sO
2 4
2 4 3
30 20 10
2 4
40 20 15 10 15 1.0
a 4
40 20 1s 10 15 10
20 10 10 5 10 5
2 4
150 20 so 10 so 10
2 3 10
25
5
1
55S
11 1
53i
1
Ta*l.
A-4
kwif~ut
az
AM) WUMUU,
IN
IMMIX
w~ingan UEI
. L . lNt . . .
Pro o* 1ii
U fP
Control Wase, stool rt.
0o.
site
No.
Cohttaa
boQW,
COMMr
ef.
Yird boater
3,1
2
8
13 4
8
13
1,000 ft
I1ON ft3 1,000 ft 3 1,000 fta Ixtraction column Cool iq tower 1,000 fte 1,000 its 1:0"01 t-1 1,000 ita go. 1,000 ft 1,000 ft* 1,000 ft0 14.000 te
3
0.7
14 1.4
2.2 0.3
14 1.3
1.0
2.0
0.31
1.2
chemical
ator
Prosou&r
Vessel, bar::.
vOrt.
No.
No. it 3 g0 360 40 210 40 20 s0 is 10 60 is 10
4
3 120
3 i0 so
3 100 a 170
rf. rf.
750
12 2 3 4
20
2 3 4 70 20 10 20 10 3 20
spherical
Electr$c motor
Ste"
turbine
1.000 tt 3 1,00001W X 11DS6 2 1.000 GPM x Toil 3 1,000 GMo x 1z* 4 up up Hp 2 Np up 2 Hp 2 Hp No. No. No,
410 70 40 123 20 13
3 4
4 O 7O 40 125 20 13 125 20 1
2 2 a
2 2 2
125
20 13
2
2
1o
5
8
1 1
-~~T~1Aii
~~
VIS WIXMIftMU .
I~IN ~ ~
VWIT "
Cul
8/0),vmukx
.
P. , 1. t KO.. . 5154
4, 000 ON;Ro.
27 ,m0
Sit#
13
2.2 0.3
14
i.3
0.31
1.0
3 20 80 20
2 3 4
70 20 1o 20 10 5 10
2 3 4
400 70 40 125 20 1, 20 is
2 a 2
2 2 2 S
Table
A..
NUIJ1M!t
aIlo
ANDO MAInM:
WIT
ftqlent
No,
sit&
#01
Uss,
0.
Me.
so,
lt.
NO.
Caotrol house,
Wlrd b&ata"
C00r, rf.
1,000 fta
1,006 Wt.
$.2
3.4
12
6,5
2
0.23
10
4.6
0.6
1.1
0.1
0.5
Kitraction column
Cooling tomer Ebtitor, XSector. cra .Jlg 4b"mlcal
1,000 f t~
1,000 it* N. 1,000 ft 1 1,000 tt 1.,0 te. 1,000 ita %orts. vert, No. ft. ft rf. 1,000 ft
a 1
04
1.6
0.017
1.3
3 3 100 10 10
1,000 ft a 1,000 tte 1.000 GPM X TON 1.000 OM x ?o 1,000 or* x TM* up 2 4
Storov tak, P
70 30 20 10 20 10
130 go6 40 20 40 20
10
a 4
0 50 30
9le"ttic motor
15
3 3 2 30 is
up
Steso t ufblm Idp up 2 2
kip
"Atr$f .sl Seat exthan Filt*er lostrume t c blomer r up *0o No. iq*1 N3O. 1 1 . 4 4 4 4
/4I
SaaLR. ru1
_________
No.
si"
Equimemnt by Rofir'ry Type and Cepeoity_ (-/D) Couplet. Pro gonn Aphalt 12 141,000 _________ so, sit' ?fo. Sit* No. StaB
~000
0.067
1.3
3 3 100 10 10 10
2 4
90 50 30 15 30 15
3 2
5 2
4 1
4 1
mB
TableAEQUIPMENT SIZES AND NUMS L SIA CATALYTIC CRAC*INO PROCX T .ue plete t by filry IING
Larg
78,00 2quipamnt Control house, steel rf. Control house, Fired heater Fractionation column cotior. rf. t;nit of Masuro 1,000 ftz l,000 le 38.0 2 2 4 4 4 4 4 4 11.0 10,0 16.6 1,3 0.7 0.6 5.4 2.9 No.
Size
2. 0, 0. 0. 0. 0.;
ION oor
1,0o ft 1,000 1,000 1,000 1,000 1,000 1,000
fta ft, ft 3 ft ft 3 ft
3
1,000 ft 1,000 fta No. 1,000 ft 1,000 ft 3 1,000 ft 1,000 ft, No. No. ft 1,000 ft3 1,000 t
3 3
8.8 4 2.1
17 4 4
2.9 2,5
19 4 4
0,10
Rglenerstor Pressure vessel, horiz. Pressure vessel, vert. Pipe support Storage tank, cone rf. Storage tank, fltg, rf. Storage tank, spherical Pumps
4 28 24
6.8
4 28 24
4 28 24
0,6
20 10 10 lo 16 10
1,000 ftt 1,000 GPM X TIH 1,000 GPM X TiON' 1,000 GPM x TuH* Hp Hp Hp up Hp Hp HP No. No. No.
* 12
ElectTic motor
Steam turbine
73 24
12
12
Table *D IJMURS
"-
TLYp
Ad Caacitty As Pki t
mail rwi
24, wo
12 000
14,00
0.
site
No.
Size
go.
81".
No.
"' 31w-
"7"o. A1:,
~
X6.
No.
UlA
77
22 35 2.7 1.6 1.4 11.5 5.3
19 2.5 4 4
0.10 0.6
0.12 0.6
0.11 0.6
0.24 0.6
1.0 1.5
4 28 24
0.6 7 8 20 10 10 10 16 10 16
0.6 7 6 20 10 10 10 10 16
0.6 7 6 20 10 10 10 10 2 14
0.7 7 6 20 50 30 30 20 10 10 a 2 10 5 75 2 10 4
5 7
5 7
5 2 3 24
15 24 24
75 24
60
2 24
12
Table A-7
CATALYTIC 1Rr=mIil
POGESSINC, UNI
eai Ax Ko. 31tA
?rquipment by Roflle
Cople te Large ruel Iquipnt Control Unit of Meaqut,. 1,00o Ito No. si e o. Niza Srell Fkel Mo. SLze Procesping K01 size
Wi.ae,
steel rf.
rf,
1,000 fto
1,000 ft 1,000 1,00 1,000 1,000 1,000 1,000 ft fto ifa ft-I fto Ito
3
25 7 33.8 1. 3.2
4
4 4
Extractio c
olumn
1,000 ft3 1,000 ft No. 1,000 fto 1,000 it, 1,000 fto 3 1.000 ft No. No. ft 1,000 ft
3
4.1 1 0.8
7.8 16 1.5
1.3 4 1
7.8 16 1.5
0.081 4 0.6
Reactor, chemical
Regenerator Pressure vessel, horia. Pressure vessel, vert. Pipe support Storage tank, cone rf. Storage tank, fltg.
rf.
3 100 s0
3 20 10 10 10 12 10
1.0Di I t
330
90 2 6 4 3 2 3 2 2 12 90 70 30 30 20 10 30 20 10 350
1,000 fto 1,000 GPM X Tw 1,000 GOGP X TtD0 1,000 P X ThN Hp Hp Hp Hp Hp Hp Hp Ho. No. Nb. 4
Electric motor
Steam turbine
Centrifugal blower
50 12
Heat exchanger
Filter n13trument cubicle
II!
Table A-7
:ATALrrIC R7270R(ZI4
M'1OCELSIN
U1(T
AP Ahelt 14,000
go,
-nd
iLt Lube
___0
No.
-, Site
27,000
Siam
No,
SIR*
1.3 4
7.0
0.094 4 0.6
0.047 4 0.6
0.13 4 0,6
0.99 4 O.M
16
3 100 90 0 330 90 2 6 4 3 2 3 2 2 12 90 70 30 30 20
3 .0 10 10 10 12 10 12 20 10 10 10 10
3 20 10 10 10 12 10
3 20 10 30 10 12 10
3 80 60 210 s0 2 6 4 3 2 70 50 20 20 15 10 20 15 10 250
10
30 20 10 350
8
4 12 4 8 4S
a 3 2
O0
12 12
50 12
30 12
75
2 12
11
Tabla A-S
POINVAIMTIOK
PR0CESS1N0
WIZT
T p. an A
12 (
Vuel
Site Md. Zisa
Pr""aveing
194,_____ -
________
Unit of Measure
1,000 ft3 1,000 ft' 1,000 ft 1,000 it Z 1,000 1,000 1,000 1,000 ft ita fto 3 ft
3
No.
size
1110,
NHit.
size
Wo.
Sine
2.0
2.0
"
Fractionation column
1.4 1.5 9
2.1 2,6 16
1,O0 ft'
ExtractIon column Coollng tower RMctor, crackIng Reactor, chemicul 1,000 ft, 1,000 fta
No.
1,000 ft' 1,000 f 1,OOO it 1,000 No. No. it cone rf, 1,000 ft
3 3 3
0.29
0.54
0,01
0.94
0.057
0.6
0.6
0.6
0.6 I
Regenerator Pressure vessel, horis, Pressure vessel, vort. Pipe support Stora tank,
W 3 3 40 20 3 20 3 40 20 3
1,000 it 1,000 it
40 60 2 4 2 2 40 20 10 15 10 5 15 10 5 2 4 2 2
S0 110 80 30 10 25 10 5 25 10 5 6
20 20
120
210 2 4 2 2 130 .0 20 40 6 a 3
10
10 20 10 10 5 10 5
1.000 am X Thn 1,000 CPU X Thrl 1,000 CFM x TI)r Hp Hp Hp Hp Hp Hp Hp No. No. No.
2
3
20 10 10 5 10 5
Electric motor
15
10 40 15 10 3
Steam turbine
99
SGallmon
POLYW~$11AricK Pito85l)IX
tUNIT
_________________by
ReD
1PM
IM
fid
copiatt
small tual
5=3m14,00
51 Noi, SIR#.
Pr1si
9* S12s No,
Aothal t
4b
7
sia*. No~. mim
~
P.
o sit*
No.
2.0
2.0
1.4
1.8 9
0,23
0,3 1.6
211
2.6 ii
0.1
0.2 0.9
0,15
0&2 1
0.1
0.4
0,1
0.A
0.2
1.2
0.01
0.04
0,057
0.067
0.024
0.011
0.012
06
0.6
U.6
0.6
0,6
0.6
0.6
33 20 40
3
20
3 20
3 20
33 20 20
020 10 o 0 0 8 0 5 0 6 2 3 20 20 10 10 5 10 a 2 4
10 10 20 10 2.0 6 a 3
2.0 10 20 10 10 a 2 3
IQ 10 20 10 10 8
10 10 10 6 2 3
10 10 I 10 10
2
2
20
40 15 3 10 40 15Is 10 4 8
10
10
10
1.0
Table
guIp&Gnt Control house, &teel rt. Control house, concr. rt. Fired hester Fravlonrtion coltm-
Unit of Measure
3 1,000 It a 1,000 ft
1o'
it%*
Ito.
Sie
No.
size
Ho.
4UI
81
25 12 17 29 12 10
24 22 17 28 11 9.4
1,000 fIt
1,000 t'
1,000 fta
Extraction column Cooling tower Reactor, crackintg Reactor, chemical Regenerator Pressure vesel, horis. Pressure veael, vert. Pipe support Storage tank, cone rf. Storagf, tan,
Storage tank. Puaps
1.6
3.1
0.42
3,0
4 6 4
0.6
4 6 4
2 6 4
0.6
.4 6 4
0.-S
360
330
3
700
630
I00
60
680
600
fltg. rt.
spherical
1,000 it
1,000 ft
120
330 2 9 4 60 at, 40 20 25 15 20 25 15 2 9 4 4 2 5 2 15
240
630 110 160 70 30 80 20 30 s0 20 11 4 5 2 6 2
20
80 20 10 10 5 10 5
240
600
2
0 4 4
100 150 70 30 50 20 30 50 20
Electric motor
4
2 5
2
6 2 15
Steam turbine
2
15
Centrifugal blower
meet oxcbanger litr
Up
go. No. 15
lnstrumnt cubicle
No.
Gallo
G.G..GME I
squlpat I
N - o. 8144
b_
ft
"
(jVD) .....
a
rocaom
No,
Ste
L&bub
7_______
Luba 2KEW00
NO,
Size
No.
it"
No.
SIR 1a
o,
Ai se
a.
24 22
11
26 11 9.4 2
0.42
3.u
U.065
0.44
06
0.9
0.6
0.8
4 100 60 20 60 11 4 20 10 10 a 10
4 20 10 10 10 15 10
4 100 60 30 60 11 4 3 2 a 2 20 10 10 5 10 3
2 6 2
7 a
p a
2
3 2 1 1 15
20
30 50 20
15
1 is
1 i5
Il
Table A-10
WYOM00M
1l1
Large Fu4-1
,1 i
Ta
Equipmen~t
go.
31"e
40.
i.
1,000 ita 1,000 it 1,000 ftt 1,000 1,0G 1,000 1,000 1,000 1,000 fts 3 ft ft* s ft O t 3 ft
3
25 25 10 22
Extraction "olimn
Coolilug tower Reactor, crackilg Reactor, chu
Ragwnerstor
6.1 4 2 2 1
0.31 2 0.6
6.1 4 2 2 1
cal
1,000 it,
PrCaaur
hobriz,
3 560 1,800 00 900 2 4 2 2 600 320 130 175 100 40 175 100 40
3 20 50 30 20 2 4 2 3 30 20 10 to
3 560 1,100 900 900 2 4 2 2 & 600 320 130 175 100 40 175 100 40
Pressure vessel, vert. Pipe support Storag* trnk, co". rf. Storage tank, fltg, rf. Storage tank, spherical Pumps
1,000 it
3 1,0 0 ft
1,000 G021X TH* 1.GOOO GPM X TH 1,000 GPM X TDHO HP Np HP Hp Hp Hp HP No. No. No.
Electric motor
$team turbine
10 5
12 1
12 I
12 I
12 I
"III p*.
Fuel aito
ry TMp 12-
imudCapacity (l/fl) A4,o I.t asz go. SS1 and Lube No. Ii No. sis LUZ Po. size
sit
No.
25 10 22
0.31 2 0.6
6.1 4 2 2 1
3 20 so 30 20
560 1,800 9.0 900 2 4 2 2 600 320 130 175 100 17 100 40
2 4 2 3
30 20 10 10 540
10 5
12
Table A-11
zWPz
ir siMS AND
ft$MAS
Large fuel
. quimnt Unit Of Measure No. also N. S i
Small Fuel
No. size
Processing
so. Site wo.-
I.IonO I 1,000 t 4
8.3
11
Tired heater
Fractionation colusn
1,000 it' 3 1,000 ft 1,000 It 3 1,000 It 1,000 ft' 1,000 It 1,000 ft 1,000 St'
0 3
4 4 8
r 18 2.5
5.4 11 1.7
4. 4 8
Extraction column Cooling tower Reactor, cracking Reactor, cemacal Rege erator Pressure vessel, horiz. Pressure vessel, vort, Pipe support Stora" tank, ce" rf.
iCOO it
1,000 ft No. 1,000 ft' 1,000 it* 1,000 ft' 1,000 It No. No. it 1,000 ft 1,000 ft' 1,000 ft
3 3 3
4.9
9.4
1.5
6.7
1.9
4 110 3,120
4 220 6,000
1 40 620
4 ISO 3,750
1,000 GP x TDH* 1,000 ON X TDH* 1,000 GPM X Tl* Hp Hp Hp Hp Hp Hp Hp No. No. No.
16
40
16
80
s0
16
60
Electric motor
15
14
15
20
Steam turbine
15
25
15
20
20
20
20
II
Table A-42
SIMS M ND lBMZR8tVAC)Ub FLASINO PROCMSSIN0 UNIT
___
proh.1f. I w_
No.
asoz
11
N.
,00 size
3.4
Asphalt _
Ud .14,O
IA"
Lute
7,o No.
me.
Size4
No.
Silo
4. 4 B
4 11.5 1.8
8 6.3 1.6
1.5
C.7
1.9
2.2
1
40 620
4
160 3,750
1
50 880
1
60 1,020
50
16
60
70
80
15
20
20
25
15
20
20
25
20
I. .. . ................. ..
V-
A-12
7 8o 0 ,0
.. uipeent Control homUe, steel rf. Unit of Measure 1,000 tto 1,000 ft 1,O00 ft 1,000 ft
t 4 3 3
L7rft
Puel No.
5 0. 000 510
o , , 0 0o .. .Prvveseing
No. SiX4 No. .8
No,
Six*
17 4 4 12 3.9 8 a'8
Extraction column Cooling tower Reactor, cracking Reactor, chemical Regenerator Pressure vessel, horiz. Pressure vessel, vert. Pipe support Storage tank, cons rf. Storage tank, fltg. rf. Storage tank, Pumps spherical
ft 3 ft ft3 3 ft 3 ft fta ft 3 ft
3
4.3
3
12 100 2,400
1,000 ft, 1.000 GPM X 1D0* 1,000 GM X TVH* 1,000 GPM X TWO Hp Hp Hp Hp Hp Hp Op 11. 28 24 40
Electric motor
12
15
Stem
turbine
12
15
No.
No. 4
/4.
E~quipownt by R~fin!LrjT
sa.1l
6M Capacity W /D)
Vu.l
'
Pro-mirls
_
_ _4,000
A.. epbalt
C;Z0 2o1
and Luba
14,.000
No. No, site 81.
____
,o,
8tie
9 go .
a@
size
17 4 4 12 3.9 8 0.8
5 4 2,1 0.3
8 7.6 6 0.9
4.3
111
0,31
2.1
12 100 2,400
3 40 440
3 20 140
3 60 960
24
40
40
10
70
12
15
15
20
12
15
15
20
28 4
7 1
7 1
7 1
Table A-S
$all no.
-__, o
__
esaure
No.
ftt#
b0 3 2,35 9 1
1,000 ft3 1,000 ft 1,000 1,000 1000 1,000 1,000 1,000 1,000 1,000 No. 1000 fte 3 1,000 ft 3 1,000 ft 1,000 ft horiz. vent. No. No. ft con. rf. fltS. rf. 1,000 ft
3 "
3
ft 3 ft ft3 ft 3 ft WI 3 ft fta
4 2
a,6
1.3 3.5 6 1 1.3 3.6
Reactor, chomicl Regenerator Pressure vessel, Pressure vessel, Pipe support Storage tank, Storage tank,
1,000 ft 1,000 ft
3
gO
40 20 20 10 20 10 130 40 40 15 40 15
1,000 GPM X TDHu 1,OO0 GPM X TOH* 1,000 GPM X T0NO Hp Hp Hp Hp Hp Hp No. No. No.
Ilectric motor
Ste * turbine
&
50 6 5
vqU, u
t b
iflur
Ty-nd Ce celt
(9/D)
Saall rue%
JO, six
prclsa
No. go. N#s
AMP44~t
At" go. Sle
and Lubei
No. #Ie I. SIX*
Lub#
Xo, sie
4 2
4 2
2.1
0,1 1.3 0.4 0.5
12 7 150 s0 20 10 60 10
30
30
50 6 3
50 3
s0 3
S
Tibla A-4
IQUIHM NT SIZS AV NLt ,MMK: AEPHALT PhIMS1NO UNIT
Egipant by MitAry T
sVn 0
cople
Lary_________________
tquipmnt Control boue, Control house, Fired hoatvr steel rf. conar. rt.
...
No.
,000',...
6l1e
smal
fl700
2
rwul SsIe
Prcw
A*
1, U,
No, 2 sie
____z
No.
o
61 2,0
No,
0,7
3,1
2,9
Frantionation column
1,000 ft.,
1,000 ft' 1,000 1,000 1,000 1,000 ft3 ft ft 3 it
8
0,2
0.6
0,6
Extraction column
Cooling tower Reactor, cracking
1,00 ft 3 3 1,000 It
No. 1,000 ft 3 1,000 ft 0.19 0.89 0.91
Reactor, ch*mical
Regenerator Pressure vessel, horiz, Pressure vessel, vert, Pipe support Storago tank, cone rf.
1,000 Wt
1,000 fta No. No. ft 1,000 t
3 3
20 50
40 320
30 300
1.000 ft
1,000 ft
1,000 GPM X TO"' 1,000 GPM x TWO' up Hp Np Np Hp Hp Hp No. No. cubile No.
10
2 2 2
30 20 10
2 2 2
30 20 10
Electric motor
Steam turbine
10
10
. . . . . . . .. . . . . .
squipmnt b
Capavil
Aint.
No. 2
No. j
Siz
I-
size
2
.i"
3i 000 0. AIs&
-0
0,1 0.2
3,1 0.8
2.1 0.
3.4 0,7
1,7
0.4
0.19
0,9
0.31
0.94
0.47
20 so
40 30
30 300
40
20 150
350
10
2
2 2
30 20 10 O
2 2 2
30 20 10
2 2 2
30 20 10
2 2
20 10 z0
10
10
10
10 3
Table A-18 14VIMXXT SIKO AWV $iiZ*', LICX? OIL TIIAITINO PXEISI1tO W*I Iipwt q -P
No, Viso
~
No.
~
asot a27
,,
__________
sFu211 ruel
1oW
tUfit of Weaire
. L.-Qv ft
Wo.
8i:. 14,6
Bfia
27
No.,
Mild
2.0
Cotrelhouse,
ate I r
citaur, rt.
1,000 ft
1,000 ft
1,000 f t3
1,000 ft3 1,000 fto
12
12
3,7
Is
12
12
7.3
2,9
3
3
4.6
1.9
12
12
7,2
2,0
3
3
2.0
0.1
Fractionatiou col mn
1,0"0 it-3
1,000 ft 1 1,000 ft 3 1,000 ft straotion Colun
12
1,8
12
2.9
119
12
2.9
0.6
4.6
17
2.7
17
1,.1
aracgking
chemical
Nernerstor Proooqro vessel, Pressure vessel, Pipe support Storae tank, cone rt. Storse tank, Slt. rf.
so
40 Mo 4,000 6,0ow
20 10 so 630 640
20 10 30 280 230
40 40 20 20 20 20
100 40 30 1 30 is
40 40 20 20 20 20
200 s0 40 28 60 28
10 10 a 6 5 5
s0 50 30 18 30 1s
40 40 20 20 30 20
200 s0 60 25 60 28
10 10 10
30 20 10
Electric motor
Stea
tiurbine
10
10
o0
s0
20
s0
20
,4-
Tebl*
AJW.KUUid
"s4
O0 UIIT tooo' 11/b))
S~~~~ll4~1 YL*A101tL
le, M1iA b Po, Ili" 21 $ o, Als 1,0 go. Slav We. It"
~
R. sise
b
+. 41,.
2
: 3 2 .3 0.9 3
2
2.2 0. 3 3
2.0 0.05
0,2
4.# a 1.9
12 12
1.2. 2.0
3 1
2.0 0.0
3
3
3. 1,15
1 7.7
1.9
12 17
2.0
3 1.1
0.8
3 1.3
0.0
. 0.61
0.i
3 0.31
0.2
3 2.1
1.0
O 0 s0 S30 640
20 10 30 230 230
20 10 40 200 270
20 10 20 110 110
20 10 20 70 70
20 10 so 450 440
0
o
s0 s0 30 is
40 40 20 20 20
200 t0 go 23 CO 25
10 10 10 10
30 20 10
10 10 5 5 5 0
40 30 15 10 18 10
10 10 5
20 10 10
20
10
10 10 5 8 & 0
70 40 20 1s 20 15
10
3 S
10
10 0
10
13
41n
20
20
20
20
20
Il
Table A.-16
MUIMYIn
NPCIALTIS 11 !
tare
ztU1I'tent _ Unit of Meirue 1,000 te 1,000 fta 1,000 tte 1,000 ftl 1,000 ft NO. sit
Ia
___ _"" _oo_ _
Small 7LUAl
pr.*Ok
go. P0.
24,000
NO.
No,
Mle
ite
l.
Cotrol ba mw,
Control bousm, tired hostr
Fractionation almo1a
1,000 Wt
Cooling tower Remotor, orsaking No. 1,000 ft, 3 1,000 ft 1,000 ft 1,000
3 3
Reactor,
cbai.cl
Xegtnertor
No.
No.
Pipe support
Storage tank, Storage tank, Storage tank, Pumps cons rf. fltg. rf. spherical
ft
1,00 fit, 1,000 fit 1,000 ft
3
3 1,000 ONM X
Hp
HP Centrifugal blower Heat exch1anger Filter up No. No.
list
nt cubiclo
No.
'I
7TI
C/D) ad a I be
_____
Hi
132 000
________
14,000
No.
slim
Ito,
sma
Xo.
miso
go.
s1n
NO.
0.1
12 7
200
30 20 10 60 10
30
30
50 3
'-
.... 1
Table A-17 XUIPMT 81258ANMNJUMM: PIPS SUPPORTS AND UTILITIES Rquipment by Refinery TM! e Comple to PrcssA No.
miss
_0.___
Equipment
Uinit ot Mssur.
No.
fta.l Fuel
1T7
Mo.
site
Pipe supp~orts Utilities, gas motor Utilities, gans regulator Utli~ties, electric tran~forawr
Sao 1 1 2 1 1 3
2,000 1 1 1
210
Equipment by Refiner
p:e.
TE
Aa.h
t
Lubc No. o'7,00" Size 60 1 1 1 1 No.
Si.
Processin
and Luba
12,0
0. ails 2,000 1 1 Xo. also 210 1 1 No.
14,0oo
slz 240 1 1 Mo.
7.
$Im 240
400
2.....
Appendix B PRODUCT YIELD FROM CRUDE OILS AFTER~ DOW BLAST OVERPRES SURE
Appendix H PRIODUCT YIELD FROM CRUDE OILS AFTER LOW BLAST OVERPRESSURE
For each refinery, the equipment that remained operable and its degree of operability after low blast overpressure of 0.3-0.5 psi and 1.0 psi is determined,9,l o Assumptions were made of rerouting process
flows within each refinery, to bypass damaged or shutdown equipment. The product yields from both thw normal crude oils and alternative crude oils were recalculated. In every instance, the reduced capacity
If a
refinery must use alternative crude oils, the throughput is reduced further. At the overpressure that reduces the cooling towers to 70 percent capacity (0.3-0.5 psi 9 e
10
considered at 70 percent of initial capacity and the refinery production estimated for this condition.
At the 1.0 psi overpressure, the crude topping, vacuum flashing, light oil treating, and asphalt process units are considered shut down. Suffi-
cient repair is made to the crude topping process unit to permit the refinery to operate at 50 percent of initial capacity. The vacuum flashing, While
light oil treating, and asphalt process units remain shut down.
13.o
3%l
that all light oils find a market, even though they do not meet normal specifications; vacuum distillation units are assumed to process topped crude In the production of specialty products; and thermal cracking and catalytic cracking units are assumed to usm part of their input, The product yields in each instance are sumarized in Tables B-1 through B-6 for the six types of refineries. Yields are developed at some topped crude oil as a A
100 percent capacity with undamaged conditions, 70 percent capacity after 0.3 to 0.5 psi blast damage, and 50 percent capacity with appropriate volume modifications required for partial shutdown of equipment after 1,0
psi.
14
140
Table 8-1 PRODUCT YIELD FRPM CRUMK OILS AMR LOW BLAST OVERPPESURE! LARGE FUL RZFIXERY
Production as a Percent of Initial Refinery Capacit) Undamaged After 0.3-0.5 psi Aftev 1.0 ,0 oor. 70% 50
Normal:
30*-40* API Gulf 541 15 14 --. 13 --... 4 100% 20*-25* API West Coast 1,% 5 6 -... 13 ..... 2 38% 20*-250 API Midcontinent 8% 4 4 --... 13 .....
2
Gasol ine Kerosene Diesel Lube Fuel oil Asphalt Coke Total Alternative: Gasoline Kerosene Diesel Lube Fuel oil Asphalt Coke Total Alternative: Gasoline Kerosene Diesel Lube Fuel oil Asphalt
Coke
38. 10 10 .. 9 3 70%
26% 8 7 7 2 50%
9 3 4 9 1 26%
6 2 3 7 1 1979
6% 3 3 9
1
4% 2 2 7
Total
31%
22%
15%
141
Table U-2 PROM=C YIULD VAKMCSWEM OILS ArM L41W "I OVPLUUKI
Prouction am a IParsw*#t of
,fteiqaryCGp*,ty
After 1,0 psi
________
4
I
3% 11 10 11 2
I
26% 0 7 0
--
Total Alternative: Gasoline Kerosene Diesel Lubae-Fuel oil Asphalt tCoke Total Alternative: Gasoline Kerosene Diesel Lube Fuel oil Asphalt
Coke
70%
50%
10% 4 4 11 1 1 31%
7% 3 4 9
--
23%
as 3 3 119
38 2 2
1
1
1
--
--
Total
33%
24%
16%
142
ULAST UVIAMS-SNUM
a Vvcint of pexI
4.ftsr q.-.
70%
?Xor~al
Gsoline
KXIurooen
4 7
1 1 1
Total
Alternatve K. ros uai Luba * * fulol11 Asphailt 'otal Alternati~ve; Oaha.irna K. rosona Diesel 20'-25' API MKccouitnunt W-25# API Vogt Coat Ga
10%701.
3011"
~o10%
4 3 1I-
711 3 2 37 2
36%
2411
201%
Lube
Fuel oil Asphal t Coke. Total
611 a 3
4v 2 2
-
2
11 1I1I 27%1 N7
31 2 2
19%1
1511
143
31
Tabl
1-4A. LT OSfllTllttUf
pWAIaCT Y&W) VWl CRUIX 0ILL AMA LOW AlM i'ALT OIXYIJMXY
Predution as a Percent of III& t lsi Unndaged tondl Alter 0,3-O, p:i After 1.0 pse
100-*
70
15
1 111, 4 4 .
52~, :3 2 1 1
Asplt
Total Alterative: Lube Gaoline Keroene Diesel tuel alil Asphalt Coke Total Alternative: Gasoline
Lab
4
14% 206-40 APl Welt Coa t 1n 5 7 4 14 41'% 20'25* API Mldcoatsnt 11% 5 6 9 13
3
171
--
5%
61 4 4 3 10 11 1 1
--
17%
--
3%
-
dl 4 4
11 1 1 2
coke
10
--
Total
Kerosene144
44%
33
37.
* amrgfncy repairs made to crude toppiLng process.i Sol asalt equipment used for fel onls,
Diefol 6a
GAXOI~~ I W1%i
"LT
8U
CnlS~iflAter
Initial RfjnwrV
U40&Owt 0.3-0.3
16 Aiphalt
Fuel all
t
a12
40
Altarnativel
Gasolin 1%
Lutw Fuel oil
-
1' 24'l
1
-
Coke---
Total
Alitor~lu:
xoro0eeno
13
20.-23
Fual Oil
Ws Lua3 Apat7
Total
Alternative; W-3
FU4I oil
Coke-Tota1l6;
3 3 2 3
1;
Liancyrepair& &ade to crude tappirig pnroc.js
'
145
,--
laset Cani~lot
HeXIaaU capacity (I and products: 30 -45' API Lube
: 50%
Utd~q
OVA,
Crucil oi Moruln2;
Al 4, 15 17 30% 10 21. 7
Gasoline Diesel
1
--
r
3-
Total
A1ternative: Gai1ne Kerosene Diesel Luba Fuel oil phalt 30"-40# API Ulf
0%
50%
21% 7 7 I 6
39% 14 14 14 11
--
26% 10 9 10 7
-
92%
6r^
49*
L~lbe
7% 4 5 7
5% .? 3 3 4
3 4
Fuel oil
Asphalt Coke Total Alternative: Gasoline Diesel Lu.be Fuel oil Asphalt
..
--
. 22% 19 4
34%
Toal
265
17%
15%
I
!I
Apedi
PRDC YEDF ISA
ICUE
tt
Ur
This appendix details the estimated product yields from each of the six types of refineries after each of the four stages of reconstruction summarized in Section V of this report. For the large and small fuel
types and the complete processing refineries, these repair stages are: A. B. C. D. Repair crude topping unit Repair processing units utilized in cracking processes Repair processing units utilized in upgrading of products Repair all other processing units
Slight modifications of these stages are considered for the specialty refineries to permit the production of some of the necessary nonfuels products. main text. In all instances, the repaired equipment is considered to be returned Sroute to initial capacity. At Repair Stages A, B, and C, it is necessary to reprocess flows within each refinery to bypass the processuntno The repair sequences are detailed in Table 7 in the
A summary of the pertinent factors of the products produced after each repair stage is outlined below.
149
i-
riw stocks.
D. C. D.
Larger volume and Improved quality gasoline is produced. Light oil products are "on-grade." Coke is produced,
Small fuel refinery: A. Low octane gasoline, kerosene, and diesel are produced as raw stocks. B. C. D. Balance of crude oil is produced as fuel oils.
Larger volume and improved quality gasoline is produced, Light oil products are "on-grade." Asphalt is produced.
Complete processing refinery: A. Low octane gasoline, kerosene, and diesel are produced as raw stocks. B. C. D. Balance of crude oil is produced as fuel oils.
Larger volume and improved quality gasoline is produced. Light oil products are "on-grade." Asphalt and coke are produced.
Asphalt refinery: A. Low octane gasoline, kerosene, and diesel are produced as raw stocks. B. C. D. Balance of crude oil is produced as fuel oils.
Asphalt is produced. Larger volume and improved quality gasoline is produced. Light oil products are "on-grade."
.
150
Lube refinery: A. Low octane gasoline, kerosene, and diesel are produced as raw stocks. B. C. D. Balance of crude oil is produced as fuel oils.
Lubes and greases are produced. Larger volume and improved quality gasoline is produced. Light oil products are 'on-grade."
After each repair stage, the product yield for each refinery has been calculated by methods comparable to those indicated in Appendix B. The product percentages produced reflect both the availability of repaired equipment, the equipment capacities, and the composition of the crude oil used. The repair sequence selected results in the individual In
refinery product percentages summarized in Tables C-1 through C-6. all cases, production is shown as the percentage of initial refinery capacity,
151
Ii
-Table C-I
I
1009 FUEL RFIRY API 20"-25 API 23'API
vidcotinent 3% 3 3
--
Production as a Percent of Initial efilnery Capacity Normal Alternative Crude Oils Crude Oil
Repair
Stage A Product Gasoline Kerosene Diesel Lube Fuel oil Asphalt Coke Total 8 Gasoline Kerosene Diesel
30-40
Gulf 13% a 5
--
West Coast 4% 3 4
--
13
13 i
24% 7% 4 4
--
22% 4% 3 3
--
Lube
Fuel oil
13
--
13
---
13
--
Asphalt
Coke Totai C Gasoline Kerosene Diesel Lube Fuel oil
"50% 33% 10 9
--
28% 10% 4 5
--
23% 7% 3 3
--
13
--
13
--
13
--
Asphalt
Coke Total D Gasoline Kerosene Diesel Lube Fuel oil
65% 54% 15 14
--
32% 12% 5 6
-
26% 8% 4 4
--
Asphalt
Coke Total
13 ..-. 4 1001
13 2 38%
13
--
2 31%
152
Table C-2 PROtUCT YIELD FROM CRUDE OILS AT FOUR IPUAIH STAGES: SMALL FUEL B b'XflVY
Production as a Percent of Initial Refinery Capacity Normal Crude Oil 30".40- API ouiz i5! 7 7 -15
--
Rocunstruction _ t____ A
Product Gasoline Kerosene Diesel Lube Fuel oil Asphalt Coke Tota .
Alternative Crude Oils 206-gV" API 20'.23- API West Coast Midcontinant 5% 4 4 -15
--.
4% 3 3 -15
--
445 29% 9 9
--
26% 9% 4 5
--
25% 6% 3 4
--
15
- - ..
15 .
--
15
28% 8% 4 4 -15
-.
Luba
Fuel oil Asphalt Coke Total
153
. .W
4;..
Table C-3
PRODlUCT YZZI
iN=
CRUD
oCMPIZU
pvfuet A Gaoline Kerosene Diesel Lube Fuel oil Asp ha lt Coke T:tal
wideonti:nn
3%
2
2 11
32% 14% 6 6
--
Gasoline Kerosene Diesel Lube Fuel cil Asphal t Coke Total Gasoline Kerosene Diesel Lube Fuel oil Asphalt Coke Total
3 3
--
11 ......
--
11 _. 2 9% 4
11
--
19% 4% 3 3 2 11 -
8
2 11 3--.. 31% 10% 4 5 3 11 1
23% 6% 3 3 2 11 1
Coke
Total
2
100% 35%
1
27%
154
ASP4AL
i&WIRMy
Productisi
orn 1 Crude Oil
Rleconstruction bsat
A
Product
Gasoline Kerosene Diesel Lube Fuel oil) ruasplalt Coke Total
20r= 7 Nideuntinent
11% 6 9
-
67
10
33
- -..
41
-
31% 11 V 5S 3
61% 11% 9
6g1 11% S 9
--
Luba
fuel oil
A8phalt Coke Total C Gasoline Kr n10 DieseL
Lua--
10
33 _--.
41
31% 11 4 4
---
61 ., 6 7
20
---
Asphalt
Coke Total D Gasoline Kerosonj Diesel Lube Fuel oil I Ap68 Coke Total 100% 24. 41$ 44% 98" .6% 11% 10 11
--
442 11% 4 4
--
117
5
8
19
22
155
j"
Table C-3
-a ct
Gasoline
Mersene Diesel Lube
Coke
11
4 12
--
5%
2 2
--
0%
4 4 4 4
Fuel all
-----
~~Asphalt
.435
Total
94
14%
25
31%
Gasoline Fuel oI
4% 5 15 -12
5% 2 2 2
5% 2l
3 4. 3
5% 4 3 4 3
99% 5% 5
15 ....
14% 5% 2
2
a4, 65 3
3
31% 5 5% 3
3
~~coke
12 so
2 --
3 4
Fuel oil
Asphalt
2
7
Total
109%
13%
23%
24%
155
151n
Table C-6 PNO=UCT YMI.M YMN CRUtU OIL$ AT FOUR ZPA% STAKS:
opacity
fta-uclaSoo
A
W Lube API W
11% 5aroac 5 ........ ........
*o W0-45 os Art 4% 3
Vuel ila
Aspbalt
CokeTotal Fugi oil Oaoolte Ker"aewmm Luba Fuel oil Asph lt D11o
_. 11 4% 3 5 11 3 26% 4% 3 3 5 11
32' 11 217% 0 0 11 10
011.M 11 7 4 a 11 5
I
C
Total
Gosalin oera Diesel Lube Fuel oil Asphalt Cob Total Gsoline OD Kerosene Di#601 Luba FW1 oil Coke Total
61
42% 11 11 12 11
--
65% 27% 10 10 10 11
-.....
31%
7% 4 5 6 11
39% 14 14 14 11 02%
335 7% 4 5 7 11 -Z 4%
241 4% 3 3 1
245
157
!I I
I
-
This appehdix details the labor repair requiroments for each of the six types of refiteries after blast dmaje from overpressure of 1/20 1, 5, and 10 psi, for each of the selected Ropair Stages A, 0, C, and D.
Calculations follow the method outline in Section V, "Refinery Repair," in this report. The mathematical model is:
Ra
I- e-k(P-X) I
[=(')
+ b]
= size of equipment being investigated x, yj m# C 0 , and b are the parameters of the selected items of equipment as listed in Table 9 in the main text.
L, k,
piece of equipment at the sizes (values of C) and total numbers detailed in Appendix A to yield the estimated labor repair required. The results
are totaled to indicate the total labor requirement for each process unit,
161
of refinery.
The totaled repair requirements are siusarized for the six typos of
to permit an estimator to resequence process unit repair. pair requirement after resequencing would be rounded.
16
II
182
th
11
wl
aa
In
I-
.44
II
u0
41 +JI' IL 0 )09
I0
A 163
14 Q cD
49
'51
Ot1
20 in 0 0 .I 1 nt 0 c o,4 m 14 m 0 n 10.*I
in~
'n
m~
.44
1 'A
o ba lb on
.4
06
u- I
S..
*
am n~
164
2M
04
eq
bf1.t
aab
0%
41.
W..
V,
*4 -
ul~v '
m.i 01
wt
Vlw
ot
-44
444
44
0 Q
16
Dt
wv'
40
1u t
too
S1v ttv-
miv~ m 0
144
O)4 D
*1 4M
u 6
InIAI
IsI
166
r64
01
4C4
C4
Ni
m4 o*m0t
I 'D
cog
ko
,.4
C: 0a
uu 46
16
Ir 9
14
31
Aii
10
414
~.d
11 b
ftI
I.,
ic' t.
00
N -N olye
-4
boa
Lo
ID~
C4
'4
o4
16
'4
q4
I~ J S.
1A~
9-
tuf
4454
xP
~ 04
~ Ib~JI
10
es
'to
11 W
ol
kAa
d9d
170
-~
ON
U."
&
171
REFERENExcS
1.
elson, W. L.,, Potroleum Refinery Engineering, *th Zdltton, Mc rawill, 1958 Stormont, D. H., refining ead,ThQ Oil and Gas Journal, Issues 1950
to date, published weekly, The Petroloum Publishing Company
2.
3.
Rocq, Margaret M., U.S. Sources of Petroleum and Natural Gas Statistics, A Project of the Petroleum Section, Science-Technology Division, Special Libraries Association, 1961 Petroleum Facts & Figures, American Petroleum Institute, 1967 Ed. Minerals Yearbook 1967, Vol, I-I, Metals, Mineral#, and Fuels, Crude Petroleum and Petroleum Products, U.S. Bureau of Mines, United States Department of the Interior, 1968
4. 5,
6,
Bureau of Mines, Report of Investigations, RI 6819, Analyses of Crude Oils from 546 Important Oilfiolds in the United States, United States Department of the Interior, 1966
7.
"National Petroleum News Factbook Issue 1968," National Petroleum News, Mid-May 1968 Bland, William F., and Robert L. Davidson, Petroleum Processing Handbook, McGraw-Hill, 1967 Critical Industry Repair Analysis - Petrolaum Industry, prepared for the Office of Civil Defense under Contract OCD-PS-64-201, OCD Subtask 3311 A, Report No. CIRA-4, Advance Research, Inc., October 1965, DDC No. AD 482 909L
8.
9.
10.
to the Basic Chemical Industry from Nuclear Attack and Resultant Requirements for Repair and Reclamation, 'u7LS 687-4, prepared for Stanford Research Institute and Office of Civil Defense, Contract Number 12475 (6300A-300), Work Unit 3311 B, June 1968
173
11.
12.
Badger, W. L., and W. L. McCabe, Elemento of Chemical Eninnuring, Second Edition, McOraw-Hill, 1936 Engineering News Record, published wmekly, McGraw-44i11 .
13,
I I p
I:I
1
4
ii
BIBLIOGRAPHY
Css'ron Hydraulic Data, Eleventh Edition, Ingersoll-Rsnd Company, 1042 Civil Defense and Emergency Planning for the Petroleum and Gas Industries, Volume I - Principles and Procedures, Volume II - Guide and
Sample Company Plans, National Petroleum Council, 19 March 1964 Domestic Oil Requirements and Economic Incentives, A Forecast to 1980, Petroleum Industry Research Foundation, Inc., February 1967
Glasstone, Samuel, The Effects of Nuclear Weapons, U.S. Dept. of Defense, published by U.S. Atomic Energy Commission, April 1962 McFadden, Fred R., and Charles D. Bigelow, Development of Rapid Shutdown Work Unit 2321A, January 1966,
Methods of Estimating Production for Industries Following Nuclear Attack, John Cone, 27 April 1959
-.nvielle, L.# and W. Van Horn, Recovery of Petroleum Refineries Contaminated by Fallout, USNRDL-TR-656, 24 June 1963, DDC No. AD 419 334
1963 Census of Manufacturers: Distillate and Residual Fuel Oil Consumed 1962, U.S. Dept. of Commerce, Bureau
1963 Census of Manufacturers, Petroleum Refining and Related Industries, Petroleum and Coal Products, Major Group 29, U.S. Dept. of Commerce, Bureau of the Census, March 1966 Palmer, Mona ed., 1967 Technical Data Book, Petroleum Refining, American Petroleum Institute, 1966 175 International Petroleum Register, 38th Flition, 1966/
lis V. Shaner, The Eff ects of Nuclear Attackse try, SRI Project No. IU-3084, prepared for
Office of Civil Dei nse Mobilistion under Contract Nos. CN-5 R59-19 end CEU-SR-E 7, July 1960, DDC No. AD 276 539
"
176
Unclassified
DOUMN
CONTROL DATI-TL&
Stnlr Re
I MMen~lo~ Pa,
ar hIsiueUcasfe
Clda lifornital ,, 4025
Frank E. Walker
41. ftPOR OAT& 74L TOTAL NO. OFP A094 16. NO. or Npail
July 1969
IMLCONYTACT On GRANT No,
208
G& @fl1iOATOW11 MEPOUT kLIM'119111
14
DAHC 20-67-C-0136
b. PPIOJzCT No.
Sht mv beaM
This document has been approved for public release and sale; its distribution is unlimited.
It.
SUPf'LILMCHYANY NOTMIS It.
_______________________________
Thisa report details a method for estimating surviving petroleum refinery capability and repair effort needed to restore production capability following exposure to selected blast overpressures. The method addresses information required for postattack decision areas. The results shou~ld facilitate decisions of which refineries should be restored and to what degree, based on products needed and repair effort
available. The many variations inherent in petroleum refining have been reduced to readily
usable numbers: the total U.S. refineries are classified by six refinery types; crude oils are grouped into three major types and three specialty types; refining processes are typified by the 16 most prominent; all refinery equipment is represented by 25 items most vital to process operation, most susceptible to blast damage, and requiring largest labor input for repair; and petroleum products are represented by seven major groups._, In this context the method of estimating refinery production capability and repai requirements is detailed, and the application of the method to any individual refine ryi is illustrated.( at...,.roduction capability is reduced to about 70 percent after Results India a 0.3-0.5 psi, and to about 50 pifemt after 1 psi. After overpressure greater than 1.5 psi refineries are shut down and must be repaired in order to operate. Repair requirements and partial production are calculable by repair stage. Additional potential areas of method application include petrochemical and natural gasoline industries.
181
EI
"c"
Unclassified
UUtOlCAifLled
. ...
_
Ikoe
Oe. wv aoc
6 0
Crude oile
Reftnery types Refining processes Refinery equipment Petroleum products Production capability Repair requirement# Repair stages Partial produ.tiao
II
182
Unclasuift Led