Che122l Group 5

Sheena Mae E.
Sietereales
Tracy Anne C. Capuso
Syra Marie O. Pacheco
Experiment # 3
Chemical Kinetics: The Bromination of Acetone
SET ONE
Table 1.1: 5ml 6M acetone +5 ml 1M HCl + 5ml 0.0028M Br2
absorbance
time
[Br2]
ln([Br2])
1/[Br2]
0.345
20
0.00345
-5.669381048
289.8550725
0.336
30
0.00336
-5.695814305
297.6190476
0.322
40
0.00322
-5.738373919
310.5590062
0.307
50
0.00307
-5.786077717
325.732899
0.296
60
0.00296
-5.822566011
337.8378378
0.277
70
0.00277
-5.888907959
361.0108303
0.264
80
0.00264
-5.936976362
378.7878788
0.244
90
0.00244
-6.01575724
409.8360656
0.227
100
0.00227
-6.087975447
440.5286344
0.207
110
0.00207
-6.180206672
483.0917874
0.186
120
0.00186
-6.287178791
537.6344086
0.175
130
0.00175
-6.348139491
571.4285714
0.151
140
0.00151
-6.495645628
662.2516556
0.134
150
0.00134
-6.615085665
746.2686567
0.117
160
0.00117
-6.75075153
854.7008547
0.099
170
0.00099
-6.917805615
1010.10101
0.08
180
0.0008
-7.13089883
1250
0.61
190
0.0061
-5.099466508
163.9344262
0.42
200
0.0042
-5.472670754
238.0952381
0.24
210
0.0024
-6.032286542
416.6666667
0.005
220
0.00005
-9.903487553
20000
Zero Order
0.004
0.0035
0.003
y = -2E-05x + 0.0041
0.0025
0.002
0.0015
0.001
0.0005
0
0
50
100
150
200
250
First Order
0
0
50
100
150
200
250
-2
y = -0.0146x - 4.7055
-4
-6
-8
-10
-12
Second Order
25000
20000
y = 35.045x - 2772.3
15000
10000
5000
0
0
-5000
50
100
150
200
250

absorbance
time
[Br2]
ln([Br2])
1/[Br2]
1.825
20
0.01825
-4.003590199
54.79452055
1.817
30
0.01817
-4.007983397
55.03577325
1.807
40
0.01807
-4.013502174
55.34034311
1.796
50
0.01796
-4.019608216
55.67928731
1.795
60
0.01795
-4.020165164
55.71030641
1.781
70
0.01781
-4.027995182
56.14823133
1.772
80
0.01772
-4.033061334
56.43340858
1.761
90
0.01761
-4.039288356
56.78591709
1.75
100
0.0175
-4.045554398
57.14285714
1.738
110
0.01738
-4.052435159
57.53739931
1.725
120
0.01725
-4.059943136
57.97101449
1.708
130
0.01708
-4.069847091
58.54800937
1.684
140
0.01684
-4.08399827
59.3824228
1.68
150
0.0168
-4.086376393
59.52380952
1.667
160
0.01667
-4.094144582
59.9880024
1.653
170
0.01653
-4.102578367
60.49606776
1.64
180
0.0164
-4.110473944
60.97560976
1.625
190
0.01625
-4.11966237
61.53846154
1.609
200
0.01609
-4.129557318
62.15040398
1.592
210
0.01592
-4.140179099
62.81407035
1.576
220
0.01576
-4.150280195
63.45177665
1.56
230
0.0156
-4.160484365
64.1025641
1.547
240
0.01547
-4.168852614
64.64124111
1.53
250
0.0153
-4.179902451
65.35947712
1.505
260
0.01505
-4.196377288
66.44518272
1.453
270
0.01453
-4.231539801
68.82312457
1.46
280
0.0146
-4.22673375
68.49315068
1.452
290
0.01452
-4.23222827
68.87052342
1.44
300
0.0144
-4.240527072
69.44444444
Zero Order
0.02
0.018
0.016
0.014
0.012
0.01
0.008
0.006
0.004
0.002
0
y = -1E-05x + 0.0188
50
100
150
200
250
300
350
250
300
350
300
350
First Order
-3.95
-4
50
100
150
200
-4.05
-4.1
-4.15
-4.2
-4.25
y = -0.0009x - 3.9652
-4.3
Second Order
80
70
60
y = 0.0536x + 52.235
50
40
30
20
10
0
0
50
100
150
200
250

Absorbance
Time
[Br2]
ln([Br2])
1/[Br2]
2.737
20
0.02737
-3.598307756
36.53635
2.736
30
0.02736
-3.598673186
36.54971
2.738
40
0.02738
-3.597942459
36.52301
2.737
50
0.02737
-3.598307756
36.53635
2.738
60
0.02738
-3.597942459
36.52301
2.737
70
0.02737
-3.598307756
36.53635
2.739
80
0.02739
-3.597577296
36.50968
2.739
90
0.02739
-3.597577296
36.50968
2.739
100
0.02739
-3.597577296
36.50968
2.737
110
0.02737
-3.598307756
36.53635
2.737
120
0.02737
-3.598307756
36.53635
2.737
130
0.02737
-3.598307756
36.53635
2.736
140
0.02736
-3.598673186
36.54971
2.738
150
0.02738
-3.597942459
36.52301
2.736
160
0.02736
-3.598673186
36.54971
2.736
170
0.02736
-3.598673186
36.54971
2.737
180
0.02737
-3.598307756
36.53635
2.736
190
0.02736
-3.598673186
36.54971
2.736
200
0.02736
-3.598673186
36.54971
2.734
210
0.02734
-3.599404448
36.57644
2.734
220
0.02734
-3.599404448
36.57644
2.733
230
0.02733
-3.599770279
36.58983
2.731
240
0.02731
-3.600502343
36.61662
2.733
250
0.02733
-3.599770279
36.58983
2.733
260
0.02733
-3.599770279
36.58983
2.735
270
0.02735
-3.59903875
36.56307
2.732
280
0.02732
-3.600136244
36.60322
2.732
290
0.02732
-3.600136244
36.60322
2.73
300
0.0273
-3.600868577
36.63004
Zero Order
0.0274
0.02738
0.02736
0.02734
y = -2E-07x + 0.0274
0.02732
0.0273
0.02728
0
50
100
150
200
250
300
350
250
300
350
300
350
First Order
-3.597
-3.5975 0
50
100
150
200
-3.598
-3.5985
-3.599
-3.5995
-3.6
y = -9E-06x - 3.5974
-3.6005
-3.601
-3.6015
Second Order
36.64
36.62
36.6
y = 0.0003x + 36.503
36.58
36.56
36.54
36.52
36.5
0
50
100
150
200
250
SET TWO
Table 4.2: 5ml 0.6M acetone +5 ml 1M HCl + 5ml 0.028M Br2
Absorbance
Time
[Br2]
ln([Br2])
1/[Br2]
2.746
20
0.02746
-3.595024879
36.41660597
2.75
30
0.0275
-3.593569274
36.36363636
2.75
40
0.0275
-3.593569274
36.36363636
2.749
50
0.02749
-3.593932977
36.37686431
2.75
60
0.0275
-3.593569274
36.36363636
2.751
70
0.02751
-3.593205704
36.35041803
2.752
80
0.02752
-3.592842266
36.3372093
2.736
90
0.02736
-3.598673186
36.5497076
2.736
100
0.02736
-3.598673186
36.5497076
2.741
110
0.02741
-3.596847369
36.48303539
2.74
120
0.0274
-3.597212266
36.49635036
2.735
130
0.02735
-3.59903875
36.5630713
2.742
140
0.02742
-3.596482605
36.46973012
2.751
150
0.02751
-3.593205704
36.35041803
2.746
160
0.02746
-3.595024879
36.41660597
2.74
170
0.0274
-3.597212266
36.49635036
2.742
180
0.02742
-3.596482605
36.46973012
2.745
190
0.02745
-3.595389111
36.4298725
Zero Order
0.02755
0.0275
0.02745
y = -4E-07x + 0.0275
0.0274
0.02735
0.0273
0
50
100
150
200
150
200
First Order
-3.592
-3.593
50
100
-3.594
-3.595
-3.596
y = -2E-05x - 3.5939
-3.597
-3.598
-3.599
-3.6
Second Order
36.6
36.55
36.5
y = 0.0006x + 36.375
36.45
36.4
36.35
36.3
0
50
100
150
200

Absorbance
Time
[Br2]
ln([Br2])
1/[Br2]
2.751
20
0.02751
-3.593205704
36.35041803
2.752
30
0.02752
-3.592842266
36.3372093
2.756
40
0.02756
-3.591389833
36.28447025
2.751
50
0.02751
-3.593205704
36.35041803
2.77
60
0.0277
-3.586322866
36.10108303
2.758
70
0.02758
-3.590664407
36.25815809
2.759
80
0.02759
-3.590301891
36.24501631
2.756
90
0.02756
-3.591389833
36.28447025
2.761
100
0.02761
-3.589577253
36.21876132
2.761
110
0.02761
-3.589577253
36.21876132
2.761
120
0.02761
-3.589577253
36.21876132
2.76
130
0.0276
-3.589939506
36.23188406
2.76
140
0.0276
-3.589939506
36.23188406
2.76
150
0.0276
-3.589939506
36.23188406
2.76
160
0.0276
-3.589939506
36.23188406
2.76
170
0.0276
-3.589939506
36.23188406
2.76
180
0.0276
-3.589939506
36.23188406
2.76
190
0.0276
-3.589939506
36.23188406
Zero Order
0.02775
0.0277
0.02765
y = 4E-07x + 0.0275
0.0276
0.02755
0.0275
0
50
100
150
200
150
200
First Order
-3.585
-3.586 0
50
100
-3.587
-3.588
-3.589
y = 1E-05x - 3.5919
-3.59
-3.591
-3.592
-3.593
-3.594
Second Order
36.4
36.35
36.3
36.25
y = -0.0005x + 36.302
36.2
36.15
36.1
36.05
0
50
100
150
200

Absorbance
Time
[Br2]
ln([Br2])
1/[Br2]
2.748
20
0.02748
-3.594296812
36.39010189
2.745
30
0.02745
-3.595389111
36.4298725
2.74
40
0.0274
-3.597212266
36.49635036
2.739
50
0.02739
-3.597577296
36.50967506
2.748
60
0.02748
-3.594296812
36.39010189
2.751
70
0.02751
-3.593205704
36.35041803
2.749
80
0.02749
-3.593932977
36.37686431
2.753
90
0.02753
-3.59247896
36.32401017
2.753
100
0.02753
-3.59247896
36.32401017
2.749
110
0.02749
-3.593932977
36.37686431
2.75
120
0.0275
-3.593569274
36.36363636
2.748
130
0.02748
-3.594296812
36.39010189
2.748
140
0.02748
-3.594296812
36.39010189
2.747
150
0.02747
-3.594660779
36.40334911
2.747
160
0.02747
-3.594660779
36.40334911
2.75
170
0.0275
-3.593569274
36.36363636
2.748
180
0.02748
-3.594296812
36.39010189
2.747
190
0.02747
-3.594660779
36.40334911
Zero Order
0.02756
0.02754
0.02752
0.0275
0.02748
0.02746
0.02744
0.02742
0.0274
0.02738
0.02736
y = 2E-07x + 0.0275
50
100
150
200
150
200
First Order
-3.592
-3.593
50
100
y = 7E-06x - 3.5952
-3.594
-3.595
-3.596
-3.597
-3.598
-3.599
Second Order
36.55
36.5
36.45
36.4
y = -0.0003x + 36.422
36.35
36.3
0
50
100
150
200
Table 7.3: 5ml 6.0M acetone +5 ml 0.10M HCl + 5ml 0.028M Br2
Absorbance
Time
[Br2]
ln([Br2])
1/[Br2]
2.772
20
0.02772
-3.585601105
36.07503608
2.773
30
0.02773
-3.585240419
36.06202669
2.771
40
0.02771
-3.58596192
36.08805485
2.77
50
0.0277
-3.586322866
36.10108303
2.776
60
0.02776
-3.584159143
36.02305476
2.771
70
0.02771
-3.58596192
36.08805485
2.772
80
0.02772
-3.585601105
36.07503608
2.776
90
0.02776
-3.584159143
36.02305476
2.774
100
0.02774
-3.584879864
36.04902668
2.774
110
0.02774
-3.584879864
36.04902668
2.774
120
0.02774
-3.584879864
36.04902668
2.774
130
0.02774
-3.584879864
36.04902668
2.773
140
0.02773
-3.585240419
36.06202669
2.772
150
0.02772
-3.585601105
36.07503608
2.771
160
0.02771
-3.58596192
36.08805485
2.773
170
0.02773
-3.585240419
36.06202669
2.774
180
0.02774
-3.584879864
36.04902668
2.772
190
0.02772
-3.585601105
36.07503608
Zero Order
0.02777
0.02776
0.02775
y = 4E-08x + 0.0277
0.02774
0.02773
0.02772
0.02771
0.0277
0.02769
0
50
100
150
200
150
200
First Order
-3.584
0
50
100
-3.5845
-3.585
y = 1E-06x - 3.5854
-3.5855
-3.586
-3.5865
-3.587
Second Order
36.11
36.1
36.09
36.08
36.07
36.06
36.05
36.04
36.03
36.02
36.01
y = -5E-05x + 36.068
50
100
150
200
Absorbance
Time
[Br2]
ln([Br2])
1/[Br2]
2.758
20
0.02758
-3.590664407
36.25815809
2.768
30
0.02768
-3.587045148
36.12716763
2.771
40
0.02771
-3.58596192
36.08805485
2.77
50
0.0277
-3.586322866
36.10108303
2.771
60
0.02771
-3.58596192
36.08805485
2.77
70
0.0277
-3.586322866
36.10108303
2.77
80
0.0277
-3.586322866
36.10108303
2.77
90
0.0277
-3.586322866
36.10108303
2.771
100
0.02771
-3.58596192
36.08805485
2.772
110
0.02772
-3.585601105
36.07503608
2.771
120
0.02771
-3.58596192
36.08805485
2.771
130
0.02771
-3.58596192
36.08805485
2.77
140
0.0277
-3.586322866
36.10108303
2.77
150
0.0277
-3.586322866
36.10108303
2.77
160
0.0277
-3.586322866
36.10108303
2.769
170
0.02769
-3.586683942
36.11412062
2.769
180
0.02769
-3.586683942
36.11412062
2.771
190
0.02771
-3.58596192
36.08805485
Zero Order
0.02774
0.02772
y = 2E-07x + 0.0277
0.0277
0.02768
0.02766
0.02764
0.02762
0.0276
0.02758
0.02756
0
50
100
150
200
First Order
-3.585
0
50
100
-3.586
150
y = 8E-06x - 3.5873
200
-3.587
-3.588
-3.589
-3.59
-3.591
Second Order
36.3
36.25
36.2
36.15
36.1
y = -0.0003x + 36.137
36.05
0
50
100
150
200
Absorbance
Time
[Br2]
ln([Br2])
1/[Br2]
2.737
20
0.02737
-3.59831
36.53635
2.747
30
0.02747
-3.59466
36.40335
2.746
40
0.02746
-3.59502
36.41661
2.746
50
0.02746
-3.59502
36.41661
2.747
60
0.02747
-3.59466
36.40335
2.747
70
0.02747
-3.59466
36.40335
2.747
80
0.02747
-3.59466
36.40335
2.747
90
0.02747
-3.59466
36.40335
2.747
100
0.02747
-3.59466
36.40335
2.747
110
0.02747
-3.59466
36.40335
2.746
120
0.02746
-3.59502
36.41661
2.748
130
0.02748
-3.5943
36.3901
2.747
140
0.02747
-3.59466
36.40335
2.747
150
0.02747
-3.59466
36.40335
2.746
160
0.02746
-3.59502
36.41661
2.747
170
0.02747
-3.59466
36.40335
2.746
180
0.02746
-3.59502
36.41661
2.745
190
0.02745
-3.59539
36.42987
Zero Order
0.0275
y = 1E-07x + 0.0274
0.02748
0.02746
0.02744
0.02742
0.0274
0.02738
0.02736
0
50
100
150
200
150
200
First Order
-3.594
-3.5945 0
50
100
-3.595
-3.5955
y = 5E-06x - 3.5955
-3.596
-3.5965
-3.597
-3.5975
-3.598
-3.5985
-3.599
Second Order
36.56
36.54
36.52
36.5
36.48
36.46
y = -0.0002x + 36.435
36.44
36.42
36.4
36.38
0
50
100
150
200

Che122l Group 5

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Che122l Group 5

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Sheena Mae E.

Table 2.1: 5ml 6M acetone +5 ml 1M HCl + 5ml 0.01410M Br2

Table 3.1: 5ml 6M acetone +5 ml 1M HCl + 5ml 0.028M Br2

Table 5.2: 5ml 3.0M acetone +5 ml 1M HCl + 5ml 0.028M Br2

Table 6.2: 5ml 6.0M acetone +5 ml 1M HCl + 5ml 0.028M Br2

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