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spec 2011

spec 2011

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Published by Christopher Grant
chemistry past paper for spectroscopy
chemistry past paper for spectroscopy

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Categories:Types, School Work
Published by: Christopher Grant on Apr 17, 2012
Copyright:Attribution Non-commercial

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04/17/2013

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S?EC
/[5
THEIJ1\'lVERSITYOF
THE
'VESTINDrESST.AUGUSTINE
EXAMINATIONSOFAPRll.,
I
M.4Y2011
CodeandName
ofCourse:
CHElVI2015-SI'ECmOSCOpy
Duration:
Two
(2)hours
iNSTRUCTIONSTOCANDIDATES:
ThispaperbasEIGIIT(8)pages,THREE(3)SECTIONSandSIX
(6)
questions.
Youarerequired
to:
1.
Answer
FOUR(4)
QUESTI()NS.2.AnsweratleastONE(1)QUESTIONfromEACHSECTION.
3.ANSWEREACH'SECTIONINASEPARATEAN·SWER
BOOKLET.
THE
lJSE
OFNON-PROGRAMMABLE
CALC'ULATORS
IS
PER.MITTED.
SPECTROSC()PICDATABOOKLETSWIl,LBEPROVIDED.
h
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6.63
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Page2
SECTIONA
1"Thefollowingequationsmaybeneeded~oanswerthefollowingquestion:
Er
=
hBJ(1
+
1)
I1,.
=he
v
(v+lh)(a)Whatpropertymustadiatomicmoleculepossesstogivearotationalspectrum.(2marks)(b)GiveabriefdescriptionofthegasphaseinfraredspectrumofthediatomicmoleculeHCI.(6marks)(c)Therotationalconstantof
lH35Cl
is320GHz.Determinethelengthofthe
Hel
bond.(M
r
of
3j
CI
=
35.0andIH=1.0)(7marks)(d)ThebondforceconstantofHCIis516Nm"lCalculatethefundamentalvibrationalfrequencyof
lH35Cl
inwavenumbers.(6marks)(e)Thefundamentalvibrationalfrequencycorrespondstoatransitionfromthev=Otov=IvibrationalenergylevelTransitionsformv=0to
....=2,
knownasthefirstovertonevibration,canalsobedetected(withlowerintensity).Whyisthefirstovertonevibrationallowedandatwhat(approximate)frequencywouldyouexpecttoseeit?(4marks)
PLEASETURN
TOTHE
NEXT
PAGE
©
TheUniversityoftheWestIndiesCourseCode
CHEM
2015
.Ql\_
2010/201l/..:~
c=========~--~~~~
 
Page3Thespectrumbelowisthe
IH
NIv'IR
spectrumof1-bromo-z-fluoroethanc,usingaspectrometerwithanoperatingfrequencyof100
:MHz.
v
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4.494.204.903.80
Chel'licalShif"t
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(P"P"')
3:.
GO
3.40
3.2103
(a)Howmanyinequivalentsetsofprotonsareinthesampleof
l-bro
mo-Z-fluoroethane?(1mark)(b)Measurethechemicalshiftsinthespectrum(inppm).(4marks)(c)"Measurethespin-spincouplings(inHz).Note:
l~
hasanuclearspinof%andanaturalabundanceof
100%.
(6marks)(d)
Explain
theappearanceandthemagnitudeoftheobservedspin-spincouplingpatternsinthisspectrum.(6marks)(e)Whatwould
you
expecttheprotondecoupled
Be
NMRspectrumofl-brcmo-z-fluoroethanctolooklike?(6marks)(f)Whatwouldyouexpecttheprotondecoupled
191"
NMRspectrumofI-bromo-2-fluoroethanetolooklike?(2marks)
ENDOFSECTIONA
PLEASETlJRNTOTHENEXTPAGECourseCodeCHEM2015
20l0/2011l.:~.,,,n
1£..
©
TheUniversityoftheWestIndies

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