Ligantes

Contagem eletrnica de tomos neutros 2 2 2 2 2 2

Contagem eletrnica de estado de oxidao 2 2 2 2 2 2 Alkoxide Thiolate

Ligantes

Contagem eletrnica de tomos neutros (M OR) (M SR) (M CR2) (M CR) 1 1 2 3 1 3

Contagem eletrnica de estado de oxidao 2 2 4 6 2 4

Carbonyl

(M Co)

Thiocarbonyl (M CS) Phosphine Amine Dinitrogen Dihydrogen (M PR3) (M NR3) (M N N) H M| H C M || C | C M ||| C |

Carbene = Alkylidene Cabyne = Alkylidyne - Allyl - Allyl M M CH2

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Alkene

- Enzyl

C M // C /

Alkyne *

4 Cyclopentadienyl M

Isocyanide

(M CNR)

5 Cyclopentadienyl M

Nitrosyl bent (M N O

6 Benzene | M

Nitrosyl linear (M N O)

7 Cycloheptatrienyl M

Halogen

(M X)

8 cyclooctatetraenyl | M

10

Hydrogen Alkyl

(M H) (M R) O (M C R) (M Ph) (M NR2) (M PR2)

1 1

2 2

Carbonyl Halogen

[M (CO) M] (M X M) | C M - ||| -M C | [M H M] [M (CR3) M] [M (NR2) M] [M (PR2) M]

2 3

2 4

Acyl

Alkyne

Aryl Amine Phosphide

1 1 1

2 2 2

Hidrogen Alkyl Amide Phosphide

1 1 3 3 3

2 2 4 4 4

Cyclopentadieno Clyclobutadieno

Alkoxide [M (OR) M]