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Table Of Contents

1 INTRODUCTION
1.1 SCOPE
1.2 CHLORINE INSTITUTE STEWARDSHIP PROGRAM
1.3 DISCLAIMER
1.4 APPROVAL
1.5 REVISIONS
1.6 REPRODUCTION
2 CHEMISTRY AND PHYSICAL PROPERTIES OF SODIUM HYPOCHLORITE
OR
2.4 AQUEOUS CHEMISTRY
2.5 REACTIONS OF SODIUM HYPOCHLORITE
2.6 DANGEROUS REACTIONS OF SODIUM HYPOCHLORITE
2.7 VAPOR PRESSURE OF 12.5% SODIUM HYPOCHLORITE SOLUTIONS
2.8 SPECIFIC GRAVITY OF SODIUM HYPOCHLORITE SOLUTIONS
2.9 APPROXIMATE FREEZING POINT OF SODIUM HYPOCHLORITE SOLUTIONS
2.10 SODIUM CHLORATE CRYSTALS
3 STABILITY OF HYPOCHLORITE SOLUTIONS
3.1 GENERAL
3.2 BLEACH DECOMPOSITION REACTIONS
3.3 CONCENTRATION EFFECT
3.4 EFFECT OF TRANSITION METAL IONS
3.5 UV-LIGHT EFFECT
3.6 EFFECT OF ANIONS
3.7 PH EFFECT
4 OVERVIEW OF PRODUCTION METHODS FOR SODIUM HYPOCHLORITE
4.1 OVERVIEW
4.2 TRAINING
4.3 DESIGN AND OPERATING GUIDELINES
5 ADDITIONAL SAFETY CONSIDERATIONS
5.1 GENERAL
5.2 PRECAUTIONS FOR HANDLING SODIUM HYPOCHLORITE SOLUTIONS
Precaution for handling sodium hypochlorite solutions include:
6 HANDLING, STORAGE AND EQUIPMENT
6.1 GENERAL GUIDELINES
6.2 STORAGE CONTAINERS
6.3 TRANSFER SYSTEMS
6.4 SODIUM HYPOCHLORITE FEED SYSTEMS
7 NON-BULK PACKAGING AND SHIPPING OF HYPOCHLORITE SOLUTIONS
7.1 PRODUCT REGISTRATION
7.2 HAZARDOUS MATERIALS REGISTRATION
7.3 TRAINING
7.4 CONTAINERS
7.5 SHIPPING PAPERS
7.6 EMERGENCY RESPONSE INFORMATION
7.7 LABELS AND MARKINGS
7.8 PLACARDS
7.9 PERSONAL PROTECTIVE EQUIPMENT
7.10 SAFETY EQUIPMENT
7.11 MEDICAL EVALUATION
7.12 PRODUCTION/FILLING EQUIPMENT
7.13 SHIPPING DRUMS AND OTHER NON-BULK CONTAINERS
7.14 STANDARD OPERATION PROCEDURES
7.15 WASTES
7.16 REPORTING REQUIREMENTS
8 BULK PACKAGING AND SHIPPING OF SODIUM HYPOCHLORITE SOLUTIONS
8.1 PRODUCT REGISTRATION
8.2 TRAINING
8.3 BULK TANK TRAILERS (TANKERS)
8.4 SHIPPING PAPERS
8.5 HAZARDOUS MATERIALS REGISTRATION
8.6 HAZARDOUS SUBSTANCES
8.7 EMERGENCY RESPONSE INFORMATION
8.8 LABELS AND MARKINGS
8.9 PLACARDING
8.10 PERSONAL PROTECTIVE EQUIPMENT
8.11 SAFETY EQUIPMENT
8.12 MEDICAL EVALUATIONS
8.13 RECEIVING AND SPOTTING SODIUM HYPOCHLORITE SOLUTION CARGO TANKS
8.14 SODIUM HYPOCHLORITE SOLUTION CARGO TANK LOADING
8.15 SODIUM HYPOCHLORITE CARGO TANK UNLOADING
8.16 MAINTENANCE REQUIREMENTS
8.17 STANDARD OPERATING PROCEDURES
8.18 WASTE
8.19 REPORTING REQUIREMENTS
9 SECURITY
9.1 GENERAL
10 EMERGENCY RESPONSE AND DISPOSAL
10.1 NOTIFICATION OF A SPILL
10.2 SPILLS
10.3 RECOVERY OF SPILLED MATERIAL
10.4 DISPOSAL AND NEUTRALIZATION OF SODIUM HYPOCHLORITE SOLUTIONS
11 ANALYTICAL PROCEDURES
11.1 GENERAL
11.2 SAMPLING
11.3 SPECIFIC GRAVITY
11.4 DETERMINATION OF PH
11.5 DETERMINATION OF SODIUM HYPOCHLORITE CONCENTRATION
11.6 DETERMINATION OF SODIUM HYDROXIDE AND SODIUM CARBONATE
APPENDIX A DEFINITIONS
APPENDIX B REGULATIONS
APPENDIX C DILUTION OF SODIUM HYPOCHLORITE SOLUTIONS (NaOCl) (11/16/04)
APPENDIX D REFERENCES
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41207582 Sodium Hipochlorite Manual

41207582 Sodium Hipochlorite Manual

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Published by: kreeshnu on Apr 30, 2012
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