: HPC-PASECO .

2011


1.

2.

................................................................................................................................................... 3
1.1

................................................................................................................. 3

1.2

................................................................................................................. 4

............................................................................................................................... 6
2.1

2.1.1

........................................................................................................... 6

2.1.2

....................................................................................................... 7

2.2

3.

................................................................................................10

2.2.1

.........................................10

2.2.2

..........................................11

2.2.3

....................................................................................................................17

..................................................................................................................................................18
3.1

...................................................................................................18

3.1.1

.....................................................................................................................................18

3.1.2

- .....................................................18

3.1.3

.....................................................................19

3.1.4

..........................................................................21

3.2

4.

......................................................................................................... 6

............................................................................24

3.2.1

........................................................24

3.2.2

..................................................................................................25

3.2.3

.........................................................................28

.............................................................................................................32
4.1

.............................................32

4.2

...........32

4.2.1

.............................................................................................................32

4.2.2

() ..................................................................................34

4.2.3

..........................................................35

4.3
-
35
5.

.......................................................................................................................................39

. ..
III.
V.
(:
)
V.
2009 2010 (: )
V. 1981, 1991 2001 (: )
V.
V. 892//11-07-2001: ,
98/83/
3 1998 ( 2/2600/2001) EK 630//26-04-2007:

2/2600/2001 ,
98/83/ 3
1998
IX. Langelier (Langelier Saturation Index) Dow
Water & Process Solutions: FILMTEC Reverse Osmosis Membranes - Technical
Manual
X. First desalination plant in Cyprus product water aggresivity and corrosion control
V.Siamarou-Marangou and Kyros Savvides 2001, ELSEVIER

01. 1:15.000
02. 1:15.000

1.
1.1


84/2011
13
( ).
,
.
:
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2. (,
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1 2
.

1:

2:

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4:

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,
.
.
, , HPCPASECO .

1.2
:
1. :

.. / ( , ,
, TERRAMENTOR )
2. :
S&B ..
(HPC PASECO , 2007)
3.
: 2007-2011
4. 2009-2010 (

4

5.
6.
7.
8.

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..

(3)

(2)
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).

2.
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.
:

,

( )

2.1.1

,
.
, (1981, 1991, 2001)
(2011).

1981, 1991 2001 .. (
).

1: 1981, 1991 2001

. .

1981

1991

2001

679

553

644

838
1.017
919
1.103
4556

668
1.080
921
1.168
4390

788
1.029
919
1.391
4771

2011
() .
:
6

2001.

(2011),
.

2: (2011)

. .

2.1.2

('81-'91)
('91-'01)
1

2011

-2,03%

1,54%

0,80%

697

-2,24%

1,67%

0,80%

853

0,60%

-0,48%

0,80%

1.114

0,02%

-0,02%

0,80%

995

0,57%

1,76%

0,80%

1.506

-0,37%

0,84%

0,80%

5.167

.
, ,
,
.
10% .. ,
30% .. .
,
(
).

, : &
, (2006)
1


. :

(, ),

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100% .
50% .

3: ,

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()

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2583

50

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:

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.

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20%
70%
100%
30%

 ,
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( travel.diadiktyo.net,
) .

30% .


.

.. ( )
.

4: , (2011)

..

..

..

..

82

91

1.842

156

105

3.599

14

355

316

7.953

32

2.184

571

38.868

55

3.535

972

62.902

13

259

293

5.806

80

91

1.842

2011
()
5%2.

, : &
, (2006)
2

2.2
2.2.1

,

.
.

.
5:

(m3)

23/7/2007 - 23/10/2007

38.680

23/10/2007 - 20/12/2007

18.582

20/12/2007 - 31/12/2007

3.487

2007:

60.749

1/1/2008 - 20/3/2008

29.119

20/3/2008 - 20/6/08

53.609

20/6/08 - 22/9/08

96.481

22/9/08 - 20/12/08

74.117

20/12/08 - 31/12/08

3.146

2008:

256.472

1/1/09 - 20/3/09

54.625

20/3/09 - 19/6/09

99.000

19/6/09 - 20/9/09

90.146

19/6/09 - 20/9/09

105.577

20/9/2009 - 20/12/09

97.863

20/12/2009 - 31/12/09

8.569

2009:

455.780

01/01/2010 - 20/03/2010

62.482

21/03/2010 - 20/06/2010

129.284

21/06/2010 - 20/09/2010

93.383

21/06/2010 - 20/09/2010

103.087

21/09/2010 - 20/12/2010

98.701

21/12/2010 - 31/12/2010

8.750

2010:

495.687

10

(m3)

1/1/2011 - 20/03/2011

53.756

21/03/2011 - 20/06/2011

91.391

2011 ( 20/6):

145.147

()
.

(.. , ).


( ) .

6:

(m3)

(m3)

(m3)

2009

244.465

5.000

249.465

2010

292.450

5.000

297.450

2009 : 1-(249.465/455.780)=0.4527 = 45,27%

2010 : 1-(297.450/495.687)=0.6000 = 40,00%

2.2.2

2.2.2.1

, 2001.
2011
.


.
11

 7:

. .

150

150

150

150

150

, .

,
.

8:

10%

10%

10%

10%

10%

**

20%

20%

20%

20%

20%

**

5%

5%

5%

5%

5%

**

.
,
.

(, , )
, (, , , , ,
)
(, , )

+20%
0%
-20%

12

9:

(m3)

3.760

4.601

6.009

5.367

8.123

27.860

3.396

4.156

5.427

4.848

7.337

25.164

4.700

5.751

7.511

6.709

10.154

34.825

4.548

5.566

7.269

6.502

10.021

33.906

4.700

5.751

7.511

6.720

10.534

35.216

4.548

5.566

7.269

6.526

10.666

34.574

6.515

7.973

10.412

9.378

19.408

53.685

6.515

7.973

10.412

9.433

22.705

57.038

5.458

6.679

8.723

7.822

12.405

41.086

4.700

5.751

7.511

6.718

10.349

35.029

4.548

5.566

7.269

6.492

9.827

33.702

3.760

4.601

6.009

5.367

8.123

27.860

57.144

69.934

91.332

81.882

139.653

439.944

2.2.2.2

,
.

,
.



.

13


50% .

(<1000 )

.
.
10:

. .

/
/

225

225

225

225

225

, ,
,
.
10% .. ,
30% .. .

14

 11:

(m3)

28

555

583

32

1.085

1.117

95

2.398

2.493

224

15.236

15.459

381

24.656

25.037

88

1.751

1.839

28

555

583

875

46.236

47.112

,
(
). .

.
.

15

 12:

(m3)

1.945

2.380

3.108

2.776

4.202

14.410

1.945

2.380

3.108

2.776

4.202

14.410

3.889

4.760

6.216

5.552

8.403

28.821

2.2.2.3

.

( ),
.

.
13:

(m3)

27.860
25.164
34.825
34.489
36.333
37.068
83.555
96.485
42.925
35.612

16

 (m3)

33.702
27.860
515.877

30%.

2.2.3

(2011)

2010 (515.877 m3 495.687 m3).

( 30%)
40%
.
,
~35% 5% 1-2%
, 0,5-1% 3-4%
.

,

,
.

17

3.
3.1
3.1.1

, ,
, , ,

,
.

.
,
.
,

.

.

3.1.2

,
.
,
.
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( 8,5/m3). ,

(
),
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. 22

18

 ,
.

...
2007. ...-
3,5 . .
3.360 m3/.
.
,
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3.1.3

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.
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.
(
).

19

 5:

(. 6),

. , Ph
.

3, .
.

6:

site www.QualityNet.gr 15/7/2009 .

3

20

 7: .

,
, 100 m3, .
,
~2.950 m3, .

5 2.2.1.

3.1.4

.
, ,

.

(,
).

,
4

21

 ~2.950 m3.
. :
1. 90 HDPE
,
,
2. PVC
.
25 m3 .
3. PVC 110
( ..)
4. HDPE

.
HDPE 110
. HDPE 110
.
5.
.
6.
500m3
.
PVC, 500 m
.

:
1. .

, ( )
/
2. ()
.



3. (/)

4.
,

5. PVC

22

6. ,
, 100m
,
.

, , ,

.

.

30-50% .
50-70% .
,
.
.
, , ,
1km ( )
.
.

. ,
,
.

23

3.2
3.2.1

EK 630//26-04-2007:
2/2600/2001
, 98/83/
3 1998.
,
:
14: EK 630//26-04-2007

< 20cfu/ml

A 37 C

:
20cfu/ml)

E-coli

0cfu /100 ml

0cfu /100ml

0cfu /100ml

0,2-0,5mg/l

pH

6,5 9,5

<2.500 S/cm

(P)

250mg/l CaCO3

(T)

250mg/l CaCO3

250mg/l CaCO3

275 mg/l HCO3-

250 mg/l

0,50 mg/l

50 mg/l

250 mg/l

0,2 mg/l

200 mg/l

12 mg/l

1,0 mg/l

24

1NTU

3.2.2

4:
1.
.

Fe(OH)2
. (2H+ +2e- H2 F2++2 OHFe(OH)2)
2.

. (O2+2H2O +4e- 4OH- F2++2 OH-Fe(OH)2)
, ,
,
,
.
Ca(HCO3)2CaCO3+H2O+CO2
S Langelier (Saturation index)

.
Langelier (1936)5 CaCO3
. H
- (2001)6

Langelier.
Water Treatment Handbook, Degremont, 1979
Langelier, W.F., 1936The analytical control of anticorrosion water treatment. J.Amer.Water
Works Association
6 V.Siamarou-Marangou and Kyros Savvides 2001, First desalination plant in Cyprus product
water aggresivity and corrosion control, ELSEVIER -

4
5

25

 , Langelier (LSI) 7
LSI = pH - pHs

CaCO3. LSI
.
, .
pHs :
pHs = pCa + pAlk + "C"
:
pCa:
( 15)
Ca mg/l.
pAlk:
( 15) CaCO3
mg/l.
C:
( 15)
mg/l (,
, , , , , , , ).

Dow Water & Process Solutions, FILMTEC Reverse Osmosis Membranes Technical Manual

26

 15: Langelier (: Water Conditioning for Industry, Sheppard T.Powell,

1954)

27

3.2.3

(
2/...38295, 630/2007,
).
:
1. 9/6/2011

: . .1


. .2
( )
.
,

. .1

. .2
10/6/2011
.
2. 23/6/2011

. .
24/6/2011
.
3. 14/7/2011

.

.

,
. 18/7/2011

.
( )
28


200C, Langelier
:
10/06/2011:
pHs = pCa + pAlk + "C" = 5 + 4,3 + 2,27 = 11,57
LSI = pH - pHs = 5,5 11,57 = -6,07
24/06/2011:
pHs = pCa + pAlk + "C" = 4,35 + 3,84 + 2,3 = 10,49
LSI = pH - pHs = 8,5 10,49 = -1,99
18/07/2011:
pHs = pCa + pAlk + "C" = 4,6 + 3,6 + 2,29 = 10,49
LSI = pH - pHs = 8,4 10,49 = -2,09

( 2/...38295, 630/2007,
) :
16:

10/06/2011

24/06/2011

18/07/2011

0/100ml

310

0/100ml

0,2-0,5mg/l

-*

<0,15

0,21

6,5 9,5

5,5

8,5

8,4

250 mg/l

180.8

310.2

254

1 mg/l

1,3

1,5

0,33

>0 (

-6,07

-1,99

-2,09

pH

Cl-

B
LSI
( Langelier)

29

1. 10/06/2011: pH 5,5,
6,5 .
1,3 mg/lt 1,0
mg/lt .
.
LSI,
DOW (. )
, ,
1
,
.
2. 24/06/2011:


. 310,2 mg/lt
250 mg/lt .
1,5 mg/lt 1,0
mg/lt .
.
LSI,
DOW ,
, 1
,
.
3. 18/07/2011:
254 mg/lt 250 mg/lt
( 2/...38295, 630/2007,
).
Langelier (LSI),
DOW (.
) ,
, 1
,
.
0,33 mg/lit
.
0,7-0,9 mg/lt.
,
, .


( ).
30


,
pH 9,5.
3.2.3.1

.

( ).

2008-2009

Langelier. 4 .

pH
.
. :
1. / 7/2/2008, pH
10,05 9,5

2. / 20/2/2008, pH
10,4 9,5

3. / 10/4/2008, pH
10, 5 9,5
, 1,1 1,0

4. / 6/7/2009,
LSI = -0,655
, 291mg/l
200mg/l .

.

31

4.
4.1
1.

2.

.

. , pH
8,0 8,2
LSI , .
+ 0,05 +0.1.
10 12
.
.


(high rejection membranes).
, /
.
,
LSI, ,
, pH TDS.

4.2

4.2.1

- ,

10% (
32

 ,
) 50%
,
.
25 - 30%.
35%.
:
)

5%
10% 20,

.
(
5% 40)

.

(.. ).
-
.
:
i.
:
. 3
.
ii.
- :

(..
,

(>160 mm) (..
)
iii.
:
, ( )

,
.

33

 ,
, ,

.
)

. :
1) , -
2)

3)
,
4)
5)
.


( 30-50% ).
,
1km
.
4.2.2

()

:
1. .
, ,

.
.
.
2.

. .
/
.
3. (/)
.
4.
.

34

5.
PVC .
6. ,
100m ,
.

4.2.3

.


. ,
,
( ) .


. ,

,
(
).

4.3

.
( , 2008)
,
. ,


,
,
( , 2008).


.

.
35

, .

:
1.

.
.

.
2.
,
(
),
.

:

, ,

.

.
3.


,
.
.
:

36







.
4. ()

. , ,
.

- , - .

,
, . ,

:

, ,
,

,
.
-

(.. )-
,
.

1 p.p.m.
( 5% ,

37

) 30 gr/m.


.

.
.

.
, ,


.

38

5.

, : &
, 2006
Water Treatment Handbook, Degremont, 1979
Langelier, W.F., The analytical control of anticorrosion water treatment. J.Amer.Water
Works Association, 1936
V.Siamarou-Marangou and Kyros Savvides, First desalination plant in Cyprus product
water aggresivity and corrosion control, ELSEVIER, 2001-

Dow Water & Process Solutions, FILMTEC Reverse Osmosis Membranes Technical
Manual -

Koutsoyiannis, D., N. Zarkadoulas, A. N. Angelakis, and G. Tchobanoglous, Urban water

management in Ancient Greece: Legacies and lessons, Journal of Water Resources
Planning and Management - ASCE, 134 (1), 4554, 2008

39

40

 :
..

41

 III:

42

 V:

(:
)

43

 V:

2009 2010 (:
)

44

 V:
1981, 1991 2001 (: )

45

 V:

46

 V: 892//11-07-2001:
,
98/83/
3 1998 (
2/2600/2001) EK 630//26-04-2007:

2/2600/2001
,
98/83/
3 1998

47

 IX: Langelier
(Langelier Saturation Index) Dow Water &
Process Solutions: FILMTEC Reverse Osmosis
Membranes - Technical Manual

48

 X: First desalination plant in Cyprus

product water aggresivity and corrosion control
V.Siamarou-Marangou and Kyros Savvides 2001,
ELSEVIER

49