S GIO DC O TO THI BNH Trng THPT Chuyn

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THI KHO ST CHT LNG KHI 12 LN 3 NM HC 2011-2012 MN HO HC 12 (Khi B) Thi gian lm bi: 90 pht; (50 cu trc nghim) H, tn th sinh:........................................................................ S bo danh:...............................................................................

Cu 1: Hn hp Z gm 2 axit cacboxylic no, n chc k tip nhau trong dy ng ng. t chy hon ton hn hp Z thu c khi lng H2O t hn khi lng CO2 l 5,46 gam. Nu ly 1/2 lng hn hp Z trn cho tc dng vi dung dch NaOH va th sau phn ng thu c 3,9 gam hn hp mui khan. Cng thc ca axit c khi lng mol phn t nh trong Z: A. C3H7COOH B. HCOOH C. CH3COOH D. C2H5COOH Cu 2: Cu hnh electron khng ng? A. Cr ( z = 24): [Ar] 3d44s2 B. Cr2+: [Ar] 3d4 5 1 C. Cr ( z = 24): [Ar] 3d 4s D. Cr3+: [Ar] 3d3 Cu 3: Cho 11,6 gam mui FeCO3 tc dng va vi dung dch HNO3, c hn hp kh CO2, NO v dung dch X. Khi thm dung dch HCl (d) vo dung dch X, th dung dch thu c ho tan ti a bao nhiu gam bt ng kim loi, bit rng c kh NO bay ra. A. 32 gam. B. 6,4 gam C. 3,2 gam. D. 64 gam. Cu 4: Cho cc s phn ng sau : xt xt xt a) 6X Y b) X + O2 Z c) E + H2O G
H xt d) E + Z F e) F + H2O Z + G. iu khng nh no sau y ng A. Cc cht X, Y, Z, E, F, G u c cng s C trong phn t. B. Ch c X v E l hirocacbon C. Cc cht X, Y, Z, E, F, G u phn ng c vi dung dch AgNO3 trong NH3. D. Cc cht X, Y, Z, E, F, G u c nhm chc CHO trong phn t. Cu 5: Ho tan ht hn hp FeS2, FeCO3 bng dung dch HNO3 c, nng c dung dch X v 4,48 lt (ktc) hn hp kh Y c t khi so vi hiro bng 22,75. Hp th ton b kh Y vo 300 ml dung dch NaOH 1M c dung dch Z. Tng khi lng cc cht tan trong Z l: A. 18,85g. B. 20,00g. C. 16,85g. D. 32,20g. Cu 6: Nung nng AgNO3 c cht rn X v kh Y. Dn kh Y vo cc nc c dung dch Z. Cho ton b X vo Z thy X tan mt phn v thot ra kh NO duy nht. Gi thit cc phn ng xy ra hon ton. Phn trm khi lng ca X khng tan trong Z l A. 20%. B. 25%. C. 30%. D. 40%. Cu 7: Phn ng gia HNO3 vi Fe3O4 to ra kh X (sn phm kh duy nht) c tng h s trong phng trnh ho hc l 20 th kh X l A. NO. B. N2. C. NO2. D. N2O. Cu 8: Cho 1,2 lt hn hp gm hiro v clo vo bnh thu tinh y kn v chiu sng bng nh sng khuch tn. Sau mt thi gian ngng chiu sng th thu c mt hn hp kh cha 30% hiroclorua v th tch v hm lng ca clo gim xung cn 20% so vi lng clo ban u. Thnh phn phn trm v th tch ca hiro trong hn hp ban u bng A. 88,25% B. 30,75% C. 66,25% D. 81,25% Cu 9: Chia hn hp X gm hai axit n chc, k tip nhau trong dy ng ng ra hai phn bng nhau. Phn I phn ng va vi 500 ml dung dch NaOH 1M. Phn II phn ng vi lng d dung dch AgNO3/NH3 to ra 43,2 gam Ag. Phn trm khi lng ca axit c khi lng mol phn t nh trong X l A. 33,82%. B. 35,55%. C. 18,4%. D. 36,22% 0 Cu 10: T m gam tinh bt iu ch c 575 ml ancol etylic 10 (khi lng ring ca ancol nguyn cht l 0,8 gam/ml) vi hiu sut c qu trnh l 75%, gi tr ca m l: A. 60,75g B. 108g C. 135g D. 75,9375g Cu 11: Cho cc nhn xt sau: 1- Cht bo thuc loi cht este. 2- T nilon, t capron, t enang u iu ch bng phn ng trng ngng. 3- Vinyl axetat khng iu ch c trc tip t axit v ancol tng ng. 4- Nitro benzen phn ng vi HNO3 c (xc tc H2SO4 c) to thnh m-initrobenzen. 5- Anilin phn ng vi nc brom d to thnh p-bromanilin.

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S nhn xt ng l: A. 4. B. 5. C. 2. D. 3. Cu 12: Cho 2 mol axit axetic v 3 mol ancol etylic vo bnh cu cho phn ng sau xy ra: CH3COOH + C2H5OH CH3COOC2H5 + H2O Khi phn ng t ti trng thi cn bng, trong hn hp c 1,2 mol este. nhit , hng s cn bng ca phn ng c gi tr l A. 2,8 B. 3,2. C. 1,2. D. 1,0. Cu 13: ho tan hon ton mt hiroxit ca kim loi M (c ho tr khng i) cn mt lng axit H2SO4 ng bng khi lng hiroxit em ho tan. Cng thc phn t hiroxit kim loi l A. Cu(OH)2. B. Mg(OH)2 C. Fe(OH)3 D. Al(OH)3 Cu 14: Mt s hin tng sau: (1) Thm (d) NaOH vo dung dch K2Cr2O7 th dung dch chuyn t mu da cam sang mu vng (2) Thm (d) NaOH v Cl2 vo dung dch CrCl2 th dung dch t mu xanh chuyn thnh mu vng.
(3) Thm t t dung dch NaOH vo dung dch CrCl3 thy xut hin kt ta vng nu tan li trong NaOH (d) (4) Thm t t dung dch HCl vo dung dch Na[Cr(OH)4] thy xut hin kt ta lc xm, sau tan li.

S ng: A. 1 B. 2 C. 3 D. 4 Cu 15: Dng phng php in phn nng chy iu ch c A. cc kim loi hot ng trung bnh v yu. B. tt c cc kim loi vi tinh khit cao. C. ch cc kim loi hot ng mnh. D. ch cc kim loi hot ng trung bnh. Cu 16: t chy hon ton 1,1g hn hp X gm metan, etin, propen thu c 3,52g CO2. Mt khc, khi cho 448 ml hn hp kh X (ktc) i qua dung dch nc brom d th ch c 4g brom phn ng. Phn trm th tch etin trong hn hp X l: A. 40% B. 50% C. 25% D. 60% Cu 17: Cho dung dch cha 1,22 gam cht hu c X l ng ng ca phenol tc dng vi nc brom (d) thu c 3,59 gam hp cht Y cha 3 nguyn t brom trong phn t (H=100%). Cng thc phn t ca X l A. C8H10O. B. C10H14O. C. C7H8O. D. C9H12O. Cu 18: Mt hn hp gm Al2(SO4)3 v K2SO4, trong s nguyn t oxi chim 20/31 tng s nguyn t c trong hn hp. Ho tan hn hp trn vo nc ri cho tc dng vi dung dch BaCl2 d, hi khi lng kt ta thu c gp bao nhiu ln khi lng hn hp ban u? A. 1,788 ln B. 1,488 ln C. 1,588 ln D. 1,688 ln Cu 19: Nh t t 3V1 ml dung dch Ba(OH)2 (dung dch X) vo V1 ml dung dch Al2(SO4)3 (dung dch Y) th phn ng va v ta thu c kt ta ln nht l m gam. Nu trn V2 ml dung dch X trn vo V1 ml dung dch Y th kt ta thu c c khi lng bng 0,9m gam. So snh t l V2/V1 thy A. V2/V1 = 2,7 hoc V2/V1 = 3,55 B. V2/V1 = 1,7 hoc V2/V1 = 3,75 C. V2/V1 = 2,5 hoc V2/V1 = 3,55 D. V2/V1 = 0,9 hoc V2/V1 = 1,183 Cu 20: phn bit cc cht lng gm: C6H5OH, C2H5OH, CH3COOH v CH2 = CH - COOH ta dng ho cht: A. dung dch hn hp NaCl v NaOH B. dung dch Br2 C. CaCO3 v dung dch Br2 D. qu tm m v dung dch Br2 Cu 21: Cht A c cng thc: CxHyOz, cho A tc dng vi NaOH thu c (B) v (C). (C) khng tc dng O2 hhCaO,NaOH Na vi Na v: (C) (D) (B) ankan n gin nht. Thnh phn % theo khi xt t0 lng ca cacbon trong A l: A. 60%. B. 55,8% C. 57,4% D. 54,6% Cu 22: Pht biu no sau y khng ng? A. Cht bo lng l cc triglixerit cha gc axit no trong phn t B. Phn ng ca glixerol vi axit bo c H2SO4 c xc tc (to) l phn ng este ha C. Phn ng ca cht bo vi NaOH l phn ng x phng ha D. Etyl acrylat, triolein, tristearin u l este Cu 23: Dy cc cht no sau y tc dng c vi dung dch AgNO3/NH3? A. Glucoz, anehit fomic, axit fomic, saccaroz. B. Fructoz, anehit fomic, axit fomic, but-2-in C. Glixerol, axetilen, olein, saccaroz. D. Glucoz, fructoz, anehit fomic, vinylaxetilen.
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t , xt Cu 24: Thc hin phn ng tng hp amoniac N2 + 3H2 2NH3. Khi phn ng t ti cn bng, nng mol ca cc cht nh sau: [N2 ] = 0,5 mol/l; [NH3 ] = 0,8 mol/l; [H2 ] = 0,8 mol/l. Hng s cn bng ca phn ng trong iu kin trn l: A. 5 B. 1,5 C. 2,5 D. 3 Cu 25: Cho 0,1 mol phenyl axetat tc dng vi 300ml dung dch NaOH 1M, sau khi phn ng xy ra hon ton, c cn dung dch th thu c bao nhiu gam cht rn khan? A. 12,2g B. 23,8g C. 19,8g D. 21,8g Cu 26: Mt dung dch c cha H2SO4 v 0,543 gam mui natri ca mt axit cha oxi ca clo (mui X). Cho thm vo dung dch ny mt lng KI cho n khi iot ngng sinh ra th thu c 3,05 gam I2. Phn trm khi lng Clo trong mui X l A. 33,45%. B. 39,23%. C. 40%. D. 48,56%. Cu 27: t chy han ton 5,15 gam mt cht hu c X cn phi dng 5,88 lt oxi. Sau phn ng thu c 4,05 gam H2O v 5,04 lt hn hp gm CO2 v N2. Bit rng cc th tch kh u o iu kin tiu chun. T l s nguyn t C v N trong phn t X l: A. 3:1 B. 5:2 C. 4:1 D. 2:1 Cu 28: Hp cht hu c A c cng thc phn t C3H9NO2. Cho A tc dng vi dung dch NaOH thu c mui B v kh C lm xanh qu tm m. Nung B vi vi ti xt thu c mt hirocacbon c khi lng phn t nh nht. Phn trm theo khi lng cacbon trong cht C l A. 38,71% B. 53,33% C. 33,33% D. 26,67% Cu 29: Thc hin phn ng nhit nhm 26,8 gam hn hp bt nhm v st (III) oxit c hn hp G. Ho tan G trong dung dch NaOH d, thot ra 6,72 lt kh H2 (cc phn ng xy ra hon ton, th tch kh o ktc). Khi lng nhm c trong hn hp ban u bng A. 10,8 gam. B. 8,1 gam. C. 5,4 gam. D. 11,2 gam Cu 30: Nguyn t ca nguyn t X c tng s electron trong cc phn lp p l 7. Nguyn t ca nguyn t Y c tng s ht mang in nhiu hn tng s ht mang in ca X l 8. Tng s proton ca hp cht to bi X v Y l: A. 28 B. 82 C. 64 D. 30 Cu 31: Polime c tng hp bng phn ng trng ngng l : A. poli (vinylclorua) B. polibuta1,3ien C. polistiren D. poli(etylen terephatalat) Cu 32: Cho mt lng ancol E i vo bnh ng Na (d), sau khi phn ng xy ra hon ton thy khi lng bnh tng thm 6,3 gam v c 1,568 lt kh H2 (ktc) thot ra. Cng thc ancol E l A. C3H7OH B. C2H4(OH)2 C. C3H5(OH)3 D. C2H5OH Cu 33: Cht X cha C, H, O c t khi i vi H2 l 30. X c phn ng trng gng, s cng thc cu to ph hp ca X l: A. 1 B. 2 C. 3 D. 4 Cu 34: Cho cc cht Cu, FeO, Fe3O4, C, FeCO3, Fe(OH)2, Fe tc dng ln lt vi H2 SO4 c, nng u gii phng kh SO2. S cht m khi tc dng vi 1 mol H2SO4 u gii phng ra 1/4 mol SO2 l: A. 4 B. 3 C. 5 D. 6 Cu 35: Pht biu no sau y khng ng? A. Phn ng c kim loi tham gia l phn ng oxi ho - kh. B. Mt cht hoc ch c tnh oxi ho hoc ch c tnh kh. C. Phi kim l cht oxi ho trong phn ng vi kim loi v hiro. D. Mt cht c tnh oxi ho gp mt cht c tnh kh, c th xy ra phn ng oxi ho - kh. Cu 36: Hn hp X c hai hirocacbon l ng ng lin tip, M x = 31,6. Ly 6,32g X li vo 200g dung dch xc tc thy thot ra 2,688 lt kh kh KTC c M = 33 thu c dung dch Z. Bit dung dch Z cha anehit vi nng C%. Gi tr ca C l: A. 1,043 B. 1,305 C. 1,208 D. 1,409. Cu 37: Lng tiu th than ca mt nh my nhit in trong mt nm l 2,5 triu tn than, than cha 3% lu hunh. Gi s ton b lng lu hunh chuyn thnh SO2 th mi pht nh my in thi vo kh quyn bao nhiu kg SO2? A. 356,5 kg B. 285,4 kg C. 190,0 kg D. 147,2 kg Cu 38: Ho tan hn hp X gm Cu v Fe2O3 trong 400 ml dung dch HCl a mol/lt c dung dch Y v cn li 1 gam ng khng tan. Nhng thanh Mg vo dung dch Y, sau khi phn ng xong, nhc thanh Mg ra thy khi lng tng 4 gam so vi ban u v c 1,12 lt kh H2 (ktc) bay ra. (Gi thit ton b lng kim loi thot ra u bm vo thanh Mg). Khi lng ca Cu trong X v gi tr ca a l A. 1,0g v a = 1M B. 4,2g v a = 1M. C. 3,2g v 2M. D. 4,2g v 2M. Trang 3/4 - M thi 132

Cu 39: Cho m gam hn hp FeS, FeS2 t l s mol 1:1 vo dung dch HNO3 d, t0 ch thot ra hn hp kh cha 0,4 mol NO2, 0,2 mol NO (l sn phm kh duy nht). Tnh m? A. 10,4 gam B. 9,25 gam C. 10,3 gam D. 8,67 gam Cu 40: Ho tan 10 gam hn hp Cu2S v CuS bng 200 ml dung dch KMnO4 0,75M trong mi trng axit H2SO4. Sau khi un si ui ht kh SO2 sinh ra, lng KMnO4 cn d phn ng va ht vi 175 ml dung dch FeSO4 1M. Khi lng CuS trong hn hp ban u l: A. 4,8 gam. B. 5 gam. C. 6 gam. D. 9,6 gam. Cu 41: Khi vt bng gang, thp b n mn in ho trong khng kh m, nhn nh no sau y ng? A. Tinh th st l cc dng, xy ra qu trnh kh. B. Tinh th cacbon l cc m, xy ra qu trnh oxi ho. C. Tinh th cacbon l cc dng, xy ra qu trnh oxi ho. D. Tinh th st l cc m, xy ra qu trnh oxi ho. Cu 42: Dung dich A c cc cht: Ca(HCO3)2, NaOH, KNO3. Dung dch B c cc cht: MgSO4, KCl, Al(NO3)3. Dung dch C cha cc cht: Na2CO3, Ba(OH)2, NaNO3. Dung dch D c cc cht: NaOH, Ba(OH)2, NaCl. Dung dch E c cc cht: AgNO3, BaCl2, KNO3. Dung dch F c cc cht: Fe(NO3)2, HCl, NaCl. S dung dch khng tn ti trong thc t l: A. 5 B. 2 C. 3 D. 4 Cu 43: Cho cc cht imetylamin (1), Metylamin (2), Amoniac (3), Anilin (4), p-metylanilin (5), pnitroanilin (6). Tnh baz tng dn theo th t l A. (3), (2), (1), (4), (5), (6) B. (6), (5), (4), (3), (2), (1) C. (6), (4), (5), (3), (2), (1) D. (1), (2), (3), (4), (5), (6) Cu 44: Mt nc 20 triu dn, mt nm tiu th ht khong 2,522.108 tn than (85% cacbon). Bit khi t chy hon ton 1kg than (85% cacbon) to ra 6658,33 kcal. Vy tnh trung bnh mi ngi trong 1 ngy cn bao nhiu kcal nhit? A. 2,3.105 kcal B. 5,3.103 kcal C. 1,96.105 kcal D. 4,7.104 kcal Cu 45: Thi hi nc qua than nng thu c hn hp kh A kh (H2, CO, CO2). Cho A qua Ca(OH)2 cn li hn hp kh B kh (H2, CO). Mt lng kh B tc dng va ht vi 8,96g CuO thy to thnh 1,26 g nc. Thnh phn % theo th tch ca CO2 trong A l: A. 33,33% B. 20,00% C. 11,11% D. 30,12%. Cu 46: Khi thy phn C4H6O2 trong mi trng axit ta thu c hn hp hai cht u c phn ng trng gng. Vy CTCT ca C4H6O2 l mt trong cc cu to no sau y? C O CH CH 2 CH3 C O CH 2 CH CH 2 H O O A. B. CH2 CH C O CH3 H C O CH CH CH3

O O C. D. Cu 47: Dung dch A cha cc ion: SO42-, 0,2 mol Ca2+, 0,1 mol NH4+ v 0,2 mol NO3-. Tng khi lng cc mui khan c trong dung dch A l: A. 36,2 gam B. 36,6 gam C. 36,3 gam D. 36,4 gam Cu 48: t chy hon ton m gam mt ancol no X thu c cng m gam H2O. Bit khi lng phn t ca X nh hn 100 vC. S ng phn cu to ca ancol X l A. 4 B. 5 C. 8 D. 6 Cu 49: Cho mt lng bt CaCO3 tc dng hon ton vi dung dch HCl 32,85%. Sau phn ng thu c dung dch X trong nng HCl cn li l 24,20%. Thm vo X mt lng bt MgCO3 khuy u cho phn ng xy ra hon ton thu c dung dch Y trong nng HCl cn l 21,10%. Nng phn trm MgCl2 trong dung dch Y l A. 12,35%. B. 3,54%. C. 10,35%. D. 8,54%. Cu 50: Trong tinh bt, cc mt xch -glucoz lin kt vi nhau bng A. lin kt -1,4-glicozit v -1,6-glicozit B. lin kt -1,4-glicozit v -1,2-glicozit C. lin kt -1,4-glicozit v -1,4-glicozit D. lin kt -1,6-glicozit v -1,4-glicozit --------------------------------------------------------- HT ---------D KIN THI TH I HC LN 4 VO: 31/03/2012 Trang 4/4 - M thi 132