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iit jee Chemistry 2005 solution

iit jee Chemistry 2005 solution

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Published by saurav gupta
iitjee 2005 solution by fiitjee
iitjee 2005 solution by fiitjee

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Published by: saurav gupta on May 10, 2012
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FIITJEE
Ltd. ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Term.), New Delhi - 16, Ph : 2686 5182, 26965626, 2685 4102, 26515949 Fax : 26513942 
 
IIT-JEE 2005-M-1
FFIIII T TJJEEEE
 
SSoolluuttiioonnssttoo I  I  I  J  J  E E E E – – 2 2000055 M aaiinnssP Paa p pee 
CChheemmiisstt y y
 
Time: 2 hoursNote:
Question number 1 to 8 carries
2 marks
each, 9 to 16 carries
4 marks
each and 17 to 18 carries
marks
each.
Q.1.
Monomer A of a polymer on ozonolysis yields two moles of HCHO and one mole of CH
3
COCHO.a) Deduce the structure of A.b) Write the structure of “all cis” – form of polymer of compound A.
Solution1.
(a)
CH
2
CH
2
CH
3
ozonolysis
OHHCH
3
OHO
2
 A
 (b)
CH
3
CH
2
HCH
2
CH
3
HCH
2
CH
3
CH
2
H
 “all cis” form of polymer of A
Q.2.
Fill in the blanksa)
1372351979205240
UnAB.......................
+ + +
 b)
ο
 +
82341
Se2e....................
Solution 2.
(a)
235
U
92
+
0
n
1
 
137
 A
52
+
97
B
40
+ 2
0
n
1
(b)
82
Se
34
2
-1
e
0
+
82
Kr 
36
 
Q.3.
a) Calculate the amount of Calcium oxide required when it reacts with 852 gm of P
4
O
10
.b) Write the structure of P
4
O
10
.
Solution 3.
a) 6CaO + P
4
O
10
 
2Ca
3
(PO
4
)
2
Moles of P
4
O
10
=
8523284
=
 Moles of CaO = 3 × 6 = 18Wt. of CaO = 18 × 56 = 1008 gm.(b)
POPPOOPOOOOOOO
 
 
 
FIITJEE
Ltd. ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Term.), New Delhi - 16, Ph : 2686 5182, 26965626, 2685 4102, 26515949 Fax : 26513942 
 
IIT-JEE 2005-M-2
Q.4.
An element crystallizes in fcc lattice having edge length 400 pm. Calculate the maximum diameter of atom which can be placed in interstitial site without distorting the structure.
Solution4.
In FCC, interstitial sites will be octahedral voids & tetrahedral voids.For octahedral voids For tetrahedral voids
12
0.414
=
 
12
0.225
=
 Where r 
1
= radius of atom in interstitial sites
2
= radius of atom arranged in FCC.i.e. 4r 
2
=
2a
,For maximum diameter of atom in interstitial site, octahedral voids will be considered.Diameter = 2r 
1
= 2(0.414 r 
2
)40020.41422
= × ×
= 117.1 pm
Q.5.
20% surface sites have adsorbed N
2
. On heating N
2
gas evolved from sites and were collected at0.001 atm and 298 K in a container of volume is 2.46 cm
3
. Density of surface sites is 6.023×10
14
/ cm
2
 and surface area is 1000 cm
2
, find out the no. of surface sites occupied per molecule of N
2
.
Solution 5.
 
2
N
P0.001atm
=
, T = 298 K, V = 2.46 cm
2
 By ideal gas, PV = nRT
2
37N
PV0.0012.4610n1.010RT0.0821298
× ×= = = ××
 Now molecules of N
2
= 6.023 × 10
23
× 1 × 10
-7
= 6.023 × 10
16
 Now total surface sites available = 6.023 × 10
14
× 1000 = 6.023 × 10
17
 
Surface site used to adsorb N
2
 
17
206.02310100
= × ×
= 12.04 × 10
16
 
Sites occupied per molecule of N
2
1616
12.041026.0210
×= =×
 
Q.6.
Predict whether the following molecules are iso structural or not. Justify your answer.(i) NMe
3
(ii) N(SiMe
3
)
3
 
Solution 6.
 
( ) ( )
333
NMe&NSiMeare not isostructural. N(Me)
3
is trigonal pyramidal while
( )
33
NSiMe istrigonal planar due to back bonding.
NMeMeMe
 
N(Me)
3
SiSi(Me)
3
Si(Me)
3
 
Q.7.
OH
+33
1.OH/
 ∆
NaOH2.Zn/CHCOOH
XY
 
O
 Identify X and Y.
 
 
FIITJEE
Ltd. ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Term.), New Delhi - 16, Ph : 2686 5182, 26965626, 2685 4102, 26515949 Fax : 26513942 
 
IIT-JEE 2005-M-3
Solution 7.
OH
 
 Å
H/
 ∆
OHH
 
CH
2
 
ringexpansion
H(X)
← 
33
OZn/CHCOOH
HOOCH
3
← 
NaOH
O
 
Q.8.
Which of the following disaccharide will not reduce Tollen’s reagent?a)
OOOHCH
2
OHHCH
2
OHHOHOHHOHHHOHHOHHOH
(Q)
 b)
OOHHOH
2
CHOHHHOHOCH
2
OHHOHOHHOHHOHH
(P)
 
Solution 8.
In structure (P) both the rings are present in acetyl form therefore it will not hydrolyse insolution that why Fehling solution cannot react with this.In structure (Q) one ring present in the form of hemiacetal. This will hydrolyse in solution and itcan reduce Fehling solution.
Q.9.
Write balanced chemical equation for developing a black and white photographic film. Also givereason why the solution of sodium thiosulphate on acidification turns milky white and give balanceequation of this reaction.
Solution 9.
a) Reactions used in developing the photographic film
( )
( )
( )
646422blacksilver quinoneHydroquinoneparticlesdeveloper 
2AgBrCHOH2Ag2HBrCHO
+ + +
 
( )
2233232sensitive,Hyposolutionunexposedemulsion
 AgBr2NaSONaAgSONaBr 
+ +
 b)
22323colloidalsulphur 
NaSO2H2NaHSOS
+ +
+ + +
 
Q.10.
 
SCN(excess)F(excess)3
Febloodred(A)colourless(B)
+
 
 Identify A and B.a) Write IUPAC name of A and B.b) Find out spin only magnetic moment of B.
Solution 10.
 
( )
( ) ( )
( )( )
2aqueous325excess Abloodred
FeSCNFeSCNHO
++
+
 

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