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V . A D I T Y A V A R D H A N
H T T P : / / W W W . A D I C H E M A D I . C O M
1
Prepared by V. Aditya vardhan adichemadi(at)gmail.com
WARANGAL
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AIEEE-2009MODEL PAPER - 1(CHEMISTRY)
Note: This paper is not only for AIEEE but equally useful for other competitive examinations like IIT-JEE,EAMCET, KCET and other CHEMISTRY entrance examinations of various universities and institutions.
1)Which of the following compounds containing chiral carbons is optically inactive?a) (R)-Lactic acidb) (R,R)-Tartaric acidc) (R,S)-Tartaric acidd) Glycine2)Which of the following radial distribution graph corresponds to orbital with n = 3,
l
= 2 ?3)Complete coagulation of one litre of an aquasol requires 0.001 equivalents of Na
3
PO
4
. Whereasthe coagulation of the same requires 0.1 equivalents of AlCl
3
. During electrophoresis of thiscolloidal solution, the sol particles will migrate towards;a) anodeb) cathodec) both anode and cathoded) does not migrate4)The major product formed in the following reaction is
CHO
NaBH
4
a)
CHO
b)
CH
2
OH
V . A D I T Y A V A R D H A N
H T T P : / / W W W . A D I C H E M A D I . C O M
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Prepared by V. Aditya vardhan adichemadi(at)gmail.com
WARANGAL
c) d)
CH
2
OH
5)Dioxygen is paramagnetic becausea) there are two unpaired electrons in doubly degenerate
-LUMO’s.b) there are two unpaired electrons in doubly degenerate
-HOMO’s.c) there are two unpaired electron in a
-LUMO.d) Dioxygen is not paramagnetic and hence there are no unpaired electrons.6)Austenite form of iron has FCC crystal lattice structure, whereas its alpha form has BCC crystallattice structure. Assuming closest packed arrangement of iron atoms, what will be the ratio of density of Austenite to that of alpha iron?a) 1 : 1.088b) 1 : 1.837c) 1 : 1d) 1.088 : 17)The anti-histamine which reduces the secretion of pepsin and hydrochloric acid in stomach isa) Pencillinb) Terfenadine (Seldane)c) Brompheneramined) Cimetidine8)The correct IUPAC name of a) 3,4,9-Trimethyldecaneb) 2-Ethyl-3,7-dimethylnonanec) 2,7,8-Trimethyldecaned) 3,4,9-Trimethylnonane9)A diamagnetic compound of a metal ‘M’,which belongs to Nickel group,with the formula -M(NO
2
)(CN)(NH
3
)(CO) does not show electrical conductivity in aqueous solutions. Which of the following is the incorrect statement about this compound?a) The metal contains (n-1)d
8
configuration.b) The metal undergoes dsp
2
hybridisation.c) In this complex, pairing energy(P) is less than crystal field splitting energy(
o
).d) The complex exhibits optical activity.10)The percent ionization of a 0.20 M acetylsalicylic acid solution in the stomach where the pH is1.00 is (K
a
of acetylsalicylic acid = 3.0 × 10
–4
)a) 3.8%b) 0.30%c) 0.03%d) 0.0003%11)Phosphorus reacts with caustic soda by giving a salt ‘X’ and a poisonous gas ‘Y’. The numberof P-H bonds respectively present in ‘X’ and ‘Y’ are,a) 1 & 3b) 2 & 2c) 2 & 1d) 2 & 312)Two hydrocarbons ‘X’ and ‘Y’, of same molecular formula C
7
H
12
, gave 6-Oxoheptanal andHeptane-2,3-dione respectively upon ozonolysis. ‘X’ and ‘Y’ are respectively,a)
CH
3
and
V . A D I T Y A V A R D H A N
H T T P : / / W W W . A D I C H E M A D I . C O M
3
Prepared by V. Aditya vardhan adichemadi(at)gmail.com
WARANGAL
b)
and
c)
CH
3
andCH
3
CH
3
d)
andCH
3
13)For HI the molar entropy of vaporization is 89.0 J/K mol and the molar enthalpy of vaporization is 21.16 kJ/mol. The temperature at which the value of
G becomes equal to zerofor the vaporisation process will bea) -273
o
Cb) -35.4
o
Cc) 23.8 Kd) 42
o
C14)In 1895, Lord Rayleigh discovered that samples of nitrogen from the air were of a differentdensity than nitrogen resulting from chemical reactions. The correct explanation for this obser-vation isa) Nitrogen samples obtained from air has heavier isotopes.b) Nitrogen samples obtained from air contains argon.c) Nitrogen samples obtained from chemical reactions also contains helium.d) All of the above.15)The rate of a reaction is increased by four times when the concentration of reactants is doubled.The true statement about this reaction is;a) The units of the specific rate of reaction is L
2
.mol
-2
s
-1
.b) Half life of the reaction is proportional to the initial concentration of reactants.c) Half life of the reaction is inversely proportional to the initial concentration of reactants.d) It is a first order reaction.16)
Assertion(A):
LiCl is an ionic compound but dissolves in non polar solvents.
Reason(R):
Li
+
ion unergoes polarization due to strong polarizing power of Cl
-
ion and hencethe compound shows some covalent nature.a) Both ‘A’ & ‘R’ are correct ; and ‘R’ is the correct explanation of ‘A’b) Both ‘A’ & ‘R’ are correct ; but ‘R’ is not the correct explanation of ‘A’.c) ‘A’ is correct but ‘R’ is incorrectd) ‘A’ is incorrect but ‘R’ is correct.17)A diamagnetic colorless salt liberated a paramagnetic reddish brown gas upon heating andleaves behind an orange yellow solid residue. Upon addition of dil.HCl, its solution gave awhite precipitate, which is soluble in hot water. Its solution also gave a yellow precipitate withPotassium chromate solution. The salt is most likely to be,a) Zn(NO
3
)
2
b) Pb(NO
3
)
2
c) Ba(NO
3
)
2
d) NH
4
NO
3
18)The depression in freezing point of a dilute aqueous solution of a non electrolytic solute is
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