BI 1: ANCOL( RU) A. L THUYT I.

Cng thc ng phn- Tn gi

Bi 1. Gi tn thng thng (gc chc), tn IUPAC v cho bit bc ca cc ancol sau : a) CH3CH2CH2CH2OH b) CH3CH(OH)CH2CH3 d) (CH3)2CHCH2CH2OH e) CH2=CH-CH2OH C6H5CH2OH -Vit cng thc cu to ca cc ancol sau : a) Ancol isobutylic b) Ancol isoamylic c) 2-metylhexan-3-ol

c) (CH3)3COH g)

Bi 2. Hy vit cng thc cu to v gi tn cc ancol ng phn ng vi cng thc phn t C 4H10O, C5H12O, C6H12O Bi 3. Vit CTCT a. Ru bc I c CTPT C6H14O b. Ru thm c CTPT C8H10O c. Ru a chc c CTPT C3H8O2 Bi 4. Vit CTCT a. Hp cht n chc c CTPT C4H10O v gi tn b. Ru khng no c CTPT C4H8O Bi 5. Vit CTTQ ca ru a. no n chc, h b. no a chc mch h c. ru tng qut Bi 6. Cho ru A c CTPT C5H12O , A phn ng vi CuO ,t 0 to ra B phn ng trng gng (dd AgNO 3/NH3) .Khi tch H2O ca A bng ddH 2SO4 c nng ch thu c sn phm duy nht C khng lm mt mu ddBr 2 k thng. Tm CTCT A, B, C vit ptpu v gi tn A Bi 7. Cho ru X c CTPT C8H10O, A phn ng vi CuO, t 0 to ra Y phn ng trng gng (dd AgNO 3/NH3). Khi tch H2O ca A bng ddH 2SO4 c nng 170 0C thu c sn phm Z, trng hp Z c polime T . Tm CTCT X, Y, Z, T v vit ptpu Bi 8. iu kin mt ru a chc ha tan c Cu(OH)2/OH- : phi c 2 nhm OH- lin kt vi hai nguyn t C gn nhau. Hy cho bit ru C4H10O2 c bao nhiu CTCT ha tan c Cu(OH)2/OH- cho dung dch mu xanh. Bi 9. Cho A c CTCT HO-C6H4-CH2OH .Vit ptpu ca A vi : ddHCl, Na, NaOH, CuO nung nng. Bi 10. Trong tinh du bc h c mentol, tinh du hoa hng c geraniol. Cng thc thu gn nht ca chng cho bi khi nim v tecpen. a) Hy vit cng thc thu gn, phn loi v gi tn chng theo IUPAC. b) Vit phng trnh ho hc ca phn ng khi cho tc dng vi Br 2 d v vi CuO un nng. II. Tnh cht vt l. Bi 1. a. Trong dd ru tn ti bao nhiu loi lin kt hidro. Vit cng thc biu din b. Trong hn hp ru etylic v phenol tn ti bao nhiu loi lin kt hidro. Vit cng thc biu din Bi 2. so snh nhit si ca cc cht cho di y(sp xp theo chiu tng dn): ru etylic, ru propylic, propan, clopropan, axit fomic. Gii thch III. Tnh cht cht ha hc v iu ch. Bi 1 1. 2. Vit cc phng trnh phn ng trc tip iu ch ru tylic, Glyxrin. Phn ng no dng sn xut cng nghip ? Vit cc phng trnh phn ng iu ch ru tylic; ru Mtylic; ru Alytic; Glyxrin; Propandiol -1,2; rru Benzylic t vi v than . . .

Nu nguyn tc chung chuyn ru t bc 1 thnh bc 2 v t ru bc 2 thnh bc 3 ? Cho v d minh ho 4. ru l g ? Cho v d Bi 2. Cho cc ru c cng thc l C3H8On 3. 1. 2. Vit cng thc cu to ca cc ru v gi tn Vit phng trnh phn ng khi cho cc ru trn tc dng vi Na, CuO/t 0, Cu(OH)2, HNO3, CH3COOH/H2SO4 c nng

Bi 3: Cho s bin ho sau :

C2H4

Cl2

B A
C2H5OH xt

+D
xt

C2H5Cl

E A R
NaOH C2H5OH

A +C
Na

G
H2O

A, B, C, . . . l k hiu ca cc cht v c v hu c. hon thnh s phn ng. Bit A cha 2 nguyn t Ccbon Bi 4. Hy vit cc phng trnh ho hc ca phn ng v gi tn cc sn phm hu c to thnh trong cc trng hp sau : a) Propan-2-ol tc dng vi H 2SO4 c 140oC. b) Metanol tc dng vi H 2SO4 c to thnh imetyl sunfat. c) Propan-2-ol tc dng vi KBr v H 2SO4 un nng. d) Ancol isoamylic tc dng vi H 2SO4 c 180oC. Bi 9. Bng phng php ho hc, hy phn bit cc cht trong cc nhm sau : a) Butyl metyl ete, butan-1,4-iol v etylen glicol (etan-1,2-iol) b) Xiclopentanol, pent-4-en-1-ol v glixerol.

B. CC DNG TON V RU DNG 1: RU- HIU SUT IU CH

Cu 1. Cho 20ml cn tc dng vi Na d th thu c 0,76 g H 2 ( khi lng ring ca ancol etylic l 0,8 g/ml). ru trong loi cn trn l bao nhiu? Cu 2. Cho Na d vo 100 ml cn 460 ( khi lng ring ca ancol etylic l 0,8 g/ml) . Tnh th tch H2 ktc? Cu 3. Cho 1 lt cn 950 tc dng vi Na d . Bit rng ancol nguyn cht c d=0,8g/ml. Tnh th tch H 2 to ra ktc? Cu 4. Cho 50 ml dd ancol etylic( dd X) tc dng vi Na d th thu c 15,68 lt H 2 ( ktc). Bit khi lng ring ca ancol nguyn cht l 0,8 g/ml. Xc nh ancol v nng mol ca dd X? Cu 5: Cho phn ng ht 4,6 gam Na vi ancol etylic v 4,6gam Na vi nc tnh th tch kh H 2(ktc) thot ra trong tng trng hp. Tnh khi lng natri etylat v natri hiroxit to thnh? s:2,24lt Cu 6. Cho 10ml ancol etylic 960 tc dng vi Na d a/Vit phng trnh phn ng v tnh khi lng ancol nguyn cht tham gia phn ng, bit D ru =0,8g/ml b/Ly 100ml ru 960 trn c th pha c bao nhiu lt ancol 40 0 c/Ly 50ml ru trn th iu ch c bao nhiu gam dung dch axit axetic 5%. Bit hiu sut phn ng t 90%? s:a/7,68g; b/240ml; c/ 901,8g

Cu 7. Tnh khi lng tinh bt ( cha 80%-(C6H10O5)n ) cn ly iu ch 7 lit ancoletylic 450 bit D=0,8g/ml v hiu sut qu trnh iu ch l 75% Cu 8. Tnh khi lng glucozo cn ly iu ch a lit ancoletylic 450 bit D=0,8g/ml v hiu sut phn ng iu ch l 75%. Lng kh CO2 sinh ra hp th hon ton vo 1lit dd Ca(OH) 2 1M thu c 60gam kt ta.

DNG 2: PHN NG NATRI-PHN NG CHY

1.MT RU Cu 1. Hp cht hu c X cha cc nguyn t C, H, O. Khi ho hi 0,93 g X thu c th tch hi ng bng th tch ca 0,48 g O2 o cng iu kin. Mt khc, cng 0,93 g X tc dng ht vi Na to ra 336 ml H 2(ktc). Xc nh CTCT ca X? Cu 2. Tm cng thc phn t v cng thc cu to ca cc ancol sau a) Cho 3,8 g mt iol tc dng vi mt lng Na d thu c 0,56 l kh H 2 ( 2 atm, O0C)? b) Cho 2,3g mt ancol no ( M = 92) tc dng ht vi kali thu c 0,84 l H 2 ( o ktc) Cu 3:T khi hi i vi khng kh ca mt ancol no bng 2,13. Khi cho 3,1g ru tc dng ht vi Na thy thot ra 1,12lt H2 (kc). Hi ancol l n chc hay a chc, vit CTCT ca ancol Cu 4: T khi hi i vi Nit ca mt ancol no A bng 2,214. Khi cho 3,1g A tc dng ht vi Na thy thot ra 1,2218(l) H2 ( 250C, 1atm). a/Vit CTCT ca A b/T ancol etylic v cc cht v c cn thit, vit phng trnh phn ng iu ch A? s:C 2H4(OH)2 Cu 5: Cho 6 gam mt ancol no, n chc, mch h A tc dng vi Na thu c 1,12lt kh H2(ktc) a/Xc nh CTPT ca A b/Xc nh CTCT ng ca A v gi tn A, bit rng oxi ha A bng oxi c (Cu xc tc) to ra anehit c/T A, vit phng trnh phn ng to ra C (l ng phn ca ancol A) s:Propanol-1 Cu 6: T khi hi i vi khng kh ca mt ancol no bng 2,13. Khi cho 3,1g ancol tc dng ht vi Na thy thot ra 1,12lt H2 (kc). Hi ancol l n chc hay a chc, vit CTCT ca ancol ? Bi 7: Mt ancol no A c t khi hi i vi khng kh l 2,57. Ngi ta ly 3,7gam ancol cho tc dng ht vi Na thu c 0,56lt H2 (ktc) a/Tm CTPT ca A b/Xc nh CTCT ca A bit rng khi un nng 1800C c H2SO4 c ta thu c 2 olefin ? s:C4H9OH Cu 8. t chy hon ton mt ancol X thu c CO2 v H2O c t l mol tng ng l 3 : 4. Th tch kh oxi cn dng t chy X bng 1,5 ln th tch kh CO2 thu c ( cng iu kin ). Cng thc phn t ca X? Cu 9. Khi t chy hon ton 6,44g mt ancol no mch h A th thu c 9,24g CO 2 . Mt khc khi cho 1 mol A tc dng vi K thu c 33,6l H2 ( ktc). Tm cng thc phn t vit cng thc cu to ca A? Cu 10. X l ancol no mch h khi t chy hon ton 1 mol X cn va 3,5 mol O 2. Xc nh cng thc cu to ca X? Cu 11. t chy hon ton 0,5 mol mt ancol no a chc X thu c 33,6l CO 2 ktc. Xc nh CTPT, vit CTCT ca X bit MX = 92. 2. HN HP RU Cu 11. Cho natri phn ng hon ton vi 18,8g hn hp 2 ancol no, n chc, mch h k tip nhau trong dy ng ng sinh ra 5,6 lt kh hiro (ktc). Xc nh cng thc phn t hai ancol? Cu 12. Hn hp X gm 2 ancol no, n chc, mch h A, B k tip nhau trong dy ng ng. Cho 3,35 g hh X phn ng vi Na th thu c 0,56 lt H2 (ktc) . Xc nh CTCT thu gn ca A, B? Cu 13. Cho Na phn ng hon ton vi 18,8 g hh 2 ancol k tip nhau trong dy ng ng ca ancol etylic thy sinh ra 5,6 lt H2(ktc). Xc nh CTPT 2 ancol? Cu 14. Cho hh gm 1,6 g ancol A v 2,3 g ancol B l 2 ancol no, n chc, mch h k tip nhau trong dy ng ng tc dng vi Na c 1,12 lt H2 ( ktc). Xc nh CTPT 2 ancol? Cu 15. Cho 15,6 g hh 2 ancol n chc k tip nhau trong dy ng ng tc dng ht vi 9,2g Na thu c 24,5g cht rn. Xc nh hai ancol ? Cu 16. cho 2,84 gam hn hp X gm 2 ancol n chc , l ng ng k tip nhau tc dng va vi Na to ra 4,6 gam cht rn v V lt kh H2 (ktc). Xc nh gi tr ca V v CTPT ca hai ancol? Cu 17. cho 1,52 gam hn hp hai ancol n chc l ng ng k tip nhau tc dng vi Na va , sau phn ng thu c 2,18 gam cht rn. X cng thc phn t ca hai ancol? Cu 18: Cho 11g hn hp gm hn hp gm hai ancol no n chc, mch h k tip nhau trong dy ng ng tc dng ht vi Na thu c 3,36 lt kh H2 (kc). Vit CTPT v CTCT ca hai ancoltrn? s:CH3OH; C2H5OH

Cu 19: Cho 28,2g hn hp hai ancol no n chc, mch h k nhau trong dy ng ng tc dng ht vi Na (ly d), sinh ra 8,4 lt kh H2 (kc). Vit CTCT ca hai ancol v tnh thnh phn % v khi lng ca chng trong hn hp, bit phn ng xy ra hon ton? s:CH 3OH (51,06%); C2H5OH (48,94%) Cu 20: Cho 28,2gam hn hp hai ancol no, n chc, mch h k tip nhau trong dy ng ng tc dng ht vi Na thu c 8,4 lt H2(ktc). Vit CTCT ca hai ancol trn v tnh thnh phn % khi lng ca chng, bit phn ng xy ra hon ton? s: 51,06%CH3OH; 48.94%C2H5OH Cu 21: Cho 25,8gam hn hp hai ancol no n chc k tip nhau trong dy ng ng tc dng ht vi Na d thu c 5,6 lt H2(ktc). Vit CTPT ca hai ru trn v tnh thnh phn % khi lng ca chng ? Cu 22: Hn hp A cha Glixerol v mt ancol no, n chc, mch h. Cho 20,3 gam A tc dng vi Na d thu c 5,04lt H2 (ktc) mt khc 8,12gam A ha tan va ht 1,96gam Cu(OH) 2. Hy xc nh CTPT v % khi lng ca ancol trong hn hp A? s:C4H9OH(54,95%) Cu 23. t chy hon ton m gam 2 ancol l ng ng k tip ca nhau thu c 0,3 mol CO 2 v 7,65 g H2O. Mt khc nu cho m gam hn hp 2 ancol trn tc dng vi Na th thu c 2,8 lt kh H 2 (ktc). Xc nh CTPT vit CTCT ca hai ancol trn? Cu 24: t chy 23g mt hp cht hu c A thu c 44g CO 2 v 27g H2O. a/Chng minh rng A l mt hp cht no c cha Oxi. b/Xc nh CTCT ca A bit rng A tc dng vi Na to ra kh H2 . c/Mt hn hp X gm A v mt hp cht B thuc cng dy ng ng vi A, khi lng ca X l 18,8g. X tc dng vi Na d to ra 5,6lt H2 (kc). Xc inh B v thnh phn hn hp X? s:C2H5OH(0,2mol); CH3OH(0,3mol). Cu 25: Cho 16,6 gam hn hp gm ancol etylic v ancol propylic phn ng ht vi Na d thu c 3,36 lt H2(ktc). Tnh thnh phn % khi lng cc ru c trong hn hp? s: 27,7%C 2H5OH Cu 26. Chia m gam hn hp X gm 2 ancol A v B thnh 2 phn bng nhau : Phn 1 : Cho tc dng vi Na d thu c 1,68 lt H2 (ktc) Phn 2 : t chy hon ton thu c 9,9 gam CO2 v 6,75 gam H2O. Gi tr ca m ?

DNG 3: PHN NG TCH NC TO ANKEN-ETE

Bi 1. un nng 7,8 gam mt hn hp X gm 2 ancol no, n chc, mch h vi H 2SO4 c 1400C thu c 6 gam hh Y gm 3 ete. Bit 3 ete c s mol bng nhau v phn ng xy ra hon ton. Xc nh CTPT ca 2 ancol? Bi 2. Cho 11g hn hp 2 ancol n chc vo bnh ng Na (d) thy thot ra 3,36 lt H2 ( ktc). Nu cho hh ancol vo dung dch H2SO4 c 1400C thu c mg ete ( hiu sut phn ng t 80%). Gi tr ca m? Bi 3. un nng 7,8 gam mt hn hp X gm 2 ancol no, n chc, mch h vi H 2SO4 c 1400C thu c 6 gam hh Y gm 3 ete. Bit 3 ete c s mol bng nhau v phn ng xy ra hon ton. CTPT ca 2 ancol? Bi 4. khi un nng m gam ancol no n chc mch h X vi H 2SO4 c lm xc tc nhit thch hp thu c m2 gam hp cht hu c B. T khi hi ca B so vi X l 0,7. X CTCT ca X? Bi 5: un nng mt hn hp gm hai ancol no n, mch h chc vi H 2SO4 c 1400C thu c 21,6g H2O v 72g hn hp 3 ete. Xc nh CTCT ca hai ancol trn bit 3 ete thu c c s mol bng nhau v phn ng xy ra hon ton?s:CH3OH; C2H5OH Bi 6. un 1,66 hn hp hai ancol vi H2SO4 c, thu c hai anken ng ng k tip ca nhau. Hiu sut gi thit l 100 %. Nu t hn hp anken cn dng 2,688 lt kh O 2 (ktc). Tm cng thc cu to 2 ancol? Bi 7: iu ch etylen ngi ta un nng ancol etylic 95 0 vi axit H2SO4 c 1700C. Tnh th tch ancol 950 cn a vo phn ng thu c 2 lt etylen (ktc). Bit hiu sut phn ng t 60%, khi lng ring ca etylic l 0,8g/ml. Tnh lng ete sinh ra khi un nng mt th tich ancol nh trn 140 0C vi axit H2SO4 c. Bit hiu sut cng t 60% ? s:8,99ml; 3,3g Bi 8: Kh nc hon ton hn hp hai ancol ta thu c hn hp 2 anken ng ng lin tip co t khi hi i vi H2 l 23,8 a/Tm CTPT vit CTCT v tnh % khi lng ca hai ancol trong hn hp b/Tnh khi lng CO2 v hi nc to thnh khi t chy han 6,56g hn hp hai ancol trn ? Bi 9: um m gam hn hp A gm ancol etylic v propylic vi H 2SO4 c ta c hn hp olefin kh X. Ton b X lm mt mu 1lt dung dch brom 0,5M (va ). Bit t khi hi ca X so vi H2 l 16,8. a/Tnh gi tr ca m b/Tnh th tch oxi (ktc) cn t chy 1/10 hn hp A ni trn? s:m=25,8g; 4,032lt Bi 10: un nng mt ancol n chc vi H2SO4 ta thu hircacbon c cu to i xng, 14g hircacbon tc dng va vi 40g Br2. Xc nh CTCT ca ancol ban u? s:C2H5OH

BI 2: PHENOL

I. L THUYT
1. Hy vit cng thc cu to cc ng phn c cng thc phn t C 7H8O cha vng benzen. Gi tn v phn loi chng theo nhm chc. 2. Cho phenol tc dng vi hiro c xc tc Ni v un nng th thu c xiclohexanol. Vit phng trnh ho hc ca phn ng v ngh phng php tch ly xiclohexanol v thu hi phenol cn d (da vo tnh cht vt l v ho hc). Hy nhn bit cc cht trong cc nhm sau y da vo tnh cht vt l v ho hc ca chng : a) Phenol, etanol v xiclohexanol. v benzyl clorua. b) p-Crezol, glixerol

3.

4. Hon thnh cc phng trnh ho hc ca phn ng sau, v r vng benzen : a) oBrC6H4CH2Br + NaOH (dd) ; b) p-HOCH2C6H4OH + HBr c) mHOCH2C6H4OH + NaOH (dd) ; d) p-CH3C6H4OH + Br2 (dd) 5. Hin nay, trong cng nghip ngi ta iu ch etanol v phenol nh th no ? Vit s phn ng ? Bi 1 1. Phnol l g ? Phn bit Phnol v ru thm ? Cho v d ? 2. Vit cng thc cu to ca cc hp cht thm c cu to phn t C7H8O v gi tn 3. Nu v vit phng trnh phn ng minh ho tnh cht ho hc ca Phnol 4. Nu nh hng qua li trong phn t Phnol. vit phng trnh phn ng minh ho 5. So snh mc linh ng ca nguyn t H trong nhm - OH ca Phnol v ru tylic. Vit phng trnh phn ng minh ho 6. Chng minh rng Phnol c tnh axit v l axit yu Bi 2 Cho hp cht c cng thc cu to

HO

CH2OH

Vit phng trnh phn ng khi cho vht ny tc dng vi K; KOH; Dung dch Br 2; HCl Bi 3: Cho Na ln lt vo ru etylic; axit axetic; phenol. Trng hp no xy ra phn ng? Nu thay bng dung dch NaOH; Na2CO3 th kt qu th no. Vit cc phng trnh phn ng Bi 4: a/ T vi v cc cht v c cn thit hy iu ch phenol v axit picric b/ Axit benzylic t phenol v ngc li Bi 5: i t cht ban u l metan, cc cht v c v iu kin phn ng cn thit hy vit phng trnh iu ch: a/ Nha phenolfomanehit b/ Anehit benzoic Bi 6. T Tluen v cc cht v c cn thit, hy vit cc phng trnh iu ch : a) C6H5CH2OH b) p CH3C6H4OH Bi 7. a/ T Benzen c th iu ch c m Nitrophnol b/ xi ho Xiclohexanol bng axit Nitric c thu c axit Aipic. Vit cc phng trnh phn ng Bi 8: Bng phng php ha hc hy phn bit cc cht lng: a/ Benzen; phenol; ru benzylic; stiren; toluen b/ Phenol; ru n-propylic; glixerin Bi 9: a/ C 2 ng nghim khng nhn cha tng cht ring bit : ru butylic, phenol (lng). Bng phng php ha hc, hy nhn bit xem ng nghim no ng cht g ? Vit phng trnh phn ng. b/ Cho 1 hn hp gm ru butylic v phenol. Bng phng php ha hc , hy tch 2 cht ra khi nhau . Vit phng trnh phn ng.

II. TON PHENOL

Bi 1:Cho 62,4g dung dch gm phenol, ru etylic c ln nc tc dng vi Na kim loi th thu c 11,2 lt kh (ktc) . Mt khc, nu cho lng hn hp ny tc dng vi 200ml dung dch NaOH 2M th va . Tm thnh phn % v khi lng ca hn hp s:%C6H5OH=60,256; %C2H5OH=36,859; %H2O=2,885 Bi 2 :a/ Dung dch Natri phenolat b vn c khi thi kh CO2 vo .Vit pt phn ng v gii thch hin tng b/ Cho nc brom d v dung dch phenol thu c 6,62g kt ta trng. Tnh khi lng phenol c trong dung dch?s:1,88g

Bi 3:Mt dung dch cha 6,1g cht ng ng ca phenol n chc. Cho dung dch trn tc dng vi nc brom d thu c 17,95g hp cht cha ba nguyn t brom trong phn t .Xc nh CTPT ca cht s:C 8H10O Bi 4: Mt hn hp gm ru metylic, ru etylic v phenol c khi lng 28,9g. Chia hn hp thnh hai phn bng nhau. Phn 1 cho phn ng hon ton vi Na cho 2,806(l) H2 ( 270C, 750mm Hg). Phn 2 cho phn ng va ht vi 100ml dung dch NaOH 1M a/ Vit cc phn ng xy ra b/ Tnh thnh phn % cc cht trong hn hp? s:%CH 3OH=11,07; %C2H5OH=23,88 Bi 5 :t chy 5,8g cht hu c Ata thu c 2,65g Na2CO3, 2,25g H2O v 12,1g CO2 a/ Xc nh C.T.P.T. ca A, bit 1 phn t A ch cha 1 nguyn t oxi b/ Cho kh CO2 sc vo dung dch ca A thu c cht B l mt dn xut ca benzen . trung ha a(g) hn hp gm B v mt ng ng tip theo C ca B cn dng 200(g) dung dch NaOH nng (6a/31)%. Tnh t l s mol ca B v C trong hn hp X s:n B:nC=12 Bi 6 : a/ Xc nh thnh phn % khi lng hn hp (A) gm benzen, phenol v ru etylic, bit rng : * 71,1(g) (A)trung ha va 2 lt dung dch NaOH 0,25M * 142,2(g) (A) tc dng vi Na d gii phng 14,784lt H2 (o 27,3 C , 1 atm) b/ Tch phenol ra khi 71,1(g) hn hp (A) trn ri cho lng phenol ny tc dng vi 630 (g) HNO 3 Phn ng hon ton cho ra 1 sn phm th duy nht cha 18,34% N . Tnh s mol HNO 3 cn li s:%C6H5OH=66,1; %C2H5OH=6,47; b/ 8,5mol Bi 7: a/ Axit picric(tc 2,4,6_trintophenol) c iu ch bng cch cho phenol tc dng vi hn hp gm axit nitric c v axit sunfuric c(lm cht xc tc). Vit phng trnh phn ng b/ Cho 47g phenol tc dng vi hn hp gm 200g HNO 3 68% v 250g H2SO4 96%. Ga s phn ng xy ra hon ton, hy tnh: Khi lng axit picric sinh ra v nng % HNO 3 cn d sau khi tch ht axit picric ra khi hn hp? s:m=114,5g; C%HNO 3 d=10,85 Bi 8: Tm CTPT v CTCT cc cht trong mi trng hp sau: a/ 0,54g mt ng ng ca phenol (n chc) trung ha va bi 10ml NaOH 0,5M b/ t chy hon ton 1,22g mt ru thm n chc thu c 3,52 g CO 2 Bi 9: t chy hon ton 0,324g hp cht hu c X (cha C, H, O). Sn phm chy c dn qua bnh cha 380ml dung dch Ba(OH)2 0,05ml ta thy kt ta b tan mt phn ng thi khi lng bnh tng ln 1,14g. Cn nu sn phm chy dn qua 220ml dung dch Ba(OH) 2 0,1M th kt ta cc i. Tm CTPT ca X bit rng t khi hi ca X so vi He l 27 Bi 10: Hn hp gm axit benzoic v phenol lm mt mu va 1,5kg nc Brom 3,2%. trung ha cc cht sau th nghim phi dng 180,2ml dung dch NaOH 10% (D=1,11 g/ml). Xc nh thnh phn hn hp.