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June 2012 Edexcel Chemistry Unit 1

June 2012 Edexcel Chemistry Unit 1

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Published by EzioAudi77
June 2012 Edexcel Chemistry Unit 1
June 2012 Edexcel Chemistry Unit 1

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Published by: EzioAudi77 on Jul 09, 2012
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01/10/2013

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Centre NumberCandidate NumberWrite your name here
SurnameOther names
 Total Marks
Paper Reference
Edexcel GCE
P39306A
©2012 Pearson Education Ltd.
7/7/5/5/5/
*P39306A0124*
Chemistry
Advanced SubsidiaryUnit 1: The Core Principles of Chemistry
 Tuesday 15 May 2012 – Afternoon
Time: 1 hour 30 minutes
6CH01/01
Candidates may use a calculator.
Instructions
 
Use
black 
ink or ball-point pen.
 
Fill in the boxes
at the top of this page with your name,centre number and candidate number.
 
Answer
all
questions.
 
Answer the questions in the spaces provided
there may be more space than you need 
.
Information
The total mark for this paper is 80.
The marks for
each
question are shown in brackets
– use this as a guide as to how much time to spend on each question.
Questions labelled with an
asterisk 
(
*
) are ones where the quality of yourwritten communication will be assessed
– you should take particular care with your spelling, punctuation and grammar, aswell as the clarity of expression, on these questions.
A Periodic Table is printed on the back cover of this paper.
Advice
 
Read each question carefully before you start to answer it.
Keep an eye on the time.
Try to answer every question.
Check your answers if you have time at the end.
Turn over 
 
2
*P39306A0224*
SECTION AAnswer ALL the questions in this section. You should aim to spend no more than 20 minutes onthis section. For each question, select one answer from A to D and put a cross in the box .If you change your mind, put a line through the box and then mark your new answer witha cross .1
A solution contains 66 ppm of a solute. The mass of the solute dissolved in 1 kg of thissolution is
A
66 g
B
0.66 g
C
0.066 g
D
0.000066 g
(Total for Question 1 = 1 mark)2
Complete combustion of 50 cm
3
of a hydrocarbon vapour gave 350 cm
3
of carbondioxide, both gas volumes being measured at the same temperature and pressure. Theformula of the hydrocarbon could be
A
C
8
18
B
C
16
C
C
6
14
D
C
5
12
(Total for Question 2 = 1 mark)3
hich of the following statements is true? The Avogadro constant is the number of 
A
grams of any element which contains 6.02 × 10
23
atoms of that element.
B
atoms contained in one mole of any element.
C
atoms contained in one mole of any monatomic element.
D
 particles (atoms, molecules or ions) required to make one gram of a substance.
(Total for Question 3 = 1 mark)
 
3
*P39306A0324*
Turn over 
 
4
n an experiment to determine the enthalpy change of combustion of an alcohol, a spirit burner containing the alcohol was weighed, lit and placed under a copper can containinga known volume of water. The temperature rise of the water was measured and the burner reweighed. The enthalpy change calculated from the results was much lessexothermic than the value reported in the literature.hich of the following factors is
most
likely to be the cause of this error?
A
eat loss around the side of the copper can.
B
The use of a thermometer with a range of 0 – 110 °C rather than 0 – 50 °C.
C
The use of a measuring cylinder for measuring the water rather than a pipette.
D
vaporation of the alcohol during the weighing.
(Total for Question 4 = 1 mark)5
The standard enthalpy changes of formation of carbon dioxide and of methanoic acid areíN-PRO
 –1
DQGíN-PRO
 –1
respectively. Calculate the enthalpy change for thereaction
2
(g)  C
2
(g)
o
C(l)
A
íN-PRO
 –1
B
íN-PRO
 –1
C
N-PRO
 –1
D
N-PRO
 –1
(Total for Question 5 = 1 mark)6
or which of the following changes is the value of 
 H 
negative?
A
(g)
o
 
(g)  e
 – 
B
 
Cl
 – 
(s)
o
 
(g)  Cl
 – 
(g)
C
Cl(g)  e
 – 
o
Cl
 – 
(g)
D
Cl
2
(g)
o
2Cl(g)
(Total for Question 6 = 1 mark)

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