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PGM Catalyst Handbook USA

PGM Catalyst Handbook USA

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Published by AFLAC ............
PGM Catalyst Handbook USA
PGM Catalyst Handbook USA

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Categories:Types, Research, Science
Published by: AFLAC ............ on Jul 11, 2012
Copyright:Attribution Non-commercial

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02/05/2013

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© 2008 Johnson Matthey Plc
the catalyst technical handbook
be selective
 
2
© 2008 Johnson Matthey
2
1
INTRODUCTION
page 3 
2
CATALYSTRANGE
page 4 
2.1
Heterogeneous Catalysts
page 4 
Platinum Group Metal (PGM) Catalysts
2.1.1General Description2.1.2Liquid Phase Reactions2.1.3Gas Phase Reactions2.1.4Choice of Catalyst Support2.1.5Choice of Metal2.1.6Choice of Metal Location2.1.7Catalyst Deactivation2.1.8Safety and Handling2.1.9Packaging and Storage2.1.10Catalyst Recovery and Shipment
Base Metal Catalysts
2.1.11 General Description and Applications
Sponge Metal™ Catalysts
2.1.12 General Description2.1.13 Liquid Phase Reactions2.1.14 Choice of Metal2.1.15 Choice of Catalyst Particle Size2.1.16 Catalyst Deactivation2.1.17 Safety and Handling2.1.18 Packaging and Storage2.1.19 Catalyst Recovery and Shipment
2.2
Homogeneous Catalysts
page 15 
2.2.1 General Description2.2.2 The Catalytic Cycle2.2.3 Choice of Catalyst2.2.4 Product/Catalyst Separation2.2.5 Catalyst Deactivation2.2.6 Safety and Handling2.2.7 Transport and Storage2.2.8 Catalyst Recovery and Shipment
2.3
FibreCat
®
AnchoredHomogenous Catalysts
page 18 
2.3.1 General Description2.3.2 Catalyst Leaching and Recycle
2.4
Smopex
®
– Metal
page 20 
Scavengers
2.4.1 General Description2.4.2Smopex
®
Application
3
CATALYSTSERVICES
page 21
3.1 Saving Time in Process Development3.2Catalyst Kits3.3 Chemical Development and Optimization3.4 Metal Recovery Evaluation Service3.5 Supply of Catalysts3.6 Partnership in CatalystDevelopment/Production3.7 Technical Support for Catalytic Processes3.8 Refining of Catalyst ResiduesSmopex
®
Traditional Refining3.9 Metal Management
4
CHEMISTRIES
page 24 
4.1
Hydrogenation
page 24 
4.1.1 Carbon-Carbon Multiple Bonds4.1.2 Aromatic Ring Compounds4.1.3 Carbonyl Compounds4.1.4 Nitro and Nitroso Compounds4.1.5 Halonitroaromatics4.1.6 Reductive Alkylation4.1.7 Reductive Aminations4.1.8 Imines4.1.9 Nitriles4.1.10Oximes4.1.11HydrogenolysisDebenzylationsHydrodehalogenationsRosenmund Reductions4.1.12Transfer Hydrogenations
4.2
Dehydrogenation
page 41
4.3
Hydroformylation
page 43 
4.4
Carbonylation
page 45 
4.5
Decarbonylation
page 46 
Contents
 
3
© 2008 Johnson Matthey Plc
3
4.6
Hydrosilylation
page 47 
4.7
Cross-Coupling Reactions
page 48 
4.7.1 Heck Reaction4.7.2 Suzuki-Miyaura Coupling4.7.3Alpha-ketone Arylation4.7.4 Carbon-heteroatom coupling e.g.Buchwald-Hartwig amination4.7.5 Organometallic Reactions4.7.6 Sonogashira Reaction4.7.7 Palladacycles
4.8
Cyclopropanation andCarbene Reactions
page 53 
4.9
Isomerization
page 54 
4.10
Oligomerization andPolymerization
page 55 
4.11
Selective Oxidation
page 56 
4.11.1Alcohols to Carbonyls or Carboxylic Acids4.11.2 Dihydroxylation of Alkenes4.11.3Oxygen Insertion Reactions4.11.4Acetoxylation
4.12
Particulate Catalysts
page 59 
4.12.1Organic Synthesis4.12.2Gas Purification
4.13
Chiral Catalysis
page 63 
4.13.1Asymmetric Hydrogenation4.13.2Enantioselective Hydroamination4.13.3Enantioselective Alkyne Addition4.13.4Asymmetric Michael Addition4.13.5CATAXA™ Anchored Catalysts
5
TABLE
:
HETEROGENEOUSCATALYSTS
page 69 
6
TABLE
:
HOMOGENEOUSCATALYSTS
page 73 
7
TABLE
:
SMOPEX
®
METALSCAVENGINGPRODUCTS
page 86 
8
GLOSSARYOFTERMS
page 87 
9
OTHERPUBLICATIONS
page 88 
10
ADDRESSESOFLOCALOFFICES
page 89 

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