366CHEMISTRY
(ii) unsaturated and (iii) aromatichydrocarbons. Saturated hydrocarbonscontain carbon-carbon and carbon-hydrogensingle bonds. If different carbon atoms are joined together to form open chain of carbonatoms with single bonds, they are termed asalkanes as you have already studied inUnit 12. On the other hand, if carbon atomsform a closed chain or a ring, they are termedas cycloalkanes. Unsaturated hydrocarbonscontain carbon-carbon multiple bonds – double bonds, triple bonds or both. Aromatichydrocarbons are a special type of cycliccompounds. You can construct a large number of models of such molecules of both types(open chain and close chain) keeping in mindthat carbon is tetravalent and hydrogen ismonovalent. For making models of alkanes, you can use toothpicks for bonds andplasticine balls for atoms. For alkenes, alkynesand aromatic hydrocarbons, spring models can be constructed.
13.2 ALKANES
As already mentioned, alkanes are saturatedopen chain hydrocarbons containingcarbon - carbon single bonds. Methane (CH
4
)is the first member of this family. Methane is a gas found in coal mines and marshy places. If you replace one hydrogen atom of methane by carbon and join the required number of hydrogens to satisfy the tetravalence of theother carbon atom, what do you get? You get C
2
H
6
. This hydrocarbon with molecular formula C
2
H
6
is known as ethane. Thus youcan consider C
2
H
6
as derived from CH
4
by replacing one hydrogen atom by -CH
3
group.Go on constructing alkanes by doing thistheoretical exercise i.e., replacing hydrogenatom by –CH
3
group. The next molecules will be C
3
H
8
, C
4
H
10
… These hydrocarbons are inert under normal conditions as they do not react withacids, bases and other reagents. Hence, they were earlier known as paraffins (
latin : parum,
little;
affinis,
affinity). Can you think of thegeneral formula for alkane family or
homologous series
? The general formula for alkanes is C
n
H
2n+2
, where n stands for number of carbon atoms and 2n+2 for number of hydrogen atoms in the molecule. Can yourecall the structure of methane? According to VSEPR theory (Unit 4), methane has a tetrahedral structure (Fig. 13.1) which ismultiplanar, in which carbon atom lies at thecentre and the four hydrogen atoms lie at thefour corners of a regular tetrahedron. AllH-C-H bond angles are of 109.5°.In alkanes, tetrahedra are joined together in which C-C and C-H bond lengths are154 pm and 112 pm respectively (Unit 12). Youhave already read that C–C and C–H
σ
bondsare formed by head-on overlapping of
sp
3
hybrid orbitals of carbon and 1
s
orbitals of hydrogen atoms.
13.2.1Nomenclature and Isomerism
You have already read about nomenclatureof different classes of organic compounds inUnit 12. Nomenclature and isomerism inalkanes can further be understood with thehelp of a few more examples. Common namesare given in parenthesis. First three alkanes – methane, ethane and propane have only one structure but higher alkanes can havemore than one structure. Let us writestructures for C
4
H
10
. Four carbon atoms of C
4
H
10
can be joined either in a continuouschain or with a branched chain in thefollowing two ways :
Fig. 13.1
Structure of methane
Butane (
n
- butane), (b.p. 273 K)I
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