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the maximum amount of product, which is calculated using the balanced equation.
Actual yield:
Learning Check
With a limited amount of oxygen, the reaction of carbon and oxygen produces carbon monoxide. 2C(g) + O2(g) 2CO(g) What is the percent yield if 40.0 g of CO are produced when 30.0 g of O2 are used? 1) 25.0% 2) 75.0% 3) 76.2%
Solution
3) 76.2% yield STEP 1 Given: 40.0 g of CO produced (actual) 30.0 g of O2 used Need: percent yield of CO STEP 2 Write a plan to calculate % yield of CO: g of O2 moles of moles of g of CO O2 CO (theoretical) Percent yield of CO = g of CO (actual) x 100% g of CO (theoretical)
General, Organic, and Biological Chemistry Copyright 2010 Pearson Education, Inc. 6
Solution (continued)
STEP 3 Write conversion factors: 1 mole of O2 = 32.0 g of O2 1 mole O2 and 32.0 g O2 32.0 g O2 1 mole O2 1 mole of O2 = 2 moles of CO 1 mole O2 and 2 moles CO 2 moles CO 1 mole O2 1 mole of CO = 28.0 g of CO 1 mole CO and 28.0 g CO 28.0 g CO 1 mole CO
General, Organic, and Biological Chemistry Copyright 2010 Pearson Education, Inc. 7
Solution (continued)
STEP 4 Setup to calculate theoretical yield in g of O2: 30.0 g O2 x 1 mole O2 x 2 moles CO x 28.0 g CO 32.0 g O2 1 mole O2 1 mole CO = 52.5 g of CO (theoretical) Setup to calculate percent yield: 40.0 g CO (actual) x 100 = 76.2% yield (3) 52.5 g CO (theoretical)
General, Organic, and Biological Chemistry Copyright 2010 Pearson Education, Inc. 8
Learning Check
When N2 and 5.00 g of H2 are mixed, the reaction produces 16.0 g of NH3. What is the percent yield for the reaction? N2(g) + 3H2(g) 1) 31.3% of NH3 2) 56.9% of NH3 3) 80.0% of NH3 2NH3(g)
Solution
2) 56.9% STEP 1 Given: 16.0 g of NH3 produced (actual) 5.00 g of H2 used Need: percent yield of NH3 STEP 2 Write a plan to calculate % yield of NH3: g of H2 moles of moles of g of NH3 H2 NH3 (theoretical) Percent yield of NH3 = g of NH3 (actual) x 100% g of NH3 (theoretical)
General, Organic, and Biological Chemistry Copyright 2010 Pearson Education, Inc. 10
Solution (continued)
STEP 3 Write conversion factors: 1 mole of H2 = 2.02 g of H2 1 mole H2 and 2.02 g H2 2.02 g H2 1 mole H2 1 mole of H2 = 2 moles of NH3 1 mole H2 and 2 moles NH3 2 moles NH3 1 mole H2 1 mole of NH3 = 17.0 g of NH3 1 mole NH3 and 17.0 g NH3 17.0 g NH3 1 mole NH3
General, Organic, and Biological Chemistry Copyright 2010 Pearson Education, Inc.
Solution (continued)
STEP 4 Setup to calculate theoretical yield of g of NH3: 5.00 g H2 x 1 mole H2 x 2 moles NH3 x 17.0 g NH3 2.02 g H2 3 moles H2 1 mole NH3 = 28.1 g of NH3 (theoretical) Setup to calculate percent yield: Percent yield = 16.0 g NH3 x 100 = 56.9% yield (2) 28.1 g NH3
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Limiting Reactant
A limiting reactant in a chemical reaction is the substance that
is used up
limits the amount of product that can form and stops the reaction
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Reacting Amounts
In a table setting, there is 1plate, 1 fork, 1 knife, and 1 spoon.
How many table settings are possible from 5 plates, 6 forks, 4 spoons, and 7 knives?
What is the limiting item?
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15
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With 1 tablespoon of peanut butter, only 1 sandwich could be made. The peanut butter is the limiting item.
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Limiting Reactant
When 4.00 moles of H2 is mixed with 2.00 moles of Cl2, how many moles of HCl can form?
H2(g)
Cl2(g)
2HCl(g)
??? Moles
Calculate the moles of product that each reactant, H2 and Cl2, could produce.
The limiting reactant is the one that produces the smaller number of moles of product.
General, Organic, and Biological Chemistry Copyright 2010 Pearson Education, Inc. 19
4.00 moles of HCl is the smaller number of moles produced. Thus, Cl2 will be used up.
The limiting reactant is Cl2.
General, Organic, and Biological Chemistry Copyright 2010 Pearson Education, Inc. 20
Check Calculations
Equation Initially H2 4.00 moles Cl2 2.00 moles 2HCl 0 mole
2.00 moles
2.00 moles
+4.00 moles
2.00 moles 0 moles 4.00 moles (4.00 2.00) (2.00 2.00) (0 + 4.00) Excess Limiting Product possible
Copyright 2010 Pearson Education, Inc. 21
Learning Check
What is the mass of water that can be produced when 8.00 g of H2 and 24.0 g of O2 react?
2H2(g) + O2(g)
1) 8.0 g of H2O 2) 27.0 g of H2O 3) 72 g of H2O
2H2O(l)
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Solution
3) 72 g of H2O
Moles of H2O from H2: 8.00 g H2 x 1 mole H2 x 2 moles H2O = 4.0 moles of H2O 2.0 g H2 2 moles H2 Moles of H2O from O2: 24.0 g O2 x 1 mole O2 x 2 moles H2O = 1.50 moles of H2O 32.0 g O2 1 mole O2 Smaller number
of moles of H2O