CHUYN HIROCACBON

Cu 1: t hon ton mt hirocacbon A thy cn 7,84 lt O2 (ktc) v thu c 5,4 gam nuc. Cng thc phn t ca A
l:
A. C2H6
B. C2H4
C. C2H2
D. CH4
Cu 2: t V lt hn hp kh X (ktc) gm metan, etan v butan sn phm dn qua bnh 1 ng H2SO4, bnh II ng
KOH d, thy bnh I tng 7,2 gam bnh II tng 13,2 gam. Gi tr ca V l:
A. 1,12 lt
B. 2,24 lt
C. 3,36 lt
D. 4,52 lt
Cu 3: Mt hn hp gm hai ankan ng ng k tip c khi lng 24,8 gam chim th tch 11,2 lt (ktc). Thnh phn
% th tch ca 2 ankan l:
A. 35% v 65%
B. 30% v 70%
C. 40% v 60%
D. 20% v 80%
Cu 4: Clo ha mt ankan theo t l mol 1 : 1 ch thu c mt dn xut mono clo c t khi i vi NO l 4,95. Ankan ny
l:
A. 2,3,3-trimetylpentan
B. 2,2,3,3-tetrametylbutan
C. 2,3,4-trimetylpentan
D. octan
Cu 5: Crckinh 560 (lt) C4H10 sau mt thi gian thu c 1010 (lt) hn hp C4H10. CH4, C3H6, C2H4, C2H6 (cc cht cng
iu kin). Th tch C4H10 cha phn ng l:
A. 100 (lt)
B. 110 (lt)
C. 55 (lt)
D. 85 (lt)
Cu 6: t chy hon ton mt hirocacbon A thu c CO2 v H2O vi t l v khi lng l 0,44 : 0,21. A to c 2 dn
xut monoclo. A c tn l:
A. 2-metyl pentan
B. 2,4-imetyl pentan
C. 2,3-imety butan
D. pentan
Cu 7: Crckinh 5,8 gam butan thu c hn hp kh X. t hon ton kh X thu c bao nhiu gam nc ?
A. 4,5 gam
B. 9 gam
C. 18 gam
D. 20 gam
Cu 8: t hn hp X gm CH4, C2H2 v C4H6 thu c th tch CO2 bng th tch hi nc (o cng iu kin). Thnh
phn phn trm th tch ca metan trong hn hp X l:
A. 33,33%
B. 50%
C. 66,67%
D. 80%
Cu 9: Clo ha metan c mt dn xut X trong clo chim 92,2% khi lng. Tn ca X l:
A. metylen clorua
B. metyl clorua
C. clorofom
D. cacbon tetraclorrua
Cu 10: t 11,2 lt hn hp X gm ankan A v xicloankan B thy cn 44,8 lt O2 v thu c 29,12 lt CO2 kh o (ktc).
Thnh phn phn trm th tch ca A trong hn hp X l:
A. 20%
B. 80%
C. 50%
D. 75%
Cu 11: t hn hp X gm C2H4, C2H4 v C3H8 thu c 8,96 lt CO2 (ktc) v 9 gam nc. Th tch oxi (ktc) cn
t ht hn hp trn l:
A. 14,56 lt
B. 20,16 lt
C. 11,2 lt
D. 15,5 lt
Cu 12: t hn hp X gm etilen, xiclopropan v butylen thy cn 6,72 lt O2 (ktc). Sn phm dn qua dung dch nc
vi d thu c m gam kt ta. Gi tr ca m l:
A. 10
B. 15
C. 20
D. 30
Cu 13: t hon ton m gam hn hp X gm axetilen, metylaxetilen v butaien thu c 6,72 lt CO2 (ktc) v 3,6 gam
H2O. Nu hiro ha hon ton m gam hn hp X cn V lt H2 (ktc). Gi tr ca V l:
A. 2, 24
B. 4, 48
C. 6, 72
D. 7,98
Cu 14: T khi hi ca hn hp X gm CH4 v C2H2 i vi H2bng 11,5 th lng O2 cn dng t chy ht 1 mol hn
hp X l:
A. 3, 75 mol
B. 2, 35 mol
C. 2, 75 mol
D. 1, 55 mol
Cu 15: t hon ton hn hp X gm mt ankan v mt ankin cn 6, 72 lt O2 (ktc) sn phm dn qua dung dch nc
vi d thy bnh nc vi tng a gam v tch c 20 gam kt ta. Gi tr ca a l:
A. 12,4
B. 10,6
C. 4,12
D. 5,65
Cu 16: t hn hp kh X gm mt anken v mt xicloankan thy cn 3,36 lt O2 (ktc); sn phm dn qua dung dch
nc vi trong d thy bnh nc vi trong d thy bnh nc vi tng m gam v tch c p gam kt ta. Gi tr ca m, p
ln lt l:
A. 6,2 ; 15
B. 9,3 ; 15
C. 6,2 ; 10
D. 9,3 ; 10
Cu 17: X, Y, Z l ba hirocacbon ng ng k tip c tng khi lng phn t l 174(vC). Khi t chy X th thu c
mol CO2< mol H2O
A. C2H6, C3H8, C4H10
B. C3H8, C4H10, C5H12
C. C2H4, C3H4, C4H8
D. C3H6, C4H8, C5H10
Cu 18: t chy hon ton ba hirocacbon A, B, C c s mol bng nhau ta thu c lng CO2 nh nhau v t l s mol
nH2O : nCO2 ca A, B, C tng ng bng 0,5 ; 1 ; 1,5. A, B, C ln lt l :
A. C4H8, C4H10, C4H6
B. C2H6, C3H6, C3H8
C. C3H8, C3H4, C3H6
D. C2H2, C2H4, C2H6
Cu 19: t chy hon ton mt hn hp nhiu xicloankan thu c: ( a + 10) gam H2O v (a + 36) gam CO2. Xc nh gi
tr ca a?

A. 10
B. 9
C. 8
D. 7
Cu 20: Cho 5,4 gam ankin A phn ng vi dung dch AgNO3trong NH3 thu c 16,1 gam kt ta. Tn ca A l:
A. propin
B. but-1-in
C. pent-1-in
D. hex-1-in
Cu 21: Hiro ha hon ton mt anken A cn 2,24 lt H2 (ktc) v thu c mt ankan phn nhnh. Cng lng anken
trn tc dng vi dung dch brom d thu c 21,6 gam dn xut ibrom. Tn ca anken A l:
A. isobutylen
B. but-2-en
C. 2-metylpent-2-en
D. 2-metyl but-2-en
Cu 22: Nhit phn 2,8 lt etan (ktc) c hn hp kh A, dn A qua dung dch AgNO3 d trong NH3 thu c 1,2 gam
kt ta. Kh cn li dn qua bnh brom d thy bnh brom d thy bnh brom tng 2,8 gam. Hiu sut phn ng nhit phn
l:
A. 80%
B. 84%
C. 90%
D. 96%
Cu 23: Trng hp 5,6 lt C2H4 (ktc), nu hiu sut phn ng l 90% th khi lng polime thu c l:
A. 6,3 gam
B. 5,3 gam
C. 7,3 gam
D. 4,3 gam
Cu 25: A, B, C l ba hirocacbon kh kin thng k tip trong dy ng ng . Bit Mc = 2MA. A, B, C ln lt l:
A. CH4, C2H6, C3H8
B. C2H2, C3H4, C4H6
C. C2H4, C3H6, C4H8
D. C2H6, C3H8, C4H10
Cu 26: t 8,96 lt hn hp X gm ankin A v anken B thu c 17,93 lt CO2 (ktc) v 12,6 gam nc. Thnh phn
phn trm th tch ca A, B trong hn hp X ln lt l:
A. 90% v 10%
B. 10% v 90%
C. 80% v 20%
D. 20% v 80%
Cu 27: t hon ton hn hp hai hirocacbon c khi lng phn t hn km nhau 14 cV thu c m gam nc v 2m
gam CO2. Cng thc phn t ca hai hirocacbon l:
A. C2H2 v C3H4
B. C2H6 v C3H8
C. C3H6 v C4H8
D. C4H10 v C5H12
Cu 28: t hon ton hirocacbon A (A kh iu kin thng) bng oxi d, sau phn ng c hn hp kh B c thnh
phn phn trm th tch nh sau: 55%O2, 27%CO2 v 18% hi nc. Cng thc ca A l:
A. C2H2
B. C3H4
C. C2H4
D. C2H6
Cu 29: t 6,72lt hn hp X (ktc) gm ankan A v ankin B thu c 11,2lt CO2 (ktc) v 7,2 gam nc. Thnh
phn phn trm th tch A, B trong hn hp X ln lt l:
A. 25% v 75%
B. 50% v 50%
C. 33,3% v 66,7%
D. 75% v 25%
Cu 30: Dn 4,48 lt (ktc) hn hp X ng s mol gm ankin A v anken B (cng s nguyn t hiro trong phn t) qua
bnh ng dung dch brom d thy bnh brom tng 6,8 gam. Cng thc ca A, B ln lt l:
A. C3H4 v C2H4
B. C4H6 v C3H6
C. C2H2 v C2H4
D. C5H8 v C4H8
Cu 31: Dn 8,96 lt (ktc) hn hp X gm ankan A v anken B kh ( iu kin thng) qua dung dch brom d thy
bnh brom tng 16,8 gam. Cng thc phn t ca B l:
A. C2H4
B. C3H6
C. C4H8
D. C5H7
Cu 32: t V lt (ktc) hn hp X gm axetilen, ivinyl v metylaxetilen thu c 6,272 lt CO2 (ktc) v 3,24 gam nc.
Gi tr ca V l :
A. 2,24
B. 3,36
C. 1,12
D. 6,72
Cu 33: t hon ton 4,48 lt hn hp X (ktc) gm CH4, C2H6 v C2H4 thu c 6,72 lt CO2 (ktc) v 7,56 gam
nc. Tnh thnh phn phn trm th tch ca C2H4 trong hn hp X?
A. 25%
B. 30%
C. 40%
D. 50%
Cu 34: Hn hp X gm ankin A, anken B v H2 c th tch 11,2 lt (ktc). Dn hn hp X qua Ni nung nng khi phn
ng hon ton c 4,48 lt mt hirocacbon Y duy nht (ktc) c t khi vi hiro bng 22. Cng thc phn t ca A, B
v thnh phn phn trm th tch ca A, B trong hn hp X l:
A. C2H2 (75%) v C2H4 (25%)
B. C3H4 (50%) v C3H6 (50%)
C. C2H2 (50%) v C2H4 (50%)
D. C3H4 (25%) v C3H6 (75%)
Cu 35: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trong khng kh, oxi
chim 20% th tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam nc. Th tch khng kh ( ktc) nh nht cn dng
t chy hon ton lng kh thin nhin trn l
A. 70,0 lt
B. 78,4 lt
C. 84,0 lt
D. 56,0 lt
Cu 36: Dn V lt ( ktc) hn hp X gm axetilen v hiro i qua ng s ng bt niken nung nng, thu c kh Y. Dn
Y vo lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 12gam kt ta. Kh i ra khi dung dch phn ng va
vi 16 gam brom v cn li kh Z. t chy hon ton kh Z thu c 2,24 lt kh CO2 ( ktc) v 4,5 gam nc. Gi tr
ca V bng
A. 11,2
B. 13,44
C. 5,60
D. 8,96
Cu 37: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2 , tc dng c vi Na v vi NaOH.
Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol X tham gia phn ng v X ch tc dng c vi
NaOH theo t l s mol 1:1. Cng thc cu to thu gn ca X l
A. C6H5CH(OH)2
B. HOC6H4CH2OH
C. CH3C6H3(OH)2
D. CH3OC6H4OH
Cu 38: Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu c hn hp Z gm
hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch

NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (th
tch dung dch thay i khng ng k)
A. C2H5OH v C3H7OH B. C2H5OH v C4H9OH
C. C3H7OH v C4H9OH
D. C4H9OH v
C5H11OH
Cu 39: Khi cho ankan X (trong phn t c phn trm khi lng cacbon bng 83,72%) tc dng vi clo theo t l s mol
1:1 (trong iu kin chiu sng) ch thu c 2 dn xut monoclo ng phn ca nhau. Tn ca X l?
A. 3-metylpentan
B. 2,3-imetylbutan
C. 2-metylpropan
D. butan.
Cu 40: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn
t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l?
A. 20
B. 40
C. 30
D. 10
Cu 41: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l
A. 2-metylpropen v but-1-en (hoc buten-1).
B. propen v but-2-en (hoc buten-2).
C. eten v but-2-en (hoc buten-2).
D. eten v but-1-en (hoc buten-1).
Cu 42: un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c hn hp kh
Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li 0,448 lt hn hp kh Z ( ktc) c t khi
so vi O2 l 0,5. Khi lng bnh dung dch brom tng l
A. 1,04 gam
B. 1,32 gam
C. 1,64 gam
D. 1,20 gam
Cu 43: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng khi
lng ca CO2 v H2O thu c l
A. 20,40 gam
B. 18,60 gam
C. 18,96 gam
D. 16,80 gam
Cu 44: Cho cc cht: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3-C(CH3)=CH-CH3, CH2=CH-CH2CH=CH2. S cht c ng phn hnh hc l
A. 2
B. 3
C. 1
D. 4.
Cu 45: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch kh o cng iu kin
nhit v p sut); t khi ca Y so vi H2 bng 12. Cng thc phn t ca X l?
A. C6H14
B. C3H8
C. C4H10
D. C5H12
Cu 46: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon
ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng
thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc)
A. CH4v C2H4
B. CH4v C3H4
C. CH4v C3H6
D. C2H6v C3H6.
Cu 47: Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba trong mt phn t.
t chy hon ton 1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit , p sut). Khi cho X tc dng vi
Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l
A. 3.
B. 4.
C. 2.
D. 5.
Cu 48: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2lt hi H2O (cc th tch
kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l
A. C2H6B. C2H4C. CH4D. C3H8
Cu 49: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0
ml CO2(cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh hiro l
A. 12,9
B. 25,8
C. 22,2
D. 11,1
Cu 50: t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO2 bng s mol H2O. Thnh
phn phn trm v s mol ca X v Y trong hn hp M ln lt l
A. 75% v 25%
B. 20% v 80%
C. 35% v 65%
D. 50% v 50%