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49.

50.

51.

In which of the following groups all the the members have linear shape (a) NO2+, N3, H C H (b) N3, I3, H C H (c) XeF2, C2H2, SO2 (d) CO2, BeCl2, SnCl2 Consider the following molecules : H2O H2 S H2Se H2Te I II III IV Arrange these molecules in increasing order of bond angles. (a) I < II < III < IV (b) IV < III < II < I (c) I < II < IV < III (d) II < IV < III < I The correct order of the increasing ionic character is(a) BeCl2 < MgCl2 < CaCl2 < BaCl2 (b) BeCl2 < MgCl2 < BaCl2 < CaCl2 (c) BeCl2 < BaCL2 < MgCl2 < CaCl2 (d) BaCl2 < MgCl2 < CaCl2 < BeCl2

52.

The molecule BF3 borth are covalent compounds. But BF, is non,polar and NF 3 is polar. The reason is that(a) boron is a metal and nitrogen is a gas in uncombined state (b) B F bond have no dipole moment whereas N F bond have dipole moment (c) atomic size of boron is smaller than that of nitrogen (d) BF3 is symmetrical molecule where as NF3 is unsymmetrical 53. One mole of ethanol is treated with one mole of ethanoic acid at 25C. Onefourth of the acid changes into ester at equilibrium. The equilibrium constant for the reaction will be (A) 1/9 (B) 4/9 (C) 9 (D) 9/4 54. The equilibrium, PCl5(g) PCl3(g) + Cl2(g) is attained at 25C in a closed container and an inert gas He is introduced. Which of the following statements are correct? (A) concentration of PCl5, PCl3 and Cl2 are changed (B) more Cl2 is formed (C) concentration of PCl3 is reduced (D) Nothing happens 55. In which of the following equilibrium, the value of KP is less than KC? (A) N2O4 2NO2 (B) N2 + O2 (C) N2 + 3H2 2NH3 (D) 2SO2 + O2 56. In the reaction A2(g) + 4B2 (g) 2AB4(g) , H > at (A) low temperature and high pressure (B) high temperature and low pressure (C) low temperature and low pressure (D) high temperature and high pressure 1 57. For the reaction SO2(g) + O2(g) SO3(g) 2 Calculate Kc. 12 (A) 1.7 10 12 (C) 8.40 10

2NO 2SO3

0. The decomposition of AB4 (g) will be favoured

Kp = 1.7 10 (B) 0.7 10 12 (D) 1.2 10


12

12

at 20C and 1 atm pressure.

58. For a gaseous equilibrium 2A(g) 2B(g) + C(g) , Kp has a value 1.8 at 700K. What is the value of Kc for the equilibrium 2B(g) + C(g) 2A at that temperature (A) 0.031 (B) 32 3 (C) 44.4 (D) 1.3 10