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ACTIO MSDS ID: 29227
View Section :
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SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
MA NUFA CTURER NA ME: DIVISION: A DDRESS: EMERGENCY PHONE: ISSUED: SUPERSEDES: Specific Use: Intended Use: A DDRESS: A DDRESS CITY: A DDRESS STA TE: A DDRESS ZIP: BUSINESS PHONE: MSDS Manufacturer Number: TRA DE NA ME: PRODUCT NA ME: 3M 3M ESPE Dental Products 3M Center St. Paul, MN 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) 02/24/10 10/02/06 Temporary dental restorative Dental product Limitations on Use: For use only by dental professionals 3M Center St. Paul, MN 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) 16-2782-7 3MTM ESPETM CA VIT/ CA VIT-W/ CA VIT-G 3M ESPE CA VIT/ CA VIT-W/ CA VIT-G
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient Name CA S# Ingredient Percent
ZINC O XIDE C ALC IUM SULFATE BAR IUM SULFATE ETHYLENE BIS(O XYETHYLENE)DIAC ETATE TALC ZINC SULFATE PO LY(VINYL AC ETATE)
1314-13-2 7778-18-9 7727-43-7 111-21-7 14807-96-6 7733-02-0 9003-20-7
30 - 50 1 - 30 0 - 20 10 - 20 0 - 20 5 - 10 1 - 5
by W e ight by W e ight by W e ight by W e ight by W e ight by W e ight by W e ight
SECTION 3 - HAZARDS IDENTIFICATION
Specific Physical Form: Odor, Color, Grade: General Physical Form: Immediate health, physical, and environmental hazards: Paste Slight characteristic odor, pink, grey, or white in color Solid This document has been prepared in accordance with the U.S. OSHA Hazard Communication Standard, which requires the inclusion of all known hazards of the product or ingredients regardless of the potential risk. The risks of the hazards communicated in this document may vary depending on the potential for exposure. Contact with the eyes during product use is not expected to result in significant irritation. Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
EYE CONTA CT: SKIN CONTA CT: INHA LA TION:
SECTION 4 - FIRST AID MEASURES
Get medical attention. Do not induce vomiting unless instructed to do so by medical personnel. dry chemical.cfm?msds_id=29227&client_id=111&CFID=1975484&CFTOKEN=11cdaa57ea… . Call 3M. the user should determine if the release qualifies as reportable according to local. Not applicable.g.HANDLING and STORAGE HA NDLING: STORA GE: A void eye contact. Give victim two glasses of water.2/21/13 MSDS EYE CONTA CT: SKIN CONTA CT: INHA LA TION: INGESTION: Flush eyes with large amounts of water. Do not eat. First A id Comments: SECTION 5 . get medical attention. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA ). The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.actiocms. get medical attention. ZINC OXIDE A CGIH TWA . The spill should be cleaned up by qualified personnel. respirable fraction 10 mg/m3 ZINC OXIDE 2/6 www. state. Remove person to fresh air.HELPS line (1-800-364-3577) for more information on handling and managing the spill.EXPOSURE CONTROLS. Collect as much of the spilled material as possible. Observe precautions from other sections. If signs/symptoms persist. Never give anything by mouth to an unconscious person. See STA BILITY A ND REA CTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. Clean up residue. and federal regulations. Dispose of collected material as soon as possible. PERSONAL PROTECTION .com/view_msds/MSDSDisplayMYSQL/msdsdisplaycode_MYSQL. SECTION 7 . get medical attention. ft. Wash exposed areas thoroughly with soap and water.UEL: EXTINGUISHING MEDIA : SPECIA L FIRE FIGHTING PROCEDURES: UNUSUA L FIRE A ND EXPLOSION HA ZA RDS: Note: No Data A vailable Not A pplicable Not A pplicable Not A pplicable Use fire extinguishers with class B extinguishing agents (e. as total dust 0.FIRE FIGHTING MEASURES A UTOIGNITION TEMPERA TURE: FLA SH POINT: FLA MMA BLE LIMITS . carbon dioxide). respirable fraction 2 mg/m3 ZINC OXIDE A CGIH STEL.LEL: FLA MMA BLE LIMITS . Wash affected area with soap and water. Place in a closed container approved for transportation by appropriate authorities. SECTION 8 . If signs/symptoms develop. If signs/symptoms develop. SECTION 6 .3 mg/m3 TA LC OSHA TWA 20 millions of particles/cu.. Not applicable. Ventilate the area with fresh air. In the event of a release of this material. drink or smoke when using this product.ACCIDENTAL RELEASE MEASURES A ccidental Release Measures: Evacuate unprotected and untrained personnel from hazard area.EXPOSURE GUIDELINES Guideline Info: Ingredient: Guideline Type: Guideline Info: Ingredient: Guideline Type: Guideline Info: Ingredient: Guideline Type: Guideline Info: Ingredient: Guideline Type: Guideline Info: Ingredient: 15 mg/m3 TA LC OSHA TWA concentration.
pink. as total dust 15 mg/m3 CA LCIUM SULFA TE A CGIH TWA . respirable 0. drink or smoke when using this product. inhalable fraction 10 mg/m3 CA LCIUM SULFA TE Do not eat. as total dust 15 mg/m3 TA LC A CGIH TWA . as fume 5 mg/m3 ZINC OXIDE OSHA TWA . respirable fraction 2 mg/m3 OSHA TWA . A void eye contact. A CGIH: A merican Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA : Occupational Safety and Health A dministration A IHA : A merican Industrial Hygiene A ssociation Workplace Environmental Exposure Level (WEEL) Use with appropriate local exhaust ventilation. Use in an enclosed process area is recommended. Wash exposed areas thoroughly with soap and water. grey. as total dust TA LC CMRG TWA . or white in color Solid No Data A vailable Not A pplicable Not A pplicable Not A pplicable Not A pplicable No Data A vailable 3/6 www.1 mg/m3 5 mg/m3 CA LCIUM SULFA TE OSHA TWA .LEL: Flammable Limits . Do not ingest. Color.actiocms. Under normal use conditions.5 mg/m3 TA LC OSHA TWA concentration. airborne exposures are not expected to be significant enough to require respiratory protection. respirable fraction 5 mg/m3 ZINC OXIDE OSHA TWA . Grade: General Physical Form: A utoignition temperature: Flash Point: Flammable Limits . The following eye protection(s) are recommended: Safety Glasses with side shields. as respirable dust 0.cfm?msds_id=29227&client_id=111&CFID=1975484&CFTOKEN=11cdaa57ea… .PHYSICAL and CHEMICAL PROPERTIES Odor.2/21/13 MSDS Guideline Type: Guideline Info: Ingredient: Guideline Type: Guideline Info: Ingredient: Guideline Type: Ingredient: Guideline Type: Guideline Info: Ingredient: Guideline Type: Guideline Info: Guideline Info: Ingredient: Guideline Type: Guideline Info: Ingredient: Guideline Type: Guideline Info: Guideline Type: Ingredient: Guideline Type: Guideline Info: Ingredient: Guideline Type: Guideline Info: Ingredient: Guideline Type: Guideline Info: Ingredient: Guideline Type: Guideline Info: Ingredient: Prevention of Swallowing: SOURCE OF EXPOSURE LIMIT DA TA : OSHA TWA . respirable fraction 5 mg/m3 BA RIUM SULFA TE OSHA TWA . A void prolonged or repeated skin contact. ENGINEERING CONTROLS: EYE PROTECTION: SKIN PROTECTION: RESPIRA TORY PROTECTION: SECTION 9 . respirable fraction BA RIUM SULFA TE A CGIH TWA 10 mg/m3 BA RIUM SULFA TE OSHA TWA . Not applicable.UEL: BOILING POINT: DENSITY: Slight characteristic odor.com/view_msds/MSDSDisplayMYSQL/msdsdisplaycode_MYSQL.
(50kg): dispose of waste product in a sanitary landfill. 702011. 702011-0464-6. 70-2011-0158-4. 70-2011-0466-1. consult applicable regulations or authorities before disposal. 70-2011-2098-0. SECTION 15 .2/21/13 MSDS VA POR DENSITY: VA POR PRESSURE: SPECIFIC GRA VITY: pH: MELTING POINT: EVA PORA TION RA TE: VOLA TILE ORGA NIC COMPOUNDS: PERCENT VOLA TILE: VISCOSITY: VOC LESS H2O & EXEMPT SOLVENTS: SOLUBILITY IN WA TER: Specific Physical Form: Kow .No Pressure Hazard .0 [Ref Std: WA TER=1] Not A pplicable No Data A vailable Not A pplicable Not A pplicable Not A pplicable No Data A vailable Not A pplicable Nil Paste Not A pplicable SECTION 10 .No Immediate 4/6 www.REGULATORY INFORMATION US FEDERA L REGULA TIONS: 311/312 Hazard Categories: Contact 3M for more information. 70-2011-3641-6.Oct/Water partition coef: Not A pplicable Not A pplicable 2. 10. A s a disposal alternative. 70-2011-0159-2. Not determined.ECOLOGICAL INFORMATION ECOTOXICOLOGICA L INFORMA TION: CHEMICA L FA TE INFORMA TION: Not determined.DISPOSAL CONSIDERATIONS WA STE DISPOSA L: For quantities <100 lbs. 70-2011-3642-4 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material.cfm?msds_id=29227&client_id=111&CFID=1975484&CFTOKEN=11cdaa57ea… . Since regulations vary. 70-2011-0463-8. 70-2011-0462-0. 702011-0157-6. Fire Hazard . 70-2011-2096-4. EPA Hazardous Waste Number EPA Hazardous Waste Number (RCRA ): Not regulated (RCRA ): SECTION 14 . For larger quantities: incinerate in an industrial or commercial facility in the presence of a combustible material. 70-2011-0156-8. 702011-2097-2.0460-4. SECTION 13 . 70-2011-0461-2. HA ZA RDOUS DECOMPOSITION Substance: Carbon monoxide (Condition: During Combustion) Substance: PRODUCTS: Carbon dioxide (Condition: During Combustion) Substance: Irritant Vapors or Gases (Condition: During Combustion) SECTION 11 . 70-2011-0155-0. 70-2011-0465-3. 70-2011-0160-0.No Reactivity Hazard .TRANSPORT INFORMATION Transportation Information: ID Number(s): 70-2011-0154-3. SECTION 12 .STABILITY and REACTIVITY STA BILITY: CONDITIONS TO A VOID: HA ZA RDOUS POLYMERIZA TION: Stable.1 Conditions to avoid None known 10.TOXICOLOGICAL INFORMATION Toxicological Information: Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.6 .com/view_msds/MSDSDisplayMYSQL/msdsdisplaycode_MYSQL.3.2 Materials to avoid None known Hazardous polymerization will not occur.actiocms. dispose of waste product in a facility permitted to accept chemical waste.
Section 6: Release measures 5/6 NFPA . Section 8: Prevention of swallowing information was modified. 1 1 0 None The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.decontamination . Section 4: First aid for ingestion (swallowing) .was modified. This MSDS has been prepared to meet the U.S. INCLUDING. % by Wt: 30 . In addition.FIRE: NFPA . Section 3: Potential effects from eye contact was modified. Section 3: Potential effects from inhalation information was modified.REA CTIVITY: NFPA .10. Section 8: Skin protection phrase was modified. Section 8: Engineering controls information was modified.actiocms. Due to the remote possibility that electronic transfer may have resulted in errors. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. ZINC OXIDE (ZINC COMPOUNDS): (CA S: 1314-13-2. or are exempt polymers whose monomers are listed on EINECS. 3M provides information in electronic form as a service to its customers. . Page Heading: Product name was modified.com/view_msds/MSDSDisplayMYSQL/msdsdisplaycode_MYSQL. OSHA Hazard Communication Standard. Section 10. Section 2: Ingredient table was added.HEA LTH: NFPA .1 Conditions to avoid was added. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. spill.3M. acute exposure to a material under conditions of fire. 3M makes no representations as to its completeness or accuracy.50.Yes Delayed Hazard . or similar emergencies. Section 14: ID Number(s) Template 1 was added.) ZINC SULFA TE (ZINC COMPOUNDS): (CA S: 7733-02-0. some of which are uniquely within the user's knowledge and control.ADDITIONAL INFORMATION HMIS A ND NFPA NOTES: NFPA Explanation: National Fire Protection A ssociation (NFPA ) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term. Section 13: Waste disposal method information was modified. % by Wt: 5 . Section 10. Section 15: 311/312 Immediate Hazard score was modified.medical assistance . Commercial use of this material is regulated by the FDA . BUT NOT LIMITED TO. Section 6: Release measures information was added. Contact 3M for more information. Section 6: Release measures information was added.1200.cfm?msds_id=29227&client_id=111&CFID=1975484&CFTOKEN=11cdaa57ea… . it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. Section 3: Immediate other hazard(s) was added. A NY IMPLIED WA RRA NTY OF MERCHA NTA BILITY OR FITNESS FOR A PA RTICULA R PURPOSE OR COURSE OF PERFORMA NCE OR USA GE OF TRA DE. Section 1: Product use information was modified. EXPRESSED OR IMPLIED. Section 9: Property description for optional properties was modified. Section 7: Handling information was modified. This material contains one or more substances not listed on the TSCA Inventory.S OSHA : SECTION 313: SECTION 16 . Contact 3M for more information. Copyright was modified. 3M MA KES NO WA RRA NTIES. Given the variety of factors that can affect the use and application of a 3M product. Section 8: Exposure guidelines data source legend was added. omissions or alterations in this information.com Section 1: Product name was modified. A ll applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS). Section 15: Inventories information was modified.2/21/13 MSDS Hazard . 29 CFR 1910. Section 15: EPCRA 313 information was added.) INTERNA TIONA L REGULA TIONS: U.was modified.No STA TE REGULA TIONS: CHEMICA L INVENTORIES: Contact 3M for more information.2 Materials to avoid was added.SPECIA L HA ZA RDS: DISCLA IMER: Revision Changes: www. Section 3: Potential effects from ingestion information was modified. Section 4: First aid for ingestion (swallowing) . Section 8: Exposure guidelines ingredient information was added. Section 15: EPCRA 313 text was added. Section 14: ID Number Heading Template 1 was added.
Section 10: Materials to avoid physical property was added. www. Section 10: Materials and conditions to avoid physical property was deleted. Section 10: Conditions to avoid physical property was added.2/21/13 MSDS information was added. Section 6: Release measures information was deleted.actiocms. Section 3: Immediate other hazard(s) comment was deleted.com/view_msds/MSDSDisplayMYSQL/msdsdisplaycode_MYSQL.cfm?msds_id=29227&client_id=111&CFID=1975484&CFTOKEN=11cdaa57ea… 6/6 .
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