You are on page 1of 71

1

2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DMEPLANT.HSC

Unit Set:

NewUser1

Date/Time:

Wed May 23 23:14:35 2012

6

Material Stream: 1

7
8
9

Basis-1

Property Package:

PRSV

CONDITIONS

10
11

Overall

12

Vapour / Phase Fraction

13

Temperature:

14

Pressure:

15

Liquid Phase

0.0000

1.0000

(C)

25.00 *

(atm)

1.000 *

1.000

Molar Flow

(kgmole/h)

0.7520 *

0.7520

16

Mass Flow

(tonne/d)

0.5765

0.5765

17

Std Ideal Liq Vol Flow

(m3/h)

3.012e-002

3.012e-002

18

Molar Enthalpy

-2.483e+005

19

Molar Entropy

20

Heat Flow

21

Liq Vol Flow @Std Cond

25.00

(kJ/kgmole)

-2.483e+005

(kJ/kgmole-C)

1.946

1.946

(kJ/h)

-1.867e+005

-1.867e+005

3.009e-002 *

(m3/h)

3.009e-002

22

COMPOSITION

23
24

Overall Phase

25
26

Fluid Package:

COMPONENTS

MOLAR FLOW
(kgmole/h)

27

MOLE FRACTION

MASS FLOW
(kg/h)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (m3/h)

0.0000

LIQUID VOLUME
FRACTION

28

Methanol

0.7370 *

0.9800 *

23.6134 *

0.9831 *

0.0297 *

0.9852 *

29

diM-Ether

0.0008 *

0.0010 *

0.0346 *

0.0014 *

0.0001 *

0.0017 *

30

H2O

0.0113 *

0.0150 *

0.2031 *

0.0085 *

0.0002 *

0.0068 *

31

AcetAldehyde

0.0008 *

0.0010 *

0.0331 *

0.0014 *

0.0000 *

0.0014 *

32

AceticAcid

0.0011 *

0.0015 *

0.0685 *

0.0029 *

0.0001 *

0.0022 *

33

Acetone

0.0011 *

0.0015 *

0.0663 *

0.0028 *

0.0001 *

0.0028 *

34

Total

0.7520

1.0000

1.0000

0.0301

1.0000

35

Liquid Phase

36
37

24.0190

COMPONENTS

MOLAR FLOW
(kgmole/h)

38

MOLE FRACTION

MASS FLOW
(kg/h)

Phase Fraction

1.000

MASS FRACTION

LIQUID VOLUME
FLOW (m3/h)

LIQUID VOLUME
FRACTION

39

Methanol

0.7370

0.9800

23.6134

0.9831

0.0297

0.9852

40

diM-Ether

0.0008

0.0010

0.0346

0.0014

0.0001

0.0017

41

H2O

0.0113

0.0150

0.2031

0.0085

0.0002

0.0068

42

AcetAldehyde

0.0008

0.0010

0.0331

0.0014

0.0000

0.0014

43

AceticAcid

0.0011

0.0015

0.0685

0.0029

0.0001

0.0022

44

Acetone

0.0011

0.0015

0.0663

0.0028

0.0001

0.0028

45

Total

0.7520

1.0000

24.0190

1.0000

0.0301

1.0000

46

K VALUE

47
48

COMPONENTS

MIXED

LIGHT

HEAVY

49

Methanol

0.0000

0.0000

---

50

diM-Ether

0.0000

0.0000

---

51

H2O

0.0000

0.0000

---

52

AcetAldehyde

0.0000

0.0000

---

53

AceticAcid

0.0000

0.0000

---

54

Acetone

0.0000

0.0000

---

55

UNIT OPERATIONS

56
57
58

FEED TO
Pump:

59

PRODUCT FROM
P-100

LOGICAL CONNECTION
Adjust:

ADJ-1

UTILITIES

60
61

( No utilities reference this stream )

62

PROCESS UTILITY

63
64
65
66
67
68
69

Aspen Technology Inc.
Licensed to: LEGENDS

Aspen HYSYS Version 7.2 (24.0.0.7263)

Page 1 of 71
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DMEPLANT.HSC

Unit Set:

NewUser1

Date/Time:

Wed May 23 23:14:35 2012

6

Material Stream: 2

7
8
9

Basis-1

Property Package:

PRSV

CONDITIONS

10
11

Overall

Liquid Phase

12

Vapour / Phase Fraction

13

Temperature:

14

Pressure:

15

Molar Flow

(kgmole/h)

16

Mass Flow

(tonne/d)

0.5765

0.5765

17

Std Ideal Liq Vol Flow

(m3/h)

3.012e-002

3.012e-002

18

Molar Enthalpy

-2.482e+005

19

Molar Entropy

20

Heat Flow

21

Liq Vol Flow @Std Cond

(C)

0.0000

1.0000

25.20

25.20

16.78 *

(atm)

16.78

0.7520

0.7520

(kJ/kgmole)

-2.482e+005

(kJ/kgmole-C)

1.960

1.960

(kJ/h)

-1.867e+005

-1.867e+005

3.009e-002 *

(m3/h)

3.009e-002

22

COMPOSITION

23
24

Overall Phase

25
26

Fluid Package:

COMPONENTS

MOLAR FLOW
(kgmole/h)

27

MOLE FRACTION

MASS FLOW
(kg/h)

Vapour Fraction

0.0000

MASS FRACTION

LIQUID VOLUME
FLOW (m3/h)

LIQUID VOLUME
FRACTION

28

Methanol

0.7370

0.9800

23.6134

0.9831

0.0297

0.9852

29

diM-Ether

0.0008

0.0010

0.0346

0.0014

0.0001

0.0017

30

H2O

0.0113

0.0150

0.2031

0.0085

0.0002

0.0068

31

AcetAldehyde

0.0008

0.0010

0.0331

0.0014

0.0000

0.0014

32

AceticAcid

0.0011

0.0015

0.0685

0.0029

0.0001

0.0022

33

Acetone

0.0011

0.0015

0.0663

0.0028

0.0001

0.0028

34

Total

0.7520

1.0000

24.0190

1.0000

0.0301

1.0000

35

Liquid Phase

36
37

COMPONENTS

MOLAR FLOW
(kgmole/h)

38

MOLE FRACTION

MASS FLOW
(kg/h)

Phase Fraction

1.000

MASS FRACTION

LIQUID VOLUME
FLOW (m3/h)

LIQUID VOLUME
FRACTION

39

Methanol

0.7370

0.9800

23.6134

0.9831

0.0297

0.9852

40

diM-Ether

0.0008

0.0010

0.0346

0.0014

0.0001

0.0017

41

H2O

0.0113

0.0150

0.2031

0.0085

0.0002

0.0068

42

AcetAldehyde

0.0008

0.0010

0.0331

0.0014

0.0000

0.0014

43

AceticAcid

0.0011

0.0015

0.0685

0.0029

0.0001

0.0022

44

Acetone

0.0011

0.0015

0.0663

0.0028

0.0001

0.0028

45

Total

0.7520

1.0000

24.0190

1.0000

0.0301

1.0000

46

K VALUE

47
48

COMPONENTS

MIXED

LIGHT

HEAVY

49

Methanol

0.0000

0.0000

---

50

diM-Ether

0.0000

0.0000

---

51

H2O

0.0000

0.0000

---

52

AcetAldehyde

0.0000

0.0000

---

53

AceticAcid

0.0000

0.0000

---

54

Acetone

0.0000

0.0000

---

55

UNIT OPERATIONS

56
57
58

FEED TO
Valve:

59

PRODUCT FROM
VLV-100

Pump:

LOGICAL CONNECTION
P-100

UTILITIES

60
61

( No utilities reference this stream )

62

PROCESS UTILITY

63
64
65
66
67
68
69

Aspen Technology Inc.
Licensed to: LEGENDS

Aspen HYSYS Version 7.2 (24.0.0.7263)

Page 2 of 71
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DMEPLANT.HSC

Unit Set:

NewUser1

Date/Time:

Wed May 23 23:14:35 2012

6

Material Stream: 3

7
8
9

Basis-1

Property Package:

PRSV

CONDITIONS

10
11

Overall

Liquid Phase

12

Vapour / Phase Fraction

13

Temperature:

14

Pressure:

15

Molar Flow

(kgmole/h)

16

Mass Flow

(tonne/d)

0.5765

0.5765

17

Std Ideal Liq Vol Flow

(m3/h)

3.012e-002

3.012e-002

18

Molar Enthalpy

-2.482e+005

19

Molar Entropy

20

Heat Flow

21

Liq Vol Flow @Std Cond

(C)

0.0000

1.0000

25.23

25.23

15.10 *

(atm)

15.10

0.7520

0.7520

(kJ/kgmole)

-2.482e+005

(kJ/kgmole-C)

1.989

1.989

(kJ/h)

-1.867e+005

-1.867e+005

3.009e-002 *

(m3/h)

3.009e-002

22

COMPOSITION

23
24

Overall Phase

25
26

Fluid Package:

COMPONENTS

MOLAR FLOW
(kgmole/h)

27

MOLE FRACTION

MASS FLOW
(kg/h)

Vapour Fraction

0.0000

MASS FRACTION

LIQUID VOLUME
FLOW (m3/h)

LIQUID VOLUME
FRACTION

28

Methanol

0.7370

0.9800

23.6134

0.9831

0.0297

0.9852

29

diM-Ether

0.0008

0.0010

0.0346

0.0014

0.0001

0.0017

30

H2O

0.0113

0.0150

0.2031

0.0085

0.0002

0.0068

31

AcetAldehyde

0.0008

0.0010

0.0331

0.0014

0.0000

0.0014

32

AceticAcid

0.0011

0.0015

0.0685

0.0029

0.0001

0.0022

33

Acetone

0.0011

0.0015

0.0663

0.0028

0.0001

0.0028

34

Total

0.7520

1.0000

24.0190

1.0000

0.0301

1.0000

35

Liquid Phase

36
37

COMPONENTS

MOLAR FLOW
(kgmole/h)

38

MOLE FRACTION

MASS FLOW
(kg/h)

Phase Fraction

1.000

MASS FRACTION

LIQUID VOLUME
FLOW (m3/h)

LIQUID VOLUME
FRACTION

39

Methanol

0.7370

0.9800

23.6134

0.9831

0.0297

0.9852

40

diM-Ether

0.0008

0.0010

0.0346

0.0014

0.0001

0.0017

41

H2O

0.0113

0.0150

0.2031

0.0085

0.0002

0.0068

42

AcetAldehyde

0.0008

0.0010

0.0331

0.0014

0.0000

0.0014

43

AceticAcid

0.0011

0.0015

0.0685

0.0029

0.0001

0.0022

44

Acetone

0.0011

0.0015

0.0663

0.0028

0.0001

0.0028

45

Total

0.7520

1.0000

24.0190

1.0000

0.0301

1.0000

46

K VALUE

47
48

COMPONENTS

MIXED

LIGHT

HEAVY

49

Methanol

0.0000

0.0000

---

50

diM-Ether

0.0000

0.0000

---

51

H2O

0.0000

0.0000

---

52

AcetAldehyde

0.0000

0.0000

---

53

AceticAcid

0.0000

0.0000

---

54

Acetone

0.0000

0.0000

---

55

UNIT OPERATIONS

56
57
58

FEED TO
Mixer:

59

PRODUCT FROM
V-104

Valve:

LOGICAL CONNECTION
VLV-100

UTILITIES

60
61

( No utilities reference this stream )

62

PROCESS UTILITY

63
64
65
66
67
68
69

Aspen Technology Inc.
Licensed to: LEGENDS

Aspen HYSYS Version 7.2 (24.0.0.7263)

Page 3 of 71
* Specified by user.

0012 32 AceticAcid 0.9816 28.0008 0.0001 0.0693 0.0000 0.0008 0.0013 0.0013 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 39 Methanol 0.0360 1.8997 1.0023 34 Total 0.0127 0.0346 0.0331 0.2998 0.0356 0.0001 0.96 (atm) 1.0000 35 Liquid Phase 36 37 COMPONENTS MOLAR FLOW (kgmole/h) 38 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0008 0.0064 31 AcetAldehyde 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 4 7 8 9 Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall 12 Vapour / Phase Fraction 13 Temperature: 14 Pressure: 15 Liquid Phase 0.0012 0.0000 --- 55 UNIT OPERATIONS 56 57 58 FEED TO Heater: 59 PRODUCT FROM E-100 Mixer: LOGICAL CONNECTION V-104 UTILITIES 60 61 ( No utilities reference this stream ) 62 PROCESS UTILITY 63 64 65 66 67 68 69 Aspen Technology Inc.0008 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 28 Methanol 0.9849 0.8997 0.604e-002 18 Molar Enthalpy -2.0000 0.0. .9849 0.0024 0.0014 30 H2O 0.0011 0.0080 0.6896 17 Std Ideal Liq Vol Flow (m3/h) 3.0008 0.0012 0.0023 45 Total 0.078 (kJ/h) -2.0008 0.080 Molar Flow (kgmole/h) 0.0012 0.080 1.0693 0.0080 0.0013 0.7326 1.0000 1.8832 0.2295 0.0012 0. Licensed to: LEGENDS Aspen HYSYS Version 7.0000 --- 52 AcetAldehyde 0.222e+005 3.0008 0.0142 0.0023 0.0014 41 H2O 0.0356 0.222e+005 -2.0000 0.078 6.0000 0.0000 0.0000 28. MA USA 3 4 5 Case Name: DMEPLANT.0127 0.8997 16 Mass Flow (tonne/d) 0.2998 0.8832 0.7326 1.0012 0.0000 --- 50 diM-Ether 0.601e-002 22 COMPOSITION 23 24 Overall Phase 25 26 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 27 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.7263) Page 4 of 71 * Specified by user.0360 1.0346 0.0000 --- 51 H2O 0.0001 0.0000 (C) 32.96 32.0008 0.0013 0.0000 --- 53 AceticAcid 0.0001 0.0002 0.8997 1.9868 29 diM-Ether 0.0000 0.0000 28.0012 43 AceticAcid 0.0023 0.0331 0.601e-002 * (m3/h) 3.0000 0.0018 44 Acetone 0.0064 42 AcetAldehyde 0.470e+005 19 Molar Entropy 20 Heat Flow 21 Liq Vol Flow @Std Cond (kJ/kgmole) -2.1 2 LEGENDS Burlington.9868 40 diM-Ether 0.0142 0.9816 28.0000 0.0012 0.0001 0.604e-002 3.0663 0.0000 46 K VALUE 47 48 COMPONENTS MIXED LIGHT HEAVY 49 Methanol 0.0018 33 Acetone 0.6896 0.0011 0.0.0002 0.2 (24.0024 0.2295 0.0000 --- 54 Acetone 0.0663 0.0000 0.0001 0.0000 0.470e+005 (kJ/kgmole-C) 6.

9849 0.9868 29 diM-Ether 0.0023 34 Total 0.0000 28.0346 0.0000 0.0013 0.604e-002 3.0 * (atm) 14.9816 28.0001 0.0008 0.0000 28.0663 0.0.0000 46 K VALUE 47 48 COMPONENTS MIXED LIGHT HEAVY 49 Methanol --- --- --- 50 diM-Ether --- --- --- 51 H2O --- --- --- 52 AcetAldehyde --- --- --- 53 AceticAcid --- --- --- 54 Acetone --- --- --- 55 UNIT OPERATIONS 56 57 58 FEED TO Equilibrium Reactor: 59 PRODUCT FROM ERV-100 Heater: LOGICAL CONNECTION E-100 UTILITIES 60 61 ( No utilities reference this stream ) 62 PROCESS UTILITY 63 64 65 66 67 68 69 Aspen Technology Inc.0693 0.2295 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 39 Methanol 0.0001 0.0014 41 H2O 0.7326 1.723e+005 3.0023 45 Total 0.0018 33 Acetone 0.0011 0.0024 0.914e+005 (kJ/kgmole-C) 142.0142 0.0127 0.0013 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 5 7 8 9 Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall Vapour Phase 12 Vapour / Phase Fraction 13 Temperature: 14 Pressure: 15 Molar Flow (kgmole/h) 16 Mass Flow (tonne/d) 0.0000 0.99 * 1.0013 0.8997 1.8832 0.8997 1.9849 0.9868 40 diM-Ether 0.0331 0.0000 0.0024 0.0127 0.0008 0.0356 0.0064 31 AcetAldehyde 0.0012 0.1 2 LEGENDS Burlington.0000 250.0356 0.723e+005 -1.8997 0.0008 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 28 Methanol 0.99 0.0331 0.0663 0.0360 1. Licensed to: LEGENDS Aspen HYSYS Version 7.0008 0.6 142.0012 43 AceticAcid 0.6896 17 Std Ideal Liq Vol Flow (m3/h) 3.601e-002 * (m3/h) 3. .0064 42 AcetAldehyde 0.914e+005 19 Molar Entropy 20 Heat Flow 21 Liq Vol Flow @Std Cond 1.0080 0.0142 0. MA USA 3 4 5 Case Name: DMEPLANT.2295 0.601e-002 22 COMPOSITION 23 24 Overall Phase 25 26 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 27 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 1.9816 28.0000 35 Vapour Phase 36 37 COMPONENTS MOLAR FLOW (kgmole/h) 38 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.7263) Page 5 of 71 * Specified by user.0346 0.0080 0.0000 (C) 250.0008 0.0012 0.0012 0.0008 0.2998 0.0002 0.0012 0.2 (24.6 (kJ/h) -1.0012 0.0008 0.0000 0.0 14.6896 0.0001 0.0012 0.0014 30 H2O 0.0.604e-002 18 Molar Enthalpy -1.0001 0.0018 44 Acetone 0.0002 0.0023 0.0001 0.8997 (kJ/kgmole) -1.0011 0.0360 1.0023 0.0012 32 AceticAcid 0.8832 0.0001 0.2998 0.0013 0.0693 0.7326 1.0008 0.

0017 55 Acetone 0.1706 0.0000 0.0000 1.2369 0. MA USA 3 4 5 Case Name: DMEPLANT.99 14.0000 1.0.9 (atm) 14.0008 0.0000 0.0023 0.2369 0.914e+005 -1.0008 0.0024 0.000 1.6562 52 H2O 0.8554 0.0012 0.8997 0.0024 0.0062 0.0022 34 Total 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 6A 7 8 9 Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall 12 Vapour / Phase Fraction 13 Temperature: 14 Pressure: 15 Vapour Phase Liquid Phase 1.0013 0.000 1.0012 0.0000 28.99 14.0013 0.0000 0.8554 0.000 1.1608 40 diM-Ether 0.0000 0.0012 0.914e+005 19 Molar Entropy 20 Heat Flow 21 Liq Vol Flow @Std Cond (kJ/kgmole-C) 190.0023 0.3659 0.6562 41 H2O 0.000 --- 62 H2O 1.1706 0.0008 0.0000 18 Molar Enthalpy (kJ/kgmole) -1.0000 17 Std Ideal Liq Vol Flow (m3/h) 3.847e-002 * (m3/h) 22 COMPOSITION 23 24 Overall Phase 25 26 Fluid Package: COMPONENTS 27 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 1.0000 28.0000 1.7 190.0011 32 AceticAcid 0.0000 3.0000 0.000 --- 65 Acetone 1.7327 1.0022 56 Total 0.0062 0.1530 0.0000 0.0000 0. .832e-002 0.847e-002 0.0011 0.0013 0.0251 0.0383 1.0001 0.0013 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 39 Methanol 0.0000 46 Liquid Phase 47 48 COMPONENTS 49 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.8997 1.0693 0.000 --- 64 AceticAcid 1.0017 33 Acetone 0.8997 1.0000 35 Vapour Phase 36 37 COMPONENTS 38 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0012 0.1780 53 AcetAldehyde 0.0000 0.0022 45 Total 0.99 Molar Flow (kgmole/h) 0.0000 0.0000 0.7263) Page 6 of 71 * Specified by user. Licensed to: LEGENDS Aspen HYSYS Version 7.8997 0.2 (24.0017 44 Acetone 0.4200 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 28 Methanol 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 50 Methanol 0.000 --- 63 AcetAldehyde 1.1530 0.0000 0.000 --- 66 67 68 69 Aspen Technology Inc.9015 0.0024 0.3659 0.0000 0.0.3779 0.0013 0.0000 0.0000 0.1700 0.9015 0.723e+005 -1.1 2 LEGENDS Burlington.1700 4.1608 51 diM-Ether 0.1608 29 diM-Ether 0.000 1.0011 43 AceticAcid 0.6896 0.0693 0.4200 6.914e+005 -1.0000 0.4066 16.0068 0.0663 0.0331 0.0000 0.7 (kJ/h) -1.000 1.0008 0.1780 31 AcetAldehyde 0.0000 0.0068 0.0000 0.0023 0.5866 0.4066 0.9 365.0001 0.8072 0.0013 0.8072 0.0000 1.4200 6.0000 (C) 365.0008 0.0383 1.0251 0.1780 42 AcetAldehyde 0.0331 0.723e+005 0.0011 54 AceticAcid 0.3779 0.0000 0.0012 0.0000 0.1700 4.832e-002 3.0000 0.4066 16.0000 0.0000 0.0000 16 Mass Flow (tonne/d) 0.0663 0.0000 57 K VALUE 58 59 COMPONENTS MIXED LIGHT HEAVY 60 Methanol 1.9 365.0000 0.5866 0.0000 0.7327 1.0011 0.5866 0.6562 30 H2O 0.000 --- 61 diM-Ether 1.6896 0.2369 0.1706 0.000 1.7 190.0001 0.0001 0.0000 3.

1608 42 diM-Ether 0.0017 57 Acetone 0.0000 (C) 365.0000 0. MA USA 3 4 5 Case Name: DMEPLANT.0013 0.2369 0.1608 53 diM-Ether 0.0000 59 Liquid Phase 60 61 COMPONENTS 62 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0000 0.0013 0.7 190.0000 0.0000 0.0000 0.0000 1.0000 0.0000 0.2369 0.0000 0.0000 0.1700 0.1706 0.0000 0.0000 0.0000 0.0000 0.914e+005 -1.1706 0.0.5866 0.2369 0.0000 0.0000 1.0000 0.0012 0.0000 0.6562 65 H2O 0.0000 0.0000 0.0000 31 Molar Enthalpy (kJ/kgmole) -1.4200 0.0000 0.9 365.0000 0.5866 0.5866 0.0000 0.9 365.0000 0.0000 0.0011 56 AceticAcid 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 52 Methanol 0.1 2 LEGENDS Burlington.0000 0.0011 45 AceticAcid 0.0000 0.0000 * (m3/h) 35 COMPOSITION 36 37 Overall Phase 38 39 Fluid Package: COMPONENTS 40 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0022 47 Total 0.0000 0.0013 0.6562 54 H2O 0.0023 0.0000 1.1700 0.0000 0.0012 0.0017 46 Acetone 0.0000 0.0000 29 Mass Flow (tonne/d) 0.0000 0.0.0000 0.0000 0.7 190.4066 0.0000 0.0000 1.1706 0.1608 64 diM-Ether 0.0011 67 AceticAcid 0.2 (24.0000 48 Vapour Phase 49 50 COMPONENTS 51 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0000 0.0013 0.4200 0.4200 0.4066 0.0000 0.0000 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 6A (continued) 7 8 9 Basis-1 Property Package: PRSV UNIT OPERATIONS 10 11 12 Fluid Package: FEED TO PRODUCT FROM Mixer: MIX-100 Equilibrium Reactor: 13 LOGICAL CONNECTION ERV-100 UTILITIES 14 15 ( No utilities reference this stream ) 16 PROCESS UTILITY 17 18 19 Material Stream: 6B 20 21 22 Basis-1 Property Package: PRSV CONDITIONS 23 24 Overall 25 Vapour / Phase Fraction 26 Temperature: 27 Pressure: 28 Vapour Phase Liquid Phase 0.0000 0.7 (kJ/h) -0.0000 0.0000 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 63 Methanol 0.99 14.914e+005 -1.0023 0.0008 0.0000 0.0013 0.0000 0.0000 0.99 Molar Flow (kgmole/h) 0.0000 30 Std Ideal Liq Vol Flow (m3/h) 0.0000 0.1780 44 AcetAldehyde 0.0022 Page 7 of 71 * Specified by user.0000 69 Aspen Technology Inc.0022 58 Total 0.4066 0.0000 0.0000 1.7263) 0.0000 0.0000 0. .0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 41 Methanol 0.0000 0.0000 0.0000 0.0000 1.0008 0.1700 0.0013 0.0000 0.0000 0.0000 1.0000 0.0024 0.0000 0.0000 0.0000 0.0012 0.0024 0.0000 0.0017 68 Acetone 0.0000 0.0000 0.0000 0.1780 55 AcetAldehyde 0.6562 43 H2O 0.9 (atm) 14.1780 66 AcetAldehyde 0.0008 0.0000 0.0000 0.99 14.0000 0.0000 0.0000 0. Licensed to: LEGENDS Aspen HYSYS Version 7.0000 0.0000 0.0000 0.0000 0.914e+005 32 Molar Entropy 33 Heat Flow 34 Liq Vol Flow @Std Cond (kJ/kgmole-C) 190.0000 0.0023 0.0000 0.0024 0.

000 1.8997 1.0.2369 0.8554 0.1700 4.1608 67 diM-Ether 0.1706 0.7 (kJ/h) -1.6562 57 H2O 0.000 --- 21 AceticAcid 1.000 1.000 0.6896 0.99 Molar Flow (kgmole/h) 0.914e+005 (kJ/kgmole-C) 190.4066 16.847e-002 * (m3/h) 49 3.4200 6.3779 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 55 Methanol 0.0331 0.0013 0.0017 60 Acetone 0. MA USA 3 4 5 Case Name: DMEPLANT.914e+005 46 Molar Entropy 47 Heat Flow 48 Liq Vol Flow @Std Cond (kJ/kgmole) -1.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 66 Methanol 0.0000 62 Vapour Phase 63 64 COMPONENTS 65 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.723e+005 -1.6896 44 Std Ideal Liq Vol Flow (m3/h) 3.0000 (C) 365.0693 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 6B (continued) 7 8 9 Basis-1 Property Package: PRSV COMPOSITION 10 11 Liquid Phase (continued) 12 13 Fluid Package: Total 0.0024 0.5866 0.0663 0.1530 0.9 365.1608 56 diM-Ether 0.000 --- 22 Acetone 1.0001 0.0023 0.4200 6. .000 1.4066 16.1780 58 AcetAldehyde 0.8072 0.000 --- 18 diM-Ether 1.000 --- 19 H2O 1.1700 4.0000 1.0008 0.0012 0.0383 1.0000 14 1.99 14.0022 61 Total 0.0013 0.0011 0.832e-002 3.0000 1.723e+005 3.000 1.000 1.0062 0.8554 0.7263) 0.2 (24.0068 69 Aspen Technology Inc.0000 1.0001 0.847e-002 COMPOSITION 50 51 Overall Phase 52 53 Fluid Package: COMPONENTS 54 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 1.0000 1.9 (atm) 14.8997 0.3779 0.8072 0.5866 0.9015 0.0000 K VALUE 15 16 COMPONENTS MIXED LIGHT HEAVY 17 Methanol 1.1706 0.2369 0.0012 0.0008 0.0000 0.000 1.1780 Page 8 of 71 * Specified by user.1 2 LEGENDS Burlington.0011 59 AceticAcid 0.0000 Phase Fraction 0.7327 1.832e-002 45 Molar Enthalpy -1.1530 0.0062 0.000 --- 23 UNIT OPERATIONS 24 25 26 FEED TO PRODUCT FROM Mixer: MIX-100 Equilibrium Reactor: 27 LOGICAL CONNECTION ERV-100 UTILITIES 28 29 ( No utilities reference this stream ) 30 PROCESS UTILITY 31 32 33 Material Stream: 6 34 35 36 Basis-1 Property Package: PRSV CONDITIONS 37 38 Overall 39 Vapour / Phase Fraction 40 Temperature: 41 Pressure: 42 Vapour Phase 1.0251 0.9015 0. Licensed to: LEGENDS Aspen HYSYS Version 7.0.3659 0.8997 43 Mass Flow (tonne/d) 0.0068 0.0251 0.7 190.0000 28.0000 0.6562 68 H2O 0.000 --- 20 AcetAldehyde 1.3659 0.

90 0.2 (24.0251 0.910e+005 (kJ/kgmole-C) 124.0011 0.628e-003 3.0000 67 68 69 Aspen Technology Inc.0693 0.0001 0.7327 1.1706 0.0024 0.6896 0.0013 0. Licensed to: LEGENDS Aspen HYSYS Version 7.0012 0.0.0011 64 AceticAcid 0.0000 28.832e-002 2.0000 0.0000 0.0022 66 Total 0.964e+004 3.2369 0.956e-002 8.0011 16 AceticAcid 0.2 158.1780 63 AcetAldehyde 0.0012 0.0001 0.0008 0.6562 62 H2O 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 6 (continued) 7 8 9 Basis-1 Property Package: PRSV COMPOSITION 10 11 Vapour Phase (continued) 12 13 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.90 14.0013 0.006e+005 -9.4142 135.0000 28.2 (C) 135.0.758e-003 50 Molar Enthalpy -2.4066 16.4200 6.4976 0.1700 4.0022 18 Total 0.0001 0.1530 0. .0062 0.5858 0.003e+005 -1.8997 1.0008 0.3659 0.8997 1.0331 0.5270 0.3727 0.5866 0.1920 49 Std Ideal Liq Vol Flow (m3/h) 3.5858 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 60 Methanol 0.0000 0.8997 (kJ/kgmole) -2.90 * 14.226e+005 -1.1608 61 diM-Ether 0.1 2 LEGENDS Burlington.0000 0.0331 0.2 * 135.7327 1.0663 0.2 (atm) 14.847e-002 * (m3/h) 54 COMPOSITION 55 56 Overall Phase 57 58 Fluid Package: COMPONENTS 59 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0068 0.0012 0.0008 0.0383 1.9015 0.0013 0.0024 0.0000 19 K VALUE 20 21 COMPONENTS MIXED LIGHT HEAVY 22 Methanol --- --- --- 23 diM-Ether --- --- --- 24 H2O --- --- --- 25 AcetAldehyde --- --- --- 26 AceticAcid --- --- --- 27 Acetone --- --- --- 28 UNIT OPERATIONS 29 30 31 FEED TO PRODUCT FROM Cooler: E-101 Mixer: LOGICAL CONNECTION MIX-100 32 UTILITIES 33 34 ( No utilities reference this stream ) 35 PROCESS UTILITY 36 37 38 Material Stream: 7 39 40 41 Basis-1 Property Package: PRSV CONDITIONS 42 43 Overall Vapour Phase Aqueous Phase 44 Vapour / Phase Fraction 45 Temperature: 46 Pressure: 47 Molar Flow (kgmole/h) 48 Mass Flow (tonne/d) 0.0001 0.0023 0.6 75.3779 0.080e-002 8.0017 65 Acetone 0.66 (kJ/h) -2.0012 0.0017 17 Acetone 0.0008 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 15 AcetAldehyde 0.8072 0.0023 0.0663 0.5858 0. MA USA 3 4 5 Case Name: DMEPLANT.8554 0.7263) Page 9 of 71 * Specified by user.0693 0.673e+005 51 Molar Entropy 52 Heat Flow 53 Liq Vol Flow @Std Cond 0.0013 0.0383 1.0011 0.

0001 0.0000 0.6 125.042e+005 -9.8443 17 H2O 0.86 38 H2O 0.921e+005 (kJ/kgmole-C) 125.0009 0.7317 1.0028 0.0027 0.0157 0.0001 0.97 (kJ/h) -2.0034 0.5858 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 15 Methanol 0.26 10.57 --- 37.6029 0.0058 31 Acetone 0.0212 28 H2O 0.0007 0.0067 0.0946 16 diM-Ether 0.0694 0.0156 0.0322 0.3345 0.7263) Page 10 of 71 * Specified by user.0000 22 Aqueous Phase 23 24 COMPONENTS MOLAR FLOW (kgmole/h) 25 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.1073 0.5270 1.0.0003 0.6891 16.6896 0.0000 0.0005 20 Acetone 0.5885 29 AcetAldehyde 0. Licensed to: LEGENDS Aspen HYSYS Version 7.2065 --- 0.3971 125.0052 0.0012 0.27 --- 24.6029 0.1247 0.57 42 UNIT OPERATIONS 43 44 45 0.6767 0.2287 39 AcetAldehyde 24.0923 0.0000 0.0014 0.0.0564 18 AcetAldehyde 0.27 40 AceticAcid 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 7 (continued) 7 8 9 Basis-1 Property Package: PRSV COMPOSITION 10 11 Vapour Phase 12 13 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0021 0.0002 0.6 10.26 0. MA USA 3 4 5 Case Name: DMEPLANT.2248 0.8 72.0002 32 Total 0.689e+005 65 Molar Entropy 66 Heat Flow 67 Liq Vol Flow @Std Cond (C) (atm) 0.0296 1.1752 1.226e+005 -1.1317 2.0000 0.5878 --- 37 diM-Ether 94.8997 (kJ/kgmole) -2.0002 0.847e-002 * 68 69 Aspen Technology Inc.3573 0.0000 20.0651 0.0009 1.832e-002 3.0031 0.86 --- 94.5068 0.0000 0.0536 0.0017 0.0014 19 AceticAcid 0.0016 0.4142 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 26 Methanol 0.2065 41 Acetone 37.2241 2.1438 0.1 2 LEGENDS Burlington.0250 0.6429 0.179e-003 (m3/h) 3.0088 1.8070 0.6634 0.609e+004 3.0008 0.0024 0.2287 --- 0. .5424 0.300e-003 64 Molar Enthalpy -2.120e-002 8.0009 0.0001 0.0000 0.26 * 10.002e-002 8.2855 0.003e+005 -1.0001 0.9 160.0005 0.0001 0.3841 27 diM-Ether 0.3632 0.3727 1.0011 0.7306 0.0000 0.7661 5.0000 0.5878 FEED TO PRODUCT FROM Valve: VLV-101 LOGICAL CONNECTION Cooler: E-101 46 UTILITIES 47 48 ( No utilities reference this stream ) 49 PROCESS UTILITY 50 51 52 Material Stream: 8 53 54 55 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 56 57 Overall Vapour Phase Aqueous Phase 58 Vapour / Phase Fraction 59 Temperature: 60 Pressure: 61 Molar Flow (kgmole/h) 62 Mass Flow (tonne/d) 0.0073 0.0000 8.0000 33 K VALUE 34 35 COMPONENTS MIXED LIGHT HEAVY 36 Methanol 0.6 125.1827 63 Std Ideal Liq Vol Flow (m3/h) 3.2 (24.0835 0.0802 0.0028 21 Total 0.0001 30 AceticAcid 0.

0030 0.0001 43 Total 0.0001 0.6717 16.0067 0.3291 0.0001 0.21 --- 36.0300 1.0000 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 8 (continued) 7 8 9 Basis-1 Property Package: PRSV COMPOSITION 10 11 Overall Phase 12 13 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.2 (24.0000 0.5058 0.1706 0.7263) Page 11 of 71 * Specified by user.7842 0.0001 0.5866 0.0000 0.0006 0.34 --- 60.0015 0.0000 0.1 2 LEGENDS Burlington.0000 21.1608 16 diM-Ether 0.8072 0.0000 33 Aqueous Phase 34 35 COMPONENTS MOLAR FLOW (kgmole/h) 36 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0331 0.0608 29 AcetAldehyde 0.0514 0.3971 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 37 Methanol 0.0251 0.1780 18 AcetAldehyde 0.0000 0.0003 0.0011 0.9015 0.21 51 AceticAcid 0.1012 0.0000 44 K VALUE 45 46 COMPONENTS MIXED LIGHT HEAVY 47 Methanol 0.1700 4.0000 0.0325 0.4 49 H2O 0.0128 39 H2O 0.0011 0.4 --- 155.0024 0.0.1185 1. .0000 0.0007 0.0009 0.0059 42 Acetone 0.2291 52 Acetone 60.0001 0.0068 0.0000 0.0001 0.3779 0.34 53 UNIT OPERATIONS 54 55 56 0.3643 0.0012 0.1003 27 diM-Ether 0.0011 19 AceticAcid 0.0863 0.0023 0.0050 0.6029 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 26 Methanol 0.0000 7.6298 FEED TO Distillation: 57 PRODUCT FROM T-100 Valve: LOGICAL CONNECTION VLV-101 UTILITIES 58 59 ( No utilities reference this stream ) 60 PROCESS UTILITY 61 62 63 64 65 66 67 68 69 Aspen Technology Inc.0711 0.0013 0.2189 2.0005 0.3659 0.1865 1.0663 0.0001 41 AceticAcid 0.6562 17 H2O 0.1134 0.1378 2.6546 0.0028 32 Total 0.0008 0.6029 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 15 Methanol 0.6298 --- 48 diM-Ether 155.0083 1.2291 --- 0.2409 50 AcetAldehyde 36.0043 0.0001 0.0021 0.8226 0.0014 30 AceticAcid 0.0000 22 Vapour Phase 23 24 COMPONENTS MOLAR FLOW (kgmole/h) 25 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0022 21 Total 0.3957 0.0062 0.1530 0.2369 0.5424 1.0250 0.0007 0.0000 0.0693 0.7948 0.0179 0.2767 0.8997 1.8341 28 H2O 0.0748 0.0017 20 Acetone 0. MA USA 3 4 5 Case Name: DMEPLANT.2409 --- 0.0006 31 Acetone 0.0013 0.0008 0.7743 4.9845 0. Licensed to: LEGENDS Aspen HYSYS Version 7.4066 16.3794 38 diM-Ether 0.0093 0.6141 1.0656 0.0000 28.6017 40 AcetAldehyde 0.0000 0.0018 0.0000 0.0024 0.0000 0.0031 0.0012 0.0.7327 1.0008 0.4200 6.0031 0.0383 1.0782 0.0015 0.0000 0.8554 0.0014 0.3573 1.

Licensed to: LEGENDS Aspen HYSYS Version 7.0022 0.8551 0.0000 0.0019 0.459e+004 2.0009 0.0000 46 K VALUE 47 48 COMPONENTS MIXED LIGHT HEAVY 49 Methanol 0.0025 0.29 45.0000 0.0000 0.0397 0.0253 1.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 39 Methanol 0.0020 0.528e-002 18 Molar Enthalpy -2.0016 31 AcetAldehyde 0.0000 0.0000 (C) 45.0000 33 Acetone 0.0251 0.0000 0.0000 0.0016 42 AcetAldehyde 0.0329 0.0000 40 diM-Ether 0.4073 17 Std Ideal Liq Vol Flow (m3/h) 2.0001 0. .0007 0.29 (kJ/h) -7.7263) Page 12 of 71 * Specified by user.0000 --- 55 UNIT OPERATIONS 56 57 FEED TO 58 PRODUCT FROM Distillation: 59 LOGICAL CONNECTION T-100 Adjust: ADJ-1 UTILITIES 60 61 ( No utilities reference this stream ) 62 PROCESS UTILITY 63 64 65 66 67 68 69 Aspen Technology Inc.3696 0.0017 43 AceticAcid 0.0007 0.1 2 LEGENDS Burlington.0000 29 diM-Ether 0.0416 0.0000 0.0000 --- 53 AceticAcid 0.0000 0.0.9703 1.0000 0.0001 0.0025 0.0000 44 Acetone 0.0000 0.0000 --- 52 AcetAldehyde 0.0009 0.0019 0.2 (24.3696 16 Mass Flow (tonne/d) 0.0.739e-002 22 COMPOSITION 23 24 Overall Phase 25 26 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 27 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0023 0.0000 0.0000 16.9946 30 H2O 0.0000 0.00 Molar Flow (kgmole/h) 0.0000 0.0001 0.459e+004 -7.0017 32 AceticAcid 0.0020 0.29 (atm) 10.3659 0.9703 1.0000 0.9932 0.9900 16.0000 35 Liquid Phase 36 37 COMPONENTS MOLAR FLOW (kgmole/h) 38 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0001 0.4073 0.0001 0.0000 0.9900 16.0023 0.0000 --- 54 Acetone 0.018e+005 (kJ/kgmole-C) 84.0019 0.0329 0.0021 34 Total 0.0000 1.9932 0.0007 0.0000 0.018e+005 19 Molar Entropy 20 Heat Flow 21 Liq Vol Flow @Std Cond (kJ/kgmole) -2.3696 1.0000 0.0000 --- 50 diM-Ether 0.0060 0.0253 1.0000 0.8551 0.0000 0.0000 0.0022 0.9946 41 H2O 0.0000 16.0019 0.528e-002 2.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: DME Product 7 8 9 Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall 12 Vapour / Phase Fraction 13 Temperature: 14 Pressure: 15 Liquid Phase 0.00 10.0000 --- 51 H2O 0.0000 0.0007 0.739e-002 * (m3/h) 2.0060 0.0000 0.0251 0.0021 45 Total 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 28 Methanol 0.3659 0.0000 0.3696 1.0000 0.0397 0.0001 0. MA USA 3 4 5 Case Name: DMEPLANT.0000 0.29 84.0000 0.0416 0.

0000 30 H2O 0.7624 1.4724 29 diM-Ether 0.0000 --- 0.5302 1.0002 0.98 (kJ/h) -1.0247 0.3757 0.0000 11.0 166.5201 31 AcetAldehyde 0.287e-002 * (m3/h) 1.0000 0.26 10.4166 0.0008 0.0051 44 Acetone 0.0024 45 Total 0.0000 0. MA USA 3 4 5 Case Name: DMEPLANT.0000 --- 0.5201 42 AcetAldehyde 0.7085 6.0012 0. Licensed to: LEGENDS Aspen HYSYS Version 7.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 10 7 8 9 Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall 12 Vapour / Phase Fraction 13 Temperature: 14 Pressure: 15 Aqueous Phase 0.5302 1.287e-002 22 COMPOSITION 23 24 Overall Phase 25 26 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 27 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0000 0.7085 6.0000 51 H2O 0.7263) Page 13 of 71 * Specified by user.5302 0.0000 --- 0.0062 0.0.1529 0.0000 0.26 Molar Flow (kgmole/h) 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 39 Methanol 0.0022 0.0068 0.304e-002 18 Molar Enthalpy -2.0024 34 Total 0.0000 0.0059 0.4166 0.0000 32 AceticAcid 0.0000 --- 0.9005 0.9005 0.0000 0.0000 55 UNIT OPERATIONS 56 57 58 FEED TO Valve: 59 PRODUCT FROM VLV-102 Distillation: LOGICAL CONNECTION T-100 UTILITIES 60 61 ( No utilities reference this stream ) 62 PROCESS UTILITY 63 64 65 66 67 68 69 Aspen Technology Inc.0008 0.2 (24.0021 0.0004 0.3757 0.0.386e+005 -1.0000 0.0002 0.0000 0.2885 4.0012 0.0022 0.1529 0.0000 0.5302 16 Mass Flow (tonne/d) 0.7624 1.0059 0.0130 1.0000 0.0000 11.0000 0.0000 0.0000 --- 0.0068 0.2823 0.4724 40 diM-Ether 0.2885 4.0051 33 Acetone 0.0000 50 diM-Ether 0.0000 0.7675 0.0001 0.0000 0.0000 0.5753 0.5753 0.0 (atm) 10.0002 0.2823 17 Std Ideal Liq Vol Flow (m3/h) 1.0000 41 H2O 0.0002 0.7675 0.0693 0.0000 (C) 166.0000 35 Aqueous Phase 36 37 COMPONENTS MOLAR FLOW (kgmole/h) 38 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0000 0.0000 0.0000 0.1 2 LEGENDS Burlington.0693 0.304e-002 1.0000 54 Acetone 0.0000 53 AceticAcid 0.0000 --- 0.0021 0.615e+005 (kJ/kgmole-C) 81.0000 46 K VALUE 47 48 COMPONENTS MIXED LIGHT HEAVY 49 Methanol 0.0062 0.0004 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 28 Methanol 0.0001 0.386e+005 1. .0247 0.0000 43 AceticAcid 0.0000 52 AcetAldehyde 0.0000 1.0130 1.615e+005 19 Molar Entropy 20 Heat Flow 21 Liq Vol Flow @Std Cond (kJ/kgmole) -2.0000 0.98 81.0000 0.

6 --- 132.0000 0.2885 4.0260 0.0000 0.0071 0.0008 1.0023 44 Acetone 0.0000 0.0051 33 Acetone 0.5273 65 Acetone 46.0000 0.4865 0.0002 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 11 7 8 9 Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall 12 Vapour / Phase Fraction 13 Temperature: 14 Pressure: 15 Molar Flow (kgmole/h) 16 Mass Flow 17 Std Ideal Liq Vol Flow 18 Molar Enthalpy 19 Molar Entropy 20 Heat Flow 21 Liq Vol Flow @Std Cond Vapour Phase Aqueous Phase 0.08 158.6958 --- 0.0000 11.2780 4.209e-002 1.287e-002 * (m3/h) 22 COMPOSITION 23 24 Overall Phase 25 26 Fluid Package: COMPONENTS 27 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0000 0.615e+005 -2.0005 0.9 6.7675 0.174e+005 (kJ/kgmole-C) 82.0133 0.0000 0.0502 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 28 Methanol 0.0176 0.0000 35 Vapour Phase 36 37 COMPONENTS 38 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 5.0001 0.9498 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 50 Methanol 0.0052 55 Acetone 0.4854 0.0247 0.03 (kJ/h) -1.7 78.3623 0.5036 (tonne/d) 0.0002 0.868e-004 1.0000 0.0000 0.50 --- 46.2402 0.0000 54 AceticAcid 0.386e+005 -5790 -1.0001 0.0024 34 Total 0.0502 0.0000 11.0000 57 K VALUE 58 59 COMPONENTS MIXED LIGHT HEAVY 60 Methanol 1.9 150.3558 0.0022 0.5753 0.0000 0.0000 0.0000 30 H2O 0.0001 0.0002 0.0000 0.0001 0.0000 0.50 1.9 150.0000 0.6958 63 AcetAldehyde 38.0000 0.225e-002 -2.0061 0.0873 1.0028 0.0019 0.0062 0.0266 1.5036 1.0011 0.0004 0.4046 0.4724 29 diM-Ether 0.4166 0.9498 150.2823 1.0130 1.0000 0.0056 0.0000 0.0.0059 0.0000 32 AceticAcid 0.6630 40 diM-Ether 0.5273 0.7085 6.0007 56 Total 0. Licensed to: LEGENDS Aspen HYSYS Version 7.0003 0.620e-002 0.2 (24.0000 0.6 62 H2O 0.0012 0.5302 1.0008 0. .800e-004 1.0000 0.0000 0.910 0.6149 0.4601 51 diM-Ether 0.5302 2.3059 42 AcetAldehyde 0.0114 0. MA USA 3 4 5 Case Name: DMEPLANT.750 --- 61 diM-Ether 132.5007 0.0002 43 AceticAcid 0.5887 0.1 2 LEGENDS Burlington.638e+005 (C) (atm) (kJ/kgmole) -2.0123 1.0002 0.0006 0.022e-002 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 39 Methanol 0.01 --- 38.663e-002 0.5339 53 AcetAldehyde 0.0674 0.0000 0.1529 0.304e-002 7.0000 0.0022 0.7263) Page 14 of 71 * Specified by user.0000 0.0000 0.0002 0.910 6.0068 0.0012 0.0000 46 Aqueous Phase 47 48 COMPONENTS 49 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.9005 0.0004 41 H2O 0.0002 0.7195 6.0693 0.2661 (m3/h) 1.0021 0.329e+005 7.0283 45 Total 0.0000 0.910 * 6.0000 0.750 66 67 68 69 Aspen Technology Inc.0000 0.3757 0.6751 1.0000 0.0065 0.0000 52 H2O 0.0000 0.0000 0.1400 0.0002 0.0001 0.5201 31 AcetAldehyde 0.5273 --- 0.0000 0.7624 1.0001 0.0.4151 0.01 64 AceticAcid 0.0003 0.0502 0.0130 0.

794e-004 2.987e+005 -2.0000 48 Vapour Phase 49 50 COMPONENTS 51 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 2.0010 0.0009 45 AceticAcid 0.0000 0.0000 0.664e-003 29 Mass Flow (tonne/d) 5.0000 0.218e-006 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 52 Methanol 0.0638 0.0091 0.0023 0.2 (24.0000 57 Acetone 0.76 (kJ/h) -1545 -2.0.0009 0. MA USA 3 4 5 Case Name: DMEPLANT.0007 0.1107 0.0000 0.0001 0.210e-008 5.1960 0.76 135.8783 0.0000 0.0000 0.0000 0.0091 0.0010 0.478e-008 6.0000 0.348e-010 2.0002 0.0018 0.319e+005 -1.1960 0.0000 0.0000 0.664e-003 1.0000 0.0000 68 Acetone 0.0000 0.5 (atm) 6.8533 0.8783 0.1341 0.0003 1.0073 0.5 122.0002 0.0073 66 AcetAldehyde 0.0061 0.5 122.356e-003 1.2232 1.0000 0.0054 0.0000 (C) 122.0004 0.0000 0.1107 0.0000 1.0007 0.0000 0.0000 0.0000 46 Acetone 0.0073 44 AcetAldehyde 0.0000 0.0000 0.0012 43 H2O 0.0000 0.0002 0.0000 0.794e-004 * (m3/h) 35 COMPOSITION 36 37 Overall Phase 38 39 Fluid Package: COMPONENTS 40 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0086 54 H2O 0.0000 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 63 Methanol 0.8791 42 diM-Ether 0. .0000 69 Aspen Technology Inc.0000 0.0000 0.0004 0.0000 0.0002 0.1348 58 Total 0.0000 0.0057 0.9179 0.0.800 6.8518 53 diM-Ether 0.0000 0.1116 47 Total 0.7263) 0.0000 0.0000 0.356e-003 30 Std Ideal Liq Vol Flow (m3/h) 2.1116 Page 15 of 71 * Specified by user.0067 1.0000 0.0000 0.9179 0.4 52.0012 65 H2O 0.0000 0.800 6.0024 56 AceticAcid 0.802e-004 31 Molar Enthalpy (kJ/kgmole) -2.0061 0.0000 0.0000 0.0009 0.0020 0.319e+005 32 Molar Entropy 33 Heat Flow 34 Liq Vol Flow @Std Cond (kJ/kgmole-C) 52.1 2 LEGENDS Burlington.0788 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 11 (continued) 7 8 9 Basis-1 Property Package: PRSV UNIT OPERATIONS 10 11 12 Fluid Package: FEED TO PRODUCT FROM Distillation: T-101 Valve: LOGICAL CONNECTION VLV-102 13 UTILITIES 14 15 ( No utilities reference this stream ) 16 PROCESS UTILITY 17 18 19 Material Stream: 12 20 21 22 Basis-1 Property Package: PRSV CONDITIONS 23 24 Overall 25 Vapour / Phase Fraction 26 Temperature: 27 Pressure: 28 Vapour Phase Liquid Phase 0.0247 0.802e-004 6.0000 0. Licensed to: LEGENDS Aspen HYSYS Version 7.0001 0.0000 0.0247 0.800 Molar Flow (kgmole/h) 6.0169 0.0009 67 AceticAcid 0.0000 0.0000 1.0024 55 AcetAldehyde 0.0030 0.0002 0.0000 1.0000 0.0000 0.0002 0.0007 0.0000 0.0169 0.0000 0.0000 0.0020 0.0007 0.327e-010 2.0000 59 Liquid Phase 60 61 COMPONENTS 62 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0000 1.0000 0.0000 0.937e-003 -1545 6.0000 0.0000 0.0638 0.8791 64 diM-Ether 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 41 Methanol 0.0000 0.9084 0.

2 (24.4077 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 55 Methanol 0.3755 0.0000 0.0128 1.637e+005 46 Molar Entropy 47 Heat Flow 48 Liq Vol Flow @Std Cond (kJ/kgmole) -2.695 2.910 Molar Flow (kgmole/h) 0.0693 0.0000 0.0000 0.0000 57 H2O 0.0067 1.0000 (C) 151.5392 1.2003 0.0001 0.2003 --- 22 Acetone 1. Licensed to: LEGENDS Aspen HYSYS Version 7.0000 0.7654 0.1468 0.910 6.0.0000 59 AceticAcid 0.4634 67 diM-Ether 0.259e-002 49 COMPOSITION 50 51 Overall Phase 52 53 Fluid Package: COMPONENTS 54 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.695 --- 21 AceticAcid 0.05 (kJ/h) -1.1 2 LEGENDS Burlington.2805 4.0000 0.5235 0.0000 0.5863 0.259e-002 * (m3/h) 1.000 1.0059 0.0000 1.0000 11.0000 Phase Fraction 0.7263) 0.0052 60 Acetone 0.0060 0.0000 0.0059 0.5863 0.593 7.2769 0.0000 62 Aqueous Phase 63 64 COMPONENTS 65 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0000 68 H2O 0.0003 1.1468 0.7173 6.7654 0.0000 0.5235 1.0000 0.2232 14 1.0.0000 0.0068 69 Aspen Technology Inc. .0000 0.7173 6.7045 0.380e+005 1.380e+005 -1.2769 44 Std Ideal Liq Vol Flow (m3/h) 1.234 --- 23 UNIT OPERATIONS 24 25 FEED TO PRODUCT FROM 26 LOGICAL CONNECTION Distillation: T-101 27 UTILITIES 28 29 ( No utilities reference this stream ) 30 PROCESS UTILITY 31 32 33 Material Stream: 13 34 35 36 Basis-1 Property Package: PRSV CONDITIONS 37 38 Overall 39 Vapour / Phase Fraction 40 Temperature: 41 Pressure: 42 Aqueous Phase 0.0000 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 66 Methanol 0.2 151.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 12 (continued) 7 8 9 Basis-1 Property Package: PRSV COMPOSITION 10 11 Liquid Phase (continued) 12 13 Fluid Package: Total 0.0000 0.05 78.7045 0.637e+005 (kJ/kgmole-C) 78.3755 0.0000 0.4634 56 diM-Ether 0.3383 0.5235 43 Mass Flow (tonne/d) 0.3383 --- 20 AcetAldehyde 2.0000 0.4077 0.0000 0.9896 --- 18 diM-Ether 7.276e-002 1.9896 0.0000 0.593 --- 19 H2O 0.0000 61 Total 0.0022 0.234 1.2 (atm) 6.276e-002 45 Molar Enthalpy -2.2805 4.5314 58 AcetAldehyde 0.0000 K VALUE 15 16 COMPONENTS MIXED LIGHT HEAVY 17 Methanol 0.0000 0.5314 Page 16 of 71 * Specified by user.0000 0.0012 0. MA USA 3 4 5 Case Name: DMEPLANT.0068 0.0000 0.0000 0.0000 0.

090 * 1.090 1.0000 --- 0.0.0000 23 diM-Ether 0.61 93.7654 0.5863 0.0000 --- 0.5392 1.0000 0.0000 62 H2O 0.0000 16 AceticAcid 0.7173 6.1468 0.0000 --- 0.0693 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 13 (continued) 7 8 9 Basis-1 Property Package: PRSV COMPOSITION 10 11 Aqueous Phase (continued) 12 13 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0052 65 Acetone 0.2769 4.7045 0.7263) Page 17 of 71 * Specified by user.259e-002 * (m3/h) 54 COMPOSITION 55 56 Overall Phase 57 58 Fluid Package: COMPONENTS 59 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0000 64 AceticAcid 0.717e+005 (C) (atm) (kJ/kgmole) -2.0000 24 H2O 0.0693 0.795e+004 -1.0000 --- 0.637e+005 -2.276e-002 2.0000 0.090 0.61 93.0000 0.0000 --- 0.0000 0.0000 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 15 AcetAldehyde 0.0000 0.0068 0.201e+005 2. Licensed to: LEGENDS Aspen HYSYS Version 7.0000 28 UNIT OPERATIONS 29 30 31 FEED TO PRODUCT FROM Valve: VLV-103 LOGICAL CONNECTION Distillation: T-101 32 UTILITIES 33 34 ( No utilities reference this stream ) 35 PROCESS UTILITY 36 37 38 Material Stream: 14 39 40 41 Basis-1 Property Package: PRSV CONDITIONS 42 43 Overall 44 Vapour / Phase Fraction 45 Temperature: 46 Pressure: 47 Molar Flow (kgmole/h) 48 Mass Flow 49 Std Ideal Liq Vol Flow 50 Molar Enthalpy 51 Molar Entropy 52 Heat Flow 53 Liq Vol Flow @Std Cond Vapour Phase Aqueous Phase 0.0000 26 AceticAcid 0.0000 0.0000 0. .88 (kJ/h) -1.5235 8.3755 0.0012 0.0000 25 AcetAldehyde 0.328e-003 1.0060 0.0060 0.0000 0.380e+005 -1.0000 0.0000 0.0052 17 Acetone 0.0001 0.0000 67 68 69 Aspen Technology Inc.2 (24.0000 66 Total 0.4077 0.141e-002 0.4421 (tonne/d) 0.0128 1.0000 0.1555 0.043e-002 -2.205e+005 (kJ/kgmole-C) 79.0000 0.0000 0.0000 0.0059 0.1555 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 60 Methanol 0.0000 18 Total 0.61 1.0000 11.0000 19 K VALUE 20 21 COMPONENTS MIXED LIGHT HEAVY 22 Methanol 0.0000 0.0000 --- 0.40 169.1 62.0000 11.0000 0.5235 1.5392 1.0012 0.0000 0.308e-003 1.0022 0.0128 1.0022 0.0000 0.827e-002 0.0000 0.4634 61 diM-Ether 0.1555 0.2287 (m3/h) 1.0000 27 Acetone 0.0000 0.029e-002 1. MA USA 3 4 5 Case Name: DMEPLANT.0001 0.0000 0.0000 0.5235 1.1 2 LEGENDS Burlington.5314 63 AcetAldehyde 0.8445 93.0000 0.0000 0.0000 0.0000 0.0.2805 4.

0.050e+005 -1.7263) Page 18 of 71 * Specified by user.856e-003 64 Molar Enthalpy -2.0002 0.6638 16 diM-Ether 0.744e-003 * 6.0000 0.0000 0.5279 1.0000 0.0000 21 Total 0.0384 0.0000 0.0104 1.792e+005 (kJ/kgmole-C) 75.3841 0.6 --- 264.0000 0.3647 0.0000 0.0000 9.0010 0.3325 18 AcetAldehyde 0.1084 0.0060 0.4421 1.0008 0.8 (atm) 1. MA USA 3 4 5 Case Name: DMEPLANT.6290 0.3762 62 Mass Flow (tonne/d) 0.0000 0.2297 0.0037 20 Acetone 0.8261 --- 0.2 (24.0000 0.0000 0.0000 0.4187 27 diM-Ether 0.0000 28 H2O 0.62 (kJ/h) -1.9929 0.856e-003 6.0023 1.1555 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 15 Methanol 0.0001 0.0000 0.0000 0.900 1.0091 0.0113 1.0000 0.0000 0.0000 0.2 42 UNIT OPERATIONS 43 44 45 1.0429 0.0015 0.6114 0. Licensed to: LEGENDS Aspen HYSYS Version 7.0045 0.0000 0.0000 0. .3327 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 14 (continued) 7 8 9 Basis-1 Property Package: PRSV COMPOSITION 10 11 Vapour Phase 12 13 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.4714 1.0000 0.7000 39 AcetAldehyde 264.744e-003 68 69 Aspen Technology Inc.0000 0.3762 0.0000 22 Aqueous Phase 23 24 COMPONENTS MOLAR FLOW (kgmole/h) 25 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0000 0.6 40 AceticAcid 0.922 FEED TO PRODUCT FROM Distillation: T-102 Valve: LOGICAL CONNECTION VLV-103 46 UTILITIES 47 48 ( No utilities reference this stream ) 49 PROCESS UTILITY 50 51 52 Material Stream: 15 53 54 55 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 56 57 Overall 58 Vapour / Phase Fraction 59 Temperature: 60 Pressure: 61 Aqueous Phase 0.0000 33 K VALUE 34 35 COMPONENTS MIXED LIGHT HEAVY 36 Methanol 1.0000 (C) 118.0814 1.792e+005 65 Molar Entropy 66 Heat Flow 67 Liq Vol Flow @Std Cond (kJ/kgmole) -2.5758 29 AcetAldehyde 0.0000 0.050e+005 (m3/h) 6.0000 0.900 Molar Flow (kgmole/h) 0.1641 63 Std Ideal Liq Vol Flow (m3/h) 6.8445 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 26 Methanol 0.0000 0.0601 0.0023 0.0000 19 AceticAcid 0.2 --- 502.62 75.0000 0.0000 0.0000 0.0000 0.0000 2.922 --- 37 diM-Ether --- --- --- 38 H2O 0.7725 0.0000 0.0000 32 Total 0.0000 1.1 2 LEGENDS Burlington.0019 0.0000 30 AceticAcid 0.8 118.0063 0.0.1641 0.0000 17 H2O 0.7524 5.0000 0.0000 0.2453 3.4749 0.0000 0.0000 0.8261 41 Acetone 502.0000 0.5267 0.0044 0.7000 --- 0.0055 31 Acetone 0.

0000 0.405e+005 65 Molar Entropy 66 Heat Flow 67 Liq Vol Flow @Std Cond (kJ/kgmole) -2.0000 28 H2O 0.9855 0.7391 0.0000 0.0095 31 Acetone 0.0000 0. .896e-003 * 5.896e-003 68 69 Aspen Technology Inc.0.0000 6.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 26 Methanol 0.8383 1.0000 19 AceticAcid 0.1473 62 Mass Flow (tonne/d) 0.0000 0.1128 63 Std Ideal Liq Vol Flow (m3/h) 5.080 1.0056 16 diM-Ether 0.080 Molar Flow (kgmole/h) 0.0068 0.0000 1.0000 0.0000 0.0000 39 AcetAldehyde --- --- --- 40 AceticAcid 0.0000 22 Aqueous Phase 23 24 COMPONENTS MOLAR FLOW (kgmole/h) 25 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0001 0.0045 0.0000 0.0000 0.0010 0.0000 0.0000 0.9855 0.0000 0.0.0000 0.0000 0.0000 0.0000 (C) 70.0000 0.0069 1.9944 6.8383 1.0056 27 diM-Ether 0.901e-003 5.0000 0.0000 33 K VALUE 34 35 COMPONENTS MIXED LIGHT HEAVY 36 Methanol 0.543e+004 -3.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 15 (continued) 7 8 9 Basis-1 Property Package: PRSV COMPOSITION 10 11 Overall Phase 12 13 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0000 0.7263) Page 19 of 71 * Specified by user.0000 17 H2O 0.0000 --- 37 diM-Ether --- --- --- 38 H2O 0.0030 0.1 2 LEGENDS Burlington.0000 21 Total 0.0000 41 Acetone --- --- --- 42 0.0100 0.0000 0.0000 0.901e-003 64 Molar Enthalpy -2.3762 1.0000 6.9849 29 AcetAldehyde 0.0068 0.2 (24.9849 18 AcetAldehyde 0.22 (kJ/h) -3.0000 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 15 Methanol 0.0000 0.0095 20 Acetone 0.0000 0.0025 0.0000 0.1473 0.0100 0. Licensed to: LEGENDS Aspen HYSYS Version 7.0000 0.0000 0.0000 --- 0.0011 0.0010 0.0000 0.405e+005 (kJ/kgmole-C) 24.0000 0.3741 0.18 70.0045 0.22 24.0000 0.18 (atm) 1.7391 0.0000 --- 0.0069 1.0000 30 AceticAcid 0.0030 0.0000 32 Total 0.0025 0.0307 0.0011 0.0685 0.0000 0. MA USA 3 4 5 Case Name: DMEPLANT.0000 0.0000 0.0685 0.0307 0.0000 UNIT OPERATIONS 43 44 FEED TO PRODUCT FROM 45 Distillation: 46 LOGICAL CONNECTION T-102 UTILITIES 47 48 ( No utilities reference this stream ) 49 PROCESS UTILITY 50 51 52 Material Stream: 16 53 54 55 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 56 57 Overall 58 Vapour / Phase Fraction 59 Temperature: 60 Pressure: 61 Liquid Phase 0.3762 1.0000 0.0000 0.9944 6.543e+004 (m3/h) 5.1128 0.3741 0.0001 0.0000 0.

0000 0.1459 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 16 (continued) 7 8 9 Basis-1 Property Package: PRSV COMPOSITION 10 11 Overall Phase 12 13 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.405e+005 65 Molar Entropy 66 Heat Flow 67 Liq Vol Flow @Std Cond 70.0000 0.552e+004 -3.0263 0.1473 1.1477 * 0.0000 0.0000 0.0000 30 AceticAcid 0.0000 0.0000 0.0000 4.9942 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 15 Methanol 0.0000 0.1477 62 Mass Flow (tonne/d) 0.0000 0.0000 0.0000 21 Total 0.1131 0.0000 0.1473 1.0001 0.22 (kJ/h) -3.0000 22 Liquid Phase 23 24 COMPONENTS MOLAR FLOW (kgmole/h) 25 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0000 4.0000 0.9942 0.0000 --- 38 H2O 0.0000 0.7263) Page 20 of 71 * Specified by user.0000 33 K VALUE 34 35 COMPONENTS MIXED LIGHT HEAVY 36 Methanol 0.917e-003 64 Molar Enthalpy -2.9900 4.0000 0.0000 0.18 (kJ/kgmole) -2.7009 1.0.0000 0.0000 0.0000 17 H2O 0.0000 32 Total 0.0000 0.1131 63 Std Ideal Liq Vol Flow (m3/h) 5.0000 1.080 Molar Flow (kgmole/h) 0.0000 0.0045 29 AcetAldehyde 0.0000 0.9954 27 diM-Ether 0.0099 0.0000 0.0002 0.0000 0.0001 31 Acetone 0.0059 0.0000 --- 42 UNIT OPERATIONS 43 44 45 FEED TO PRODUCT FROM Recycle: RCY-1 Distillation: 46 LOGICAL CONNECTION T-102 UTILITIES 47 48 ( No utilities reference this stream ) 49 PROCESS UTILITY 50 51 52 Material Stream: 17 53 54 55 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 56 57 Overall 58 Vapour / Phase Fraction 59 Temperature: 60 Pressure: 61 Liquid Phase 0.0000 0.0000 0.0000 0.0056 0.1459 0.0015 0.0000 0.9954 16 diM-Ether 0.0059 1.0000 19 AceticAcid 0.0056 0.0000 0.0000 0.0000 0.0015 0.18 * (atm) 1.0263 0.0000 0.7009 1.0001 20 Acetone 0.917e-003 5. MA USA 3 4 5 Case Name: DMEPLANT.0000 0.0007 0.0099 0.6739 0.9900 4.080 * 1.0000 0.2 (24.0000 --- 41 Acetone 0.0000 0.0000 0. Licensed to: LEGENDS Aspen HYSYS Version 7.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 26 Methanol 0.552e+004 (m3/h) 5.0000 0.0000 --- 40 AceticAcid 0.0000 0.0000 0.912e-003 68 69 Aspen Technology Inc.0.0000 0.6739 0.0000 0.0000 (C) 70.0000 0.912e-003 * 5.0059 1.0000 0.0002 0.0000 0.22 24.0059 0.0001 0.0000 28 H2O 0.0000 --- 37 diM-Ether 0.405e+005 (kJ/kgmole-C) 24.0007 0.0000 0.0000 0.0045 18 AcetAldehyde 0.0000 0.1 2 LEGENDS Burlington. .0000 --- 39 AcetAldehyde 0.

1463 0.0000 0.0059 1. .9942 * 0.0045 29 AcetAldehyde 0.1463 * 0.0000 0.6864 0.0045 * 18 AcetAldehyde 0.0000 0.0000 0.0000 * 19 AceticAcid 0.7135 1.0000 * 0.1477 1.0000 * 0.99 kJ/h 59 Property Package: PRSV Duty Calculation Operation: Minimum Available Duty: P-100 --- Maximum Available Duty: --- COMPOSITION 60 61 ( Not a material stream .0000 * 0.0000 4.0000 33 K VALUE 34 35 COMPONENTS MIXED LIGHT HEAVY 36 Methanol 0.0000 * 0.0000 28 H2O 0.0000 0.0000 0.0001 31 Acetone 0.0000 * 0.0000 0.0059 0.0000 * 0.0000 * 0.0000 LIQUID VOLUME FRACTION 15 Methanol 0.0000 --- 41 Acetone 0.0000 * 0.0015 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 26 Methanol 0.0000 0.0001 * 20 Acetone 0.0000 0.0000 0.0000 0.0000 --- 40 AceticAcid 0.0002 0.0000 0.0000 0.0001 * 0.No compositions exist ) 62 UNIT OPERATIONS 63 64 FEED TO Pump: 66 PRODUCT FROM LOGICAL CONNECTION P-100 UTILITIES 67 68 69 Basis-1 CONDITIONS 56 65 Fluid Package: ( No utilities reference this stream ) Aspen Technology Inc.0000 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 17 (continued) 7 8 9 Basis-1 Property Package: PRSV COMPOSITION 10 11 Overall Phase 12 13 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction MASS FRACTION LIQUID VOLUME FLOW (m3/h) 0.0000 0.0264 * 0.0000 * 17 H2O 0.0000 * 21 Total 0.0000 --- 39 AcetAldehyde 0.0007 * 0.0015 * 0.0000 22 Liquid Phase 23 24 COMPONENTS MOLAR FLOW (kgmole/h) 25 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.6864 * 0.9954 * 16 diM-Ether 0. MA USA 3 4 5 Case Name: DMEPLANT.9942 0. Licensed to: LEGENDS Aspen HYSYS Version 7.0.0000 * 0.9900 4.0059 1.0001 0.0000 30 AceticAcid 0.0056 0.0000 0.1 2 LEGENDS Burlington.0000 0.7135 1.0000 * 0.7263) Page 21 of 71 * Specified by user.0000 32 Total 0.2 (24.0000 * 0.0056 * 0.0000 * 0.0000 0.9900 * 4.0000 * 0.0000 0.0000 --- 42 UNIT OPERATIONS 43 44 45 FEED TO Mixer: PRODUCT FROM V-104 Recycle: 46 LOGICAL CONNECTION RCY-1 UTILITIES 47 48 ( No utilities reference this stream ) 49 PROCESS UTILITY 50 51 52 Energy Stream: Q-100 53 54 55 57 Duty Type: 58 Duty SP: Direct Q 64.0000 0.0099 * 0.0099 0.9954 27 diM-Ether 0.0000 0.0000 0.0.0000 0.0264 0.0000 * 0.0000 0.0000 * 0.0000 * 0.0000 * 0.0002 * 0.0007 0.0000 0.0000 4.0000 --- 37 diM-Ether 0.0000 --- 38 H2O 0.0000 0.1477 1.0059 * 0.0000 * 0.

.No compositions exist ) 42 UNIT OPERATIONS 43 44 FEED TO PRODUCT FROM 45 Cooler: LOGICAL CONNECTION E-101 46 UTILITIES 47 48 ( No utilities reference this stream ) 49 PROCESS UTILITY 50 51 52 Energy Stream: T101COND 53 54 55 Basis-1 Property Package: PRSV CONDITIONS 56 57 Duty Type: 58 Duty SP: Direct Q 1.0.802e+004 kJ/h Duty Calculation Operation: E-101 Minimum Available Duty: 39 --- Maximum Available Duty: --- COMPOSITION 40 41 ( Not a material stream .No compositions exist ) 62 UNIT OPERATIONS 63 64 FEED TO 65 PRODUCT FROM Distillation: 66 LOGICAL CONNECTION T-100 UTILITIES 67 68 69 Fluid Package: ( No utilities reference this stream ) Aspen Technology Inc.994e+004 kJ/h Duty Calculation Operation: 19 --- Maximum Available Duty: --- COMPOSITION 20 21 ( Not a material stream .0.7263) Page 22 of 71 * Specified by user. Licensed to: LEGENDS Aspen HYSYS Version 7.948e+004 kJ/h Duty Calculation Operation: Condenser @COL1 Minimum Available Duty: 59 --- Maximum Available Duty: --- COMPOSITION 60 61 ( Not a material stream .1 2 LEGENDS Burlington.No compositions exist ) 22 UNIT OPERATIONS 23 24 25 E-100 Minimum Available Duty: FEED TO Heater: PRODUCT FROM LOGICAL CONNECTION E-100 26 UTILITIES 27 28 ( No utilities reference this stream ) 29 PROCESS UTILITY 30 31 32 Energy Stream: Q-102 33 34 35 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 36 37 Duty Type: 38 Duty SP: Direct Q 2.2 (24. MA USA 3 4 5 Case Name: DMEPLANT.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Energy Stream: Q-100 (continued) 7 8 9 Fluid Package: Basis-1 Property Package: PRSV Fluid Package: Basis-1 Property Package: PRSV PROCESS UTILITY 10 11 12 Energy Stream: Q-101 13 14 15 CONDITIONS 16 17 Duty Type: 18 Duty SP: Direct Q 4.

HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Energy Stream: T101COND (continued) 7 8 9 Fluid Package: Basis-1 Property Package: PRSV Fluid Package: Basis-1 Property Package: PRSV PROCESS UTILITY 10 11 12 Energy Stream: T101REB 13 14 15 CONDITIONS 16 17 Duty Type: 18 Duty SP: Direct Q 6518 kJ/h Duty Calculation Operation: 19 --- Maximum Available Duty: --- COMPOSITION 20 21 ( Not a material stream .1 2 LEGENDS Burlington.2 (24. .No compositions exist ) 22 UNIT OPERATIONS 23 24 25 Reboiler @COL1 Minimum Available Duty: FEED TO Distillation: PRODUCT FROM LOGICAL CONNECTION T-100 26 UTILITIES 27 28 ( No utilities reference this stream ) 29 PROCESS UTILITY 30 31 32 Energy Stream: T102C 33 34 35 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 36 37 Duty Type: 38 Duty SP: Direct Q 2407 kJ/h Duty Calculation Operation: Condenser @COL2 Minimum Available Duty: 39 --- Maximum Available Duty: --- COMPOSITION 40 41 ( Not a material stream .No compositions exist ) 62 UNIT OPERATIONS 63 64 FEED TO Distillation: 66 PRODUCT FROM LOGICAL CONNECTION T-101 UTILITIES 67 68 69 Basis-1 CONDITIONS 56 65 Fluid Package: ( No utilities reference this stream ) Aspen Technology Inc.0. Licensed to: LEGENDS Aspen HYSYS Version 7.0.7263) Page 23 of 71 * Specified by user.No compositions exist ) 42 UNIT OPERATIONS 43 44 FEED TO PRODUCT FROM 45 Distillation: 46 LOGICAL CONNECTION T-101 UTILITIES 47 48 ( No utilities reference this stream ) 49 PROCESS UTILITY 50 51 52 Energy Stream: T102R 53 54 55 57 Duty Type: 58 Duty SP: Direct Q 1460 kJ/h 59 Property Package: PRSV Duty Calculation Operation: Reboiler @COL2 Minimum Available Duty: --- Maximum Available Duty: --- COMPOSITION 60 61 ( Not a material stream . MA USA 3 4 5 Case Name: DMEPLANT.

00 Molar Flow (kgmole/h) 0.0000 (C) 45.29 (kJ/h) -1.8146 63 Std Ideal Liq Vol Flow (m3/h) 5.492e+005 0.0000 -1.No compositions exist ) 42 UNIT OPERATIONS 43 44 45 Fluid Package: FEED TO PRODUCT FROM Distillation: LOGICAL CONNECTION T-102 46 UTILITIES 47 48 ( No utilities reference this stream ) 49 PROCESS UTILITY 50 51 52 Material Stream: Reflux @COL1 53 54 55 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 56 57 Overall 58 Vapour / Phase Fraction 59 Temperature: 60 Pressure: 61 Vapour Phase Liquid Phase 0. MA USA 3 4 5 Case Name: DMEPLANT.29 45.7391 0.8146 0.841e+005 (kJ/kgmole-C) 84.00 10.056e-002 0.00 10.0000 0.8 84.0000 5.7263) Page 24 of 71 * Specified by user.0000 0.0. . Licensed to: LEGENDS Aspen HYSYS Version 7.29 138.2 (24.0000 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Energy Stream: T102R (continued) 7 8 9 Fluid Package: Basis-1 Property Package: PRSV Fluid Package: Basis-1 Property Package: PRSV PROCESS UTILITY 10 11 12 Energy Stream: T103COND 13 14 15 CONDITIONS 16 17 Duty Type: 18 Duty SP: Direct Q 3.594e+004 kJ/h Duty Calculation Operation: Condenser @COL3 Minimum Available Duty: 19 --- Maximum Available Duty: --- COMPOSITION 20 21 ( Not a material stream .355e+004 kJ/h Duty Calculation Operation: Reboiler @COL3 Minimum Available Duty: 39 --- Maximum Available Duty: --- COMPOSITION 40 41 ( Not a material stream .018e+005 65 Molar Entropy 66 Heat Flow 67 Liq Vol Flow @Std Cond (kJ/kgmole) -2.056e-002 64 Molar Enthalpy -2.479e-002 * 68 69 Aspen Technology Inc.0.492e+005 0.29 (atm) 10.7391 62 Mass Flow (tonne/d) 0.018e+005 -1.0000 1.29 45.1 2 LEGENDS Burlington.0000 5.No compositions exist ) 22 UNIT OPERATIONS 23 24 FEED TO PRODUCT FROM 25 LOGICAL CONNECTION Distillation: T-102 26 UTILITIES 27 28 ( No utilities reference this stream ) 29 PROCESS UTILITY 30 31 32 Energy Stream: T103REB 33 34 35 Basis-1 Property Package: PRSV CONDITIONS 36 37 Duty Type: 38 Duty SP: Direct Q 3.479e-002 (m3/h) 5.

502e-002 (kJ/kgmole-C) 114. Method) 56 Reid VP at 37.0.0000 5.479e-002 0.1 2 LEGENDS Burlington. Licensed to: LEGENDS Aspen HYSYS Version 7.1217 1.0060 0.247 (kJ/kgmole) 1.8431 3.656 2.877e-002 0.2 (24.0000 17.0001 0. Mass Density (kg/m3) 671.0000 --- --- 25 Cost Based on Flow (Cost/s) 0.072 1.7317 0.0000 (dyne/cm) 9.1217 (cP) 7.48 30 Std.8 (kJ/kg-C) 2.0000 1. 45 Phase Fraction [Molar Basis] 46 Surface Tension 47 Thermal Conductivity 48 Viscosity 49 Cv (Semi-Ideal) 50 Mass Cv (Semi-Ideal) 51 Cv 52 Mass Cv 53 Cv (Ent.50 0.914e-002 0.5 618.48 0.9932 0.8 (kJ/kg-C) 2.1307 0.8 C (atm) 8.072 1.0503 0. Mass Density (Std.7103 0.0000 67 diM-Ether 0.072 1.321e+006 21 LHV Mass Basis (Std) (kJ/kg) 2.1 76.62 28 Specific Heat (kJ/kgmole-C) 123.Sum(Std.0016 Page 25 of 71 * Specified by user.3 31 Act.500 (kJ/kgmole-C) --- --- --- (kJ/kg-C) --- --- --- --- --- --- 8.0000 0.122 1.5 (m3/h) 5.09 114. Basis] --- --- 1.0000 0.321e+006 1.8 67.0019 0.0000 5.002e-002 2.203 8.8 61.381 --- 9. Cond) 41 Liq.4693 0.0000 --- --- 1.681 1.20 123.327 2.1 Mass Heat Capacity (kJ/kg-C) 2. Cond) (m3/h) 5. Vol.681 20 LHV Vol Basis (Std) (kJ/kgmole) 1.876e+004 22 Phase Fraction [Vol. Liq.297 8. Flow (Std. 39 Kinematic Viscosity 40 Liq.57 14.479e-002 0. MA USA 3 4 5 Case Name: DMEPLANT.62 14.8 C (atm) 57 True VP at 37.0000 26 Act.92 46.7263) 0.836 (kJ/kgmole-C) 123.0000 1.0000 0.1 76.92 (kgmole/m3) 12.643e-005 --- 1.836 3. Method) 55 Cp/Cv (Ent.0000 1.0001 69 Aspen Technology Inc. Density (kgmole/m3) 14. Volume Flow 16 Mass Enthalpy 17 Mass Entropy 18 Heat Capacity 19 Vapour Phase Liquid Phase 45.000 (m3/kgmole) 8. Gas Flow (STD_m3/h) 17. .500 1.479e-002 1. Cond) 42 Liquid Fraction 43 Molar Volume 44 Mass Heat of Vap.643e-005 32 Z Factor 33 Watson K 34 User Property 35 Partial Pressure of H2S 36 Cp/(Cp . Liq.326e+006 1.0794 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: Reflux @COL1 (continued) 7 8 9 Basis-1 Property Package: PRSV PROPERTIES 10 11 Overall 12 Molecular Weight 13 Molar Density 14 Mass Density 15 Act.89 114.38 11.1 29 Std.502e-002 9.9 (m3/h) 5.0044 0.381 (W/m-K) 0.803e-003 7.269 60 COMPOSITION 61 62 Overall Phase 63 64 Fluid Package: COMPONENTS 65 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0000 0. Gas Flow (ACT_m3/h) --- --- --- 27 Avg. Ideal Liq.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 66 Methanol 0.229 8.002e-002 (kJ/kg) 382.000 0. Flow (m3/s) 1.062e-002 11.269 8.000 23 Phase Fraction [Mass Basis] 0.7 --- --- 0.0001 0.475 2.20 123.38 --- --- --- 0.R) 37 Cp/Cv 38 Heat of Vap.50 (kg/m3) 573.3 619.229 58 Liq.000 24 Partial Pressure of CO2 (atm) 0.285 8.0.876e+004 2.914e-002 (kJ/kg) -4396 -4000 -4396 (kJ/kg-C) 1.0001 0.1307 (kg/m3) 619.500 (kJ/kgmole-C) 114. Method) 54 Mass Cv (Ent.02 45.89 573. Flow .5 671. Vol.479e-002 59 Viscosity Index --- -9.9946 68 H2O 0.072 1.0023 0.500 1.0000 0.3 670.0000 5.862 --- (atm) --- 0.015 1.4539 12.38 11.881e+004 2.757e+004 --- --- (cSt) 0.9 20.9900 33.

0000 33.0000 0.0014 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 15 AcetAldehyde 0.0019 0.0019 0.0000 28 Acetone 0.0020 0.0000 30 Liquid Phase 31 32 COMPONENTS MOLAR FLOW (kgmole/h) 33 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.007 --- 46 H2O 0.0005 27 AceticAcid 0.00 Aspen HYSYS Version 7.1034 --- 45 diM-Ether 1.0000 0.0001 0.0001 0.0000 0.0000 0.0000 0. Licensed to: LEGENDS Vapour Phase 1.0000 0.0.0018 0.0021 40 Total 0.0000 1.0000 0.0000 1. . MA USA 3 4 5 Case Name: DMEPLANT.0001 0.0000 0.7263) Page 26 of 71 * Specified by user.0019 0.0015 0.0503 0.65 (atm) 10.0001 0.0000 0.0000 33.0658 0.0025 0.0000 0.0005 26 AcetAldehyde 0.0000 0.0506 1.0000 0.3171 --- 48 AceticAcid 1.0000 1.0000 19 Vapour Phase 20 21 COMPONENTS MOLAR FLOW (kgmole/h) 22 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0000 (C) 46.0832 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 34 Methanol 0.0000 0.0000 39 Acetone 0.0025 0.2940 --- 47 AcetAldehyde 0.0060 0.0000 0.9946 36 H2O 0.0000 0.7103 0.976e-002 --- 49 Acetone 0.0000 0.0000 0.0000 24 diM-Ether 0.9900 33.0000 0.9974 0.0000 0.9932 0.0000 0.0000 0.7317 0.0000 0.0506 1.0000 0.65 46.0001 0.7391 1.0006 0.0017 16 AceticAcid 0.0000 0.0000 0.0016 37 AcetAldehyde 0.1059 0.0000 35 diM-Ether 0.0000 17 Acetone 0.0014 0.0017 38 AceticAcid 0.0007 0.2 (24.1059 --- 50 UNIT OPERATIONS 51 52 53 FEED TO Tray Section: PRODUCT FROM Main TS @COL1 Total Condenser: 54 LOGICAL CONNECTION Condenser @COL1 UTILITIES 55 56 ( No utilities reference this stream ) 57 PROCESS UTILITY 58 59 60 Material Stream: To Condenser @COL1 61 62 63 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 64 65 Overall 66 Vapour / Phase Fraction 67 Temperature: 68 Pressure: 69 Aspen Technology Inc.9984 0.0000 0.0001 0.1 2 LEGENDS Burlington.9406 1.1034 0.0000 0.0000 0.0000 41 K VALUE 42 43 COMPONENTS MIXED LIGHT HEAVY 44 Methanol 0.0002 29 Total 0.0000 1.0001 0.0021 18 Total 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: Reflux @COL1 (continued) 7 8 9 Basis-1 Property Package: PRSV COMPOSITION 10 11 Overall Phase (continued) 12 13 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0003 0.007 1.9988 25 H2O 0.2940 0.0006 0.0019 0.0000 0.00 10.0000 0.0020 0.0000 0.0658 0.0000 0.0001 0.0044 0.0015 0.7391 1.0832 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 23 Methanol 0.0000 0.0000 0.0000 0.0023 0.0000 0.0000 0.0019 0.0.976e-002 1.0794 0.0002 0.3171 0.9406 1.

584e-002 15 Molar Enthalpy -1.0000 0.4747 (kg/m3) 619.889e-002 1.8449 0.218e-002 PROPERTIES 20 21 Overall 22 Molecular Weight 23 Molar Density 24 Mass Density 25 Act.000 1. Liq.000 33 Phase Fraction [Mass Basis] 1.14 Mass Heat Capacity (kJ/kg-C) 1. Method) 64 Mass Cv (Ent.21 26.218e-002 * 19 8.043e+005 (m3/h) 8.321e+006 31 LHV Mass Basis (Std) (kJ/kg) 2.5 619.8449 11.0000 1.246 1.889e-002 (cP) 9.14 76.000 1.218e-002 69 Fluid Package: (atm) 0.757e+004 --- (cSt) 0.Sum(Std.222 14 Std Ideal Liq Vol Flow (m3/h) 7.14 (STD_m3/h) 26. Mass Density 41 Act.82 (kJ/kg-C) 1. Cond) 51 Liq. Method) 66 Reid VP at 37.8 C (atm) 8. Density (kgmole/m3) 14.4747 0.458 2.246 (kJ/kgmole) 1.843e+005 16 Molar Entropy 17 Heat Flow 18 Liq Vol Flow @Std Cond 1.217 (kJ/kg) 382. Method) 65 Cp/Cv (Ent.21 (kg/m3) 671.2 (24.38 11. Vol.218e-002 8.584e-002 7.043e+005 -2.7263) Page 27 of 71 * Specified by user. 55 Phase Fraction [Molar Basis] 56 Surface Tension 57 Thermal Conductivity 58 Viscosity 59 Cv (Semi-Ideal) 60 Mass Cv (Semi-Ideal) 61 Cv 62 Mass Cv 63 Cv (Ent.4 139.0.0000 (m3/kgmole) 2.123 1.477 (kJ/kgmole-C) 61.222 1.036 3.62 14. Liq. 49 Kinematic Viscosity 50 Liq.218e-002 8.0000 Act.92 (kgmole/m3) 0.3 671. Vol.843e+005 (kJ/kgmole-C) 139.13 61.13 (kJ/kg-C) 1.458 (kJ/kg) -4013 -4013 Mass Entropy (kJ/kg-C) 3. Cond) 52 Liquid Fraction 53 Molar Volume 54 Mass Heat of Vap.830e-003 (kJ/kgmole-C) 67.123 1.321e+006 1.218e-002 0.62 (kJ/kgmole-C) 76. Gas Flow 40 Std. Gas Flow (ACT_m3/h) 2.0000 --- (Cost/s) 0.876e+004 32 Phase Fraction [Vol. Flow (Std.82 67.331 1.71 20.658 30 LHV Vol Basis (Std) (kJ/kgmole) 1.4 (kJ/h) -2.109 13 Mass Flow (tonne/d) 1. Basis] 1.8 C (atm) 67 True VP at 37.458 Avg.1 2 LEGENDS Burlington.7 --- 1.109 (kJ/kgmole) -1. Licensed to: LEGENDS 0.036 Heat Capacity (kJ/kgmole-C) 76.477 1. Flow 42 Z Factor 43 Watson K 44 User Property 45 Partial Pressure of H2S 46 Cp/(Cp .HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: To Condenser @COL1 (cont 7 8 9 Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall Vapour Phase 12 Molar Flow (kgmole/h) 1.000 34 Partial Pressure of CO2 35 Cost Based on Flow 36 37 38 Specific Heat 39 Std.269 Aspen HYSYS Version 7. .229 68 Liq.71 (m3/h) 2. Ideal Liq.5 (m3/h) 8.876e+004 2.R) 47 Cp/Cv 48 Heat of Vap.4510 0.4510 (kg/m3) 20.658 1.92 45.0000 0. Volume Flow 26 Mass Enthalpy 27 28 29 Vapour Phase 45. Flow . MA USA 3 4 5 Case Name: DMEPLANT.229 8. Cond) (m3/h) 8.269 8.331 (kJ/kgmole-C) --- --- (kJ/kg-C) --- --- Aspen Technology Inc.3 (m3/s) --- --- 0.217 2.38 --- --- (atm) --- 1.0.14 76.458 2. Mass Density (Std.830e-003 9.0000 --- --- 8.0000 (dyne/cm) --- --- (W/m-K) 1.

0000 0.0019 0.0000 0.5654 0.1087 1.0000 50.0754 0.1 2 LEGENDS Burlington.0060 0.1102 0.0021 25 Total 1.0001 0.0025 0.362e-003 5.0.5654 0.9900 50.0001 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 19 Methanol 0.0022 0.0023 0.0001 0.9109 1.0000 24 Acetone 0.0060 0.0754 0.0016 33 AcetAldehyde 0.0000 1.0021 0.0001 0.1248 0.0016 22 AcetAldehyde 0.0000 35 Acetone 0.0066 0.7263) Page 28 of 71 * Specified by user.0002 0.0000 0.0028 0.0022 0.0758 1.0019 0.0020 0.0000 (C) 166.0000 26 Vapour Phase 27 28 COMPONENTS MOLAR FLOW (kgmole/h) 29 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.1102 67 Std Ideal Liq Vol Flow (m3/h) 5.0987 0.0017 34 AceticAcid 0.1087 1.362e-003 68 Molar Enthalpy (kJ/kgmole) -2.0021 0.1191 0.607 13 COMPOSITION 14 15 Overall Phase 16 17 Basis-1 PROPERTIES 10 12 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 18 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 1.9900 50.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: To Condenser @COL1 (cont 7 8 9 11 Overall Viscosity Index Property Package: PRSV Vapour Phase -9. Licensed to: LEGENDS Aspen HYSYS Version 7.0758 1.607 -9.0000 37 K VALUE 38 39 COMPONENTS MIXED LIGHT HEAVY 40 Methanol --- --- --- 41 diM-Ether --- --- --- 42 H2O --- --- --- 43 AcetAldehyde --- --- --- 44 AceticAcid --- --- --- 45 Acetone --- --- --- 46 UNIT OPERATIONS 47 48 49 FEED TO Total Condenser: PRODUCT FROM Condenser @COL1 Tray Section: 50 LOGICAL CONNECTION Main TS @COL1 UTILITIES 51 52 ( No utilities reference this stream ) 53 PROCESS UTILITY 54 55 56 Material Stream: Boilup @COL1 57 58 59 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 60 61 Overall 62 Vapour / Phase Fraction 63 Temperature: 64 Pressure: 65 Vapour Phase 1.0021 36 Total 1.9946 32 H2O 0.169e+005 69 Aspen Technology Inc.0019 0.0.0000 0.9946 21 H2O 0.0001 0.0000 20 diM-Ether 1.0000 31 diM-Ether 1.0976 0.0028 0. .0000 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 30 Methanol 0.0000 0.0019 0.1785 66 Mass Flow (tonne/d) 0.169e+005 -2.1191 0.0017 23 AceticAcid 0.0025 0.0023 0.0000 0.9932 0.0 166.0001 0.0000 0.0066 0.9932 0.0000 50.0001 0.0002 0.0001 0.0001 0.0987 0. MA USA 3 4 5 Case Name: DMEPLANT.9109 1.0000 0.1248 0.0020 0.0000 0.0976 0.0000 0.0001 0.26 10.1785 0.0 (atm) 10.0000 0.0000 0.0000 0.2 (24.26 Molar Flow (kgmole/h) 0.

0.313e-003 0.08 42.5737 0. Flow .2819 66 67 68 69 Aspen Technology Inc.302 1.000 1.0.220 (kg/m3) 855. Flow 38 Z Factor 39 Watson K 40 User Property 41 Partial Pressure of H2S 42 Cp/(Cp . Method) 61 Cp/Cv (Ent.220 4. Ideal Liq.1 2 LEGENDS Burlington.344e+004 1.62 10. . Vol.000 29 Phase Fraction [Mass Basis] 1.099 6.2 (24.5737 Avg.0000 1.501 1.2819 0.28 (kJ/kgmole-C) 50.R) 43 Cp/Cv 44 Heat of Vap.9 156.5725 64 Liq.344e+004 28 Phase Fraction [Vol.0000 Act. Gas Flow 36 Std.041e-002 1.08 (kJ/kg-C) 1.801e-002 2. Cond) (m3/h) 5.313e-003 65 Viscosity Index 6.001 21 Act.313e-003 5. Flow (Std.871e+004 -3.3111 (atm) 0.871e+004 (m3/h) 5.9 (m3/s) --- --- 0.650 25.9 855.000 30 Partial Pressure of CO2 31 Cost Based on Flow 32 33 34 Specific Heat 35 Std.9 (kJ/h) -3.313e-003 5.801e-002 (cP) 1.960 26 LHV Vol Basis (Std) (kJ/kgmole) 3. Basis] 1.5737 22 Mass Enthalpy (kJ/kg) -8434 -8434 23 Mass Entropy (kJ/kg-C) 6.40 25 Mass Heat Capacity (kJ/kg-C) 1.40 50. Method) 62 Reid VP at 37.9152 0. 45 Kinematic Viscosity 46 Liq.515e+004 --- (cSt) 1.5725 0. Liq.001 8.8 C (atm) 63 True VP at 37. Gas Flow (ACT_m3/h) 0.72 0. Cond) 47 Liq. Cond) 48 Liquid Fraction 49 Molar Volume 50 Mass Heat of Vap. Liq. Mass Density 37 Act.302 (kg/m3) 863.9 863.501 (kJ/kgmole-C) --- --- (kJ/kg-C) --- --- --- --- 0.214 3. Method) 60 Mass Cv (Ent.313e-003 PROPERTIES 16 17 Overall Vapour Phase 18 Molecular Weight 19 Molar Density (kgmole/m3) 20 Mass Density (kg/m3) 8. Licensed to: LEGENDS Aspen HYSYS Version 7.9152 10.455e+005 27 LHV Mass Basis (Std) (kJ/kg) 1. MA USA 3 4 5 Case Name: DMEPLANT.306 1.3111 0.198 1.0000 --- 1.Sum(Std.0000 (dyne/cm) --- --- (W/m-K) 2.72 25.636 (kJ/kgmole-C) 38.041e-002 (kJ/kgmole-C) 42.214 (kJ/kg) 1367 --- 1.40 50.198 1.60 38.960 1.455e+005 3.0000 (m3/kgmole) 3.099 24 Heat Capacity (kJ/kgmole-C) 50.0000 --- (Cost/s) 0. Volume Flow (m3/h) 0.40 (STD_m3/h) 4. Vol.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: Boilup @COL1 (continued) 7 8 9 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall 12 Molar Entropy 13 Heat Flow 14 Liq Vol Flow @Std Cond Vapour Phase (kJ/kgmole-C) 156.306 (kJ/kgmole) 3.000 1.636 1.8 C (atm) 0.60 (kJ/kg-C) 1. Mass Density (Std.5737 0.0000 0.62 --- --- (atm) 0.9 (m3/h) 5.7263) Page 29 of 71 * Specified by user. Density (kgmole/m3) 33. 51 Phase Fraction [Molar Basis] 52 Surface Tension 53 Thermal Conductivity 54 Viscosity 55 Cv (Semi-Ideal) 56 Mass Cv (Semi-Ideal) 57 Cv 58 Mass Cv 59 Cv (Ent.313e-003 * 15 5.0000 0.650 6.28 33.

0000 33 K VALUE 34 35 COMPONENTS MIXED LIGHT HEAVY 36 Methanol --- --- --- 37 diM-Ether --- --- --- 38 H2O --- --- --- 39 AcetAldehyde --- --- --- 40 AceticAcid --- --- --- 41 Acetone --- --- --- 42 UNIT OPERATIONS 43 44 45 FEED TO Tray Section: PRODUCT FROM Main TS @COL1 Reboiler: 46 LOGICAL CONNECTION Reboiler @COL1 UTILITIES 47 48 ( No utilities reference this stream ) 49 PROCESS UTILITY 50 51 52 Material Stream: To Reboiler @COL1 53 54 55 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 56 57 Overall 58 Vapour / Phase Fraction 59 Temperature: 60 Pressure: 61 Vapour Phase Liquid Phase 0.26 10.26 10.2977 18 AcetAldehyde 0.0224 0.839e+005 0.0004 0.0000 0.0025 0.0035 0.4801 2.0000 0.839e+005 0.5896 1.0857 0.0548 32 Total 0.0000 0.0004 0.4801 2.26 Molar Flow (kgmole/h) 0.7455 0.0040 0.0054 1.0224 0.5931 0.0016 0.0016 17 H2O 0.8 158.0000 4. .0000 0.135e+005 (kJ/kgmole-C) 79.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: Boilup @COL1 (continued) 7 8 9 Basis-1 Property Package: PRSV COMPOSITION 10 11 Overall Phase 12 13 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 1.0020 20 Acetone 0.0000 0.7455 0.0016 0.818e-002 (m3/h) 1.0007 0.0004 30 AceticAcid 0.0000 0.0000 1.0000 -1.3471 0.0000 4.2323 0.5931 0.5982 0.0017 0.0857 0.0004 19 AceticAcid 0.818e-002 * 68 69 Aspen Technology Inc.0003 0.0012 0.2 (24.7086 62 Mass Flow (tonne/d) 0.8 158.0003 0.0506 0.840e-002 0.7263) Page 30 of 71 * Specified by user.0002 0.6435 27 diM-Ether 0.0000 (C) 158.77 (kJ/h) -1.6435 16 diM-Ether 0.0000 0.0000 0.1 2 LEGENDS Burlington.0000 0.0884 0.0025 0.7086 0.0548 21 Total 0.0000 1.2323 0.0012 0.0884 0.0007 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 15 Methanol 0.0115 0.0017 0.0000 22 Vapour Phase 23 24 COMPONENTS MOLAR FLOW (kgmole/h) 25 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0000 0.0002 0.0000 1.840e-002 64 Molar Enthalpy -2.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 26 Methanol 0.0.0011 0.0002 0.0020 31 Acetone 0.0040 0.1785 1.0000 0.77 155.3924 0.0011 0.1 79. MA USA 3 4 5 Case Name: DMEPLANT.0115 0.2977 29 AcetAldehyde 0.0000 0.4955 1.8 (atm) 10.5982 0.0054 1.3924 63 Std Ideal Liq Vol Flow (m3/h) 1.595e+005 65 Molar Entropy 66 Heat Flow 67 Liq Vol Flow @Std Cond (kJ/kgmole) -2.5896 1.0506 0.0001 0.0035 0.0002 0.1785 1.0001 0.0.0000 0.595e+005 -2. Licensed to: LEGENDS Aspen HYSYS Version 7.4955 1.0016 28 H2O 0.3471 0.0057 0.0057 0.

995e-006 32 Z Factor 33 Watson K 34 User Property 35 Partial Pressure of H2S 36 Cp/(Cp .96 (W/m-K) 0.1 2 LEGENDS Burlington.477 1.919 5.000 23 Phase Fraction [Mass Basis] 1. Gas Flow (ACT_m3/h) --- --- --- 27 Avg.1268 (kg/m3) 899.0004 0. Flow .83 23. Method) 55 Cp/Cv (Ent.124e+004 (kJ/kg-C) 3.1268 1.457 (kJ/kgmole-C) 122.7 9. Ideal Liq.604e-002 1. .3 44.477 (kJ/kgmole-C) --- --- --- (kJ/kg-C) --- --- --- --- --- --- 0.2483 0.640 4.5113 0. Gas Flow (STD_m3/h) 16.76 30 Std.3 (kJ/kg-C) 4.24 122.4162 (cP) 9.818e-002 0.3 Mass Heat Capacity (kJ/kg-C) 5.88 38. Liq.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 66 Methanol 0.0.0000 0. 39 Kinematic Viscosity 40 Liq.941 1. Vol.816e-003 10.6 (m3/h) 1.0000 1.180e+005 2.0000 1.0000 1.9046 8.0.302 20 LHV Vol Basis (Std) (kJ/kgmole) 2.0000 --- --- 1.76 0.6017 0.83 (kg/m3) 757.0000 0.24 122.7 831.046e-002 3. 45 Phase Fraction [Molar Basis] 46 Surface Tension 47 Thermal Conductivity 48 Viscosity 49 Cv (Semi-Ideal) 50 Mass Cv (Semi-Ideal) 51 Cv 52 Mass Cv 53 Cv (Ent.3 57.0000 (atm) --- 0.3605 0.170 1.7 (m3/h) 2.125 3.0000 0.0059 0. MA USA 3 4 5 Case Name: DMEPLANT.158e-002 0.07 29.60 10.2386 0. Volume Flow 16 Mass Enthalpy 17 Mass Entropy 18 Heat Capacity 19 Vapour Phase Liquid Phase 23. Cond) 42 Liquid Fraction 43 Molar Volume 44 Mass Heat of Vap.818e-002 0.457 5.5 899.0 (kJ/kg-C) 4.2 (24.604e-002 (kJ/kgmole-C) 114.612e+004 --- --- (cSt) 0. Mass Density (kg/m3) 888.2483 (atm) 0.000 24 Partial Pressure of CO2 25 Cost Based on Flow 26 Act.3 29 Std. Cond) 41 Liq.51 27.0000 1.4553 Page 31 of 71 * Specified by user.6549 8.6 840.64 10.0 48. Liq.8 C (atm) 57 True VP at 37.6 888.7 31 Act.51 28 Specific Heat (kJ/kgmole-C) 122.8487 0. Flow (m3/s) 5.0001 0.069 0.3367 7.276 (kJ/kgmole) 3.86 103.6460 0.200 3.995e-006 --- 5.0000 0. Licensed to: LEGENDS Aspen HYSYS Version 7.4162 2.0096 0. Flow (Std.0000 0.073 1.4676 0.000 (m3/kgmole) 3.020e-002 9.124e+004 -7158 -1.0000 --- --- (Cost/s) 0.184 1.941 (kJ/kgmole-C) 103.R) 37 Cp/Cv 38 Heat of Vap.504 4.818e-002 1. Method) 56 Reid VP at 37.0000 (dyne/cm) 33.0000 2.07 (kgmole/m3) 32.6017 Liq.818e-002 --- --- --- 60 COMPOSITION 61 62 Overall Phase 63 64 Basis-1 COMPONENTS 65 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.270e+005 21 LHV Mass Basis (Std) (kJ/kg) 9839 1.302 1.3 57.184 1.0000 16.4641 0.60 --- --- --- 0. Mass Density (Std.5222 67 diM-Ether 0.0084 69 Aspen Technology Inc.5353 0.Sum(Std.736e+004 9839 22 Phase Fraction [Vol.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Fluid Package: Material Stream: To Reboiler @COL1 (continu Property Package: 7 8 9 PRSV PROPERTIES 10 11 Overall 12 Molecular Weight 13 Molar Density 14 Mass Density 15 Act. Density (kgmole/m3) 38.546 757.96 --- 33.073 1. Cond) (m3/h) 1.3200 32.0000 (atm) 0.83 0. Basis] --- --- 1.0002 0.668e-002 0. Vol.93 114.0005 68 H2O 0.270e+005 5.8 C 58 59 Viscosity Index 0.7263) 0.158e-002 (kJ/kg) -1. Method) 54 Mass Cv (Ent.000 0.046e-002 (kJ/kg) 1565 --- --- 0.

77 --- 50 UNIT OPERATIONS 51 52 53 FEED TO Reboiler: PRODUCT FROM Reboiler @COL1 Tray Section: 54 LOGICAL CONNECTION Main TS @COL1 UTILITIES 55 56 ( No utilities reference this stream ) 57 PROCESS UTILITY 58 59 60 Material Stream: 10 @COL1 61 62 63 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 64 65 Overall 66 Vapour / Phase Fraction 67 Temperature: 68 Pressure: 69 Aspen Technology Inc.2570 0.47 57.0001 16 AceticAcid 0.0062 0.0019 0.2343 0.0000 0.0001 0.0096 0.0013 0.0000 0.0017 27 AceticAcid 0.0.0013 0.0000 0.0184 1.0000 0.1952 26 AcetAldehyde 0.0001 0.0004 0.3605 0.0012 28 Acetone 0.0000 0.0 166.0000 0.0001 0.0000 19 Vapour Phase 20 21 COMPONENTS MOLAR FLOW (kgmole/h) 22 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0049 0.1172 0.0157 0. Licensed to: LEGENDS Vapour Phase Liquid Phase 0.0000 0.0001 0.0000 41 K VALUE 42 43 COMPONENTS MIXED LIGHT HEAVY 44 Methanol 1.0000 0.5184 0. MA USA 3 4 5 Case Name: DMEPLANT.0000 0.0001 0.433 --- 45 diM-Ether 57.0000 0.0177 40 Total 0.0001 38 AceticAcid 0.7086 1.0000 0.0001 0.5924 --- 47 AcetAldehyde 18.0199 25 H2O 0.26 Aspen HYSYS Version 7.2282 0.0044 0.0184 1.0000 0.4676 0.0042 39 Acetone 0.5113 0.0000 16.0044 0.2 (24.2570 0.0000 0.0 166.5418 24 diM-Ether 0.4108 0.0000 0.0049 0.26 10.0000 1.0000 0.0000 0.0000 0.29 18.0807 0.1 2 LEGENDS Burlington.0000 0.0000 1.4641 0.0019 0.6549 8.0000 30 Liquid Phase 31 32 COMPONENTS MOLAR FLOW (kgmole/h) 33 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.26 10.0000 0.0000 0.0157 0.0011 0.0104 0.0002 0.0001 0.7086 1. .0000 0.3520 1.0005 36 H2O 0.0016 0.0003 0.0177 18 Total 0.0160 0.6460 0.4108 --- 49 Acetone 18.3520 1.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 34 Methanol 0.0000 0.0000 16.47 --- 46 H2O 0.5924 0.4553 37 AcetAldehyde 0.77 18.0000 0.2402 29 Total 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 15 AcetAldehyde 0.0019 0.0000 0.0062 0.0008 0.433 1.0016 0.0.5222 35 diM-Ether 0.0000 0.29 --- 48 AceticAcid 0.0000 1.0059 0.4826 0.0000 1.7263) Page 32 of 71 * Specified by user.0 (atm) 10.0042 17 Acetone 0.0000 0.0000 (C) 166.0019 0.3879 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 23 Methanol 0.3367 7.0084 0.0000 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Fluid Package: Material Stream: To Reboiler @COL1 (continu Property Package: 7 8 9 PRSV COMPOSITION 10 11 Overall Phase (continued) 12 13 Basis-1 COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0807 0.0003 0.0000 0.2386 0.

304e-002 15 Molar Enthalpy -2.041e-002 8.314 1.0.19 (kgmole/m3) 34.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 10 @COL1 (continued) 7 8 9 Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall Vapour Phase Liquid Phase 12 Molar Flow (kgmole/h) 0.0000 0.5725 0.59 --- --- --- 0.9 913.234e-003 10.6 42. Vol.9 (m3/h) 1.076 1.615e+005 -2.0000 --- --- (Cost/s) 0.0000 0.314 30 LHV Vol Basis (Std) (kJ/kgmole) 1.9 39 Std.287e-002 Aspen Technology Inc.98 156.4485 (cP) 8.076 1. Basis] --- --- 1.0000 13 Mass Flow (tonne/d) 0.287e-002 1.7263) Page 33 of 71 * Specified by user.61 (W/m-K) 0.0000 0.222e-002 1.2 855.214 2.287e-002 (m3/h) 1.R) 47 Cp/Cv 48 Heat of Vap.6 (kJ/kg-C) 4.2 41 Act.98 (kJ/h) -1.259e-006 --- 4.2267 (atm) 0. Cond) 51 Liq.169e+005 (kJ/kgmole-C) 81.076 1. Gas Flow (ACT_m3/h) --- --- --- 37 Avg.54 40 Std. Liq.72 22.302 0.9 50.501 4.0000 1.67 38 Specific Heat (kJ/kgmole-C) 117.0000 1.939 (kJ/kgmole-C) --- --- --- (kJ/kg-C) --- --- --- --- --- --- 0.871e+005 31 LHV Mass Basis (Std) (kJ/kg) 8435 1.0000 1.636 4. Licensed to: LEGENDS Aspen HYSYS Version 7.9 863.892e-002 (kJ/kg) 1621 --- --- 0.59 10.2823 14 Std Ideal Liq Vol Flow (m3/h) 1.871e+005 3.0000 0.001 767.0000 (dyne/cm) 34.222e-002 (kJ/kgmole-C) 109. Flow (m3/s) 4. Method) 64 Mass Cv (Ent.9 81.533e-002 0.28 40.533e-002 (kJ/kg) -1.076 1.8 C 68 69 Fluid Package: 0.1 2 LEGENDS Burlington.287e-002 * 19 PROPERTIES 20 21 Overall 22 Molecular Weight 23 Molar Density 24 Mass Density 25 Act.58 0.0000 (atm) --- 0.344e+004 8435 32 Phase Fraction [Vol.8 C (atm) 67 True VP at 37.2 (24.9 902.2823 0.2819 0.1072 (kg/m3) 913.4485 2.000 33 Phase Fraction [Mass Basis] 1. Cond) 52 Liquid Fraction 53 Molar Volume 54 Mass Heat of Vap.08 109.58 (kg/m3) 767. Mass Density (kg/m3) 902.615e+005 16 Molar Entropy 17 Heat Flow 18 Liq Vol Flow @Std Cond 0.695 (kJ/kgmole-C) 117.5302 0. . 49 Kinematic Viscosity 50 Liq.6 (kJ/kg-C) 4.0000 12. Flow (Std.0000 1.4555 Liq.0000 1. Method) 65 Cp/Cv (Ent.0000 1.596e+004 --- --- (cSt) 0.939 1.939 (kJ/kgmole-C) 109.19 25. Mass Density (Std. Cond) (m3/h) 1.939 1.40 117.Sum(Std.0000 -1.60 109.801e-002 0. MA USA 3 4 5 Case Name: DMEPLANT.0000 1.287e-002 0.455e+005 1.0000 (atm) 0.2 8.000 0. Method) 66 Reid VP at 37.2 (m3/h) 1.3111 34.5302 (kJ/kgmole) -2.9 50.62 10.9152 8. Vol. Liq.000 (m3/kgmole) 2.0000 0.2267 0.54 0.198 1.892e-002 3. 55 Phase Fraction [Molar Basis] 56 Surface Tension 57 Thermal Conductivity 58 Viscosity 59 Cv (Semi-Ideal) 60 Mass Cv (Semi-Ideal) 61 Cv 62 Mass Cv 63 Cv (Ent.099 3.67 33.179e+004 (kJ/kg-C) 3. Flow .61 --- 34.000 34 Partial Pressure of CO2 35 Cost Based on Flow 36 Act.40 117.287e-002 0.306 (kJ/kgmole) 3.695 6.1072 1.304e-002 0.386e+005 0.179e+004 -8434 -1. Volume Flow 26 Mass Enthalpy 27 Mass Entropy 28 Heat Capacity 29 Vapour Phase Liquid Phase 22. Gas Flow (STD_m3/h) 12.6 38.0000 --- --- 1.960 5.386e+005 0. Ideal Liq.9 Mass Heat Capacity (kJ/kg-C) 5. Density (kgmole/m3) 40.0.4555 0.259e-006 42 Z Factor 43 Watson K 44 User Property 45 Partial Pressure of H2S 46 Cp/(Cp .

0000 23 AceticAcid 0.0130 1.0000 0.1529 0.0020 35 Acetone 0.4724 20 diM-Ether 0.0068 0.0008 0.4166 0.2885 4.0000 0.4928 0.0000 0.0000 45 AceticAcid 0.0000 0.0051 24 Acetone 0.0016 32 H2O 0.0000 0.0059 0.5982 0.93 --- 57 UNIT OPERATIONS 58 59 60 FEED TO Material Stream: 61 PRODUCT FROM 10 Reboiler: LOGICAL CONNECTION Reboiler @COL1 UTILITIES 62 63 ( No utilities reference this stream ) 64 PROCESS UTILITY 65 66 67 68 69 Aspen Technology Inc.3471 0.0002 0.0000 43 H2O 0. Licensed to: LEGENDS Aspen HYSYS Version 7.0000 0.0012 0.0000 0.0000 11.0012 0.0000 0.0002 0.0000 0.2977 33 AcetAldehyde 0.5201 44 AcetAldehyde 0.0000 0.0068 0.0693 0.0021 0.7624 1.6993 0.7675 0.0011 0.0000 0.99 24.0002 0.0000 0.0062 0.5201 22 AcetAldehyde 0.0004 34 AceticAcid 0.0548 36 Total 0.0001 0.0000 26 Vapour Phase 27 28 COMPONENTS MOLAR FLOW (kgmole/h) 29 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0000 0.2885 4.7085 6.0000 0.0224 0.5302 1.0000 21 H2O 0.7624 1.664 --- 52 diM-Ether 77.0004 0.664 1.0024 47 Total 0.0000 0.0004 0.0000 0.0062 0.0000 0.0000 37 Liquid Phase 38 39 COMPONENTS MOLAR FLOW (kgmole/h) 40 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0000 0.9005 0.0001 0.5753 0.4928 --- 56 Acetone 27.93 27. .0000 0.7263) Page 34 of 71 * Specified by user.0051 46 Acetone 0.0000 0.0008 0. MA USA 3 4 5 Case Name: DMEPLANT.4724 42 diM-Ether 0.0000 11.0000 0.0000 1.0000 0.5302 1.0000 0.0002 0.0000 0.0022 0.0000 0.67 --- 53 H2O 0.6993 --- 54 AcetAldehyde 24.0000 0.4955 0.0000 0.0693 0.0000 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 19 Methanol 0.7675 0.0000 0.0506 0.3757 0.0059 0.0007 0.0247 0.0000 1.0000 0.0000 1.0000 0.0002 0.0000 0.0024 25 Total 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 30 Methanol 0.3757 0.1529 0.2 (24.0000 0.6435 31 diM-Ether 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 41 Methanol 0.0022 0.0021 0.0.4801 0.0000 0.0000 0.0130 1.99 --- 55 AceticAcid 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 10 @COL1 (continued) 7 8 9 11 Overall Viscosity Index Vapour Phase --- Property Package: PRSV Liquid Phase --- 13 --- COMPOSITION 14 15 Overall Phase 16 17 Basis-1 PROPERTIES 10 12 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 18 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0000 48 K VALUE 49 50 COMPONENTS MIXED LIGHT HEAVY 51 Methanol 1.0000 0.67 77.0000 0.0004 0.0012 0.4166 0.5753 0.0000 0.0.0025 0.0000 0.7085 6.1 2 LEGENDS Burlington.9005 0.0000 0.0247 0.

6 (atm) 10.96 90.1 (m3/h) 1. 0.300e-003 18 Molar Enthalpy -2.590 1.68 --- 44.585e-002 0.136e-002 0.0000 0.581 --- Avg.1 2 LEGENDS Burlington.221 Aspen HYSYS Version 7.3971 (C) 125.262e+004 (kJ/kg-C) 3.168 1.6029 0.R) 50 Cp/Cv 51 Heat of Vap.629 4.7834 0.8 72.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 8 @COL1 7 8 9 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall 12 Vapour / Phase Fraction 13 Temperature: 14 Pressure: 15 Vapour Phase Aqueous Phase 0.531e+004 6916 35 Phase Fraction [Vol.83 8. Cond) 54 Liq.030e-003 11.31 (kJ/kg-C) 2.6896 0.6 125.196 (kJ/kgmole) 3.93 21.5659 0.527e+005 9.9138 8.921e+005 (kJ/kgmole-C) 125.7834 0.951 33 LHV Vol Basis (Std) (kJ/kgmole) 6.26 10.3573 16 Mass Flow (tonne/d) 0.27 12.5424 0.93 38.7350 0.8997 0.003e+005 -1. Method) 67 Mass Cv (Ent.449 (kg/m3) 749.8503 0.767 2.26 Molar Flow (kgmole/h) 0. Gas Flow (ACT_m3/h) 1. Liq.9 160. Cond) 55 Liquid Fraction 56 Molar Volume 57 Mass Heat of Vap.5109 (cP) --- 1.474e+005 34 LHV Mass Basis (Std) (kJ/kg) 2.5068 0.843 4.091 1.561 (kJ/kgmole-C) 78.226e+005 -1.0000 Act.74 105.0.6029 0. 58 Phase Fraction [Molar Basis] 59 Surface Tension 60 Thermal Conductivity 61 Viscosity 62 Cv (Semi-Ideal) 63 Mass Cv (Semi-Ideal) 64 Cv 65 Mass Cv 66 Cv (Ent. Flow 45 Z Factor 46 Watson K 47 User Property 48 Partial Pressure of H2S 49 Cp/(Cp .055 --- --- 1.542e-006 --- 2.02 59.042e+005 -9.1391 (kJ/kgmole-C) 76.151e-003 (kJ/kg) -6970 -4933 -1.847e-002 3.31 (kgmole/m3) 0.238 (kJ/kgmole-C) --- --- 86.044e+004 2.3971 (dyne/cm) 44.943 4.1827 17 Std Ideal Liq Vol Flow (m3/h) 3.542e-006 Licensed to: LEGENDS (atm) --- 0.18 (kJ/kg-C) 2.6029 0.42 (kJ/kg-C) --- --- 4.798e+004 --- --- (cSt) --- 0. Ideal Liq.8 931.36 832. Flow (Std.2 (24.15 71.05 (kg/m3) 18.0000 --- --- (Cost/s) 0.3 (m3/s) 2.3431 39.15 71.0000 0.0.581 9. Basis] 0.002e-002 8.0 (m3/h) 3.179e-003 0. Mass Density (Std.5 Mass Heat Capacity (kJ/kg-C) 2.847e-002 * 22 PROPERTIES 23 24 Overall 25 Molecular Weight 26 Molar Density 27 Mass Density 28 Act.561e-002 (m3/kgmole) (kJ/kg) 1189 --- --- 0.6029 0.97 (kJ/h) -2.48 18.1672 (kg/m3) 746.832e-002 3.443 1.666 1.5 (STD_m3/h) 21.108 1.581 1.74 105.8 703. 52 Kinematic Viscosity 53 Liq. Gas Flow 43 Std.07 13.42 97.120e-002 8.120e-002 8.26 10. MA USA 3 4 5 Case Name: DMEPLANT.3971 0. Mass Density 44 Act.7350 (atm) 0.130 3.540 4. Density (kgmole/m3) 23.33 10.9 676.61 --- --- --- 0.0000 1.7263) Page 35 of 71 * Specified by user.05 (kJ/kgmole-C) 85.689e+005 19 Molar Entropy 20 Heat Flow 21 Liq Vol Flow @Std Cond (kJ/kgmole) -2.07 43.424 (kJ/kgmole-C) 85. . Vol.914 2. Volume Flow 29 Mass Enthalpy 30 Mass Entropy 31 Heat Capacity 32 Vapour Phase Aqueous Phase 31.6 125. Method) 68 Cp/Cv (Ent.83 63.406 1.2166 36 Phase Fraction [Mass Basis] 0. Liq.5 917.609e+004 3.0000 --- --- 1.000 1.179e-003 (m3/h) 3.27 11.131 1.856e+005 1.2650 37 Partial Pressure of CO2 38 Cost Based on Flow 39 40 41 Specific Heat 42 Std. Method) 69 Aspen Technology Inc.68 (W/m-K) --- 2.086 1.

Sum(Std.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 8 @COL1 (continued) 7 8 9 Basis-1 Property Package: PRSV PROPERTIES 10 11 Overall Vapour Phase Aqueous Phase 12 Reid VP at 37.0000 0.5424 1.0000 0.0001 0.2409 --- 0.0007 0.0000 0.0608 36 AcetAldehyde 0.7842 0.0782 0.0005 0.0000 40 Aqueous Phase 41 42 COMPONENTS MOLAR FLOW (kgmole/h) 43 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0663 0.0000 0.0062 0.1134 0.0711 0.0128 46 H2O 0.0179 0.7327 1.6298 FEED TO Tray Section: 64 PRODUCT FROM Main TS @COL1 Material Stream: LOGICAL CONNECTION 8 UTILITIES 65 66 ( No utilities reference this stream ) 67 68 69 Aspen Technology Inc.1 2 LEGENDS Burlington.2767 0.4 56 H2O 0.0000 0. .0007 0.6717 16.0030 0.9845 0.2291 59 Acetone 60.0000 51 K VALUE 52 53 COMPONENTS MIXED LIGHT HEAVY 54 Methanol 0.8554 0.0000 0.0000 0.0325 0.0000 0.3779 0.2189 2.3291 0.0017 27 Acetone 0.2 (24.0050 0.0000 0.3794 45 diM-Ether 0.0009 0.8341 35 H2O 0.0014 0.0006 0.8997 1.6141 1.0300 1.0021 0.6298 --- 55 diM-Ether 155. MA USA 3 4 5 Case Name: DMEPLANT.0001 0.4200 6.323 7.34 60 UNIT OPERATIONS 61 62 63 0.9015 0.3659 0.5241 COMPOSITION 17 18 Overall Phase 19 20 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 21 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0656 0.0018 0.1003 34 diM-Ether 0.8072 0.0011 26 AceticAcid 0.9266 --- 16 0.0083 1.0024 0.0014 37 AceticAcid 0.0006 38 Acetone 0.0022 28 Total 0.0000 29 Vapour Phase 30 31 COMPONENTS MOLAR FLOW (kgmole/h) 32 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0000 7.0068 0.0093 0.0012 0.0001 0.0000 28.0001 0.7263) Page 36 of 71 * Specified by user.0863 0.0011 0.6029 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 22 Methanol 0.1865 1.1706 0.0000 0.5058 0.0251 0.2369 0.8 C (atm) 7.0514 0.21 --- 36.417 14 Liq.6017 47 AcetAldehyde 0.0008 0.4 --- 155.0001 48 AceticAcid 0.3643 0.0031 0.871 13 True VP at 37.120e-002 8.0331 0.1608 23 diM-Ether 0.0001 0.21 58 AceticAcid 0.436 7.0023 0.1012 0.0.0000 0. Flow .0.0748 0.0067 0.3573 1.0003 0.1700 4.0015 0.0008 0. Cond) (m3/h) 3.7743 4.6546 0.1185 1.0015 0. Licensed to: LEGENDS Aspen HYSYS Version 7.1530 0.938e-002 3.0000 21.0013 0.082 6.0000 0.0000 0.179e-003 15 Viscosity Index --- 0.2409 57 AcetAldehyde 36.0024 0.0013 0.4066 16.6562 24 H2O 0.0059 49 Acetone 0.0012 0.7948 0. Vol.2291 --- 0.3957 0.0031 0.1780 25 AcetAldehyde 0.0043 0.34 --- 60.1378 2.3971 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 44 Methanol 0.6029 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 33 Methanol 0.8226 0.8 C (atm) 6.0001 50 Total 0.0011 0.0250 0.0001 0.0028 39 Total 0.0383 1.0008 0.5866 0.0693 0.

757e+004 --- --- (cSt) 0.00 10.8 67.000 43 Partial Pressure of CO2 (atm) 0.50 0.3 670.4073 0.8431 3. Basis] --- --- 1.072 1.502e-002 (kJ/kgmole-C) 114. Flow (Std.38 11.9 20. Flow (m3/s) 8.738 0.3 619.29 (atm) 10. Mass Density (kg/m3) 671.3 50 Act. Licensed to: LEGENDS (atm) --- 0.0.0.836 (kJ/kgmole-C) 123.0000 0.0000 --- --- 1.7263) Page 37 of 71 * Specified by user.20 123.8 Aspen HYSYS Version 7.7 --- --- 0.0000 0. Cond) 60 Liq.0000 -7.1307 0.0000 1.4073 23 Std Ideal Liq Vol Flow (m3/h) 2. .29 138. Gas Flow (ACT_m3/h) --- --- --- 46 Avg. Liq.0000 1.0000 0. Gas Flow (STD_m3/h) 8. Liq.656 2. Density (kgmole/m3) 14.015 1.681 1.803e-003 7.0000 0.739e-002 0.0000 (dyne/cm) 9.29 45.0000 45 Act. Volume Flow 35 Mass Enthalpy 36 Mass Entropy 37 Heat Capacity 38 Vapour Phase Liquid Phase 45.62 14.062e-002 11.8 84.876e+004 41 Phase Fraction [Vol.528e-002 24 Molar Enthalpy -2. 58 Kinematic Viscosity 59 Liq.018e+005 25 Molar Entropy 26 Heat Flow 27 Liq Vol Flow @Std Cond (kJ/kgmole) -2.0000 0.92 (kgmole/m3) 12.29 (kJ/h) -7.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 8 @COL1 (continued) 7 8 9 Fluid Package: Basis-1 Property Package: PRSV Fluid Package: Basis-1 Property Package: PRSV PROCESS UTILITY 10 11 12 Material Stream: 9 @COL1 13 14 15 CONDITIONS 16 17 Overall 18 Vapour / Phase Fraction 19 Temperature: 20 Pressure: 21 Vapour Phase Liquid Phase 0.247 (kJ/kgmole) 1.528e-002 0.459e+004 0.072 1.5 671.1 48 Std.738 49 Std.1 76.4539 12.0000 (C) 45.957e-002 (kJ/kg) -4396 -4000 -4396 (kJ/kg-C) 1.1307 (kg/m3) 619.1217 1.321e+006 1.002e-002 (kJ/kg) 382.89 114. MA USA 3 4 5 Case Name: DMEPLANT.4693 0.5 618. Ideal Liq.018e+005 -1.072 1.0000 8.3696 22 Mass Flow (tonne/d) 0.0000 1.739e-002 * 28 PROPERTIES 29 30 Overall 31 Molecular Weight 32 Molar Density 33 Mass Density 34 Act.02 45.1217 (cP) 7. Mass Density (Std.681 39 LHV Vol Basis (Std) (kJ/kgmole) 1.29 45.0000 2.00 Molar Flow (kgmole/h) 0.20 123.57 14.381 (W/m-K) 0.R) 56 Cp/Cv 57 Heat of Vap.89 573.203 8.000 0.122 1.321e+006 40 LHV Mass Basis (Std) (kJ/kg) 2.841e+005 (kJ/kgmole-C) 84.5 (m3/h) 2.957e-002 0.38 --- --- --- 0.0000 2.0000 --- --- 44 Cost Based on Flow (Cost/s) 0.381 --- 9.0000 2.2 (24. Vol.881e+004 2.214e-006 --- 8.92 46.0000 0.50 (kg/m3) 573.1 2 LEGENDS Burlington.62 47 Specific Heat (kJ/kgmole-C) 123.3696 0.502e-002 9.1 Mass Heat Capacity (kJ/kg-C) 2.0000 1.000 (m3/kgmole) 8.739e-002 (m3/h) 2.836 3.002e-002 2.0000 2.214e-006 51 Z Factor 52 Watson K 53 User Property 54 Partial Pressure of H2S 55 Cp/(Cp .326e+006 1.000 42 Phase Fraction [Mass Basis] 0.459e+004 0.877e-002 0.739e-002 1. Cond) 61 Liquid Fraction 62 Molar Volume 63 Mass Heat of Vap.072 1.00 10.876e+004 2. 64 Phase Fraction [Molar Basis] 65 Surface Tension 66 Thermal Conductivity 67 Viscosity 68 Cv (Semi-Ideal) 69 Aspen Technology Inc.38 11.9 (m3/h) 2.0000 0.1 76.

0007 0.9703 1.0000 0.0000 0.285 8.1059 --- 66 67 68 69 Aspen Technology Inc.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 50 Methanol 0.269 22 COMPOSITION 23 24 Overall Phase 25 26 Fluid Package: COMPONENTS 27 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0060 0.09 114.0025 0.500 1.0000 0.3696 1.3659 0.269 8.0000 16.0001 0.0007 0.0000 0.0000 0.9900 16.0000 0.0000 0.0000 0.Sum(Std.0006 0.0000 0.0018 0.0002 0.1 2 LEGENDS Burlington.9932 0.0009 0.0005 42 AcetAldehyde 0.0000 0.0001 0.0000 0.0000 0.007 1.0000 0.0003 0.9988 41 H2O 0.862 --- (kJ/kg-C) 2.0000 0.0000 0. MA USA 3 4 5 Case Name: DMEPLANT.0000 0.3696 1.0000 1.0019 0.0020 0.0007 0.0000 0.0000 0.0000 0.739e-002 21 Viscosity Index --- -9.0009 0.327 2.0021 34 Total 0.0253 1.9974 0.229 8.0251 0.0000 2.0416 0.8 C (atm) 19 True VP at 37.3171 0.0000 55 Acetone 0.0007 0. Licensed to: LEGENDS Aspen HYSYS Version 7.0000 0.0022 0.0000 0.0.0000 0. Method) 17 Cp/Cv (Ent.0253 1.9984 0.3171 --- 64 AceticAcid 1.0001 0.0000 0.0397 0.0000 0.7263) Page 38 of 71 * Specified by user.0016 53 AcetAldehyde 0.500 (kJ/kgmole-C) --- --- --- (kJ/kg-C) --- --- --- --- --- --- 8.0001 0.0025 0.229 20 Liq.9703 1.0005 43 AceticAcid 0.0000 0.0329 0.0006 0.0000 57 K VALUE 58 59 COMPONENTS MIXED LIGHT HEAVY 60 Methanol 0.0000 0.0002 45 Total 0.739e-002 0. Method) 16 Mass Cv (Ent.0019 0.297 8.0000 0.500 (kJ/kgmole-C) 114.0000 33 Acetone 0.0.0000 46 Liquid Phase 47 48 COMPONENTS 49 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0022 0.0021 56 Total 0.007 --- 62 H2O 0.0000 0.0329 0.0251 0.0019 0.0000 0.0000 51 diM-Ether 0.0000 44 Acetone 0.0060 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 9 @COL1 (continued) 7 8 9 Basis-1 Property Package: PRSV PROPERTIES 10 11 Overall Vapour Phase Liquid Phase 12 Mass Cv (Semi-Ideal) 13 Cv 14 Mass Cv 15 Cv (Ent.0000 0.0017 32 AceticAcid 0.0020 0.0007 0.0000 0.8 61.0416 0.0000 0.500 1.0017 54 AceticAcid 0.0000 0. .0000 0.0000 29 diM-Ether 0.0016 31 AcetAldehyde 0.0000 40 diM-Ether 0. Cond) (m3/h) 2.0000 0.2940 --- 63 AcetAldehyde 0.0397 0.475 2.8 (kJ/kg-C) 2. Flow .0001 0.0000 0.976e-002 --- 65 Acetone 0.9946 52 H2O 0.0019 0.0023 0.0001 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 39 Methanol 0.0000 0.1034 --- 61 diM-Ether 1.0000 35 Vapour Phase 36 37 COMPONENTS 38 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.1034 0.976e-002 1.0000 0.0000 1.0023 0.9932 0.0000 1.9946 30 H2O 0.8 C (atm) 8.0000 0.0000 0.0000 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 28 Methanol 0.9900 16. Method) 18 Reid VP at 37.2 (24.3659 0.8551 0.8551 0.0000 0.0000 0. Vol.2940 0.0000 0.0000 16.1059 0.

7263) Page 39 of 71 * Specified by user.No compositions exist ) 29 UNIT OPERATIONS 30 31 32 Fluid Package: FEED TO Energy Stream: PRODUCT FROM T101COND Total Condenser: 33 LOGICAL CONNECTION Condenser @COL1 UTILITIES 34 35 ( No utilities reference this stream ) 36 PROCESS UTILITY 37 38 39 Energy Stream: T101REB @COL1 40 41 42 Basis-1 Property Package: PRSV CONDITIONS 43 44 Duty Type: 45 Duty SP: Direct Q 6518 kJ/h Duty Calculation Operation: Reboiler @COL1 Minimum Available Duty: 46 --- Maximum Available Duty: --- COMPOSITION 47 48 ( Not a material stream .0.0000 (C) 122.800 6.2 (24.800 (kgmole/h) 6. MA USA 3 4 5 Case Name: DMEPLANT. .HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 9 @COL1 (continued) 7 8 9 Basis-1 Property Package: PRSV UNIT OPERATIONS 10 11 12 Fluid Package: FEED TO Material Stream: PRODUCT FROM DME Product Total Condenser: 13 LOGICAL CONNECTION Condenser @COL1 UTILITIES 14 15 ( No utilities reference this stream ) 16 PROCESS UTILITY 17 18 19 Energy Stream: T101COND @COL1 20 21 22 Basis-1 Property Package: PRSV CONDITIONS 23 24 Duty Type: 25 Duty SP: Direct Q 1.0.5 (atm) 6.1 2 LEGENDS Burlington.664e-002 0.0000 6.948e+004 kJ/h Duty Calculation Operation: Condenser @COL1 Minimum Available Duty: 26 --- Maximum Available Duty: --- COMPOSITION 27 28 ( Not a material stream .800 6.664e-002 Aspen HYSYS Version 7. Licensed to: LEGENDS Vapour Phase Liquid Phase 0.0000 1.0000 0.5 122.No compositions exist ) 49 UNIT OPERATIONS 50 51 52 Fluid Package: FEED TO Reboiler: PRODUCT FROM Reboiler @COL1 Energy Stream: 53 LOGICAL CONNECTION T101REB UTILITIES 54 55 ( No utilities reference this stream ) 56 PROCESS UTILITY 57 58 59 Material Stream: Reflux @COL2 60 61 62 Basis-1 Property Package: PRSV CONDITIONS 63 64 Overall 65 Vapour / Phase Fraction 66 Temperature: 67 Pressure: 68 Molar Flow 69 Fluid Package: Aspen Technology Inc.5 122.

Method) 64 Cp/Cv (Ent. Cond) 50 Liq.0000 2.4 40 Act.0000 1. Gas Flow (STD_m3/h) 1.0000 0.29 23.64 --- -31.2548 1.319e+005 -1.0000 3.0000 1. 54 Phase Fraction [Molar Basis] 55 Surface Tension 56 Thermal Conductivity 57 Viscosity 58 Cv (Semi-Ideal) 59 Mass Cv (Semi-Ideal) 60 Cv 61 Mass Cv 62 Cv (Ent.295e-003 0.63 10.2871 0.051 1.0000 --- --- 34 Cost Based on Flow (Cost/s) 0.933e+005 30 LHV Mass Basis (Std) (kJ/kg) 2. Flow (m3/s) 9. (atm) --- 0. MA USA 3 4 5 Case Name: DMEPLANT.070e+004 31 Phase Fraction [Vol.055 0.766 5.338 4.0 38 Std.928 (kJ/kgmole-C) --- --- --- (kJ/kg-C) --- --- --- --- --- --- 0. Volume Flow 25 Mass Enthalpy 26 Mass Entropy 27 Heat Capacity 28 Vapour Phase Liquid Phase 33.5 --- --- 0.794e-003 * 18 PROPERTIES 19 20 Overall 21 Molecular Weight 22 Molar Density 23 Mass Density 24 Act.802e-003 0.576 (kJ/kgmole-C) 171.0000 -1.1715 8.0000 (m3/h) 2.92 162.194e+005 6.160 1.76 135.78 37 Specific Heat (kJ/kgmole-C) 171.969 1.000 32 Phase Fraction [Mass Basis] 0.522 4. Cond) 51 Liquid Fraction 52 Molar Volume 53 Mass Heat of Vap.8 (m3/h) 2.3 796.000 (m3/kgmole) 4.2 (24.R) 46 Cp/Cv 47 Heat of Vap.928 1. Gas Flow (ACT_m3/h) --- --- --- 36 Avg.108 1.356e-002 0.283e+004 --- --- (cSt) 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: Reflux @COL2 (continued) 7 8 9 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall 12 Mass Flow 13 Std Ideal Liq Vol Flow 14 Molar Enthalpy 15 Molar Entropy 16 Heat Flow 17 Liq Vol Flow @Std Cond Vapour Phase Liquid Phase (tonne/d) 5.0000 0.545e+004 0.10 0.0000 0.64 Licensed to: LEGENDS Aspen HYSYS Version 7.63 --- --- --- 0.2871 (atm) 0.8 797.63 10.2548 (kg/m3) 798.0000 35 Act.1715 (kJ/kgmole-C) 162.576 39 Std.975e-002 4.975e-002 (kJ/kg) 980.545e+004 0. Cond) (m3/h) 2.8 C (atm) 66 True VP at 37.863 673.933e+005 7.76 (kJ/h) -1.0000 1. Liq.000 0.0 Mass Heat Capacity (kJ/kg-C) 5.0000 2.1397 (cP) 0.48 34.300 1.051 1.5 47.319e+005 (kJ/kgmole-C) 52.108 29 LHV Vol Basis (Std) (kJ/kgmole) 6.16 (W/m-K) 0.300 1.576 3.8 C 67 68 Viscosity Index 69 Aspen Technology Inc.0000 5.7263) Page 40 of 71 * Specified by user.0 798.794e-003 0.Sum(Std.1 2 LEGENDS Burlington.0 60.000 33 Partial Pressure of CO2 (atm) 0.315e-003 (kJ/kg) -6924 -5825 -6924 (kJ/kg-C) 1. Mass Density (kg/m3) 796.209e-007 --- 9. Ideal Liq.576 0.3721 0.4 794.7 51.5 (kJ/kg-C) 3.0000 2. .2892 Liq.315e-003 0.0000 0.0.794e-003 -31. Mass Density (Std.132e-002 0.802e-003 (kJ/kgmole) -2.0.4 52.78 23.23 171.859 1.9087 1.48 (kgmole/m3) 20.109e+004 2.3627 0. Basis] --- --- 1. Method) 65 Reid VP at 37.987e+005 -2.11 33. Vol.401 3.23 171.10 (kg/m3) 673.794e-003 0. Flow (Std.356e-002 2.042e-002 10.070e+004 2. Flow .7 (kJ/kg-C) 4.1 (m3/h) 3.794e-003 (m3/h) 2.1397 2.2305 20.0000 --- --- 1.0000 (dyne/cm) 15.859 (kJ/kgmole-C) 131.2892 0.16 --- 15. 48 Kinematic Viscosity 49 Liq.79 131.1 7.260 (kJ/kgmole) 3.209e-007 41 Z Factor 42 Watson K 43 User Property 44 Partial Pressure of H2S 45 Cp/(Cp . Vol. Density (kgmole/m3) 23.0000 1.0 60. Method) 63 Mass Cv (Ent.794e-003 1. Liq.

0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 15 Methanol 0.1 2 LEGENDS Burlington.0169 0.0000 0.0000 0.2003 0.9601 0.8783 0.0000 0.9896 --- 48 diM-Ether 7.0007 0.0000 0.0169 0.1348 32 Total 0.8533 0.0009 0.0000 0.0003 0.9179 1.0000 0.0000 0.0000 0.0043 0.0000 0.0000 0.0054 0.0638 0.1116 21 Total 0.0000 0.0000 0.9179 1.0011 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 37 Methanol 0.9896 0.0030 0.0024 30 AceticAcid 0.0000 0.695 2.0000 0.0.0007 0.0000 0.0091 0.0024 29 AcetAldehyde 0.0010 0.695 --- 51 AceticAcid 0.8518 27 diM-Ether 0.0000 0.2316 1.0009 0.0043 0.0012 39 H2O 0.593 7.0612 0.0000 42 Acetone 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: Reflux @COL2 (continued) 7 8 9 Basis-1 Property Package: PRSV COMPOSITION 10 11 Overall Phase 12 13 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0000 0.0025 0.0203 0.0009 41 AceticAcid 0.0000 0.8791 38 diM-Ether 0.0000 0.9601 0.0073 40 AcetAldehyde 0. Licensed to: LEGENDS Aspen HYSYS Version 7.0203 0.0000 0.8791 16 diM-Ether 0.0000 0.0000 0.0000 0.8783 0.0018 0.0000 0.0000 0.0003 0.0020 0.0010 0.0000 0.0000 31 Acetone 0.0000 0.2470 0.0000 0.0091 0.0000 0.0000 0.0000 0.0000 44 K VALUE 45 46 COMPONENTS MIXED LIGHT HEAVY 47 Methanol 0.0.1107 0.0612 0.0788 0.3383 0.0666 1.0009 19 AceticAcid 0. MA USA 3 4 5 Case Name: DMEPLANT.0000 20 Acetone 0.0007 0.0000 0.0022 0.2316 1.234 --- 53 UNIT OPERATIONS 54 55 56 FEED TO Tray Section: 57 PRODUCT FROM Main TS @COL2 Total Condenser: LOGICAL CONNECTION Condenser @COL2 UTILITIES 58 59 ( No utilities reference this stream ) 60 PROCESS UTILITY 61 62 63 64 65 66 67 68 69 Aspen Technology Inc.234 1.593 --- 49 H2O 0.0000 0.0000 2.3383 --- 50 AcetAldehyde 2.0028 1.0020 0.0000 0.0007 0.0023 0.0666 1. .9084 0.2003 --- 52 Acetone 1.1341 0.2470 0.0000 0.0086 28 H2O 0.1116 43 Total 0.0011 0.7263) Page 41 of 71 * Specified by user.0012 17 H2O 0.0000 0.0000 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 26 Methanol 0.0000 0.0000 33 Liquid Phase 34 35 COMPONENTS MOLAR FLOW (kgmole/h) 36 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0000 0.0638 0.0000 1.0000 0.0000 0.0073 0.0025 0.0000 22 Vapour Phase 23 24 COMPONENTS MOLAR FLOW (kgmole/h) 25 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.1107 0.0000 0.0000 1.0000 1.0022 0.0000 2.0028 1.0000 0.0073 18 AcetAldehyde 0.0000 0.0057 0.2 (24.

891e-002 17 Std Ideal Liq Vol Flow (m3/h) 3.073e-003 0.933e+005 6.8 (m3/h) 3. MA USA 3 4 5 Case Name: DMEPLANT.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: To Condenser @COL2 7 8 9 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall 12 Vapour / Phase Fraction 13 Temperature: 14 Pressure: 15 Vapour Phase 1. 52 Kinematic Viscosity 53 Liq.683 7. Liq.933e+005 34 LHV Mass Basis (Std) (kJ/kg) 2.0000 1.358 (kJ/kg) 980.331e-002 16 Mass Flow (tonne/d) 5. Cond) 54 Liq.32 (STD_m3/h) 1. Ideal Liq.358 4.772 33 LHV Vol Basis (Std) (kJ/kgmole) 6.6 (kJ/h) -1. Method) 68 Cp/Cv (Ent.01 51.000 1.2294 0.78 (kJ/kgmole-C) 59.800 Molar Flow (kgmole/h) 7.082e-003 18 Molar Enthalpy (kJ/kgmole) -1.000 37 Partial Pressure of CO2 38 Cost Based on Flow 39 40 41 Specific Heat 42 Std.7 123.073e-003 * 22 3.146e-002 2.95 46.283e+004 --- (cSt) 1.070e+004 2.163 1. Method) 67 Mass Cv (Ent.314e-003 (kJ/kgmole-C) 51.32 32 Mass Heat Capacity (kJ/kg-C) 1.772 1. Flow (Std.263 (kJ/kgmole) 3.733 1.891e-002 5.051 4.082 (kg/m3) 798.990e+005 19 Molar Entropy 20 Heat Flow 21 Liq Vol Flow @Std Cond (kJ/kgmole-C) 135.32 59.073e-003 3.7 (atm) 6. Density (kgmole/m3) 23. Gas Flow 43 Std.082 1.331e-002 7.402 (kJ/kgmole-C) --- --- (kJ/kg-C) --- --- --- --- Aspen HYSYS Version 7.3195 Avg.0000 (m3/kgmole) 4.523 1.6 135.0. Method) 69 Aspen Technology Inc. 58 Phase Fraction [Molar Basis] 59 Surface Tension 60 Thermal Conductivity 61 Viscosity 62 Cv (Semi-Ideal) 63 Mass Cv (Semi-Ideal) 64 Cv 65 Mass Cv 66 Cv (Ent.082e-003 3.051 31 Heat Capacity (kJ/kgmole-C) 59.314e-003 8.0000 1.2 (24. Mass Density 44 Act.523 (kJ/kgmole-C) 46.78 23. Cond) 55 Liquid Fraction 56 Molar Volume 57 Mass Heat of Vap.0000 0.4 (m3/s) --- --- 0. Liq.95 (kJ/kg-C) 1.0000 --- 1.1 2 LEGENDS Burlington.9102 10.3195 0. Flow 45 Z Factor 46 Watson K 47 User Property 48 Partial Pressure of H2S 49 Cp/(Cp . Basis] 1.163 1.0000 --- (Cost/s) 0. 33.070e+004 35 Phase Fraction [Vol.683 28 Act.63 --- --- Licensed to: LEGENDS (atm) 0.32 59.459e+004 -1.0000 Act.000 1. .990e+005 -1. Gas Flow (ACT_m3/h) 0.3195 29 Mass Enthalpy (kJ/kg) -5944 -5944 30 Mass Entropy (kJ/kg-C) 4.48 33.402 1.7263) Page 42 of 71 * Specified by user.263 1. Vol.4 796.2294 (atm) 0.48 0.8 798.073e-003 PROPERTIES 23 24 Overall Vapour Phase 25 Molecular Weight 26 Molar Density (kgmole/m3) 27 Mass Density (kg/m3) 7. Mass Density (Std.9102 0.0000 (C) 123.800 6.63 10.733 (kg/m3) 796. Volume Flow (m3/h) 0.01 (kJ/kg-C) 1.0000 0.146e-002 (cP) 8.R) 50 Cp/Cv 51 Heat of Vap.5 --- 1.000 36 Phase Fraction [Mass Basis] 1.0.3195 0.0000 (dyne/cm) --- --- (W/m-K) 2.459e+004 (m3/h) 3.

8 C (atm) 0.0000 0.0000 1.0001 0.2717 0.0000 0.0000 0.073e-003 15 Viscosity Index 4.0. Cond) (m3/h) 3.0673 0.0012 0.0010 0.0000 27 Acetone 0.0000 0.0047 0.0000 40 K VALUE 41 42 COMPONENTS MIXED LIGHT HEAVY 43 Methanol --- --- --- 44 diM-Ether --- --- --- 45 H2O --- --- --- 46 AcetAldehyde --- --- --- 47 AceticAcid --- --- --- 48 Acetone --- --- --- 49 UNIT OPERATIONS 50 51 52 FEED TO Total Condenser: PRODUCT FROM Condenser @COL2 Tray Section: 53 LOGICAL CONNECTION Main TS @COL2 UTILITIES 54 55 ( No utilities reference this stream ) 56 PROCESS UTILITY 57 58 59 Material Stream: Boilup @COL2 60 61 62 Basis-1 Property Package: PRSV CONDITIONS 63 64 Overall 65 Vapour / Phase Fraction 66 Temperature: 67 Pressure: 68 Molar Flow 69 Fluid Package: Aspen Technology Inc.8783 0.0733 1.0009 37 AceticAcid 0.4547 1.0007 0.2 (atm) 6.2871 13 True VP at 37.0000 2.0000 0.0000 0. MA USA 3 4 5 Case Name: DMEPLANT.959e-002 3.0.4547 1.0223 0.0733 1.8783 0.0000 29 Vapour Phase 30 31 COMPONENTS MOLAR FLOW (kgmole/h) 32 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0000 2.0091 0.2892 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 33 Methanol 0.0007 0.0169 0.0031 1.0009 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: To Condenser @COL2 (cont 7 8 9 Basis-1 Property Package: PRSV PROPERTIES 10 11 Overall Vapour Phase 12 Reid VP at 37.0009 0.2717 0.0223 0.0009 26 AceticAcid 0.0027 0.0000 0.0673 0.0000 0.1561 0.910 6. Vol.910 (kgmole/h) 3.0000 0.8 C (atm) 0.0047 0.0000 0.0010 0.0003 0.315 0.0000 0.0007 0.9179 2. .0027 0.315 4.0031 1.0022 0.0169 0.0000 0.0000 0.7263) Page 43 of 71 * Specified by user.9179 2.1107 0.0638 0.8791 34 diM-Ether 0.0007 0.0000 0. Flow .2892 14 Liq.0001 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 22 Methanol 0.0000 0.0000 0.0000 38 Acetone 0.8791 23 diM-Ether 0.0000 (C) 151.0024 0.959e-002 Aspen HYSYS Version 7.1107 0.2 (24.0091 0.Sum(Std.0012 0.2 151.2871 16 COMPOSITION 17 18 Overall Phase 19 20 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 21 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 1.0000 0.0000 0.1116 28 Total 0.0022 0.0012 24 H2O 0.0003 0.0638 0.0000 0.073e-003 3.0073 36 AcetAldehyde 0.0024 0.0012 35 H2O 0.1116 39 Total 0.0073 25 AcetAldehyde 0.1 2 LEGENDS Burlington.0000 0.1561 0. Licensed to: LEGENDS Vapour Phase 1.

870 (kg/m3) 866.9383 10.02 25.0000 --- 1.291 24 Act.291 5.0000 0.87 38. Gas Flow (ACT_m3/h) 0.1218 67 Liq.886 29 LHV Vol Basis (Std) (kJ/kgmole) 3.728 (kJ/kg) 1469 --- 1. Flow (Std.886 1.0000 (m3/kgmole) 4.1872 Avg. 48 Kinematic Viscosity 49 Liq. Method) 64 Cp/Cv (Ent.000 1.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: Boilup @COL2 (continued) 7 8 9 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall 12 Mass Flow 13 Std Ideal Liq Vol Flow 14 Molar Enthalpy 15 Molar Entropy 16 Heat Flow 17 Liq Vol Flow @Std Cond Vapour Phase (tonne/d) 2.0000 (dyne/cm) --- --- (W/m-K) 2.4 859. Density (kgmole/m3) 34.36 (kJ/kgmole-C) 47.2246 Aspen HYSYS Version 7.728 4.293 (kJ/kgmole) 3.87 (kJ/kg-C) 1. Vol.000 1.9362 0.870 1.9362 (kg/m3) 859.459 1.329 27 Heat Capacity (kJ/kgmole-C) 47.628e-002 2.293 1.0000 Act.19 28 Mass Heat Capacity (kJ/kg-C) 1.0.174e+005 (kJ/kgmole-C) 158.329 6.71 10.459 (kJ/kgmole-C) --- --- (kJ/kg-C) --- --- --- --- 0.50 (kJ/kg-C) 1.3 (m3/h) 1.R) 46 Cp/Cv 47 Heat of Vap.0000 --- (Cost/s) 0.3 158.676e+004 --- (cSt) 1. 54 Phase Fraction [Molar Basis] 55 Surface Tension 56 Thermal Conductivity 57 Viscosity 58 Cv (Semi-Ideal) 59 Mass Cv (Semi-Ideal) 60 Cv 61 Mass Cv 62 Cv (Ent.143e-003 1.143e-003 PROPERTIES 19 20 Overall Vapour Phase 21 Molecular Weight 22 Molar Density (kgmole/m3) 23 Mass Density (kg/m3) 5.152e-003 (kJ/kgmole) -2.4 (m3/s) --- --- 0.000 32 Phase Fraction [Mass Basis] 1.7263) Page 44 of 71 * Specified by user.554 1. Gas Flow 39 Std.171e+005 3.143e-003 1.0000 1. Liq. .268e+004 1.895e-003 (kJ/kgmole-C) 38. Flow 41 Z Factor 42 Watson K 43 User Property 44 Partial Pressure of H2S 45 Cp/(Cp . Cond) (m3/h) 1.377e-002 1.000 33 Partial Pressure of CO2 34 Cost Based on Flow 35 36 37 Specific Heat 38 Std.143e-003 68 Viscosity Index 10.214 1.174e+005 -2. 25.2115 (atm) 0.554 (kJ/kgmole-C) 36.2 (24.1872 25 Mass Enthalpy (kJ/kg) -8690 -8690 26 Mass Entropy (kJ/kg-C) 6.1 2 LEGENDS Burlington.8 C (atm) 66 True VP at 37.143e-003 * 18 1. Liq.143e-003 0.2246 0.19 (STD_m3/h) 0.71 69 Aspen Technology Inc.0.3 866. MA USA 3 4 5 Case Name: DMEPLANT. Basis] 1. Cond) 50 Liq.171e+005 30 LHV Mass Basis (Std) (kJ/kg) 1. Volume Flow (m3/h) 0.895e-003 9.02 0.1872 0.268e+004 31 Phase Fraction [Vol.628e-002 (cP) 9. Cond) 51 Liquid Fraction 52 Molar Volume 53 Mass Heat of Vap. Flow .8 C (atm) 0.1218 0.0000 0.152e-003 2.2115 0.19 47.1872 0. Vol. Ideal Liq. Mass Density (Std.9383 0.50 36.62 10.19 47.Sum(Std.3 (kJ/h) -8607 -8607 (m3/h) 1.62 --- --- Licensed to: LEGENDS (atm) 0.36 34. Method) 65 Reid VP at 37.214 1. Mass Density 40 Act. Method) 63 Mass Cv (Ent.377e-002 (m3/h) 1.

0000 0.0000 (C) 150.0000 0.0000 0.0008 0.0000 0.0000 1.373e-002 (m3/h) 1.5631 62 Mass Flow (tonne/d) 0.2 (24.630e+005 65 Molar Entropy 66 Heat Flow 67 Liq Vol Flow @Std Cond (kJ/kgmole) -2.0012 0. Licensed to: LEGENDS Aspen HYSYS Version 7.6287 0.0023 31 Acetone 0.58 157.0028 0.0000 0.3121 29 AcetAldehyde 0.4955 0.0000 1.3590 0.7263) Page 45 of 71 * Specified by user.481e+005 0.0000 0.5033 0.910 Molar Flow (kgmole/h) 0.0000 0.0000 32 Total 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: Boilup @COL2 (continued) 7 8 9 Basis-1 Property Package: PRSV COMPOSITION 10 11 Overall Phase 12 13 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 1.0000 0.391e-002 0.3624 0.0000 0.0000 0.0023 20 Acetone 0.0000 0.630e+005 -2.6347 0.5631 0.5 (atm) 6.0000 0.0196 0.0012 1.3007 0.0000 0.0000 19 AceticAcid 0.0000 28 H2O 0.0012 1.0000 0.0000 0.58 (kJ/h) -1.0000 0.0000 30 AceticAcid 0.0000 0.0.0000 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 26 Methanol 0.5 150.481e+005 0.5033 0.0012 0.0000 22 Vapour Phase 23 24 COMPONENTS MOLAR FLOW (kgmole/h) 25 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0028 0.0000 0.0000 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 15 Methanol 0.3590 0.0000 0.0000 0.0000 0.9905 1.0000 0.0028 0.0000 17 H2O 0.6287 0.0000 0.0000 0.910 6.6347 0.0000 0.0000 -1.0000 0.0028 0.0000 0.0000 0.0000 1.0000 0.1 2 LEGENDS Burlington.4955 0.6856 27 diM-Ether 0.0008 0.0000 0.0004 0.0199 0.0000 33 K VALUE 34 35 COMPONENTS MIXED LIGHT HEAVY 36 Methanol --- --- --- 37 diM-Ether --- --- --- 38 H2O --- --- --- 39 AcetAldehyde --- --- --- 40 AceticAcid --- --- --- 41 Acetone --- --- --- 42 UNIT OPERATIONS 43 44 45 FEED TO Tray Section: PRODUCT FROM Main TS @COL2 Reboiler: 46 LOGICAL CONNECTION Reboiler @COL2 UTILITIES 47 48 ( No utilities reference this stream ) 49 PROCESS UTILITY 50 51 52 Material Stream: To Reboiler @COL2 53 54 55 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 56 57 Overall 58 Vapour / Phase Fraction 59 Temperature: 60 Pressure: 61 Vapour Phase Liquid Phase 0.6856 16 diM-Ether 0.0000 0.391e-002 64 Molar Enthalpy -2.0000 0.0199 0.0000 0.0396 1.0000 0.0000 21 Total 0.6 77.0004 0.0.0000 0. .0000 0.0000 0.0000 0.0000 0.9905 1. MA USA 3 4 5 Case Name: DMEPLANT.3624 0.0196 0.3121 18 AcetAldehyde 0.5 150.910 6.165e+005 (kJ/kgmole-C) 77.3007 63 Std Ideal Liq Vol Flow (m3/h) 1.0396 1.373e-002 * 68 69 Aspen Technology Inc.

0000 (atm) 0. Flow (m3/s) 4.600e-002 (kJ/kg) -1.077 1.0000 0. Licensed to: LEGENDS Aspen HYSYS Version 7. Ideal Liq.5132 Page 46 of 71 * Specified by user.9 900. Cond) 41 Liq.7263) 0. Volume Flow 16 Mass Enthalpy 17 Mass Entropy 18 Heat Capacity 19 Vapour Phase Liquid Phase 22.444e-006 32 Z Factor 33 Watson K 34 User Property 35 Partial Pressure of H2S 36 Cp/(Cp .864 1.4818 67 diM-Ether 0.903e+005 21 LHV Mass Basis (Std) (kJ/kg) 8552 1.48 33.1664 0. Method) 56 Reid VP at 37.4531 2.0000 0.0067 0.89 108.610e-002 0.0000 1. Basis] --- --- 1. Vol.0000 68 H2O 0.5 47.2237 (atm) 8.2 (kJ/kg-C) 4.2 (24.63 116.000 24 Partial Pressure of CO2 25 Cost Based on Flow 26 Act.5 29 Std.31 0.5686 0.R) 37 Cp/Cv 38 Heat of Vap.8 855.82 40. Liq. Gas Flow (ACT_m3/h) --- --- --- 27 Avg.8 C 58 59 Viscosity Index 0.487 (kJ/kgmole-C) 116.1 2 LEGENDS Burlington.373e-002 1.2 (kJ/kg-C) 4.716 2.2 36. Mass Density (Std. 39 Kinematic Viscosity 40 Liq.0.2 (m3/h) 1.63 116.864 (kJ/kgmole-C) --- --- --- (kJ/kg-C) --- --- --- --- --- --- (atm) 0. Gas Flow (STD_m3/h) 13.60 --- --- --- 0.077 1.0000 --- --- 1.1292 1.3 912.31 30 Std.0000 (atm) --- 0. Cond) (m3/h) 1.882 5.8 31 Act.31 --- 37.3955 0. Density (kgmole/m3) 40. Cond) 42 Liquid Fraction 43 Molar Volume 44 Mass Heat of Vap.0000 0.587e-002 Liq.373e-002 0.554 4.373e-002 0.0000 0.841e-002 (kJ/kg) 1678 --- --- 0.000 (m3/kgmole) 2.444e-006 --- 4.487 6.4256 0.2237 0. Method) 54 Mass Cv (Ent. Vol.077 1.211 1. MA USA 3 4 5 Case Name: DMEPLANT.0000 1.1292 (kg/m3) 912.238 1.1012 (kJ/kgmole-C) 108.20 0.4531 (cP) 0.0000 (dyne/cm) 37. Liq.5 47.0071 69 Aspen Technology Inc.077 1. Flow .0000 --- --- (Cost/s) 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 66 Methanol 0. Method) 55 Cp/Cv (Ent.304e+005 1.291 (kJ/kgmole) 3.182e+004 (kJ/kg-C) 3.2956 5.31 (W/m-K) 0.2 862. Flow (Std.833e-003 0.373e-002 --- --- --- 60 COMPOSITION 61 62 Overall Phase 63 64 Basis-1 COMPONENTS 65 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.600e-002 0.1 5.000 0.31 108.832 0.238 20 LHV Vol Basis (Std) (kJ/kgmole) 1.0000 1.648e-003 10.8 C 57 True VP at 37.0000 0.62 10.1 (m3/h) 1.0000 1. .0.3332 0.864 1.2 39.1012 9.000 23 Phase Fraction [Mass Basis] 1. 45 Phase Fraction [Molar Basis] 46 Surface Tension 47 Thermal Conductivity 48 Viscosity 49 Cv (Semi-Ideal) 50 Mass Cv (Semi-Ideal) 51 Cv 52 Mass Cv 53 Cv (Ent.587e-002 0.25 25. Mass Density (kg/m3) 900.458 4.734e+004 --- --- (cSt) 0.Sum(Std.1244 0.2121 35.25 (kgmole/m3) 35.60 10.7023 7.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Fluid Package: Material Stream: To Reboiler @COL2 (continu Property Package: 7 8 9 PRSV PROPERTIES 10 11 Overall 12 Molecular Weight 13 Molar Density 14 Mass Density 15 Act.0000 13.5 Mass Heat Capacity (kJ/kg-C) 5.864 (kJ/kgmole-C) 108.1269 8.903e+005 3.0000 0.0000 0.841e-002 4.0000 0.2247 0.0000 0.226 3.306e+004 8552 22 Phase Fraction [Vol.31 22.48 28 Specific Heat (kJ/kgmole-C) 116.366 783.0000 1.9374 5.20 (kg/m3) 783.182e+004 -8557 -1.

0000 0.7263) Page 47 of 71 * Specified by user.0000 0.0000 19 Vapour Phase 20 21 COMPONENTS MOLAR FLOW (kgmole/h) 22 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0049 17 Acetone 0.0139 1.0000 1. MA USA 3 4 5 Case Name: DMEPLANT.0000 0.0000 0.0000 0.0000 0.0000 0.4825 0.0000 0.5631 1.0000 0.0000 0.0012 0.0000 30 Liquid Phase 31 32 COMPONENTS MOLAR FLOW (kgmole/h) 33 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.7023 7.6871 0.0000 0.0000 0.3955 0.5198 --- 49 Acetone 40.0000 0.0000 0.747 --- 45 diM-Ether 120.0000 0.0000 0.5297 1. .0000 0.2 151.747 1.0000 0.0021 0.0000 0.1 --- 46 H2O 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 15 AcetAldehyde 0.1 2 LEGENDS Burlington.0000 0.4818 35 diM-Ether 0.0021 28 Acetone 0.2946 26 AcetAldehyde 0.0000 0.0000 0.5631 1.2956 5.910 6.0071 0.0000 0.0000 0.0000 0.0000 40 Total 0.0000 1.0.6538 0.0000 0.0000 1.5686 0.5163 0.0000 0.0000 27 AceticAcid 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Fluid Package: Material Stream: To Reboiler @COL2 (continu Property Package: 7 8 9 PRSV COMPOSITION 10 11 Overall Phase (continued) 12 13 Basis-1 COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.2 (24.0139 1.3435 0.0001 0.0000 0.0000 0.0000 0.68 34.0000 0.0000 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 23 Methanol 0.91 --- 50 UNIT OPERATIONS 51 52 53 FEED TO Reboiler: PRODUCT FROM Reboiler @COL2 Tray Section: 54 LOGICAL CONNECTION Main TS @COL2 UTILITIES 55 56 ( No utilities reference this stream ) 57 PROCESS UTILITY 58 59 60 Material Stream: 13 @COL2 61 62 63 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 64 65 Overall 66 Vapour / Phase Fraction 67 Temperature: 68 Pressure: 69 Aspen Technology Inc.0000 0.0.0000 (C) 151.1664 0.910 6.0000 0.0000 0.0000 0.6871 --- 47 AcetAldehyde 34.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 34 Methanol 0.0000 12.0000 0.0026 0.0000 0.0000 0.0000 1.0000 38 AceticAcid 0.0720 0.3332 0.0000 16 AceticAcid 0.0000 0.0000 12.2 (atm) 6.0000 0.0011 0.0000 25 H2O 0.0001 0.5132 37 AcetAldehyde 0.0000 0.1 120.0001 29 Total 0.0057 0.7032 24 diM-Ether 0.0067 0.0000 0.0049 39 Acetone 0.2 151.0012 0.0021 0.0000 0.1244 0.68 --- 48 AceticAcid 0.0000 41 K VALUE 42 43 COMPONENTS MIXED LIGHT HEAVY 44 Methanol 1.4256 0.0001 0.0720 0.91 40.5297 1.0000 0.0057 0. Licensed to: LEGENDS Vapour Phase Liquid Phase 0.0000 0.0000 0.0000 0.0000 36 H2O 0.5198 0.0000 0.910 Aspen HYSYS Version 7.0000 0.0000 0.0000 18 Total 0.0000 0.0000 0.

Cond) (m3/h) 1.459 4.7 36.0000 (atm) --- 0. 0. Mass Density (kg/m3) 904. 55 Phase Fraction [Molar Basis] 56 Surface Tension 57 Thermal Conductivity 58 Viscosity 59 Cv (Semi-Ideal) 60 Mass Cv (Semi-Ideal) 61 Cv 62 Mass Cv 63 Cv (Ent.214 1.0000 -1.291 787.38 40 Std.74 (W/m-K) 0.0000 --- --- (Cost/s) 0.628e-002 0.0000 0.951e-002 (kJ/kgmole-C) 106. Flow .5235 (kJ/kgmole) -2.0000 1.5 859.87 106.895e-003 9.728 2.000 (m3/kgmole) 2.737e+004 --- --- (cSt) 0.807e+005 31 LHV Mass Basis (Std) (kJ/kg) 8198 1. Gas Flow (STD_m3/h) 12.2 5.078 1.000 0.36 41.839 (kJ/kgmole-C) 106.000 34 Partial Pressure of CO2 35 Cost Based on Flow 36 Act.839 (kJ/kgmole-C) --- --- --- (kJ/kg-C) --- --- --- --- --- --- (atm) 0.0000 0.0 39 Std.1264 1.554 4.072e-006 --- 4.807e+005 3.839 1.174e+005 (kJ/kgmole-C) 78.0000 0.05 (kJ/h) -1.466e-002 (kJ/kg) -1.216 1.0000 1.870 0.276e-002 15 Molar Enthalpy -2. Cond) 51 Liq.541 6.2236 (atm) 8.R) 47 Cp/Cv 48 Heat of Vap. Cond) 52 Liquid Fraction 53 Molar Volume 54 Mass Heat of Vap. Vol.1264 (kg/m3) 916.293 (kJ/kgmole) 3.800e-002 (kJ/kg) 1696 --- --- 0. Density (kgmole/m3) 41.343e-002 0.59 10.05 158.886 5.0 47. Mass Density (Std. MA USA 3 4 5 Case Name: DMEPLANT. Method) 65 Cp/Cv (Ent.078 1.078 1.216 30 LHV Vol Basis (Std) (kJ/kgmole) 1.Sum(Std.0000 --- --- 1.59 --- --- --- 0.7263) Page 48 of 71 * Specified by user.2236 0.0. Gas Flow (ACT_m3/h) --- --- --- 37 Avg.0000 0.196e+004 (kJ/kg-C) 3.2769 0.2 (24.19 115.2769 14 Std Ideal Liq Vol Flow (m3/h) 1.0 Mass Heat Capacity (kJ/kg-C) 5.50 106.72 0. Method) 66 Reid VP at 37.8 C 68 69 Aspen Technology Inc.2 (m3/h) 1.329 3.0000 1.4632 2.800e-002 4.1 2 LEGENDS Burlington. Ideal Liq.3 916. Flow (Std.9383 5.0000 (atm) 0.5 41 Act. Basis] --- --- 1.02 22.951e-002 9. Liq.0.259e-002 Licensed to: LEGENDS Aspen HYSYS Version 7. Flow (m3/s) 4.556e-003 10.74 --- 37. Liq.0 47.171e+005 1.0000 0.1218 8.72 (kg/m3) 787.0000 13 Mass Flow (tonne/d) 0.04 34.268e+004 8198 32 Phase Fraction [Vol.259e-002 (m3/h) 1.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 13 @COL2 (continued) 7 8 9 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall Vapour Phase Liquid Phase 12 Molar Flow (kgmole/h) 0.62 10.196e+004 -8690 -1.04 38 Specific Heat (kJ/kgmole-C) 115.4 904.0000 12.541 (kJ/kgmole-C) 115.380e+005 0.276e-002 0.8 C 67 True VP at 37.637e+005 16 Molar Entropy 17 Heat Flow 18 Liq Vol Flow @Std Cond 0.7 38.3 (m3/h) 1.0000 1.19 115.7 (kJ/kg-C) 4.04 (kgmole/m3) 35.380e+005 0.637e+005 -2.04 25. Method) 64 Mass Cv (Ent. Volume Flow 26 Mass Enthalpy 27 Mass Entropy 28 Heat Capacity 29 Vapour Phase Liquid Phase 22. Vol.4632 (cP) 9.2246 0.0000 1.3 866.3 78.7 (kJ/kg-C) 4.0000 1.078 1.5235 0.0000 1.2115 35.466e-002 0.000 33 Phase Fraction [Mass Basis] 1.259e-002 * 19 PROPERTIES 20 21 Overall 22 Molecular Weight 23 Molar Density 24 Mass Density 25 Act.38 0. 49 Kinematic Viscosity 50 Liq.343e-002 Liq.259e-002 0.839 1.259e-002 0.0000 (dyne/cm) 37.072e-006 42 Z Factor 43 Watson K 44 User Property 45 Partial Pressure of H2S 46 Cp/(Cp . .259e-002 1.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DMEPLANT.HSC

Unit Set:

NewUser1

Date/Time:

Wed May 23 23:14:35 2012

6

Material Stream: 13 @COL2 (continued)

7
8
9

11

Overall
Viscosity Index

Vapour Phase
---

Property Package:

PRSV

Liquid Phase
---

13

---

COMPOSITION

14
15

Overall Phase

16
17

Basis-1

PROPERTIES

10

12

Fluid Package:

COMPONENTS

MOLAR FLOW
(kgmole/h)

18

MOLE FRACTION

MASS FLOW
(kg/h)

Vapour Fraction

0.0000

MASS FRACTION

LIQUID VOLUME
FLOW (m3/h)

LIQUID VOLUME
FRACTION

19

Methanol

0.1468

0.2805

4.7045

0.4077

0.0059

0.4634

20

diM-Ether

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

21

H2O

0.3755

0.7173

6.7654

0.5863

0.0068

0.5314

22

AcetAldehyde

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

23

AceticAcid

0.0012

0.0022

0.0693

0.0060

0.0001

0.0052

24

Acetone

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

25

Total

0.5235

1.0000

11.5392

1.0000

0.0128

1.0000

26

Vapour Phase

27
28

COMPONENTS

MOLAR FLOW
(kgmole/h)

29

MOLE FRACTION

MASS FLOW
(kg/h)

Phase Fraction

0.0000

MASS FRACTION

LIQUID VOLUME
FLOW (m3/h)

LIQUID VOLUME
FRACTION

30

Methanol

0.0000

0.4955

0.0000

0.6347

0.0000

0.6856

31

diM-Ether

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

32

H2O

0.0000

0.5033

0.0000

0.3624

0.0000

0.3121

33

AcetAldehyde

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

34

AceticAcid

0.0000

0.0012

0.0000

0.0028

0.0000

0.0023

35

Acetone

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

36

Total

0.0000

1.0000

0.0000

1.0000

0.0000

1.0000

37

Liquid Phase

38
39

COMPONENTS

MOLAR FLOW
(kgmole/h)

40

MOLE FRACTION

MASS FLOW
(kg/h)

Phase Fraction

1.000

MASS FRACTION

LIQUID VOLUME
FLOW (m3/h)

LIQUID VOLUME
FRACTION

41

Methanol

0.1468

0.2805

4.7045

0.4077

0.0059

0.4634

42

diM-Ether

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

43

H2O

0.3755

0.7173

6.7654

0.5863

0.0068

0.5314

44

AcetAldehyde

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

45

AceticAcid

0.0012

0.0022

0.0693

0.0060

0.0001

0.0052

46

Acetone

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

47

Total

0.5235

1.0000

11.5392

1.0000

0.0128

1.0000

48

K VALUE

49
50

COMPONENTS

MIXED

LIGHT

HEAVY

51

Methanol

1.767

1.767

---

52

diM-Ether

130.9

130.9

---

53

H2O

0.7016

0.7016

---

54

AcetAldehyde

37.65

37.65

---

55

AceticAcid

0.5312

0.5312

---

56

Acetone

45.78

45.78

---

57

UNIT OPERATIONS

58
59
60

FEED TO
Material Stream:

61

PRODUCT FROM
13

Reboiler:

LOGICAL CONNECTION

Reboiler @COL2

UTILITIES

62
63

( No utilities reference this stream )

64

PROCESS UTILITY

65
66
67
68
69

Aspen Technology Inc.
Licensed to: LEGENDS

Aspen HYSYS Version 7.2 (24.0.0.7263)

Page 49 of 71
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DMEPLANT.HSC

Unit Set:

NewUser1

Date/Time:

Wed May 23 23:14:35 2012

6

Material Stream: 11 @COL2

7
8
9

Fluid Package:

Basis-1

Property Package:

PRSV

CONDITIONS

10
11

Overall

12

Vapour / Phase Fraction

13

Temperature:

14

Pressure:

15

Vapour Phase

Aqueous Phase

0.0502

0.0502

0.9498

(C)

150.9

150.9

150.9

(atm)

6.910

6.910

6.910

Molar Flow

(kgmole/h)

0.5302

2.663e-002

0.5036

16

Mass Flow

(tonne/d)

0.2823

1.620e-002

0.2661

17

Std Ideal Liq Vol Flow

(m3/h)

1.304e-002

7.868e-004

1.225e-002

18

Molar Enthalpy

-2.638e+005

19

Molar Entropy

20

Heat Flow

21

Liq Vol Flow @Std Cond

(kJ/kgmole)

-2.615e+005

-2.174e+005

(kJ/kgmole-C)

82.08

158.7

78.03

(kJ/h)

-1.386e+005

-5790

-1.329e+005

7.800e-004

1.209e-002

(m3/h)

1.287e-002 *

22

PROPERTIES

23
24

Overall

25

Molecular Weight

26

Molar Density

27

Mass Density

28

Act. Volume Flow

29

Mass Enthalpy

30

Mass Entropy

31

Heat Capacity

32

Vapour Phase

Aqueous Phase

22.19

25.35

22.02

(kgmole/m3)

3.792

0.2117

35.80

(kg/m3)

84.13

5.368

788.3

(m3/h)

0.1398

0.1258

1.406e-002

(kJ/kg)

-1.179e+004

-8576

-1.198e+004

(kJ/kg-C)

3.700

6.261

3.544

(kJ/kgmole-C)

111.3

47.72

114.7

Mass Heat Capacity

(kJ/kg-C)

5.017

1.882

5.208

33

LHV Vol Basis (Std)

(kJ/kgmole)

1.871e+005

3.306e+005

1.796e+005

34

LHV Mass Basis (Std)

35

Phase Fraction [Vol. Basis]

36

Phase Fraction [Mass Basis]

37

Partial Pressure of CO2

38

Cost Based on Flow

39
40
41

Specific Heat

42

Std. Gas Flow

43

Std. Ideal Liq. Mass Density

44

Act. Liq. Flow

45

Z Factor

46

Watson K

47

User Property

48

Partial Pressure of H2S

49

Cp/(Cp - R)

50

Cp/Cv

51

Heat of Vap.

52

Kinematic Viscosity

53

Liq. Mass Density (Std. Cond)

54

Liq. Vol. Flow (Std. Cond)

55

Liquid Fraction

56

Molar Volume

57

Mass Heat of Vap.

58

Phase Fraction [Molar Basis]

59

Surface Tension

60

Thermal Conductivity

61

Viscosity

62

Cv (Semi-Ideal)

63

Mass Cv (Semi-Ideal)

64

Cv

65

Mass Cv

66

Cv (Ent. Method)

67

Mass Cv (Ent. Method)

68

Cp/Cv (Ent. Method)

69

Aspen Technology Inc.

(kJ/kg)

8435

1.304e+004

8155

6.035e-002

6.035e-002

0.9396
0.9426

5.739e-002

5.739e-002

(atm)

0.0000

---

---

(Cost/s)

0.0000

0.0000

0.0000

Act. Gas Flow

(ACT_m3/h)

0.1258

0.1258

---

Avg. Liq. Density

(kgmole/m3)

40.67

33.84

41.10

(kJ/kgmole-C)

111.3

47.72

114.7

(STD_m3/h)

12.54

0.6296

11.91

(kg/m3)

902.2

858.0

905.0

(m3/s)

3.907e-006

---

3.907e-006

Licensed to: LEGENDS

(atm)

---

0.9379

5.547e-003

10.59

10.62

10.59

---

---

---

0.0000

---

---

1.081

1.211

1.078
1.078

1.005

1.289

(kJ/kgmole)

3.748e+004

---

---

(cSt)

---

1.845

0.1267

(kg/m3)

913.9

865.4

916.9

(m3/h)

1.287e-002

7.800e-004

1.209e-002

0.9498

0.0000

1.000

0.2637

4.723

2.793e-002

(m3/kgmole)
(kJ/kg)

1689

---

---

0.0502

0.0502

0.9498

(dyne/cm)

37.89

---

37.89

(W/m-K)

---

2.622e-002

0.4649

(cP)

---

9.903e-003

9.984e-002

(kJ/kgmole-C)

103.0

39.40

106.4

(kJ/kg-C)

4.643

1.554

4.831

(kJ/kgmole-C)

110.7

37.02

106.4

(kJ/kg-C)

4.990

1.460

4.831

(kJ/kgmole-C)

---

---

---

(kJ/kg-C)

---

---

---

---

---

---

Aspen HYSYS Version 7.2 (24.0.0.7263)

Page 50 of 71
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DMEPLANT.HSC

Unit Set:

NewUser1

Date/Time:

Wed May 23 23:14:35 2012

6

Material Stream: 11 @COL2 (continued)

7
8
9

Basis-1

Property Package:

PRSV

PROPERTIES

10
11

Overall

Vapour Phase

Aqueous Phase

12

Reid VP at 37.8 C

(atm)

0.2267

0.2495

13

True VP at 37.8 C

(atm)

0.4555

0.4987

0.2113

14

Liq. Vol. Flow - Sum(Std. Cond) (m3/h)

1.287e-002

7.800e-004

1.209e-002

15

Viscosity Index

---

10.57

---

16

0.2244

COMPOSITION

17
18

Overall Phase

19
20

Fluid Package:

COMPONENTS

MOLAR FLOW
(kgmole/h)

21

MOLE FRACTION

MASS FLOW
(kg/h)

Vapour Fraction

0.0502

MASS FRACTION

LIQUID VOLUME
FLOW (m3/h)

LIQUID VOLUME
FRACTION

22

Methanol

0.1529

0.2885

4.9005

0.4166

0.0062

0.4724

23

diM-Ether

0.0000

0.0000

0.0002

0.0000

0.0000

0.0000

24

H2O

0.3757

0.7085

6.7675

0.5753

0.0068

0.5201

25

AcetAldehyde

0.0000

0.0000

0.0002

0.0000

0.0000

0.0000

26

AceticAcid

0.0012

0.0022

0.0693

0.0059

0.0001

0.0051

27

Acetone

0.0004

0.0008

0.0247

0.0021

0.0000

0.0024

28

Total

0.5302

1.0000

11.7624

1.0000

0.0130

1.0000

29

Vapour Phase

30
31

COMPONENTS

MOLAR FLOW
(kgmole/h)

32

MOLE FRACTION

MASS FLOW
(kg/h)

Phase Fraction

5.022e-002

MASS FRACTION

LIQUID VOLUME
FLOW (m3/h)

LIQUID VOLUME
FRACTION

33

Methanol

0.0130

0.4865

0.4151

0.6149

0.0005

0.6630

34

diM-Ether

0.0000

0.0002

0.0002

0.0003

0.0000

0.0004

35

H2O

0.0133

0.5007

0.2402

0.3558

0.0002

0.3059

36

AcetAldehyde

0.0000

0.0001

0.0001

0.0002

0.0000

0.0002

37

AceticAcid

0.0000

0.0012

0.0019

0.0028

0.0000

0.0023

38

Acetone

0.0003

0.0114

0.0176

0.0260

0.0000

0.0283

39

Total

0.0266

1.0000

0.6751

1.0000

0.0008

1.0000

40

Aqueous Phase

41
42

COMPONENTS

MOLAR FLOW
(kgmole/h)

43

MOLE FRACTION

MASS FLOW
(kg/h)

Phase Fraction

0.9498

MASS FRACTION

LIQUID VOLUME
FLOW (m3/h)

LIQUID VOLUME
FRACTION

44

Methanol

0.1400

0.2780

4.4854

0.4046

0.0056

0.4601

45

diM-Ether

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

46

H2O

0.3623

0.7195

6.5273

0.5887

0.0065

0.5339

47

AcetAldehyde

0.0000

0.0000

0.0001

0.0000

0.0000

0.0000

48

AceticAcid

0.0011

0.0022

0.0674

0.0061

0.0001

0.0052

49

Acetone

0.0001

0.0002

0.0071

0.0006

0.0000

0.0007

50

Total

0.5036

1.0000

11.0873

1.0000

0.0123

1.0000

51

K VALUE

52
53

COMPONENTS

MIXED

LIGHT

HEAVY

54

Methanol

1.750

---

55

diM-Ether

132.6

---

132.6

56

H2O

0.6958

---

0.6958

57

AcetAldehyde

38.01

---

38.01

58

AceticAcid

0.5273

---

0.5273

59

Acetone

46.50

---

46.50

60

UNIT OPERATIONS

61
62
63

1.750

FEED TO
Tray Section:

64

PRODUCT FROM
Main TS @COL2

Material Stream:

LOGICAL CONNECTION
11

UTILITIES

65
66

( No utilities reference this stream )

67
68
69

Aspen Technology Inc.
Licensed to: LEGENDS

Aspen HYSYS Version 7.2 (24.0.0.7263)

Page 51 of 71
* Specified by user.

0000 --- --- 44 Cost Based on Flow (Cost/s) 0.794e-004 (m3/h) 2.10 0.0000 -1545 0.356e-003 23 Std Ideal Liq Vol Flow (m3/h) 2.0 (STD_m3/h) 0.1397 (cP) 0.975e-002 4.0 60.132e-002 0.209e-008 (atm) --- 0.5 --- --- 0.283e+004 --- --- (cSt) 0. .0000 0.0000 2.987e+005 -2.863 673.0000 1.300 1.0000 --- --- 1.0000 1.000 43 Partial Pressure of CO2 (atm) 0.92 162. Density (kgmole/m3) 23.794e-004 0.0 Mass Heat Capacity (kJ/kg-C) 5.933e+005 40 LHV Mass Basis (Std) (kJ/kg) 2. Flow (Std.10 (kg/m3) 673.070e+004 41 Phase Fraction [Vol.051 1.1 (m3/h) 3.0000 2. Gas Flow (ACT_m3/h) --- --- --- 46 Avg. Cond) 60 Liq.0000 (dyne/cm) 15.1715 (kJ/kgmole-C) 162.108 1.76 135.2548 (kg/m3) 798.664e-003 0.16 --- 15.78 23. Cond) 61 Liquid Fraction 62 Molar Volume 63 Mass Heat of Vap.0000 45 Act.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 11 @COL2 (continued) 7 8 9 Fluid Package: Basis-1 Property Package: PRSV Fluid Package: Basis-1 Property Package: PRSV PROCESS UTILITY 10 11 12 Material Stream: 12 @COL2 13 14 15 CONDITIONS 16 17 Overall 18 Vapour / Phase Fraction 19 Temperature: 20 Pressure: 21 Vapour Phase Liquid Phase 0.0000 2.802e-004 24 Molar Enthalpy (kJ/kgmole) -2.0000 0. Liq.4 52. 64 Phase Fraction [Molar Basis] 65 Surface Tension 66 Thermal Conductivity 67 Viscosity 68 Cv (Semi-Ideal) 69 Aspen Technology Inc.0000 5.109e+004 2.0 798. Mass Density (Std.0000 (C) 122.1576 (kg/m3) 796.48 (kgmole/m3) 20.1715 8. Vol.48 34.63 --- --- --- 0.2 (24.664e-003 22 Mass Flow (tonne/d) 5.4 794.5 122.9087 1.63 10.000 0.794e-004 * 28 PROPERTIES 29 30 Overall 31 Molecular Weight 32 Molar Density 33 Mass Density 34 Act.1397 2.576 3.7263) Page 52 of 71 * Specified by user.000 (m3/kgmole) 4.766 5.5 122.315e-004 0.0.0000 3.933e+005 7.000 42 Phase Fraction [Mass Basis] 0.070e+004 2.975e-002 (kJ/kg) 980.800 6.23 171.5 (atm) 6. Ideal Liq. Liq.160 1.051 1. Gas Flow 49 Std. Volume Flow 35 Mass Enthalpy 36 Mass Entropy 37 Heat Capacity 38 Vapour Phase Liquid Phase 33.0000 6.76 (kJ/h) -1545 0.055 0.194e+005 6.0000 0.8 (m3/h) 2.0000 1.260 (kJ/kgmole) 3.356e-003 0. Flow 51 Z Factor 52 Watson K 53 User Property 54 Partial Pressure of H2S 55 Cp/(Cp .3 796.319e+005 -1. 58 Kinematic Viscosity 59 Liq.300 1.0000 0. Licensed to: LEGENDS (kJ/kgmole-C) 171. Mass Density 50 Act. Basis] --- --- 1.0 60.R) 56 Cp/Cv 57 Heat of Vap.1 7.800 Molar Flow (kgmole/h) 6.0.315e-004 (kJ/kg) -6924 -5825 -6924 (kJ/kg-C) 1.29 23.7 51.11 33.576 (kJ/kgmole-C) 171.78 47 Specific Heat 48 Std.0000 0.4 (m3/s) 9.800 6.1576 0.16 (W/m-K) 0.295e-003 0.63 10.0000 0.108 39 LHV Vol Basis (Std) (kJ/kgmole) 6.2548 1. MA USA 3 4 5 Case Name: DMEPLANT.042e-002 10.0000 1.8 797.1 2 LEGENDS Burlington.802e-004 0.209e-008 --- 9.969 1.338 4.7 Aspen HYSYS Version 7.2305 20.794e-004 1.319e+005 25 Molar Entropy 26 Heat Flow 27 Liq Vol Flow @Std Cond (kJ/kgmole-C) 52.23 171.

0000 0.0000 0.522 4.0000 0.2003 0. Licensed to: LEGENDS Aspen HYSYS Version 7.1341 0.794e-004 -31.0000 0.8518 40 diM-Ether 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 12 @COL2 (continued) 7 8 9 Basis-1 Property Package: PRSV PROPERTIES 10 11 Overall 12 Mass Cv (Semi-Ideal) 13 Cv 14 Mass Cv 15 Cv (Ent.928 1.0007 0.0004 0.9179 0.0000 0.0000 0.0000 0.8533 0.3627 0.0010 0.0000 0.0020 0.1116 56 Total 0.0073 0. Flow .2 (24.0012 52 H2O 0.0000 1. Method) 16 Mass Cv (Ent.3383 --- 63 AcetAldehyde 2.0000 0.9179 0.0247 0.0091 0.2892 0.1960 0.0000 44 Acetone 0.0169 0.1116 34 Total 0.0002 0.593 --- 62 H2O 0.2871 0.8 C (atm) 19 True VP at 37.5 47.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 39 Methanol 0.0061 0.0000 57 K VALUE 58 59 COMPONENTS MIXED LIGHT HEAVY 60 Methanol 0. . Cond) (m3/h) 2.8 C 20 21 Viscosity Index Vapour Phase Liquid Phase (kJ/kg-C) 4.0.0000 0.0010 0.0000 0.0000 0.1 2 LEGENDS Burlington. MA USA 3 4 5 Case Name: DMEPLANT.0073 31 AcetAldehyde 0.0003 1.695 2.0024 43 AceticAcid 0.9896 --- 61 diM-Ether 7.0788 0.401 3.0003 1.5 (kJ/kg-C) 3.0002 0. Method) 17 Cp/Cv (Ent.79 131.0000 33 Acetone 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 28 Methanol 0.8783 0.0000 0. Vol.0000 0.0000 0.0000 0.0007 0.0000 0.0000 46 Liquid Phase 47 48 COMPONENTS 49 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0000 0.0000 0.2232 1.0007 0.0057 0.0067 1.0061 0.0000 0.0000 0.234 --- 66 67 68 69 Aspen Technology Inc.0002 0.0000 0.0002 0.0000 0.1107 0.0000 0.0000 0.0030 0.0169 0.0000 0.8791 51 diM-Ether 0.859 (kJ/kgmole-C) 131.7263) Page 53 of 71 * Specified by user.0000 0.0.3383 0.0000 0.0073 53 AcetAldehyde 0.0009 0.1348 45 Total 0.0000 0.0067 1.0086 41 H2O 0.8791 29 diM-Ether 0.859 1.0000 0.0000 1.0000 0.0000 0.2232 1.0000 55 Acetone 0.0023 0.0638 0.0000 2.0024 42 AcetAldehyde 0.8783 0.0002 0.9896 0.2871 (atm) 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 50 Methanol 0.0004 0.234 1.0000 0.0247 0.1960 0.9084 0.0002 0.0054 0.Sum(Std.0000 35 Vapour Phase 36 37 COMPONENTS 38 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0000 0. Method) 18 Reid VP at 37.0000 1.0001 0.928 (kJ/kgmole-C) --- --- --- (kJ/kg-C) --- --- --- --- --- --- 0.0000 0.0000 0.0009 32 AceticAcid 0.64 --- -31.0000 0.0000 0.0000 0.0000 0.3721 0.0000 0.0001 0.0000 0.0018 0.0000 0.0091 0.64 22 COMPOSITION 23 24 Overall Phase 25 26 Fluid Package: COMPONENTS 27 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0012 30 H2O 0.0009 0.0638 0.0000 0.0020 0.1107 0.0000 0.593 7.0000 0.2892 Liq.0009 54 AceticAcid 0.0000 0.0007 0.695 --- 64 AceticAcid 0.2003 --- 65 Acetone 1.794e-004 0.0000 0.

0. MA USA 3 4 5 Case Name: DMEPLANT. Licensed to: LEGENDS Vapour Phase Liquid Phase 0.18 70.080 (kgmole/h) 0.080 1.0000 0.0000 0.18 (atm) 1.0000 (C) 70.2 (24.1 2 LEGENDS Burlington. .HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 12 @COL2 (continued) 7 8 9 Basis-1 Property Package: PRSV UNIT OPERATIONS 10 11 12 Fluid Package: FEED TO PRODUCT FROM Material Stream: 12 Total Condenser: 13 LOGICAL CONNECTION Condenser @COL2 UTILITIES 14 15 ( No utilities reference this stream ) 16 PROCESS UTILITY 17 18 19 Energy Stream: T102C @COL2 20 21 22 Basis-1 Property Package: PRSV CONDITIONS 23 24 Duty Type: 25 Duty SP: Direct Q 2407 kJ/h Duty Calculation Operation: Condenser @COL2 Minimum Available Duty: 26 --- Maximum Available Duty: --- COMPOSITION 27 28 ( Not a material stream .7263) Page 54 of 71 * Specified by user.0.No compositions exist ) 29 UNIT OPERATIONS 30 31 32 Fluid Package: FEED TO PRODUCT FROM Energy Stream: T102C Total Condenser: 33 LOGICAL CONNECTION Condenser @COL2 UTILITIES 34 35 ( No utilities reference this stream ) 36 PROCESS UTILITY 37 38 39 Energy Stream: T102R @COL2 40 41 42 Basis-1 Property Package: PRSV CONDITIONS 43 44 Duty Type: 45 Duty SP: Direct Q 1460 kJ/h Duty Calculation Operation: Reboiler @COL2 Minimum Available Duty: 46 --- Maximum Available Duty: --- COMPOSITION 47 48 ( Not a material stream .080 1.7367 0.7367 Aspen HYSYS Version 7.0000 1.No compositions exist ) 49 UNIT OPERATIONS 50 51 52 Fluid Package: FEED TO Reboiler: PRODUCT FROM Reboiler @COL2 LOGICAL CONNECTION Energy Stream: 53 T102R UTILITIES 54 55 ( No utilities reference this stream ) 56 PROCESS UTILITY 57 58 59 Material Stream: Reflux @COL3 60 61 62 Basis-1 Property Package: PRSV CONDITIONS 63 64 Overall 65 Vapour / Phase Fraction 66 Temperature: 67 Pressure: 68 Molar Flow 69 Fluid Package: Aspen Technology Inc.18 70.

1 (kJ/kg-C) 4.2250 (atm) 0.8 C 67 68 Viscosity Index 69 Aspen Technology Inc.000 0.430 0.1 40.954 1.4 48.02 31.5641 0. Mass Density (Std.10 158.54 4.850e-006 --- 8.0000 2.2250 0.8 (m3/h) 3.42 166. Vol.186e-002 0.231 (kJ/kgmole) 4.989e+004 1.61 --- -12.954 1.948e-002 0. Liq.0000 --- --- 1.8 C (atm) 66 True VP at 37.2231 Liq.053 1. MA USA 3 4 5 Case Name: DMEPLANT. .1 39.97 37 Specific Heat (kJ/kgmole-C) 166.254 737.12 (kg/m3) 737.405e+005 (kJ/kgmole) -2.R) 46 Cp/Cv 47 Heat of Vap.0000 3.771e+005 0.5641 (m3/h) 2.325e-002 (kJ/kg) 1274 --- --- 0.405e+005 -1.948e-002 (m3/h) 2.954 (kJ/kgmole-C) --- --- --- (kJ/kg-C) --- --- --- --- --- --- 0.0.7592 4.948e-002 1.4182 5.0000 2.850e-006 41 Z Factor 42 Watson K 43 User Property 44 Partial Pressure of H2S 45 Cp/(Cp .91 (W/m-K) 0.0000 0.000 (atm) 0. Flow .2231 0.7592 (kJ/kgmole-C) 166.61 Licensed to: LEGENDS Aspen HYSYS Version 7.229 4.0000 1.948e-002 0.1 (kJ/kg-C) 4.954 (kJ/kgmole-C) 158.6 797.0000 0.63 10.3085 6.1634 1.3 (m3/h) 2. Flow (Std.771e+005 0.980e+004 1.995e+005 (kJ/kgmole-C) 24.980e+004 --- --- 1.186e-002 (kJ/kg) -7537 -6231 -7537 (kJ/kg-C) 0.3 796.215 (kJ/kgmole) 6.1 2 LEGENDS Burlington. Basis] 32 Phase Fraction [Mass Basis] 33 Partial Pressure of CO2 34 Cost Based on Flow 35 Act.253 4.1634 (cP) 0.053 1.62 10. Gas Flow (ACT_m3/h) --- --- --- 36 Avg. Mass Density (kg/m3) 796.325e-002 25.369e+005 6. Method) 64 Cp/Cv (Ent.658e-003 10.4 (kJ/kg-C) 5.12 3.7 795.42 39 Std.97 24. Gas Flow (STD_m3/h) 17.22 141. Cond) 50 Liq. 31.91 --- 22.318e+005 (kJ/kg) 1.0000 2.053 1.3085 (kJ/kgmole-C) 158.22 (kJ/h) -1.916e-002 23. Liq.2246 0. Method) 65 Reid VP at 37.053 1.9791 1.9 796.512 5.62 --- --- --- 0. Vol.950e-002 -2. Ideal Liq.0000 17. 54 Phase Fraction [Molar Basis] 55 Surface Tension 56 Thermal Conductivity 57 Viscosity 58 Cv (Semi-Ideal) 59 Mass Cv (Semi-Ideal) 60 Cv 61 Mass Cv 62 Cv (Ent. 48 Kinematic Viscosity 49 Liq.0000 1.948e-002 -12. Cond) (m3/h) 2.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: Reflux @COL3 (continued) 7 8 9 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall 12 Mass Flow 13 Std Ideal Liq Vol Flow 14 Molar Enthalpy 15 Molar Entropy 16 Heat Flow 17 Liq Vol Flow @Std Cond Vapour Phase Liquid Phase (tonne/d) 0.4182 (kg/m3) 797. Volume Flow 25 Mass Enthalpy 26 Mass Entropy 27 Heat Capacity 28 Mass Heat Capacity 29 LHV Vol Basis (Std) 30 LHV Mass Basis (Std) 31 Phase Fraction [Vol.0000 --- --- (Cost/s) 0.42 0.0000 0. Method) 63 Mass Cv (Ent.000 (m3/kgmole) 4.066e+004 --- --- (cSt) 0.4 38 Std.86 24.2250 0.42 166.950e-002 0.0000 -1.91 (kgmole/m3) 23.0000 (atm) --- 0.7 40 Act.0000 2.215 1.0000 0. Density (kgmole/m3) 24.318e+005 6.34 158.2 (24.Sum(Std.948e-002 * 18 PROPERTIES 19 20 Overall Vapour Phase Liquid Phase 21 Molecular Weight 22 Molar Density 23 Mass Density 24 Act.379 0.0000 0.0000 (dyne/cm) 22.0000 1.8 24.0.207 1.4 48.8 1.7263) Page 55 of 71 * Specified by user.91 32. Cond) 51 Liquid Fraction 52 Molar Volume 53 Mass Heat of Vap.743e-003 0.000 0.638e-002 0. Flow (m3/s) 8.

MA USA 3 4 5 Case Name: DMEPLANT.0000 0.008 --- 48 diM-Ether 28.1961 --- 50 AcetAldehyde 6.9954 16 diM-Ether 0.0000 32 Total 0.0000 0.0000 21 Total 0.623 2.0000 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 37 Methanol 0.0000 0.0000 0.0000 0.9980 0.24 --- 49 H2O 0.9942 0.0000 0.7293 0.24 28.0000 0.0000 0.0000 0.0000 28 H2O 0.0011 0.0073 0.0000 0.0000 0.0000 0.9900 23.0000 0.0000 0.0295 1.0000 0.623 --- 53 UNIT OPERATIONS 54 55 56 FEED TO Tray Section: 57 PRODUCT FROM Main TS @COL3 Total Condenser: LOGICAL CONNECTION Condenser @COL3 UTILITIES 58 59 ( No utilities reference this stream ) 60 PROCESS UTILITY 61 62 63 64 65 66 67 68 69 Aspen Technology Inc.7263) Page 56 of 71 * Specified by user.0000 0.7293 0.0019 0.0000 0.433 6.0294 0.0036 0.0000 23. .0000 0.0000 0.0000 0.0000 0.0000 0.0001 42 Acetone 0.0073 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 15 Methanol 0.0000 0.1316 0.9991 27 diM-Ether 0.9954 38 diM-Ether 0.0000 0.5046 1.0000 0.0000 0.0000 43 Total 0.2 (24.0045 18 AcetAldehyde 0.0001 0.1316 0.0000 44 K VALUE 45 46 COMPONENTS MIXED LIGHT HEAVY 47 Methanol 1.1855 --- 52 Acetone 2.0000 0.0000 0.0000 0.0000 0.1 2 LEGENDS Burlington.5046 1.0000 0.0000 0.9989 0.0000 19 AceticAcid 0.0000 0.0000 0.0056 0.0000 0.008 1.0045 40 AcetAldehyde 0.7367 1.0001 20 Acetone 0.0000 1.0.0000 0.0000 22 Vapour Phase 23 24 COMPONENTS MOLAR FLOW (kgmole/h) 25 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0000 0.0001 0.0000 39 H2O 0.1855 0.0000 0.0295 1.0002 0.0000 31 Acetone 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: Reflux @COL3 (continued) 7 8 9 Basis-1 Property Package: PRSV COMPOSITION 10 11 Overall Phase 12 13 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0001 0.0000 1.0000 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 26 Methanol 0.0099 0. Licensed to: LEGENDS Aspen HYSYS Version 7.1961 0.0000 0.0000 0.0000 0.9942 0.0000 0.0000 0.0000 0.0000 0.0000 0.0.0294 0.0001 0.3693 0.0000 0.0000 0.0000 1.0000 0.0099 0.3693 0.433 --- 51 AceticAcid 0.0001 0.0036 0.0000 0.0000 30 AceticAcid 0.0000 0.0000 0.0000 17 H2O 0.7367 1.0000 41 AceticAcid 0.0002 0.0000 23.0000 0.0000 0.0009 29 AcetAldehyde 0.9900 23.0000 0.0056 0.0000 33 Liquid Phase 34 35 COMPONENTS MOLAR FLOW (kgmole/h) 36 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.

Volume Flow 29 Mass Enthalpy 30 31 32 Vapour Phase 31.3 797. Mass Density 44 Act. Method) 69 Aspen Technology Inc. 52 Kinematic Viscosity 53 Liq.231 (kJ/kgmole) 4.469 4.766e+005 -1.255 (kJ/kgmole-C) 39.6 142.231 1.537e-002 * 22 3.60 (kJ/kg) 1274 --- 1.537e-002 3.0000 --- (Cost/s) 0.469 Heat Capacity (kJ/kgmole-C) 48.080 Molar Flow (kgmole/h) 0.1 2 LEGENDS Burlington.080 1.0000 Act.537e-002 0.63 (kJ/kg) -6262 -6262 Mass Entropy (kJ/kg-C) 4.0000 1.246 1.7263) Page 57 of 71 * Specified by user.8840 0.0000 1.906e-002 (kg/m3) 1.36 Mass Heat Capacity (kJ/kg-C) 1.0000 (m3/kgmole) 25.646e-002 1.540e-002 3.0000 0. Density (kgmole/m3) 24.906e-002 3.000 36 Phase Fraction [Mass Basis] 1.000 1.0000 --- 1.998e+005 (kJ/kgmole-C) 142.2 (24.980e+004 35 Phase Fraction [Vol.6 (kJ/h) -1.066e+004 --- (cSt) 5.97 (kJ/kgmole-C) 48.60 25.318e+005 6. Ideal Liq.318e+005 34 LHV Mass Basis (Std) (kJ/kg) 1.246 (m3/h) 22.208 1.63 22. Gas Flow 43 Std. 58 Phase Fraction [Molar Basis] 59 Surface Tension 60 Thermal Conductivity 61 Viscosity 62 Cv (Semi-Ideal) 63 Mass Cv (Semi-Ideal) 64 Cv 65 Mass Cv 66 Cv (Ent.R) 50 Cp/Cv 51 Heat of Vap.208 1. Method) 67 Mass Cv (Ent. (atm) 0.95 (atm) 1.29 39.0. Liq.97 24.0.998e+005 19 Molar Entropy 20 Heat Flow 21 Liq Vol Flow @Std Cond (kJ/kgmole) -1.6769 0.7 (m3/s) --- --- 0.537e-002 PROPERTIES 23 24 Overall 25 Molecular Weight 26 Molar Density 27 Mass Density 28 Act. Cond) 55 Liquid Fraction 56 Molar Volume 57 Mass Heat of Vap. Liq.516 1. Method) 68 Cp/Cv (Ent.255 1.9793 10.6769 17 Std Ideal Liq Vol Flow (m3/h) 3.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: To Condenser @COL3 7 8 9 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall 12 Vapour / Phase Fraction 13 Temperature: 14 Pressure: 15 Vapour Phase 1.231 (kJ/kgmole-C) --- --- (kJ/kg-C) --- --- --- --- Aspen HYSYS Version 7.436 (kg/m3) 797.000 37 Partial Pressure of CO2 38 Cost Based on Flow 39 40 41 Specific Heat 42 Std.0000 0.436 5.91 31.62 --- --- Licensed to: LEGENDS (atm) 0.980e+004 1.7 796.63 Avg. .646e-002 (cP) 6.8840 16 Mass Flow (tonne/d) 0.231 1.9793 0. Mass Density (Std.90 (kg/m3) 796. Flow 45 Z Factor 46 Watson K 47 User Property 48 Partial Pressure of H2S 49 Cp/(Cp .540e-002 18 Molar Enthalpy -1. Cond) 54 Liq.36 (STD_m3/h) 20.0000 (dyne/cm) --- --- (W/m-K) 1.29 (kJ/kg-C) 1.63 22.000 1. Basis] 1.90 20.62 10.36 48. Gas Flow (ACT_m3/h) 22.516 33 LHV Vol Basis (Std) (kJ/kgmole) 6. MA USA 3 4 5 Case Name: DMEPLANT. Vol. Flow (Std.36 48.774e-003 6.05 40.05 (kJ/kg-C) 1.91 (kgmole/m3) 3.766e+005 (m3/h) 3.95 70.774e-003 (kJ/kgmole-C) 40.0000 (C) 70.3 (m3/h) 3.

900 1.537e-002 15 Viscosity Index 19.0000 35 H2O 0.0000 28.0043 0. MA USA 3 4 5 Case Name: DMEPLANT.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 22 Methanol 0.9900 28.0001 0. .8 (atm) 1.0000 0.0000 0.0045 25 AcetAldehyde 0.0043 0.8840 1.0000 0.0045 36 AcetAldehyde 0.76 0.0000 40 K VALUE 41 42 COMPONENTS MIXED LIGHT HEAVY 43 Methanol --- --- --- 44 diM-Ether --- --- --- 45 H2O --- --- --- 46 AcetAldehyde --- --- --- 47 AceticAcid --- --- --- 48 Acetone --- --- --- 49 UNIT OPERATIONS 50 51 52 FEED TO Total Condenser: PRODUCT FROM Condenser @COL3 Tray Section: 53 LOGICAL CONNECTION Main TS @COL3 UTILITIES 54 55 ( No utilities reference this stream ) 56 PROCESS UTILITY 57 58 59 Material Stream: Boilup @COL3 60 61 62 Basis-1 Property Package: PRSV CONDITIONS 63 64 Overall 65 Vapour / Phase Fraction 66 Temperature: 67 Pressure: 68 Molar Flow 69 Fluid Package: Aspen Technology Inc.0000 (C) 118.0000 0.0000 0.9954 34 diM-Ether 0.0000 0.0002 0.0000 0.0000 0.2231 14 Liq.900 (kgmole/h) 0.0000 0.0000 0.0088 0.0001 0.0056 0.0000 0.0000 0. Licensed to: LEGENDS Vapour Phase 1.0000 0.8 118.Sum(Std.1580 0.537e-002 3.8840 1.9954 23 diM-Ether 0.8 C (atm) 0.9900 28.0000 1.8752 0.2055 1.0099 0.0000 0.0000 0. Flow .8752 0.0.1 2 LEGENDS Burlington.0000 0.8398 Aspen HYSYS Version 7.0354 1.0000 0.2231 0.0088 0.0000 0.0000 0.0000 0.0000 29 Vapour Phase 30 31 COMPONENTS MOLAR FLOW (kgmole/h) 32 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0001 27 Acetone 0.0000 39 Total 0.0000 0.0000 0.0000 28 Total 0.2250 16 COMPOSITION 17 18 Overall Phase 19 20 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 21 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 1.2250 13 True VP at 37.7263) Page 58 of 71 * Specified by user.2 (24.0002 0.0000 0.0001 0. Cond) (m3/h) 3.8 C (atm) 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: To Condenser @COL3 (cont 7 8 9 Basis-1 Property Package: PRSV PROPERTIES 10 11 Overall Vapour Phase 12 Reid VP at 37.0000 37 AceticAcid 0.0352 0.0000 0.0000 0.0002 0.0056 0.0000 24 H2O 0.0000 28.2055 1.0099 0. Vol.8398 0.0000 0.0000 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 33 Methanol 0.0000 0.9942 0.0000 0.0000 0.0000 0.0001 0.76 19.0352 0.0000 0.0432 0.0000 0.0.0001 38 Acetone 0.9942 0.0002 0.1580 0.0354 1.0000 26 AceticAcid 0.0432 0.0000 0.

461 (kJ/kgmole-C) 26.576e-002 2.420 9.511e-002 1.63 (kJ/kg-C) 1.68 (kJ/kg) 2192 --- 1.702e-003 (kJ/kgmole-C) 26.996e-002 5. Method) 64 Cp/Cv (Ent.22 (kgmole/m3) 5.0000 1.89 Licensed to: LEGENDS Aspen HYSYS Version 7.9854 0.000 1.008e+005 -2.313e+004 Mass Entropy (kJ/kg-C) 9.01 14.95 (STD_m3/h) 19.092 1. .7263) Page 59 of 71 * Specified by user.511e-002 0.616e-002 Liq. 48 Kinematic Viscosity 49 Liq. Ideal Liq. Cond) 50 Liq.68 16.9854 9.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: Boilup @COL3 (continued) 7 8 9 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall 12 Mass Flow 13 Std Ideal Liq Vol Flow 14 Molar Enthalpy 15 Molar Entropy 16 Heat Flow 17 Liq Vol Flow @Std Cond Vapour Phase (tonne/d) 0.5 (kJ/h) -2. Basis] 1.1 2 LEGENDS Burlington.8 C 66 True VP at 37.392e+005 (kJ/kgmole) -2. Method) 65 Reid VP at 37.000 33 Partial Pressure of CO2 34 Cost Based on Flow 35 36 37 Specific Heat 38 Std.576e-002 (cP) 9. Method) 63 Mass Cv (Ent. Gas Flow 39 Std.333 1.R) 46 Cp/Cv 47 Heat of Vap.511e-002 22.1 316.1557 (atm) 6.0000 (dyne/cm) --- --- (W/m-K) 2.3672 0.68 54. Mass Density (Std.0000 --- 1.8 C 67 68 Viscosity Index 69 Aspen Technology Inc.000 32 Phase Fraction [Mass Basis] 1.008e+005 (m3/h) 1.68 (kJ/kgmole-C) 34.0000 0. Vol.536e-002 -2. Volume Flow 25 Mass Enthalpy 26 27 28 Vapour Phase 18.01 Avg.743 Heat Capacity (kJ/kgmole-C) 34.0000 Act.22 18.996e-002 (kg/m3) 1.420 --- --- (atm) 0.511e-002 PROPERTIES 19 20 Overall 21 Molecular Weight 22 Molar Density 23 Mass Density 24 Act.22 26. Cond) 51 Liquid Fraction 52 Molar Volume 53 Mass Heat of Vap. Mass Density 40 Act.439 1. Density (kgmole/m3) 54.3 (m3/s) --- --- 0.0.312 1.1557 0.86 19. (atm) 0.95 34. Flow (Std. Flow 41 Z Factor 42 Watson K 43 User Property 44 Partial Pressure of H2S 45 Cp/(Cp . Vol.333 (kJ/kgmole) 3.Sum(Std.63 26.536e-002 1.511e-002 1.2 (24.0000 0.743 9. Cond) (m3/h) 1.616e-002 6. Liq.995e+004 --- (cSt) 8.89 22.01 (kJ/kg) -1.86 (kg/m3) 996.461 1. Gas Flow (ACT_m3/h) 14.881 (kg/m3) 1013 1013 (m3/h) 1. MA USA 3 4 5 Case Name: DMEPLANT. 54 Phase Fraction [Molar Basis] 55 Surface Tension 56 Thermal Conductivity 57 Viscosity 58 Cv (Semi-Ideal) 59 Mass Cv (Semi-Ideal) 60 Cv 61 Mass Cv 62 Cv (Ent.918 29 LHV Vol Basis (Std) (kJ/kgmole) 5761 5761 30 LHV Mass Basis (Std) (kJ/kg) 316.881 8.3672 (m3/h) 1.5 177.0000 --- (Cost/s) 0.702e-003 9.01 14.95 34.0000 (m3/kgmole) 16.1 31 Phase Fraction [Vol.0. Liq.918 1.511e-002 * 18 1.392e+005 (kJ/kgmole-C) 177.3 996. Flow .312 1.000 1.95 Mass Heat Capacity (kJ/kg-C) 1.439 (kJ/kgmole-C) --- --- (kJ/kg-C) --- --- --- --- (atm) 0.313e+004 -1.092 (m3/h) 14.22 (kJ/kg-C) 1.

HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: Boilup @COL3 (continued) 7 8 9 Basis-1 Property Package: PRSV COMPOSITION 10 11 Overall Phase 12 13 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 1.8328 0.7 (atm) 1.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 26 Methanol 0.0000 0.0000 0.900 1.0000 0.9805 0.0042 0.394e+005 0.791e+005 (kJ/kgmole-C) 75.0000 -3.0000 1.0000 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 15 Methanol 0.0032 0.0000 0.0000 15.9917 15.0150 0.185e-002 (m3/h) 2.0000 0.9788 29 AcetAldehyde 0.0031 0.0000 0.0150 0.791e+005 -2.7 118.0.0002 0.1360 0.0000 0.0000 21 Total 0.0000 0.0000 17 H2O 0.0106 0.2 (24.0000 22 Vapour Phase 23 24 COMPONENTS MOLAR FLOW (kgmole/h) 25 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0000 0.394e+005 0.1360 0.0111 27 diM-Ether 0.0051 0.0089 0.222e-002 (kJ/kgmole) -2.5314 0. .0000 0.7263) Page 60 of 71 * Specified by user.0000 0.0.0000 33 K VALUE 34 35 COMPONENTS MIXED LIGHT HEAVY 36 Methanol --- --- --- 37 diM-Ether --- --- --- 38 H2O --- --- --- 39 AcetAldehyde --- --- --- 40 AceticAcid --- --- --- 41 Acetone --- --- --- 42 UNIT OPERATIONS 43 44 45 FEED TO Tray Section: PRODUCT FROM Main TS @COL3 Reboiler: 46 LOGICAL CONNECTION Reboiler @COL3 UTILITIES 47 48 ( No utilities reference this stream ) 49 PROCESS UTILITY 50 51 52 Material Stream: To Reboiler @COL3 53 54 55 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 56 57 Overall 58 Vapour / Phase Fraction 59 Temperature: 60 Pressure: 61 Vapour Phase Liquid Phase 0.0111 16 diM-Ether 0.61 177.0089 0.1625 0.0101 31 Acetone 0.0000 0.0000 (C) 118.0000 32 Total 0.0000 0.5314 63 Std Ideal Liq Vol Flow 64 Molar Enthalpy 65 Molar Entropy 66 Heat Flow 67 Liq Vol Flow @Std Cond (m3/h) 2.0000 2.0000 0.0000 15.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 2.7 118.185e-002 * 68 69 Aspen Technology Inc.0000 0.0051 0.6 75.390e+005 -2.0000 0.0000 0.0106 0.0000 0.0000 0.0002 0.0032 0.0000 0.9805 0.222e-002 0.0031 0.0000 0.0042 0.0000 0.8398 1.0000 30 AceticAcid 0.0000 1.900 1.0154 1. Licensed to: LEGENDS Aspen HYSYS Version 7.0000 19 AceticAcid 0.9788 18 AcetAldehyde 0.1625 0.0000 0.0000 0.0000 0.0154 1.216 0. MA USA 3 4 5 Case Name: DMEPLANT.3017 1.3017 1.0000 28 H2O 0.61 (kJ/h) -3.1 2 LEGENDS Burlington.0000 0.8328 0.8398 1.9917 15.900 Molar Flow (kgmole/h) 1.0002 0.0000 0.0027 0.0101 20 Acetone 0.0002 0.216 62 Mass Flow (tonne/d) 0.0027 0.

Density (kgmole/m3) 54.68 1.1 2 LEGENDS Burlington.1493 0.0000 0. Method) 55 Cp/Cv (Ent.123 1.157e-003 9.7263) 0.185e-002 0.2069 0.1748 0.6830 (cP) 0.341 --- --- --- 0.0000 1.167 1.614e-002 6.0000 0.0002 0. Flow (m3/s) 6. MA USA 3 4 5 Case Name: DMEPLANT. 39 Kinematic Viscosity 40 Liq.716 4.6 31 Act.0094 67 diM-Ether 0.0000 2.0000 (dyne/cm) 54. 45 Phase Fraction [Molar Basis] 46 Surface Tension 47 Thermal Conductivity 48 Viscosity 49 Cv (Semi-Ideal) 50 Mass Cv (Semi-Ideal) 51 Cv 52 Mass Cv 53 Cv (Ent.28 18.0000 0.87 35.683 9.000 (atm) 0.185e-002 0.1462 9.0000 0.73 28 Specific Heat (kJ/kgmole-C) 75.0000 --- --- 1. Cond) 41 Liq.70 67.0.75 30 Std.0000 1.0000 (atm) --- 0.311 1.0000 --- --- (Cost/s) 0. Gas Flow (STD_m3/h) 28.54 (kJ/kg-C) 3. Flow .616e-002 Liq.573e-002 0.490 (kJ/kgmole-C) --- --- --- (kJ/kg-C) --- --- --- --- --- --- (atm) 0. Cond) 42 Liquid Fraction 43 Molar Volume 44 Mass Heat of Vap. Gas Flow (ACT_m3/h) --- --- --- 27 Avg. Mass Density (Std.9820 0.958e-002 (kJ/kg) 2194 --- --- 0.9926 21.01 75.28 63. Mass Density (kg/m3) 996.123 1.194 1.000 0.71 --- 54.152 9.6 441.332 (kJ/kgmole) 3.6 994.71 (W/m-K) 0.381e-002 0.958e-002 16.461 3.614e-006 --- 6.73 54. Vol. Cond) (m3/h) 2.7422 0.381e-002 (kJ/kg) -1. Basis] 23 Phase Fraction [Mass Basis] 24 Partial Pressure of CO2 25 Cost Based on Flow 26 Act.0000 2.0.710 1.533e+004 -1.21 (kgmole/m3) 51. Method) 54 Mass Cv (Ent.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Fluid Package: Material Stream: To Reboiler @COL3 (continu Property Package: 7 8 9 PRSV PROPERTIES 10 11 Overall 12 Molecular Weight 13 Molar Density 14 Mass Density 15 Act.07 (kg/m3) 929.2 (24.0000 68 H2O 1.533e+004 (kJ/kg-C) 4.995e+004 --- --- (cSt) 0.8 996.438 3.75 0.916 4.Sum(Std.0000 0.8 C 58 59 Viscosity Index --- --- 1.000 0.0000 0. Method) 56 Reid VP at 37.0000 28.43 54.9 (m3/h) 2.699e-003 0.21 18.07 5.87 35.614e-006 32 Z Factor 33 Watson K 34 User Property 35 Partial Pressure of H2S 36 Cp/(Cp . Flow (Std.0218 69 Aspen Technology Inc.185e-002 --- --- --- 60 COMPOSITION 61 62 Overall Phase 63 64 Basis-1 COMPONENTS 65 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0000 1.01 75.000 (m3/kgmole) 1. Ideal Liq.0000 0.0052 0.0000 0. Vol.6 22 Phase Fraction [Vol.1462 (kJ/kgmole-C) 67. .8 C 57 True VP at 37.0000 2.54 26.490 1.308e+004 -1.55 26.9853 1.152 (kJ/kgmole-C) 75.0000 0.6830 2.616e-002 6.0043 0.997e-002 51.1573 8.850 0. Licensed to: LEGENDS Aspen HYSYS Version 7.9 1.55 (kJ/kg-C) 3.167 20 LHV Vol Basis (Std) (kJ/kgmole) 5219 8066 5219 21 LHV Mass Basis (Std) (kJ/kg) 286.1493 (atm) 6.0075 0.3 286.87 Mass Heat Capacity (kJ/kg-C) 4.096 929. Liq. Liq.185e-002 1.710 (kJ/kgmole-C) 63.R) 37 Cp/Cv 38 Heat of Vap.1573 (kg/m3) 1013 1011 1013 (m3/h) 2.9807 Page 61 of 71 * Specified by user.1667 0.341 9.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 66 Methanol 0.194 1.87 29 Std. Volume Flow 16 Mass Enthalpy 17 Mass Entropy 18 Heat Capacity 19 Vapour Phase Liquid Phase 18.

0000 0.900 Aspen HYSYS Version 7.0000 0.0000 0. MA USA 3 4 5 Case Name: DMEPLANT.1667 0.2159 1.0187 24 diM-Ether 0.0000 0.0000 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Fluid Package: Material Stream: To Reboiler @COL3 (continu Property Package: 7 8 9 PRSV COMPOSITION 10 11 Overall Phase (continued) 12 13 Basis-1 COMPONENTS MOLAR FLOW (kgmole/h) 14 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0000 0.0218 0.0000 30 Liquid Phase 31 32 COMPONENTS MOLAR FLOW (kgmole/h) 33 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0000 0.0000 0.0032 0.0000 0.7263) Page 62 of 71 * Specified by user.0002 0.1400 1.0000 0.8 (atm) 1.9741 0.0000 0.0222 1.0000 0.2069 0.0.0000 0.2311 0.0000 0.0000 41 K VALUE 42 43 COMPONENTS MIXED LIGHT HEAVY 44 Methanol 1.0000 (C) 118.0000 0.0000 0.0099 17 Acetone 0.9926 21.989 1.9955 --- 47 AcetAldehyde --- --- --- 48 AceticAcid 1. .0000 16 AceticAcid 0.0000 0.0222 1.0000 0.0000 0.0000 0.0032 0.0000 0.0000 0.0000 0.0000 0.0038 0.0000 0.7422 0.0000 18 Total 1.2159 1.989 --- 45 diM-Ether --- --- --- 46 H2O 0.0000 0.059 1.9807 37 AcetAldehyde 0.0000 0.0000 29 Total 0.0094 35 diM-Ether 0.0.0000 0.0000 0.0000 0.8 118.0000 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 34 Methanol 0.0000 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 15 AcetAldehyde 0.0000 0.0000 0.0000 0.0000 36 H2O 1.0149 0.900 1.0002 0.0000 0.0000 0.0085 0.0000 38 AceticAcid 0.0000 40 Total 1.0052 0.0043 0.0000 0.0034 0.0000 19 Vapour Phase 20 21 COMPONENTS MOLAR FLOW (kgmole/h) 22 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0000 0.0000 0.0099 39 Acetone 0.2311 0.0000 0.0000 0.0000 27 AceticAcid 0.0000 1.9955 0.0000 0.8 118.0000 0.0000 25 H2O 0.0104 0.0000 22.0000 0.0000 1.0000 1.0000 0.0075 0.1 2 LEGENDS Burlington.1400 1.0000 0.9820 0. Licensed to: LEGENDS Vapour Phase Liquid Phase 0.0000 0.2 (24.0000 22.0000 0.900 1.0000 0.0104 0.0000 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 23 Methanol 0.0104 28 Acetone 0.059 --- 49 Acetone --- --- --- 50 UNIT OPERATIONS 51 52 53 FEED TO Reboiler: PRODUCT FROM Reboiler @COL3 Tray Section: 54 LOGICAL CONNECTION Main TS @COL3 UTILITIES 55 56 ( No utilities reference this stream ) 57 PROCESS UTILITY 58 59 60 Material Stream: 15 @COL3 61 62 63 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 64 65 Overall 66 Vapour / Phase Fraction 67 Temperature: 68 Pressure: 69 Aspen Technology Inc.0000 0.0000 0.0110 0.0000 1.0000 0.9881 0.9709 26 AcetAldehyde 0.0038 0.0002 0.

092 930. . Density (kgmole/m3) 54.895 40 Std.953e-002 (kJ/kg) 2197 --- --- 0.744e-003 Licensed to: LEGENDS Aspen HYSYS Version 7.392e+005 (kJ/kgmole-C) 75.312 1.0000 13 Mass Flow (tonne/d) 0.333 (kJ/kgmole) 3. Method) 64 Mass Cv (Ent. Flow (Std.5 75. Mass Density (kg/m3) 997.702e-003 0.348e-003 (kJ/kg) -1.000 0. Ideal Liq.050e+005 0. Liq.000 (m3/kgmole) 1.158 30 LHV Vol Basis (Std) (kJ/kgmole) 4009 5761 4009 31 LHV Mass Basis (Std) (kJ/kg) 220.124 1. Cond) 51 Liq. Method) 66 Reid VP at 37.041e-006 42 Z Factor 43 Watson K 44 User Property 45 Partial Pressure of H2S 46 Cp/(Cp . 49 Kinematic Viscosity 50 Liq.1561 (kg/m3) 1014 1013 1014 (m3/h) 6.87 54.78 --- 54.1278 0.7 (m3/h) 7.481 (kJ/kgmole-C) --- --- --- (kJ/kg-C) --- --- --- --- --- --- (atm) 0.7263) Page 63 of 71 * Specified by user.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 15 @COL3 (continued) 7 8 9 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall Vapour Phase Liquid Phase 12 Molar Flow (kgmole/h) 0.041e-006 --- 2.0.160 (kJ/kgmole-C) 75.536e+004 -1.22 63.4 41 Act.0000 (dyne/cm) 54.000 0. Mass Density (Std.792e+005 -2.6 316.102 --- --- --- 0.744e-003 (m3/h) 6.576e-002 0.4 996.881 0. Method) 65 Cp/Cv (Ent. Gas Flow (ACT_m3/h) --- --- --- 37 Avg. Cond) 52 Liquid Fraction 53 Molar Volume 54 Mass Heat of Vap.701 1.617e-002 Liq.1278 (atm) 6.160 9.18 (kgmole/m3) 51.461 3.743 4.1452 (kJ/kgmole-C) 67.20 5.1561 8.6847 2.050e+005 0.0000 6.744e-003 1.18 18.87 38 Specific Heat (kJ/kgmole-C) 75.154e-003 9.0000 8.0000 0.481 1. Basis] 33 Phase Fraction [Mass Basis] 34 Partial Pressure of CO2 35 Cost Based on Flow 36 Act.994e+004 --- --- (cSt) 0.124 1.1452 9.701 (kJ/kgmole-C) 63.313e+004 -1.62 (kJ/h) -1.1557 0.59 Mass Heat Capacity (kJ/kg-C) 4.1 220.95 75.617e-002 6.0000 7.953e-002 16.78 (W/m-K) 0.856e-003 0.792e+005 16 Molar Entropy 17 Heat Flow 18 Liq Vol Flow @Std Cond 0.63 67.1641 0. --- --- 1.0000 -1.3 997.28 (kJ/kg-C) 3. Flow (m3/s) 2.439 3.0.0000 1.616e-002 6.7 1.68 1. MA USA 3 4 5 Case Name: DMEPLANT.0000 1.22 18.348e-003 0.29 (kJ/kg-C) 3.0000 6.R) 47 Cp/Cv 48 Heat of Vap.0000 0.1641 14 Std Ideal Liq Vol Flow (m3/h) 6.0000 --- --- 1.918 4.20 (kg/m3) 930.102 9.856e-003 15 Molar Enthalpy -2.1 2 LEGENDS Burlington.6847 (cP) 0.996e-002 51.744e-003 0. Volume Flow 26 Mass Enthalpy 27 Mass Entropy 28 Heat Capacity 29 Vapour Phase Liquid Phase 18.3762 (kJ/kgmole) -2.29 26.3762 0.28 26.420 9.744e-003 0.62 177.Sum(Std.194 1.59 39 Std. Gas Flow (STD_m3/h) 8.0000 --- --- (Cost/s) 0.2 (24. Cond) (m3/h) 6.9854 1.59 34.194 1.0000 0.536e+004 (kJ/kg-C) 4.744e-003 * 19 PROPERTIES 20 21 Overall 22 Molecular Weight 23 Molar Density 24 Mass Density 25 Act.59 34.0000 1. Liq.000 (atm) 0.6 32 Phase Fraction [Vol.158 1.8 C 68 69 Aspen Technology Inc.0000 0.895 0.0000 6.0000 (atm) --- 0.0000 0. 55 Phase Fraction [Molar Basis] 56 Surface Tension 57 Thermal Conductivity 58 Viscosity 59 Cv (Semi-Ideal) 60 Mass Cv (Semi-Ideal) 61 Cv 62 Mass Cv 63 Cv (Ent. Flow .0000 6. Vol.68 54.95 75. Vol.8 C 67 True VP at 37.

0100 0.9855 0.0307 0.0000 43 H2O 0.7263) Page 64 of 71 * Specified by user.0000 25 Total 0.0000 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 30 Methanol 0.0051 0.0068 0.0000 0.0011 0.0000 0.0000 0.8383 1.0000 0.0000 0.9788 33 AcetAldehyde 0.0000 0.0000 0.0000 0.9917 0.0000 23 AceticAcid 0.0000 0.0000 1.0000 0.0030 0.0000 0.0000 1.0000 0.0307 0.0095 46 Acetone 0.0.0000 37 Liquid Phase 38 39 COMPONENTS MOLAR FLOW (kgmole/h) 40 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.0032 0.0000 0.0000 0.8383 1.9805 0.0000 0.0000 45 AceticAcid 0.0030 0.0010 0.7391 0.0000 0.3741 0.0111 31 diM-Ether 0.0011 0.0000 47 Total 0.0069 1.0068 0.9944 6.9855 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 19 Methanol 0.0000 0.3741 0.0025 0.0000 0.0000 0.0000 0.0000 26 Vapour Phase 27 28 COMPONENTS MOLAR FLOW (kgmole/h) 29 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0000 0.0000 0.0000 36 Total 0.0000 0.0000 0.0000 0.0000 21 H2O 0.0101 35 Acetone 0.987 1.0000 0.0000 0.9944 6.0000 0.0000 0.0001 0.0000 0.0025 0.7391 0.0685 0.0000 1. . Licensed to: LEGENDS Aspen HYSYS Version 7. MA USA 3 4 5 Case Name: DMEPLANT.0000 0.0000 0.0685 0.0000 0.0000 0.2 (24.987 --- 52 diM-Ether --- --- --- 53 H2O 0.0000 0.9973 0.0045 0.0106 0.0000 0.0000 0.0000 0.0000 0.062 1.0056 42 diM-Ether 0.0000 0.0000 0.9849 44 AcetAldehyde 0.0.9849 22 AcetAldehyde 0.0000 0.0000 48 K VALUE 49 50 COMPONENTS MIXED LIGHT HEAVY 51 Methanol 1.3762 1.0000 0.0000 0.0056 20 diM-Ether 0.0000 6.0069 1.0000 0.0100 0.0000 0.0000 0.1 2 LEGENDS Burlington.0000 32 H2O 0.0010 0.0000 0.0000 0.0045 0.0000 34 AceticAcid 0.9973 --- 54 AcetAldehyde --- --- --- 55 AceticAcid 1.0000 0.0000 0.0000 0.0000 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 15 @COL3 (continued) 7 8 9 11 Overall Viscosity Index Vapour Phase --- Property Package: PRSV Liquid Phase --- 13 --- COMPOSITION 14 15 Overall Phase 16 17 Basis-1 PROPERTIES 10 12 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 18 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.0000 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 41 Methanol 0.0000 0.0089 0.3762 1.0000 0.0000 6.0000 0.0000 0.0001 0.062 --- 56 Acetone --- --- --- 57 UNIT OPERATIONS 58 59 60 FEED TO Material Stream: 61 PRODUCT FROM 15 Reboiler: LOGICAL CONNECTION Reboiler @COL3 UTILITIES 62 63 ( No utilities reference this stream ) 64 PROCESS UTILITY 65 66 67 68 69 Aspen Technology Inc.0000 0.0095 24 Acetone 0.

308e-003 1.1 Mass Heat Capacity (kJ/kg-C) 4.1 (STD_m3/h) 12.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 14 @COL3 7 8 9 Fluid Package: Basis-1 Property Package: PRSV CONDITIONS 10 11 Overall 12 Vapour / Phase Fraction 13 Temperature: 14 Pressure: 15 Vapour Phase Aqueous Phase 0.924 33 LHV Vol Basis (Std) (kJ/kgmole) 1.8445 (dyne/cm) 49. Ideal Liq. Mass Density (Std.6 (m3/s) 3. MA USA 3 4 5 Case Name: DMEPLANT. 52 Kinematic Viscosity 53 Liq.22 2.1 62.R) 50 Cp/Cv 51 Heat of Vap.308e-003 1. (kJ/kg) 8198 1.40 169. Method) 69 Aspen Technology Inc.112 0.358 4.259e-002 2.61 10.4988 (cP) --- 8.88 (kJ/h) -1. Volume Flow 29 Mass Enthalpy 30 Mass Entropy 31 Heat Capacity 32 Vapour Phase Aqueous Phase 22.090 1.56 97.61 93. Density (kgmole/m3) 41.014 1. Vol.0000 Act.248 1. .61 93. Liq.88 106.5 863.111e-002 (kJ/kg) -1.674e-002 39.090 Molar Flow (kgmole/h) 0.1555 0.1555 0.8175 0.182 0.380e+005 -1. Gas Flow (ACT_m3/h) 2.1743 0. Liq.095 1.068e-002 0.2292 (kJ/kgmole-C) 87. 58 Phase Fraction [Molar Basis] 59 Surface Tension 60 Thermal Conductivity 61 Viscosity 62 Cv (Semi-Ideal) 63 Mass Cv (Semi-Ideal) 64 Cv 65 Mass Cv 66 Cv (Ent.1825 0.984 1.087e-006 Licensed to: LEGENDS (atm) --- 0.39 (kJ/kgmole-C) 96.637e+005 -2.0000 0.085 1.538 (kJ/kgmole-C) --- --- --- (kJ/kg-C) --- --- --- --- --- --- Aspen HYSYS Version 7.844 2.10 97.0000 --- --- (Cost/s) 0.272e-003 0.59 10.4421 16 Mass Flow (tonne/d) 0.261e+004 (kJ/kg-C) 3.223e+004 7346 0.807e+005 3.090 1.205e+005 (kJ/kgmole-C) 79.7263) Page 65 of 71 * Specified by user.216 2.2 (m3/h) 1.2673 (kg/m3) 916.0000 --- --- 1.265 (kJ/kgmole) 4.2769 4.216 --- Avg.538 (kJ/kgmole-C) 94.04 24.8445 0.259e-002 * 22 PROPERTIES 23 24 Overall 25 Molecular Weight 26 Molar Density 27 Mass Density 28 Act.583e+005 34 LHV Mass Basis (Std) 35 Phase Fraction [Vol.81 33.299 1.12 41.2 (24.70 --- 49.3 926.029e-002 (m3/h) 1.71 21.340 4. Cond) 54 Liq.000 4.023e+005 1.103e-004 10. Method) 67 Mass Cv (Ent.602 6.0.80 (kJ/kg-C) 3.2287 17 Std Ideal Liq Vol Flow (m3/h) 1.8257 0. Method) 68 Cp/Cv (Ent.085 1.04 34.827e-002 0.55 (kgmole/m3) 0.9078 857.59 --- --- --- 0.97 42.0.1555 0.9857 9.3 871.80 (kJ/kg-C) 4.276e-002 2.12 41. Mass Density 44 Act.253 27. Cond) 55 Liquid Fraction 56 Molar Volume 57 Mass Heat of Vap.361 1.141e-002 0.0000 0.0000 1.38 1.717e+005 19 Molar Entropy 20 Heat Flow 21 Liq Vol Flow @Std Cond (kJ/kgmole) -2.227 2.1 2 LEGENDS Burlington. Basis] 36 Phase Fraction [Mass Basis] 37 Partial Pressure of CO2 38 Cost Based on Flow 39 40 41 Specific Heat 42 Std.043e-002 18 Molar Enthalpy -2.201e+005 2.216 1.087e-006 --- 3.79 (kg/m3) 5.918 (kJ/kgmole-C) 96.1825 0.9 913. Flow (Std.61 (atm) 1.88 106.513e-002 (m3/kgmole) (kJ/kg) 1909 --- --- 0.1555 0.029e-002 0.795e+004 -1. Flow 45 Z Factor 46 Watson K 47 User Property 48 Partial Pressure of H2S 49 Cp/(Cp .328e-003 1.1743 (atm) 0.8445 (C) 93.196e+004 -8923 -1.45 (kg/m3) 904. Gas Flow 43 Std.2351 3.5235 8.5 (m3/h) 2.695 4.70 (W/m-K) --- 2.75 33.925 10.207e+004 --- --- (cSt) --- 9.

922 --- 55 diM-Ether --- --- --- 56 H2O 0.0000 0.2 (24.0000 48 AceticAcid 0.0055 49 Acetone 0.1555 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 33 Methanol 0.0000 51 K VALUE 52 53 COMPONENTS MIXED LIGHT HEAVY 54 Methanol 1.0000 9.0000 0.0000 0.0000 0.3841 0.9929 0.2453 3.0000 0.2233 13 True VP at 37.0000 29 Vapour Phase 30 31 COMPONENTS MOLAR FLOW (kgmole/h) 32 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0000 0.5267 0.260e-002 2.0000 0.73 16 COMPOSITION 17 18 Overall Phase 19 20 Fluid Package: COMPONENTS MOLAR FLOW (kgmole/h) 21 MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0. Licensed to: LEGENDS Aspen HYSYS Version 7.7725 0.0068 0.5235 1.4077 0.0000 0.0000 0.5758 47 AcetAldehyde 0.0000 50 Total 0.0000 0.8261 --- 0.0000 0.3325 36 AcetAldehyde 0.0037 38 Acetone 0.0060 0.0000 40 Aqueous Phase 41 42 COMPONENTS MOLAR FLOW (kgmole/h) 43 MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0059 0.0000 0.7654 0.0000 35 H2O 0.1468 0.0000 0. .0000 0.8445 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 44 Methanol 0.0.0000 0.0000 0.0010 0.0000 0.1555 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 22 Methanol 0.0000 0.1084 0.4634 23 diM-Ether 0.2 60 UNIT OPERATIONS 61 62 63 1.4187 45 diM-Ether 0.1166 7.2805 4.0000 0.0000 0.0045 0.0000 0.0000 0.2 --- 502.4749 0.0002 0.343e-002 0.0000 0.0008 0.0012 0.0000 0.0000 0.2243 0.0000 0.0000 0.0000 0.0429 0.0113 1.922 FEED TO Tray Section: 64 PRODUCT FROM Main TS @COL3 Material Stream: LOGICAL CONNECTION 14 UTILITIES 65 66 ( No utilities reference this stream ) 67 68 69 Aspen Technology Inc.0000 0.0023 0.877e-002 14 Liq.5392 1.6638 34 diM-Ether 0.0091 0.3647 0.0000 2.5863 0.0104 1.0000 0.0001 0.0000 0.04 -28.7000 57 AcetAldehyde 264.0000 11.0000 0.0000 0.0000 37 AceticAcid 0.7524 5.5279 1.8 C (atm) 0.7173 6.2236 0.0384 0.0000 0.0000 0.0052 27 Acetone 0.0128 1.0000 0.5314 25 AcetAldehyde 0.7045 0.6 --- 264.8 C (atm) 8.029e-002 15 Viscosity Index --- 23.0601 0.0.0000 24 H2O 0.0000 0. Cond) (m3/h) 1.0000 0. Flow .0000 0.4714 1.0000 0.7263) Page 66 of 71 * Specified by user.0000 0.0000 0.0001 0.6 58 AceticAcid 0.6114 0.0000 0.0000 0.3755 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 14 @COL3 (continued) 7 8 9 Basis-1 Property Package: PRSV PROPERTIES 10 11 Overall Vapour Phase Aqueous Phase 12 Reid VP at 37.0000 0.0015 0.0000 39 Total 0.0044 0.0000 0.308e-003 1.0019 0.0063 0.0000 46 H2O 0.0022 0.0000 26 AceticAcid 0.3327 0.0000 28 Total 0. MA USA 3 4 5 Case Name: DMEPLANT. Vol.0023 1.6290 0.0814 1.0060 0.8261 59 Acetone 502.0000 0.0000 0.Sum(Std.4421 1.1 2 LEGENDS Burlington.0000 0.0693 0.2297 0.7000 --- 0.

0000 0.4 48.R) 56 Cp/Cv 57 Heat of Vap.0000 3.42 166.8 24.896e-003 0.430 0.000 (m3/kgmole) 4.207 1.0000 0.896e-003 (m3/h) 5. Liq.980e+004 --- --- 1.770e-006 --- 1.000 (atm) 0. Gas Flow (ACT_m3/h) --- --- --- 46 Avg. Basis] 42 Phase Fraction [Mass Basis] 43 Partial Pressure of CO2 44 Cost Based on Flow 45 Act. 64 Phase Fraction [Molar Basis] 65 Surface Tension 66 Thermal Conductivity 67 Viscosity 68 Cv (Semi-Ideal) 69 Aspen Technology Inc.484 0.318e+005 6.4182 (kg/m3) 797.0000 --- --- (Cost/s) 0.4182 5.543e+004 0.0000 0.901e-003 24 Molar Enthalpy -2.000 0.0000 6.1634 (cP) 0.7263) Page 67 of 71 * Specified by user.215 1.7592 4.379 0.0000 1.901e-003 0.0000 1.1473 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 14 @COL3 (continued) 7 8 9 Fluid Package: Basis-1 Property Package: PRSV Fluid Package: Basis-1 Property Package: PRSV PROCESS UTILITY 10 11 12 Material Stream: 16 @COL3 13 14 15 CONDITIONS 16 17 Overall 18 Vapour / Phase Fraction 19 Temperature: 20 Pressure: 21 Vapour Phase Liquid Phase 0. Licensed to: LEGENDS 31.22 (kJ/h) -3.0000 (atm) --- 0.9 796.0000 --- --- 1.543e+004 0.18 (atm) 1. Cond) 61 Liquid Fraction 62 Molar Volume 63 Mass Heat of Vap.053 1.000 0.0000 5.0.7 50 Act.91 --- 22. Mass Density (kg/m3) 796.512 5.080 1.080 Molar Flow (kgmole/h) 0.0000 0.638e-002 0.86 24.3085 6.405e+005 25 Molar Entropy 26 Heat Flow 27 Liq Vol Flow @Std Cond (kJ/kgmole) -2.1473 22 Mass Flow (tonne/d) 0.318e+005 (kJ/kg) 1.372e-003 0.770e-006 51 Z Factor 52 Watson K 53 User Property 54 Partial Pressure of H2S 55 Cp/(Cp .484 49 Std.1128 23 Std Ideal Liq Vol Flow (m3/h) 5.405e+005 -1.254 737.02 31.916e-002 23.3085 (kJ/kgmole-C) 158.231 (kJ/kgmole) 4. MA USA 3 4 5 Case Name: DMEPLANT.42 166.0.1 40.0000 5.91 32.896e-003 * 28 PROPERTIES 29 30 Overall Vapour Phase Liquid Phase 31 Molecular Weight 32 Molar Density 33 Mass Density 34 Act.325e-002 (kJ/kg) 1274 --- --- 0.1 Aspen HYSYS Version 7.18 70. 58 Kinematic Viscosity 59 Liq.4 (kJ/kg-C) 5.1128 0.10 158. Vol.0000 1.4 48.97 24. Mass Density (Std.97 47 Specific Heat (kJ/kgmole-C) 166.12 (kg/m3) 737.6 797.658e-003 10.4 48 Std.22 141.989e+004 1. Cond) 60 Liq.0000 0.1634 1.053 1.8 1.066e+004 --- --- (cSt) 0.0000 0.325e-002 25.12 3.3 (m3/h) 5.0000 1.54 4.7592 (kJ/kgmole-C) 166.18 70.0000 5. . Volume Flow 35 Mass Enthalpy 36 Mass Entropy 37 Heat Capacity 38 Mass Heat Capacity 39 LHV Vol Basis (Std) 40 LHV Mass Basis (Std) 41 Phase Fraction [Vol.053 1.0000 -3.995e+005 (kJ/kgmole-C) 24. Flow (Std.0000 0.0000 (dyne/cm) 22.980e+004 1.91 (kgmole/m3) 23.2 (24.896e-003 1.8 (m3/h) 6.9791 1.63 10.215 (kJ/kgmole) 6. Density (kgmole/m3) 24.1 2 LEGENDS Burlington. Ideal Liq.62 10. Flow (m3/s) 1.0000 (C) 70.369e+005 6.62 --- --- --- 0.91 (W/m-K) 0.7 795.080 1.743e-003 0.3 796. Liq. Gas Flow (STD_m3/h) 3.053 1.372e-003 (kJ/kg) -7537 -6231 -7537 (kJ/kg-C) 0.

MA USA 3 4 5 Case Name: DMEPLANT.0000 0.0000 0.0099 0.0000 0.0045 53 AcetAldehyde 0.0059 1.0000 0.0000 44 Acetone 0.7263) Page 68 of 71 * Specified by user.2231 Liq.623 2.1 (kJ/kg-C) 4.9954 29 diM-Ether 0.0007 0.0000 0.0000 52 H2O 0.0001 0.0015 0.0056 0.0000 1.0000 0.8 C (atm) 19 True VP at 37.0019 0.0000 0.0001 33 Acetone 0.1459 0.0011 0.8 C 20 21 Viscosity Index Vapour Phase Liquid Phase (kJ/kg-C) 4.0000 1.0000 0.0000 0.0000 0.0000 56 Total 0. Method) 18 Reid VP at 37. Method) 16 Mass Cv (Ent.0000 0.0059 0.0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 39 Methanol 0.0000 0.0000 0.954 1.0000 0.0000 0.0000 0.0000 0.9942 0.0099 0.9942 0.0000 0.1961 0.0000 0.7009 1.0000 0.0000 35 Vapour Phase 36 37 COMPONENTS 38 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 0.0000 0.1473 1.24 --- 62 H2O 0.1855 0.9900 4.7009 1.0000 0.623 --- 66 67 68 69 Aspen Technology Inc.0000 0.0000 1.433 6.0000 0.24 28.34 158. Cond) (m3/h) 5.0000 45 Total 0.0263 0.0059 0.9989 0.0002 0.0000 0.0059 1.253 4.0000 0.0009 42 AcetAldehyde 0.0000 0.0000 30 H2O 0.0000 0.0000 43 AceticAcid 0.0000 0.6739 0.0000 0.0000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 28 Methanol 0.1855 --- 65 Acetone 2.896e-003 0.Sum(Std.0002 0.954 1.1 39.0000 0.61 22 COMPOSITION 23 24 Overall Phase 25 26 Fluid Package: COMPONENTS 27 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Vapour Fraction 0.229 4.2231 0.0.1 2 LEGENDS Burlington.0000 0.896e-003 -12.0000 34 Total 0.0000 0. Flow .0000 0.9954 51 diM-Ether 0.0000 0.0000 32 AceticAcid 0.1473 1.0000 0.000 MASS FRACTION LIQUID VOLUME FLOW (m3/h) LIQUID VOLUME FRACTION 50 Methanol 0.008 1.0263 0.0045 31 AcetAldehyde 0.0000 0.9991 40 diM-Ether 0.0000 0.9900 4. .2 (24.0000 0.0000 4.0000 0.008 --- 61 diM-Ether 28.954 (kJ/kgmole-C) 158. Method) 17 Cp/Cv (Ent.0000 0.0000 0.2246 0.0000 54 AceticAcid 0.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 16 @COL3 (continued) 7 8 9 Basis-1 Property Package: PRSV PROPERTIES 10 11 Overall 12 Mass Cv (Semi-Ideal) 13 Cv 14 Mass Cv 15 Cv (Ent.0000 0.0000 0.0000 0.0000 41 H2O 0.2250 0.1961 --- 63 AcetAldehyde 6.0007 0.2250 0.0000 4.0015 0.0000 0.0000 0.0000 5.0000 0.0056 0.954 (kJ/kgmole-C) --- --- --- (kJ/kg-C) --- --- --- --- --- --- 0.61 --- -12.433 --- 64 AceticAcid 0. Vol.0000 0.0000 0.0000 0.6739 0.0000 0.0000 0.0000 0.0001 55 Acetone 0.0000 0.0000 0.0000 0.2250 (atm) 0.0000 0.0000 0.0000 0. Licensed to: LEGENDS Aspen HYSYS Version 7.0001 0.0000 0.0000 0.0000 57 K VALUE 58 59 COMPONENTS MIXED LIGHT HEAVY 60 Methanol 1.0000 0.0000 0.0000 0.1459 0.0000 0.9980 0.0000 46 Liquid Phase 47 48 COMPONENTS 49 MOLAR FLOW (kgmole/h) MOLE FRACTION MASS FLOW (kg/h) Phase Fraction 1.

1 2 LEGENDS Burlington.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Material Stream: 16 @COL3 (continued) 7 8 9 Basis-1 Property Package: PRSV UNIT OPERATIONS 10 11 12 Fluid Package: FEED TO PRODUCT FROM Material Stream: 16 Total Condenser: 13 LOGICAL CONNECTION Condenser @COL3 UTILITIES 14 15 ( No utilities reference this stream ) 16 PROCESS UTILITY 17 18 19 Energy Stream: T103COND @COL3 20 21 22 Basis-1 Property Package: PRSV CONDITIONS 23 24 Duty Type: 25 Duty SP: Direct Q 3.0.0. .No compositions exist ) 49 UNIT OPERATIONS 50 51 52 Fluid Package: FEED TO Reboiler: PRODUCT FROM Reboiler @COL3 Energy Stream: 53 LOGICAL CONNECTION T103REB UTILITIES 54 55 ( No utilities reference this stream ) 56 PROCESS UTILITY 57 58 59 Equilibrium Reactor: ERV-100 60 61 62 CONNECTIONS 63 64 Inlet Stream Connections 65 Stream Name 66 67 5 E-100 Outlet Stream Connections 68 69 From Unit Operation Heater Aspen Technology Inc.594e+004 kJ/h Duty Calculation Operation: Condenser @COL3 Minimum Available Duty: 26 --- Maximum Available Duty: --- COMPOSITION 27 28 ( Not a material stream .355e+004 kJ/h Duty Calculation Operation: Reboiler @COL3 Minimum Available Duty: 46 --- Maximum Available Duty: --- COMPOSITION 47 48 ( Not a material stream .7263) Page 69 of 71 * Specified by user. Licensed to: LEGENDS Aspen HYSYS Version 7. MA USA 3 4 5 Case Name: DMEPLANT.No compositions exist ) 29 UNIT OPERATIONS 30 31 32 Fluid Package: FEED TO Energy Stream: PRODUCT FROM T103COND Total Condenser: 33 LOGICAL CONNECTION Condenser @COL3 UTILITIES 34 35 ( No utilities reference this stream ) 36 PROCESS UTILITY 37 38 39 Energy Stream: T103REB @COL3 40 41 42 Basis-1 Property Package: PRSV CONDITIONS 43 44 Duty Type: 45 Duty SP: Direct Q 3.2 (24.

0000 kPa --- 0.2 (24.0000 3.0000 0.908 1.93 31. .02 1* 32 REACTION RESULTS FOR : 33 34 Global Rxn Set Extents 35 36 Act.0. 37 Rxn-1 Base Comp.06 9.294e-023 3.088e-007 1.050e-004 45 AcetAldehyde 2.539e-006 1.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Equilibrium Reactor: ERV-100 (continued) 7 8 9 CONNECTIONS 10 Outlet Stream Connections 11 Stream Name 12 13 14 To Unit Operation 6A 6B 15 Mixer: MIX-100 Mixer: MIX-100 Energy Stream Connections 16 Stream Name 17 From Unit Operation 18 19 PARAMETERS 20 21 Physical Parameters Optional Heat Transfer 22 Delta P Vessel Volume Duty 23 0.0000 0. Licensed to: LEGENDS 5 6B 6A 31.249e-005 43 diM-Ether 2.0.0000 61 Elevation (% of Height) (%) --- --- --- 62 PROPERTIES 63 64 Name 65 Molecular Weight 66 Molar Density 67 Mass Density 68 Act.7263) Page 70 of 71 * Specified by user.380 (m3/h) 2.3778 0.063 Aspen HYSYS Version 7.647e-023 2.0000 0.382 0.014e-004 1.93 31.2937 0.0000 60 Elevation (Ground) (m) 0.68 Eqm Constant Methanol 38 Rxn Extent 5. % Conv. 82.453e-004 -2.07 1* 31 H2O 18.171e-007 5.93 (kgmole/m3) 0.000e-002 5. Volume Flow 69 Aspen Technology Inc.0000 0. MA USA 3 4 5 Case Name: DMEPLANT.000e-002 5.204e-007 47 Acetone 3.088e-007 46 AceticAcid 3.016e-004 44 H2O 3.380 9.014e-004 1.088e-007 2.04 -2 * 30 diM-Ether 46.0000 kJ/h 24 Energy Stream User Variables 25 26 REACTION DETAILS 27 28 Component Molecular Weight Stoichiometric Coefficient 29 Methanol 32.2937 (kg/m3) 12.204e-007 0.028e-004 4.000e-002 59 Elevation (Base) (m) 0.014e-004 Balance 39 40 Total Inflow Total Rxn Total Outflow 41 42 Methanol 2.1 2 LEGENDS Burlington.0000 3.171e-007 48 RATING 49 50 Sizing 51 52 53 Cylinder Vertical Volume --- Diameter 54 No Height --- Nozzles 55 56 Reactor has a Boot: --- 0.0000 m * Base Elevation Relative to Ground Level 57 Diameter --- Height --- 5 6A 6B 58 Diameter (m) 5.

9 (m3/h) 3.0000 (m3/kgmole) 2.27 0. Flow (Std.97 --- 23.29 (kJ/kg-C) 1.0000 0.0000 (dyne/cm) --- 0.674 2.082 56 57 58 59 60 61 62 63 64 65 66 67 68 69 Aspen Technology Inc. Ideal Liq.0000 21.223 1.321e-002 9.0 746. Licensed to: LEGENDS Aspen HYSYS Version 7.0.013 (kJ/kgmole-C) --- --- --- (kJ/kg-C) --- --- --- --- --- --- 0.0000 22 Act.0000 --- 28 Z Factor 0.625e+004 3. Gas Flow (ACT_m3/h) 2. . Liq.013 2.873e+004 3.93 15 Mass Heat Capacity (kJ/kg-C) 2.8 749.127 Cp/Cv 1.000 0.150 1.847e-002 0.7263) Page 71 of 71 * Specified by user.972 14 Heat Capacity (kJ/kgmole-C) 65.601e-002 0.000 0.584e-002 5.404 (kJ/kg) 899.30 --- --- --- 0.0000 1. Vol.044e+004 18 Phase Fraction [Vol.0000 3.3 749.185e-002 2.4232 --- (W/m-K) 3.8 C (atm) 53 True VP at 37.0000 0.3148 (kg/m3) 798. Mass Density (kg/m3) 797.978e+004 2.315e+005 6.625e+004 1.527e+005 6.9821 0.2419 6.000 19 Phase Fraction [Mass Basis] 1. Flow .786 2.9243 --- --- 29 Watson K 10.27 26 Std. MA USA 3 4 5 Case Name: DMEPLANT.8 27 Act.000 20 Partial Pressure of CO2 (atm) 0. 41 Phase Fraction [Molar Basis] 42 Surface Tension 43 Thermal Conductivity 44 Viscosity 45 Cv (Semi-Ideal) 46 Mass Cv (Semi-Ideal) 47 Cv 48 Mass Cv 49 Cv (Ent. Method) 52 Reid VP at 37.93 73.315 16 LHV Vol Basis (Std) (kJ/kgmole) 6.150 (kJ/kgmole) 2.315 2.857e-002 (kJ/kgmole-C) 57.0000 Cp/(Cp .0000 0.0000 0.972 5. 35 Kinematic Viscosity 36 Liq.382 --- 3.0000 21 Cost Based on Flow (Cost/s) 0.436 7.647 3.0000 1.055 2.62 11.0000 0.001 11. Cond) 38 Liquid Fraction 39 Molar Volume 40 Mass Heat of Vap.46 64. Method) 51 Cp/Cv (Ent.0000 3. Density (kgmole/m3) 24. Liq.61 65.127 1.61 (kJ/kg-C) 1.088e-002 (cP) 1.R) 1. Cond) 37 Liq.847e-002 55 Viscosity Index 3.6 1135 1135 1.601e-002 0.36 73.0000 0.0000 1.Sum(Std.48 24 Specific Heat (kJ/kgmole-C) 65.2417 7. Vol.9 746.044e+004 2.055 (kJ/kgmole-C) 53.0000 0.146 1.063 23 Avg.0.953e-003 1.000 --- 1.27 11. Cond) (m3/h) 3. Mass Density (Std.082 6.27 30 User Property 31 Partial Pressure of H2S 32 33 34 Heat of Vap.2 (24.29 64.04 65.1 2 LEGENDS Burlington.93 25 Std. Basis] 1.436 54 Liq.30 11.8 C (atm) 0. Gas Flow (STD_m3/h) 21.466 5.HSC Unit Set: NewUser1 Date/Time: Wed May 23 23:14:35 2012 6 Equilibrium Reactor: ERV-100 (continued) 7 8 9 PROPERTIES 10 11 Name 12 Mass Enthalpy 13 5 6B 6A (kJ/kg) -5995 -5995 -5995 Mass Entropy (kJ/kg-C) 4.527e+005 17 LHV Mass Basis (Std) (kJ/kg) 1.93 73. Flow (m3/s) --- 0.404 3.36 73.047 2.980 (atm) (cSt) 0. Method) 50 Mass Cv (Ent.