12

th
ABCD (Date: 08-05-2011) Review Test-1
PAPER-2
Code-A
ANSWER KEY
CHEMISTRY
SECTION-1
PART-A
Q.1 D
Q.2 B
Q.3 C
Q.4 A
Q.5 D
Q.6 D
Q.7 D
Q.8 B,C
Q.9 A,B,C,D
Q.10 A,B,C,D
Q.11 B,C
Q.12 A,B,C,D
PART-B
Q.1 (A) P,R
(B) P,Q
(C) P,Q,R,S
Q.2 (A) Q,R,T
(B) P,S,T
(C) P
(D) Q,T
PART-C
Q.1 0106
Q.2 0643
Q.3 4000
Q.4 1032
PHYSICS
SECTION-2
PART-A
Q.1 B
Q.2 B
Q.3 D
Q.4 D
Q.5 A
Q.6 D
Q.7 B
Q.8 C
Q.9 A,B
Q.10 A,B
Q.11 D
Q.12 A
PART-B
Q.1 (A) P
(B) R
(C) S
Q.2 (A) P,S,T
(B) Q,S
(C) Q,R
(D) P
PART-C
Q.1 0006
Q.2 0004
Q.3 0010
Q.4 0009
MATHS
SECTION-3
PART-A
Q.1 D
Q.2 D
Q.3 D
Q.4 C
Q.5 C
Q.6 D
Q.7 D
Q.8 A,B,C
Q.9 C,D
Q.10 A,B,D
Q.11 A,B,C
Q.12 A,C
PART-B
Q.1 (A) P, Q
(B) P, R
(C) R, S
Q.2 (A) Q
(B) R
(C) S
(D) Q
PART-C
Q.1 0020
Q.2 0011
Q.3 0006
Q.4 0009
CHEMISTRY
Code-A Page # 1
PART-A
Q.2
[Sol.
1
H H
1
c c
V T V T

=

1 5 / 7
1
c
H
H
c
4
1
V
V
T
T


|
.
|

\
|
=
|
|
.
|

\
|
=
Now, q = 100
%
T
T
1
H
c
|
|
.
|

\
|

=
%
4
1
1 100
5 / 2
(
(

|
.
|

\
|

]
Q.3
[Sol. ]
Q.4
[Sol. (A) & (D) both are Erythreo but (A) is most stable Erythreo form due to intramolecular hydrogen
bonding. ]
Q.6
[Sol. In Benzene, t-electrons are completely delocalised but in borazine t-bonds are formed by Back donation
so it is not delocalised. ]
Q.7
[Sol. Compound is optically inactive due to centre of symmetry]
Q.10
[Sol. (A) For example:
C
Cl
Cl
Cl
Cl

CCl
= 0

net
= 0
CHEMISTRY
Code-A Page # 2
(C) Al [Ne] 3s
2
3p
1
Ga [Ar] 3d
10
4s
2
4p
1
& I.E.
Ga
~
I.E.
Al
due to d-orbitals in Ga having
5.999 5.987 weak shielding effect.
eV/atom eV/atom
(D)
Xe
F
F
F F
F
]
Q.11
[Sol. Acid-base reaction takes place from the siode of strong acid-strong base to weak acid-weak base. ]
Q.12
[Sol. A : N = C = S:
..
..
H C
3
Bent.
B :
H Si N = C = S:
3
+
+
..
+

p d t t
due to pt dt back bonding it is linear..
C :
N C I C N

D :
P
SiH
3
SiH
3
H Si
3
..
pt dt back bonding is absent hence it is pyramidal. ]
PART-B
Q.2
[Sol. (A)
COOK
KOOC


is Electrolys
Compound has plane of symmetry
Double bond equivalent 2
Axis of symmetry C3
(B) CH CH
3
O
Mg(Hg)
H O
2

H H
| |
CH C C CH
| |
OH OH
3 3

Chiral centre = Two
One of the product is = meso
CHEMISTRY
Code-A Page # 3
(C) CH COC H
3 5 2
O
Na
liq. NH
3

3 3
CH CH C CH
| | |
OH O

(D)
FeSO
4
H O
2 2
]
PART-C
Q.1
[Sol. Moles of N
2
=
28
168
= 6 Moles of H
2
=
2
30
= 15
Limiting reagent is H
2
AU = AH An
g
RT
= (24) 5 (2)
5 700
1000
2

= 106 kcal ]
Q.2
[Sol. P
4
O
10
POP bonds = 6
[P
4
O
12
]
4
POP bonds = 4
[P
4
O
13
]
6
POP bonds = 3 ]
Q.3
[Sol. q = AU w = 0 w = w
= | | } 16 32 ( 1 { ) 4 16 ( 2 + = 40 bal-L
= 4000J Ans.]
PHYSICS
Code-A Page # 1
PART-A
Q.1
[Sol. n sin 45 > 1
n >
2
]
Q.2
[Sol.

F
3
=
R 2
2 3

+
R
2
' F
3

=
R
2 3

+
R 2
2
R 2 F
3
=

,
R 2 ' F
3
=

]
Q.3
[Sol. u = oeAT
4
and o
1
e and T are constant

1
2
1
2
A
A
u
u
=
=
2
3
R 4
2 ) R R 2 (
2
2 2
=
t
t + t
]
Q.4
[Sol. c cos u =
n
c
cos |
n cos u = cos |
1 sin u = n sin |
n
2
cos
2
u +
1
n
sin
2
2
=
u
c cos u
C
u
|
C/n
air
glass
| cos
n
c
n
2
n
2
sin
2
u +
1
n
sin
2
2
=
u
sin
2
u
2 2
2
n 1 n
n
1
=
(

sin
2
u =
2
2
n 1
n
+
2
n 1+
1
n
u
sin u =
2
n 1
n
+
tan u = n ]
Q.5
[Sol. z coordinate is inverted
y
z
x
]
PHYSICS
Code-A Page # 2
Q.10
[Sol. o
min
s 30
2
2
60
sin
2
30 60
sin
2
60
sin
2
60
sin
min
=
|
.
|

\
|
|
.
|

\
| +
s
|
|
.
|

\
| o +
=
60
60
2 s
o
max
> 30
i + 90 60 > 30 i > 0
3
2
>
sin 60 > 1 sin 90 ]
Q.11
[Sol. u = 8 v = 3
8
1
u
1
v
1
=

8
1
8
1
3
1
= +

8
1
24
3 8
=

f =
8 . 4
5
24
=
u
v
h
h
0
I
=

8
5
6
h
I
=
10 m
8
3
6
h
I
=
h
I
=
25 . 2
8
18
=
]
Q.12
[Sol.
l
l A
= Y
A
T
y
1
= 2y
2
Al
1
=
2
2
l A
T
1
= T
2
= F
l
l A
o =
A
r
r
=
Ay
T
y o
Ar
1
=
2
r
4
1
A
]
PHYSICS
Code-A Page # 3
PART-C
Q.1
[Sol. AW = 0
AQ = U
f
U
i
)
`

)
`

+ =
2
NRT 5
2
RT 3

3
N 2
2
RT 5
3
N 2
6
NRT
2
NRT 5
3
NRT 8
= =
]
Q.2
[Sol. i sin 90 = sin |
| |
3
8m
x
| = 53
3
x
= tan 53 =
3
4
x = 4
r = 8 x = 4 m ]
Q.3
[Sol. NS = x
|
.
|

\
|

3 / 4
1
1
=
4
x
cm
x
O
5cm
obj. at 5 + x
4
x
= 5 +
4
x 3
Image at 5 +
4
x 3
behind mirror..
Final image = 5 + x
4
x
+ 5 +
4
x 3
= 10 +
2
x 3
= 25 cm
x = 10 cm ]
Q.4
[Sol.
15
10
=
x 10
x

15 cm
B
10 x
u
u
A
x
10 cm
20 2x = 3x
x = 4 9 cm ]
MATHEMATICS
Code-A Page # 1
PART-A
Q.1
[Sol. 2a + b + c = 0 4a + 2b + 2c = 0

0 c c b 2 a 4
) 0 ( f
) 2 ( f
= + + +

As f (0) + f (2) = 0
Either f (0) = 0 = f (2) or f (0). f (2) < 0
Either 0 and 2 are roots or one root lie in (0, 2) of f (x) = 0.
Two real and distinct roots of f (x) = 0 ]
Q.2
[Sol.
2
n
n
n
n
1
1
e
Lim
|
.
|

\
|
+

=
|
.
|

\
|
+

n
1
1 n n
n
n
2
e
e
Lim
l
=
|
.
|

\
|
+

n
1
1 n n n
n
2
e Lim
l
; Put n =
y
1
=
2
y
) y 1 ( n y
0 y
e Lim
+

l
=
2
1
e
=
e
Ans.]
Alternatively: L =
2
n
n
n
n
1
1
e
Lim
|
.
|

\
|
+

ln L =
|
|
.
|

\
|
|
.
|

\
|
+
n
1
1 n n n Lim
2
n
l
Put n =
y
1
, we get ln L =
2
0 y
y
) y 1 ( n y
Lim
+

l
ln L =
2
2
0 y
y
........
2
y
y y
Lim
|
|
.
|

\
|
+

=
2
1
L =
2
1
e = e Ans.]
Q.3
[Sol. For continuity of f at x = c
) x ( f Lim
c x
= f (c) = sin c
ac + b = sin c a =
c
b c sin
Ans.]
Q.4
[Sol. (i), (ii) and (iv) are not derivable number of functions which are not differentiable, is 3 Ans.
Q.5
[Sol. Range of f (x) = tan
1
(3x
2
+ bx + c) is
|
.
|

t
2
, 0
if and only if range of g (x) = 3x
2
+ bx + c is [0, ).
This is possible only when discriminant of the equation 3x
2
+ bx + c = 0 is equal to zero.
i.e. b
2
= 12 c Ans. ]
MATHEMATICS
Code-A Page # 2
Q.6
[Sol. Option (D) is true.
Statement-1 is false because f is not bijective. Ans.]
Q.7
[Sol. sgn (x) + sgn( x) is 0 x e R continuous
Also f (x) = | cos x | + x | x | + | sin x | + | x | + sin | x | is continuous at x = 0
hence f (x) is continuous at x = 0. Hence statement-1 is false.
Obviously Statement-2 is true. Ans.]
Q.8
[Sol. (A)


x 1
x x
x a
e
1
a
2
a Lim
|
|
.
|

\
|
|
.
|

\
|
+ +
|
.
|

\
|

= a
provided a > e as in this case
x
a
2
|
.
|

\
|
0 and
x
a
e
|
.
|

\
|
1 as
x
1
0 x
2 Lim

1
a e [e, ) (A) is correct.
(B) If L = 2e then a is {2e}
(C) If L = e then e
x
1
x x
x
1
e
a
e
2
e Lim
|
|
.
|

\
|
+
|
.
|

\
|
+
|
.
|

\
|

= e, provied 0 < a s e
(D) If L = 2a then 2a
x
1
x x x
x a 2
e
2
1
a
1
Lim
|
|
.
|

\
|
|
.
|

\
|
+
|
.
|

\
|
+
|
.
|

\
|

= 2a, provided
a 2
e
= 1 a =
2
e
]
Q.9
[Sol. Let
|
o
= +
4
\
/
0 a x 6 x
2
and
| o
= +
3
/\
0 6 cx x
2
.
Now, o + 4| = 6 and 4o| = a
o + 3| = c and 3o| = 6
We get o| = 2 a = 8.
So, the first equation is
x
2
6x + 8 = 0 x = 2, 4
If o = 2 and 4| = 4, then | = 1.
If o = 4 and 4| = 2, then | =
2
1
3| =
2
3
, which is non-integer..
The common root is 2. Ans.]
MATHEMATICS
Code-A Page # 3
Q.10
[Sol. cos x = tan y =
z tan
z tan 1
2

=
( )
x tan
x tan 1
x tan
x tan 1
1
2
2
2

cos x =
x tan 1
1 x tan 2
2
2

1
y
tan z
1 tan z
2
1
z
tan x
1 tan x
2
cos
2
x (1 tan
2
x ) = 2 tan
2
x 1
cos
2
x sin
2
x = 2 tan
2
x 1 2 cos
2
x = 2 tan
2
x cos
2
x = tan
2
x
sin
2
x = cos
4
x sin
2
x = (1 sin
2
x)
2
sin
4
x 3sin
2
x + 1 = 0
sin
2
x =
2
5 3
=
2
5 3
=
4
5 2 6
(positive not possible)
sin x = sin y = sin z =
2
1 5
>
2
1
A, B, D. Ans.]
Q.11
[Sol. Graph of y = g(x)
From the graph it is clear that
(A) range of g(x) is [ 4, )
(B) | | 1 ) x ( g Lim
0 x
=

2
1
1 2 3
2
2
2
1
1
x
g (x)
4
4
O
(C) g(x) is continuous at x = 0
(D) g(x) is continuous at x =
2
3
but discontinuous at x =
2
3
options (A), (B), (C) are correct. Ans.]
Q.12
[Sol.(A) Let h(x) =
) x ( g
) x ( f
be continuous at x = a. Also given g(x) is continuous at x = a.
Hence h(x) g(x) = f(x) must be continuous at x = a but given f(x) is discontinuous at x = a.
Hence our assumption is false h(x) must be discontinuous.
(B) False because f(x) can be discontinuous in [a, b].
(C) Obviously true.
(D) D is false. Example sgn (cot
1
x) at x = 0 is continuous and (cot
1
x) is also continuous at x = 0. But
sgn (x) is discontinuous at x = 0. Ans.]
MATHEMATICS
Code-A Page # 4
PART-B
Q.1
[Sol.
(A) f (x) = (x + 1) | x 1| =

<
>
1 x ; x 1
1 x ; 1 x
2
2
(B) f (x) = min. (| x |, 1| x |)
|||||
||||||
||||||
||||||||
||||||||||||
|||||||||
|||||
|||||||||
||||||
|||
|||||||
|||||||
||||||||
(C) f (x) = { x }+ 2 [ x ] = x + [ x ]
At x e I ,
L.H. L = I + (I 1) = 2 I 1
RH.L. = I + I = 2I = f (I)
Not continuous, hence not differentiable at integral points.]
Q.2
[Sol.
(A) Let first term of G.P. be a and common ratio is r.
Now,
( )
625
r 1
r 1 a
201
=

...................................(1)
Also,
=
201
0 i
201 2 1 i
a
1
..... ..........
a
1
a
1
a
1
+ + + =
=
200 2
ar
1
........ ..........
ar
1
ar
1
a
1
+ + + +
=
|
.
|

\
|

|
|
.
|

\
|

|
.
|

\
|
1
r
1
1
r
1
a
1
201
=
a
1

|
|
.
|

\
|

r 1
r 1
201
.
200
r
1
=
200
r
1
a
625
a
1

(using (1)) =
( )
( )
625
625
a
625
ar
625
2
101
2
100
= =
= 1 Ans.
MATHEMATICS
Code-A Page # 5
(B) Consider |
.
|

\
|
+ +

bx x ax x Lim
2 2
x
( )
Rationalisation,
bx x ax x
x ) b a (
Lim
2 2
x
+ + +


=
x
Lim
(

+ + +

x
b
1
x
a
1 x
x ) b a (
=
2
b a
= 2
(a b) = 4 .........(1)
Now,
2 2
a x
a x
b a b x
Lim

=
b a a 4
1

=
64
1

4 a 4
1
=
64
1

a 8
1
=
64
1
a = 8 and b = 4 a/b = 2 Ans.]
(C) We have
x
2
2mx + m
2
1 = 0
(x m)
2
1 = 0 (x m + 1) (x m 1) = 0
x = m 1, m + 1
Now, 2 < m 1 and m + 1 < 4.
1 < m < 3. Ans.
(D) Clearly, f(x) =
( )

|
.
|

\
| t
e =
(

\
| t
e
2
, 0 x ; x x
0 ,
2
x ; x tan
O
x
t
2
t
2

y = f (x)
Number of points of non-differentiability of f (x) is 1 i.e. x = 0 ]
PART-C
[INTEGER TYPE]
Q.1
[Hint: l
1
=
12
2
; l
2
=
12
6
; l
3
=
12
6
; l
4
=
12
4
; l
5
=
12
1
]
Q.2
[Sol. The equation of the parabola can be taken as
y = m
2
4
1
x
|
.
|

\
|

8
9
(given that minimum value is
8
9
when x =
4
1
)
or y = m
8
9
2
x
16
1
x
2

|
.
|

\
|
+
or y =
8
9
16
m
x
2
m
mx
2
+ .....(1)
Comparing equation (1) with y = ax
2
+ bx + c,
Hence a = m, b =
2
m
and c =
8
9
16
m

But a + b + c is an integer
8
9
16
m
2
m
+ =
16
18 m 9
is an integer..
If a + b + c = 0 m = 2
MATHEMATICS
Code-A Page # 6
If a + b + c = 1 m =
9
2
If a + b + c = 2 m =
9
14
which is negative
Hence minimum positive value of coefficient of x
2
which is m =
9
2
p = 2 and q = 9
Hence (p + q) = 11. Ans.]
Q.3
[Sol.
[ [
= =

=
|
|
.
|

\
|

n
1 k
n
1 k
2
k
2 2
k
2
k
2
a
d a
a
d
1 =
( ) ( )
[
=
+
n
1 k k
k
k
k
a
d a

a
d a
=
[
=
+
n
1 k k
1 k
k
1 k
a
a

a
a
(

= +
=
+

1 k k
1 k k
a d a
a d a
=
|
|
.
|

\
|

n
1 n
2
1
1
0
a
a
......
a
a

a
a

|
|
.
|

\
|
+
n
1 n
2
3
1
2
a
a
......
a
a

a
a
=
|
|
.
|

\
|
|
|
.
|

\
|
+
1
1 n
n
0
a
a
a
a
=
|
|
.
|

\
|
|
|
.
|

\
|
+
n
1 n
1
0
a
a
a
a
[but a
0
= a
1
d]
=
|
|
.
|

\
| +
|
|
.
|

\
|
n
n
1
1
a
d a
a
d a
=
|
|
.
|

\
|

1
a
d
1
|
|
|
|
|
.
|

\
|
+
+


n as zero
1
d ) 1 n ( a
d
1 =
1
a
d
1
but
4
1
a
d
1
1
=

1
a
d
4
3
=

d
4
3 8
=
Hence d = 6. Ans.]
Q.4
[Sol. Subtracting equation (2) from (1), common roots are the roots of x
2
+ q r = 0 which has two roots say
x
1
& x
2
such that x
1
+ x
2
= 0
x
1
+ x
2
+ o = 2 and x
1
+ x
2
+ | = 1
o = 2, | = 1
L.H.L. =
) h 1 ( n
3 n
h
0 h
e Lim

l
l
= e
ln 3
= 3 f (0

) = f (0) = a = 3
R.H.L. =
|
.
|

\
|
+
|
.
|

\
|
+ +

h 2 1 e
h 2 1 e 1 n
Lim b
2
2
h
h
0 h
l

h
h 2 1 e
2
h
|
.
|

\
|
+

h tan
h
= 2b b =
2
3
Hence 2(a + b) = 9 Ans.]