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Revision Date: 08/25/2004 Z17000000146/Version: 1.1 Print Date: 10/13/2005 Page: 1/6
1. Identification of the substance/preparation and of the company/undertaking
Product name: KODAK MEDICAL X-RAY LIQUID FIXER, MX 1764-6, Part A Product code: 10080754 - Part A Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York 14650; KODAK CANADA INC., 3500 Eglinton Avenue W., Toronto, Ontario, M6M 1V3 For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA) For other information or to request an MSDS, call (800) 242-2424. Synonyms: PCD 6444
2. Hazards identification
CONTAINS: Ammonium thiosulphate (7783-18-8), Ammonium sulphite (10196-04-0), Acetic acid (64-197), Sodium bisulphite (7631-90-5) WARNING! MAY BE HARMFUL IF SWALLOWED. CAUSES EYE IRRITATION DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT. MAY LIBERATE SULFUR DIOXIDE HMIS II Hazard Ratings: Health - 2, Flammability - 1, Reactivity (Stability) - 0 NFPA Hazard Ratings: Health - 2, Flammability - 1, Instability - 0 NOTE: HMIS II and NFPA hazard indexes involve data review and interpretation that may vary among companies. They are intended only for rapid, general identification of the magnitude of the potential hazards. An asterisk (*), in the HMIS II health field, designates potential chronic or target organ hazards. To adequately address safe handling, ALL information in this MSDS must be considered.
3. Composition/information on ingredients
Weight % 45 - 50 39 5 - 10 3 1- 5 1- 5 Components (CAS-No.) Water (7732-18-5) Ammonium thiosulphate (7783-18-8) Sodium thiosulphate (7772-98-7) Ammonium sulphite (10196-04-0) Sodium acetate (127-09-3) Acetic acid (64-19-7)
clothing). Hazardous Combustion Products: Carbon oxides. Reacts violently with oxidizing materials. organic compounds containing reducible functional groups. Ensure adequate ventilation. Get medical attention if symptoms persist. sulfur oxides (see also Hazardous Decomposition Products section). nitrogen oxides (NOx). Ingestion: Drink 1-2 glasses of water. paper. rags.) . 6. Fire or excessive heat may produce hazardous decomposition products. sawdust. move to fresh air. Prevention of Fire and Explosion: Keep from contact with oxidizing materials. Accidental release measures Methods for cleaning up: Collect in a noncombustible container for prompt disposal. porous material (e. Keep away from incompatible substances (see Incompatibility section. cotton. Get medical attention. Remove and wash contaminated clothing promptly. carbon dioxide (CO2). Get medical attention if symptoms occur. immediately flush eyes with plenty of water for at least 15 minutes. Storage: Store in original container. Flush with plenty of water. Eyes: In case of contact.1 Print Date: 10/13/2005 Page: 2/6 1. highly oxygenated or halogenated solvents. May cause spontaneous heating and ignition when absorbed on combustible. Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing. Skin: Wash off with soap and water. Unusual Fire and Explosion Hazards: Dried product residue can act as a reducing agent. Clean surface thoroughly to remove residual contamination. Never give anything by mouth to an unconscious person. Flush into sewer with plenty of water. Keep container tightly closed to prevent the loss of water. 7. Wash thoroughly after handling. 5. First aid measures Inhalation: If symptomatic. Fire-fighting measures Extinguishing Media: water spray. alcohol-resistant foam.5 Sodium bisulphite (7631-90-5) 4. dry chemical. Handling and storage Personal precautions: Avoid breathing mist or vapour at concentrations greater than the exposure limits.MATERIAL SAFETY DATA SHEET Revision Date: 08/25/2004 Z17000000146/Version: 1. For Large Spills: Flush with plenty of water.g. Seek medical attention. Treat symptomatically. Avoid contact with eyes and prolonged or repeated contact with skin.
closed systems.6 Volatile fraction by weight: 45 .0 °C (68.0 °F)) : 24 mbar (18. If respirators are used.1 Print Date: 10/13/2005 Page: 3/6 8. A respirator should be worn if hazardous decomposition products are likely to be or have been released. Ventilation rates should be matched to conditions. Recommended Decontamination Facilities: Safety shower. 9.31 Vapour pressure (at 20. Respirator type: Acid gas. an approved respirator must be worn. Supplementary local exhaust ventilation. Respiratory protection: If engineering controls do not maintain airborne concentrations below recommended exposure limits. Skin and body protection: It is a good industrial hygiene practice to minimize skin contact. Wear impervious gloves and protective clothing appropriate for the risk of exposure. Eye protection: Wear safety glasses with side shields (or goggles). washing facilities as appropriate to condition of use. Physical and Chemical Properties Physical form: liquid Colour: light yellow Odour: acetic acid Specific gravity: 1.0 °F) Water solubility: complete pH: 5.0 °C (> 212. Respirator type: full-face organic vapour cartridge.0 mm Hg) Relative vapour density: 0. a program should be instituted to assure compliance with OSHA Standard 29 CFR 1910.50 % Boiling point/range: > 100.MATERIAL SAFETY DATA SHEET Revision Date: 08/25/2004 Z17000000146/Version: 1. or respiratory protection may be needed in special circumstances. Ventilation should be sufficient so that applicable occupational exposure limits are not exceeded. eye wash.4 . Exposure controls / personal protection Occupational exposure controls Chemical Name Acetic acid Regulatory List ACGIH ACGIH OSHA Z1 ACGIH Value Type Time Weighted Average (TWA): Short Term Exposure Limit (STEL): PEL: Time Weighted Average (TWA): Value 10 ppm 15 ppm 10 ppm 25 mg/m3 5 mg/m3 Sodium bisulphite Ventilation: Good general ventilation should be used.134.
faintness. Hazardous decomposition products: ammonia. Incompatibility: Acids. In contact with strong acids or if heated. Some asthmatics or hypersensitive individuals may experience difficult breathing. Contact with base liberates flammable material. Contact with strong acids liberates sulphur dioxide. weakness and diarrhea. 12. Hazardous Polymerization: Hazardous polymerisation does not occur.1 Print Date: 10/13/2005 Page: 4/6 Flash point: None. sodium hypochlorite (bleach). Toxicological information Effects of Exposure Inhalation: Expected to be a low hazard for usual industrial or commercial handling by trained personnel. Eyes: Causes irritation. oxidizing agents. cases of human skin sensitization have been reported.MATERIAL SAFETY DATA SHEET Revision Date: 08/25/2004 Z17000000146/Version: 1. Contact with sodium hypochlorite (bleach) may form chloramine (toxic gas). Contact with base liberates ammonia. 10. Stability and reactivity Stability: Stable. Some asthmatics or sulfite-sensitive individuals may experience wheezing. sulphites may liberate sulphur dioxide gas. halogenated compounds. stomach upset. strong bases. Potential Toxicity: Fish LC50: Daphnid EC50: Algal IC50: Waste treatment organisms EC50: Organics Readily Degradable: Potential Bioaccumulation: > 100 mg/l > 100 mg/l > 100 mg/l > 100 mg/l Readily biodegradable log Pow < 1 . however. chest tightness. Ingestion: May be harmful if swallowed. 11. Skin: This material has a low potential to cause allergic skin reactions. Sulphur dioxide gas is irritating to the respiratory tract. hives. chloramine. Ecological information The following properties are ESTIMATED from the components of the preparations.
Sodium bisulphite (7631-90-5) WARNING! MAY BE HARMFUL IF SWALLOWED. provincial. Other information US/Canadian Label Statements: CONTAINS: Ammonium thiosulphate (7783-18-8). state. MAY LIBERATE SULFUR DIOXIDE Keep container tightly closed to prevent the loss of water. Regulatory information U.MATERIAL SAFETY DATA SHEET Revision Date: 08/25/2004 Z17000000146/Version: 1. Transport information Not regulated for all modes of transportation. 14. Since emptied containers retain product residue. For transportation information regarding this product call the Kodak Worldwide Transportation Hazmat Hot Line: (585) 722-2400 between 8 a. 65: none Carcinogenicity Classification (components present at 0. California Prop. Consult state or local regulatory authorities before flushing to sewer with large amounts of water. Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372: Ammonium thiosulphate (as a source of aqueous ammonia). Occupational Safety and Health Administration (OSHA): none Chemical(s) subject to the reporting requirements of U. Ammonium sulphite (as a source of aqueous ammonia) 16. 15. (Eastern Standard Time).S.m. or disposal is subject to national. . Monday through Friday. or municipal laws.1 Print Date: 10/13/2005 Page: 5/6 COD (approximate): BOD (approximate): 360 g/l 290 g/l 13. In Canada: General Shipping Information. call: (416) 766-8233.S.S. Acetic acid (64-19-7).) U.m.1% or more): International Agency for Research on Cancer (IARC): Sodium bisulphite: 3 (not classifiable as to carcinogenicity to humans). and 5 p.S. National Toxicology Program (NTP): none U. Ammonium sulphite: 3 (not classifiable as to carcinogenicity to humans) American Conference of Governmental Industrial Hygienists (ACGIH): Sodium bisulphite: Group A4 (Not classifiable as a human carcinogen. Disposal considerations Discharge. treatment. follow label warnings even after container is emptied. Ammonium sulphite (10196-04-0). CAUSES EYE IRRITATION DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT.
1 Print Date: 10/13/2005 Page: 6/6 Keep from contact with clothing and other materials. S-2. Remove and wash contaminated clothing promptly. alcohol-resistant foam. IN CASE OF SPILL: Flush with plenty of water. R-1. Keep out of reach of children. For additional information. The information relating to the working solution is for guidance purposes only. seek medical advice. dry chemical or carbon dioxide. FIRST AID: If swallowed. follow label warnings even after container is emptied. and is based on correct mixing and use of the product according to instructions. Never give anything by mouth to an unconscious person.MATERIAL SAFETY DATA SHEET Revision Date: 08/25/2004 Z17000000146/Version: 1. Get medical attention. IN CASE OF FIRE: Use water spray. Ensure adequate ventilation. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use and disposal of these materials and the safety and health of employees and customers and the protection of the environment. C-1 . In case of eye contact. immediately flush eyes with plenty of water for at least 15 minutes. F-1. Since emptied containers retain product residue. Wash thoroughly after handling. see Material Safety Data Sheet (MSDS) for this material. The information contained herein is furnished without warranty of any kind. Avoid breathing mist or vapour. Avoid contact with eyes and prolonged or repeated contact with skin.
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