7/25/2010

Manila Review Institute, Inc. Chemical Engineering Review

DISTILLATION
Dr. Servillano Olano, Jr.

25 July 2010

Servillano Olano, Jr.

1

Theory and Equations

Phase Equilibria in Distillation Gibbs Phase Rule A = more volatile B = less volatile For binary system: TA < TB pA > pB

φ=2–2+2=2

Two degrees of freedom is needed to define equilibrium, e.g. specifying temp and press will fix the compositions specifying pressure and composition will fix temperature, etc

25 July 2010

Servillano Olano, Jr.

2

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7/25/2010 25 July 2010 Servillano Olano. 20 10 . Jr. 19 Next 25 July 2010 Servillano Olano. Jr.

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