important problems from De Hoff

Attribution Non-Commercial (BY-NC)

1.0K views

important problems from De Hoff

Attribution Non-Commercial (BY-NC)

- Thermodynamics 2011
- Assign 5 Solutions
- Assign 2 Solutions
- Assign 3 Solutions
- Metallurgical Thermo Dynamics
- Solution 4
- Assignment 1 Soln
- Met05011_41_80
- MSE 308 Problem Set 12 Solutions
- 278981_Ragone Solution Manual From Nanyang University
- Gaskell Manual Solution (4th Edition)
- 05_1113_01_MS_tcm143-409119
- thermodehoff04
- ProblemSet8_solutionscomplete
- Lab. DSC and Phase Diagrams (1)mm
- chem hw solutions
- MSE 308 Problem Set 10 Solutions
- Metallurgical Thermo Dynamics9 r h Tupkary
- MSE 308 Problem Set 11 Solutions
- Phase-Transformations-in-Metals-and-Alloys-solutions--.pdf

You are on page 1of 2

An empirical equation for the excess Gibbs energy of liquid Ag[1]-Cu[2] alloy is Gex = - R (2100 + 0.511 T) x1 x2. Derive the equations for Hex, Sex, 1, 2 and compute 1 and 2 at 1550 K and x2 = 0.5 2. The activity coefficient of Zn in liquid Zn Cd alloy at 700 K is given by ln zn = 0.875 X2cd 0.30 X3cd Derive the expression for ln cd on composition and calculate the Gibbs free energy of mixing for Xcd = 0.4 at 700 K. 3. CaO and MgO form solid solutions with limited solubility. Assuming that the solutes obey Henrys law with CaO = 12.88 and MgO = 6.23, calculate the solubility of CaO in MgO and MgO in CaO. 4. Melts in the system Pb-Sn exhibit regular solution behaviour. At 473 C, apb = 0.055 in a liquid solution of Xpb = 0.1. Calculate the value of the aoL and find the activity of Sn in a liquid solution of Xsn = 0.5 at 500 C. 5. The Gibbs free energy of mixing of a solid solution is given by Gmix = 10,600 X1 X2 + RT [X1 ln X1 + X2 ln X2] Calculate the critical temperature Tc for phase separation. Calculate the spinoidal and the phase boundary at 0.7 Tc. 6. Ge-Si forms an isomorphous system with complete solid and liquid solutions. The melting points of Ge and Si are 1200 oC and 1680 oC respectively. At 1475 oC, the liquidus and solidus compositions are respectively, XSi = 0.32 and XSi = 0.665. Assuming the both the solid and liquid solutions are ideal solutions, estimate the values of heat of fusion of Ge and Si. 7. A (TmA= 1400 K) and B (TmB=1000 K) form a eutectic and their Heats of Fusion are 3200 and 2500 cals/mol respectively. At 1200 K, solubility of B in solid A, XBS = 0.05 and in liquid XBL = 0.40. At 600 K, the solubility of A in solid B is 0.07 and of B in solid A is 0.03. Find the activity coefficient of A and B at 600 K and of B in solid A at 1200 K. Assume the liquid to be an ideal solution. 8. The excess gibbs free energy for the Fe-Ni liquid solution is given by the expression

Gex = (-4100 + 0.8 T) x1 x2 J/mol. Calculate the values for Hex, Sex and compute 1 and 2 at 1800 K and x2 = 0.5 9. Two elements A and B (or 1 and 2) form complete solutions in both the solid [] and liquid [L] phases. Two calculate the phase diagram, it is necessary to compare the Gibbs free energy of mixing of both the solutions. Assume that both the solutions are regular solutions. Formulate the equations for Gibbs free energy of mixing of both the solutions assuming that the reference state is {L,L}

- Thermodynamics 2011Uploaded byleongpingchow
- Assign 5 SolutionsUploaded byAnshu Kumar Gupta
- Assign 2 SolutionsUploaded byAnshu Kumar Gupta
- Assign 3 SolutionsUploaded byAnshu Kumar Gupta
- Metallurgical Thermo DynamicsUploaded bypahnin
- Solution 4Uploaded byAnshu Kumar Gupta
- Assignment 1 SolnUploaded byAlbert_LZK
- Met05011_41_80Uploaded byDaniel Alvarez Vega
- MSE 308 Problem Set 12 SolutionsUploaded byAnshu Kumar Gupta
- 278981_Ragone Solution Manual From Nanyang UniversityUploaded byRijalCok
- Gaskell Manual Solution (4th Edition)Uploaded bySeungho_Jeong_1514
- 05_1113_01_MS_tcm143-409119Uploaded byDương Ngọc Cường
- thermodehoff04Uploaded byposhalin17
- ProblemSet8_solutionscompleteUploaded byAnshu Kumar Gupta
- Lab. DSC and Phase Diagrams (1)mmUploaded byKevin Cruz
- chem hw solutionsUploaded byabdulrehman786
- MSE 308 Problem Set 10 SolutionsUploaded byAnshu Kumar Gupta
- Metallurgical Thermo Dynamics9 r h TupkaryUploaded byRahul Pandey
- MSE 308 Problem Set 11 SolutionsUploaded byAnshu Kumar Gupta
- Phase-Transformations-in-Metals-and-Alloys-solutions--.pdfUploaded bysantasatana
- Gaskell HalUploaded byarcher1638
- Aquatic Solution ChemistryUploaded bygoroti
- Introduction to the Thermodynamics of Materials 4e GaskellUploaded byEvan Steadman
- MSE 308 Problem Set 5 SolutionsUploaded byAnshu Kumar Gupta
- Handout6Uploaded bycoppernitrate
- Entropy and EquilibriumUploaded bySJen
- Chemical Equilibrium by Gibbs Energy Minimization on SpreadsheetsUploaded bykaarevalom
- Introduction to the Thermodynamics of Materials - Gaskell 4taEd.pdfUploaded byJeevan Vajha
- Lec. 1 Solubility and Distribution PhenomenaUploaded byFiqri VengeanceHaner
- nadroparina-calcica-identificareUploaded byMaria Cârlan

- Rubber tireUploaded byRajveer Fandan
- Module 4Uploaded byRajveer Fandan
- Module 5Uploaded byRajveer Fandan
- Seminar ListUploaded byRajveer Fandan
- Lecture 4Uploaded byRajveer Fandan
- M.a.pscschemeUploaded byRajveer Fandan
- format for thesis of IIT BombayUploaded bysummerrao
- 1-s2.0-S0167931707002286-mainUploaded byRajveer Fandan
- TiresUploaded byRajveer Fandan
- Octave LinuxUploaded byRajveer Fandan
- quiz1-98Uploaded byRajveer Fandan
- Serial KeyUploaded byRajveer Fandan
- EldUploaded byRajveer Fandan
- SchrodingerUploaded byRajveer Fandan
- DiffusionUploaded byRajveer Fandan
- James-Quantum-Dots-Seminar.pptUploaded byPhuong Thai
- jp806791sUploaded bysofsof79
- Prepaid Energy MeterUploaded byRajveer Fandan
- EldUploaded byRajveer Fandan
- BisectorUploaded byRajveer Fandan
- 88.Automatic Power Failure Indication System for Domestic and Commercial UseUploaded byRajveer Fandan
- 3 a High Performance Induction Motor Drive SystemUploaded byMachiraju Viswanath
- 121G522FChallan (1)Uploaded byǺmįt Kumąr
- TPS ReportUploaded byRajveer Fandan
- Academic Calander 2011 12Uploaded byRajveer Fandan

- (EM0114-03-M) Performance Data G3520CUploaded byVictor Cipriani
- Manual TLC200ProUploaded byRicardo Lozano Del Valle
- Deh-2300ub Manual en Fr It Es de Nl RupdfUploaded byfalko
- Esa TrevUploaded byPeejay Ollabrac
- Microcor Transmitter MT-9485-Man Rev NCUploaded byvladimir198405
- Pds Staad-foundation-Advanced Ltr en LrUploaded byLava Sat
- Compositional and Functional Properties of ButtermilkUploaded bykumaranprasad
- CONG NGHE SAN XUAT DAU BOI TRON .pdfUploaded byMinh Hai Rung
- Actuadores de ValvulasUploaded byPedro Elias Castro Arenas
- 2003 Service Manual Magura HS33Uploaded bydrishk
- ContourUploaded byMangam Rajkumar
- Ss7 TutorialUploaded byarifbudianto
- Evolution of Modern AircraftUploaded bysearchtyagi
- Ethics Activity 2_answerUploaded byJonathan Robregado
- Phocos Datasheet Inverter-1000 2000W e WebUploaded byRedHammer
- 01_IT110-Intro1Uploaded byDonna Hernandez
- Sitecore Serialization GuideUploaded byAniteja Kota
- Tutorial 3 _questions Only_PVT Behavior_Ideal Gas_Virial EOSUploaded byMihir Kumar Mech
- resorsinolUploaded byAlvitaWidyastuti
- JetUploaded byChandru S
- MS16 Yaya Kumandalı İstif MakinalasıUploaded bymehmetaliozgur
- Duke-Energy-Carolinas,-LLC-Schedule-PG---Parallel-GenerationUploaded byGenability
- Protection Unit DMX3Uploaded byvvlike767
- 10987C_TrainerPrepGuideUploaded byAyamin
- human detecting robot structure.pdfUploaded bychirayilrichard
- ISOPHORONE.docxUploaded bysandeep
- TDA8946J reemplazo tfa9844j.PDFUploaded byAndres Alegria
- 5b. Kenzo TangeUploaded byHerseya Tags
- 7. Power Plant.pdfUploaded byshaito
- Produk AC Dan SparepartUploaded byMuhammad Arief Rahman

## Much more than documents.

Discover everything Scribd has to offer, including books and audiobooks from major publishers.

Cancel anytime.