1B 2B 3A 4C 5B 6D 7C 8B 9B 10 C

11 B 12 C 13 A 14 B 15 C 16 C 17 A 18 C 19 A 20 D

21 D 22 A 23 A 24 D 25 D 26 A 27 D 28 C 29 B 30 C

31 D 32 A 33 B 34 C 35 D 36 C 37 C 38 C 39 A 40 B

Section A

A1 (a) (i) A copper;

(ii) B copper (II) oxide;
(iii) C copper (II) sulphate;
(iv) D carbon dioxide; [4]
(b) Neutaralisation;
(c) Transistion;
(d) zinc; a more reactive metal than copper can displace it from copper (II)
sulphate solution;
(e) CuSO4 + Zn  Cu + ZnSO4; [5]

A2 (a) (i) aluminium, iron;

(ii) fluorine, chlorine;
(iii) magnesium and fluorine;
(iv) carbon and chlorine or fluorine
(v) chlorine, fluorine; [5]
(b) Drawing consists of magnesium ion circle with 8 crosses and charge 2+;
Fluoride or chloride ions two circles of 7 dots and one cross and one
negative
charge. [2]

A3 (a) bromine gas or chlorine gas or nitrogen dioxide gas; [1]

(b) (i) by photochemical reaction between nitrogen dioxide and oxygen gas;
(ii) It produces peroxyacyl nitrates PAN – photochemical smog which
causes tearing of the eye or in high concentration triggers asthmatic
attacks; [2]
(c) Describes energy being absorbed during a reaction; [1]

1
 (d) The energy absorbed in breaking the oxygen bonds; is greater; than the
energy evolved in the forming bonds to give ozone [2]
(e) PbS(s) + 2O3(g)  PbSO4(s) + O2(g) ;
lead (II) sulphide is oxidized to PbSO4; when the oxidation state of S is
increased from – 2 to + 6; [3]

A4 (a) potassium sulphate;

(b) 4OH –  2H2O + O2 + 4 e – ;
(c) copper will be oxidisied to copper(II) oxide by oxygen gas liberated at the
anode;
(d) (i) CUSO4:no hydrogen gas but metal copper will be deposited at the
cathode;
(ii) NaI:no oxygen gas but iodine vapour will be liberated at the anode;
[5]

A5 (a) 1mol citric acid + 3moles KOH  1mol potassium citrate + 3mol water;

Structure of sodium citrate: the three acidic H are replaced by three

potassium atoms; [2]

(b) 1mol citric acid reacts with 3 mols potassium hydroxide

0.0350 mol citric acid reacts with 0.105 mols of KOH;
M x V = 0.105 mol KOH
V = 0.105/0.1 = 1.05 dm3 KOH; [2]

(c) H+ + OH -  H2O; [1]

A6 (a) In paraffin oil; [1]

(b) (i) 2Q + Cl2  2QCl; [1]
(ii) Vigorous reaction of white flash of light; white fumes condensed
as white solid on side of vessel; [2]
(c) by electrolysis of molten Q chloride; using carbon electrodes; [2]
(d) vigorous reaction o Q darting about on the surface of the solution or
effervence; and a blue precipitate forms; [2]

A7 (a) Addition; [1]

(b) poly(methyl methacrylate); [1]
H CH3 H CH3 H CH3
I I I I I I
(c) - C – C – C – C – C – C – [2]
I I I I I I
H H H H H H
(d) Mr methylmethacrylate = 100;
No. of monomers = 960000 / 100 = 9600; [2]

2
 (c) the polymermer does not shatter like glass in a crash; [1]
Section B

B8 (a) (i) n = 2; because the percentage of C in C2H6O = 24/46 x 100%

= 52.2% [1]
(ii) the isomers are propan- 1-ol; and propan -2-ol;
all covalent bonds must be shown [2]

(b) Crack heptane using catalyst at a high temperature;

Addition reaction between propene and steam;
Phosphoric acid (catalyst), at 300 oC, 70 atmospheres;
C7H16  C3H6 + C4H10;
C3H6 + H2O  C3H7OH; [5]

(c) Add silver nitrate solution follow by nitric acid;

HCl gives a white precipitate but not ethanoic acid; [2]

B9 (a) (i) 1:14.3

(ii) After travelling for a distance, the car engine is hot; nitrogen and oxygen
from the air for reacting with the fuel in the engine, react to form nitric
oxide;
(iii) nitrogen and carbon dioxide;
2NO + 2CO  2CO2 + N2; [5]

(b) (i) Na+, OH-, H+;

(ii) H2 + 2OH -  2H2O + 2 e- ; (iii)
oxidation, as there is a loss of electrons;
(iv) in order to balance the flow of electrons leaving and entering the cell
the overall reaction is: 2H2 + O2  2H2O
two volumes hydrogen and one volume of oxygen must be fed into the
cell;
(v) 2.4 dm3 hydrogen; [5]

3
Either
B10 (a) The blue colour of copper (II) sulphate solution will fade or turn colourless;
Zn will be coated with a layer of brown substance;
The rod AB will dip at B; [3]

(b) (i) aluminium and iron(III) oxide; [1]

(ii) the mixture will turn red hot or molten brown liquid form;
a white ash will also form; [2]
(iii) magnesium oxide and copper; [1]
(iv) add excess sulphuric acid to dissolve all magnesium oxide;
filter the mixture to collect copper (residue);
rinse the copper with distilled water to remove soluble insolubilities. [3]

Or
B11 (a) Catalyst – a substance that increases the rate of a reaction but remains
chemically unchanged;
It also lowers the activation energy of a reaction, so that many more
molecules can react at a lower energy; [2]

(b) Increase in temperature increases the KE of the reacting molecules and

they move at higher speed;
the molecules will hence collide more frequently and more forcefully
leading to a rise in the rate of reaction; [2]

(c) NO – double the concentration, increases the rate four times;

CO – increase in concentration does not increase the rate;
O2 – increase in concentration does not incrase the rate; [3]

(d) Zinc displaces copper from copper (II) sulphate

The copper deposited on the zinc surface acts as a catalyst;
Zn + CuSO4  Cu + ZnSO4
1.00g of Zn = 1/65 mol, 5 g of CuSO4 = 5/160
CuSO4 will be in excess;
all zinc will be reacted completely, and none left for reaction with the
sulphuric acid; [3]