SO
2
(g) +Cl
2
(g) is attained at 25 C in a closed container and an inert gas,
helium, is introduced. Which of the following statement is correct ?
(A) Concentrations of SO
2
, Cl
2
and SO
2
Cl
2
change
(B) More Cl
2
is formed
(C) Concentration of SO
2
is reduced
(D) None of these
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3. The decomposition of N
2
O
4
into NO
2
is carried out at 280K in chloroform. When equilibrium has been
established 0.2 mole of N
2
O
4
and
3
2 10
mole of NO
2
are present in 2 litres of solution. The equilibrium
constant for the reaction
2 4 2
N O 2NO
is :
(A)
2
1 10
(B)
3
2 10
(C)
5
1 10
(D)
5
2 10
4. If pressure is applied to the equilibriumsystemof solid
)
(A) 8.73 (B) 9.08 (C) 9.43 (D) 11.72
6. K
a
for hydrofluoric acid is
4
6.9 10
. What is K
C
for this reaction ?
( )
2
F (aq) H O( ) HF aq OH (aq)
+ +
(A)
11
6.9 10
(B)
11
1.4 10
(C)
9
2.6 10
(D)
6
8.3 10
7. The dissociation constant K
a
of a weak monobasic acid is
7
10
A mixture initially containing one mole of each of CO and steamis allowed to reach equilibrium. How many
moles of CO are now present ?
(A) 1/4 (B) 1/3 (C) 1/2 (D) 2/3
9. One mole of a compound AB reacts with one mole of a compound CD according to the equation,
AB CD AD CB + +
. When equilibriumhad been established, it was found that 3/4 mole each of reactant
AB and CD had been converted to AD and CB. There is no change in volume. The equilibrium constant for the
reaction is :
(A)
9
16
(B)
1
9
(C)
16
9
(D) 9
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10. When 25 g of MCO
3
(s) were enclosed in a 10 litre evacuated flask heated to 727 C 80% , of MCO
3
got
decomposed into solid MO (Molecular weight =56) and CO
2
(g). K
p
for the decomposition of MCO
3
is :
(A) 1.642 atm (B) 3.91 atm (C) 0.631 atm (D) 4.261 atm
11. Which of the following solution cannot function as a buffer when mixed in equal volume ?
(A) 0.1 M HCl mixed with 0.2 M NH
4
OH. (B) 0.2 M CH
3
CO
2
H mixed with 0.1 M NaOH.
(C) 0.1 M NaOH mixed with 0.1 MH
2
CO
3
. (D) 0.1 M CH
3
CO
2
H mixed with 0.1 MNH
4
OH.
12. A 0.1 M solution of acetic acid is titrated with a 0.05M solution of NaOH. What is the pH when 60% of the
acid has been neutralized ? (pKa of CH
3
COOH =4.74, log 2 =0.3, log 3 =0.48)
(A) 2.38 (B) 4.56 (C) 4.92 (D) 7
13. Ka for HCN is
10
5 10
mole K
2
Cr
2
O
7
reacts completely with
3
9 10
mole X
n+
to give
3
3
XO andCr
+
. The value of n is :
(A) 1 (B) 2 (C) 3 (D) None of these
16. If m
A
gramof a metal A displaces m
B
gramof another metal B from its salt solution and if the equivalent
weights are E
A
and E
B
respectively then equivalent weight of A can be expressed as :
(A)
A
A B
B
m
E E
m
= (B)
A B
A
B
m m
E
E
= (C)
B
A B
A
m
E E
m
= (D)
A
A B
B
m
E E
m
=
17. In a chemical reaction, K
2
Cr
2
O
7
+xH
2
SO
4
+ySO
2
K
2
SO
4
+Cr
2
(SO
4
)
3
+zH
2
O ; the value of x, y and z
respectively are :
(A) x =1, y =3, z =1 (B) x =4, y =1, z =4
(C) x =3, y =2, z =1 (D) x =2, y =2, z =1
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18. Hydrazine reacts with KIO
3
in presence of HCl as :
2 4 3 2 2
N H IO 2H Cl ICl N 3H O
+
+ + + + +
The equivalent masses of N
2
H
4
and KIO
3
respectively are :
(A) 8 and 53.5 (B) 16 and 53.5 (C) 8 and 35.6 (D) 8 and 87
19. The ratio of moles of Fe (II) oxidized by equal volumes of equimolar KMnO
4
and K
2
Cr
2
O
7
solutions in acidic
mediumwill be :
(A) 5: 3 (B) 1:1 (C) 1: 2 (D) 5: 6
20. Dichromate ion in acidic mediumoxidizes stannous ion as :
2 2 4 3
2 7 2
xSn yCr O zH aSn bCr cH O
+ + + +
+ + + +
The incorrect statement is :
(A) the value of x: yis1: 3 (B) the value of x +y +z is 18
(C) a: bis3: 2 (D) the value of z cis7
21. pK
b
of NH
4
OH is 4.74 and pK
b
of A , B , C andD
are 3, 4, 5, 6 respectively. An aqueous solution of
0.01M has pH in given increasing order :
(A)
4 4 4 4
NH A NH B NH C NH D < < < (B)
4 4 4 4
NH D NH B NH C NH A < < <
(C)
4 4 4 4
NH D NH C NH B NH A < < < (D) None of these
22. Equilibriumconstant of the reaction is
7
3.6 10
2
OCl (aq) H O( ) HOCl(aq) OH (aq)
+ +
. What is the K
a
for HOCl ?
(A)
8
2.8 10
(B)
7
3.6 10
(C)
4
6 10
(D)
6
2.8 10
23. The pH of 0.1M solution of the following salts increases in the order.
(A)
4
NaCl NH Cl NaCN HCl < < < (B)
4
HCl NH Cl NaCl NaCN < < <
(C)
4
NaCN NH Cl NaCl HCl < < < (D)
4
HCl NaCl NaCN NH Cl < < <
24. Which of the following will not show common ion effect on addition of HCl ?
(A) CH
3
COOH (B) H
2
S (C) C
6
H
5
COOH (D) H
2
SO
4
25. 10 ml of a strong acid solution of pH =2.000 are mixed with 990 ml of another strong acid solution of
pH =4.000 of. The pH of the resulting solution will be :
(A) 4.002 (B) 4.000 (C) 4.200 (D) 3.72
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PART  II PHYSICS
26. An electron and a proton start moving towards each other under the action of mutual attraction. At a certain
instant their velocities are v
1
and v
2
respectively. The velocity of their centre of mass is :
(A) zero (B) v
1
(C) v
2
(D)
1 2
2
v v +
27. A particle of mass 4m which is at rest explodes into three fragments. Two of fragments, each of mass m are
found to move with a speed v each in mutually perpendicular directions. The total energy released in the
process is :
(A)
2
1
2
mv (B) mv
2
(C)
2
3
2
mv
(D)
2
5
2
m / v
28. Two persons A and B of weight 80 kg and 50 kg respectively
are standing at opposite ends of a boat of mass 70 kg and length
2m, at rest. When they interchange their positions then
displacement of the centre of mass of the boat will be :
(A) 60 cm towards left (B) 30 cm towards right
(C) 30 cm towards left (D) None of these
29. In a onedimensional collision between two identical particles A and B, B is stationary and A has momentum P
before impact. During impact, B gives impulse J to A. Choose the incorrect statement :
(A) The total momentumof the A plus B systemis P before and after the impact.
(B) During the impact, A gives impulse J to B
(C) The coefficient of restitution is
2
1
J
P
(D) The coefficient of restitution is 1
J
P
30. A ball of mass m is attached to one end of a light rod of length , the
other end of which is hinged. What minimum velocity v should be
imparted to the ball downwards, so that it can complete the circle?
(A) g (B) 5g
(C) 3g (D) 2g
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31. A particle is given an initial speed u inside a smooth spherical shell of radius R =1m
that it is just able to complete the circle. Acceleration of the particle when its velocity
is vertical is :
(A) 10 g
(B) g (C) 2 g (D) 3g
32. A particle inside the rough surface of a rotating cone about its axis is at rest relative to it at a height of 1m above
its vertex. Friction coefficient is =0.5. If half angle of cone is 45 , the maximum angular velocity of
revolution of cone can be :
(A) 10 rad / s (B) 30rad / s (C) 40 rad / s (D) 50 rad / s
33. In the following figure, the velocities are in ground frame and the cylinder is
performing pure rolling on the plank, velocity of point A would be :
(A) 2
C
V (B) 2
C P
V V +
(C) 2
C P
V V (D) ( ) 2
C P
V V
34. In the following figure, the bar is uniform and weighing 500 N.
How large must W be if T
1
and T
2
are to be equal ?
(A) 500 N
(B) 300 N
(C) 750 N
(D) 1500 N
35. For the uniformT shaped structure, with mass 3M, moment of inertia
about an axis normal to the plane and passing through O would be :
(A)
2
2
M
3
(B)
2
M
(C)
2
M
3
(D) None of these
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R
u
V
C
A
C
V
P
2
O
T
1
0.3L
T
2
0.4L
0.3L
W
T
1
T
2
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36. In the balance machine, shown in figure which armwill move downward ?
(A) left
(B) right
(C) None
(D) can not be said
37. A motorcycle is going on an over bridge of radius R. The driver maintains a constant speed. As the motorcycle
is ascending on the over bridge, the normal force on it :
(A) increases (B) decreases
(C) remains constant (D) first increases then decreases
38. A stone is attached to one end of a string and rotates in a vertical circle. If string
breaks at the position of maximumtension, it will break at :
(A) A (B) B
(C) C (D) D
39. For the systemshown in figure, M
A
=m and M
B
=2m. There is
no friction between B and ground while coefficient of friction
between A and B is . The block B is connected to the block C
by means of a string and pulley system. The system is released
fromrest, then find the minimum value of mass of C so that
there is no relative motion between A and B.
(A)
m
(B)
2 1
1
m
+
+
(C)
3
1
m
(D)
6
1
m
+
40. A mass of 1 kg is acted upon by a single force
( )
4 4 F i j = +
is :
(A) ( ) 3 2 , excluding 25 . (B) [0, 1] excluding 0.5
(C)
 ) 2 1 , excluding 0 (D) None of these
55. If K is any integer then the period of the function ( )
{ } 2 x sin x  sin x . . .  sin K x
f x e
+ + + +
= is :
(A) 1 (B) K (C)
2
K
= is :
(A)
( )
2, + (B) ( ) 0, + (C) ( ) 1, + (D) None of these
59. Consider the function g (x) defined as
( )
( )
( )
( ) ( )
( )
2008
2007 2 1
2 4 2
1 1 1 1 1 1 g x . x x x x . . . x
 
= + + + + 

\ .
The value of g (2) equals to :
(A) 1 (B) 2 (C) 3 (D) 4
60. The number of real solutions of the equation 0 1
a
log x  x , a = < < , is :
(A) 0 (B) 1 (C) 2 (D) None of these
61. The equation of the circle whose one diameter is PQ, where the ordinates of P, Q are the roots of the
equation
2
2 3 0 x x + = and the abscissae are the roots of the equation
2
4 12 0 y y + = , is :
(A)
2 2
2 4 15 0 x y x y + + + = (B)
2 2
4 2 15 0 x y x y + =
(C)
2 2
4 2 15 0 x y x y + + + = (D) None of these
62. The two circles
2 2
2 6 6 0 x y x y + + + = and
2 2
5 6 15 0 x y x y + + + = touch each other. The equation of
their common tangent is :
(A) x =3 (B) y =6
(C) 7 12 21 0 x y = (D) 7 12 21 0 x y + + =
63. The locus of the centre of a circle, which externally touches the circle
2 2
6 6 14 0 x y x y + + = and also
touches the yaxis, is given by the equation :
(A)
2
6 10 14 0 x x y + = (B)
2
10 6 14 0 x x y + =
(C)
2
6 10 14 0 y x y + = (D)
2
10 6 14 0 + = y x y
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64. A circle with centre (h, k) [where k >0] touches the xaxis and also touches the circle with centre at (0, 3) and
radius 2. The locus of (h, k) is :
(A) an ellipse (B) a circle (C) a hyperbola (D) a parabola
65. If the lines 2 3 1 0 x y + + = and 3 4 0 x y = lie along diameters of a circle of circumference 10 , then the
equation of the circle is :
(A)
2 2
2 2 23 0 x y x y + + = (B)
2 2
2 2 23 0 x y x y + =
(C)
2 2
2 2 23 0 x y x y + + + = (D)
2 2
2 2 23 0 x y x y + + =
66. If one of the diameters of the circle
2 2
2 6 6 0 x y x y + + = is a chord to a circle with centre (2, 1), then the
radius of that circle is :
(A) 3 (B) 2 (C) 3 (D) 2
67. Which of the following statements is true regarding the following two circles ?
2 2
4 8 0 x y x y + = and
2 2
8 6 20 0 x y x y + + =
(A) These circles do not touch each other (B) These circles touch each other internally
(C) These circles touch each other externally
(D) None of these
68. If the circles
2 2
9 x y + = and
2 2
2 2 1 0 x y x y + + + + = touch each other externally, then can be:
(A) 0 (B) 1 (C)
4
3
(D) No values
Paragraph for Q.69  71
Tangents PA and PB are drawn from ( )
1 1
P x , y to the circle
2 2
2 2 0 S x y gx fy c + + + + = . Then answer the
following questions
( )
2 2 2 2
1 1 1 1 1
2 2 S x y g fy c, r g f c + + + + = + .
69. The angle between PA and PB :
(A)
2
1 1
1
2
S r
tan
r S
(B)
1 1
2
1
2r S
tan
S r
(C)
1 1
2 2
1
r S
tan
S r
(D)
2
1 1
S r
tan
S . r
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70. The length of the chord AB is :
(A)
1
2
1
2r S
S r +
(B)
1
2 2
1
S
S r
(C)
1
2 2
1
2r S
S r
(D) None of these
71. The area of the triangle PAB is :
(A) S
1
(B)
1
2 2
1
r S
S r +
(C)
1
2
1
r S
S r
(D)
3 2
1
2
1
/
rS
S r +
72. True / False :
S
1
: f :
   
3 3 9 9 , , defined as f (x) =x  x  is an odd function.
S
2
: For real values of x and y the relation
2 2
2 1 y x x = represents y as a function of x.
S
3
; If ( ) ( ) ( ) { }
2 3 = f x log x x and ( ) ( ) ( ) 2 3 g x log x log x = + , then f =g
S
4
: If ( ) 2 2 5 f x x + = , then ( ) 2 9 f x x =
(A) TTFF (B) TTFT (C) TFTF (D) FTTF
73. The function f ( ) 1
1 2
x
x x
x
e
= + +
is :
(A) an odd function (B) an even function
(C) neither an odd nor an even function (D) a periodic function
74. ( )
( )
2
10
1 f x log x x = + + is :
(A) an odd function (B) a periodic function
(C) an even function (D) None of these
75. True / False :
S
1
: If the point (0, g) lies inside the circle
2 2
2 0 x y gx c + + + = , then c cannot be positive.
S
2
: Length of tangent fromorigin to the circle
2 2
4 4 8 8 1 0 x y x y + + + + = is
1
2
.
S
3
; The equation
2 2
4 4 12 8 13 + + = x y x y k represents a point if k =0.
S
4
: The point ( ) 1 , + lies inside the circle
2 2
1 x y + = if
1
2
= .
(A) FFTT (B) TTTF (C) TFFF (D) TTTT
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* * * * * *End of 3HRT3/ACEG/JEE2013* * * * * *