Compilation of Henry’s Law Constants for Inorganic and Organic Species of Potential Importance in Environmental Chemistry

http://www.mpch-mainz.mpg.de/~sander/res/henry.html
Rolf Sander Air Chemistry Department Max-Planck Institute of Chemistry PO Box 3060 55020 Mainz Germany e-mail: sander@mpch-mainz.mpg.de Version 3 (April 8, 1999)
c Rolf Sander (non-commercial reproduction permitted)

Contents
1 Introduction 2 The physical quantity of solubility 3 Temperature dependence 4 Unit conversions 5 How to use the Tables 6 Further Sources of Information 7 Data Table (Inorganic) oxygen (O) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . hydrogen (H) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . nitrogen (N) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . fluorine (F) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . chlorine (Cl) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . bromine (Br) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iodine (I) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . sulfur (S) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . rare gases . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . other elements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 3 3 3 4 4 6 6 6 7 8 9 10 11 12 13 13

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R. Sander: Henry’s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)

8 Data Table (Organic) alkanes (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . cycloalkanes (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . aliphatic alkenes and cycloalkenes (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . aliphatic alkynes (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . mononuclear aromatics (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . terpenes and polynuclear aromatics (C and H only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . alcohols (ROH) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . polyols (R(OH)n ) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

14 14 27 28 30 31 35 37 41 43 44 46 48 50 54 55 58 59 59 61 65 66 68 71 82 84 86 89 90 92 96 99 99

peroxides (ROOH) and peroxy radicals (ROO) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . aldehydes (RCHO) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ketones (RCOR) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . carboxylic acids (RCOOH) and peroxy carboxylic acids (RCOOOH) (C, H, and O only) . . . . . . . . . . . . . . esters (RCOOR) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ethers (ROR) (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . miscellaneous, e.g. multiple functional groups (C, H, and O only) . . . . . . . . . . . . . . . . . . . . . . . . . . . compounds with nitrogen: amines (RNH2 ) (C, H, O, and N only) . . . . . . . . . . . . . . . . . . . . . . . . . . . compounds with nitrogen: amino acids (RCHNH2 COOH) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . compounds with nitrogen: heterocycles (C, H, O, and N only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . compounds with nitrogen: nitrates (RONO2 ) (C, H, O, and N only) . . . . . . . . . . . . . . . . . . . . . . . . . compounds with nitrogen: nitriles (RCN) (C, H, O, and N only) . . . . . . . . . . . . . . . . . . . . . . . . . . . compounds with nitrogen: nitro (RNO2 ) (C, H, O, and N only) . . . . . . . . . . . . . . . . . . . . . . . . . . . . compounds with fluorine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . aliphatic compounds with chlorine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . aromatic compounds with chlorine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . compounds with chlorine and fluorine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . compounds with bromine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . compounds with iodine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

compounds with sulfur . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . polychlorobiphenyls (PCB’s), pesticides, etc. 9 Notes 10 Acknowledgements References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

R. Sander: Henry’s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)

3

1

Introduction

Henry’s law constants (solubilities) of trace gases of potential importance in environmental chemistry (atmospheric chemistry, waste water treatment, . . . ) have been collected and converted into a uniform format. Disclaimer: Although this compilation has been edited with greatest care the possibility of errors cannot be excluded. If you use data from this table it is recommended that you also check the original literature. If you find an error in this table, please tell me about it!

2

The physical quantity of solubility

There are several ways of describing the solubility of a gas in water. Usually the Henry’s law constant kH is defined as: kH = ca /pg
def

(1)

Here, ca is the concentration of a species in the aqueous phase and pg is the partial pressure of that species in the gas phase. If kH refers to standard conditions (T = 298.15 K) it will be denoted as kH . Henry’s law constant can also be expressed as the dimensionless ratio between the aqueous-phase concentration ca of a species and its gas-phase concentration cg :
cc kH = ca /cg = kH × RT def

(2)

where R = gas constant and T = temperature. To distinguish these different physical quantities, this constant has been cc named kH here.
px Sometimes the reciprocal value kH ,inv is used, representing the volatility instead of the solubility. The usual definition is: px kH ,inv = pg /xa = def H2 O

MH2 O × kH

(3)

where xa = molar mixing ratio in the aqueous phase,

H2 O

= density of water, and MH2 O = molar mass of water.

3

Temperature dependence

A simple way to describe Henry’s law as a function of temperature is: kH = kH × exp −∆soln H R 1 1 − T T (4)

where ∆soln H = enthalpy of solution. Here, the temperature dependence is: −d ln kH ∆soln H = d(1/T ) R (5)

4

Unit conversions

Detailed information about the conversion between different units and definitions of Henry’s law constants is given by Sander [1999]. Here is a short summary: The commonly used unit for kH is [M/atm] = [ molaq /dm3 molaq /m3 aq aq ]. The official SI unit is [ ]. The conversion is: atm Pa (6)

kH kH = 101.325 × [M/atm] [(molaq /m3 aq )/Pa]
cc The relation between kH and kH is:

T kH cc × = 12.2 × kH [K] [M/atm]

(7)

rounded to two significant digits and given in the unit [K].15 K this leads to: kH cc = 0. Br. F.g. Cl. Ph. Hetero atoms (N.inv × = 55. It is possible that they were recalculating data from the same source. trivial names (if any). everything with carbon. and S) are sorted in the same way as for inorganic compounds.de/~sander/res/henry.). followed by original publications of experimental determinations of kH . The column labeled ‘substance’ gives the systematic name. and PCBs: Mackay et al. For each table entry the column labeled ‘type’ denotes how the Henry’s law constant was obtained in the given reference. The column labeled ‘−d ln kH /d(1/T )’ contains the temperature dependence of the Henry’s law constants as defined in equations (4) and (5). if the original work they refer to is not known one has to be careful when evaluating the reliability.g. I haven’t seen the paper that I cite here. The product of kH and kH. Organic substances (i.inv is [atm]. The types listed here are roughly ordered by decreasing reliability: ‘L’ ‘M’ ‘V’ ‘R’ The cited paper is a literature review. The cited paper doesn’t clearly state how the value was obtained. The value is estimated. 6 Further Sources of Information Further important references: • monoaromatic hydrocarbons. personal communication.4 R.e. Cl. Thermodynamical calculation (∆soln G = −RT ln kH . I found it referenced by another paper or I know about it through others. extrapolation to a different temperature or concentration range). and in several cases the CAS registry number (in square brackets). Literature reviews are usually most reliable. Sander: Henry’s law constants (http://www. The column labeled ‘kH ’ contains the Henry’s law constants as defined in equation (1). Original publication of a measured value (e. including CO and CO2 ) are sorted somewhat arbitrarily by increasing chain length and complexity. theses. rare gases.mpg.mpch-mainz. ‘T’ ‘C’ ‘X’ ‘?’ ‘E’ In some cases there might be good agreement between different authors. The similarity in that case would not be due to independent investigations.0409 × kH [M/atm] (8) px px The commonly used unit for kH . The order chosen is: O. Other data has to be treated more carefully. N.D. The paper that is cited here refers to another reference which I could not obtain (e. H.g. I. I.3 [M/atm] [atm] (9) 5 How to use the Tables Inorganic substances are sorted according to the elements they contain. internal papers etc. the chemical formula. [1992a] . S. Estimates are only listed if no reliable measurements are available for that compound.html) At T = 298. chlorobenzenes. F. However.inv is constant: px kH kH . Vapor pressure of the pure substance is used to determine the Henry’s law constant (c/p for a saturated solution). others. see Sander [1999] for details). Br. The cited paper presents a recalculation of previously published material (e. head-space or bubble column technique as explained by Betterton [1992]). rounded to two significant digits and given in the unit [M/atm].

[1998]. Watts and Brimblecombe [1987]. polychlorinated dioxins. [1992]. [1989]. and dibenzofuranes: Mackay et al.html . Rice et al. [1992a]. [1987]. [1997]. [1997]. [1992]. Heron et al. Sander: Henry’s law constants (http://www. Peng and Wan [1997]. Roberts and D¨ andliker [1983]. [1995] • pestizides. [1991] • additional references that are not (yet) included: Lide and Frederikse [1995]. and sulfur containing compounds: Mackay et al. [1994]. Gan and Yates [1996].html) 5 • polynuclear aromatic hydrocarbons. Murphy et al. [1998]. Duce et al. Hassett and Milicic [1985]. Shiu et al. [1997]. Ettre et al.gov/chemistry • The Pesticide Properties Database (PPD) at http://www. [1992b] • volatile organic chemicals: Mackay et al. [1998]. Nirmalakhandan et al. Fendinger and Glotfelty [1988]. De Maagd et al.arsusda. Shiu et al. [1985] • predictive methods for Henrys law coefficients (QSPRs): Russell et al. PCB’s.mpg. Leuenberger et al. nitrogen.R. [1993] • oxygen. Economou et al. Kolb et al. Brennan et al. [1985]. [1992]. etc. [1998] On the Internet: • The NIST Chemistry WebBook at http://webbook. Tse et al. [1981].: Westcott et al. Wong and Wang [1997].de/~sander/res/henry.nist.mpch-mainz. Suleimenov and Krupp [1994]. [1993]. Yin and Hassett [1986]. Burkhard et al. Becker et al. Fendinger et al.gov/rsml/ppdb2. Wright et al. [1988].

1×104 7.9×10−3 7.6×104 −3 −d ln kH d(1/T ) substance [K] reference type note oxygen (O) oxygen O2 [7782-44-7] 1700 1800 1500 1700 1500 1700 2300 2000 2000 2300 2700 2500 2400 2400 2900 Loomis Carpenter Wilhelm et al.2×101 2.1×105 8.1×10−2 1.4×10−3 1.6×103 9.0×103 1. Berdnikov and Bazhin Chameides Schwartz Jacob Weinstein-Lloyd and Schwartz Hanson et al.7×103 7.3×10−3 1.0×103 5.0×103 4.7×104 6.mpg.9×104 1. R´ egimbal and Mozurkewich Martin and Damschen Hoffmann and Jacob Yoshizumi et al.mpch-mainz. Durham et al.2×10−2 1.1×104 1.8×10−4 7. Dean Lide and Frederikse Berdnikov and Bazhin Mozurkewich Jacob Lelieveld and Crutzen Lelieveld and Crutzen Lelieveld and Crutzen Hanson et al.3×10−3 1.2×10−3 1.2×103 9. Staffelbach and Kok Zhou and Lee [1928] [1966] [1977] [1992] [1995] [1980] [1928] [1939] [1977] [1981] [1983] [1984] [1984] [1986] [1986] [1980] [1965] [1977] [1992] [1995] [1970] [1986] [1986] [1991] [1991] [1991] [1992] [1970] [1984] [1984] [1986] [1991] [1992] [1997] [1981] [1984] [1984] [1984] [1985] [1994] [1996] [1993] [1992] X M L ? L X X M L C M T ? C C X R L ? L T T C C C C T T T T E T T R T ? M T M M M M M 1 2 3 1 ozone O3 [10028-15-6] 4 3 hydrogen (H) hydrogen H2 [1333-74-0] hydroxyl radical OH [3352-57-6] 490 640 500 3100 5300 2 5 6 hydroperoxy radical HO2 [3170-83-0] 4500 4800 5 7 6600 5900 7000 7300 6600 7900 6300 7400 7500 6500 hydrogen peroxide H2 O2 [7722-84-1] 4 8 9 10 .4×105 9. Chameides Hwang and Dasgupta Lind and Kok O’Sullivan et al.3×104 1.0×102 9.8×10−4 2.3×10−2 1.8×10−4 7.3×10 1.9×101 3.0×105 8.html) 7 Data Table (Inorganic) kH [M/atm] 1.5×101 2.3×10−3 1. Kosak-Channing and Helz Chameides Hoffmann and Jacob Jacob Seinfeld Kavanaugh and Trussell Hine and Weimar Wilhelm et al.6 R.1×10−2 9.8×10−4 7.2×10−2 9.3×10−2 1.4×10−3 8.2×10−3 1. Dean Lide and Frederikse Kavanaugh and Trussell Loomis Briner and Perrottet Wilhelm et al.0×103 3. Sander: Henry’s law constants (http://www.2×10−2 1.5×101 2.de/~sander/res/henry.0×101 4.

4×10−2 1.2×10−2 4.1×10−2 1.1×10−4 7.6×10−2 2.6×101 5.8×101 5. Chameides Berdnikov and Bazhin Chameides Thomas et al. [1928] [1974] [1977] [1986] [1992] [1995] [1963] [1977] [1980] [1977] [1980] [1981] [1981] [1992] [1995] [1970] [1981] [1981] [1981] [1981] [1981] [1984] [1970] [1986] [1993] [1996] [1998] [1998] X ? L ? ? L X L X L M L C ? L T M C C L C T T T M M M M 1 13 2 14 3 2 5 15 nitrogen dioxide NO2 [10102-44-0] nitrogen trioxide NO3 (nitrate radical) [12033-49-7] 2500 2000 1900 2000 5 16 17 . laughing gas) [10024-97-2] 4400 3100 2 11 12 3 nitrogen N2 [7727-37-9] nitrogen monoxide NO (nitric oxide) [10102-43-9] 2.8×101 5.6×101 6.0×101 9.mpg. Sander: Henry’s law constants (http://www.0×101 6.0×10−3 4. Seinfeld Dean Lide and Frederikse Perry Wilhelm et al.R. Kavanaugh and Trussell Wilhelm et al.9 [K] 4100 4100 1500 4200 3400 4100 4100 4100 4200 4200 2100 reference type note nitrogen (N) ammonia NH3 [7664-41-7] Sillen and Martell Robinson and Stokes Wilhelm et al.4×10−2 6.4×10−2 2. Zafiriou and McFarland Schwartz and White Durham et al.9×101 5.2×101 5.0×10−2 2. Hales and Drewes Chameides Holzwarth et al.9×10−3 3.4×10−2 7.9×10−3 1.html) −d ln kH d(1/T ) 7 substance kH [M/atm] 5. Hoffmann and Jacob Dasgupta and Dong Dasgupta and Dong Clegg and Brimblecombe Dean Van Krevelen et al.7×101 1.9×10−3 1. Seinfeld and Pandis Thomas et al. Kavanaugh and Trussell Wilhelm et al.6×101 5. Bone et al.9×10−7 1. Dean Lide and Frederikse Berdnikov and Bazhin Lee and Schwartz Lee and Schwartz Lee and Schwartz Schwartz and White Durham et al.8 2600 2800 2600 2700 1300 1300 3800 1500 1700 1400 1800 Loomis Liss and Slater Wilhelm et al.5×10−2 2.8×101 7.1×101 7.5×10−2 2.4×101 6.mpch-mainz.0×10−1 see note 1. Edwards et al.4×10−3 1.9×10−3 1.5×10−4 6.7×101 6.4×10−2 1.4×10−2 2.2×10−2 3. Rudich et al. [1964] [1970] [1977] [1978] [1979] [1984] [1984] [1984] [1986] [1986] [1989] [1992] [1949] [1983] [1980] [1977] X X L L M T M ? M T M ? X ? X L 1 1 4 hydrazoic acid HN3 [7782-79-8] dinitrogen monoxide N2 O (nitrous oxide.0 6.de/~sander/res/henry.1×101 2.5×10−2 2.2×101 2.

9×101 4.5×105 /KA 2. [1994] Sander and Crutzen [1996] Schwartz and White Durham et al. Chameides Martin Park and Lee Becker et al.9×101 5.mpch-mainz.9×101 3.8 R. M¨ oller and Mauersberger R´ egimbal and Mozurkewich Amels et al.de/~sander/res/henry.0×101 2.0×103 2. [1977] L .6×101 1.2×104 4.0×104 1.0×105 1.7×101 4. [1977] L 8.9×10−4 1900 Wilhelm et al. Sander: Henry’s law constants (http://www.0×10−1 2. 4 20. 21 22 23 fluorine (F) fluorine atom F [14762-94-8] hydrogen fluoride HF [7664-39-3] nitrogen trifluoride NF3 [7783-54-2] dinitrogen tetrafluoride N2 F4 (tetrafluorohydrazine) [10036-47-2] 400 Berdnikov and Bazhin [1970] 5 9.8×101 4.html) −d ln kH d(1/T ) substance dinitrogen trioxide N2 O3 [10544-73-7] dinitrogen tetroxide N2 O4 [10544-72-6] dinitrogen pentoxide N2 O5 (nitric anhydride) [10102-03-1] nitrous acid HNO2 [7782-77-6] kH [M/atm] 6. Chameides Hoffmann and Jacob Brimblecombe and Clegg Lelieveld and Crutzen Jacob et al.1×105 2.1 ∞ 4.5×10−4 2500 Wilhelm et al.6/KA 7400 Brimblecombe and Clegg [1989] T 20.4 1.6×106 3.6 ∞ 2.1×10 −2 [K] reference Schwartz and White [1981] Durham et al.9×104 2. [1981] Schwartz and White [1981] Durham et al.4×106 /KA 2. Schwartz and White Durham et al. [1981] [1981] [1984] [1984] [1988] [1996] [1981] [1981] [1984] [1984] [1989] [1991] [1989] [1992] [1997] [1996] type L C L C E E E L C T T M M T C T ? T R C E T M T note 3400 18 19 18 4800 4800 4700 4900 4900 nitric acid HNO3 [7697-37-2] pernitric acid HNO4 [26404-66-0] 8700 8700 8700 8700 0 6900 20.1×105 8. [1981] Jacob [1986] Fried et al.mpg. 21 7.

Dean Brian et al.5×10−2 8.05 1 [K] 9000 reference type note chlorine (Cl) hydrogen chloride HCl [7647-01-0] Loomis Loomis Chen et al.8×102 9.7×105 /KA 1. [1997] Frenzel et al. 21 2 hypochlorous acid HOCl [7790-92-3] 24 5900 5100 nitrosyl chloride NOCl [2696-92-6] nitryl chloride ClNO2 [13444-90-1] chlorine nitrate ClNO3 [14545-72-3] molecular chlorine Cl2 [7782-50-5] 2.0×10−1 4100 Holzwarth et al. Lide and Frederikse Kavanaugh and Trussell Wilhelm et al.6×102 > 0.6×10−2 1. Wagman et al.5×103 2. [1984] M .R.0×106 /KA 1.9×10 1.html) −d ln kH d(1/T ) 9 substance kH [M/atm] 1. Hanson and Ravishankara Blatchley et al. Scheer et al.7×101 1.7×101 1. Sander: Henry’s law constants (http://www.4×10−2 4.9×101 4200 Holzwarth et al.0×10−1 9.3×10−2 6.1×10−2 6.0×101 1.3×10−2 9. [1984] 2. Lide and Frederikse Kavanaugh and Trussell Berdnikov and Bazhin Mozurkewich [1962] [1977] [1982] [1992] [1962] [1995] [1980] [1977] [1995] [1977] [1995] [1980] [1970] [1986] ? L T ? L L X L L L L X T T M 26 2 3 14 3 5 4800 Holzwarth et al.2×10−2 9. Wagman et al.mpg.5×103 2. Graedel and Goldberg Marsh and McElroy Seinfeld Brimblecombe and Clegg Dean Wagman et al.3×102 6.5×10−2 2.0 8.6×10−2 ∞ Behnke et al.3×102 4.0×106 /KA 7.0 1.4×101 2500 2800 2300 3200 2100 2000 1800 1700 3300 3300 3400 1500 Kruis and May Wilhelm et al.5×10−1 1.20 1 2000 9000 600 9000 13 20. [1928] [1928] [1979] [1983] [1985] [1986] [1989] [1992] [1982] [1984] [1991] [1992] [1995] [1982] [1997] X X X C T ? T ? T M M M L T M 1 1. Lide and Frederikse Wilhelm et al.mpch-mainz. [1998] Sander and Crutzen [1996] E E E 25 18 dichlorine monoxide Cl2 O [7791-21-1] chlorine dioxide ClO2 [10049-04-4] chlorine atom Cl [22537-15-1] chloramide NH2 Cl [10599-90-3] dichloroamine NHCl2 (chlorimide) [3400-09-7] nitrogen trichloride NCl3 [10025-85-1] see note 9.9×101 2.1 2.de/~sander/res/henry. Huthwelker et al. Holzwarth et al. [1984] M 1.6×102 2.

10 R.6×10−1 1. [1998] Berdnikov and Bazhin [1970] Mozurkewich [1986] X M M R M T ? M M T T M M E T T 30 8 2 31 31 32 33 34 5 .2 3600 4100 3900 4000 4100 3300 3700 5600 1800 Winkler [1899] Kelley and Tartar [1956] Jenkins and King [1965] Jenkins and King [1965] Hill et al.html) −d ln kH d(1/T ) substance kH [M/atm] 1. Fickert Frenzel et al. [1987] see note see note Disselkamp et al.mpg.1×10−1 9.2×10−1 2.4×10−2 1.3×10 /KA 7. [1987] Dubik et al. [1968] Wagman et al.9×103 1.2 1. [1989] [1992] [1992] [1982] [1992] [1995] [1996] [1998] [1998] [1998] T C ? T M T E M E E 20.4×10−1 5. [1998] Bartlett and Margerum [1998] Frenzel et al.2×108 /KA >1.3×101 see note 6. Mozurkewich Vogt et al.8 4.9×10−1 7.de/~sander/res/henry. Frenzel et al.8 9. Blatchley et al.7×10−1 8.9×10−1 7.3×10−1 7.1 7.1×103 3.2 9.9×10−1 3.0×10−1 9 [K] 10000 6100 370 10000 reference type note bromine (Br) hydrogen bromide HBr [10035-10-6] hypobromous acid HOBr [13517-11-8] Brimblecombe and Clegg Chameides and Stelson Dean Wagman et al. Sander: Henry’s law constants (http://www. 21 27 2 28 29 nitryl bromide BrNO2 [13536-70-4] bromine nitrate BrNO3 [40423-14-1] molecular bromine Br2 [7726-95-6] ∞ Sander and Crutzen [1996] E 18 bromine chloride BrCl [13863-41-7] bromine atom Br [10097-32-2] 7.5×101 7.4×10−1 5.mpch-mainz. [1982] Dean [1992] Dubik et al.0×10−1 6.

Thompson and Zafiriou Palmer et al. 21 4600 4800 4400 2300 35 5 Wagman et al. [1982] T . [1982] 2.de/~sander/res/henry.1 3.2×109 /KA >4.1×102 3.mpch-mainz.3 1.5×10 /KA 2.1×102 9 [K] reference type note iodine (I) hydrogen iodide HI [10034-85-2] hypoiodous acid HOI [14332-21-9] molecular iodine I2 [7553-56-2] iodine atom I [14362-44-8] iodine chloride ICl [7790-99-0] iodine bromide IBr [7789-33-5] 9800 9800 Brimblecombe and Clegg [1989] Wagman et al. [1982] Thompson and Zafiriou Thompson and Zafiriou Palmer et al.1 3.5×104 >4.3×10−3 8.0×10−2 1. Berdnikov and Bazhin Mozurkewich [1983] [1983] [1985] [1970] [1982] [1983] [1985] [1970] [1986] T T E E C R T C R T T T 20. Sander: Henry’s law constants (http://www. Berdnikov and Bazhin Wagman et al.mpg.0 6.html) −d ln kH d(1/T ) 11 substance kH [M/atm] 2.4×101 Wagman et al.5×101 <4.R.

2 1.4 1. Carroll and Mather Dean Lide and Frederikse De Bruyn et al. Edwards et al.2 1. Kavanaugh and Trussell Sillen and Martell Hales and Sutter Liss and Slater Smith and Martell Wilhelm et al.2 1.5 1.1 1.0×10−1 1.0×10−1 8.2 1.0×10−1 1.2 1.0×10−1 1.3 ∞ −3 [K] 2300 2100 2100 2200 2300 2000 2100 2200 3200 3100 3100 2800 3000 3100 3100 3200 3100 2900 3200 2900 2800 reference type note sulfur (S) hydrogen sulfide H2 S [7783-06-4] Loomis Hine and Weimar Wilhelm et al.2 1. Chameides Hoffmann and Jacob Jacob Pandis and Seinfeld Dean Maahs Maahs Lide and Frederikse Kavanaugh and Trussell Sander and Crutzen [1928] [1965] [1977] [1978] [1989] [1992] [1995] [1995] [1980] [1964] [1973] [1974] [1976] [1977] [1978] [1981] [1984] [1984] [1986] [1989] [1992] [1982] [1982] [1995] [1980] [1996] X R L L L ? L M X X c c X L L C T ? C C ? X X L X E 1 2 sulfur dioxide SO2 [7446-09-5] 3 1 1 4 2 11 1 3 18 sulfur trioxide SO3 [7446-11-9] sulfuric acid H2 SO4 [7664-93-9] sulfur hexafluoride SF6 [2551-62-4] see note Gmitro and Vermeulen [1964] M 36 2.8×10−2 1.2 1.2 1.mpch-mainz.0×10 1.4 1.0×10−1 1.2 1.2 1.mpg.de/~sander/res/henry.2 1.html) −d ln kH d(1/T ) substance kH [M/atm] 1. [1977] L .4×10−4 2400 Wilhelm et al.12 R.7×10−2 9. Sander: Henry’s law constants (http://www. Edwards et al. Durham et al.0×10−1 1.

[1977] L 8. [1977] Morrison and Johnstone [1954] Wilhelm et al. [1977] L 8.8×10−4 4.html) −d ln kH d(1/T ) 13 substance kH [M/atm] 3.3×10−3 −4 [K] 360 92 530 450 1100 1500 1500 1900 1900 2200 2600 reference type note rare gases helium He [7440-59-7] neon Ne [7440-01-9] argon Ar [7440-37-1] krypton Kr [7439-90-9] xenon Xe [7440-63-3] radon Rn [10043-92-2] selenium hydride H2 Se [7783-07-5] phosphorus trihydride PH3 (phosphine) [7803-51-2] arsenic hydride AsH3 (arsine) [7784-42-1] mercury Hg [7439-97-6] Morrison and Johnstone [1954] Wilhelm et al. [1977] Wilhelm et al.5×10−4 4.5×10−4 1.4×10−3 2.4×10−2 1900 Wilhelm et al.1×10−3 2000 Wilhelm et al.4×10−3 2.mpg.7×10 3. [1977] Morrison and Johnstone [1954] Wilhelm et al.9×10−3 2100 Wilhelm et al.4×10−3 1.de/~sander/res/henry.3×10−3 9.3×10−3 4. Sander: Henry’s law constants (http://www.R.5×10−3 4. [1977] Morrison and Johnstone [1954] Wilhelm et al. [1977] L 9.3×10−2 Brimblecombe [1986] ? 38 . [1977] M L M L M L M L M L L 37 37 other elements 8. [1977] Morrison and Johnstone [1954] Wilhelm et al.mpch-mainz.

1×10−3 8.5×10−3 1.6×10−4 5.9×10−3 2.0×10−3 1.2-dimethylpropane C5 H12 2700 39 3400 39 39 4.3×10−3 1.1×10−3 1.3×10−3 1.7×10−4 8.de/~sander/res/henry.14 R.3×10−3 1.5×10−3 1.2×10−3 1.0×10−4 8.mpch-mainz.7×10−4 4. Mackay and Shiu Lide and Frederikse Yaws and Yang Hine and Mookerjee Wilhelm et al. Sander: Henry’s law constants (http://www.0×10−3 1.8×10−3 2.4×10−3 9.5×10−3 1.mpg.9×10−4 7.1×10−3 1.2×10−3 1.5×10−3 1.3×10−4 −d ln kH d(1/T ) substance [K] reference type note alkanes (C and H only) methane CH4 Butler and Ramchandani Hine and Weimar Liss and Slater Hine and Mookerjee Wilhelm et al.7×10−4 Yaws and Yang [1992] ? 39 .4×10−3 1.9×10−3 1.4×10−3 1.4×10−3 4.4×10−4 8.1×10−4 7.1×10−2 2.1×10−4 8.7×10−4 1.9×10−4 2.html) 8 Data Table (Organic) kH [M/atm] 9.5×10−4 8. Mackay and Shiu Yaws and Yang Hine and Mookerjee Wilhelm et al. Mackay and Shiu Hine and Mookerjee Mackay and Shiu Yaws and Yang Mackay and Shiu Yaws and Yang [1935] [1965] [1974] [1975] [1977] [1981] [1992] [1995] [1992] [1980] [1935] [1975] [1977] [1981] [1995] [1992] [1975] [1977] [1981] [1995] [1992] [1935] [1975] [1977] [1981] [1992] [1975] [1977] [1981] [1992] [1975] [1977] [1981] [1975] [1981] [1992] [1981] [1992] V R C V L L ? L ? X V V L L L ? V L L L ? V V L L ? V L L ? V L L V L ? L ? 1700 1900 1600 1800 2 14 39 3 ethane C2 H6 2400 2300 39 propane C3 H8 2700 2700 39 butane C4 H10 3100 39 2-methylpropane HC(CH3 )3 (isobutane) dimethylpropane C(CH3 )4 (neopentane) pentane C5 H12 2-methylbutane C5 H12 (isopentane) 2.4×10−3 1.3×10−4 7. Mackay and Shiu Dean Lide and Frederikse Yaws and Yang Kavanaugh and Trussell Butler and Ramchandani Hine and Mookerjee Wilhelm et al. Mackay and Shiu Lide and Frederikse Yaws and Yang Butler and Ramchandani Hine and Mookerjee Wilhelm et al.4×10−3 1.0×10−3 1. Mackay and Shiu Yaws and Yang Hine and Mookerjee Wilhelm et al.

8×10−4 7.6×10−4 7.0×10−3 5.9×10−3 2. Mackay and Shiu Hansen et al.html) −d ln kH d(1/T ) 15 substance hexane C6 H14 2-methylpentane C6 H14 (isohexane) [107-83-5] 3-methylpentane C6 H14 2.3-dimethylpentane C7 H16 2.3-dimethylpentane C7 H16 3-ethylpentane C7 H16 2.1×10−4 5.3×10−1 5.9×10−4 1.5×10−4 6.4-dimethylpentane C7 H16 3.0×10−4 5.2-dimethylbutane C6 H14 2. Mackay and Shiu Yaws and Yang [1975] [1981] [1992] [1988] [1975] [1981] [1992] [1988] [1975] [1981] [1992] [1975] [1981] [1992] [1981] [1992] [1975] [1981] [1995] [1992] [1993] [1981] [1995] [1992] [1993] [1981] [1992] type V L ? X V L ? X V L ? V L ? L ? V L L ? X L M ? X L ? L ? L ? V L ? L ? ? note 7500 39 3 960 39 3 39 39 39 3700 3700 -3600 -3500 39 3 40 39 3 39 2-methylhexane C7 H16 3-methylhexane C7 H16 2.9×10−4 [K] reference Hine and Mookerjee Mackay and Shiu Yaws and Yang Ashworth et al.9×10−4 4.8×10−4 5.3-trimethylbutane C7 H16 Mackay and Shiu [1981] Yaws and Yang [1992] Mackay and Shiu [1981] Yaws and Yang [1992] Hine and Mookerjee Mackay and Shiu Yaws and Yang Mackay and Shiu Yaws and Yang [1975] [1981] [1992] [1981] [1992] 39 39 39 39 39 Yaws and Yang [1992] 4.4×10−4 5.2×10−4 3.7×10−4 1.9×10−4 5.7×10−4 4.2×10−3 3. Hine and Mookerjee Mackay and Shiu Yaws and Yang Ashworth et al.2×10−3 2.mpch-mainz.mpg.2×10−4 3.de/~sander/res/henry.9×10−3 4.0×10−4 7.2×10−4 3.9×10−4 8.7×10−4 1.1×10−4 Yaws and Yang [1992] ? 39 .5×10−4 3. Hine and Mookerjee Mackay and Shiu Yaws and Yang Hine and Mookerjee Mackay and Shiu Yaws and Yang Mackay and Shiu Yaws and Yang Hine and Mookerjee Mackay and Shiu Hansen et al.8×10−4 6.8×10−4 1.2-dimethylpentane C7 H16 2. Sander: Henry’s law constants (http://www.4×10−4 1. Yaws and Yang Hansen et al.4×10−4 5.1×10−4 5.9×10−4 1.2.8×10−4 3.4×10−4 3.R.9×10−4 5.2×10−4 3.9×10−4 6. Yaws and Yang Hansen et al.3-dimethylbutane C6 H14 heptane C7 H16 kH [M/atm] 5.

7×10−4 2.8×10−4 Yaws and Yang [1992] ? 39 3.9×10−3 2.4-dimethylhexane C8 H18 kH [M/atm] 3.9×10−4 Yaws and Yang [1992] ? 39 2.html) −d ln kH d(1/T ) substance octane C8 H18 2-methylheptane C8 H18 3-methylheptane C8 H18 4-methylheptane C8 H18 2.6×10−4 Yaws and Yang [1992] ? 39 2.3-dimethylhexane C8 H18 2.1×10−4 3.16 R.7×10−4 [K] reference Hine and Mookerjee Mackay and Shiu Yaws and Yang Hansen et al.4×10−4 2.4-dimethylhexane C8 H18 2.7×10−4 2.7×10−4 2.6×10−4 Yaws and Yang [1992] ? 39 2. Hoff et al.0×10−4 Yaws and Yang [1992] ? 39 2. Yaws and Yang [1975] [1981] [1992] [1993] [1993] [1992] type V L ? X ? ? L ? ? note 7800 39 3 13 39 Mackay and Shiu [1981] Yaws and Yang [1992] Yaws and Yang [1992] 39 39 2.4×10−4 Yaws and Yang [1992] ? 39 .mpg.0×10−4 2. Sander: Henry’s law constants (http://www.3-dimethylhexane C8 H18 3.7×10−4 2.de/~sander/res/henry.mpch-mainz.5-dimethylhexane C8 H18 3.2-dimethylhexane C8 H18 2.

html) −d ln kH d(1/T ) 17 substance 3-ethylhexane C8 H18 2.6×10−4 Yaws and Yang [1992] ? 39 .3×10−4 Yaws and Yang [1992] ? 39 2.2. Sander: Henry’s law constants (http://www.6×10−4 Yaws and Yang [1992] ? 39 3.0×10−4 2.de/~sander/res/henry.3.mpg.2.3.6×10−4 [K] reference Yaws and Yang [1992] type ? note 39 2.1×10−4 3.3-tetramethylbutane C8 H18 kH [M/atm] 2.4-trimethylpentane C8 H18 2.3-trimethylpentane C8 H18 2.R.4-trimethylpentane C8 H18 3-ethyl-2-methylpentane C8 H18 3-ethyl-3-methylpentane C8 H18 2.6×10−4 Mackay and Shiu [1981] Yaws and Yang [1992] Yaws and Yang [1992] L ? ? 39 39 2.7×10−4 2.3.3×10−4 5.3-trimethylpentane C8 H18 2.mpch-mainz.3×10−4 3.2.4×10−4 Hine and Mookerjee Mackay and Shiu Yaws and Yang Yaws and Yang [1975] [1981] [1992] [1992] V L ? ? 39 39 5.

9×10−4 Yaws and Yang [1992] ? 39 1.0×10−4 1.9×10−4 Yaws and Yang [1992] ? 39 .2-dimethylheptane C9 H20 2.5-dimethylheptane C9 H20 2.4×10−3 2.html) −d ln kH d(1/T ) substance nonane C9 H20 2-methyloctane C9 H20 3-methyloctane C9 H20 4-methyloctane C9 H20 2.1×10−4 Yaws and Yang [1992] ? 39 1.6-dimethylheptane C9 H20 3. Sander: Henry’s law constants (http://www.1×10−4 Yaws and Yang [1992] ? 39 2.9×10−4 Yaws and Yang [1992] ? 39 1.0×10−4 1.de/~sander/res/henry.9×10−4 Yaws and Yang [1992] ? 39 1.7×10−4 2.0×10−4 Yaws and Yang [1992] ? 39 1.4-dimethylheptane C9 H20 2.4-dimethylheptane C9 H20 3-ethylheptane C9 H20 4-ethylheptane C9 H20 kH [M/atm] 2.4-dimethylheptane C9 H20 3.8×10−4 Yaws and Yang [1992] ? 39 2.mpg.3-dimethylheptane C9 H20 3.mpch-mainz.0×10−4 Yaws and Yang [1992] ? 39 1.9×10−4 Mackay and Shiu [1981] Yaws and Yang [1992] Yaws and Yang [1992] L ? ? 39 39 2.1×10−4 Yaws and Yang [1992] ? 39 2. Yaws and Yang [1981] [1992] [1988] [1992] type L ? X ? note 210 39 3 39 2.0×10−4 1.1×10−4 [K] reference Mackay and Shiu Yaws and Yang Ashworth et al.5-dimethylheptane C9 H20 4.0×10−4 Yaws and Yang [1992] ? 39 2.3-dimethylheptane C9 H20 2.18 R.

3.7×10−4 Mackay and Shiu [1981] Yaws and Yang [1992] Yaws and Yang [1992] L ? ? 39 39 1.1×10−4 Yaws and Yang [1992] ? 39 1.2.3.3-trimethylhexane C9 H20 2.9×10−4 1.7×10−4 Yaws and Yang [1992] ? 39 1.3.4-trimethylhexane C9 H20 2.2.6×10−4 Yaws and Yang [1992] ? 39 .3.8×10−4 Yaws and Yang [1992] ? 39 2.4-trimethylhexane C9 H20 3.9×10−4 1.3.4-trimethylhexane C9 H20 3-ethyl-2-methylhexane C9 H20 4-ethyl-2-methylhexane C9 H20 3-ethyl-3-methylhexane C9 H20 3-ethyl-4-methylhexane C9 H20 2.1×10−4 Yaws and Yang [1992] ? 39 2.6×10−4 Yaws and Yang [1992] ? 39 1.3.5-trimethylhexane C9 H20 2.de/~sander/res/henry.mpg.7×10−4 Yaws and Yang [1992] ? 39 1.html) −d ln kH d(1/T ) 19 substance 2.2.9×10−4 Yaws and Yang [1992] ? 39 1.3.2.8×10−4 Yaws and Yang [1992] ? 39 1. Sander: Henry’s law constants (http://www.4-trimethylhexane C9 H20 2.4-tetramethylpentane C9 H20 kH [M/atm] 1.4-tetramethylpentane C9 H20 2.3-trimethylhexane C9 H20 2.4.4-tetramethylpentane C9 H20 2.9×10−4 Yaws and Yang [1992] ? 39 2.2.3.0×10−4 Yaws and Yang [1992] ? 39 1.3-tetramethylpentane C9 H20 2.mpch-mainz.5-trimethylhexane C9 H20 2.9×10−4 Yaws and Yang [1992] ? 39 1.4.7×10−4 Yaws and Yang [1992] ? 39 1.9×10−4 [K] reference Yaws and Yang [1992] type ? note 39 2.R.2.

1×10−4 1.html) −d ln kH d(1/T ) substance 3-ethyl-2.5×10−4 Yaws and Yang [1992] ? 39 1.de/~sander/res/henry.2-dimethyloctane C10 H22 2.4-dimethylpentane C9 H20 3.7×10−4 Yaws and Yang [1992] ? 39 1.4-dimethyloctane C10 H22 2.8×10−4 [K] reference Yaws and Yang [1992] type ? note 39 1.mpg.4×10−4 2.7×10−4 Yaws and Yang [1992] ? 39 1.6×10−4 Yaws and Yang [1992] ? 39 .7×10−4 Yaws and Yang [1992] ? 39 1.6×10−4 Yaws and Yang [1992] ? 39 1.3-diethylpentane C9 H20 decane C10 H22 2-methylnonane C10 H22 3-methylnonane C10 H22 4-methylnonane C10 H22 5-methylnonane C10 H22 2.7×10−4 Yaws and Yang [1992] ? 39 1.7×10−4 Yaws and Yang [1992] ? 39 1.5-dimethyloctane C10 H22 2.2-dimethylpentane C9 H20 3-ethyl-2.5×10−4 Yaws and Yang [1992] ? 39 1.3-dimethylpentane C9 H20 3-ethyl-2.mpch-mainz.3-dimethyloctane C10 H22 2.5×10−4 Yaws and Yang [1992] ? 39 1. Sander: Henry’s law constants (http://www.6-dimethyloctane C10 H22 kH [M/atm] 1.8×10−4 Mackay and Shiu [1981] Yaws and Yang [1992] Yaws and Yang [1992] L ? ? 39 39 1.20 R.8×10−4 Yaws and Yang [1992] ? 39 1.

4-dimethyloctane C10 H22 4.5×10−4 Yaws and Yang [1992] ? 39 1.mpg.6×10−4 Yaws and Yang [1992] ? 39 1.3-trimethylheptane C10 H22 2.7-dimethyloctane C10 H22 3.6×10−4 Yaws and Yang [1992] ? 39 1.4-dimethyloctane C10 H22 3.3-dimethyloctane C10 H22 3.5-dimethyloctane C10 H22 3-ethyloctane C10 H22 4-ethyloctane C10 H22 2. Sander: Henry’s law constants (http://www.5×10−4 Yaws and Yang [1992] ? 39 1.2.5-dimethyloctane C10 H22 3.6-dimethyloctane C10 H22 4.de/~sander/res/henry.7×10−4 [K] reference Yaws and Yang [1992] type ? note 39 1.4-trimethylheptane C10 H22 kH [M/atm] 1.mpch-mainz.6×10−4 Yaws and Yang [1992] ? 39 .5×10−4 Yaws and Yang [1992] ? 39 1.html) −d ln kH d(1/T ) 21 substance 2.6×10−4 Yaws and Yang [1992] ? 39 1.5×10−4 Yaws and Yang [1992] ? 39 1.5×10−4 Yaws and Yang [1992] ? 39 1.R.2.6×10−4 Yaws and Yang [1992] ? 39 1.

5-trimethylheptane C10 H22 kH [M/atm] 1.4.3.4-trimethylheptane C10 H22 3.22 R.4.2.mpg.mpch-mainz.3.8×10−4 Yaws and Yang [1992] ? 39 1.5.4×10−4 Yaws and Yang [1992] ? 39 1.5×10−4 Yaws and Yang [1992] ? 39 1.3.6×10−4 Yaws and Yang [1992] ? 39 1.4×10−4 Yaws and Yang [1992] ? 39 .3.5×10−4 Yaws and Yang [1992] ? 39 1.6×10−4 [K] reference Yaws and Yang [1992] type ? note 39 1.5-trimethylheptane C10 H22 3.4.6-trimethylheptane C10 H22 2.4.3×10−4 Yaws and Yang [1992] ? 39 1.4-trimethylheptane C10 H22 2.html) −d ln kH d(1/T ) substance 2.4×10−4 Yaws and Yang [1992] ? 39 1.3-trimethylheptane C10 H22 2.6-trimethylheptane C10 H22 2.5-trimethylheptane C10 H22 2.3. Sander: Henry’s law constants (http://www.4.4×10−4 Yaws and Yang [1992] ? 39 1.3.de/~sander/res/henry.4-trimethylheptane C10 H22 2.2.7×10−4 Yaws and Yang [1992] ? 39 1.4×10−4 Yaws and Yang [1992] ? 39 1.6-trimethylheptane C10 H22 2.5-trimethylheptane C10 H22 3.4-trimethylheptane C10 H22 3.5-trimethylheptane C10 H22 2.5-trimethylheptane C10 H22 2.5×10−4 Yaws and Yang [1992] ? 39 1.3×10−4 Yaws and Yang [1992] ? 39 1.

2.5×10−4 Yaws and Yang [1992] ? 39 1.R.4×10−4 Yaws and Yang [1992] ? 39 1.6×10−4 Yaws and Yang [1992] ? 39 1.4×10−4 Yaws and Yang [1992] ? 39 1.5×10−4 [K] reference Yaws and Yang [1992] type ? note 39 1.2×10−4 Yaws and Yang [1992] ? 39 .4×10−4 Yaws and Yang [1992] ? 39 1.3.html) −d ln kH d(1/T ) 23 substance 3-ethyl-2-methylheptane C10 H22 4-ethyl-2-methylheptane C10 H22 5-ethyl-2-methylheptane C10 H22 3-ethyl-3-methylheptane C10 H22 4-ethyl-3-methylheptane C10 H22 3-ethyl-5-methylheptane C10 H22 3-ethyl-4-methylheptane C10 H22 4-ethyl-4-methylheptane C10 H22 4-propylheptane C10 H22 4-isopropylheptane C10 H22 2.6×10−4 Yaws and Yang [1992] ? 39 1.7×10−4 Yaws and Yang [1992] ? 39 1.mpg.mpch-mainz.de/~sander/res/henry.3.4×10−4 Yaws and Yang [1992] ? 39 1. Sander: Henry’s law constants (http://www.4-tetramethylhexane C10 H22 kH [M/atm] 1.2.2×10−4 Yaws and Yang [1992] ? 39 1.6×10−4 Yaws and Yang [1992] ? 39 1.3-tetramethylhexane C10 H22 2.

mpch-mainz.2.24 R.4×10−4 Yaws and Yang [1992] ? 39 1.3. Sander: Henry’s law constants (http://www.5-tetramethylhexane C10 H22 2.4.5-tetramethylhexane C10 H22 2.4-tetramethylhexane C10 H22 2.5.4-dimethylhexane C10 H22 4-ethyl-2.html) −d ln kH d(1/T ) substance 2.3-dimethylhexane C10 H22 3-ethyl-2.2×10−4 Yaws and Yang [1992] ? 39 1.2.4×10−4 Yaws and Yang [1992] ? 39 1.3.mpg.4.2-dimethylhexane C10 H22 4-ethyl-2.4.8×10−4 Yaws and Yang [1992] ? 39 1.6×10−4 [K] reference Yaws and Yang [1992] type ? note 39 1.4.2×10−4 Yaws and Yang [1992] ? 39 1.3×10−4 Yaws and Yang [1992] ? 39 1.de/~sander/res/henry.3.5×10−4 Yaws and Yang [1992] ? 39 .4-tetramethylhexane C10 H22 2.3×10−4 Yaws and Yang [1992] ? 39 1.5×10−4 Yaws and Yang [1992] ? 39 1.4×10−4 Yaws and Yang [1992] ? 39 1.4-dimethylhexane C10 H22 3-ethyl-2.5-tetramethylhexane C10 H22 3.3.4-tetramethylhexane C10 H22 2.2.3.4×10−4 Yaws and Yang [1992] ? 39 1.4.3-dimethylhexane C10 H22 4-ethyl-2.2-dimethylhexane C10 H22 3-ethyl-2.3.4-tetramethylhexane C10 H22 3-ethyl-2.0×10−4 Yaws and Yang [1992] ? 39 1.5-tetramethylhexane C10 H22 2.3.5-tetramethylhexane C10 H22 2.3.2.6×10−4 Yaws and Yang [1992] ? 39 1.4×10−4 Yaws and Yang [1992] ? 39 1.5-dimethylhexane C10 H22 kH [M/atm] 1.2×10−4 Yaws and Yang [1992] ? 39 1.

0×10−4 Yaws and Yang [1992] ? 39 1.3-diethyl-2-methylpentane C10 H22 2.3-trimethylpentane C10 H22 3-ethyl-2.3×10−4 Yaws and Yang [1992] ? 39 1.3.3×10−4 Yaws and Yang [1992] ? 39 1.4-pentamethylpentane C10 H22 2.mpch-mainz.3.3×10−4 [K] reference Yaws and Yang [1992] type ? note 39 1.4×10−4 Yaws and Yang [1992] ? 39 1.3×10−4 Yaws and Yang [1992] ? 39 .4.de/~sander/res/henry.1×10−4 Yaws and Yang [1992] ? 39 1.4-diethylhexane C10 H22 3-isopropyl-2-methylhexane C10 H22 2.4-trimethylpentane C10 H22 3.4-dimethyl-3-isopropylpentane C10 H22 kH [M/atm] 1.4-pentamethylpentane C10 H22 3-ethyl-2.R.0×10−4 Yaws and Yang [1992] ? 39 1.1×10−4 Yaws and Yang [1992] ? 39 1.0×10−4 Yaws and Yang [1992] ? 39 1.mpg.2.3. Sander: Henry’s law constants (http://www.1×10−4 Yaws and Yang [1992] ? 39 1.2.3-dimethylhexane C10 H22 3-ethyl-3.3×10−4 Yaws and Yang [1992] ? 39 1.3-diethylhexane C10 H22 3.4-dimethylhexane C10 H22 3.3.2.2.html) −d ln kH d(1/T ) 25 substance 4-ethyl-3.4-trimethylpentane C10 H22 3-ethyl-2.

8×10−2 Yaws and Yang [1992] ? 39 1.de/~sander/res/henry.1×10−3 Yaws and Yang [1992] ? 39 4.1×10−1 Yaws and Yang [1992] ? 39 3.26 R.1 Yaws and Yang [1992] ? 39 . Sander: Henry’s law constants (http://www.html) −d ln kH d(1/T ) substance undecane C11 H24 dodecane C12 H26 tridecane C13 H28 tetradecane C14 H30 pentadecane C15 H32 hexadecane C16 H34 heptadecane C17 H36 octadecane C18 H38 nonadecane C19 H40 eicosane C20 H42 kH [M/atm] 5.3×10−4 [K] reference Mackay and Shiu [1981] Yaws and Yang [1992] Mackay and Shiu [1981] Yaws and Yang [1992] Yaws and Yang [1992] type L ? L ? ? note 39 39 39 8.mpg.5×10−4 1.8×10−4 Yaws and Yang [1992] ? 39 2.4×10−1 Yaws and Yang [1992] ? 39 3.3×10−3 Yaws and Yang [1992] ? 39 1.5×10−5 5.4×10−4 4.4×10−4 1.mpch-mainz.

3×10−3 1.3×10−2 5.1×10−3 5.2-dimethylcyclohexane C6 H10 (CH3 )2 trans-1.9×10−3 9.1×10−3 5.8×10−3 2.6×10−3 5. Yaws and Yang [1975] [1981] [1995] [1992] [1993] [1975] [1981] [1992] [1988] [1982] [1993] [1992] L ? V L M ? X V L ? X X ? ? ? ? V L ? V L M ? X V L ? ? 39.8×10−3 2. Yaws and Yang Hansen et al.6×10−1 1.4×10−3 6.8×10−3 2.8×10−3 2.html) −d ln kH d(1/T ) 27 substance kH [M/atm] 1.5×10−4 7.5×10−3 6.3×10−3 9.1×10−2 1.5×10−4 5.4-dimethylcyclohexane C6 H10 (CH3 )2 1. Hine and Mookerjee Mackay and Shiu Yaws and Yang Ashworth et al.1×10−2 9.3-trimethylcyclopentane C5 H7 (CH3 )3 propylcyclopentane C5 H9 C3 H7 pentylcyclopentane C5 H9 C5 H11 decahydronaphthalene C10 H18 (decalin) [91-17-8] 39 39 1.6×10−3 6.4×10−3 5.3×10−3 2. [1977] Yaws and Yang [1992] Hine and Mookerjee Mackay and Shiu Hansen et al.3×10−3 4100 Mackay and Shiu [1981] Yaws and Yang [1992] Mackay and Shiu [1981] Yaws and Yang [1992] Ashworth et al.1.8×10−3 2.4×10−3 2.5×10−3 9. Yaws and Yang Hansen et al.1×10−3 1. Hine and Mookerjee Mackay and Shiu Yaws and Yang Yaws and Yang [1975] [1981] [1992] [1975] [1981] [1995] [1992] [1993] [1975] [1981] [1992] [1992] 39 9400 9100 39 3 cis-1.1×10−3 [K] 1700 reference type note cycloalkanes (C and H only) cyclopropane C3 H6 cyclopentane C5 H10 Wilhelm et al.1×10−3 1.4×10−4 Mackay and Shiu [1981] Yaws and Yang [1992] Mackay and Shiu [1981] L ? L 39 1.2-dimethylcyclohexane C6 H10 (CH3 )2 trans-1.6×10−3 5.de/~sander/res/henry. 41 3400 3300 39 3 cyclohexane C6 H12 3200 710 cycloheptane C7 H14 cyclooctane C8 H16 methylcyclopentane C5 H9 CH3 methylcyclohexane C6 H11 CH3 39 3 3 13 39 13 39 Hoff et al. [1988] L ? L ? X 39 39 3 .mpg. Sander: Henry’s law constants (http://www.2×10−3 5. USEPA Hoff et al.8×10−3 2.1×10−3 6.R.6×10−3 5. [1993] Yaws and Yang [1992] Hine and Mookerjee Mackay and Shiu Yaws and Yang Hine and Mookerjee Mackay and Shiu Hansen et al.7×10−3 2.6×10−3 2.mpch-mainz.

3×10−3 [K] reference type note aliphatic alkenes and cycloalkenes (C and H only) ethene C2 H4 (ethylene) Loomis Hine and Mookerjee Wilhelm et al.4×10−3 4.5×10−3 4.7×10−3 5.8×10−3 4.8×10−3 2.mpch-mainz.9×10−3 1.5×10−3 3000 Hine and Mookerjee Wilhelm et al.28 R.9×10−3 4.0×10−3 4.7×10−3 4.6×10−3 4.9×10−3 1.3×10−3 4.8×10−3 7. Sander: Henry’s law constants (http://www.3×10−2 1.7×10−3 4. Mackay and Shiu Seinfeld Yaws and Yang Hine and Mookerjee Wilhelm et al.html) −d ln kH d(1/T ) substance kH [M/atm] 4.7×10−3 4.4×10−3 Irrmann [1965] X 42 4.mpg. Mackay and Shiu Yaws and Yang Hine and Mookerjee Mackay and Shiu Yaws and Yang Mackay and Shiu Yaws and Yang [1975] [1977] [1981] [1992] [1975] [1981] [1992] [1981] [1992] V L L ? V L ? L ? V ? V 39 39 39 Hine and Mookerjee [1975] Yaws and Yang [1992] Hine and Mookerjee [1975] 39 1. Mackay and Shiu Yaws and Yang Hine and Mookerjee Wilhelm et al.3×10−3 4.5×10−3 2.8×10−3 4.9×10−3 Hine and Mookerjee [1975] Mackay and Shiu [1981] Yaws and Yang [1992] V L ? 39 .9×10−3 4.4×10−3 4.8×10−3 4.4×10−3 4.0×10−3 1.7×10−3 1.4×10−3 4.de/~sander/res/henry. Mackay and Shiu Yaws and Yang Irrmann [1928] [1975] [1977] [1981] [1986] [1992] [1975] [1977] [1981] [1992] [1975] [1977] [1981] [1992] [1965] X V L L ? ? V L L ? V L L ? X 1 1800 13 39 propene C3 H6 (propylene) 1-butene C4 H8 3400 39 6400 cis-2-butene C4 H8 trans-2-butene C4 H8 2-methylpropene C4 H8 (isobutene) 1-pentene C5 H10 cis-2-pentene C5 H10 trans-2-pentene C5 H10 2-methyl-2-butene C5 H10 3-methyl-1-butene C5 H10 39 42 4.5×10−3 2.

3×10−3 3.5×10−3 [K] reference Hine and Mookerjee Mackay and Shiu Yaws and Yang Mackay and Shiu Yaws and Yang Hine and Mookerjee Mackay and Shiu Yaws and Yang Yaws and Yang [1975] [1981] [1992] [1981] [1992] [1975] [1981] [1992] [1992] type V L ? L ? V L ? ? note 39 39 39 39 2.3-dimethyl-1.2×10−2 2.3-butadiene C6 H10 cyclopentene C5 H8 cyclohexene C6 H10 1-methylcyclohexene C6 H9 CH3 1.3-butadiene C4 H6 kH [M/atm] 2.1×10−3 1.3×10−2 Hine and Mookerjee [1975] Yaws and Yang [1992] Hine and Mookerjee Nielsen et al.mpg.4×10−3 1.3×10−2 2.5×10−3 7.5-cycloheptatriene C7 H8 1.3.4×10−3 8.4×10−3 3.mpch-mainz.8×10−2 1.4×10−2 1.5×10−2 2.2×10−3 Hine and Mookerjee [1975] Mackay and Shiu [1981] Hine and Mookerjee Mackay and Shiu Yaws and Yang Yaws and Yang [1975] [1981] [1992] [1992] V L V L ? ? 39 39 methylbutadiene C5 H8 (isoprene) 1.6×10−2 1.6×10−2 1.4×10−3 2.2×10−2 1.de/~sander/res/henry.6×10−3 2.5×10−3 2.3×10−2 1.4×10−3 4500 Hine and Mookerjee Wilhelm et al.4×10−2 1.1×10−2 Hine and Mookerjee [1975] V 1.6×10−3 1.3×10−2 8.1×10−3 1.5-hexadiene C6 H10 2.6×10−2 2.R. Mackay and Shiu Yaws and Yang Hine and Mookerjee Mackay and Shiu Karl and Lindinger Yaws and Yang Hine and Mookerjee Mackay and Shiu Yaws and Yang Hine and Mookerjee [1975] [1977] [1981] [1992] [1975] [1981] [1997] [1992] [1975] [1981] [1992] [1975] V L L ? V L M ? V L ? V 39 43 39 39 2.1×10−1 Yaws and Yang [1992] ? 39 .6×10−3 1.6×10−3 3.4×10−2 1.6×10−3 1. Yaws and Yang Hine and Mookerjee [1975] [1994] [1992] [1975] V ? V M ? V 39 39 2.6×10−3 1.3×10−3 8.4-pentadiene C5 H8 1. Sander: Henry’s law constants (http://www.html) −d ln kH d(1/T ) 29 substance 1-hexene C6 H12 2-methyl-1-pentene C6 H12 4-methyl-1-pentene C6 H12 1-heptene C7 H14 trans-2-heptene C7 H14 1-octene C8 H16 1-nonene C9 H18 1.

Hine and Mookerjee Wilhelm et al. [1977] 39 39 39 1.2×10−2 1.1×10−2 9.1×10−2 2.3×10−2 5.5×10−2 4.mpg.4×10−2 see note 5.9×10−3 7.0×10−2 4.2×10−2 9.0×10−2 2.1×10−2 3.6×10−2 5.5×10−2 4. [1977] Yaws and Yang [1992] Hine and Mookerjee Mackay and Shiu Yaws and Yang Wilhelm et al.9×10−1 Yaws and Yang [1992] ? 39 .4×10−2 1.30 R.5×10−2 1.mpch-mainz.6×10−2 1.de/~sander/res/henry. Mackay and Shiu Yaws and Yang Hine and Mookerjee Mackay and Shiu Yaws and Yang Hine and Mookerjee Yaws and Yang [1975] [1981] [1992] [1977] [1975] [1977] [1981] [1992] [1975] [1981] [1992] [1975] [1992] V L ? V L ? ? V L L ? V L ? V ? V ? V ? V ? L 39 39 44 1900 39 39 39 Hine and Mookerjee [1975] Yaws and Yang [1992] Hine and Mookerjee [1975] Yaws and Yang [1992] Hine and Mookerjee [1975] Yaws and Yang [1992] 1700 Wilhelm et al.2×10−2 6.4×10−2 7.0×10−3 3.2×10−2 4.html) −d ln kH d(1/T ) substance kH [M/atm] 4.9×10−2 9. Sander: Henry’s law constants (http://www.8×10−2 [K] reference type note aliphatic alkynes (C and H only) ethyne C2 H2 (acetylene) propyne CH3 CCH (methylacetylene) 1-butyne C2 H5 CCH (ethylacetylene) 1-pentyne C3 H7 CCH 1-hexyne C4 H9 CCH 1-heptyne C5 H11 CCH 1-octyne C6 H13 CCH 1-nonyne C7 H15 CCH 3-buten-1-yne CH2 CHCCH (vinylacetylene) butadiyne C4 H2 (biacetylene) 1800 Hine and Mookerjee [1975] Wilhelm et al.

Ettre et al.6×10−1 1.2×10−1 1.8×10−1 1.5×10−1 1. Nielsen et al.1×10−1 2.6×10−1 1. Leighton and Calo Ervin et al.8×10−1 1.6×10−1 1.1×10−1 1. Mackay et al.9×10−1 1.2×10−1 1.5×10−1 1.de/~sander/res/henry. Leighton and Calo Allen et al.8×10−1 1.8×10−1 1. Ashworth et al. Vitenberg et al.5×10−1 1.6×10−1 [K] reference type note mononuclear aromatics (C and H only) benzene C6 H6 [71-43-2] Hine and Mookerjee Mackay et al.8×10−1 1. Sander: Henry’s law constants (http://www.6×10−1 1. McAuliffe Hine and Mookerjee Mackay et al.9×10−1 1. Wasik and Tsang Bohon and Claussen Hoff et al. Hartkopf and Karger Yaws and Yang USEPA Staudinger and Roberts Bissonette et al. Nielsen et al.4×10−1 1.8×10−1 1. Dewulf et al. Vitenberg et al. Dewulf et al.5×10−1 1. USEPA Kavanaugh and Trussell Ervin et al. Wasik and Tsang Bohon and Claussen Hoff et al.3×10−1 2. Mackay et al. Lamarche and Droste Allen et al.6×10−1 1. Staudinger and Roberts Bissonette et al.5×10−1 1.8×10−1 1. Mackay and Shiu Ettre et al.1×10−1 1.7×10−1 1. [1975] [1979] [1979] [1981] [1993] [1993] [1994] [1995] [1975] [1970] [1951] [1993] [1973] [1997] [1992] [1992] [1982] [1980] [1980] [1996] [1990] [1988] [1981] [1998] [1971] [1975] [1979] [1979] [1981] [1992] [1993] [1993] [1994] [1995] [1975] [1970] [1951] [1993] [1973] [1992] [1982] [1996] [1990] [1988] [1981] [1980] [1989] [1998] V M T L X M M M M M V M M M ? X X X X L X X X E X V M T L X X M M M M M V M M ? X L X X X X X E 45 3800 3600 4500 4200 3900 2200 4300 5300 4100 4300 3200 4000 43 39 3 3 3 3 3 3 3 45 methylbenzene C6 H5 CH3 (toluene) [108-88-3] 45 45 3400 4100 5900 4600 1900 4000 5000 3000 3700 4900 8400 39 3 3 3 3 3 3 .R.5×10−1 1.8×10−1 1.mpch-mainz.6×10−1 1.8×10−1 1.5×10−1 1.5×10−1 1.html) −d ln kH d(1/T ) 31 substance kH [M/atm] 1.8×10−1 1. Mackay and Shiu Kolb et al. Robbins et al.8×10−1 1. Robbins et al.5×10−1 1.6×10−1 1. Hartkopf and Karger Karl and Lindinger Yaws and Yang Cooling et al.7×10−1 2. Ashworth et al.7×10−1 1.8×10−1 1.7×10−1 1.mpg.8×10−1 1.5×10−1 1.8×10−1 1.5×10−1 1.8×10−1 1.9×10−1 2.

9×10−2 [K] reference Hine and Mookerjee Mackay and Shiu Robbins et al.1×10−1 1.mpch-mainz.4×10−1 1. Staudinger and Roberts Bissonette et al.mpg.4×10−1 4.4×10−1 1.1×10−1 2. [1975] [1981] [1993] [1995] [1970] [1992] [1988] [1996] [1990] [1975] [1981] [1995] [1951] [1992] [1988] [1996] [1990] [1975] [1981] [1995] [1951] [1970] [1992] [1993] [1990] [1988] [1996] [1981] [1992] [1975] [1981] [1995] [1992] [1993] [1981] [1992] [1988] type V L M M M ? X L X V L M V ? X L X V L M V M ? X X X L L ? V L M ? X L ? X L ? note 3400 4200 5400 3200 4000 5600 39 3 3 4000 3300 4200 6000 39 3 3 4500 5400 3000 5300 3500 3800 39 3 3 3 39 4300 4200 39 3 39 3 1. Bohon and Claussen Yaws and Yang Ashworth et al.4-dimethylbenzene C6 H4 (CH3 )2 (p-xylene) [106-42-3] 1. Bissonette et al.7×10−1 1.9×10−1 2.7×10−1 1.9×10−1 1.7×10−1 1.2×10−1 1.3×10−1 1.4.6×10−1 1.7×10−1 1.6×10−1 1.3×10−1 1. Staudinger and Roberts Mackay and Shiu Yaws and Yang Hine and Mookerjee Mackay and Shiu Hansen et al.3×10−1 1.5×10−1 2.7×10−1 1.9×10−1 2.3-trimethylbenzene C6 H3 (CH3 )3 [526-73-8] 1.de/~sander/res/henry.9×10−1 2.3×10−1 3.5×10−1 1.6×10−1 2.3×10−1 1. Ashworth et al.4×10−1 1. Wasik and Tsang Yaws and Yang Ashworth et al.5×10−1 1. Bohon and Claussen Wasik and Tsang Yaws and Yang Hansen et al.2×10−1 1. Staudinger and Roberts Bissonette et al. Yaws and Yang Hansen et al.2.6×10−1 1. Hine and Mookerjee Mackay and Shiu Dewulf et al.2.4-trimethylbenzene C6 H3 (CH3 )3 [95-63-6] kH [M/atm] 1. Hine and Mookerjee Mackay and Shiu Dewulf et al.5-tetramethylbenzene C6 H2 (CH3 )4 3600 Mackay and Shiu [1981] Yaws and Yang [1992] 39 . Dewulf et al.4×10−1 1.6×10−1 1. Sander: Henry’s law constants (http://www.2×10−1 1.2-dimethylbenzene C6 H4 (CH3 )2 (o-xylene) [95-47-6] 1.0×10−1 1.5×10−1 1.3.2.5-trimethylbenzene C6 H3 (CH3 )3 (mesitylene) [108-67-8] 1.7×10−1 1.32 R. Mackay and Shiu Yaws and Yang Ashworth et al.3-dimethylbenzene C6 H4 (CH3 )2 (m-xylene) [108-38-3] 1.0×10−2 3.8×10−1 1.html) −d ln kH d(1/T ) substance 1.9×10−1 2.

Sander: Henry’s law constants (http://www.0×10−2 7. Yaws and Yang Hansen et al. Hartkopf and Karger Yaws and Yang Staudinger and Roberts USEPA Bissonette et al. Hine and Mookerjee Mackay and Shiu Yaws and Yang Ashworth et al. Mackay and Shiu Robbins et al.2×10−1 1.2×10−2 8.8×10−2 7.mpch-mainz. Dewulf et al.7×10−2 7. Mackay and Shiu Yaws and Yang [1975] [1979] [1979] [1981] [1993] [1995] [1951] [1993] [1973] [1992] [1996] [1982] [1990] [1988] [1980] [1998] [1975] [1981] [1992] [1988] [1975] [1981] [1993] [1992] [1993] [1981] [1992] type V M T L M M V ? M ? L X X X X E V L ? X V L ? ? X L ? note 4600 4600 13 39 3 3 3 3 6100 5100 1700 5500 5000 5500 3700 39 3 3200 13 39 3 39 2.9×10−2 8.0×10−1 1.5×10−2 8.0×10−1 2.0×10−1 Mackay and Shiu [1981] Yaws and Yang [1992] L ? 39 8.3×10−1 Hine and Mookerjee [1975] Mackay and Shiu [1981] Hine and Mookerjee [1975] Mackay and Shiu [1981] Mackay and Shiu [1981] V L V L L . Ashworth et al.2×10−1 1.4×10−1 9.5×10−1 1.2×10−1 1.8×10−2 9.mpg.2×10−1 1.1×10−1 1.2×10−1 1. Bohon and Claussen Hoff et al.9×10−2 6.R.7×10−1 1. Allen et al.1×10−1 1. Hine and Mookerjee Mackay and Shiu Hoff et al.html) −d ln kH d(1/T ) 33 substance ethylbenzene C6 H5 C2 H5 [100-41-4] propylbenzene C6 H5 C3 H7 [103-65-1] (2-propyl)-benzene C6 H5 C3 H7 (isopropylbenzene.4×10−1 1. Ervin et al.1×10−2 Hine and Mookerjee Mackay and Shiu Yaws and Yang Mackay and Shiu [1975] [1981] [1992] [1981] V L ? L 39 8.8×10−2 7.5×10−1 1. cumene) [98-82-8] 1-ethyl-2-methylbenzene C6 H4 CH3 C2 H5 (o-ethyltoluene) [611-14-3] 1-ethyl-4-methylbenzene C6 H4 CH3 C2 H5 (p-ethyltoluene) [622-96-8] butylbenzene C6 H5 C4 H9 [104-51-8] 2-methylpropylbenzene C6 H5 C4 H9 [538-93-2] sec-butylbenzene C6 H5 C4 H9 [135-98-8] tert-butylbenzene C6 H5 C4 H9 [98-06-6] 1-isopropyl-4-methylbenzene C6 H4 CH3 C3 H7 kH [M/atm] 1.4×10−2 1.4×10−1 2.de/~sander/res/henry.3×10−1 1.3×10−1 1.8×10−2 2. Mackay et al.1×10−1 1.6×10−2 3.8×10−1 6.6×10−1 1.3×10−1 [K] reference Hine and Mookerjee Mackay et al.1×10−2 6.3×10−1 1.

Sander: Henry’s law constants (http://www. [1990] USEPA [1982] Yaws and Yang [1992] ? X X ? 39 3 3 39 3.7×10−1 6.7×10−1 2.html) −d ln kH d(1/T ) substance pentylbenzene C6 H5 C5 H11 hexylbenzene C6 H5 C6 H13 C6 H5 C5 H11 (tert-amylbenzene) ethenylbenzene C8 H8 (styrene) 1-ethenyl-3-methylbenzene C9 H10 (m-methylstyrene) 1-ethenyl-4-methylbenzene C9 H10 (p-methylstyrene) kH [M/atm] 1.5×10−1 Yaws and Yang [1992] ? 39 .0×10−2 4.5×10−2 Hine and Mookerjee [1975] V 3.34 R.6×10−1 4800 4200 Yaws and Yang [1992] Bissonette et al.6×10−2 [K] reference Mackay and Shiu [1981] Yaws and Yang [1992] Yaws and Yang [1992] type L ? ? note 39 39 5.mpch-mainz.de/~sander/res/henry.8×10−1 2.9×10−1 3.mpg.

R.mpch-mainz.7 1.mpg.5-dimethylnaphthalene C12 H12 2.4 1. Mackay and Shiu Bohon and Claussen Yaws and Yang Meylan and Howard USEPA Mackay and Shiu Mackay and Shiu Yaws and Yang Mackay and Shiu Hansen et al.2 1.7 2.2 1. Yaws and Yang Hansen et al.5 5. Mackay and Shiu Mackay and Shiu Bohon and Claussen Yaws and Yang [1979] [1981] [1981] [1951] [1992] M L M V ? 39 .9 8. Mackay and Shiu Yaws and Yang [1975] [1979] [1979] [1981] [1951] [1992] [1991] [1982] [1981] [1981] [1992] [1981] [1995] [1992] [1993] [1981] [1992] V M T L V ? X X L M ? L M ? X L ? L ? ? 39 3 3 39 39 3 39 Mackay and Shiu [1981] Yaws and Yang [1992] Yaws and Yang [1992] 39 39 2.6 3.7 Yaws and Yang [1992] ? 39 8.3×10−1 Yaws and Yang [1992] ? 39 2. Sander: Henry’s law constants (http://www.1 2.4 2.4-dimethylnaphthalene C12 H12 1.de/~sander/res/henry.9 2.1×10−1 2.0 5.3 1.4 3600 1200 1200 Hine and Mookerjee Mackay et al.6 Yaws and Yang [1992] ? 39 1.7 2.2 Mackay et al.1×10−3 2.1 2. Mackay et al.3-dimethylnaphthalene C12 H12 1.0 2.3-dimethylnaphthalene C12 H12 2.6-dimethylnaphthalene C12 H12 biphenyl (C6 H5 )2 2.6 1.3 3.1×10−3 2.5 3.html) −d ln kH d(1/T ) 35 substance kH [M/atm] 4.9×10−2 [K] reference type note terpenes and polynuclear aromatics (C and H only) pinene C10 H16 [127-91-3] naphthalene C10 H8 Karl and Lindinger [1997] M 43 1-methylnaphthalene C10 H7 CH3 2-methylnaphthalene C10 H7 CH3 1-ethylnaphthalene C10 H7 C2 H5 2-ethylnaphthalene C10 H7 C2 H5 1.1 2.0 Yaws and Yang [1992] ? 39 1.

7×101 1.3×101 6.4-tetrahydronaphthalene C10 H12 (tetralin) [119-64-2] kH [M/atm] 1.8 4.4 1.6×101 1.8×101 9. [1992] tenHulscher et al.3.5×103 1.mpg.5 1.5×101 3.6×10−1 2. [1992] tenHulscher et al.3×10−1 5400 Ashworth et al.9×101 2. [1992] tenHulscher et al.3-cd]pyrene benzo[a]pyrene C20 H12 [50-32-8] benzo[ghi]perylene C22 H12 [191-24-2] 1.4×101 9.5 3.7×103 9. [1992] USEPA [1982] tenHulscher et al.5×101 2.mpch-mainz.2×101 1.7×10−1 1. [1992] tenHulscher et al. Mackay and Shiu Mackay and Shiu Meylan and Howard USEPA Mackay and Shiu Mackay and Shiu USEPA Meylan and Howard Hine and Mookerjee Mackay and Shiu Mackay and Shiu Meylan and Howard USEPA Mackay and Shiu Mackay and Shiu [1975] [1979] [1981] [1981] [1982] [1991] [1975] [1979] [1981] [1981] [1991] [1982] [1981] [1981] [1982] [1991] [1975] [1981] [1981] [1991] [1982] [1981] [1981] type V M L M X X V M L M X X L M X X V L M X X L M L X X X X X X X X X note 2800 3 3 4700 3 3 3000 3 3 4000 3 3 6900 5900 1900 5500 5900 3600 110 4700 3200 Mackay and Shiu [1981] tenHulscher et al. [1992] 3 3 3 3 3 3 3 3 3 5. Sander: Henry’s law constants (http://www.2×101 4.5 1.2 6.8×101 2.2.5×101 2.1 6.6×10−1 1.0×101 8.html) −d ln kH d(1/T ) substance acenaphthene C12 H10 [83-32-9] phenanthrene C14 H10 2.3-benzindene C13 H10 (fluorene) [86-73-7] anthracene C14 H10 [120-12-7] pyrene C16 H10 [129-00-0] fluoranthene C16 H10 [206-44-0] benzo[a]fluoranthene benzo[b]fluoranthene benzo[k]fluoranthene indeno[1.9×103 1.0×103 [K] reference Hine and Mookerjee Mackay et al.36 R.5×101 8.0×101 5.2×103 3. Mackay and Shiu Mackay and Shiu USEPA Meylan and Howard Hine and Mookerjee Mackay et al.de/~sander/res/henry.5×10−1 4.7×103 2.2.1×102 1. [1988] X 3 . [1992] USEPA [1982] tenHulscher et al.

Sander: Henry’s law constants (http://www.2×102 5. H.9×102 2.2×102 2. Hine and Weimar Snider and Dawson Yaws and Yang Butler et al. [1935] Snider and Dawson [1985] Koga [1995] M M M 50 .0×102 1.0×102 1. Burnett Timmermans Gaffney and Senum Snider and Dawson Yaws and Yang Schaffer and Daubert Meylan and Howard Butler et al. and O only) methanol CH3 OH Butler et al.6×102 1.2×102 1. [1935] Snider and Dawson [1985] 8.0×101 see note 8300 Butler et al.R.7×102 1.de/~sander/res/henry.3×102 1.4×102 1.6×102 2.mpg.3×102 1.2×102 1.2×102 1.3×102 2. Buttery et al.X X M M ? X X M M M C ? M R M ? M M M M C M M V M M M 46 47 48 39 3 3 5200 5600 ethanol C2 H5 OH 47 48 6600 6400 1-propanol C3 H7 OH [71-23-8] 39 3 3 46 7500 39 2-propanol C3 H7 OH (isopropanol) [67-63-0] 1-butanol C4 H9 OH [71-36-3] 7500 39 46 7200 49 2-butanol C4 H10 O (sec-butanol) [78-92-2] 2-methyl-1-propanol C4 H10 O (isobutanol) [78-83-1] 2-methyl-2-propanol C4 H10 O (tert-butanol) [75-65-0] 7300 Butler et al.mpch-mainz. Burnett Snider and Dawson Snider and Dawson Yaws and Yang Butler et al.5×102 1.1×102 1.1×102 1.4×102 1.4×101 1. Snider and Dawson [1935] [1963] [1960] [1984] [1985] [1992] [1969] [1991] [1935] [1963] [1960] [1984] [1985] [1973] [1992] [1969] [1991] [1935] [1963] [1985] [1985] [1992] [1935] [1965] [1985] [1992] [1935] [1969] [1963] [1985] [1985] [1979] [1935] [1935] [1985] M M M.9×101 1.2×102 1.2×102 1.4×102 1.0×102 [K] reference type note alcohols (ROH) (C.X X M ? X X M M M.8×101 1.5×102 2.8×101 9. Burnett Timmermans Gaffney and Senum Snider and Dawson Rohrschneider Yaws and Yang Schaffer and Daubert Meylan and Howard Butler et al.1×102 8.6×102 2.3×102 8.3×102 1.9×102 2.1×102 2.4×101 7.html) −d ln kH d(1/T ) 37 substance kH [M/atm] 2.4×101 9. Burnett Snider and Dawson Snider and Dawson Friant and Suffet Butler et al. Butler et al.3×102 2.2×102 1.

3×101 Butler et al.9×101 Hine and Mookerjee [1975] V 3.mpch-mainz.html) −d ln kH d(1/T ) substance 1-pentanol C5 H11 OH (amylalcohol) [71-41-0] 2-pentanol C5 H12 O (sec-pentanol) [6032-29-7] 2-methyl-1-butanol C5 H12 O (isopentanol) [137-32-6] 2-methyl-2-butanol C5 H12 O (tert-pentanol) [75-85-4] 2.3×101 5.4×101 8.5×101 5. [1935] M 5. [1935] M 7.1×101 4.2×101 4. Sander: Henry’s law constants (http://www.2×101 Hine and Mookerjee [1975] V 2.mpg. Hine and Mookerjee Buttery et al.2-dimethyl-1-propanol C5 H12 O [75-84-3] 1-hexanol C6 H13 OH [111-27-3] 3-hexanol C6 H14 O [623-37-0] 2-methyl-2-pentanol C6 H14 O [590-36-3] 4-methyl-2-pentanol C6 H14 O [108-11-2] 2-methyl-3-pentanol C6 H14 O [565-67-3] 2.1×101 Butler et al.0×101 6. Hine and Mookerjee Yaws and Yang Hine and Mookerjee [1935] [1969] [1975] [1992] [1975] V M V ? V 39 3. [1935] Butler et al.5×101 5. [1935] Yaws and Yang [1992] Butler et al.3-dimethyl-2-butanol C6 H14 O [594-60-5] 1-heptanol C7 H15 OH [110-70-6] 1-octanol C8 H17 OH [111-87-5] kH [M/atm] 7.0×101 Saxena and Hildemann [1996] E 51 6.0×101 Hine and Mookerjee [1975] V 5.de/~sander/res/henry.6×101 4.2×101 6.38 R.4×101 2.0×101 Butler et al. [1935] type M V ? M note 39 7.9×101 6.7×101 7. Buttery et al.1×101 Hine and Mookerjee [1975] V 2.3×101 Butler et al. Hine and Mookerjee Yaws and Yang Butler et al. Yaws and Yang [1935] [1975] [1992] [1935] [1975] [1969] [1992] V V ? V V M ? 39 39 .9×101 8.8×101 [K] reference Butler et al.

2×101 Yaws and Yang [1992] ? 39.0×102 7200 Pierotti et al. Sander: Henry’s law constants (http://www.8×102 2.7×102 Hine and Mookerjee [1975] V 2.0×102 1.2×103 Yaws and Yang [1992] ? 39 9.0×101 Yaws and Yang [1992] ? 39 1. [1998] M 49 . Yaws and Yang Meylan and Howard USEPA Saxena and Hildemann [1957] [1992] [1991] [1982] [1996] X ? X X E 53 39 3 3 51 6.mpg.mpch-mainz.0×105 Yaws and Yang [1992] ? 39 6.R.html) −d ln kH d(1/T ) 39 substance 1-nonanol C9 H19 OH 1-decanol C10 H21 OH 1-dodecanol C12 H25 OH 1-tetradecanol C14 H29 OH 1-pentadecanol C15 H31 OH 1-hexadecanol C16 H33 OH 1-heptadecanol C17 H35 OH 1-octadecanol C18 H37 OH cyclohexanol C6 H11 OH [108-93-0] 2-propen-1-ol C3 H5 OH (allyl alcohol) [107-18-6] 2-buten-1-ol CH3 CHCHCH2 OH 2-methyl-3-buten-2-ol [115-18-4] kH [M/atm] 6.de/~sander/res/henry.7×101 Yaws and Yang [1992] ? 39 1.5×101 Iraci et al.4×102 3.1×101 Yaws and Yang [1992] ? 39 3.9×105 Yaws and Yang [1992] ? 39 3.0×102 4.1×101 [K] reference Yaws and Yang [1992] type ? note 39 3. 52 1.

9×103 7. 8 3 3 39.1×102 7200 4600 -3300 6600 Gaffney and Senum Parsons et al. m-cresol) [108-39-4] 1-hydroxy-4-methylbenzene HOC6 H4 CH3 (4-cresol.8 51 9.3×102 8. 8 3 3 3 3 .5×103 1. Janini and Quaddora Meylan and Howard USEPA Tremp et al. Yaws and Yang Meylan and Howard Janini and Quaddora Ashworth et al. o-cresol) [95-48-7] 1-hydroxy-3-methylbenzene HOC6 H4 CH3 (3-cresol. Sander: Henry’s law constants (http://www. Howe et al.0×103 1.6×102 8.0×102 7700 Parsons et al.0×103 1. 8 3 1.html) −d ln kH d(1/T ) substance hydroxybenzene C6 H5 OH (phenol) (hydroxymethyl)benzene C6 H5 CH2 OH (benzyl alcohol) [100-51-6] 4-tert-butylphenol (CH3 )3 CC6 H4 OH 1-hydroxy-2-methylbenzene HOC6 H4 CH3 (2-cresol. Saxena and Hildemann [1965] [1984] [1971] [1987] [1986] [1991] [1982] [1993] [1996] type R X M X X X X X E note 6800 3600 7300 48 54 11 3 3 3 55.1×103 5.9×103 1.3×103 2.0×103 [K] reference Hine and Weimar Gaffney and Senum Parsons et al.9×102 3.2×103 2. Yaws and Yang Janini and Quaddora Meylan and Howard Yaws and Yang Janini and Quaddora [1984] [1972] [1992] [1986] [1991] [1992] [1986] X M ? X X ? X 48 56 39. USEPA [1984] [1972] [1992] [1991] [1986] [1988] [1982] X M ? X X X X 48 56 39.mpch-mainz.0×103 2.4×103 6.40 R.6×103 9.9×102 3.3×102 7300 4600 7700 Gaffney and Senum Parsons et al.mpg.8×10−2 1.de/~sander/res/henry.3×102 1. p-cresol) [106-44-5] 1.9×10−1 4.3×102 1. [1972] M 56 8.3-dimethyl-4-hydroxybenzene C8 H10 O (2.3×102 1.4-dimethylphenol) [105-67-9] kH [M/atm] 4.

3-pentanediol C5 H12 O2 2.0×105 < 6.3-butanetriol C4 H10 O3 1.2. Sander: Henry’s law constants (http://www.3-propanediol C3 H8 O2 1.0×106 3.0×1011 Saxena and Hildemann [1996] Saxena and Hildemann [1996] Saxena and Hildemann [1996] Saxena and Hildemann [1996] Saxena and Hildemann [1996] E E E E E 51 51 51 51 51 3.3.2×105 Saxena and Hildemann [1996] Saxena and Hildemann [1996] Bone et al.0×104 < 4. H. [1983] E E M 51 51 8 6. [1983] M M 57 8 > 1.0×1020 Saxena and Hildemann [1996] E 51 3.0×1016 Saxena and Hildemann [1996] E 51 4.0×106 9.mpg. and O only) 1.7×104 4.3-propanetriol C3 H8 O3 (glycerol) 1.0×106 [K] reference type note polyols (R(OH)n ) (C.4-tetrahydroxy butane C4 H10 O4 1.2-ethanediol HO(CH2 )2 OH (ethylene glycol) [107-21-1] 1.3-butanediol C4 H10 O2 1.4.0×106 Butler and Ramchandani [1935] Saxena and Hildemann [1996] Saxena and Hildemann [1996] Saxena and Hildemann [1996] M E E E 57 51 51 51 > 1.6-hexanediol C6 H14 O2 Butler and Ramchandani [1935] Bone et al.html) −d ln kH d(1/T ) 41 substance kH [M/atm] 1.2.5-pentahydroxy pentane C5 H12 O5 1.0×104 > 6.2.4-pentanediol C5 H12 O2 1.3.de/~sander/res/henry.3-butanediol C4 H10 O2 1.0×106 > 4.0×106 Saxena and Hildemann [1996] E 51 3.4-butanediol C4 H10 O2 2.0×108 < 4.0×105 < 5.2-propanediol C3 H8 O2 1.R.0×106 Saxena and Hildemann [1996] E 51 9.0×106 Saxena and Hildemann [1996] E 51 3.2.0×1011 Saxena and Hildemann [1996] E 51 2.5-pentanediol C5 H12 O2 2.mpch-mainz.0×106 Saxena and Hildemann [1996] E 51 .4-butanetriol C4 H10 O3 1.0×1011 5.2.

2.42 R.4.4.0×1016 Saxena and Hildemann [1996] E 51 1.0×106 Saxena and Hildemann [1996] E 51 5.7-heptanediol C7 H16 O2 2.6-hexahydroxy cyclohexane C6 H12 O6 1.0×1020 Saxena and Hildemann [1996] E 51 5.0×1011 Saxena and Hildemann [1996] E 51 4.7-pentahydroxy heptane C7 H16 O5 1.0×106 [K] reference Saxena and Hildemann [1996] type E note 51 3.2.4-pentanediol C6 H14 O2 1.0×1020 Saxena and Hildemann [1996] E 51 4.3.4.3.3.0×106 Saxena and Hildemann [1996] E 51 2.0×106 Saxena and Hildemann [1996] E 51 2.5-pentahydroxy heptane C7 H16 O5 1.0×1020 Saxena and Hildemann [1996] E 51 3.2.html) −d ln kH d(1/T ) substance 2.mpch-mainz.2.mpg.3.3.de/~sander/res/henry.3-hexanediol C8 H18 O2 1.0×1025 Saxena and Hildemann [1996] E 51 4.6-hexahydroxy hexane C6 H14 O6 1.2.5-hexanediol C6 H14 O2 2-methyl-1.6-hexanetriol C6 H14 O3 1.4.3-diethyl-1.2.5.0×1026 Saxena and Hildemann [1996] E 51 2.2.3.0×1025 Saxena and Hildemann [1996] E 51 .0×106 Saxena and Hildemann [1996] E 51 2.0×106 Saxena and Hildemann [1996] E 51 2.4.5.4.5.3-pentanediol C6 H14 O2 2-methyl-2.4-heptanediol C7 H16 O2 2.6-hexahydroxy heptane C7 H16 O6 kH [M/atm] 2.3-propanediol C7 H16 O2 2-ethyl-1.6-pentahydroxy heptane C7 H16 O5 1.0×106 Saxena and Hildemann [1996] E 51 2.5-tetrahydroxy cyclohexane C6 H12 O4 1. Sander: Henry’s law constants (http://www.2.5.

mpch-mainz.7×107 2.4-dihydroxybenzene C6 H4 (OH)2 (hydroquinone) [123-31-9] methyl hydroperoxide CH3 OOH (methylperoxide) [3031-73-0] ethyl hydroperoxide C2 H5 OOH (ethylperoxide) hydroxymethyl hydroperoxide HOCH2 OOH (HMHP.4×102 6000 O’Sullivan et al.html) −d ln kH d(1/T ) 43 substance 1.7×106 1.2-dihydroxybenzene C6 H4 (OH)2 (pyrocatechol) [120-80-9] 1.0×107 4.1×102 5300 5200 Lind and Kok [1994] O’Sullivan et al.5×105 9700 10000 1500 O’Sullivan et al.0 2.0×102 3. [1996] M 1.3-dihydroxybenzene C6 H4 (OH)2 (resorcinol) [108-46-3] 1.R. Sander: Henry’s law constants (http://www.6×106 4.6×103 [K] reference Mackay et al.0×103 < 0. and O only) 3.5×107 Meylan and Howard [1991] Meylan and Howard [1991] Mackay et al.mpg.de/~sander/res/henry. [1995] type V note 8. [1996] E E M 59 60 .3×106 6300 USEPA [1982] X 3 2. [1996] M M 9 3. [1996] Staffelbach and Kok [1993] Zhou and Lee [1992] Staffelbach and Kok [1993] Zhou and Lee [1992] M M M M M 8400 6.6×107 1.1 5600 6600 Jacob [1986] Lelieveld and Crutzen [1991] Villalta et al. [1995] X X V 58 58 peroxides (ROOH) and peroxy radicals (ROO) (C. H.8×105 >1.HMP) [15932-89-5] bis(hydroxymethyl)peroxide HOCH2 OOCH2 OH (BHMP) [17088-73-2] methylperoxy radical CH3 OO peroxyacetyl radical CH3 C(O)O2 [36709-10-1] kH [M/atm] 4.

3 3.0×103 1.4×101 1.5×101 1.6 8.9 2.3×101 2. 49 64 39. 49 64 Zhou and Mopper [1990] Buttery et al.4×104 3.9 3. 49 64 39.0×103 see note 6.3 7. Yaws and Yang Zhou and Mopper Buttery et al. Yaws and Yang Zhou and Mopper Buttery et al.3×101 1.3 9.1×101 1.0×103 3.1×10−1 [K] reference type note aldehydes (RCHO) (C.9 4. 49 64 39.9 1.7 5.3×101 1. Yaws and Yang Zhou and Mopper [1990] [1969] [1992] [1990] [1969] [1992] [1990] [1969] [1992] [1990] [1969] [1992] [1990] 6500 7500 7400 6700 8700 . Sander: Henry’s law constants (http://www.0×103 7.4 6.3×101 1. 49 64 39.7 1. and O only) methanal HCHO (formaldehyde) [50-50-0] Ledbury and Blair Gaffney and Senum Chameides Dong and Dasgupta Seinfeld Betterton and Hoffmann Warneck Zhou and Mopper M¨ oller and Mauersberger Staudinger and Roberts Buttery et al.2×103 1.mpch-mainz. Yaws and Yang Zhou and Mopper Buttery et al. Janini and Quaddora [1925] [1984] [1984] [1986] [1986] [1988] [1988] [1990] [1992] [1996] [1969] [1984] [1985] [1988] [1990] [1995] [1957] [1992] [1982] [1986] [1996] [1969] [1985] [1990] [1986] [1969] [1990] [1969] [1986] M X T M ? M C M c L M X M M M M X ? X X L M C M X X M M X M M ? M M ? M M ? M M ? M M ? M 61 48 62 13 63 64 6400 7200 6500 7200 6800 ethanal CH3 CHO (acetaldehyde) [75-07-0] 48 63 64 65 39 3 3 5800 6300 5000 5700 4700 4500 5600 propanal C2 H5 CHO (propionaldehyde) [123-38-6] butanal C3 H7 CHO (butyraldehyde) [123-72-8] pentanal C4 H9 CHO (valeraldehyde) [110-62-3] hexanal C5 H11 CHO heptanal C6 H13 CHO octanal C7 H15 CHO nonanal C8 H17 CHO decanal C9 H19 CHO 5700 2400 5600 6200 4000 6300 64 3 3 64 3 64 39.3 2. [1969] Yaws and Yang [1992] Zhou and Mopper Buttery et al.44 R. Gaffney and Senum Snider and Dawson Betterton and Hoffmann Zhou and Mopper Benkelberg et al.7 2. Pierotti et al.1 1.5×101 1.7×101 1.0 1.de/~sander/res/henry.0×10−1 6.html) −d ln kH d(1/T ) substance kH [M/atm] see note 6. Yaws and Yang USEPA Janini and Quaddora Staudinger and Roberts Buttery et al.3×103 3.5 6. Snider and Dawson Zhou and Mopper Janini and Quaddora Schaffer and Daubert Zhou and Mopper Buttery et al.4 4.3×101 1.5×101 9.8 5.1×102 1.7×101 1.1×103 3. H.8 4.mpg.7 1.

2×103 Graedel and Goldberg [1983] C >3.de/~sander/res/henry.6×101 3.5×101 4.2 7.1×101 6.9×106 8600 Parsons et al. Sander: Henry’s law constants (http://www.6×101 3.5 [K] 5100 3800 5300 reference Gaffney and Senum Snider and Dawson USEPA Meylan and Howard Allen et al.0×101 3600 Buttery et al.0×102 Buttery et al.mpch-mainz. Gaffney and Senum Meylan and Howard USEPA Buttery et al.4 1.6×105 Betterton and Hoffmann [1988] Zhou and Mopper [1990] M M 63 . Iraci et al.0×101 8.html) −d ln kH d(1/T ) 45 substance propenal CH2 CHCHO (acrolein) [107-02-8] 2-methylpropenal C4 H6 O (methacrolein) [78-85-3] trans-2-butenal CH3 CHCHCHO (crotonaldehyde) trans-2-hexenal C3 H7 CHCHCHO trans-trans-2.0×101 2. [1984] [1985] [1982] [1991] [1998] [1998] type X M X X E M note 48 3 3 5.2 4. [1971] see note Hine and Mookerjee Gaffney and Senum Betterton and Hoffmann Zhou and Mopper Staudinger and Roberts Allen et al.9×101 3. [1971] [1984] [1991] [1982] [1971] M X X X M 48 3 3 1.0×105 3.R.2×101 5. Gaffney and Senum [1975] [1984] [1988] [1990] [1996] [1998] [1984] M ? V X M M L E X 66 5100 4600 4800 7000 48 63 64 3-hydroxybenzaldehyde C6 H4 (OH)CHO (3-formylphenol) 4-hydroxybenzaldehyde C6 H4 (OH)CHO (4-formylphenol) generic aldehyde RCHO ethanedial OHCCHO (glyoxal) 48 1.3 6. [1971] M 54 4.3×101 see note 3.2×101 3.mpg.7×101 4.0×105 Buttery et al.1×101 5.4-hexadienal CH3 CHCHCHCHCHO trans-2-octenal C5 H11 CHCHCHO benzaldehyde C6 H5 CHO [100-52-7] kH [M/atm] 8. [1971] M 1.

2×101 3.2×101 9.2×101 2.9×101 1. Vitenberg et al. Meylan and Howard Janini and Quaddora Janini and Quaddora [1935] [1963] [1965] [1969] [1984] [1985] [1990] [1991] [1995] [1975] [1974] [1993] [1992] [1969] [1986] [1996] [1965] [1985] [1969] [1988] [1990] [1987] [1975] [1973] [1974] [1979] [1996] [1988] [1986] [1969] [1991] [1986] [1986] R M R M X M M M M M X M ? X X L R M M X M X M M X M L X X M X X X 48 64 4800 3800 5800 5300 67 39 3 3 5000 3300 4600 5700 2-butanone C2 H5 COCH3 (methyl ethyl ketone.0×101 2.5×101 2.0×101 [K] reference type note ketones (RCOR) (C. Rohrschneider Vitenberg et al.0 3.1×101 7.mpg. [1969] Janini and Quaddora [1986] Meylan and Howard [1991] M X X 3 3 . Sander: Henry’s law constants (http://www.7 1. Gaffney and Senum Snider and Dawson Zhou and Mopper Betterton Benkelberg et al.1.3 4500 Buttery et al. .7×101 2. Zhou and Mopper Howe et al.6×101 1.0×101 2.9 7. H. Vitenberg et al.0×101 6.1 2.8×101 3.5×101 3. .7×101 2.0×101 4.8×101 2.8×101 1.5×101 3. Vitenberg et al. Yaws and Yang Schaffer and Daubert Janini and Quaddora Staudinger and Roberts Hine and Weimar Snider and Dawson Buttery et al.5×101 2.de/~sander/res/henry.2 2.3×101 2.0 3. Hoff et al. MEK) [78-93-3] 5000 68 64 11 67 49 3 3 3 3 3 5000 -5200 5800 2-pentanone C3 H7 COCH3 [107-87-9] 3-pentanone C2 H5 COC2 H5 2-heptanone C5 H11 COCH3 [110-43-0] 4600 9200 7.7×101 1. Janini and Quaddora Buttery et al.7 2.46 R. Friant and Suffet Staudinger and Roberts Ashworth et al. and O only) propanone CH3 COCH3 (acetone) [67-64-1] Butler and Ramchandani Burnett Hine and Weimar Buttery et al. Ashworth et al. 7.2 1.html) −d ln kH d(1/T ) substance kH [M/atm] 3.mpch-mainz.0×101 2.0×101 7.1 1.6×101 3.5×101 6.

R.4×101 5700 Gaffney and Senum [1984] Snider and Dawson [1985] Betterton [1991] X M M 48 . [1987] Ashworth et al. [1969] M 2.6.5-trimethyl-2-cyclohexen-1-one C9 H14 O (isophorone) [78-59-1] 2. 5. [1998] USEPA [1982] E ? M V M E X 3 6000 12000 3900 1.7 Buttery et al. [1969] M 1.4 [K] reference Buttery et al. [1998] Betterton [1991] Iraci et al. [1969] type M note 2.7×101 7.6 Buttery et al. MVK) [78-94-4] 1-phenylethanone C6 H5 COCH3 (acetophenone) [98-86-2] 3.1×101 9.html) −d ln kH d(1/T ) 47 substance 2-octanone C6 H13 COCH3 2-nonanone C7 H15 COCH3 2-undecanone C9 H19 COCH3 4-methyl-2-pentanone (CH3 )2 CHCH2 COCH3 (methyl isobutyl ketone.2 2.mpg.mpch-mainz. . [1988] X X 11 3 2.4×101 1.1×102 9.4×101 4.3-butanedione CH3 COCOCH3 (biacetyl. [1998] Hine and Mookerjee [1975] Betterton [1991] Allen et al.1×101 4.9×102 5.8×101 1.5. dimethylglycol) kH [M/atm] 5. .7×102 7800 Allen et al.de/~sander/res/henry. MIBK) [108-10-1] 3-buten-2-one C4 H6 O (methyl vinyl ketone. Sander: Henry’s law constants (http://www.2 170 Howe et al.

Sander: Henry’s law constants (http://www. Yaws and Yang Staudinger and Roberts Butler and Ramchandani Hine and Mookerjee Gaffney and Senum Keene and Galloway Winiwarter et al.mpch-mainz.3×103 2.3×103 1. Johnson et al.7×103 3. Khan et al.7×103 1.2×103 8.9×103 1.9×103 4.3×104 7. Keene et al. Johnson Keene et al.5×103 5. Butler and Ramchandani Hine and Mookerjee Khan et al.0×102 5. Servant et al. [1991] Khan et al.8×103 9.1×103 5.1×103 2. Jacob et al.2×103 5.5×103 5.7×103 5.3×102 5. [1984] [1984] [1986] [1986] [1988] [1989] [1991] [1991] [1990] [1995] [1995] [1995] [1996] [1996] [1992] [1996] [1935] [1975] [1984] [1986] [1988] [1989] [1991] [1995] [1995] [1995] [1996] [1996] [1992] [1996] [1982] [1935] [1975] [1991] [1995] [1935] [1975] [1995] X T C T T C C M X C M C M C ? ? c ? X T T T M M C C M C ? ? X M ? M M M ? M M M M ? 48 69 11 6100 5700 39 70 ethanoic acid CH3 COOH (acetic acid) [64-19-7] 48 6400 6400 69 6300 6300 4900 39 70 3 propanoic acid C2 H5 COOH (propionic acid) [79-09-4] butanoic acid C3 H7 COOH (butyric acid) [107-92-6] 2-methyl propanoic acid (CH3 )2 CHCOOH pentanoic acid C4 H9 COOH [109-52-4] 69 Servant et al. Khan et al.5×103 9. Johnson et al.8×102 2.2×103 9. Keene et al.9×103 5.4×103 3. and O only) methanoic acid HCOOH (formic acid) [64-18-6] 5700 5700 5700 5700 5700 Gaffney and Senum Chameides Jacob Keene and Galloway Winiwarter et al.2×103 3 [K] reference type note carboxylic acids (RCOOH) and peroxy carboxylic acids (RCOOOH) (C. Pandis and Seinfeld Lelieveld and Crutzen Servant et al. [1995] Staudinger and Roberts [1996] 69 70 .6×103 3.7×103 5.html) −d ln kH d(1/T ) substance kH [M/atm] 6. Johnson et al. Yaws and Yang Staudinger and Roberts USEPA Butler and Ramchandani Hine and Mookerjee Servant et al.48 R.2×103 5.4×103 3.5×10 3. H.2×103 2.0×104 8. Khan et al.4×103 8.6×103 4.2×103 8.7×103 1.2×103 6. [1995] 6583 6900 Khan et al.7×103 1.3×103 5. Keene et al. Johnson et al.mpg.0×103 3.6×103 5.de/~sander/res/henry.8×103 8.

0×106 5.0×108 1.de/~sander/res/henry. [1995] M 1.4×104 7.8×107 11000 Saxena and Hildemann [1996] USEPA [1982] E X 51 3 1.mpg.4×103 6304 5900 Khan et al.4×103 1.4×102 5900 5300 Lind and Kok [1994] O’Sullivan et al. Sander: Henry’s law constants (http://www.0×108 Saxena and Hildemann [1996] E 51 2.7×102 8.2×103 [K] reference Khan et al.6×103 Khan et al.5×102 Khan et al.0×109 Saxena and Hildemann [1996] E 51 6.2-dimethyl propanoic acid (CH3 )3 CCOOH hexanoic acid C5 H11 COOH [142-62-1] propenoic acid C3 H4 O2 (acrylic acid) [79-10-7] 2-Methyl-2-propenoic acid C4 H6 O2 (methacrylic acid) [79-41-4] benzoic acid C6 H5 COOH ethanedioic acid HOOCCOOH (oxalic acid) propanedioic acid HOOCCH2 COOH (malonic acid) butanedioic acid HOOC(CH2 )2 COOH (succinic acid) pentanedioic acid HOOC(CH2 )3 COOH (glutaric acid) hexanedioic acid HOOC(CH2 )4 COOH (adipic acid) cis-butenedioic acid HOOC(CH)2 COOH (maleic acid) ethanoic peroxyacid CH3 COOOH (peroxyacetic acid) kH [M/atm] 1.4×104 1.0×108 6500 Yaws and Yang [1992] USEPA [1982] Gaffney and Senum [1984] Saxena and Hildemann [1996] ? X X E 39 3 48 51 4. [1996] M M 9 .0×108 Saxena and Hildemann [1996] E 51 2. [1992] M 2.html) −d ln kH d(1/T ) 49 substance 3-methyl butanoic acid (CH3 )2 CHCH2 COOH 2.0×108 Saxena and Hildemann [1996] E 51 3.mpch-mainz. [1995] type M note 3. [1995] Staudinger and Roberts [1996] Yaws and Yang [1992] M ? ? 70 39 2.R.2×103 2.

1 Buttery et al. [1969] 4. [1997] V .1 4.3 Buttery et al.5 4.mpch-mainz.7 6. [1997] V 8. [1969] M 1. [1997] V 5.8 8.1 1.50 R.8 [K] reference type note esters (RCOOR) (C. [1969] M 1.5 4.8 Buttery et al.mpg. Sander: Henry’s law constants (http://www.7×10−1 Krop et al.1×101 7. [1997] V 1. [1997] V 3. and O only) methyl methanoate HCOOCH3 (methyl formate) methyl ethanoate CH3 COOCH3 (methyl acetate) methyl propanoate C2 H5 COOCH3 (methyl propionate) methyl butanoate C3 H7 COOCH3 (methyl butyrate) methyl pentanoate C4 H9 COOCH3 methyl hexanoate C5 H11 COOCH3 methyl octanoate C6 H13 COOCH3 methyl decanoate C11 H22 O2 (methyl caprate) [110-42-9] methyl dodecanoate C13 H26 O2 (methyl laurate) [111-82-0] methyl tetradecanoate C15 H30 O2 (methyl myristate) [124-10-7] methyl hexadecanoate C17 H34 O2 (methyl palmitate) [112-39-0] methyl octadecanoate C19 H38 O2 (methyl stearate) [112-61-8] Hine and Mookerjee Betterton Hoff et al.2 5.de/~sander/res/henry. [1969] M 3. [1969] M 2.0×10−1 Krop et al.4 Krop et al.html) −d ln kH d(1/T ) substance kH [M/atm] 4. Hartkopf and Karger Butler and Ramchandani Kieckbusch and King Buttery et al. H.7 Buttery et al.1×10−1 Krop et al.4×10−1 Krop et al. [1975] [1992] [1993] [1973] [1935] [1979] [1969] ? ? M M M M M V M 71 71 3800 5000 Hine and Mookerjee [1975] Buttery et al.

Z)-9.6 1. [1997] type V V V note 6. [1993] Hartkopf and Karger [1973] Butler and Ramchandani Kieckbusch and King Hoff et al.R.0 4.3 Krop et al.0×10−2 2. [1997] V 5.0×10−1 7.6 5.3 Krop et al.8×101 [K] reference Krop et al.mpg.6×101 Hine and Mookerjee [1975] V 3.Z)-9.Z.9 9.3×10−1 Krop et al. [1997] Krop et al. [1997] Krop et al. [1997] V 5.8 Hine and Mookerjee [1975] V 2.9 Hine and Mookerjee [1975] V .12-octadecadienoic acid methyl ester C19 H34 O2 (methyl linolate) [112-63-0] (Z)-9-octadecenoic acid methyl ester C19 H36 O2 (methyl oleate) [112-62-9] (Z)-13-docosenoic acid methyl ester C23 H44 O2 (methyl erucate) [1120-34-9] methyl benzoate C6 H5 COOCH3 ethyl methanoate HCOOC2 H5 (ethyl formate) ethyl ethanoate CH3 COOC2 H5 (ethyl acetate) kH [M/atm] 1.de/~sander/res/henry.0×10−1 6.mpch-mainz. Janini and Quaddora Meylan and Howard Hine and Mookerjee [1935] [1979] [1993] [1986] [1991] [1975] V ? M M M ? X X V 13 5300 5700 13 3 3 ethyl propanoate C2 H5 COOC2 H5 (ethyl propionate) ethyl butanoate C3 H7 COOC2 H5 (ethyl butyrate) ethyl pentanoate C4 H9 COOC2 H5 2.6 4300 Hine and Mookerjee [1975] Hoff et al. [1997] V 1.7 6.12.15-octadecatrienoic acid methyl ester C19 H32 O2 (methyl linolenate) [301-00-8] (Z.html) −d ln kH d(1/T ) 51 substance methyl arachidate methyl behenate (Z.4×10−1 2.5 4. Sander: Henry’s law constants (http://www.

52

R. Sander: Henry’s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
−d ln kH d(1/T )

substance ethyl heptanoate C6 H13 COOC2 H5 ethyl dodecanoate C14 H28 O2 (ethyl laurate) [106-33-2] propyl methanoate HCOOC3 H7 (propyl formate) propyl ethanoate CH3 COOC3 H7 (propyl acetate)

kH [M/atm] 2.0

[K]

reference Hine and Mookerjee [1975]

type V

note

7.8×10−1

Krop et al. [1997]

V

2.7

Hine and Mookerjee [1975]

V

propyl propanoate C2 H5 COOC3 H7 (propyl propionate) propyl butanoate C3 H7 COOC3 H7 (propyl butyrate) propyl dodecanoate C15 H30 O2 (propyl laurate) [3681-78-5] isopropyl methanoate HCOOC3 H7 (isopropyl formate) isopropyl ethanoate CH3 COOC3 H7 (isopropyl acetate) isopropyl propanoate C2 H5 COOC3 H7 (isopropyl propionate) butyl ethanoate CH3 COOC4 H9 (butyl acetate)

5.0 5.0 4.6 4.4 4.5 2.6

5500 6000

Butler and Ramchandani Hine and Mookerjee Kieckbusch and King Janini and Quaddora Meylan and Howard Hine and Mookerjee

[1935] [1975] [1979] [1986] [1991] [1975]

V V M X X V

3 3

1.9

Hine and Mookerjee [1975]

V

7.8×10−1

Krop et al. [1997]

V

1.2

Hine and Mookerjee [1975]

V

3.6 2.9

5500

Hine and Mookerjee [1975] Janini and Quaddora [1986]

V X

3

1.7

Hine and Mookerjee [1975]

V

butyl dodecanoate C16 H32 O2 (butyl laurate) [106-18-3]

3.0 3.6 3.5 3.5 2.1 7.2×10−1

6000 7500 3200

Hine and Mookerjee Kieckbusch and King Meylan and Howard Janini and Quaddora USEPA Krop et al.

[1975] [1979] [1991] [1986] [1982] [1997]

V M X X X V

3 3 3

R. Sander: Henry’s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
−d ln kH d(1/T )

53

substance 2-methylpropyl methanoate HCOOC4 H9 (isobutyl formate) 2-methylpropyl ethanoate CH3 COOC4 H9 (isobutyl acetate) [110-19-0] pentyl ethanoate CH3 COOC5 H11 (amyyl acetate) pentyl propanoate C2 H5 COOC5 H11 (amyyl propionate) isopentyl methanoate HCOOC5 H11 (isoamyyl formate) isopentyl ethanoate CH3 COOC5 H11 (isoamyyl acetate) hexyl ethanoate CH3 COOC6 H13 (hexyl acetate) 2-ethylhexyl dodecanoate (2-ethylhexyl laurate) ethenyl ethanoate CH3 COOCHCH2 (vinyl acetate) dimethyl phthalate C10 H10 O4 [131-11-3] diethyl phthalate C12 H14 O4 [84-66-2]

kH [M/atm] 1.7

[K]

reference Hine and Mookerjee [1975]

type V

note

2.2

Hine and Mookerjee [1975]

V

2.6 2.8

6500

Hine and Mookerjee [1975] Kieckbusch and King [1979]

V M

1.2

Hine and Mookerjee [1975]

V

1.5

Hine and Mookerjee [1975]

V

1.7 2.4

5000

Hine and Mookerjee [1975] USEPA [1982]

V X

3

1.9

Hine and Mookerjee [1975]

V

3.1×10−1

Krop et al. [1997]

V

1.7

2600

USEPA [1982]

X

3

3.0×103

5700

USEPA [1982]

X

3

1.2×103

5600

USEPA [1982]

X

3

54

R. Sander: Henry’s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
−d ln kH d(1/T )

substance

kH [M/atm] 9.9×10−1 1.0 9.0×10−1

[K]

reference

type

note

ethers (ROR) (C, H, and O only)
dimethyl ether CH3 OCH3 ethyl methyl ether C2 H5 OCH3 diethyl ether C2 H5 OC2 H5 Hine and Weimar [1965] Hine and Mookerjee [1975] Saxena and Hildemann [1996] R V E 51

methyl propyl ether CH3 OC3 H7 methyl 2-propyl ether CH3 OC3 H7 methyl tert-butyl ether CH3 OC(CH3 )3 ethyl propyl ether C2 H5 OC3 H7 dipropyl ether C3 H7 OC3 H7

1.1 1.1 8.0×10−1 1.2 7.8×10−1 7.9×10−1 6.8×10−1

5300

Butler and Ramchandani Hine and Weimar Signer et al. Nielsen et al. Hoff et al. Lamarche and Droste Hine and Mookerjee

[1935] [1965] [1969] [1994] [1993] [1989] [1975]

V V M M ? X V

13 3

1.2

Hine and Mookerjee [1975]

V

1.7 1.6 8.7×10−1 8.7×10−1 2.8×10−1 2.9×10−1 1.9×10−1 2.3×10−1 4.5×10−1 9.9×10−2 1.0×10−1 4.9×10−1 5.8×10−1 1.7×10−1

7700

Guthrie [1973] Robbins et al. [1993] Butler and Ramchandani [1935] Hine and Mookerjee [1975] Butler and Ramchandani Hine and Mookerjee Hoff et al. Hartkopf and Karger Yaws and Yang Hine and Weimar Hine and Mookerjee Nielsen et al. Yaws and Yang Pierotti et al. [1935] [1975] [1993] [1973] [1992] [1965] [1975] [1994] [1992] [1957]

V M V V V V ? M ? V V M ? X

13 39

8900

diisopropyl ether C3 H7 OC3 H7

dibutyl ether C4 H9 OC4 H9 methoxybenzene C6 H5 OCH3 (anisole) [100-66-3]

39 53

2.4×10−1 2.4×10−1

Hine and Weimar [1965] Hine and Mookerjee [1975]

R V

[1957] X 53 7.6-dioxaoctane-1. H.0×103 Saxena and Hildemann [1996] E 51 3.de/~sander/res/henry.5×101 Guthrie [1973] V 2.html) −d ln kH d(1/T ) 55 substance kH [M/atm] 5.8 Pierotti et al.1-trimethoxyethane CH3 C(OCH3 )3 3-oxapentane-1. multiple functional groups (C. pyruvaldehyde) 2-hydroxyethanal HOCH2 CHO (hydroxyacetaldehyde) oxoethanoic acid OHCCOOH (glyoxylic acid) [298-12-4] 2-oxopropanoic acid CH3 COCOOH (pyruvic acid) USEPA [1982] X 3 2.g.mpch-mainz.5-diol HO(CH2 )2 O(CH2 )2 OH (diethylene glycol) [111-46-6] 3. [1988] X 3 5.7×103 3.8-diol HO(CH2 CH2 O)3 H (triethylene glycol) [112-27-6] propanonal CH3 COCHO (methylglyoxal.2-epoxypropane C3 H6 O (propyleneoxide) [75-56-9] 2-methoxyethanol C3 H8 O2 [109-86-4] dimethoxymethane CH3 OCH2 OCH3 trimethoxymethane HC(OCH3 )3 1.0×105 3. and O only) 1.0×101 Guthrie [1973] V 1.2×10−2 -870 Ashworth et al.6×101 Hine and Mookerjee [1975] V 6.2×104 7500 Betterton and Hoffmann [1988] Zhou and Mopper [1990] M M 63 4.1×105 5100 5200 Khan et al.2-diethoxyethane C2 H5 OC2 H4 OC2 H5 1.R.0×109 Saxena and Hildemann [1996] E 51 9.mpg.0×1011 Saxena and Hildemann [1996] E 51 3. Sander: Henry’s law constants (http://www.3 [K] 3500 reference type note miscellaneous. e. [1995] Staudinger and Roberts [1996] Khan et al.1-diethoxyethane (C2 H5 O)2 CHCH3 1.1×105 3.0×101 Hine and Mookerjee [1975] V 1. [1992] M ? M 70 .1.1×104 4600 Betterton and Hoffmann [1988] M 63 9.

mpch-mainz.2×102 2. furfuran) [110-00-9] tetrahydrofurane C4 H8 O (THF) 2-methyltetrahydrofurane CH3 C4 H7 O 2.0×103 Saxena and Hildemann [1996] E 51 4. [1971a] Signer et al.2×102 1.9×103 5800 6700 Cabani et al.6-dimethoxyphenol) [91-10-1] 1-hydroxy-2-methoxybenzene C7 H8 O2 (guaicol) [90-05-1] 4-methyl-2-methoxyphenol hydroxybutanedioic acid HOOCCH2 CHOHCOOH (malic acid) 2.4-dioxane C4 H8 O2 (dioxane) kH [M/atm] 7. [1971a] Rohrschneider [1973] Friant and Suffet [1979] Cabani et al.3-dioxolane C3 H6 O2 1.1×102 2.0×102 1. [1971a] M 5.7 6800 Cabani et al.1×101 6200 Cabani et al. [1969] M M 1.0×101 4800 Cabani et al.8×10−1 Yaws and Yang [1992] ? 39 1.3-dimethoxy-2-hydroxybenzene C8 H10 O3 (2.0×103 [K] reference Saxena and Hildemann [1996] type E note 51 5.4×102 2.4×101 2. Sander: Henry’s law constants (http://www.de/~sander/res/henry.1×102 7500 Sagebiel et al.0×103 Saxena and Hildemann [1996] E 51 1.5-dimethyltetrahydrofurane (CH3 )2 C4 H6 O tetrahydropyran C5 H10 O (THP) 1.html) −d ln kH d(1/T ) substance 3-oxopropanoic acid OHCCH2 COOH 4-oxobutanoic acid OHC(CH2 )2 COOH 5-oxopentanoic acid OHC(CH2 )3 COOH oxacyclopentadiene C4 H4 O (furan. [1992] X 3 7.56 R. [1971a] M 8. [1992] X M M M ? X 11 49 39 3 9. [1992] Saxena and Hildemann [1996] X E 3 51 . [1971a] Yaws and Yang [1992] Sagebiel et al.4×102 4. [1971a] M 1.mpg. [1971a] M 4.0×1013 7400 Sagebiel et al.0 5900 Cabani et al.2×101 5700 Cabani et al.

R.3-dihydroxypropanal C3 H6 O3 (glyceraldehyde) carbon monoxide CO kH [M/atm] 3.mpch-mainz.2.5×10−2 3.html) −d ln kH d(1/T ) 57 substance 2-hydroxy-1.6×10−2 1300 1600 1300 2400 2400 2400 2400 2400 2400 2400 2400 2400 2300 2600 2400 2400 2200 Meadows and Spedding Liss and Slater Wilhelm et al.0×1010 Saxena and Hildemann [1996] E 51 carbon dioxide CO2 7. [1974] [1974] [1977] [1992] [1995] [1992] [1931] [1964] [1977] [1978] [1981] [1984] [1984] [1986] [1989] [1991] [1991] [1992] [1995] [1992] [1980] [1997] M c L ? L ? M X L L C T ? C C C L ? L ? X M 2 39 1 4 2 39 3 . Chameides Hoffmann and Jacob Jacob Pandis and Seinfeld Lelieveld and Crutzen Carroll et al.5×10−2 3.4×10−2 3.5×10−2 3.5×10−2 4.4×10−2 3. Edwards et al. Durham et al.0×1018 Saxena and Hildemann [1996] E 51 2.4×10−2 3.7×10−4 3.0×1018 [K] reference Saxena and Hildemann [1996] type E note 51 1. Sander: Henry’s law constants (http://www.0×107 Saxena and Hildemann [1996] E 51 1.0×109 Saxena and Hildemann [1996] E 51 7.2×10−4 9.3-dihydroxybutanedioic acid HOOCCHOHCHOHCOOH (tartaric acid) [87-69-4] 2.1×10−2 3. Dean Lide and Frederikse Yaws and Yang Morgan and Maass Sillen and Martell Wilhelm et al.4×10−2 3.4×10−2 3.de/~sander/res/henry.4×10−3 8.mpg.4×10−2 3.5×10−4 9.2×10−2 3.4×10−2 3.9×10−4 8. Dean Lide and Frederikse Yaws and Yang Kavanaugh and Trussell Zheng et al.3-propanetricarboxylic acid C6 H8 O7 (citric acid) [77-92-9] 2-oxopentanedioic acid HOOC(CH2 )2 COCOOH (α-keto glutaric acid) [328-50-7] 2-hydroxypropanoic acid CH3 CHOHCOOH (lactic acid) 2.5×10−4 9.4×10−2 3.4×10−2 3.

4×102 1. H.mpch-mainz.9×101 1. Christie and Crisp Bone et al.6×102 8200 Cabani et al.9×105 Westheimer and Ingraham [1956] M 1. Christie and Crisp Butler and Ramchandani Christie and Crisp [1977] [1967] [1983] [1935] [1977] [1967] [1935] [1967] L M ? M L M M M M M M 12 3600 Butler and Ramchandani [1935] Christie and Crisp [1967] Christie and Crisp [1967] 3.1×101 [K] 2600 reference type note compounds with nitrogen: amines (RNH2 ) (C.7×101 6.1×101 8. Sander: Henry’s law constants (http://www.0×101 1.de/~sander/res/henry.html) −d ln kH d(1/T ) substance kH [M/atm] 3. Butler and Ramchandani Wilhelm et al.7×101 3.0×102 3.1×101 4000 Wilhelm et al.8×101 4.0×101 6. [1977] Christie and Crisp [1967] Christie and Crisp [1967] Yaws and Yang [1992] USEPA [1982] Meylan and Howard [1991] Christie and Crisp [1967] see note Christie and Crisp [1967] L M M ? X X M ? M 10000 39 3 3 66 9.9×101 1.1×101 5.58 R.5×101 1. and N only) methylamine CH3 NH2 ethylamine C2 H5 NH2 [75-04-7] propylamine C3 H7 NH2 [107-10-8] butylamine C4 H9 NH2 [109-73-9] pentylamine C5 H11 NH2 hexylamine C6 H13 NH2 dimethylamine (CH3 )2 NH [124-40-3] diethylamine (C2 H5 )2 NH [109-89-7] dipropylamine (C3 H7 )2 NH dibutylamine (C4 H9 )2 NH trimethylamine (CH3 )3 N [75-50-3] triethylamine (C2 H5 )3 N ethylenediamine H2 NCH2 CH2 NH2 hexamethyleneimine (CH2 )6 NH ethanolamine HOC2 H4 NH2 [141-43-5] Wilhelm et al.5×101 8. [1983] M 8 .7 Christie and Crisp [1967] M 5.7×101 Christie and Crisp [1967] M 3. [1971b] M 6.9×101 see note 1.6×101 9.2×106 Bone et al.6 Christie and Crisp [1967] M 6.6×101 5.3×102 3.mpg. O.

0×107 2.9×101 7900 Cabani et al. [1954] Yaws and Yang [1992] Yaws and Yang [1992] Andon et al.0×1013 1.7×102 6600 Andon et al. [1971b] M 3.de/~sander/res/henry.0×1013 9. Sander: Henry’s law constants (http://www.0×101 3.0×102 5900 Andon et al.0×1013 4.2×102 7600 Cabani et al. [1971b] M 2.5×101 1.0×1012 1.1×101 6700 Andon et al.1×102 9.0×107 [K] reference type note compounds with nitrogen: amino acids (RCHNH2 COOH) glutamic acid asparagine serine glutamine glycine arginine alanine leucine Saxena and Hildemann [1996] Saxena and Hildemann [1996] Saxena and Hildemann [1996] Saxena and Hildemann [1996] Saxena and Hildemann [1996] Saxena and Hildemann [1996] Saxena and Hildemann [1996] Saxena and Hildemann [1996] E E E E E E E E 51 51 51 51 51 51 51 51 compounds with nitrogen: heterocycles (C. H.mpch-mainz. O.mpg. [1954] M ? ? M 39 39 6400 5. [1954] M .3×101 7600 Cabani et al.html) −d ln kH d(1/T ) 59 substance kH [M/atm] 1.2×102 7900 Cabani et al.4×101 1. [1954] ? M 39 1. [1954] M 6.0×107 1. α-picoline) [109-06-8] 3-methylpyridine C5 H4 NCH3 (3-picoline. [1971b] M 2. [1971b] M 1.R. β -picoline) [108-99-6] 4-methylpyridine C5 H4 NCH3 2-ethylpyridine C5 H4 NC2 H5 4.0×1017 6.3×102 6400 Yaws and Yang [1992] Andon et al. and N only) pyrrolidine C4 H8 NH N-methyl-pyrrolidine C4 H8 NCH3 piperidine C5 H10 NH N-methyl-piperidine C5 H10 NCH3 pyridine C5 H5 N [110-86-1] 2-methylpyridine C5 H4 NCH3 (2-picoline.

0×102 Buttery et al. [1954] M 1.6-dimethylpyridine C5 H3 N(CH3 )2 3.6×101 [K] 6500 reference Andon et al. [1954] M 1.5×102 7100 Andon et al.mpch-mainz.60 R. [1954] M 4.0×101 1. [1971] M 2. [1954] type M note 1. [1954] M 9.4-dimethylpyridine C5 H3 N(CH3 )2 2.8×101 Buttery et al.5-dimethylpyridine C5 H3 N(CH3 )2 2.5×101 7300 Andon et al.0×102 Buttery et al. [1971] M 4. [1954] M 2.5-dimethylpyridine C5 H3 N(CH3 )2 2-methylpyrazine C4 N2 H3 CH3 2-ethylpyrazine C4 N2 H3 (C2 H5 ) 2-isobutylpyrazine C4 N2 H3 C4 H9 2-ethyl-3-methoxypyrazine C4 N2 H3 (C2 H5 )OCH3 2-isobutyl-3-methoxypyrazine C4 N2 H3 (C4 H9 )OCH3 benzo[b]pyridine C9 H7 N (quinoline) [91-22-5] kH [M/atm] 9.html) −d ln kH d(1/T ) substance 3-ethylpyridine C5 H4 NC2 H5 4-ethylpyridine C5 H4 NC2 H5 2.2×102 6300 Andon et al. [1954] M 1.4×102 700 Andon et al.2×102 7100 Andon et al.3×101 3. [1954] M 1.7×102 6900 Andon et al.de/~sander/res/henry. [1971] M 2.mpg.4×102 6800 Andon et al.5×102 Buttery et al. Sander: Henry’s law constants (http://www.3-dimethylpyridine C5 H3 N(CH3 )2 [583-61-9] 2. [1971] M 6. [1971] Karl and Lindinger [1997] USEPA [1982] M M X 43 3 .7×103 5400 Buttery et al.4-dimethylpyridine C5 H3 N(CH3 )2 3.

[1998] V M . and N only) methyl nitrate CH3 ONO2 ethyl nitrate C2 H5 ONO2 1-propyl nitrate C3 H7 ONO2 [627-13-4] 2-propyl nitrate C3 H7 ONO2 1-butyl nitrate C4 H9 ONO2 [928-45-0] 2-butyl nitrate C4 H9 ONO2 (isobutyl nitrate) [543-29-3] tert-butyl nitrate C4 H9 ONO2 1-pentyl nitrate C5 H11 ONO2 (amyl nitrate) [1002-16-0] 2-pentyl nitrate C5 H11 ONO2 [21981-48-6] 3-pentyl nitrate C5 H13 ONO2 3-methyl-1-butanol nitrate C5 H11 ONO2 (isoamyl nitrate) [543-87-3] 1-hexyl nitrate C6 H13 ONO2 Kames and Schurath [1992] M 1.7×10−1 Hauff et al.de/~sander/res/henry. Hauff et al. O.5×10−1 8.0 1.7×10−1 3. H.6×10−1 6.7×10−1 6. Kames and Schurath Hauff et al. [1998] Kames and Schurath Hauff et al.0 [K] 4700 reference type note compounds with nitrogen: nitrates (RONO2 ) (C. Sander: Henry’s law constants (http://www. Kames and Schurath Hauff et al.1×10−1 6. Hauff et al. [1998] 3.7×10−1 4.5×10−1 6.2 4.R.html) −d ln kH d(1/T ) 61 substance kH [M/atm] 2. [1998] Hauff et al. Kames and Schurath Hauff et al. Hauff et al.5×10−1 4.9×10−1 3.mpg.0 6.5×10−1 6300 Kames and Schurath [1992] Hauff et al.1 7.0×10−1 3.6 5400 Kames and Schurath [1992] M 1. Hauff et al. Kames and Schurath [1992] [1998] [1998] [1992] [1998] [1998] [1989] [1992] [1998] [1998] [1989] [1992] [1998] [1998] [1992] M V M M M V M M M V M M M V M 1.1 1.mpch-mainz.2×10−1 8.0×10−1 5500 5400 6000 5800 5600 5400 5200 Kames and Schurath Hauff et al.3×10−1 1. Hauff et al.9×10−1 7.9×10−1 4. [1992] [1998] [1998] [1998] [1998] M V M M M V M V M 8 Hauff et al. Hauff et al. Luke et al.4×10−1 4. [1998] Hauff et al.4×10−1 6.9×10−1 6.5×10−1 7. Luke et al. Hauff et al.

0×104 3.0×104 9500 Shepson et al. [1996] M 1. [1996] Kames and Schurath [1992] Kames and Schurath [1992] type M M M M note 8 8.5×103 8800 Shepson et al.7×103 [K] 8600 reference Kames and Schurath [1992] Shepson et al.mpg.62 R. Sander: Henry’s law constants (http://www. [1996] M 5.1×104 10000 Shepson et al.mpch-mainz. [1996] M 4.html) −d ln kH d(1/T ) substance 2-nitrooxy ethanol HOC2 H4 ONO2 nitrooxy propanol C3 H7 O4 N (1. 72 8.3×103 6. 72 1.de/~sander/res/henry.2 and 2.9×104 7. [1996] M 1. [1996] M 6.0×103 Kames and Schurath [1992] M 8 .8×103 9200 Shepson et al.1) 1-nitrooxy-2-propanol C3 H7 O4 N 2-nitrooxy-1-propanol C3 H7 O4 N 2-nitrooxy-3-butanol C4 H9 O4 N 1-nitrooxy-2-butanol C4 H9 O4 N 2-nitrooxy-1-butanol C4 H9 O4 N nitrooxyacetone CH3 COCH2 ONO2 kH [M/atm] 4.0×103 9600 Shepson et al.

6-hexanediol dinitrate 2.9×101 1.2×101 Kames and Schurath [1992] Fischer and Ballschmiter [1998b] M M 8 73 1.2×102 2.4-pentanediol dinitrate t-2.3-butanediol dinitrate 1.3-propanediol dinitrate C3 H6 N2 O6 [3457-90-7] 1.2-propane dinitrate) [6423-43-4] 1.2-ethanediol dinitrate O3 NCH2 CH2 ONO2 (1.mpch-mainz.2-butanediol dinitrate 1.de/~sander/res/henry.5-pentanediol dinitrate c-2.6×102 1. Sander: Henry’s law constants (http://www.8×101 1.8×102 3.4×102 7.2-pentanediol dinitrate 1.html) −d ln kH d(1/T ) 63 substance 1.3-butanediol dinitrate 1.4-pentanediol dinitrate 1.2-ethane dinitrate) [628-96-6] 1.4-pentanediol dinitrate 1.2×101 Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] M M M M M M M M M M M M M 73 73 73 73 73 73 73 73 73 73 73 73 73 .R.5×102 3.2×101 1.2-hexanediol dinitrate 1.1×101 5.3×102 Fischer and Ballschmiter [1998b] M 73 2.5×101 9.3×101 3.mpg.5-hexanediol dinitrate 1.2×101 1.2-propanediol dinitrate C3 H6 (ONO2 )2 (1.7×100 2.8×101 1.4-butanediol dinitrate 2.5-hexanediol dinitrate kH [M/atm] 6.2-propanediol dinitrate 1.9×101 [K] reference Kames and Schurath [1992] Fischer and Ballschmiter [1998b] type M M note 8 73 1.

1 see see 2.0×100 4.9×101 2.10-decanediol dinitrate peroxyacetyl nitrate CH3 COOONO2 (PAN) kH [M/atm] 1.2×102 8.5×102 6.9×101 5.9 2.mpg. Kames and Schurath Warneck et al.html) −d ln kH d(1/T ) substance cis-1.7 see note see note 1.2-decanediol dinitrate 1.3×100 7. [1984] [1984] [1989] [1991] [1995] [1996] [1996] [1995] [1996] [1996] type M M M M M M M M M M X M C M M ? ? M ? ? M ? ? M ? ? M ? ? note 73 73 73 73 73 73 73 73 73 73 48 74 5900 6500 note note note note peroxypropionyl nitrate C2 H5 COOONO2 (PPN) peroxy-n-butyryl nitrate C3 H7 COOONO2 (PnBN) peroxy-2-propenoyl nitrate CH2 C(CH3 )COOONO2 (peroxymethacryloyl nitrate. Schurath et al. [1996] Kames and Schurath [1995] Warneck et al.6 5.9 see see [K] reference Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Fischer and Ballschmiter [1998b] Gaffney and Senum Holdren et al.3 see note see note 1.mpch-mainz.3-cyclohexanediol dinitrate trans-1.2-cycloheptanediol dinitrate 1. Schurath et al. Kames and Schurath Warneck et al.8-octanediol dinitrate 1. [1996] Schurath et al.64 R.3-cyclohexanediol dinitrate 1. [1996] .2-cyclohexanediol dinitrate cis-1. [1996] Kames and Schurath [1995] Warneck et al.8 4.2-octanediol dinitrate 1. Pandis and Seinfeld Kames et al.de/~sander/res/henry. [1996] Schurath et al. Sander: Henry’s law constants (http://www.3×101 3. MPAN) peroxy-isobutyryl nitrate C3 H7 COOONO2 (PiBN) 8 75 76 8 75 76 8 75 76 8 75 76 8 75 76 2.7-heptanediol dinitrate trans-1.2×101 3.0 2.3×102 5.0 see note see note Kames and Schurath [1995] Warneck et al.2-cyclohexanediol dinitrate trans-1. [1996] Schurath et al.9×101 1.

mpg. 77 1.9×101 Butler and Ramchandani [1935] M 1. H.R.3 1.3×101 4. Yaws and Yang Butler and Ramchandani [1965] [1978] [1984] [1965] [1984] [1984] [1985] [1986] [1995] [1992] [1935] R L X R X M M L M ? M 48 48 39 1. and N only) cyanide radical CN hydrocyanic acid HCN ethane nitrile CH3 CN (acetonitrile) [75-05-8] Berdnikov and Bazhin [1970] T 5 propane nitrile C2 H5 CN (propionitrile) [107-12-0] butane nitrile C3 H7 CN (butyronitrile) benzenenitrile C6 H5 CN (benzonitrile) [100-47-0] ethanedinitrile C2 N2 (cyanogen) [460-19-5] 2-propenenitrile C3 H3 N (acrylonitrile) [107-13-1] 9.1×101 7.7×101 5000 4100 4000 3500 4100 Hine and Weimar Edwards et al.de/~sander/res/henry.9×101 2.8 Yaws and Yang [1992] ? 39.mpch-mainz. 8 1.0×10−2 [K] 1400 reference type note compounds with nitrogen: nitriles (RCN) (C.5 2. Sander: Henry’s law constants (http://www. Snider and Dawson Arijs and Brasseur Benkelberg et al.2×101 7.9×101 2.html) −d ln kH d(1/T ) 65 substance kH [M/atm] 8.9×101 4.9×10−1 Yaws and Yang [1992] ? 39.3 2800 USEPA [1982] Meylan and Howard [1991] X X 3 3 . Gaffney and Senum Hine and Weimar Gaffney and Senum Hamm et al.4×101 4. O.8×101 5.9×101 5.

66

R. Sander: Henry’s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
−d ln kH d(1/T )

substance

kH [M/atm] 3.5×101 4.5×101 3.6 2.1×101 2.1×101 1.4×102 1.2×101 1.6×101 8.2 1.1×101 4.3×101 4.1×101 4.7×101 1.7×101 7.8 1.4×101 1.4×101 1.6×101

[K]

reference

type

note

compounds with nitrogen: nitro (RNO2 ) (C, H, O, and N only)
nitromethane CH3 NO2 nitroethane C2 H5 NO2 1-nitropropane C3 H7 NO2 2-nitropropane CH3 CH(NO2 )CH3 nitrobenzene C6 H5 NO2 [98-95-3] 2-nitrotoluene C6 H4 (NO2 )CH3 [88-72-2] 3-nitrotoluene C6 H4 (NO2 )CH3 4-nitrotoluene C6 H4 (NO2 )CH3 1-methyl-2,4-dinitrobenzene C7 H6 N2 O4 (DNT) [121-14-2] Gaffney and Senum Rohrschneider Yaws and Yang Hine and Mookerjee Gaffney and Senum Friant and Suffet Hine and Mookerjee Yaws and Yang [1984] [1973] [1992] [1975] [1984] [1979] [1975] [1992] X M ? V X M V ? V ? V X X V X V X X 48 39 48 49 39, 8

Hine and Mookerjee [1975] Yaws and Yang [1992] Hine and Mookerjee Meylan and Howard USEPA Hine and Mookerjee USEPA [1975] [1991] [1982] [1975] [1982]

39, 8

4500 2900

3 3 3

3200 3100

Hine and Mookerjee [1975] USEPA [1982] USEPA [1982]

3 3

2.1×101

2900

USEPA [1982]

X

3

R. Sander: Henry’s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
−d ln kH d(1/T )

67

substance 2-nitrophenol HOC6 H4 (NO2 ) [88-75-5] 3-nitrophenol HOC6 H4 (NO2 ) 4-nitrophenol HOC6 H4 (NO2 ) [100-02-7] 3-methyl-2-nitrophenol C7 H7 NO3 [4920-77-8] 4-methyl-2-nitrophenol C7 H7 NO3 [119-33-5] 5-methyl-2-nitrophenol C7 H7 NO3 [700-38-9] 4-(1-methylpropyl)-2-nitrophenol C10 H13 NO3 [3555-18-8] 4-methoxy-2-nitrophenol C7 H7 NO4 [1568-70-3] 4-hydroxy-3-nitro-benzaldehyde C7 H5 NO4 [3011-34-5] 2,4-dinitrophenol C6 H4 N2 O5 [51-28-5] 2,5-dinitrophenol C6 H4 N2 O5 [329-71-5] 2-methyl-4,6-dinitrophenol C7 H6 N2 O5 (dinitro-o-cresol,DNOC) [534-52-1]

kH [M/atm] 7.0×101 7.4×101 7.9×101 5.0×105

[K] 4600

reference USEPA Schwarzenbach et al. Tremp et al. Gaffney and Senum [1982] [1988] [1993] [1984]

type X V X X

note 3 8 55,8 48

2.6×106 9.9×102 3.0×104 7.9×104 2.5×102

9100 6000

Parsons et al. USEPA Schwarzenbach et al. Tremp et al. Schwarzenbach et al.

[1971] [1982] [1988] [1993] [1988]

M X V X V

54 3 8 55,8 8

6.2×101

Schwarzenbach et al. [1988]

V

8

6.8×101

Schwarzenbach et al. [1988]

V

8

2.4×101

Schwarzenbach et al. [1988]

V

8

2.3×101

Schwarzenbach et al. [1988]

V

8

9.5×102

Schwarzenbach et al. [1988]

V

8

3.5×103 1.2×104 1.5×103

Schwarzenbach et al. [1988] Tremp et al. [1993] Schwarzenbach et al. [1988]

V X V

8 55,8 8

2.3×103 4.6×103

Schwarzenbach et al. [1988] Tremp et al. [1993]

V X

8 55,8

68

R. Sander: Henry’s law constants (http://www.mpch-mainz.mpg.de/~sander/res/henry.html)
−d ln kH d(1/T )

substance

kH [M/atm] 5.9×10−2 5.9×10−2 5.2×10−2 7.2×10−2 8.7×10−2

[K]

reference

type

note

compounds with fluorine
fluoromethane CH3 F 2200 Hine and Mookerjee Wilhelm et al. Mackay and Shiu Yaws and Yang Yaws and Yang [1975] [1977] [1981] [1992] [1992] V L L ? ?

difluoromethane CH2 F2 trifluoromethane CHF3 (R23) tetrafluoromethane CF4 (carbontetrafluoride) fluoroethane C2 H5 F 1,1-difluoroethane C2 H4 F2 (R152a) 1,1,1,2-tetrafluoroethane C2 H2 F4 (R134a) hexafluoroethane C2 F6 1-fluoropropane C3 H7 F 2-fluoropropane C3 H7 F octafluorocyclobutane C4 F8 1,1-difluoroethene C2 H2 F2 tetrafluoroethene C2 F4 hexafluoropropene C3 F6

39, 38 39

1.1×10−2 1.3×10−2 1.3×10−2 1.4×10−2 2.0×10−4 2.0×10−4 2.1×10−4 1.9×10−4 4.4×10−2

3200 2200 1500 1800

Hine and Mookerjee Wilhelm et al. Yaws and Yang Zheng et al. Hine and Mookerjee Morrison and Johnstone Wilhelm et al. Yaws and Yang Yaws and Yang

[1975] [1977] [1992] [1997] [1975] [1954] [1977] [1992] [1992]

V L ? M V M L ? ?

39

39 39

4.9×10−2 3.7×10−2 5.4×10−2 1.8×10−2

2600 2700

Hine and Mookerjee [1975] Yaws and Yang [1992] Zheng et al. [1997] Zheng et al. [1997]

V ? M M

39, 78

5.9×10−5

Yaws and Yang [1992]

?

39

6.2×10−2

Yaws and Yang [1992]

?

39, 79

5.9×10−2

Yaws and Yang [1992]

?

39, 38

2.5×10−4

Yaws and Yang [1992]

?

39

2.5×10−3

Yaws and Yang [1992]

?

39

1.6×10−3 1.6×10−3 2.9×10−4

2100

Wilhelm et al. [1977] Yaws and Yang [1992] Wilhelm et al. [1977]

L ? L

39

2400

1.1.0 [K] reference Kanakidou et al. [1996] Kanakidou et al.2.0×101 3.1-trifluoro-2-propanone CF3 COCH3 fluoroethanoic acid CH2 FCOOH (fluoroacetic acid) [144-49-0] difluoroethanoic acid CHF2 COOH (difluoroacetic acid) [381-73-7] trifluoroethanoic acid CF3 COOH (trifluoroacetic acid) [76-05-1] generic peroxide with fluorine ROOH kH [M/atm] 2. [1998b] M 3.0×104 6900 Bowden et al.3.4×102 8900 Kanakidou et al.1.mpch-mainz. [1995] E 80 .3.1-trifluoro-2-propanol CF3 CHOHCH3 2.4×101 6700 Rochester and Symonds [1973] M 3. [1995] type C M E note 5. Sander: Henry’s law constants (http://www.6×102 6700 Rochester and Symonds [1973] M 4.3-pentafluoro-1-propanol CF3 CF2 CH2 OH 1.html) −d ln kH d(1/T ) 69 substance carbonyl fluoride COF2 formyl fluoride FCHO 2.9×103 9300 Bowden et al.5×101 6300 Rochester and Symonds [1973] M 1.2-trifluoroethanol CF3 CH2 OH 1.3.9×101 5900 Rochester and Symonds [1973] M 4. [1996] M 3.3.3-hexafluoro-2-propanol CF3 CHOHCF3 trifluoroacetylfluoride CF3 COF 1. [1995] Mirabel et al.2. [1996] Betterton [1991] C M M 8.R.3. [1995] Mirabel et al.5×101 3.0 1.1×104 Bowden et al.2. [1998b] M 8.5×101 6000 Rochester and Symonds [1973] M 2.3-tetrafluoro-1-propanol CHF2 CF2 CH2 OH 2.mpg.0×101 Kanakidou et al.0 3.de/~sander/res/henry.1.

3-difluorobenzene C6 H4 F2 (m-difluorobenzene) 1.4×10−1 [K] reference Mackay and Shiu Hoff et al.2×10−1 1.3×10−2 Yaws and Yang [1992] ? 39 1.3×10−1 Yaws and Yang [1992] ? 39 6.α.6×10−1 1.4-difluorobenzene C6 H4 F2 (p-difluorobenzene) (trifluoromethyl)-benzene C6 H5 CF3 (α.mpg.6×10−1 1.70 R. Hartkopf and Karger Yaws and Yang Yaws and Yang [1981] [1993] [1973] [1992] [1992] type L ? M ? ? note 13 39 39 4100 1.2×10−2 Mackay and Shiu [1981] Yaws and Yang [1992] L ? 39 5.α-trifluorotoluene) 5-fluoro-2-nitrophenol C6 H4 FNO3 [446-36-6] kH [M/atm] 1.2-difluorobenzene C6 H4 F2 (o-difluorobenzene) 1.de/~sander/res/henry. Sander: Henry’s law constants (http://www.html) −d ln kH d(1/T ) substance fluorobenzene C6 H5 F 1. [1988] V 8 .3×10−2 6.6×10−1 1.mpch-mainz.9×102 Schwarzenbach et al.

4×10−1 3.7×10−1 4.1×10−1 4. [1985] Wright et al.mpg.1×10−1 1. [1992] Gossett et al.3×10−1 4.2×10−1 2.5×10−1 4.0×10−1 4.9×10−2 1.de/~sander/res/henry.4×10−1 4.2 3.4×10−1 3.2×10−1 1. [1992b] Dilling [1977] Dilling [1977] Dilling [1977] Hoff et al.1×10−1 1.8×10−1 3.9×10−1 3.mpch-mainz.0×10−1 3.0×10−1 [K] reference type note aliphatic compounds with chlorine chloromethane CH3 Cl (methylchloride) Pearson and McConnell [1975] Hine and Mookerjee [1975] Wilhelm et al.R.0×10−1 3.5×10−1 3.7×10−1 4.4×10−2 1. [1988] Gossett et al.0×10−1 1.3×10−1 1.8 2800 4200 3000 -630 2900 dichloromethane CH2 Cl2 [75-09-2] 8 39 3 3 81. [1985] Tse et al.9×10−1 4.8 4200 3800 3800 82 4100 3600 4100 4200 3700 4300 4200 3500 4500 3900 39 3 3 3 3 3 3 3 3 . Sander: Henry’s law constants (http://www. [1977] Mackay and Shiu [1981] Gossett [1987] Moore et al.2×10−1 9. [1995] Dilling [1977] Dilling [1977] Yaws and Yang [1992] USEPA [1982] Kavanaugh and Trussell [1980] Pearson and McConnell [1975] Hine and Mookerjee [1975] Mackay and Shiu [1981] Lincoff and Gossett [1984] Gossett [1987] Wright et al.1×10−1 3. [1992a] M V L L M M V V ? X X M V L M M M V V C M M ? X L X X X X X X X 81.0×10−1 1.6×10−1 3.6×10−1 8.0×10−1 1. [1993] Hartkopf and Karger [1973] Yaws and Yang [1992] USEPA [1982] Staudinger and Roberts [1996] Kavanaugh and Trussell [1980] Leighton and Calo [1981] Ashworth et al.html) −d ln kH d(1/T ) 71 substance kH [M/atm] 1.1×10−1 3.

mpch-mainz.5×10−1 2.4×10−1 2. [1984] Nicholson et al.6×10−1 [K] reference Pearson and McConnell [1975] Hine and Mookerjee [1975] Mackay and Shiu [1981] Hunter-Smith et al.8×10−1 3.5×10−1 2.4×10−1 2. [1985] Staudinger and Roberts [1996] Munz and Roberts [1987] type M V L M M C C C M M M M M M V V C M M ? X X X X X X X X X X L X note 81.6×10−1 3. [1984] Nicholson et al.5×10−1 2.html) −d ln kH d(1/T ) substance trichloromethane CHCl3 (chloroform) [67-66-3] kH [M/atm] 3.1×10−1 2.8 3900 83 4200 4600 7300 3900 4100 3800 82 4800 4100 4600 4000 4400 5600 4200 5000 2200 4100 4300 4500 4300 39 3 3 3 3 3 3 3 3 3 3 3 .6×10−1 2.5×10−1 2.8×10−1 4. [1988] Lamarche and Droste [1989] Leighton and Calo [1981] Gossett et al.0×10−1 3.9×10−1 2. [1985] Ashworth et al.3×10−1 2. [1983] Nicholson et al. [1995] Dilling [1977] Dilling [1977] Dilling [1977] Hoff et al.9×10−1 2.3×10−1 2.3×10−1 2.2×10−1 2. [1995] Moore et al. [1984] Lincoff and Gossett [1984] Gossett [1987] Tancr` ede and Yanagisawa [1990] Wright et al.5×10−1 2.0×10−1 1.5×10−1 2. [1984] Nicholson et al.5×10−1 2.3×10−1 2. [1992b] Dewulf et al.4×10−1 2.de/~sander/res/henry. [1993] Hartkopf and Karger [1973] Yaws and Yang [1992] Barr and Newsham [1987] Kavanaugh and Trussell [1980] Wright et al. [1992a] USEPA [1982] Ervin et al.7×10−1 2.7×10−1 2.3×10−1 2. Sander: Henry’s law constants (http://www.1×10−1 3.5×10−1 9. [1980] Gossett et al.5×10−1 2.1×10−1 2.72 R.mpg.

[1992] Bissonette et al.7×10−1 1. [1995] Dilling [1977] Dilling [1977] Hoff et al.7×10−1 1.1×10−2 1. Sander: Henry’s law constants (http://www.8 3200 4400 4100 4200 4100 3600 4900 4200 1100 4700 3600 5600 3400 4000 4300 4200 4400 39 3 3 3 3 3 3 3 3 3 3100 750 2900 2600 39.R.8×10−1 1. [1995] Hansen et al.3×10−2 3. [1988] Staudinger and Roberts [1996] Lamarche and Droste [1989] type C M V L M M M M M M V C M M ? X X X X X X X X L X V L M V ? X L X V L M M M V ? X X X X X X X L X note 81.9×10−2 8.1×10−2 3.5×10−2 3. 8 3 3 4100 3600 4000 3600 3800 1700 3300 4400 4900 3100 3600 2100 39 3 3 3 3 3 3 3 3 . [1988] Munz and Roberts [1987] Staudinger and Roberts [1996] Leighton and Calo [1981] Hine and Mookerjee [1975] Mackay and Shiu [1981] Gossett [1987] Dilling [1977] Yaws and Yang [1992] USEPA [1982] Staudinger and Roberts [1996] Ashworth et al.8×10−2 2.9×10−2 8.6×10−1 1.1-dichloroethane CHCl2 CH3 [75-34-3] kH [M/atm] 3.2×10−2 3.6×10−2 1.mpg.5×10−1 1.2×10−1 5. [1993] Ashworth et al.1×10−1 8.3×10−1 1.9×10−2 1.7×10−1 1.3×10−2 3. [1995] Dilling [1977] Yaws and Yang [1992] Wright et al.4×10−2 3.7×10−1 [K] reference Liss and Slater [1974] Pearson and McConnell [1975] Hine and Mookerjee [1975] Mackay and Shiu [1981] Hunter-Smith et al. [1983] Gossett [1987] Tancr` ede and Yanagisawa [1990] Wright et al.9×10−2 3. [1992b] Dewulf et al. [1992] Kavanaugh and Trussell [1980] Ervin et al.5×10−2 5. [1980] Ashworth et al.3×10−2 3.4×10−2 4. [1992a] USEPA [1982] Kavanaugh and Trussell [1980] Tse et al.3×10−2 3.0×10−1 1.7×10−2 3.8×10−1 1.4×10−2 3.7×10−1 1.8×10−2 3. [1988] Hine and Mookerjee [1975] Mackay and Shiu [1981] Gossett [1987] Wright et al.8×10−2 3.6×10−2 3.3×10−2 3.4×10−1 6.5×10−2 8.8×10−1 1.de/~sander/res/henry.7×10−1 2. [1993] Hartkopf and Karger [1973] Yaws and Yang [1992] Wright et al.2×10−2 3.mpch-mainz.7×10−1 1.8×10−2 4.6×10−1 1.0×10−2 3. [1992a] Barr and Newsham [1987] USEPA [1982] Tse et al.8×10−1 1.5×10−2 3. [1990] Hansen et al.html) −d ln kH d(1/T ) 73 substance tetrachloromethane CCl4 (carbontetrachloride) [56-23-5] chloroethane C2 H5 Cl [75-00-3] 1.4×10−2 3. [1992b] Dewulf et al.1×10−2 4.

[1993] Kanakidou et al.9×10−2 5.4×10−1 8.2×10−1 5. [1983] Lincoff and Gossett [1984] Gossett [1987] Kolb et al.1×10−1 2.2×10−1 8. [1985] Hansen et al. [1992a] Barr and Newsham [1987] USEPA [1982] Ashworth et al.0×10−2 6.6×10−2 7. [1992] Wright et al. [1992b] Dewulf et al.8×10−2 5.0×10−1 7.8×10−2 6.5×10−1 7. [1995] Dilling [1977] Dilling [1977] Dilling [1977] Hoff et al.5×10−1 6.4×10−2 4.7×10−2 7. [1992a] Barr and Newsham [1987] Tse et al.0 8.2-dichloroethane CH2 ClCH2 Cl [107-06-2] 1. [1985] type M V L M M V C M M ? X X X X X X X L X M V L M M M X M M C M M V V V M X X X X X X X X X L X X X X note 81.9×10−2 8. [1995] Hansen et al. [1993] Munz and Roberts [1987] Gossett et al.1 7.0×10−2 3. [1992] Ervin et al.7×10−1 9. [1988] Bissonette et al.2×10−2 5.7×10−2 5.6×10−1 9.3×10−1 8.8 3200 4300 4100 3500 3200 4700 3800 3100 45 8 82 3 3 3 3 3 3 3 3 3 3 3 3 3 4600 1700 3400 4000 3700 7000 4400 5200 3400 3900 4200 3200 4100 4300 .9×10−2 6.74 R.2×10−1 1.0×10−2 [K] reference Pearson and McConnell [1975] Hine and Mookerjee [1975] Mackay and Shiu [1981] Wright et al.1×10−1 6.7×10−1 9.html) −d ln kH d(1/T ) substance 1.1×10−2 5. [1980] Leighton and Calo [1981] Bissonette et al.8 3900 4300 4100 3800 3900 3700 2400 1500 4500 4700 4200 3500 39 3 3 3 3 3 3 3 3 81.1-trichloroethane CH3 CCl3 (methylchloroform. [1995] Dewulf et al.2×10−2 3.1×10−2 6.0×10−2 1.4×10−1 8. [1990] Ashworth et al.9×10−2 6.1. MCF) [71-55-6] kH [M/atm] 1.9×10−2 6.9×10−2 5.1×10−1 5.de/~sander/res/henry.5×10−1 8. [1993] Hartkopf and Karger [1973] Yaws and Yang [1992] Tse et al. [1992b] Robbins et al.4×10−2 1.7×10−2 5. [1995] Dilling [1977] Dilling [1977] Hoff et al. [1992] Wright et al.5×10−1 8.0×10−2 6. Sander: Henry’s law constants (http://www.4×10−2 2.mpg. [1990] Lamarche and Droste [1989] Staudinger and Roberts [1996] Leighton and Calo [1981] Pearson and McConnell [1975] Hine and Mookerjee [1975] Mackay and Shiu [1981] Hunter-Smith et al.3×10−1 8.6×10−1 8. [1993] Kavanaugh and Trussell [1980] USEPA [1982] Wright et al.9×10−2 5.5×10−1 2.1×10−2 5.7×10−2 6.mpch-mainz. [1988] Staudinger and Roberts [1996] Gossett et al.

4 2.0 1.0×10−1 2. [1992a] Ashworth et al. [1995] Dilling [1977] Yaws and Yang [1992] USEPA [1982] Wright et al. [1992] Leighton and Calo [1981] Hine and Mookerjee [1975] Mackay and Shiu [1981] Dilling [1977] Yaws and Yang [1992] Hine and Mookerjee [1975] Mackay and Shiu [1981] Dilling [1977] Yaws and Yang [1992] USEPA [1982] Staudinger and Roberts [1996] Ashworth et al.4×10−1 4.1 2.9 2.2 1.mpch-mainz.6×10−1 4. Sander: Henry’s law constants (http://www.8 4.3 1.1×10−1 4.0 1.2 1.4×10−1 7. [1992b] Dilling [1977] Wright et al.2 1. [1988] Munz and Roberts [1987] type V L M M V ? X X X X X L X X V L M V X X L M V ? X X X X L X X V L V ? V L V ? X L X X note 3900 5900 2700 3800 4000 4300 4800 4900 3700 6100 39 3 3 3 3 3 3 3 4800 4500 4600 5000 3 3 4200 4700 2800 3000 3200 4800 3600 39 3 3 3 3 3 3 39 2100 5600 2600 5600 39 3 3 3 .2 2.2 1. [1992] Mackay and Shiu [1981] Wright et al.2 1.1 1. [1992b] Dilling [1977] Yaws and Yang [1992] Barr and Newsham [1987] Wright et al.6×10−1 4.1 1.1. [1993] Hine and Mookerjee [1975] Mackay and Shiu [1981] Wright et al.5×10−1 4.5×10−1 2.mpg.0 1.5×10−1 1.1 8.7×10−1 3.1.R.4 2.1.1. [1992a] Tse et al.4×10−2 1.2-trichloroethane CHCl2 CH2 Cl [79-00-5] 1.3 2. [1992b] Hansen et al.4×10−1 1.2-tetrachloroethane CHCl2 CHCl2 [79-34-5] pentachloroethane CHCl2 CCl3 [76-01-7] hexachloroethane C2 Cl6 [67-72-1] kH [M/atm] 1.2×10−1 2.0 2.2 3.8×10−2 8. [1988] USEPA [1982] Staudinger and Roberts [1996] Tse et al.3 2.8 1.de/~sander/res/henry.2 1. [1988] Staudinger and Roberts [1996] Leighton and Calo [1981] Hansen et al.2-tetrachloroethane CCl3 CH2 Cl [630-20-6] 1.5×10−1 [K] reference Hine and Mookerjee [1975] Mackay and Shiu [1981] Wright et al. [1992] Barr and Newsham [1987] Ashworth et al.2. [1992a] Tse et al.html) −d ln kH d(1/T ) 75 substance 1.0×10−1 3.1 3.2×10−1 4.0×10−1 5.

mpch-mainz. Sander: Henry’s law constants (http://www.4×10−1 4. Yaws and Yang Leighton and Calo Yaws and Yang Leighton and Calo [1975] [1993] [1992] [1981] [1992] [1981] 39 3 3 3 3 3 3 39 3 39 3 39. 8 39.4×10−1 3. 8 3500 4500 13 39 3 39 3 Hine and Mookerjee [1975] 2.4×10−2 9.76 R.4×10−1 6.9×10−2 6.8 3.0×10−2 4.0 1.1 2.2-dichloropropane C3 H6 Cl2 [78-87-5] kH [M/atm] 7.7×10−2 5. [1990] Staudinger and Roberts [1996] Leighton and Calo [1981] Ashworth et al.1-dichlorobutane C4 H8 Cl2 [541-33-3] 1.4-dichlorobutane C4 H8 Cl2 1-chloropentane C5 H11 Cl [543-59-9] 2-chloropentane C5 H11 Cl [625-29-6] Hine and Mookerjee [1975] Wright et al.html) −d ln kH d(1/T ) substance 1-chloropropane C3 H7 Cl [540-54-5] 2-chloropropane C3 H7 Cl [75-29-6] 1.9 2.0×10−2 5.4 3.5×10−1 3.0 1.0×10−1 3.2×10−2 6.0×10−1 3.7×10−1 3.0 4.4×10−1 3.4×10−1 3.1×10−2 1. [1992] Bissonette et al.de/~sander/res/henry.7×10−1 3.6×10−2 4700 Hine and Mookerjee Yaws and Yang Leighton and Calo Hine and Mookerjee [1975] [1992] [1981] [1975] V ? X V 39 3 .8×10−1 1.4×10−2 5.2×10−2 9.3×10−1 [K] reference Hine and Mookerjee Mackay and Shiu Yaws and Yang Hine and Mookerjee Yaws and Yang [1975] [1981] [1992] [1975] [1992] type V L ? V ? V M ? X X X X L X X V ? X M V ? X L L ? V ? ? X ? X V note 39.2×10−2 3.1×10−2 5.3×10−2 6.4 8. [1988] Hine and Mookerjee [1975] Yaws and Yang [1992] Leighton and Calo [1981] Tancr` ede and Yanagisawa [1990] Dilling [1977] Yaws and Yang [1992] Leighton and Calo [1981] Staudinger and Roberts [1996] Mackay and Shiu [1981] Yaws and Yang [1992] Hine and Mookerjee Hoff et al.4×10−2 4.3-trichloropropane C3 H5 Cl3 [96-18-4] 3900 4000 3500 3700 1-chloro-2-methylpropane C4 H9 Cl [513-36-0] 1-chlorobutane C4 H9 Cl [109-69-3] 2-chlorobutane C4 H9 Cl [78-86-4] 1.mpg.2.3-dichloropropane C3 H6 Cl2 [142-28-9] 1.6×10−2 2. 8 3800 2100 3600 3700 3800 4300 4300 4700 1. [1992b] Yaws and Yang [1992] USEPA [1982] Wright et al. [1992a] Tse et al.9×10−2 3.0 3100 Leighton and Calo [1981] X 3 4.

10-tetrachlorodecane C10 H18 Cl4 pentachlorodecane isomers C10 H17 Cl5 1. [1998] Drouillard et al. [1998] M 2.6×101 Drouillard et al.5×102 1.8 1600 Leighton and Calo [1981] X 3 3. [1998] Drouillard et al. [1998] M . [1998] V 5.10-dichlorodecane C10 H20 Cl2 1.1×101 3.8×10−2 [K] reference Hine and Mookerjee [1975] type V note 1.12-dichlorododecane C12 H24 Cl2 polychlorinated dodecane isomers C12 Hx Cly kH [M/atm] 3.R.0×10−1 Drouillard et al.6×10−1 Drouillard et al. [1998] M M V 7.2.html) −d ln kH d(1/T ) 77 substance 3-chloropentane C5 H11 Cl [616-20-6] 1. [1998] Drouillard et al.9×101 1.mpch-mainz.5-dichloropentane C5 H10 Cl2 2-chloro-2-methylbutane C5 H11 Cl [594-36-5] 1-chlorohexane C6 H13 Cl 1.1×10−2 4500 Leighton and Calo [1981] X 3 2.10.4×101 Drouillard et al. [1998] M M M 6.9×101 1.9.7 Drouillard et al.2.11-tetrachloroundecane C11 H20 Cl4 pentachloroundecane isomers C11 H19 Cl5 1.de/~sander/res/henry.1×10−1 Yaws and Yang [1992] ? 39 4.mpg. [1998] Drouillard et al. Sander: Henry’s law constants (http://www.

4×10−2 3. [1992] type M V L M V V ? L X M L M V V ? X X X X L X X V L M M V ? X X X L X X note 81. [1992] USEPA [1982] Ervin et al.2×10−1 2. [1988] Ervin et al. [1992a] Staudinger and Roberts [1996] Bissonette et al.9×10−2 5.6×10−2 3.5×10−1 2.8 3100 2900 3700 3100 1200 6600 4600 4000 4500 2900 8 39 3 3 3 3 3 3 4200 3800 3100 4100 4000 3900 4200 3400 39 3 3 3 3 3 .4×10−2 3.3×10−1 2.0×10−1 1. [1990] Ashworth et al.3×10−1 2.3×10−1 2.2×10−3 4.7×10−2 3.1-dichloroethene CH2 CCl2 [75-35-4] (Z)-1.2-dichloroethene) [156-59-2] kH [M/atm] 8. [1990] Tse et al.3×10−2 3.5×10−4 4.de/~sander/res/henry.3×10−2 4. [1992b] Dilling [1977] Yaws and Yang [1992] Ashworth et al.5×10−3 7.html) −d ln kH d(1/T ) substance chloroethene CH2 CHCl (vinyl chloride) [75-01-4] 1.9×10−2 4. [1988] Hine and Mookerjee [1975] Mackay and Shiu [1981] Gossett [1987] Wright et al.4×10−1 2.6×10−2 1.8×10−2 4.2×10−4 1. Sander: Henry’s law constants (http://www.7×10−2 3.8×10−2 9.1×10−1 2.4×10−2 3.78 R.7×10−2 6.2-dichloroethene CHClCHCl (cis-1.4×10−1 1. [1988] Pearson and McConnell [1975] Mackay and Shiu [1981] Gossett [1987] Dilling [1977] Dilling [1977] Yaws and Yang [1992] Tse et al.mpg. [1980] Wright et al.4×10−2 2.6×10−1 [K] reference Pearson and McConnell [1975] Hine and Mookerjee [1975] Wilhelm et al.mpch-mainz. [1980] Leighton and Calo [1981] Staudinger and Roberts [1996] Bissonette et al.0×10−2 6. [1977] Gossett [1987] Dilling [1977] Dilling [1977] Yaws and Yang [1992] Staudinger and Roberts [1996] Ashworth et al.7×10−1 2.6×10−3 3.74 3000 3300 39 3 81.3×10−1 1.3×10−3 6.

[1980] Ashworth et al.0×10−1 2.1×10−2 9.1×10−1 1.1×10−1 9.1×10−1 8. [1990] Staudinger and Roberts [1996] Cooling et al.0×10−1 9.5×10−1 1.0×10−1 1.8×10−2 9.1×10−1 1. [1993] Nielsen et al. [1993] Pearson and McConnell [1975] Hine and Mookerjee [1975] Mackay and Shiu [1981] Lincoff and Gossett [1984] Gossett [1987] Tancr` ede and Yanagisawa [1990] Wright et al. [1985] type V L M M M V ? X X X X X X L X X M V L M M M M M M M V V V M ? X X X X X L X X X X X X X X note 4200 4000 3400 3000 3400 4300 1700 5400 4800 4100 4100 3300 39 3 3 3 3 3 3 3 3 81.3×10−1 1.9×10−1 7.2-dichloroethene) [156-60-5] trichloroethene C2 HCl3 (trichloroethylene) [79-01-6] kH [M/atm] 1.7×10−2 9.9×10−2 [K] reference Hine and Mookerjee [1975] Mackay and Shiu [1981] Gossett [1987] Wright et al.6×10−2 9.5×10−1 1.0×10−1 1. [1995] Dilling [1977] Dilling [1977] Dilling [1977] Hoff et al.mpg. [1992b] Hansen et al.2×10−2 8.mpch-mainz.2×10−1 8.3×10−1 1.8 4900 4800 5200 4200 3500 3600 8 82 39 3 3 3 3 3 3 3 3 3 3 3 3 3 4100 4400 3900 4000 1600 4600 4700 5200 4300 4800 3700 4700 2100 4900 .0×10−1 1.5×10−2 9.de/~sander/res/henry.1×10−1 1.9×10−2 9.1×10−1 8. [1988] Munz and Roberts [1987] Lamarche and Droste [1989] Gossett et al.1×10−2 8. [1992a] USEPA [1982] Ervin et al.0×10−1 1. [1995] Dilling [1977] Yaws and Yang [1992] Ashworth et al.9×10−2 1.2×10−1 8.5×10−1 1.6×10−2 1. [1980] Bissonette et al.9×10−2 1. [1992b] Robbins et al. [1992a] Cooling et al. [1993] Yaws and Yang [1992] Wright et al.7×10−2 9.2-dichloroethene CHClCHCl (trans-1. [1988] Tse et al.R. Sander: Henry’s law constants (http://www.1×10−1 1.4×10−2 1.html) −d ln kH d(1/T ) 79 substance (E)-1.0×10−1 1.9×10−2 1. [1992] Wright et al.9×10−2 1.2×10−2 9.1×10−1 7. [1985] Ervin et al. [1992] Kavanaugh and Trussell [1980] USEPA [1982] Staudinger and Roberts [1996] Leighton and Calo [1981] Bissonette et al. [1994] Dewulf et al. [1992] Hansen et al. [1990] Gossett et al. [1992] Tse et al.5×10−1 1.7×10−2 1.4×10−1 1.5×10−2 8.1×10−1 1.

7×10−2 5.80 R.3×10−1 5.mpch-mainz.2×10−1 4.2×10−2 6.6×10−2 1.7×10−2 9.5×10−2 5. [1992b] USEPA [1982] Meylan and Howard [1991] Mackay and Shiu [1981] Dilling [1977] Mackay and Shiu [1981] Dilling [1977] Mackay and Shiu [1981] Dilling [1977] Pearson and McConnell Meylan and Howard USEPA Betterton and Hoffmann [1975] [1991] [1982] [1988] type M V L M M M X M M V V V C M ? X X L X X X X X X X V V ? M X X L V L V L V M X X M note 81. [1985] Hine and Mookerjee [1975] Dilling [1977] Yaws and Yang [1992] Wright et al. [1985] Ervin et al.2×10−2 6.3-dichloropropene C3 H4 Cl2 [10061-01-5] trans-1.6×10−2 7.7×10−2 3.9×10−2 3.3×10−2 1.2×10−1 4.7×10−2 6.0×10−2 3.5×10−1 2.7×10−1 4.3-dichloropropene C3 H4 Cl2 2.4×10−2 5.2×10−2 5. [1993] Yaws and Yang [1992] USEPA [1982] Kavanaugh and Trussell [1980] Staudinger and Roberts [1996] Ashworth et al.4×10−2 3.mpg.8 5100 4900 5500 3600 4500 45 8 82 1500 5000 4800 4400 4400 5100 5200 4700 5300 4600 39 3 3 3 3 3 3 3 3 3 39 3 3 4200 1500 4700 3500 81.8×10−1 2.5×10−2 5.3-dichloropropene C3 H4 Cl2 hexachlorobutadiene CCl2 CClCClCCl2 [87-68-3] trichloroethanal CCl3 CHO (trichloroacetaldehyde) chloro-2-propanone CH2 ClCOCH3 kH [M/atm] 5.2×10−1 8.6×10−1 5.4×105 [K] reference Pearson and McConnell [1975] Hine and Mookerjee [1975] Mackay and Shiu [1981] Lincoff and Gossett [1984] Gossett [1987] Tancr` ede and Yanagisawa [1990] Kolb et al.8×10−1 5.de/~sander/res/henry.7×10−2 4.0×10−2 5. [1988] Munz and Roberts [1987] Gossett et al.7×10−1 2.8 3 3 63 5.3×10−2 6.0×10−2 1.9×101 5400 Betterton [1991] M .0×10−2 8.8×10−2 5.html) −d ln kH d(1/T ) substance tetrachloroethene C2 Cl4 (tetrachloroethylene) [127-18-4] 3-chloro-1-propene C3 H5 Cl [107-05-1] 1.1×10−1 6. Sander: Henry’s law constants (http://www. [1980] Leighton and Calo [1981] Bissonette et al.0×10−2 3. [1990] Gossett et al.8×10−2 6.9×10−2 5.6×10−2 4.4×10−2 4.3-dichloropropene C3 H4 Cl2 [542-75-6] cis-1. [1993] Dewulf et al. [1995] Dilling [1977] Dilling [1977] Dilling [1977] Dilling [1977] Hoff et al.1×10−1 9. [1992] Robbins et al.0×10−2 9.

1×105 [K] 9700 reference Bowden et al.7×101 4100 USEPA [1982] X 3 6.3-epoxypropane 2-chloroethylvinylether bis(2-chloroethoxy)methane C5 H10 Cl2 O2 [111-91-1] 1. [1996] M 2. [1998b] M 7.0 Mirabel et al.2×105 8000 Bowden et al.6 2800 USEPA [1982] X 3 .5-dichloro-3-oxapentane C4 H8 Cl2 O (bis(2-chloroethyl)ether) [111-44-4] bis(2-chloroisopropyl)ether C6 H12 Cl2 O [108-60-1] kH [M/atm] 1. [1998a] M 2.8×101 3. [1998b] type M note 1.6×103 3700 2500 5500 USEPA [1982] USEPA [1982] USEPA [1982] X X X 3 3 3 4.4×104 8700 Bowden et al.mpg.html) −d ln kH d(1/T ) 81 substance chloroethanoic acid CH2 ClCOOH (chloroacetic acid) [79-11-8] dichloroethanoic acid CHCl2 COOH (dichloroacetic acid) [79-43-6] trichloroethanoic acid CCl3 COOH (trichloroacetic acid) [76-03-9] trichloroacetylchloride CCl3 COCl 1-chloro-2.de/~sander/res/henry. Sander: Henry’s law constants (http://www.1 2.R.mpch-mainz.

1×10−1 4.9×10−1 3.html) −d ln kH d(1/T ) substance kH [M/atm] 2.0×10−1 2. Mackay and Shiu [1975] [1979] [1979] [1981] [1981] [1993] [1973] [1992] [1982] [1992] [1990] [1988] [1996] [1980] [1981] [1975] [1981] [1981] [1992] [1982] [1996] [1990] [1988] [1985] [1975] [1981] [1993] [1992] [1982] [1988] [1975] [1981] [1981] [1992] [1988] [1982] [1988] [1981] [1981] [1981] [1982] [1988] [1981] V M T L M M M ? X X X X L X X V L M ? X L X X X V L M ? X X V L M ? X X X L M L X X L 4600 2100 1900 4700 2700 3800 4200 3500 39 3 3 3 3 3 3 1.2×10−1 2.2×10−1 2. Mackay and Shiu Mackay and Shiu Mackay and Shiu USEPA Ashworth et al.2.1×10−1 5. Gossett et al.de/~sander/res/henry.1×10−1 2. Hine and Mookerjee Mackay and Shiu Hoff et al.3.mpg.4×10−1 6.0×10−1 3. Staudinger and Roberts Ervin et al.3-trichlorobenzene C6 H3 Cl3 [87-61-6] 1.3×10−1 [K] reference type note aromatic compounds with chlorine chlorobenzene C6 H5 Cl [108-90-7] Hine and Mookerjee Mackay et al.6×10−1 2.2×10−1 2.6×10−1 2.5×10−1 3. Sander: Henry’s law constants (http://www.3×10−1 5.7×10−1 2.9×10−1 3.2.3×10−1 3.3×10−1 5.9×10−1 3.8×10−1 3.3×10−1 8. Mackay and Shiu Mackay and Shiu Hoff et al.0×10−1 2.5-trichlorobenzene C6 H3 Cl3 [108-70-3] 2500 4000 3 3 . Hartkopf and Karger Yaws and Yang USEPA Cooling et al.82 R.9×10−1 5.7×10−1 2.4-trichlorobenzene C6 H3 Cl3 [120-82-1] 1.3×10−1 4.2-dichlorobenzene C6 H4 Cl2 (o-dichlorobenzene) [95-50-1] 2800 5900 5100 1400 6700 39 3 3 3 3 1.1×10−1 3.mpch-mainz.2×10−1 2.3×10−1 3. Mackay et al.3×10−1 5. Ashworth et al.6×10−1 6.4-dichlorobenzene C6 H4 Cl2 (p-dichlorobenzene) [106-46-7] 2700 2700 2700 39 3 3 3 1.7×10−1 2.1×10−1 4. USEPA Ashworth et al.5×10−1 4.0×10−1 2. Leighton and Calo Hine and Mookerjee Mackay and Shiu Mackay and Shiu Yaws and Yang USEPA Staudinger and Roberts Bissonette et al.4×10−1 3.7×10−1 7. Yaws and Yang USEPA Ashworth et al. Hine and Mookerjee Mackay and Shiu Mackay and Shiu Yaws and Yang Ashworth et al.0×10−1 4.8×10−1 3.3-dichlorobenzene C6 H4 Cl2 (m-dichlorobenzene) [541-73-1] 2400 2600 39 3 3 1.9×10−1 2.4×10−1 2. Bissonette et al.2×10−1 6.2×10−1 2. Ashworth et al.

0×10−1 1.3 1.mpg.0×101 2.1 1. USEPA Mackay and Shiu [1981] [1992] [1992] [1982] [1981] L X L ? X X L 3 5800 1600 39 3 3 α-chlorotoluene C6 H5 CH2 Cl 1-chloro-2-methylbenzene C7 H7 Cl (o-chlorotoluene) [95-49-8] 1-chloronaphthalene C10 H7 Cl 2-chloronaphthalene C10 H7 Cl 1.5×102 7.6 5200 Mackay and Shiu [1981] tenHulscher et al.4 2.4×10−3 2.6×101 Schwarzenbach et al.9×10−1 1.8×10−1 3000 3500 USEPA [1982] Leighton and Calo [1981] X X 3 3 2.2.2×102 4600 USEPA [1982] X 3 1.1×101 4.3.9 2.2.5-tetrachlorobenzene C6 H2 Cl4 [95-94-3] pentachlorobenzene C6 HCl5 hexachlorobenzene C6 Cl6 kH [M/atm] 3.9×101 4900 USEPA [1982] Schwarzenbach et al.3. Sander: Henry’s law constants (http://www.de/~sander/res/henry.9×10−1 [K] 4800 reference Mackay and Shiu [1981] tenHulscher et al.R.4-tetrachlorobenzene C6 H2 Cl4 [634-66-2] 1.0×104 Mackay and Shiu [1981] Mackay and Shiu [1981] Mackay and Shiu Mackay and Shiu USEPA Meylan and Howard USEPA Meylan and Howard [1981] [1981] [1982] [1991] [1982] [1991] L M L M X X X X 3800 1300 hydroxypentachlorobenzene C6 HCl5 O (pentachlorophenol) [87-86-5] 2-hydroxychlorobenzene C6 H5 ClO (2-chlorophenol) [95-57-8] 2.4×10−1 3.9×10−1 3.7×10−1 6.html) −d ln kH d(1/T ) 83 substance 1.2 3.6 3. [1992] Mackay and Shiu [1981] Mackay and Shiu [1981] Mackay and Shiu [1981] type L X L M L note 3 1.9×10−1 2. [1988] X V 3 8 3.9×10−1 1. [1988] V 8 .4-dichlorophenol 4-chloro-2-nitrophenol C6 H4 ClNO3 [89-64-5] 4-chloro-5-methyl-2-nitrophenol C7 H6 ClNO3 (4-chloro-6-nitro-m-cresol) [7147-89-9] 3 3 3 3 1. [1992] Mackay and Shiu Yaws and Yang tenHulscher et al.2.1 5.mpch-mainz.5-tetrachlorobenzene C6 H2 Cl4 [634-90-2] 1.4.2 1.

4×10−2 2. Yaws and Yang [1975] [1977] [1995] [1992] [1980] [1997] [1992] V L ? V L C ? X M ? 39 3400 3400 2700 84 39 3 39 dichlorofluoromethane CHFCl2 (R21) chlorotrifluoromethane CF3 Cl (R13) dichlorodifluoromethane CF2 Cl2 (R12) 5.5×10−1 1.1.0×10−3 2.mpch-mainz. Sander: Henry’s law constants (http://www.0×10−2 1.5×10−3 2. Kanakidou et al.1×10−2 3.7×10−2 1.3×10−4 Hine and Mookerjee [1975] Yaws and Yang [1992] V ? 39 .3×10−2 3.mpg.1×10−3 2.0×10−2 1600 Hine and Mookerjee [1975] Wilhelm et al. [1977] Yaws and Yang [1992] Pearson and McConnell Hine and Mookerjee Wilhelm et al.2.html) −d ln kH d(1/T ) substance kH [M/atm] 1.2×10−3 1.84 R.4×10−3 2.de/~sander/res/henry.0×10−3 3.1×10−3 3.3×10−3 2.2-trichlorotrifluoroethane C2 F3 Cl3 (R113) 1.4×10−3 5.1×10−2 8.4×10−2 3.5×10−4 8.7×10−2 1.8×10−4 9. Yaws and Yang Staudinger and Roberts USEPA Ashworth et al.2-tetrachlorodifluoroethane C2 F2 Cl4 (R112) 1.8 trichlorofluoromethane CFCl3 (R11) 2700 3100 740 3500 39 3 3 1. [1977] Yaws and Yang [1992] Hine and Mookerjee Wilhelm et al.9×10−4 2.9×10−4 3200 Hine and Mookerjee [1975] Yaws and Yang [1992] Ashworth et al.0×10−2 1. Yaws and Yang Kavanaugh and Trussell Zheng et al.8 1800 3500 -210 39 3 3 81.2×10−3 9.4×10−1 3.5×10−1 3.1. Hine and Mookerjee [1975] [1975] [1977] [1981] [1992] [1987] [1982] [1974] [1975] [1981] [1983] [1992] [1996] [1982] [1988] [1975] V L ? M V L L ? X X C M L M ? L X X V 39 81.2×10−3 1.1-dichlorotetrafluoroethane C2 F4 Cl2 (R114) 1.9×10−1 [K] reference type note compounds with chlorine and fluorine chlorofluoromethane CH2 FCl (R31) chlorodifluoromethane CHF2 Cl (R22) 2600 Hine and Mookerjee [1975] Wilhelm et al.5×10−1 1.5×10−3 3. [1988] Hine and Mookerjee [1975] V ? X V 39 3 8.2-dichlorotetrafluoroethane C2 F4 Cl2 (R114) 2.2×10−3 1.2×10−4 8. Mackay and Shiu Yaws and Yang Munz and Roberts USEPA Liss and Slater Pearson and McConnell Mackay and Shiu Hunter-Smith et al.4×10−4 8.

1×10−2 3200 Kanakidou et al.0×103 Kanakidou et al.mpch-mainz. [1995] C 3.de/~sander/res/henry.2×10−4 3.4×10−2 2500 Kanakidou et al.2-tetrafluoroethane C2 HF4 Cl (R124) 2-chloro-1.0×101 Kanakidou et al.9×10−2 [K] 2800 reference Hine and Mookerjee [1975] Wilhelm et al.html) −d ln kH d(1/T ) 85 substance chloropentafluoroethane C2 F5 Cl (R115) dichlorotrifluoroethane C2 HF3 Cl2 (R123) 1-chloro-1.9×10−3 5200 Kanakidou et al.1-difluoroethane CH3 CF2 Cl (R142B) chlorodifluoroethanoic acid CF2 ClCOOH (chlorodifluoroacetic acid) [76-04-0] chlorodifluoroethanoic peroxyacid CClF2 COOOH dichlorofluoroethanoic peroxyacid CCl2 FCOOOH carbonic chloride fluoride COFCl trifluoroacetylchloride CF3 COCl generic peroxide with fluorine and/or chlorine ROOH chlorodifluoronitrooxymethane CClF2 OONO2 kH [M/atm] 3. [1995] C 1. [1977] Yaws and Yang [1992] Kanakidou et al.0×101 Kanakidou et al.4×10−4 3. [1995] C M E 80 2.1.2.1-dichloro-1-fluoroethane CH3 CFCl2 (R141B) 1-chloro-1. [1998b] M 3.0 3. Sander: Henry’s law constants (http://www. [1995] E 1.R.2. [1995] Mirabel et al.0×103 Kanakidou et al. [1995] C 2. [1995] E 85 .5×104 10000 Bowden et al.9 5900 Kanakidou et al. [1996] Kanakidou et al.5 2.1-trifluoroethane C2 H2 F3 Cl (R133) 1.7×10−2 Hine and Mookerjee [1975] V 7.mpg.8×10−4 2. [1995] C 2. [1995] type V L ? C note 39 2600 1. [1995] E 3.

[1995] Wright et al.0×10−1 1.5×10−1 4.mpch-mainz.5 1.3×10−1 1.4 1. [1992] Hine and Mookerjee [1975] Mackay and Shiu [1981] Nicholson et al.86 R.5 1. 8 Hine and Mookerjee [1975] Yaws and Yang [1992] Hine and Mookerjee [1975] Yaws and Yang [1992] Hine and Mookerjee [1975] 39.9 1. [1992a] Staudinger and Roberts [1996] Munz and Roberts [1987] Hine and Mookerjee [1975] Yaws and Yang [1992] Hine and Mookerjee Yaws and Yang USEPA Ashworth et al. [1992] Wright et al.3×10−1 1.html) −d ln kH d(1/T ) substance kH [M/atm] 1.9×10−1 1.mpg.3 1.2-dibromoethane C2 H4 Br2 [106-93-4] 1-bromopropane C3 H7 Br [106-94-5] 2-bromopropane C3 H7 Br [75-26-3] 1.1 3.1 1.2-dibromopropane C3 H6 Br2 [78-75-1] 1.0 1. [1992b] Moore et al.1 [K] reference type note compounds with bromine bromomethane CH3 Br [74-83-9] 3100 Hine and Mookerjee [1975] Wilhelm et al.6×10−1 1. Sander: Henry’s law constants (http://www.4 1. 8 39 . [1977] Mackay and Shiu [1981] Yaws and Yang [1992] USEPA [1982] Hine and Mookerjee [1975] Mackay and Shiu [1981] Wright et al.3 1.4 1.4×10−3 1.1×10−1 1.8×10−1 1.1 1.7 1.6×10−1 1.9 2.2×10−2 1. Hine and Mookerjee Yaws and Yang [1975] [1992] [1982] [1988] [1975] [1992] V L L ? X V L M M X X V L M C M M X X X L X V ? V ? X X V ? V ? V ? V 360 8 39 3 dibromomethane CH2 Br2 [74-95-3] 3900 4400 3700 4000 3 3 tribromomethane CHBr3 [75-25-2] 5700 5000 2700 4300 5200 5200 4700 3 3 3 3 39 bromoethane C2 H5 Br [74-96-4] 1. [1984] Nicholson et al.3-dibromopropane C3 H6 Br2 [109-64-8] 1900 3900 39 3 3 39. [1984] Wright et al.2 1.3×10−1 1.6 2.de/~sander/res/henry.4×10−1 9. [1992b] Moore et al.1 9.1 1. [1995] USEPA [1982] Tse et al.1 6.8 1. [1992a] Tse et al.7 2.

4×10−1 4.3×10−2 4.1×10−2 Yaws and Yang [1992] ? 39 1.8×10−1 4.mpg.8×10−1 4. [1998b] M 3.html) −d ln kH d(1/T ) 87 substance 1-bromobutane C4 H9 Br [109-65-9] 1-bromo-2-methylpropane C4 H9 Br [78-77-3] 2-bromo-2-methylpropane C4 H9 Br 1-bromo-3-methylbutane C5 H11 Br [107-82-4] 1-bromopentane C5 H11 Br 3-bromo-1-propene C3 H5 Br bromoethanoic acid CH2 BrCOOH (bromoacetic acid) [79-08-3] dibromoethanoic acid CHBr2 COOH (dibromoacetic acid) [631-64-1] tribromoethanoic acid CBr3 COOH (tribromoacetic acid) [75-96-7] bromobenzene C6 H5 Br [108-86-1] kH [M/atm] 8. 86 2.de/~sander/res/henry. Sander: Henry’s law constants (http://www.1×10−1 5. Mackay and Shiu [1975] [1981] [1981] [1995] [1992] [1993] [1981] V L M M ? X L 39 3 2.0×105 9000 Bowden et al.3×10−1 Hine and Mookerjee [1975] Mackay and Shiu [1981] Hine and Mookerjee [1975] V L V 3.4-dibromobenzene C6 H4 Br2 [106-37-6] 1-bromo-4-methylbenzene BrC6 H4 CH3 (p-bromotoluene) 1-bromo-2-ethylbenzene BrC6 H4 C2 H5 4.3×105 8900 Bowden et al.0 4.mpch-mainz.1×10−2 Yaws and Yang [1992] ? 39.9×10−2 Hine and Mookerjee [1975] V 5.3×10−2 [K] reference Hine and Mookerjee Hoff et al.4×10−1 5.5×105 9300 Bowden et al.3-dibromobenzene C6 H4 Br2 [108-36-1] 1.R.2×10−2 4. Yaws and Yang Hine and Mookerjee [1975] [1993] [1992] [1975] type V M ? V note 39 3. Yaws and Yang Hansen et al. [1998b] M 2.7×10−2 8.1×10−1 5300 5400 Hine and Mookerjee Mackay and Shiu Mackay and Shiu Hansen et al.7×10−1 Yaws and Yang [1992] ? 39 1.9×10−1 4.7×10−1 5.0×10−1 Hine and Mookerjee [1975] V . [1998b] M 1.

3×10−1 1.2 1. Ervin et al. Staudinger and Roberts Hine and Mookerjee [1984] [1984] [1984] [1995] [1982] [1992] [1980] [1996] [1984] [1984] [1984] [1995] [1982] [1992] [1988] [1980] [1996] [1975] M C C M X X X L M C C M X X X X L V 3 3 3 3 3 3 3 6. Sander: Henry’s law constants (http://www.6×10−1 8.8×10−1 8.mpg.0×103 8200 Parsons et al. [1971] M 54 2.9×10−1 Mackay and Shiu [1981] L . Nicholson et al.de/~sander/res/henry.mpch-mainz.6×10−1 5.3×10−1 4. Moore et al. Ashworth et al.0×10−1 4. Ervin et al.5×10−1 4.1 4700 1200 3900 5200 5200 4900 2500 4000 6400 5000 5500 Nicholson et al.88 R. USEPA Tse et al.7×10−1 8.2×10−1 3.3×10−1 4.html) −d ln kH d(1/T ) substance 1-bromo-2-(2-propyl)-benzene BrC6 H4 C3 H7 (o-bromocumene) 4-bromophenol HOC6 H4 Br bromotrifluoromethane CHF3 Br bromodichloromethane CHCl2 Br kH [M/atm] 1. Nicholson et al.1 7. Nicholson et al. Nicholson et al.7×10−1 [K] reference Hine and Mookerjee [1975] type V note 7.7×10−1 1.1 1.2 9. Staudinger and Roberts Nicholson et al. Moore et al.8×10−1 4.0×10−3 Hine and Mookerjee [1975] V dibromochloromethane CHClBr2 1-chloro-2-bromoethane C2 H4 BrCl [107-04-0] 1-bromo-4-chlorobenzene ClC6 H4 Br 6.0×10−1 1. USEPA Tse et al.

4×10−1 [K] reference type note compounds with iodine iodomethane CH3 I [74-88-4] Liss and Slater Hine and Mookerjee Hunter-Smith et al.1×10−1 6. [1995] L ? M 39 .5×10−1 2.mpch-mainz.7×10−1 1.8×10−1 7.1×10−1 1.5×10−1 8.3 2. Yaws and Yang [1974] [1975] [1983] [1995] [1992] [1995] [1992] C V M M ? M ? ? 3800 4300 5000 39 39 39 diiodomethane CH2 I2 [75-11-6] triiodomethane CHI3 (iodoform) [75-47-8] iodoethane C2 H5 I [75-03-6] 1-iodopropane C3 H7 I [107-08-4] 2-iodopropane C3 H7 I [75-30-9] 1-iodobutane C4 H9 I [542-69-8] iodobenzene C6 H5 I [591-50-4] chloroiodomethane CH2 ClI [593-71-5] Yaws and Yang [1992] 1.html) −d ln kH d(1/T ) 89 substance kH [M/atm] 1. Sander: Henry’s law constants (http://www.9×10−1 1. Moore et al.4×10−1 3.de/~sander/res/henry.2×10−1 8.R. Yaws and Yang Moore et al.9×10−1 4300 Mackay and Shiu [1981] Yaws and Yang [1992] Moore et al. 8 7.mpg.3×10−2 Hine and Mookerjee [1975] Yaws and Yang [1992] Hine and Mookerjee [1975] Yaws and Yang [1992] Hine and Mookerjee [1975] Yaws and Yang [1992] Hine and Mookerjee [1975] V ? V ? V ? V 39. 8 39 39.8×10−1 1.8×10−1 1.8 3.9×10−2 1.4×10−1 1.

Cline and Bates Gaffney and Senum Dacey et al.3×10−1 3800 Przyjazny et al. Russell et al. Vitenberg et al.4×10−1 2. Przyjazny et al. USEPA Hine and Mookerjee Przyjazny et al. [1983] 3.1 5. Vitenberg et al. [1983] M 8.0×10−2 4.8×10−1 8. Aneja and Overton Russell et al.8×10−1 4000 4000 Vitenberg et al.0 3. Sander: Henry’s law constants (http://www. Vitenberg et al.6×10−1 3.5×10−1 5.html) −d ln kH d(1/T ) substance kH [M/atm] 3.mpch-mainz.6×10−1 4.2×10−1 1.90 R.5×10−1 [K] reference type note compounds with sulfur methanethiol CH3 SH (methyl mercaptan) 3100 2800 1600 3400 Hine and Weimar Przyjazny et al. Vitenberg et al.5×10−1 1.7×10−1 6. Yaws and Yang [1975] [1975] [1983] [1975] [1983] [1992] M R M M M ? 8 8 8 39.6×10−1 3.6×10−1 2. De Bruyn et al. 8 .mpg.1×10−1 3.6×10−1 4.2×10−1 2.4×10−1 6.9×10−1 7.6×10−1 4. Przyjazny et al. 83 48 89 87 3700 3500 3500 3100 4600 4200 diethyl sulfide C2 H5 SC2 H5 dipropyl sulfide C3 H7 SC3 H7 di-(2-propyl)-sulfide (C3 H7 )2 S dimethyl disulfide CH3 SSCH3 diethyl disulfide C2 H5 SSC2 H5 Przyjazny et al.1 4. Vitenberg et al.0×10−1 4700 Przyjazny et al.2×10−1 9. Hine and Mookerjee Przyjazny et al.6×10−1 3.1×10−1 5. [1983] Yaws and Yang [1992] Hine and Weimar [1965] Hine and Mookerjee [1975] Hine and Weimar [1965] Hine and Mookerjee [1975] Hine and Weimar Lovelock et al. Przyjazny et al.8×10−1 4.2×10−1 5. [1965] [1972] [1975] [1975] [1983] [1983] [1984] [1984] [1990] [1992] [1995] [1975] [1983] M ? V V V V V M M R M C X M X E M V M M 39 8 8 88.1×10−1 2. Karl and Lindinger Yaws and Yang Przyjazny et al.de/~sander/res/henry.4×10−1 9.6×10−1 6.2×10−1 7.0×10−1 2.8×10−1 2. [1965] [1983] [1992] [1995] [1982] [1975] [1983] [1975] [1997] [1992] [1983] M M E M X V M M M ? M 87 3 ethanethiol C2 H5 SH (ethyl mercaptan) [75-08-1] 1-propanethiol C3 H7 SH 1-butanethiol C4 H9 SH [109-75-5] thiophenol C6 H5 SH thioanisole C6 H5 SCH3 dimethyl sulfide CH3 SCH3 (DMS) 43 39 3600 2.3×10−1 3.0 4. De Bruyn et al.6×10−1 5.

0×104 De Bruyn et al.1×10−2 2.5×10−2 2. 8 91. [1981] De Bruyn et al.4×10−2 5.0×101 3300 3300 3000 3600 2100 4000 4100 2800 1200 Hempel Winkler Winkler Stock and Kuss Wilhelm et al.2’-dichlorodiethylsulfide (ClCH2 CH2 )2 S (mustard gas) 3.mpch-mainz.de/~sander/res/henry.4×10−1 3. Sander: Henry’s law constants (http://www.1×10−2 2.html) −d ln kH d(1/T ) 91 substance thiophene C4 H4 S [110-02-1] 2-methyl-thiophene CH3 C4 H3 S dimethylsulfoxide CH3 SOCH3 (DMSO) dimethylsulfone CH3 SO2 CH3 (DMSO2) methanesulfonic acid CH3 SO3 H (MSA) carbon oxide sulfide OCS (carbonyl sulfide) kH [M/atm] 4. 83 39 30 30 39 3 .2×10−2 7.4×10−1 4. Yaws and Yang USEPA Hine and Mookerjee [1901] [1906] [1907] [1917] [1977] [1982] [1995] [1992] [1906] [1943] [1995] [1992] [1982] [1975] X X X X L X M ? X X M ? X V 30. 79 30 90 30.R.5×1013 /KA Brimblecombe and Clegg [1988] T 20 carbon disulfide CS2 2. Yaws and Yang Rex Booth and Jolley De Bruyn et al.9×10−2 5. [1994] E 6. Hoyt De Bruyn et al.2×10−2 1.6×10−2 3.2×10−2 2.4×103 >5.6×10−2 4. [1994] X C 11 >5.3×10−2 2.2×10−1 [K] 3700 reference Przyjazny et al. [1983] Yaws and Yang [1992] Przyjazny et al. [1983] type M ? M note 39 4000 1.mpg.1×10−2 1.0×104 Gmehling et al.5×10−2 5.

7×101 1.6×101 Santl et al.0 3.0×101 4.2×101 [K] reference type note polychlorobiphenyls (PCB’s). [1992] Burkhard et al. 94 93 aroclor1248 aroclor1254 aroclor1260 aroclor1268 2.e][1. [1985] Murphy et al. [1994] Shiu et al.4]dioxin C12 H6 O2 Cl2 (2.4 3. pesticides.4]dioxin C12 H5 O2 Cl3 (1. [1988] M X 92 2.7-dichlorodibenzo[b.2.3. 2.3 1.2’-PCB C12 H8 Cl2 (IUPAC-4) [13029-08-8] 2.e][1.6 2.1 3.2.5-PCB C12 H8 Cl2 (IUPAC-9) [34883-39-1] 3.5 4. [1988] M X 92 4. [1988] X M 93 .8×101 2.6×10−2 2. [1987] [1982] [1985] [1985] [1982] [1987] [1985] [1985] [1987] [1982] [1985] X X X X X X X X X X X X X X M X M X X M 3 3 3 3 3 3 3 3 3 3 3 3 93. USEPA Burkhard et al.4-tetrachlorodibenzo[b.0 2.4]dioxin C12 H4 O2 Cl4 (1. USEPA Burkhard et al. [1988] tenHulscher et al.9 3. Burkhard et al. [1983] Burkhard et al.0 2. [1985] Dunnivant et al.3.8 Burkhard et al. Murphy et al.1×101 2.4-trichlorodibenzo[b.2.6 3. Burkhard et al. [1988] Burkhard et al.7×101 Santl et al. Sander: Henry’s law constants (http://www.92 R.0 2.3’-PCB C12 H8 Cl2 (IUPAC-11) [2050-67-1] 3.e][1.5 1. USEPA Murphy et al.de/~sander/res/henry.3 7.4’-PCB C12 H8 Cl2 (IUPAC-12) [2974-92-7] Murphy et al.2×10−1 3.8 2.4 2. [1994] Shiu et al. [1988] 93 3 93 5700 1. [1985] Dunnivant et al. [1985] Dunnivant et al.mpg. Burkhard et al.3 8.mpch-mainz. [1994] Shiu et al. [1988] M X 92 5. [1985] Dunnivant et al.5 4.2.2 6700 10000 5900 7300 7500 4700 9700 8000 8300 9700 4400 8700 Burkhard et al.4-TriCDD) 1. etc.4-TCDD) [30746-58-8] aroclor1221 aroclor1242 Santl et al.7-DiCDD) [33857-26-0] 1.html) −d ln kH d(1/T ) substance kH [M/atm] 1.

4’-PCB C12 H7 Cl3 2.R.6. Coates Burkhard et al.9 9. [1981] [1981] [1985] [1985] [1988] X X X X M 93 93 93.4×101 3.2’.9 2.6’-PCB C12 H6 Cl4 (IUPAC-54) [15968-05-5] 2. [1988] Westcott et al.3 4. [1988] 93 2. [1983] [1984] [1985] [1988] [1985] [1988] type X X X M X M note 93.6’-PCB C12 H6 Cl4 (IUPAC-53) [41464-41-9] 3.8 <9.5’-PCB C12 H5 Cl5 (IUPAC-101) [37680-73-2] Burkhard et al.0×101 1.8 8.3’.2 3.3.2’.1×101 Burkhard et al. Sander: Henry’s law constants (http://www.1 3.5.9 >1. Coates Burkhard et al.6 5000 6000 Burkhard et al. 8 93 . [1985] Dunnivant et al. Murphy et al.0 [K] reference Murphy et al.4.2’.1 3. tenHulscher et al.5 1. [1988] USEPA [1982] tenHulscher et al.9 2.9 4.4’-PCB C12 H8 Cl2 (IUPAC-15) [2050-68-2] 2.4.4×10−1 1.2 5. [1992] X M X X 93 3 3 8. [1985] Dunnivant et al. Dunnivant et al. Westcott et al.4.3 6.5’-PCB C12 H6 Cl4 (IUPAC-52) [35693-99-3] kH [M/atm] 3.4×102 3. Westcott et al.2’.8 5.9 4. 94 93.7 1. [1981] [1981] [1983] [1985] [1985] [1985] [1988] [1992] [1984] [1985] [1988] X X M X X X X X X M X X X M X M 93. Oliver Burkhard et al.4’-PCB C12 H6 Cl4 (IUPAC-77) [32598-13-3] 2.mpch-mainz. 8 93 93 3 93 93 6100 2. [1988] X M 93 >2. [1985] Dunnivant et al.2 6. 8 93 93 93 93. Dunnivant et al.5.html) −d ln kH d(1/T ) 93 substance 4.9 <3. Dunnivant et al. [1985] Dunnivant et al.4 Oliver [1985] Burkhard et al.2’.5 3.de/~sander/res/henry. Dunnivant et al.3×101 1. Burkhard et al.6-PCB C12 H7 Cl3 (IUPAC-30) [35693-92-6] 2.8 3.3’-PCB C12 H6 Cl4 (IUPAC-40) [38444-93-8] 2.3’.mpg.5. Dunnivant et al.5-PCB C12 H7 Cl3 (IUPAC-26) [38444-81-4] 2. Oliver Hassett and Milicic Burkhard et al.3 4.9 Westcott et al.1 1. 94 93 93 93 2.4.

8 8.7×10−2 6. [1985] Dunnivant et al.3 3. 8 93 93 93 1500 6500 Meylan and Howard [1991] USEPA [1982] Kucklick et al.4’.2 5500 11000 Mackay and Shiu [1981] Brimblecombe [1986] Kucklick et al.94 R.mpch-mainz.4.4. 94 93 93.3. [1985] Dunnivant et al.de/~sander/res/henry.5×10−1 1.5×10−1 1. [1988] type X M note 93 2.5×101 3.5’-PCB C12 H4 Cl6 (IUPAC-153) [35065-27-1] 2.2’.4’.1×10−2 1.2.5.4. 94 93 93. [1991] Yin and Hassett [1986] L ? X X 38 3 3 . Coates Oliver Burkhard et al.6-hexachlorocyclohexane C6 H6 Cl6 γ -1. Coates Burkhard et al.html) −d ln kH d(1/T ) substance 2.4.2’. [1983] Burkhard et al.6’-PCB C12 H4 Cl6 (IUPAC-155) [33979-03-2] hexachlorocyclopentadiene C5 Cl6 [77-47-4] α-1.2.mpg. Dunnivant et al.4. Dunnivant et al.3.3.3’.1 [K] reference Burkhard et al.7 6.6.5.6-hexachlorocyclohexane C6 H6 Cl6 (lindane) [58-89-9] dodecachloropentacyclodecane C10 Cl12 (mirex) [2385-85-5] kH [M/atm] 5.3×102 Murphy et al.7 7. Sander: Henry’s law constants (http://www. [1983] [1984] [1985] [1985] [1988] [1984] [1985] [1988] X X M X X X X M X X M X X X 93.3×101 2.2’. [1988] Murphy et al.6 8.2×102 2.8×102 1.6’-PCB C12 H5 Cl5 (IUPAC-104) [56558-16-8] 2. [1991] 3 3 3 3.0 1.6×101 5.5.6.1 1.4’-PCB C12 H4 Cl6 (IUPAC-128) [38380-07-3] 2.2×103 2.2’.4.

1-trichloro-2.3×102 Mackay and Shiu [1981] L 2.7×103 Mackay and Shiu [1981] L 3.2×102 Mackay and Shiu [1981] L 2.7×103 Mackay and Shiu [1981] L 4.2×101 5.R.html) −d ln kH d(1/T ) 95 substance aldrin C12 H8 Cl6 [309-00-2] dieldrin C12 H8 OCl6 [60-57-1] 1.8×103 1.4×103 Mackay and Shiu [1981] L 4.1.9×101 2.de/~sander/res/henry.8×101 Mackay and Shiu [1981] L 3.2-bis-(4chlorophenyl)ethane C14 H9 Cl5 (DDT) [50-29-3] molinate C9 H17 NOS parathion C10 H14 NO5 PS [56-38-2] malathion C10 H19 O6 PS2 [121-75-5] methylchlorpyrifos C7 H7 NO3 Cl3 PS [5598-13-0] fenitrothion C9 H12 NO5 PS [122-14-5] dicapthon C8 H9 NO5 ClPS [2463-84-5] ronnel C8 H8 O3 Cl3 PS [299-84-3] leptophos C13 H10 O3 BrCl2 P [21609-90-5] kH [M/atm] 3.5×101 9.7×102 7300 Sagebiel et al.8×102 Mackay and Shiu [1981] L .8×101 [K] reference Mackay and Shiu [1981] Brimblecombe [1986] Mackay and Shiu [1981] Brimblecombe [1986] Mackay and Shiu [1981] Brimblecombe [1986] type L ? L ? L ? note 38 38 38 1.6×101 8. [1992] X 3 8. Sander: Henry’s law constants (http://www.mpch-mainz.mpg.

17) The value given by Seinfeld and Pandis [1998] is wrong. The temperature dependence is an estimate of the upper limit.html) 9 Notes 1) The value is taken from the compilation of solubilities by W. 7) Schwartz [1984] gives an upper limit of kH = 6. 6) Jacob [1986] assumed the temperature dependence to be the same as for water. no data was found in that reference. Res. The partial pressure of water vapor (needed to convert some Henry’s law constants) was calculated using the formula given by Sander et al. However. 30) As quoted by Kruis and May [1962]. 2) Only the tabulated data between T = 273 K and T = 303 K from Dean [1992] was used to derive kH and −∆soln H/R. the value has to be divided by the acidity constant KA . forgot to print the tables. 13) Several references are given in the list of Henry’s law constants but not assigned to specific species. 27) Chameides and Stelson [1992] refer to Jacob [1986] and Chameides [1984] but this value cannot be found there. J. To obtain the physical solubility of HA. 28) Data from Table 1 in preprint of the paper. 16) Value obtained by estimating the diffusion coefficient for NO3 to be D = 1. 1999).8×103 M/atm. Geophys. Crowley. 11) Value given here as quoted by Betterton [1992]. 29) Fickert [1998] extracted a value for HOBr from wetted-wall flow tube experiments. 10) This value was measured at low pH. However.. 22) Lelieveld and Crutzen [1991] assume the temperature dependence to be the same as for a(H+ )a(NO− 3 )/p(HNO3 ) in Schwartz and White [1981]. Therefore the parametriztaion of the solubility data (X1 ) was recalculated. 18) The assumption of irreversible hydrolysis is equivalent to an infinite effective Henry’s law constant. 24) This value was extrapolated from data at T = 215 K and T = 263 K. 31) Dubik et al. Sander: Henry’s law constants (http://www. 15) Value at T = 295 K. 1994]. [1994]. [1987] measured the solubility in concentrated salt solutions (natural brines). The quantities A and α from Dean [1992] were assumed to be identical.0×10−5 cm2 /s. 4) Hoffmann and Jacob [1984] refer to several references in their list of Henry’s law constants but they don’t assign them to specific species. pers.de/~sander/res/henry. 9) This value is a correction of the solubility published by Lind and Kok [1986]. Pandis and Seinfeld [1989].mpg. 25) fitting parameter used in numerical modeling. 8) Value at T = 293 K. . it seems that this is only because they did not consider the equilibrium Cl2 + H2 O HOCl + HCl. 20) For strong acids. In the abstract a range of 1×103 M/atm < kH < 3×103 M/atm is given. It is superseded by a later publication of the same group [Lind and Kok . 3) Value given here as quoted by Staudinger and Roberts [1996]. 5) Calculated from correlation between the polarizabilities and solubilities of stable gases. 12) Bone et al. comm. the solubility is often expressed as kH = ([H+ ] + [A− ])/p(HA). 14) The parametrization given by Lide and Frederikse [1995] (parameters A. 26) Kruis and May [1962] claim that Cl2 does not obey Henry’s law. B . Above T = 303 K the tabulated data could not be parameterized by equation (4) very well. however. 19) This value was extrapolated from data at T = 230 K and T = 273 K. and Jacob [1986]. [1968] as the source for the data. 23) M¨ oller and Mauersberger [1992] assumed the solubility to be comparable to HNO3 . [1983] gives Carter et al. it was later discovered that under the experimental conditions no evaluation of kH is possible (J. C ) doesn’t fit the data in the same paper for this substance. The mean value of this range (2×103 M/atm) has been used by Lelieveld and Crutzen [1991]. Asman (unpublished). 21) Brimblecombe and Clegg [1989] corrects erroneous data from Brimblecombe and Clegg [1988].mpch-mainz. Looking at their interpolation formula.96 R.

html) 97 32) This work. Lelieveld and Crutzen [1991]. 52) Value at T = 307 K. 42) Value given here as quoted by Wasik and Tsang [1970]. 51) Value obtained by Saxena and Hildemann [1996] using the group contribution method. [1982] and the aqueous-phase equilibrium BrCl + Br− Br2 Cl− from Wang et al.2088) . According to Morrison and Johnstone [1954] the solubility increases at higher temperatures. 36) Gmitro and Vermeulen [1964] give partial pressures of H2 SO4 over a concentrated solution (e. 59) Jacob [1986] assumes kH (CH3 OO) = kH (CH3 OOH) × kH (HO2 )/kH (H2 O2 ). comm. [1987]. 1996). using data from Wagman et al. 61) Ledbury and Blair [1925] (and also Blair and Ledbury [1925]) measured the solubility of HCHO at very high concentrations around 5 to 15 M.34) × p(HCHO)(252. 56) It is assumed here that the thermodynamic data in Parsons et al. Since the concentration range is far away from typical values in atmospheric chemistry the data is not reproduced here. 41) Value at T = 294 K.g. Their value of kH increases with HCHO concentration. 54) It is assumed here that the thermodynamic data in Parsons et al. Vogt (pers. 58) Value given here as quoted by Mackay et al. 50) Koga [1995] found that tert-butanol does not obey Henry’s law at c > 3. 44) The value given by Wilhelm et al. 57) Saxena and Hildemann [1996] say that this value is unreliable. 53) Value given here as quoted by Hine and Mookerjee [1975]. 10−7 mmHg for 70 weight-percent at 298 K). 39) Yaws and Yang [1992] give several references for the Henry’s law constants but don’t assign them to specific species. 49) Value at T = 303 K. and Pandis and Seinfeld [1989] all use these solubility data but do not specify how they extrapolated to lower concentrations. 35) Thompson and Zafiriou [1983] quote a paper as the source that gives only the solubility but not the Henry’s law constant.mpg.R. [1982] and the aqueous-phase equilibrium Cl2 + Br2 et al. 2 BrCl from Wang 33) Calculated by R. 60) Lelieveld and Crutzen [1991] assume kH (CH3 OO) = kH (HO2 ). 1933].. using data from Wagman et al.2/T +0. [1995]. 55) Value given here as quoted by L¨ uttke and Levsen [1997]. Sander: Henry’s law constants (http://www. Extrapolating this to dilute solutions can only be considered an order-of-magnitude approximation for kH . 40) Hansen et al. [1977] is wrong. They recommend the expression [HCHO] = 10(4538/T −11.8 mM. 34) Value at T = 290 K. 62) Dong and Dasgupta [1986] found that the Henry’s law constant for HCHO is not a true constant but increases with increasing concentration. 37) Interpolation of the original data at T < 300 K. Hough [1991]. 38) Value at T = 288 K. 45) Value given here as cited in Dewulf et al. [1994]. [1971] refers to the units [mol dm−3 ] and [atm] as standard states.. 47) Value given here as quoted by Hine and Weimar [1965].de/~sander/res/henry. [1995]. [1994]. 43) Karl and Lindinger [1997] also measured solubilities in salt solutions. [1972] refers to the units [mol dm−3 ] and [atm] as standard states. 46) This paper supersedes earlier work with more concentrated solutions [Butler et al. [1995] found that the solubility of 2-methylhexane increses with temperature.mpch-mainz. 48) Value given here as quoted by Gaffney et al.

mpch-mainz. 70) Staudinger and Roberts [1996] give ‘Khan & Brimblecombe’ as the reference but don’t include this paper in their list of references. 78) Value at T = 301 K. 81) The same data was also published in McConnell et al.de/~sander/res/henry. [1995]. 72) Kames and Schurath [1992] couldn’t assign the values to the isomers. 74) Value at T = 283 K.15 K and a partial pressure of p(HCHO) = 10−9 atm. 75) The value given by Warneck et al. At T = 298. 83) Solubility in sea water. and T = temperature in [K].7 M/atm This can obviously only be valid for T >> 255. 76) The value given by Schurath et al. [1982]. 80) Estimate for R = haloalkylgroup.1 K. 86) Value at T = 291 K. Sander: Henry’s law constants (http://www. 63) Betterton and Hoffmann [1988] list effective values that take into account hydration of the aldehydes: kH = ([RCHO] + [RCH(OH)2 ])/p(RCHO) 64) The data from Table 1 by Zhou and Mopper [1990] was used to redo the regression analysis. 68) Value given here as cited in Saxena and Hildemann [1996]. [1996] is wrong. [1975]. 71) Pecsar and Martin [1966] is quoted as the source. [1995] assume kH (CClF2 OONO2 ) = kH (PAN). 93) Value given here as quoted by Dunnivant et al. no details are available. 87) Calculated molecular structure relationship. 82) Value at T = 275 K. 91) Value given here as quoted by Rasmussen et al.1)) × 11. 69) The value given here was measured at a liquid phase volume mixing ratio of 10−6 . 92) Value given here as quoted by Santl et al. [1975]. However. [1988].5×103 M/atm. 79) Value at T = 287 K. 77) Value at T = 373 K. It should be noted that this expression does not converge asymptotically to a constant value at infinite dilution.mpg. 73) The same data was also published in Fischer and Ballschmiter [1998a]. [1996] is wrong. 89) Value given here as quoted by De Bruyn et al. 90) Value given here as quoted by Loomis [1928]. The data for acetone in their Table 2 is wrong. 88) Cline and Bates [1983] refer to an unpublished manuscript. 84) The temperature dependence (after a unit conversion) is given as: kH = exp(−8. Servant et al. this equation results in kH = 2. 85) Kanakidou et al. 67) Value given here as quoted by Vitenberg et al. 66) The value citet by Betterton [1992] is wrong. [1991] found that the Henry’s law constant changes at higher concentrations.689 + 205.98 R.9/(T − 255. there only activity coefficients and no vapor pressures are listed. . [1994].html) with [HCHO] = aqueous-phase concentration in [mol/l]. 94) Value at ‘room temperature’. [1983]. p(HCHO) = partial pressure in [atm]. 65) Value given here as quoted by Bone et al. for example.

1998. Henry’s law coefficients for aqueous solutions of acetone. F. A. L. Berdnikov. Chem. Hoffmann. Cox.. Clegg. Adv. Part I. Chem. W. D.. Verlinde. Environ. M. R.1: Kinetic investigation of the stability of peroxonitric acid and of its reaction with sulfur(IV) in aqueous solution. Environ. Booth. H.. Cullis. M. R.. R. Determination of Henry’s Law constants by equilibrium partitioning in a closed system using a new in situ optical absorbance method. Clegg. Air Composition & Chemistry . Becker. R.de/~sander/res/henry. Brimblecombe. Cambridge. Chem. and D. E. and R. 1998. R. 1995. B. F. 1998. Determination of Henry’s coefficient for volatile organic compounds in dilute aqueous systems. N. Westrick. A. 205–209. P. H. Negri. Pandis. McCoy. G. 1996. P. J. Chapter 3.. Wiesen. 199–209.. 1991. J. Amels. Chem. ? J. Environ. E. Betterton. Blatchley. Chem. V. 1983.. Soc. R.. Part V. Keene. and M. 1571–1578. Speece. M. Betterton. Shrout. A. . 1954. J. L. 1–50. In P. Scheer.... E. G. 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