Professional Documents
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CONTENT
Maximum Diesel Catalyst...........................................................................................................10 Olefin-Reducing Catalyst............................................................................................................11 Special Catalyst for MGD Process..............................................................................................1 Special Catalyst for !RGG Process............................................................................................1" Special Catalyst for DCC Process...............................................................................................1" Special Catalyst for M#P-CGP Process.......................................................................................1$ %&' Catalytic Crac(ing !dditi)e..........................................................................................................1* Catalytic Crac(ing Desulp+uri,ation !dditi)e...........................................................................1* Catalytic Crac(ing Gas-#ncreasing !dditi)e...............................................................................1% ' Catalytic Reforming Catalyst.......................................................................................................1Semi-Regeneration Reforming Catalyst......................................................................................1%"' .ydroprocessing Catalyst..............................................................................................................1/ .ydrorefining Catalyst................................................................................................................1/ .ydrorefining Catalyst for Clean Gasoline.................................................................................&1 Catalytic Crac(ing Gasoline Selecti)e .ydrodesulp+uri,ation..................................................&1 .ydrorefining Catalyst for Clean Diesel.....................................................................................&& Diesel 0ltra Deep Desulp+uri,ation Catalyst.............................................................................&& !)iation 1erosene .ydroprocessing Catalyst.............................................................................& 2u3e .ydrorefining Catalyst.......................................................................................................& 2u3ricant .ydro-de4axing Catalyst...........................................................................................&" Paraffin .ydrorefining Catalyst..................................................................................................&" Diene Selecti)e .ydroprocessing Catalyst.................................................................................&$ 5+ite Oil .ydroprocessing Catalyst...........................................................................................&$ .ydrocrac(ing Catalyst...............................................................................................................&$ Residue .ydro-demetalli,ation Catalyst.....................................................................................&* Residue .ydrodemetalli,ation 6 .ydrodesup+uri,ation Catalyst.............................................&* Residue .ydro-demetalli,ation and .ydrodenitrogenation Catalyst.........................................&Reforming Pre+ydroprocessing Catalyst.....................................................................................&Guard Catalyst.............................................................................................................................&7
Polyolefin Catalyst.....................................................................30
%1' P8 Catalyst 9 Gas P+ase Process................................................................................................... ............................................................................................................................................................ %&' P8 Catalyst 9 :orealis Process...................................................................................................... ............................................................................................................................................................ P8 Catalyst 9 Slurry Process............................................................................................................... ............................................................................................................................................................ 0 & &
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Lu e Base Oil.............................................................................4! "hite oil foo# gra#e .....................................................................................................4$ "hite oil cos%etic gra#e...........................................................!3
Petroleu% Co&e..........................................................................!! Paraffin "a'..............................................................................!( Li)ui# Paraffin "a'..................................................................!( *ully +efine# Paraffin "a'......................................................!7 ,e%i-+efine# Paraffin "a'......................................................!. Microcrystalline "a'................................................................!$ ,/ecialty "a'.............................................................................(0 Che0ing 1u% ,/ecial-Pur/ose "a'.......................................(2 Polyolefin Catalyst.....................................................................30 ....................................................................................................37 3. Catalysts for Basic Organic Materials.................................37 ....................................................................................................42 Other Catalysts..........................................................................42 Lu e Base Oil.............................................................................4! "hite oil foo# gra#e .....................................................................................................4$ "hite oil cos%etic gra#e...........................................................!3 Petroleu% Co&e..........................................................................!! Paraffin "a'..............................................................................!( Li)ui# Paraffin "a'..................................................................!( *ully +efine# Paraffin "a'......................................................!7
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,e%i-+efine# Paraffin "a'......................................................!. Microcrystalline "a'................................................................!$ ,/ecialty "a'.............................................................................(0 Che0ing 1u% ,/ecial-Pur/ose "a'.......................................(2
Sinopec is t+e largest domestic producer and supplier of catalyst for oil refining and c+emical purpose. #ts main products includeB oil refining catalystC polyolefin catalystC 3asic organic material catalyst and ot+er catalyst etc. :esides meeting demands of domestic mar(etsC products of Sinopec Catalyst are also exported to 8uropeanC !mericanC !sianC !frican and ot+er international mar(ets. Sinopec ad)ocates t+e construction of an enterprise team in type of Ser)iceC Study and #ntelligence. #t pursues t+e managerial p+ilosop+y of Duality t+e ?irst and Ser)ice t+e :est and t+e enterprise spirit of !l4ays Creati)e and ?ore)er <igorous. #t 4ill put into effect t+e competition strategy of product inno)ationC production efficiencyC product di)ersity and producer de)elopmentC in order to pro)ide +ig+->uality products and satisfying ser)ices for its )ast customers. Sinopec is 4illing to esta3lis+ long-term strategic partners+ip 4it+ its )ast customers +ome and a3roadC and to reali,e mutual progress and de)elopment.
1. Oil Refining Catalyst %1' Catalytic Crac(ing Catalyst Residue Crac(ing Catalyst OR:#; Series
Main purpose of OR:#;- 000 catalyst is to increase yield of gasoline and diesel oil in goal product. ;+e follo4ing tec+nological measures are ta(en in preparation process of t+is catalystB adopting composite molecular sie)e to endo4 t+is catalyst 4it+ 3ot+ excellent co(e selecti)ity and good acti)ity sta3ilityE in production of ultra-sta3ili,ed molecular sie)eC t+roug+ modifying tec+nology and exploiting middle +oles of molecular sie)eC t+e catalyst is suita3le for crac(ing +ea)y oil macromolecules. 5it+ impro)ed molecular sie)e >ualityC it is effecti)e to enforce macromolecule-crac(ing a3ility 3y means of modifying carrier into acti)e alumina. :ased on 3asic performances of OR:#;- 000 catalyst %+ig+ crac(ing acti)ity of macromoleculesC good co(e selecti)ityC suita3le for +ea)y oil processing'C OR:#;- 00 is a ne4-type R?CC catalyst successfully de)eloped t+roug+ replacing acti)e components. ;+is catalyst is suita3le for R?CC plants 4it+ large processing capacity 3ut lo4 catalyst=oil ratio. 5it+in flexi3le 4or(ing range of t+e fractionatorC de3utani,er and gas compressor systemC t+is catalyst can 3e used 4it+out any re)amp on t+e plant. ;+roug+ adFustment of acti)e components in preparation process of OR:#;- 00C metal tolerance of t+e product +as 3een impro)ed for 4orse feedstoc( and uncertainties. !iming at processing +ig+-)anadium feedstoc( from t+e Middle 8ast and increasing total li>uid yieldC 3ased on OR:#;- 00C OR:#;- *00 catalyst is a ne4 type R?CC catalyst successfully de)eloped t+roug+ optimi,ing acti)e components and modifying carrier. 5+ile impro)ing performance of molecular sie)e in preparation processC carrier is also modifiedC components 4it+ +ea)y metal resistance are also addedC t+us +ea)y metal resistance performance %especially )anadium' is effecti)ely promotedE s+ape-selecti)e ,eolite component is also added to increase 2PG yield appropriately. OR:#;- *00: catalyst is a (ind of anti-)anadium olefin-reducing catalyst 3ased on anti-)anadium catalyst OR:#;- *00. Commercial results re)eal t+at t+e catalyst +as strong +ea)y oil crac(ing a3ilityC +ig+ yield of lig+t oilC +ig+ octane num3er of gasolineC strong olefin-reducing a3ility etc. #n order to reali,e t+e o3Fecti)e of reducing olefin content in gasoline on t+e 3asis of anti-)anadium +ea)y oil crac(ing catalyst OR:#;- *00C OR:#;- *00: +as t+e follo4ing c+aractersB t+roug+ modification of G-type molecular sie)e and 3lending 4it+ acti)e componentsC on t+e premise of maintaining +ea)y oil crac(ing acti)ityC +ydrogen transfer acti)ity is strengt+ened to reac+ t+e goal of reducing olefin content in gasolineE acid distri3ution of catalyst is also adFusted reasona3ly to reduce t+e generation of co(e and dry gas.
3C ,eries
On t+e 3asis of successfully de)eloped ne4 Hone exc+angeC one calcinationI preparation tec+nology and increased crystallinity of ultra-sta3le molecular sie)eC JC series catalyst +as 3een de)eloped t+roug+ modifying acti)e componentsC adFusting +ole structure of carrier and gradient distri3ution of acti)e catalyst components. Due to t+e a3o)e modifying tec+nologiesC JC series catalysts are of +ig+ acti)ity and sta3ilityC excellent co(e selecti)ityC strong residue oil macromolecule crac(ing a3ilityC +ig+ +ea)y metal resistance performanceC +ig+ yield of +ig+-)alue product and lo4 unit cost of catalyst etc. JC--000 catalyst is especially suita3le for +ea)y oil crac(ing installations t+at use <RDS residue oil and residue oil
-
as feedstoc(C 4+ere it is difficult for catalyst of +ig+ 3ul( density to fluidi,e. 5it+ t+is catalystC material resources can 3e extendedE mean4+ile yield of lig+t oil can 3e increased. JC - 00 catalyst +as +ig+er acti)ity t+an JC--000 catalystC and is suita3le for +ea)y oil crac(ing installations using <RDS residue oil t+at is +ard to 3e crac(ed. ?or installation of lo4 catalyst=oil ratioC ideal product distri3ution can also 3e ac+ie)ed. JC--000: is de)eloped on t+e 3asis of JC--000C t+roug+ treating 4it+ modification tec+nologyC olefin-reducing a3ility is strengt+enedC and olefin content in gasoline can 3e reduced 3y $K* units.
45+ ,eries
D<R-1 R?CC catalyst is a specially formulated catalyst for catalytic crac(ing installations t+at use entire )acuum residue oil as feedstoc( %a33re)iated as <R?CC tec+nology'. <R?CC tec+nology can furt+er increase 3lending ratio of residue oil in catalytic crac(ing processC and increase economic 3enefit of oil refining enterprises to t+e full extent. #n order to meet t+e demand for 3lending )arious )acuum residue oils 3y large scaleC t+e follo4ing tec+nological measures are mainly ta(en in t+e preparation process of D<R-1 catalystB treating ultra-sta3le molecular sie)e 4it+ modification tec+nology and exploiting large and middle +oles of ultra-sta3le molecular sie)eC 4+ic+ ena3les D<R-1 catalyst to crac( +ea)y oil macromoleculesE treating carrier 4it+ acti)ation tec+nology to impro)e acid distri3ution and +ole distri3ution of carrierC so t+at crac(ing a3ility of carrier to residue oil macromolecule can 3e en+anced effecti)ely. !dditi)e tec+nology is adopted to impro)e +ea)y metal resistance performance %especially nic(el'. ;+roug+ optimi,ation of production tec+nology and post-treatmentC regeneration acti)ity and sta3ility of catalyst is impro)ed. ?or most domestic existing crac(ing installationsC 4it+out t+e need to re)amp plantsC t+is catalyst +as )ery 3road spreading and application prospect in oil refining 4it+ large 3lending ratio of )arious residue oils. ;o meet t+e demand for impro)ing product distri3ution and reducing olefin content in ?CC gasolineC D<R-& catalyst is a product suita3le for <R?CC processC 4+ile maintaining olefin-reducing performance. Results of industrial application re)eal t+at on t+e premise of maintaining )arious performances of D<R-1 catalystC D<R-& catalyst can reduce olefin content in ?CC gasoline as 4ell.
CC-2! ,eries
CC-1$ catalyst adopts R80SG molecular sie)e as its main acti)e component. ;+e carrier +as certain crac(ing acti)ityC middle 3ul( densityC +ig+ strengt+ and certain +ea)y oil crac(ing a3ility. #t can 3e used in catalytic crac(ing installations 4+ic+ use entire <GO or oil 3lended 4it+ less t+an 1$L <R as feedstoc(. CC-1$ can also 3e used in R?CC installations fed 4it+ entirely paraffin 3ased !;:C or 4it+ small amount of poor->uality CGO or D!O. #t +as 3een commercially applied in nearly t+irty domestic catalytic crac(ing installationsC including ?CC installations fed 4it+ 3lended <;: and R?CC installations 4it+ entire !;:. CC-1$ %M' catalyst can also increase octane num3er of gasoline. C.J-" C.J-" catalyst adopts ne4 generation ultra-sta3le SRG molecular sie)e as its main acti)e componentC 4+ic+ is prepared 3y 4it+dra4ing aluminum and replenis+ing silicon 4it+ H+ydrot+ermal M c+emicalI met+od. SRG
7
molecular sie)e integrates ad)antages of molecular sie)es prepared 4it+ +ydrot+ermal and c+emical met+odC possesses excellent t+ermal and +ydrot+ermal sta3ilityC more secondary pore and strong +ea)y oil crac(ing a3ility. #t +as little non-frame4or( aluminum inside 4it+ cleaning c+annelsC t+erefore non-selecti)e crac(ing reaction is a)oided to t+e most extentC and co(e selecti)ity is especially excellent. SRG molecular sie)e is a ne4 generation ultra-sta3le molecular sie)e 4it+ international ad)anced le)el de)eloped in t+e middle 1//0s. #n order to meet t+e demand of nic(el and )anadium resistanceC and furt+er en+ance con)ersion a3ility to +ea)y oilC (aolin eart+ 4it+ fine particleC large specific surface area and +ig+ acti)ity is adopted as carrierC 4+ic+ is 3lended 4it+ acti)e alumina to en+ance crac(ing a3ility of +ea)y oil. C.J-" catalyst +as 3een 4idely used in ten sets of domestic catalytic crac(ing installations of +ea)y oil. 0nder +ig+ 3lending ratio of residue oilC product distri3ution is still )ery good. C.A-1 C.A-1 is of excellent anti-al(ali nitrogen performanceC 4+ic+ +as 3een specially de)eloped for +ig+ content of al(ali nitrogen feedstoc( inside Sinopec. C.A-1 catalyst also adopts ne4 generation ultra-sta3le SRG molecular sie)e as main acti)e componentC 4+ic+ is prepared 3y 4it+dra4ing aluminum and replenis+ing silicon 4it+ H+ydrot+ermal M c+emicalI met+od. #n order to meet t+e demand of al(ali nitrogen resistance and furt+er en+ance con)ersion a3ility to +ea)y oilC (aolin 4it+ fine particleC large specific surface area and +ig+ acti)ity is adopted as carrierC 4+ic+ is 3lended 4it+ acti)e alumina to en+ance crac(ing a3ility to +ea)y oil.
C65 ,eries
C.< series catalyst adopts ne4 generation ultra-sta3le SRG molecular sie)e as main acti)e componentC 4+ic+ is prepared 3y 4it+dra4ing aluminum and replenis+ing silicon 4it+ H+ydrot+ermal M c+emicalI met+od. SRG molecular sie)e +as +ig+ silicon=aluminum ratioC little non-frame4or( aluminum and good +ydrot+ermal sta3ility. Mean4+ileC it +as excellent co(e selecti)ityC isomeri,ation performance and strong crac(ing a3ility to +ea)y oil. Core tec+nology of anti-)anadium catalyst is t+e setting of )anadium trapC and amount of traps is determined 3y t+e )anadium content in processed feedstoc(. #n order to impro)e crac(ing a3ility to +ea)y oil and anti-contamination a3ility from +ea)y metalC acti)e alumina is also introduced. Ot+er special components can also 3e added if t+ere is need to increase yield of 2PG or octane )alue. 0nder normal catalyst consumptionC t+is catalyst can 3e used in catalytic crac(ing installations of +ea)y oil containing "000K10000 ppm )anadium on 8-cat. Series of anti)anadium catalysts can 3e producedC and special catalyst can 3e tailored according to t+e practical situation of customerNs installation.
4OCP7 4OC+
;+is series of +ea)y oil crac(ing catalyst is mainly designed for )arious +ea)y oil catalytic crac(ing installations 4+ere gasoline octane num3er is needed to upgrade. 5it+ suc+ catalystC /0O or +ig+er grade gasoline can 3e produced directly. #t is especially suita3le for +ea)y oil catalytic crac(ing installations 4+ic+ process paraffin 3ased feedstoc(. JRP- %RPS!' s+ape selecti)e molecular sie)e is introduced in DOCR catalyst as (ernel acti)e componentC 4+ic+ +as +ig+ t+ermal and +ydrot+ermal sta3ilityC C P and C"P increasing a3ility and isomeri,ation a3ility. Octane )alue
/
5+ile o3taining perfect products distri3utionC at t+e same timeC impro)ing ?CC gasoline octane num3erC t+e series catalysts are all applica3le for processing 3lended +ea)y oil.
CC-204 ,eries
CC-&0D is a maximum diesel ?CC catalyst 4it+ +ig+ acti)ity and co(e selecti)ity etc. On t+e premise of ensuring con)ersion a3ility to +ea)y oilC acti)ity of large pores of carrier is increasedC and +ig+ yield of lig+t oil is ac+ie)ed. CC-&0D series catalyst adopts complex molecular sie)e preparation tec+nologyC )arieties and ratio of PSRG C R80SG and SRCG molecular sie)es are adFustedC selecti)e RPS! or JRP-$ ,eolite 4it+ different Si=!l ratio is also adopted. On customerNs demandC maximum diesel catalyst considering 2PGC octane )alue and anti-)anadium a3ility can 3e produced. CC-&0D< is a maximum diesel catalyst considering anti-)anadium a3ility. CC-&0D? is a catalyst product specially designed for dou3le-riser tec+nology. CC-&00D
10
CC-&00D is a (ind of diesel oriented catalyst 4it+ mid 3ul( density. Gield of 2PGC anti-contamination from )anadium and 3lending 4it+ residue oil are ta(en into consideration simultaneously.
Olefin-+e#ucing Catalyst
1O+-C7 1+5-C
GOR-C olefin-reducing catalyst adopts modified G molecular sie)eC MOG C as its main acti)e componentC 4+ic+ is modified 4it+ uni>ue oxide and endo4ed 4it+ excellent +ydrogen transfer acti)ityC fine co(e selecti)ity and excellent crac(ing a3ility to +ea)y oil. ;+e catalyst +as +ig+ acti)ity and strengt+C 4+ic+ can reali,e selecti)e +ydrogen transfer reaction and ensure effecti)e utili,ation of +ydrogen resource in feedstoc( and reasona3le distri3ution in product. ;+is catalyst also +as t+e a3ility to reduce olefin in ?CC gasoline prominently 3y 10K1$< L. Com3ined 4it+ operation tec+ni>uesC olefin content in ?CC gasoline can 3e steadily controlled under $<LC 4+ile content of isomeri,ed al(ane and aromatics can 3e increased and yield of 2PG (eeps at a +ig+ le)el. GR<-C is a (ind of ne4 type +ig+-efficiency anti-)anadium olefin-reducing catalyst. ;+is catalyst is composed of acti)e components and carrier 4it+ +ig+ crac(ing acti)ity to +ea)y oil and good co(e selecti)ityC 4+ic+ are specially de)eloped to4ard intermediate feedstoc(. Semi-synt+esi,ed carrier 3onded 4it+ alumina is adopted to impro)e anti-contamination a3ility of catalyst from +ea)y metal. P;# preparation tec+nology of catalyst is de)eloped to impro)e interfacial ad+esion 3et4een carrier and molecular sie)eC and furt+er increase anti-a3rasion strengt+. Crac(ing acti)ity and +ydrogen transfer acti)ity are adFusted and appropriately matc+ed to endo4 t+e catalyst 4it+ 3ot+ olefin-reducing function and strong crac(ing a3ility to +ea)y oil. !8P matrix is also adopted to adFust acid distri3ution and pore distri3ution of catalyst to ac+ie)e good co(e selecti)ity.
C4C
CDC is a 3rand-ne4 c+emically designed catalyst 4it+ gradient pore distri3ution and gradient acid centerC 4+ic+ ma(es it possi3le for +ea)y oil macromolecule to access acti)e center and 3eing of excellent desor3ing=diffusing a3ility. CDC catalyst possesses excellent acti)ity and sta3ilityC profound con)ersion a3ility to +ea)y oil and +ig+ +ydrogen transfer acti)ity. Co(e can 3e reduced at t+e same time. ;+roug+ formulation adFustmentC it can increase propylene content in product. !s a ne4 type ?CC catalystC it can meet )arious demands of oil refiners.
CO+ ,eries
;+is series of olefin-reducing catalysts adopt modified G molecular sie)eC MOG C as its main acti)e componentC 4+ic+ is modified 4it+ uni>ue oxide and endo4ed 4it+ excellent +ydrogen transfer acti)ityC fine co(e selecti)ity and excellent crac(ing a3ility to +ea)y oil. ;+e catalyst +as +ig+ acti)ity and strengt+C 4+ic+ can reali,e selecti)e +ydrogen transfer reaction and ensure effecti)e utili,ation of +ydrogen resource in feedstoc( and reasona3le distri3ution in product. ;+is catalyst also +as t+e a3ility to reduce olefin in ?CC gasoline prominently 3y 10K1$< L. Com3ined 4it+ operation tec+ni>uesC olefin content in ?CC gasoline can 3e steadily controlled under $<LC
11
4+ile content of isomeri,ed al(ane and aromatic +ydrocar3on can 3e increased. COR-C catalyst is suita3le for catalytic crac(ing installation 4it+ non-paraffin 3ased feedstoc(. COR< is suita3le for catalytic crac(ing installation 4it+ feedstoc( of +ea)y metalC especially )anadium. COR. +as excellent anti-contamination performance from metal. CORS is of +ig+ yield of diesel oil and +ig+ octane )alue of gasoline.
4OCO
DOCO olefin-reducing catalyst is good for selecti)e +ydrogen transfer reactionC 4+ic+ can control t+e co(e and dry gas yield effecti)ely and ensure li>uid yield. ;+is catalyst +as t+e a3ility to reduce olefin in gasoline prominently 3y 10K11<L at t+e same timeC and olefin content can 3e steadily controlled under $<LC 4+ic+ can meet t+e demand of ne4 standard gasoline. ;+is catalyst also +as strong isomeri,ation a3ilityC and isomeri,ation index %iso3utane to iso3utene ratio in 2PG' can 3e increased 3y 1.0&K1.0$LC isoal(ane in gasoline can 3e increased 3y 7.0/LC aromatic can 3e increased 3y 1.7/LC 4+ic+ is )ery important to (eep octane num3er.
1O+-99
:ased on industrial applications of t+e first generation olefin-reducing catalystC GOR-## is de)eloped to meet t+e demand of oil refining plants to impro)e product distri3ution and furt+er en+ance crac(ing a3ility to +ea)y oil. GOR-## catalyst +as t+e follo4ing c+aracters. 8ffecti)e matc+ of selecti)e +ydrogen transfer acti)ity and crac(ing acti)ity is ensured t+roug+ performance impro)ement and 3lending of acti)e components. Good selecti)e +ydrogen transfer acti)ity can ensure olefin-reducing effect to gasolineC 4+ile +ig+ crac(ing acti)ity can increase con)ersion 4it+ +ea)y oil. Ae4 type matrix is adopted to control pore distri3ution and increase medium pore proportion to en+ance +ea)y oil crac(ing a3ilityC increase yield of diesel oilC and restrain co(ing at t+e same time. !cid distri3ution of catalyst is adFusted properly to reduce co(e and dry gas.
1O+-999
;+e t+ird generation olefin-reducing catalystC GOR-###C is de)eloped to furt+er impro)e olefin-reduction performance. ;+roug+ furt+er modification of main acti)e componentsC selecti)e molecular sie)e and matrixC olefin-reducing margin and crac(ing a3ility is furt+er en+ancedC +ydrot+ermal sta3ility of catalyst is ele)atedC co(e selecti)ity and product distri3ution is impro)ed. #ndustrial application result re)ealsB in comparison 4it+ t+e second generation olefin-reducing catalystC 8-cat acti)ity of GOR-### can 3e decreased 3y L more and octane )alue of gasoline is ele)ated slig+tly.
+M,-.
#n order to meet t+e increasingly di)ersifying demands of customers for product distri3utionC RMS-7 catalyst is a ne4 type residue ?CC catalyst de)eloped to increase gasoline yield and reduce olefin of gasoline. Commercial application result re)eals t+at RMS-7 +as strong crac(ing a3ility to +ea)y oil macromoleculeC +ig+ gasoline yieldC
1&
good anti-contamination a3ility from +ea)y metalC and appropriate olefin reducing a3ility etc.
+14-C
RGD-C catalyst +as good industrial application effect on increasing yield of 2PG and diesel oil. Modified and composite ultra-sta3le molecular sie)e is adopted in RGD-C catalystC appropriate selecti)e molecular sie)e and trapping components for metal contaminations are addedC and content of middle-pore acti)e components are increased. ;+is catalyst +as strong con)ersion a3ility to +ea)y oilC strong anti-contamination a3ility from +ea)y metalC good co(e and dry gas selecti)ity. 2ess co(e and dry gas can 3e ac+ie)ed in reaction of gasoline under rigorous condition. RGD-C can selecti)ely crac( gasoline to 2PG 4it+ +ig+ yield of 2PG and diesel oil.
CMO4 ,eries
CMOD catalyst adopts multiple +ig+-performance molecular sie)es %ultra-sta3le G molecular sie)eC RPS! molecular sie)e etc' as its acti)e components. #t is produced 4it+ +ig+ solid content tec+nology. 5it+ +ig+ acti)ity and strengt+C CMOD catalyst +as prominent effect in increasing yield of diesel oil and 2PG. 5+en yield of 2PG reac+es 1$K&0mLC yield of diesel oil is 3asically maintained. CMOD catalyst +as good )anadium resistance. CMOD catalyst also +as good 3asic nitrogen resistanceC 4+ere large proportion co(ing gas oil can 3e processed. CMOD-100 can tolerate )anadium o)er 10C000 ppm on 8-cat. CMOD-&00 catalyst can tolerate )anadium $C000K10C000 ppm on 8-cat.
modification tec+nology are applied to endo4 C#P-& catalytic pyrolysis catalyst 4it+ +ig+ crac(ing acti)ityC +ig+ sta3ilityC good olefin selecti)ityC +ig+ octane )alue of gasoline and strong anti-a3rasion performance. Special Catalyst for CPP Process
C4002
Com3ining catalytic pyrolysis process %CPP' 4it+ matc+ed catalyst CD00&C under t+e reaction temperature of $*0K*$0 C lig+t olefinC dominant in et+ylene and propyleneC can 3e produced 4it+ +ea)y petroleum +ydrocar3on as feedstoc(. ?urt+ermoreC 3y controlling reaction conditionC yield ratio of et+ylene to propylene can also 3e adFusted to meet t+e demand c+ange 4it+ flexi3ility. CD00& catalyst contri3utes to 3ot+ +ig+ yield of lig+t olefin and +ig+ +ydrot+ermal acti)ity and sta3ility. #t can meet rigorous operation demand of catalytic pyrolysis tec+nology. Special Catalyst for M#P Process
C+022
M#P is an ?CC process t+at directly produces gasoline 4it+ lo4 olefin content and +ig+ octane )alue. #ts (ernel tec+nology is to re)amp existing ?CC riser reaction system appropriatelyC and di)ide con)entional single reaction section into t4o reaction sections 4it+ different reaction temperature and reaction time. M#P tec+nology ma(es catalytic crac(ing reaction proceed in eac+ reaction section controlla3ly and selecti)elyC and reali,es t+e goal to produce maximum isomeri,ed al(ane and ?CC gasoline 4it+ lo4 olefin content and +ig+ octane )alue directly. CR0&& catalyst is speciali,ed for M#P tec+nology. #ndustrial application result re)eals t+at it +as +ig+ +ea)y oil crac(ing performanceC good co(e selecti)ityC +ig+ yield of lig+t oil and prominent olefin-reducing function.
C+M9-2
CRM#-& catalyst is speciali,ed for M#P tec+nology 4+ic+ possesses t+e c+aracters of +ig+ acti)ityC +ig+ t+ermal and +ydrot+ermal sta3ility and good co(e selecti)ity. #n conFunction 4it+ M#P tec+nologyC it can reduce olefin content in gasolineC and maintain ROA at t+e same time. CRM# series catalyst adopts preparation tec+nology of composite molecular sie)esC )ariety and ratio of molecular sie)es %PSRG or R80SG' are adFustedC and selecti)e molecular sie)es %RPS! or JRP-$' 4it+ different Si=!l ratio are adopted to increase yield of propylene on t+e premise of maintaining +ea)y oil con)ersion and total li>uid yield.
content in gasoline. CGP series catalyst is a special designed catalyst for t+e process. Considering practical condition in specific Refinery and in conFunction 4it+ M#P-CGP tec+nologyC CGP-1 catalysts can guarantee olefin content in catalytic gasoline to meet 8urope ## or 8urope ### emission standardC on t+e premise of maintaining t+e same capacity of original installationC 4+ile octane )alue of gasoline is not lo4eredE yield of propylene %relati)e to material oil' is o)er -K7mL.
MP032
MP0 1 is de)eloped to increase t+e propylene content in 2PG aiming at t+e increasingly gro4ing demand for propylene in current mar(et. #ndustrial application result re)eals t+at under t+e same operating conditionC 4it+ a proportion of "K7mL additi)eC yield of propylene %relati)e to feedstoc(' can increase 3y 0.$K0.7mL on t+e premise of small increase in yield of 2PG.
C6P8 ,eries
C.P! is a (ind of ?CC additi)e to o3tain +ig+ yield of propylene de)eloped 3y R#PP. ;+is additi)e adopts metal modified JSM-$ molecular sie)e as acti)e componentsC and is prepared 4it+ particular carrier tec+nology. ;+e product +as certain M!; acti)ity 4it+out any influence to acti)ity of t+e main catalyst. #t can increase propylene content in 2PG %i.e. yield of propylene' 4+ile maintaining con)ersion rate and total li>uid yield.
1*
timeC lo4 +ydrogen consumption etc. Catalyst can 3e adFusted to 4ater and c+lorine 3alance >uic(ly and effecti)ely in normal running process. Regeneration is easy and safe 3y adopting a Hdry met+odI pressuri,ed processC 4+ic+ simplifies co(e 3urning procedureC s+ortens co(e 3urning timeC lessens surface area loss and c+lorine loss. Catalyst performance can 3e reco)ered )ery 4ell after regeneration. Catalyst can 3e regenerated eit+er on-site or off-siteC and off-site regeneration +as more ad)antage. C: series catalyst +as 3een used more t+an sixty plants not only 3y domestic customersC 3ut also 3y o)erseas customers.
P+T ,eries
PR;-!C PR;-:C PR;-CC PR;-D are ne4 generation strip multi-metal semi-regeneration catalytic reforming catalysts de)eloped 3y R#PP and produced 3y C+angling Di)ision. ;+ey +a)e t+e c+aracters of +ig+ carrier purityC proper pore distri3utionC +ig+ strengt+ and c+lorine-+olding a3ility. Selecti)ity and sta3ility are furt+er impro)edC and car3on deposit )elocity is decreased. PR;-! and PR;-C are multi-metal catalysts of 4+ic+ Re-to-Pt ratio is 1C and PR;-: and PR;-D are multi-metal catalysts of 4+ic+ Re-to-Pt ratio is +ig+er t+an 1. ;4o-section filling process is adopted in commercial applicationC for exampleC PR;-! and PR;-: are filled toget+erC PR;-C and PR;-D are filled toget+er. PR;-!= PR;-: +a)e t+e same performance 4it+ PR;-C= PR;-D 3asically. #n comparison 4it+ C:-*0= C:--0 catalystsC con)ersion rate of aromatic 4it+ PR;-!= PR;-: and PR;-C= PR;-D can 3e increased 3y o)er $LC li>uid yield can 3e increased 3y o)er 1LC 4+ile car3on deposit can 3e decreased 3y o)er 17L under t+e same reaction condition. Catalysts acti)ityC selecti)ity and sta3ility +a)e all reac+ed international ad)anced le)el 4it+ good regeneration performance and feed adapta3ilityC and excellent processing a3ility e)en for lean nap+t+enic straig+t-run oil and secondary processing oil. #n commercial applicationC continuous running time of PR;-!=PR;-: and PR;-C=PR;-D reac+ed t+irty mont+s and t4enty-nine mont+s respecti)ely in t+e first period. PR; series catalyst (eeps t+e c+aracters of C: series for applied process. PresentlyC PR; series catalyst +as already 3een applied in ten plants. Continuous Reforming Catalyst
1C+ ,eries
GCR series catalyst is a ne4 generation continuous reforming catalyst 4it+ +ig+ acti)ity and +ydrot+ermal sta3ility de)eloped 3y R#PP. ;+e o3)ious c+aracteristic of t+e ne4 generation GCR series continuous reforming catalyst is its impro)ed acti)ity. #t is increased 3y * to 7 degrees centigrade in comparison 4it+ pre)ious generation reforming catalyst applied 4idely in t+e domestic units. !t t+e same timeC due to t+e adoption of ne4 type catalytic materialsC t+e a3ility of anti-+ig+ temperature +ydrot+ermal treating is impro)ed significantlyC t+e surface area decreasing rate is slo4edC and its life time is prolonged dou3le times more t+an pre)ious generationC 4+ic+ impro)es t+e economics s+arply. Moreo)erC t+e c+lorine-+olding a3ility is increasedC and t+e inFected c+lorine >uantity can 3e reduced to +alfC 4+ic+ can in+i3it t+e c+loride corrosion of do4nstream process o3)iously. ;+e mec+anical strengt+ of t+e product is impro)edC 4it+ 3etter anti-a3rasion performance and less dust from circulation and transportation. 5it+in GCR seriesC GCR-100 is an economic catalyst 4it+ lo4 Pt contentC 4+ile GCR-100! +as a slig+tly +ig+er Pt content. GCR series catalyst product is in reducti)e state 4it+ small sp+ere diameter of 1."K&.0 mm. ;+e ne4 generation GCR series continuous reforming catalyst is suita3le for t+e reforming process aiming at +ig+17
octane num3er gasolineC aromaticC and +ydrogen 4it+ feedstoc( of straig+t-run nap+t+aC +ydrocrac(ing +ea)y nap+t+aC pyrolysis gasolineC co(ing gasolineC catalytic gasolineC condensed oil etc.
+C ,eries
RC series is a one of t+e ne4est generationC +ig+ selecti)e and lo4 car3on-depositing rate catalyst de)eloped 3y R#PP in recent years. RC011 PS-<# 4as applied successfully in J+en+ai Refinery :ranc+. RC011 is an economic catalyst 4it+ lo4er Pt contentC and Pt contentC 4+ile RC0 1PS-<##+as a slig+tly +ig+er Pt content. RC series continuous reforming catalyst +as o3)ious c+aracteristics as follo4sB #t +as good selecti)enessC 4it+ +ig+ C$M li>uid yieldC and increased aromatic and +ydrogen yield. Car3on-depositing rate decreases o3)iously for more t+an &0L under t+e same rigorous reacting condition. !t t+e same timeC good +ydrot+ermal sta3ilityC c+lorine+olding a3ility and excellent mec+anical strengt+ are (ept. ;+e ne4est RC series continuous reforming catalyst is suita3le for t+e reforming process aiming at +ig+-octane num3er gasolineC aromaticC and +ydrogen 4it+ feedstoc( of straig+t-run nap+t+aC +ydrocrac(ing +ea)y nap+t+aC pyrolysis gasolineC co(ing gasolineC catalytic gasolineC condensed oil etc. :ecause of t+e lo4 car3on-depositing rateC it ma(es special sense for t+e capacity expanding and re)ampingC especially for t+e continuous reforming plants 4it+ a constrained regeneration a3ility.
straig+t gas oil. #t is applica3le for moderate and +ig+ pressure +ydrocra(ing of +ig+-nitrogen and +ig+-sulfur crudeC and +ydrodenitrogenation and aromatic saturating of feedstoc(C also applica3le for moderate pressure +ydro-upgrading processing for refining section feedstoc(C suc+ as +ydrodenitrogenation of )acuum gas oilC residue catalytic crac(ing dieselC feedstoc( from atmosp+eric line and )acuum line 1. RA-& is a trilo3e-s+ape catalyst 4it+ acti)e component of Ai-5. :esides possessing all t+e properties of RA-1C RA-& catalyst increases .DA acti)ity 3y 1$L in comparison 4it+ RA-1. #n !ugust 1// C RA-& 4as industrially applied in C+angling Refinery. RA-& can 3e applied 4it+in all t+e range of RA-1C 3esidesC it is especially suita3le for +ydrotreating of inferior feedstoc( %suc+ as )acuum gas oilC co(ing gas oil'C and pre-refining of feedstoc( for moderate-pressure and +ig+pressure +ydrocrac(ing. RA-10 is a trilo3e-s+ape catalyst 4it+ acti)e component of Ai-5. RA-10 is an updated and su3stituted product for RA-1C 4it+ +ig+er +ydro-denitrogenC +ydro-desulfur and +ydro-dearomatics acti)ity. #n !pril 1//-C t+e first industrial application of RA-10 4as carried out in diesel +ydroprocessing plant of Guang,+ou Petroc+emical CompanyC and great success 4as ac+ie)ed. RA-10 can 3e applied 4it+in all t+e range of RA-1C 3esidesC it is especially suita3le for processing imported +ig+sulfur fraction and domestic +ig+-nitrogen fraction. #t also gi)e tec+nical support to production en+ancing. RA-10: is a 3utterfly-s+ape catalyst 4it+ acti)e component of Ai-5 4it+ +ig+ +ydro-denitrogenC +ydro-desulfurC +ydro-dearomatics acti)ityC +ig+ anti-crus+ strengt+ and 3ed porosityC and dramatically decreased 3ed pressure drop. RA-10: can 3e applied 4it+ di)ersified feedstoc( as 4ell. RA-10: catalyst 4as applied in t+e diesel +ydroprocessing plants of Sinopec Singmen :ranc+ and Sinopec SiNnan :ranc+ successfully. RA-10: catalyst can 3e applied to straig+t-run fraction %suc+ as gasolineC (eroseneC straig+t-run diesel etc.' and secondary processing fraction %suc+ as co(ing gasolineC co(ing dieselC co(ing gas oilC catalytic crac(ing diesel etc.'. RA-10: is especially suita3le for t+e production expanding plants t+at need to decrease pressure dropC and t+e ne4 and old plants t+at need to impro)e t+e product >uality. RA- & %including RA- &<' is a ne4 generation +ig+-performance +ydrorefining catalyst de)eloped 3y R#PP after complete optimi,ation 4it+ )ery +ig+ de-nitrogen and de-sulfur acti)ity. Compared 4it+ RA-& catalystC under reaction temperature of -$K 7$ C +ydrogen pressure of 7.0 Mpa and )olume space )elocity of 1.0 +-1C denitrogen acti)ity is increased 3y &0K&7LC de-sulfur acti)ity is increased 3y 7&K1 *LC 4+ile maintaining good acti)ity sta3ility. RA- &< catalyst +as already 3een applied in Sinopec SiNnan :ranc+C Sinopec C+angling :ranc+ and Sinopec Singmen :ranc+ successfully. RA- & catalyst is suita3le for preprocessing of +ydrocrac(ing feedstoc(C +ydrotreating of gas oilC and catalytic crac(ing feedstoc(. RA- & %including RA- &<' can not only sol)e t+e processing pro3lem of +ig+-nitrogen oilC 3ut also gi)e tec+nical support to production expanding.
&0
+94O, ,eries
Catalytic Crac(ing Gasoline +ydro-desulfur olefin-reducing tec+nology %a33re)iated as R#DOS tec+nology'C uses olefin-ric+ ?CC gasoline as its feedC and separates gasoline into t4o fractionsC lig+t fraction and +ea)y fraction according to product o3Fecti)e and feed property. 2ig+t fraction is extracted and refined 4it+ al(ali to remo)e t+iolC 4+ile +ea)y fraction is +ydro-desulfuri,ed and olefin reduced and finally lig+t fraction and +ea)y fraction are 3lended to get full-fraction gasoline product. ;+is tec+nology can 3e utili,ed in production of clean gasoline 4it+ sulfur content lo4er t+an &00 ppmC olefin content lo4er t+an &0 <LC and loss of anti-explosion index less t+an & units. #t is recogni,ed t+at R#DOS tec+nology +as reac+ed ad)anced le)el in international li(e tec+nologies. Catalysts applied in R#DOS tec+nology include RGO-& guard catalystC RS-1! +ydro-refining catalyst and R#DOS-1 +ydro-isomeri,ation catalyst. C+aracters of R#DOS series catalysts are proper s+ape 4it+ strengt+ increase and diffusion resistance decreaseC +ig+ diene saturating performanceC +ig+ +ydro-desulfuri,ationC olefin saturating and isomeri,ation acti)ityC efficient co(e restrain and long-term operation. #ts desulfuri,ation rate is o)er /0LC olefin saturating rate o)er *0LC 4it+ minor loss of octane )alue. R#DOS tec+nology 4as applied on t+e &&0C000ton=a +ydro-treating process of ?CC gasoline successfully in Gans+an :ranc+. #t is applica3le for deep desulfuri,ation and olefin-decreasing of olefin-ric+ ?CC gasolineC and o3Fect product is clean gasoline 4it+ lo4 octane num3er loss.
&1
+9C ,eries
De)eloped 3y R#PPC containing metal components %Ai and 5' and molecular sie)eC R#C-1=R#C-& catalysts are used to raise cetane )alue and decrease density of diesel oil from ?CC process 4it+ residue oil 3lended feedstoc(. ;+ese catalysts +a)e +ig+ saturating acti)ity to aromaticsC +ig+ crac(ing acti)ityC good selecti)ityC +ig+ acti)ity to remo)e sulfur and nitrogen. ;+ey can impro)e cetane )alue 3y more t+an 7K1& unitsC decrease diesel oil density 3y more t+an 0.0 $ g=cm C and diesel yield is more t+an /$L. Clean diesel 4it+ less t+an $0ppm sulfur content can 3e o3tainedC and t+e >uality of inferior diesel oil suc+ as ?CC diesel oil can 3e upgraded. R#C-1=R#C-& catalysts are mainly used to upgrade t+e >uality of inferior diesel suc+ as ?CC diesel. R#C-1=R#C-& catalysts can eit+er act as +ydrotreating catalysts in t+e single catalyst and single section processC or act as +ydrocrac(ing catalysts in t+e dou3le catalysts and dou3le sections process.
&&
Lu e 6y#rorefining Catalyst
+L-2
2u3ricant +ydrogenation R2-1 catalyst +as excellent 3alance 3et4een +ydrogenation function and acid crac(ing functionC and it +as t+e function to impro)e )iscosity-temperature performance of lu3ricant fraction effecti)ely and increase its )iscosity index. ;+e catalyst +as +ig+ aromatics saturating acti)ityC +ig+ de-sulfur and de-nitrogen acti)ity and certain isomeri,ation a3ility. ;+e catalyst +as good acti)ity sta3ilityC and its integral performance +as reac+ed current international le)el. R2-1C a trilo3e-s+ape strip catalystC ta(es Ai-5 as its acti)e component. #t +as 4ide adapta3ility to lu3ricant fractions from )arious feedstoc(. 8xperiment result re)eals t+at R2-1 +as good effect in +ydrogenation of lu3ricant fraction under 3ot+ +ig+ and moderate pressure. R2-1 catalyst +as 3een industrially applied in 1elamayi Petroc+emical Plant and Sinopec Singmen :ranc+. ?rom lu3ricant fraction of different feedC !P#C!P ##C or !P ### 3ase oilC 1&0K1$0:S 3rig+t oilC ru33er filling oil and 4+ite oil etc. can 3e produced. #t is applica3le for +ydrogenation process under 3ot+ +ig+ and moderate pressureC top grade lu3e 3ase oil can 3e produced from lu3ricant fraction of different feed.
&
&"
6y#rocrac&ing Catalyst
+T ,eries
Main components of trilo3e-s+ape strip R;-1 catalyst are AiC 5C and G molecular sie)e. R;-1 catalyst +as certain +ydro-desulp+uri,ationC +ydro-denitrogenation and aromatics saturating a3ility 4it+ good crac(ing selecti)ity and anti-nitrogen sta3ility. #t +as 3een successfully applied on industrial plants. R;-1 catalyst can also 3e used in middle-pressure +ydrocrac(ing tec+nology of +ea)y )acuum gas oil %RMC'. Main components of trilo3e-s+ape strip R;-$ moderate-pressure +ydrocrac(ing catalyst are 5C AiC and G
&$
molecular sie)e. R;-$ catalyst +as )ery strong +ydrocrac(ing acti)ity and good anti-nitrogen sta3ility 4it+ certain +ydrodesulp+uri,ationC +ydro-denitrogenation and aromatics saturating a3ility. #t +as 3een successfully applied in many domestic +ydrocrac(ing plants. Moderate-pressure +ydrogenation upgrading tec+nology com3ining RA-1 +ydrorefining catalyst and R;-$ +ydrocrac(ing catalyst is regarded as one of t+e t+ree great updated tec+nologies in t+e 4orld for producing diesel oil 4it+ lo4 sulfur and aromatics content 3y!merican Oil 6 Gas maga,ine. R;-$ catalyst can also 3e used in moderate-pressure +ydrocrac(ing tec+nology of +ea)y )acuum gas oil %RMC'. R;-$ can 3e used in moderate-pressure +ydrocrac(ing tec+nology of +ea)y )acuum gas oil %RMC'C also it can 3e used in +ig+-pressure +ydrocrac(ing process.
+6C-2
R.C-1 catalyst 4as de)eloped 3y R#PP 4it+ c+aracters of +ig+ +ydrogenation acti)ity and +ig+ selecti)e ringopening performance. #t can decrease :MC# of product tail oilC and is especially suita3le for t+e production of top grade c+emical feedstoc( under moderate pressure condition %trim pyrolysis feedstoc( of lo4 :MC# and reforming feedstoc( 4it+ +ig+ latent aromatics'C and +ydrocrac(ing process of top grade transportation fuel 4it+ ultra-lo4 sulfur content. R.C-1 catalyst 4as applied in t+e 1. million ton=a +ydrocrac(ing plant of Sinopec Gans+an :ranc+. ;+e result re)ealed :MC# of tail oil decreased 3y a3out t4o unitsC 4+ic+ increased et+ylene yield of do4nstream steamed crac(ing et+ylene process.
components. RMS-1 +as larger pore )olumeC proper pore si,e and concentrated pore distri3utionC proper acidity and density etcC 4it+ excellent +ydro-desulp+uri,ation acti)ityC +ydro-demetalli,ation %AiC <' acti)ityC +ig+er metal containing a3ilityC +ig+er de-nitrogenation and de-car3on residue a3ility at t+e same time. ;+e catalyst +as already 3een applied in industrial plants successfully %running period reac+ed eig+t mont+s'. #t is applica3le in residue +ydrotreating %R.;' process filled 3e+ind demetalli,ation catalyst. ;+e main function is to remo)e sulfurC metalC car3on residue and nitrogen from residue.
acti)e components. #t is a 3utterfly s+ape catalyst 4it+ uni>ue composition structure and optimi,ed preparation tec+nology. RS- 0 +as +ig+ acti)ity in sulfur and nitrogen remo)alC lo4 aromatic saturating acti)ityC and +ig+ mec+anical strengt+. #t is especially adapta3le for pre-+ydrogenation of reforming feedstoc( under +ig+ space )elocityC 4it+ strong mar(et competence and 3road industrial application prospect. ;+ey are applica3le for pre-+ydrorefining of reforming feedstoc(.
1uar# Catalyst
+1 ,eries
!s crude oil is 3ecoming +ea)ierC feedstoc( >uality in +ydrogenation process is also 3ecoming 4orse. 2ife of +ydrogen catalyst and operation period of installation is also s+ortened. RG-1 protector is Fust de)eloped to sol)e t+e a3o)e pro3lem 3y R#PP. #n +ydrogenation procedure of residue oilC large amount of impurities are found in t+e feedstoc( suc+ as ?eC Ca and co(e-producing material. ;+ese impurities 4ill deposit on t+e +ig+-acti)ity de-metal catalyst rapidly. !s a resultC t+e 3ed pressure-drop 4ill rise >uic(ly. #n order to delay t+e 3ed pressure-drop risingC a protecti)e layer t+at can accommodate large amount of ?e and co(e s+ould 3e placed on top of t+e de-metal catalyst layer. .ig+ acti)ity is not demanded for protecti)e catalystC 3ecause impurity atoms %suc+ as ?e etc' are )ery easy to 3e remo)ed. 5+at is needed is large space enoug+ %including t+e porosity of 3ed layer of protecti)e catalyst' to accommodate deposits. Mean4+ile t+e protector s+ould +a)e enoug+ crus+ing resistance. Protector RG-10 series catalyst is a special-s+ape catalyst 4it+ +ig+ strengt+ and large pore )olumeC 4+ic+ is specially de)eloped to sol)e t+e a3o)e pro3lem. ;+is catalyst series include RG-10C RG-10!C RG-10: and RG-10C. ;+ey can 3e used indi)idually or in com3ination according to particular situationC and can 3e used as protector in ot+er +ydrogenation processes. RG-10 is an inert guard catalyst 4it+ se)en-+ole 3all s+ape filled on t+e top of reactor. ;+e function is to 3loc( and capture granule from residueC impro)e stream status of li>uid and decrease pressure drop of 3ed. RG-10!=: are Rasc+ig ring s+ape guard catalysts 4it+ Ai-Mo=!lumina as components. Outside diameter of RG10! is a3out *.0mmC 4+ile RG-10: is a3out .$ mm. ;+e main function is to remo)e impurities suc+ as ?eC Ca and AaC as 4ell as Ai and < to a certain extent from feedstoc(. RG-10!=: are filled after RG-10 usually. ?rom RG-10 to RG-10!C RG-10:C t+e acti)ity increases from naug+t to existenceC and granular reduces from 3ig to small. RG-10C RG-10! and RG-10: +a)e excellent acti)ity and granular com3ination to protect t+e main catalyst. ;+e t+ree guard catalysts +a)e already 3een applied in industrial plants successfully. ;+ey are applica3le in +ydrotreating process of inferior feedstoc( %+ea)y oil'C and 3e filled on t+e top of reactor su3section 3y su3section. ;+e main function is to remo)e granule and impurities suc+ as ?eC Ca and Aa from feedstoc(.
+P-2
RP-1 is a (ind of acti)e support de)eloped 3y R#PP. #t is trilo3e-s+ape strip and mainly contains 5C Ai and alumina.
&7
5+en a secondary processing oil %suc+ as t+ermal processing gasolineC diesel oil and ot+er gas oil etc.' is processedC suc+ oil is easy to produce co(e under +ig+ temperature on t+e top of 3ed layer causing t+e 3ed pressure-drop to rise rapidly 3ecause t+ere are considera3le al(ene and diene in t+e oil products. #f a layer of catalyst 4it+ lo4 acti)ity is placed on top of t+e catalyst layerC diene can 3e +ydrogenated rapidly and t+e top co(ing can 3e a)oided. On demand of t+e a3o)e +ydrogenation tec+nologyC RP-1 acti)e support is designed. RP-1 +as excellent diene saturating performance and certain +ydro-desulfuri,ation a3ility and de-nitrification a3ility. #t also +as +ig+ mec+anical strengt+ 4it+ lo4 price.
&/
Polyolefin Catalyst
:2; PE Catalyst B 1as Phase Process
BC1 ,eries
:CG %:CG-# and :CG-##' catalyst is a (ind of Jiegler-Aatta type +ig+-efficiency P8 catalyst 4it+ SiO& as its support. #t is in)ented 3y :R#C#. #t is suita3le for et+ylene polymeri,ation or co-polymeri,ation in gas-p+ase fluidi,ed 3ed tec+nologyC especially t+ose of 0nipol tec+nology. #ts tec+nological c+aracters are listed 3elo4. #t +as +ig+ acti)ityC 4+ic+ is larger t+an $ (gP8=gCat %0nipol industrial installation'. #t +as )ery good fluidity. #t +as good response to +ydrogen regulation. #t +as good co-polymeri,ation performance. ;+e polymer produced +as +ig+ 3ul( densityC 4+ic+ is larger t+an 0. $ g=cm %0nipol industrial installation'. ;+e polymer produced +as good particle s+apeC narro4 particle si,e distri3ution and contains little fines.
,C1-2 ,eries
;+e SCG-1 catalyst is a ne4 type of +ig+-efficiency product used for gas-p+ase polyet+ylene plant 4it+ t+e 0nipol process. ;+e SCG-1 catalyst is a po4der catalyst 3ased on ;iCl"-Mg Cl& system. ;+e SCG-1 series catalyst contains t+ree typesB SCG-1%' C SCG-1%'C SCG-1%'C and can 3e used for producing full range density P8 resin %from lo4 to +ig+'. #t means t+at t+e resin product of all lo4C all medium and partial +ig+ densities % .DP8 4it+ M#&.1*U7' can 3e produced 3y SCG-1%' or SCG-1%'. SCG-1%' is only used for all +ig+ density and narro4 M5D P8 product. ;+e operating condition of reactor is t+e same as t+e original patent designing. ;+e main properties of SCG-1 are listed 3elo4. #t operates smoot+ly in t+e gas-p+ase fluidi,ed reactorC t+e reaction is easy to controlC and electrostatic s+eeting and )iolent polymeri,ation caused 3y catalyst can t+us 3e a)oided. #t is +ig+ in acti)ity. #t is >uic( in action and terminationC 3etter adapted to reactor at +ig+ load and condensed mode running. ;+e SCG-1 catalyst is sensiti)e to +ydrogen adFustmentC and its +ydrogen response is superior to t+at of same (ind catalysts. ;+e SCG-1 catalyst is +ig+ in copolymeri,ing po4erC and its response to copolymeri,ing monomers is superior to t+at of same (ind catalyst.
Compared 4it+ t+e imported catalystC t+e SCG-1catalyst particles are 3etter s+apedC t+e particle si,e distri3ution is a little narro4erC and it +as a suita3le strengt+ of 3urstingC no gat+eringC and ad+esion of t+e particlesC 4+ic+ manifest good free-flo4ing property and easy to feed in t+e catalyst feeder.
,LC-1
;+e S2C-G is de)eloped on t+e 3ase of catalyst formulation. ;+e commercial tec+nology including special facilities and process=>uality control 4ere self-exploited 3y S+ang+ai 2eaderC and t+e catalyst is made 4it+ tec+nology magnified 3y S+ang+ai 2eader. ;+e S2C-G catalyst is Jiegler -Aatta polyet+ylene catalyst 3ased on special silica. #t can 3e used in et+ylene co-polymeri,ation and
0
+omopolymeri,ation of gas-p+ase fluidi,ed-3ed. ;+e tec+nical c+aracteristics of t+e catalyst are listed 3elo4. #t +as +ig+ producti)ityC 4+ic+ is a3out 7-1& (gP8=gCat. #t +as )ery good response to +ydrogen regulation. #t +as good response to comonomer. #t +as +ig+ settle 3ul( density on resinC 4+ic+ is larger t+an 0. $ g=cm . 5it+ good free-flo4ing propertyC it can 3e applied in intrinsic feeder system and soft4are system of 0nipol process. ;+ere is )ery good particle s+ape of resinC narro4 particle si,e distri3ution and fe4 fines.
,C1-3C4C! ,eries
;+e SCG- catalyst is used in 0nipol process. SCG- catalyst is c+rome-3asedC 4it+ medium molecular 4eig+t distri3ution %M?RP$0/0'C used in t+e production of .DP8C and its propertiesC uses and met+od of use are t+e same as t+ose of t+e imported :- 00 %?- ' catalystC +o4e)erC 3ecause of impro)ement on t+e support and electron donorC its properties are some4+at impro)ed. ;+e SCG-" catalyst is used in 0nipol process. SCG-" catalyst is c+rome-3asedC 4it+ medium molecular 4eig+t distri3ution %M?RP$0/0'C used in t+e production of 22DP8C and its propertiesC uses and met+od of use are t+e same as t+ose of t+e imported :-"00%?-"' catalyst.!ndC 3ecause of impro)ement on t+e support and electron donorC its properties are some4+at impro)ed. ;+e SCG-$ catalyst is used for production of 3road molecular 4eig+t distri3ution%M?RP-$-1$0 ' .DP8 in 0nipol processC Fust t+e same as t+e traditional imported G- 00 %S-&' catalyst. #ts performance indices and uses are exactly t+e same as t+ose of t+e imported G00 %S-&' catalyst. #t is a c+romium %Cr' 3ased catalyst for t+e production of all t+e 3rands of .DP8 made 4it+ t+e original G- 00 catalyst.
BC, ,eries
:CS Series %:CS01C :CS0&' catalysts are a (ind of slurry catalysts 4+ic+ are applica3le to et+ylene polymeri,ation 4it+ 0nipol process and :P process. ;+ey can 3e used to produce a )ariety of P8 gradesC including inFection moldingC extrusion molding and flo4 molding. ;+ey +a)e +ig+ acti)ity 4it+in t+e range of 1$K 0(gP8=gCat in industrial process. ;+e polymer produced +as +ig+ 3ul( density 4+ic+ is larger t+an 0. &g=cm . ;+ey +a)e excellent copolymeri,ation performance and +ydrogen response. ;+e melt flo4 index of polymer produced is adFusta3le 3et4een 0.&K70 g=10min.. ;+e polymer produced +as good morp+ology and contains fe4 fines. ;+e difference is t+at :CS01 catalyst adopts MgCl& as its support and t+at :CS01 catalyst adopts SiO& as its support.
,LC-,
;+e S2C-S is de)eloped on t+e 3ase of catalyst formulation from 3enc+-scale 4it+ autonomous intellectual property. ;+e commercial tec+nology including special facilities and process=>uality control 4ere self-exploited 3y S+ang+ai 2eaderC and t+e catalyst is made 4it+ tec+nology magnified 3y S+ang+ai 2eader. ;+e S2C-S is a slurry catalyst 4it+ some solids in t+e special mineral oil. #t is a non-silica supported Mg=;i catalyst and is designed to replace traditional po4der catalyst. S2C-S is used for producing narro4 22DP8C MDP8 and .DP8 on gas-p+ase fluidi,ed-3ed polyet+ylene process. #ts main properties are s+o4n 3elo4.
1
#t +as a +ig+ producti)ityC 4+ic+ can reac+ &$- 7 (gP8=gCat. ;+e c+emistry and polymeri,ation 3e+a)ior are similar to t+ose of po4der catalystC 3ut are not identical. S2C-S and po4der catalyst re>uire same C"P=C&P or C*P=C&P ratio for a gi)en densityC 3ut t+e acti)ity of S2C-S is +ig+er 4it+ comonomer and it +as lo4er +exane extraction ratio. 2o4er S2C-S catalyst is re>uired in reactor for same !l=;i ratio. .ydrogen response of S2C-S is 0L 3etter t+an po4der catalyst for same M#. 2o4er ; & is re>uired 3y t+e reactorC and ;& le)el in t+e reactor is -$L lo4er t+an po4der catalyst. Moreo)erC t+ere is less as+ in t+e product and ?!R is 3etter.
,LC-i ,eries
;+e S2C-i catalyst is a ne4 type of +ig+-efficiency product used for gas-p+ase polyet+ylene plant of #nno)ene process. ;+e S2C-i catalyst is a po4der catalyst 3ased on ;iCl"-Mg system. ;+e S2C-i series catalyst contains t4o typesB S2C-i %2D' and S2C-i%.D'C and can 3e used for producing full range of density P8 resin %from lo4 to +ig+'. #t means t+at t+e resin product of all lo4C all medium can 3e produced 3y S2C-i %2D'. S2C-i%.D' is only used for all +ig+ density and narro4 M5D P8 product. ;+e operating condition of reactor is t+e same as #nno)ene original patent designing. ;+e main properties of S2C-i are listed 3elo4. ;+e S2C-i catalyst operates smoot+ly in t+e gas-p+ase fluidi,ed reactorC t+e reaction is easy to controlC and electrostatic s+eeting and )iolent polymeri,ation caused 3y catalyst can t+us 3e a)oided. #t is +ig+ in acti)ityC a3out *-7.$ (gP8=gCat. #t is >uic( in action and terminationC 3etter adapted to reactor at +ig+ load and condensed mode running. ;+e S2C-i catalyst is sensiti)e to +ydrogen adFustmentC and its +ydrogen response selecti)ity is superior to t+at of same (ind catalysts. #t is +ig+ in copolymeri,ing po4erC and its response to copolymeri,ing monomers is superior to t+at of same (ind catalyst.
Compared 4it+ t+e imported catalystC t+e S2C-i catalyst particles are 3etter s+apedC t+e particle si,e distri3ution is a little narro4erC and it +as a suita3le strengt+ of 3urstingC no gat+eringC and ad+esion of t+e particlesC 4+ic+ manifest good free-flo4ing property and easy to feed in t+e catalyst feeder.
&
BCE Catalyst
:C8 catalyst is a ne4 (ind of +ig+-efficiency P8 catalyst aimed to produce +ig+ grade P8 product in slurry process. #t can 3e used to produce a )ariety of .DP8 and MDP8 products including t+e pipe material of P870C P8100. #t +as +ig+ acti)ityC 4+ic+ is larger t+an &$ (gP8=gCat.. #t +as good co-polymeri,ation performance 4it+ less oligomer. ;+e +ydrogen response property is good and t+e 3ul( density of polymer is larger t+an 0. 7 g=cm C 4+ic+ is muc+ +ig+er t+an t+at of t+e same (ind of catalyst. ;+us t+e load of t+e reactor can 3e en+anced easily. ;+e polymer produced +as good morp+ologyC narro4 particle si,e distri3ution and contains fe4 fines. !ll properties of :C8 +a)e exceeded or reac+ed t+e le)el of imported catalyst.
NT-2
A;-1 catalyst is a ne4 (ind +ig+ efficiency supported catalyst. #ts acti)ity is larger t+an *00 (gP8=g;i. ;+e 3ul( density of t+e polymer produced is larger t+an 0. 0g=cm . #t +as good particle s+ape and good co-polymeri,ation performance etc. #t is suita3le for co-polymeri,ation of et+ylene 4it+ +exene and ot+er V-olefinsC and it s+o4s excellent co-polymeri,ation performance. ;+e catalyst +as )ery good response to4ard +ydrogen regulation.
N1
AG catalyst is particularly designed for t+e #nno)ene process.!nd t+e PPresin of )arious 3rands can 3e produced. #t +as 3een applied on se)eral industrial installations successfully. #ts main tec+nological c+aracters are listed 3elo4. #t +as +ig+ acti)ityC 4+ic+ is larger t+an $$ (gPP=gCat %li>uid p+ase 3ul( polymeri,ationC -0C t4o +ours'. #t +as good response to4ards +ydrogen regulationC and t+e melt flo4 index of polymer produced 4it+ it is adFusta3le 3et4een 0.&K"0 g=10min. #t +as +ig+ stereospecific a3ilityC and t+e polymer produced 4it+ it +as +ig+ isotacticity. #t +as good co-polymeri,ation performance. ;+e polymer produced 4it+ it +as +ig+ 3ul( densityC 4+ic+ is larger t+an 0."* g= cm . ;+e polymer produced 4it+ it +as good particle s+apeC good fluidity. ;+e PPresin produced 4it+ it +as excellent mec+anical performance.
N8
A!catalyst is a ne4 (ind of granular PP catalyst. #t +as +ig+ acti)ity and +ig+ impurity resistance. #t +as good morp+ologyC +ig+ specific surface area. #t +as adFusta3le stereo-specific a3ility. #t +as +ig+ sensiti)ity to +ydrogen regulationC sta3le release of acti)ity and good copolymeri,ation performance. ;+ere are fe4 fines in t+e catalyst and t+e polymer produced 4it+ it. ;+e catalyst can 3e used in production of impact-resistant co-polymer. #t +as already 3een used in producing +ig+-speed :OPP resins and impact-resistance copolymers in t+e .ypol process. ;+e main properties of A!catalyst are s+o4n 3elo4. #t +as +ig+ acti)ityC 4+ic+ is larger t+an "$ (gPP=gCat %li>uid p+ase 3ul( polymeri,ationC -0C t4o +ours'. #t +as good response
"
to4ards +ydrogen regulationC and t+e melt flo4 index of polymer produced 4it+ it is adFusta3le 3et4een 0.&K"0 g=10min. #t +as adFusta3le stereo-specific a3ilityC and t+e polymer produced 4it+ it +as an adFusta3le isotacticity. #t +as good co-polymeri,ation performance. ;+e polymer produced 4it+ it +as +ig+ 3ul( densityC 4+ic+ is larger t+an 0."* g= cm . ;+e polymer produced 4it+ it +as good particle s+apeC good fluidity. ;+e PPresin produced 4it+ it +as excellent mec+anical performance.
N4 Catalyst
AD catalyst is a ne4 (ind of PP catalyst 4it+ ne4 internal electron donor. #t +as excellent properties and can 3e used in a )ariety of PP installations. #t +as super +ig+ acti)ity 4+ic+ is a3out 0L +ig+er t+an t+at of t+e same (ind of catalyst. ;+e isotacticity index is easy to adFust. ;+e +ydrogen response performs )ariously. Series inner donors correspond to series +ydrogen responsesC from lo4 to +ig+C to meet different conditions. ;+e distri3ution of molecular 4eig+t of polymer is 3road and t+e polymer produced +as 3ot+ a good mec+anical property and a good manufacturing property. ;+e polymer produced +as good morp+ology and contains fe4 fines.
D, ,eries
GS 7"1=7"& polypropylene catalyst is gray 3ro4n crystal po4der. #ts acti)ity is larger t+an "0 (gPP=gCat. #t +as good particle s+ape and ca)ity structure. #t +as excellent polymeri,ation (inetic 3e+a)iorC 4+ic+ is fa)ora3le for t+e operation and control of industrial polymeri,ation process. #t is suita3le for PP installations of slurry processC .ypol process and 3atc+ 3ul( process. ;+e polymer produced 4it+ it s+o4s a 3ul( density a3out 0."&K0."$ g=cm . ;+e main tec+nological indexes of t+e catalyst +a)e reac+ed t+e international standard of t+e similar catalysts.
64C
.DC is Jiegler-Aatta carrier-type +ig+-efficiency catalyst 4+ic+ 3elongs to t+e fourt+ generation. #t +as t+e c+aracters of +ig+ acti)ityC long life and +ig+ impurity resistance etc. ;+e catalyst +as good co-polymeri,ation performance. ;+e polymer produced 4it+ it +as a +ig+ isotacticity. ;+e a)erage particle si,e of t+e polymer produced 4it+ it is around 0.7K$.0 mmC and t+e polymer particle is in t+e sp+erical s+ape. ;+ere are fe4 fines contained in t+e products.
acti)ity. ;+e initial temperature is around &&0-& 0 depending on production load. ;+e space-time yield can reac+ maximum &70 g8O=+.lC 4+ic+ ma(es it one of t+e 3est catalysts in commercial application. #t s+o4s extraordinary sta3ility. #t is >uite sta3le 4it+ slo4 declined speed in selecti)ity and slo4 decay in acti)ity. !nd it can 3e used for &-$ years in commercial plant application. ;+e selecti)ity in later stage is normally o)er -7L.
:.; Catalyst for Li)ui#-/hase ,electi<e 6y#rogenation of Pro/yne an# Pro/a#iene in C3 *ractions
BC-L-.3
5it+ t+e catalystC propyne and propadiene in C fractions can 3e effecti)ely remo)ed to meet t+e re>uirements of et+ylene unitsC 4it+ slig+t increase in propylene yield. :y no4 t+e process and catalyst +a)e 3een already applied to more t+an 10 units in C+inaC as 4ell as a num3er of o)erseas et+ylene units eac+ of a capacity of o)er *00 t+ousand M;!. #t offers+ig+ acti)ityC selecti)ityC and sta3ilityC 4+ile less polymers formed. #t gi)es us longer regeneration cycleC10 mont+s a3o)e under normal operational conditions. Catalyst life time longer t+an $ years. #t offers ad)anced singlestage li>uid-p+ase +ydrogenation processC featuring less e>uipmentC lo4er in)estment and more operation con)enienceC as compared 4it+ t+e con)entional t4o-stage process. #t +as +ig+ li>uid space )elocityC +ence lo4 consumption of catalyst. #t gets lo4 consumption of energy. !s t+e inlet temperature of t+e reactor ranges from &$ to "$ Cno propylene refrigeration is necessary. #ts p+ysical properties are listed 3elo4. #t +as an appearance of yello4is+ gray granules of X&.$-$mm. #ts 3ul( density is 0.7-0./g=ml. #ts composition is Pd=!l&O . #ts crus+ing strengt+ is a3out $0-100A=granule.
"1
Other Catalysts
:2; PF ,or ent
+8F-20008
#t is a (ind of solid molecular sie)e sor3ent de)eloped 3y R#PP. #t is used in t+e simulating remotion-3ed process to separate t+e +ig+ purity xylene product from t+e xylene mixture containing C7 non-aromatic compoundsC et+yl 3en,ene %8:'C Paraxylene%P@'C mata-xylene%M@' and O@. #t is an ideal selection for replacement of aromatic P@ sor3ent in separation unit. #t +as 3een used in t+e domestic Parex commercial plant designed 3y 0OP successfully. #ndustrial result re)eals t+at t+e purity of P@ is //.7LC and t+e yield of P@ is o)er /7L.
con)entional catalytic oxidi,ing catalystC .;S ma(es oxidi,ing process simpler. ;+e reaction condition is moderate as it can proceed under normal pressure and lo4 temperature %&0K100 '. ;+e catalytic oxidi,ing acti)ity is impro)ed. ;+e yield and selecti)ity of t+e final oxidi,ation products are raised. #t is also an en)ironment protecting product since t+e pollution is prominently reduced.
"
:.;G P8 Catalyst
Catalyst for Maleic 8nhy#ri#e /ro#uction fro% O'i#ation of Ben=ene :BC-22.B;
:C-117: de)eloped 3y :R#C# is a catalyst for production of maleic an+ydride from selecti)e oxidation of 3en,ene. ;+is is a ne4 type lant+anon <&O$-MoO series catalyst. ;+e acti)e components are +olding on t+e inert cricoid carrier. ;+e catalyst +as 3een used in more t+an t+irty units in C+inaC suc+ as 1aifeng organic c+emical plantC ;aiyuan DiaoyouC S+anxi ;aimingC C+ang,+ou S+uguangC S+ang+ai C+angfengC etc.
PerformanceB
.ig+ catalytic acti)ity
.ig+ single translation ratio of 3en,ene %/7LK100L' .ig+ selecti)ity and +ig+ yield t+e mass yield of maleic an+ydride is %/0-/ L' 2o4 reaction temperature
Good sta3ility %K"70'
Catalyst for P+t+alic !n+ydride production from oxidation of o-xylene %:C-& /' ;+e H:C-& /I catalyst de)eloped 3y :R#C#C 4+ic+ is a <&O$-;iO& supported catalyst used for t+e H-0-/0 gram processI fixed 3ed oxidation of o-xylene to produce P+t+alic !n+ydride. ;+e reactor is filled 4it+ different (inds of catalyst in t4oC t+ree or four partsC 4+ic+ are of different acti)ity and selecti)ity. ;+e catalyst +as 3een used in t+e P+t+alic !n+ydride production units in Sinling and Dilu
""
petroc+emical company of S#AOP8C. PerformanceB .ig+ concentration of o-xyleneB K-0-/0g=Am 2o4 reaction temperatureBSalt :at+ ;emperatureB $0K -0 S+ort induction periodB t+e concentration of o-xylene can reac+ more t+an 70g=Am in "$K-$ days .ig+ space )elocity and +ig+ yieldB Gield of P!B K11 4tL .ig+ >uality P!B t+e content of P;2D in crude P!Y0.1$4tL 5it+out adding SO&
Lu e Base Oil
"$
"*
Outline of product B ;+is product is t+e 4+ite-colored oil finely prepared t+roug+ t4o-stage +ig+-pressure p+drogenation of t+e distillation cut of petroleum lu3rication oil. C+aracteristiceB Mineral oil industrial grade is a colorlessC transparentC odourless C tasteless and oily li>uid and free from fluorescenceC #t can dissol)e in et+erC c+loroformC gasoline and 3en,eneC not in 4ater or alco+ol. Main index %StandardB S.000*-/7'
Grade Model (inetic )iscosity % "0 flas+ point%open' C pour point C color C ZP )itriol color test ' C mm&=s ZP TP *.1 -.$ 1 0 M M&0 pass
Sala3le product 10 /.0 11.0 1"0 M M&0 pass 1$ 1 .$ 1*.$ 1$0 M& M&" pass
0sesB #t se)ers as lu3ricantC sol)ent or coolant for spinning and 4ea)ing in c+emical or synt+etic fi3re industry in order to soften and 3rig+ten textiles. !lso it is used as 4etting agentC sol)ent or lu3ricant in t+e industries of synt+etic resin and plastic processing. Pac(ing B &002 in metal pail or special tan(er Aote B 1 . ;+e standard is follo4ing t+e S.01*". & . Stored in cool airiness placeC not mixed 4it+ moisture and impurity.
"-
"7
Outline of /ro#uct G ;+is product is a colorlssC odorlessC tastelessC fluorescence-freeC and clear oily li>uid. ;+is is t+e 4+ite-colored oil finely prepared t+rout+ t4o-stage +ig+-pressure +y-drogenation of t+e distillation cut of petroleum lu3rication oil and it excludes t+e 4+ite mineral oils mixed 4it+ additi)es for processing purpose. >sesG #t is suita3le for gloss settingC ad+esion pri)entionC 3u33le remo)ingC sealing and polis+ing of food. !lso it is used for anticorrosion and lu3rication of food mac+ineryC Operating appliances and p+armaceutical mac+inery. :esidesC it can prolong t+e s+elflife of li>uorC)inegarC fruits )egeta3les and canned food. Mo#el 10O C 1$O C &*O C *O ,tan#ar# 1B4.!3-$4 #tems 10 1inematic <iscosity%"0 ?las+ point C Say3olt colority Solu3le acid or al(ali Mec+anical #mpurity C L%m=m' 5ater C L%m=m' !rsenic C mg=(g .ea)y metal mg=(g Plum3um C mg=(g Max Max Max '.mm&=s Min -.* 1&." 1"$ M 0 Aone Aone Aone 1 10 1 Pass Pass "&0nm' Max 0.1 1&.$ Specifications 1$ 1-.$ &" &* &7 &.$ 1*$ M 0 Aone Aone Aone 1 10 1 Pass Pass 0.1 * /.$
Readily car3oni,a3le su3stances Solid Paraffin 0) a3sor3ance%at 4a)e lengt+ &*0 Pac&ing B &002 in metal pail Note G
"/
1 . #n assordance 4it+ t+e stipulaton Met+od 1 and t+e Dry Pod,oli,ation Met+od s+all3e used. & . #n accordance 4it+ t+e stipulation t+e dry digestion procedure spercified in t+e met+od s+all 3e used. . ;+e 4a)elengt+ detection range specified in G:=;11071 s+all 3e extended to "&0nm.
-0O
/0O
' C mm&=s
*$
-$
-$
100
ZP
& 0
& $
C+roma
ZP
M 0
M 0
easy c+arring matter coefficient of refraction C nD&0 0< a3sor3ance =cm %&*0 "&0nm' TP
pass
pass
1."-0
1."7$
1."-0
1."7$
0.1
0.1
% 10mm.g 'C ZP
& 0
&"0 $0
&.$L pointC ZP
&$$
&*0
' C (g=m
7$/
770
7*0
770
1 . ;+e standard is follo4ing t+e S.01*". & . Store in coolC 4ell-)entilated placeC a4ay from moisture and impurity.
$1
'C mm&=s
11
neutrality
TP
10
2ead C ppm TP
!s C ppm TP
0< a3sor3ency=cm TP
0.1
Solid paraffin
pass
pass
Pac&ing B &002 in metal pail Note G 1 . ;+e standard is follo4ing t+e S.01*". & . Store in coolC 4ell-)entilated placeC a4ay from moisture and impurity.
$&
Specifications 8xcellent 10 -.* 1&." 1"0 1$ 1&.$ 1-.$ 1$0 0.1 Aeutral Pass Pass 0 &* &" &7 1*0 &.$ 1*0 * /.$
Note G
1. #f 10 ml of t+is product added 4it+ 10ml neutral alco+ol is 3oiled and t+en stands-still C t+e reaction of t+e alco+ol layer to t+e 4et litmus paper s+all (eep neutral. &. Pac(ageC mar(s and transportation ;+is product s+all 3e pac(edC mar(edC storedC transportedC deli)ered and accepted in accordance 4it+ S.01*". . Sampling Sample of &2 s+all 3e ta(en in accordance 4it+ G:=;"--$* for t+e inspection and as t+e reser)ed sample.
$"
Petroleu% Co&e
SP8C#?#C!;#OA
#;8MS Sulp+urCL Max. <olatile MaxCL !s+Max Moisture MaxCL Density g=cm &.07 &.1 Report 1& 0. 1& 0. 1" 0.$ 7 117 0.7 &0 1.& &0 1.& S.=; 00&* S.=; 00&/ S.=; 00 & S.=; 00 ?#RS; GR!D8 0.$ 0.$ 0.7 1 1.$ & 1O! 1O: &O! &O: O! O: .ig+ Sulp+ur U ;8S; M8;.OD G:=; 7-
#;8MS Sulp+urCL 5olatile Ma'7 I 8sh Ma'7I Moisture Ma'7I Pac(ing B #n 3ul(
$$
Paraffin "a'
PrecautionsG 1ept in s+adyC dry stores and protected from direct suns+ineC dustC 4ater and c+emical su3stances during storage and transportation. Specification
#;8MS 2#M#;S
$&OSR Melting pointC Oil contentC 4tL Max ColorC Say3olt Min Penetration OdorC num3er Max 5ater-solu3le acid or al(ali Mec+anical impurity and 4ater 2ig+t Sta3ility C num3er Max ;otal Sol)ent Content %?or :en,ene 6;oluene'Cppm ?D! 0< !3sor3ance &70-&7/ nm &/0-&// nm 00- $/nm *0-"00nm Report Report Report Repo rt Report %100gC&$'C1=10mm Max & Ail Ail Min Max $& $" 1.0 M&$ &&
$"OSR $" $* 1.$ M1&0 & Ail Ail * Report Report Report Report Report
$"O?R $" $* 0.* M&7 11 Ail Ail Report Report Report Report Report
$*OSR $* $7 1.$ M1&0 & Ail Ail * Report Report Report Report Report
$*
Melting Min pointC Max Oil contentC 4tL Max ColorCSay3olt Min 2ig+t sta3ilityC num3er Max Penetration%&$C100g'C1=10mm Max 1inetic )iscosity %100'mm&=s OdorC num3er Max 5ater-solu3le acid or al(ali Mec+anical impurity and 4ater
$" $*
$-
#;8MS
AO.$"
2#M#;S
AO.$* $* $7 1.7 M1* & Report Report & Ail Ail AO.$7 $7 *0 AO.*0 *0 *&
;8S; M8;.OD G:=; &$ / G:=; $$" G:=; $$$ S.=; 0"0" G:=; "/7$
Melting pointC
Min Max
$" $*
Oil contentC 4tL Max ColorC Say3olt Min 2ig+t sta3ilityC num3er Max Penetration %100gC&$'C1=10m m Max %100gC $'C1=10m m 1inetic )iscosity %100'mm&=s OdorC num3er Max 5ater-solu3le acid or al(ali Mec+anical impurity and 4ater
$7
Microcrystalline "a'
8//licationG 0sed in 4ater proofC anti-corrosionC ad+esi)esC polis+esC desensiti,ersC fine castingC insulationC ru33er anti-o,onantsC medicineC cosmeticsC food-stuff and food pac(agingC etc. Pac&ingG Pac(ed in PP 4o)en 3ag 4it+ inner P8 film 3ag and (raft paper 3agC $0(g net eac+ PrecautionsG 1ept from direct sun-s+ine during storage for (eeping color sta3ilityE pre)ented from o)er +eating in melting and mingling 4it+ 4ater and impurities during storage and transportation.
Specification #;8MS -0O Grade ! Melting Point Max Min Penetration %100gC &$' 1=10mmC Max Oil Content 4tLC Max ColorC Say3olt Min 1inetic )iscosity100m=sC ?D! 0< !3sor3ance &70-&7/mm Max &/0-&//mm Max 00- $/mm Max *0-"00mm Max &.$ T*
*-&
?ood grade
*-&
Grade !
-7&
regular grade
7& 7-
Grade !
7& 7-
?ood grade
7& 7-
&0
1* 1.0
17
1" 1.0
&.$ 10[&0
$/
,/ecialty "a'
;+ere are more t+an 100 (inds of specialty 4ax products in S#AOP8CC applied in food pac(ingC paintingC ru33er protectingC sealing of 3ottle-made +andcraft and 3est roof materials for t+e mar3leC etc. ,PEC98LTD "8F TDPE, Series of Precise ?ounding 5ax Ru33er Protection 5ax Domestic ?o4l ?eat+er-Pu4ing 5ax Soft Microcrystalline 5ax Polis+ing :ride Smudge-proof 5ax Soft Paraffin 5ax Pre)enting Rust 5ax Compound 5ax for 8mulsified 8xplosi)e Specialty 5ax for P+ase C+ange 8nergy-Storing Material :ottle-made .andcraft Seal 5ax
*0
#llustrationB ;+is product +as good flexi3ilityC agglutinationC 4ater resistance and oxidation resistanceC pure 4+ite out4ard appearance and good sta3ilityC conforming to ?D!1-&.77* examination standards.
*1