S GD & T THANH HA

THI CHN T HC SINH GII LP 12

Mn thi: Ho hc
Thi gian lm bi: 150 pht
Ngy thi: 14/9/2010

Trng THPT Hm Rng

Cu 1: (4 im)
Sc kh A vo dung dch cha cht B ta c cht rn C c mu vng v dung dch D. Kh
X c mu vng lc, tc dng vi kh A to ra cht C v F. Nu X tc dng vi kh A trong nc
th to ra cht Y v F. Thm tip dung dch BaCl 2 vo th c kt ta trng xut hin. A tc dng
vi dung dch cht G l mui nitrat kim loi to ra kt ta H mu en. t chy H bi oxi th
thu c cht lng I mu trng bc.
Xc nh A, B, C, F, G, H, I, X, Y v vit phng trnh ha hc ca cc phn ng.
Cu 2: (4 im)
Cho m gam hn hp X gm hai ancol no, n chc bc 1, k tip nhau trong dy ng
ng tc dng vi CuO d, nung nng th thu c hn hp rn Z v hn hp hi Y (c t khi
hi so vi H2 l 13,75). Cho ton b Y phn ng vi lng d AgNO 3/NH3 un nng, sinh ra
64,8 gam Ag. Xc nh cng thc ca ancol v gi tr ca m.
Cu 3: (4 im)
- Cho a gam bt Al tc dng va vi dung dch HNO 3 long th thu c dung dch A
v 0,1792 lt (ktc) hn hp kh NO v N2 c t khi so vi H2 l 14,25. Tnh a.
- Cho 6,4 gam hn hp Ba, Na vo b gam nc th thu c 1,344 lt (ktc) H 2 v dung
dch B. Tm b sao cho khi phn ng xong th nng ca Ba(OH) 2 trong dung dch B l 3,42%.
Tnh nng % ca NaOH trong dung dch B.
- Cho 1/2 dung dch B tc dng vi dung dch A th thu c bao nhiu gam kt ta? Cho
tip 1/2 dung dch B cn li vo th thu c bao nhiu gam kt ta?
Cu 4: (3,5 im)
Cho bit trong cc s sau y c im no sai? Nu c sai, hy sa li v vit cc
phng trnh ho hc.
-iu ch axit p hidroxi Benzoic t toluen:
CH3

COOH

COOH

COONa

COOH

Cl

OH

OH

- iu ch 2-clo-4-nitrotoluen:
CH3

CH3

Cl

CH3

Cl

NO2

Cu 5: (4,5 im)
Cc cht DDT; 666 v 2,4-D l mt s nng dc trc y c s dng.
- Vit cng thc cu to ca chng, trnh by ng dng cho mi cht v nu tc dng ph
c hi ca cht trn khin vic s dng chng nh l nng dc b hn ch v ngn cm.
- T nguyn liu ban u l CH4 v cc cht v c (iu kin c ), vit s iu ch
666 v DDT.
Cho: H = 1; N = 14; O = 16; Na = 23; Al = 27; Ag = 108; Ba = 137
Ch : Cn b coi thi khng gii thch g thm