Kinetika 1.

4NO2(g) +O2(g) -> 2N2O5(g) Suppose that a particular moment during the reaction, molecular oxygen is reacting at the rate of 0,024 M/s a. At what rate is N2O5 being formed? B.at what rate is NO2 reacting? a. = = -2(-0,024 M/s) = 0,048 M/s b. = = 4(-0,024 M/s) -0,096M/s 2. 2NO(g) + 2H2(g) -> N2(g) +2H2O(g) From the following data collected at this temperature, deterimne (a) the rate law, (b) the rate constant, and (c) the rate of the reaction when [NO]=12. and [H2] =6. Experiment 1 2 3 a. 4= X=2 = 2= y=1 rate = k b. K= =
( )

[NO] (M) 5. 10. 10. =

( )

[H2] (M) 2. 2. 4.

Initial rate(M/s) 1,3. 5. 10.

= = s

c. V = k = = M/s 3. The decomposition of ethane(C2H6) to methyl radicals is a first order reaction with a rate constant 5,36.10^-4/s at 700 C. Calculate the half life of the reaction in minutes T1/2 = = = s = 21,5 menit 4. Iodine atoms combine to form molecular iodine in the gas phase I(g) + I(g) -> I2(g) this reaction follow second order kinetics and has the high rate constant 7.10^9/ms at 23 C. A. If the initial concentration of I was 0,86M, calculate the concentration after 2 min.

. .

=kt+. =7.10^-9.120 + .

[I]t = 1,2.10^-12M 5. The rate constant of a firs order reaction is 3,46.10^-2/s at 298K. What is the rate constant ad 350K if the activation energy for the reaction is 50,2KJ/mol? ln = (- + ) ln 2,46.10^-2/k2 = -3.01 k2=0,702/s Radiasi 1. A long cherished dream of alchemist was to produce gold from cheaper and more abundant elements. This dream was finally realized whe was converted into gold by neutron bombardment. Writea balanced equation for this reaction: + -> + 2. The atomic mass of 12753I is 126.9004 amu. Calculate the nuclear binding energy of this nucleus and the corresponding nuclear binding energy per nucleon. Massa =126,9004-(53x1,007825+74x1,008665) =126,9004amu 128,05594amu = - 1,1555 amu

3. Balance the following nuclear equations a. -> +x b. -> +x Jawab a. b. -> + 4. Write the balanced equations for the nuclear reaction the deuterium nucleus Jawab + -> +

where d represent

5. Write balanced nuclear equations for the following reactions and identify X a. b. Jawab: a. + -> + b. ->2 +