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4.

HIGH-PRESSURE PHASE EQUILIBRIUM (HPPE) DATA


OF COPOLYMER SOLUTIONS
IN SUPERCRITICAL FLUIDS
4.1. Experimental data of quasibinary copolymer solutions

_____________________________________________________________________________
Copolymers from butylene oxide and ethylene oxide
_____________________________________________________________________________
Average chemical composition of the copolymers, acronyms and references:

_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
poly(butylene oxide)-b-poly(ethylene oxide)
diblock copolymer
44.4 mol% ethylene oxide

BO-EO/44x

98ONE

_____________________________________________________________________________
Characterization:

_____________________________________________________________________________
Further information
Mn/
g/mol
_____________________________________________________________________________
Copolymer (B)

BO-EO/44x

1620 ( = 960 + 660)

SAM 185, hydroxyl terminated

_____________________________________________________________________________
Experimental HPPE data:

_____________________________________________________________________________
copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/MPa

BO-EO/44x
carbon dioxide

cloud-points

0.001
308.15
27.58

2001 by CRC Press LLC

CO2

98ONE
124-38-9

_____________________________________________________________________________
Copolymers from ethylene and acrylic acid
_____________________________________________________________________________
Average chemical composition of the copolymers, acronyms and references:

_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Ethylene/acrylic acid copolymer
3.0 wt% acrylic acid
6.0 wt% acrylic acid
7.3 wt% acrylic acid

E-AA/03w
E-AA/06w
E-AA/07w

92WIN
92WIN
92WIN

_____________________________________________________________________________
Characterization:

_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol
g/mol
_____________________________________________________________________________
Copolymer (B)

E-AA/03w
E-AA/06w
E-AA/07w

37500
30000
25000

183000
150000
126000

synthesized in the laboratory


synthesized in the laboratory
synthesized in the laboratory

_____________________________________________________________________________

Experimental HPPE data:

_____________________________________________________________________________

copolymer (B):
solvent (A):
Type of data:

E-AA/03w
ethene

92WIN
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.019
413.15
196.8

0.019
433.15
178.4

0.019
453.15
163.1

0.019
473.15
152.2

0.019
493.15
141.7

0.082
413.15
186.7

0.082
433.15
166.6

0.082
453.15
153.1

0.082
473.15
143.3

wB
T/K
P/MPa

0.082
493.15
135.4

0.128
413.15
181.2

0.128
433.15
162.8

0.128
453.15
150.1

0.128
473.15
140.3

0.128
493.15
132.2

0.186
413.15
172.1

0.186
433.15
154.3

0.186
453.15
142.5
continue

2001 by CRC Press LLC

continue
wB
T/K
P/MPa

0.186
473.15
134.0

0.186
493.15
128.5

0.231
413.15
165.6

0.231
433.15
148.9

0.231
453.15
137.7

0.231
473.15
129.8

0.231
493.15
124.2

0.295
413.15
153.1

0.295
433.15
139.8

wB
T/K
P/MPa

0.295
453.15
130.2

0.295
473.15
123.1

0.295
493.15
118.0

0.318
413.15
150.4

0.318
433.15
136.6

0.318
453.15
127.9

0.318
473.15
121.3

0.318
493.15
115.8

0.338
413.15
146.0

wB
T/K
P/MPa

0.338
433.15
134.1

0.338
453.15
125.3

0.338
473.15
118.9

0.338
493.15
113.4

0.428
413.15
127.5

0.428
433.15
119.4

0.428
453.15
113.4

0.428
473.15
108.7

0.428
493.15
105.1

wB
T/K
P/MPa

0.510
413.15
109.8

0.510
433.15
105.5

0.510
453.15
102.0

0.510
473.15
99.0

0.510
493.15
96.0

copolymer (B):
solvent (A):
Type of data:

E-AA/03w
ethene

92WIN
74-85-1

C2H4

coexistence data

T/K = 403.15
Total feed concentration of the copolymer in the homogeneous system: wB = 0.155

_____________________________________________________________________________
Fractionation during demixing
Demixing
wA
pressure bottom phase top phase
bottom phase
top phase
_____________________________________________________________________________
M w/
M z/
Mn/
M w/
M z/
P/
Mn/
MPa
g/mol g/mol g/mol
g/mol
g/mol
g/mol
_____________________________________________________________________________
116.0
161.0
178.5
188.0

0.508
0.982
0.711
0.951
0.789
0.918
0.845 (cloud-point)

42880
37500

176300
183000

2818
8803
9188
31060
510700
13170
52620
601000 (feed sample)

18920
73720
156100

_____________________________________________________________________________
copolymer (B):
solvent (A):
Type of data:

E-AA/03w
ethene

C2H4

92WIN
74-85-1

coexistence data

T/K = 433.15
continue

2001 by CRC Press LLC

continue
The total feed concentration of the copolymer in the homogeneous system is: wB = 0.164

_____________________________________________________________________________
wA

Demixing

Fractionation during demixing

pressure bottom phase top phase


bottom phase
top phase
_____________________________________________________________________________
M w/
M z/
Mn/
M w/
M z/
P/
Mn/
MPa
g/mol g/mol g/mol
g/mol
g/mol
g/mol
_____________________________________________________________________________
94.0
113.0
129.0
147.7
157.5

0.438
0.993
0.536
0.982
0.633
0.966
0.766
0.939
0.836 (cloud-point)

41500
37500

173700
183000

1520
6745
2500
8300
8200
29070
472800
11600
47030
601000 (feed sample)

13920
17620
69600
146200

_____________________________________________________________________________

copolymer (B):
solvent (A):
Type of data:

E-AA/06w
ethene

92WIN
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.038
433.15
203.4

0.038
453.15
176.8

0.038
473.15
157.3

0.038
493.15
142.0

0.057
433.15
195.7

0.057
453.15
170.5

0.057
473.15
152.3

0.057
493.15
138.9

0.076
433.15
191.2

wB
T/K
P/MPa

0.076
453.15
167.2

0.076
473.15
148.9

0.076
493.15
134.0

0.116
433.15
189.5

0.116
453.15
164.2

0.116
473.15
146.2

0.116
493.15
132.5

0.150
433.15
183.9

0.150
453.15
161.1

wB
T/K
P/MPa

0.150
473.15
145.2

0.150
493.15
130.5

0.215
433.15
172.4

0.215
453.15
152.2

0.215
473.15
135.4

0.215
493.15
125.4

0.260
433.15
165.3

0.260
453.15
146.3

0.260
473.15
132.6

wB
T/K
P/MPa

0.260
493.15
121.8

0.295
433.15
158.3

0.295
453.15
142.0

0.295
473.15
129.8

0.295
493.15
119.0

0.335
433.15
147.5

0.335
453.15
135.9

0.335
473.15
125.6

0.335
493.15
115.5

wB
T/K
P/MPa

0.383
433.15
137.5

0.383
453.15
126.9

0.383
473.15
118.5

0.383
493.15
112.2

0.430
433.15
130.1

0.430
453.15
120.2

0.430
473.15
112.0

0.430
493.15
106.3

0.505
433.15
114.4

wB
T/K
P/MPa

0.505
453.15
108.0

0.505
473.15
103.1

0.505
493.15
99.2

2001 by CRC Press LLC

copolymer (B):
solvent (A):
Type of data:

E-AA/06w
ethene

92WIN
74-85-1

C2H4

coexistence data

T/K = 433.15
The total feed concentration of the copolymer in the homogeneous system is: wB = 0.1565

_____________________________________________________________________________
P/
wA
MPa
bottom phase top phase
_____________________________________________________________________________
124.9
138.1
158.6
172.0
182.0

0.5550
0.9870
0.6130
0.9735
0.7130
0.9540
0.7855
0.9300
0.8435 (cloud-point)

_____________________________________________________________________________

copolymer (B):
solvent (A):
Type of data:

E-AA/07w
ethene

92WIN
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.043
453.15
192.4

0.043
473.15
165.6

0.043
493.15
143.9

0.102
443.15
196.2

0.102
453.15
181.4

0.102
473.15
157.7

0.102
493.15
140.2

0.160
443.15
186.0

0.160
453.15
171.4

wB
T/K
P/MPa

0.160
473.15
150.8

0.160
493.15
135.3

0.203
443.15
178.2

0.203
453.15
165.3

0.203
473.15
146.3

0.203
493.15
132.5

0.272
443.15
166.0

0.272
453.15
156.4

0.272
473.15
140.6

wB
T/K
P/MPa

0.272
493.15
126.8

0.330
443.15
155.5

0.330
453.15
147.0

0.330
473.15
134.0

0.330
493.15
122.5

0.410
443.15
141.0

0.410
453.15
134.3

0.410
473.15
123.6

0.410
493.15
114.9

wB
T/K
P/MPa

0.500
443.15
121.4

0.500
453.15
117.0

0.500
473.15
110.8

0.500
493.15
104.8

2001 by CRC Press LLC

_____________________________________________________________________________
Copolymers from ethylene and butyl acrylate
_____________________________________________________________________________
Average chemical composition of the copolymers, acronyms and references:

_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Ethylene/butyl acrylate copolymer
15.0 wt% butyl acrylate
19.0 wt% butyl acrylate
35.0 wt% butyl acrylate
67.0 wt% butyl acrylate
75.0 wt% butyl acrylate

E-BA/15w
E-BA/19w
E-BA/35w
E-BA/67w
E-BA/75w

96MUE
96MUE
96MUE
96MUE
96MUE

_____________________________________________________________________________
Characterization:

_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol
g/mol
_____________________________________________________________________________

Copolymer (B)

E-BA/15w
E-BA/19w
E-BA/35w
E-BA/67w
E-BA/75w

6980
7740
7960
11500
13900

34900
38700
39800
37000
35200

sample from BASF AG, Ger.


sample from BASF AG, Ger.
sample from BASF AG, Ger.
synthesized in the laboratory
synthesized in the laboratory

_____________________________________________________________________________

Experimental HPPE data:

_____________________________________________________________________________
copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/MPa

E-BA/15w
ethene

96MUE
74-85-1

C2H4

cloud-points

0.025
522.85
117.7

0.025
498.05
121.5

0.025
473.05
126.3

0.025
448.55
132.3

0.025
423.85
139.6

0.050
524.05
116.9

0.050
498.35
120.8

0.050
473.85
125.5

0.050
449.15
131.3
continue

2001 by CRC Press LLC

continue
wB
T/K
P/MPa

0.050
423.75
138.8

0.100
522.85
121.2

0.100
498.05
124.1

0.100
473.15
127.5

0.100
448.95
132.1

0.100
424.15
139.4

0.150
524.15
120.8

wB
T/K
P/MPa

0.150
448.95
128.5

0.150
424.35
133.6

0.200
523.35
117.3

0.200
498.05
118.8

0.200
473.35
121.5

0.200
449.15
124.8

0.200
423.35
128.7

copolymer (B):
solvent (A):
Type of data:

E-BA/19w
ethene

0.150
498.25
122.5

0.150
473.55
125.1

96MUE
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.034
523.05
116.8

0.034
498.55
120.6

0.034
472.65
125.4

0.034
448.15
131.6

0.034
423.15
138.4

0.050
523.95
118.4

0.050
497.85
121.3

0.050
473.05
125.3

0.050
449.25
130.8

wB
T/K
P/MPa

0.050
423.95
139.0

0.100
523.55
121.7

0.100
498.85
123.6

0.100
473.45
128.2

0.100
449.05
131.6

0.100
424.25
139.4

0.150
524.85
120.3

0.150
498.15
122.1

0.150
472.65
128.4

wB
T/K
P/MPa

0.150
448.95
130.6

0.150
424.25
134.7

0.199
523.25
120.7

0.199
498.55
123.0

0.199
473.35
126.1

0.199
448.95
129.8

copolymer (B):
solvent (A):
Type of data:

E-BA/35w
ethene

96MUE
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.025
523.65
111.5

0.025
498.55
115.9

0.025
473.05
120.4

0.025
448.55
127.2

0.025
423.45
134.4

0.050
523.75
109.4

0.050
498.05
113.1

0.050
472.95
117.2

0.050
448.05
122.3

wB
T/K
P/MPa

0.050
423.25
129.7

0.100
523.45
107.1

0.100
498.05
109.8

0.100
473.15
113.1

0.100
448.45
116.9

0.100
423.45
121.9

0.150
523.85
105.9

0.150
498.35
108.1

0.150
472.95
111.5

wB
T/K
P/MPa

0.150
448.05
115.1

0.150
423.85
119.8

0.199
523.75
104.9

0.199
498.05
106.7

0.199
473.25
109.5

0.199
449.15
115.4

0.199
424.05
120.5

copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/MPa

E-BA/67w
ethene

C2H4

cloud-points

0.168
522.35
96.6

2001 by CRC Press LLC

0.168
498.15
98.4

0.168
473.65
100.1

0.168
448.35
102.3

0.168
424.65
104.0

96MUE
74-85-1

copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/MPa

E-BA/75w
ethene

96MUE
74-85-1

C2H4

cloud-points

0.069
524.05
89.4

0.069
499.05
90.3

0.069
474.45
92.9

0.069
448.65
96.5

0.069
423.75
99.8

0.069
398.75
102.1

_____________________________________________________________________________
Copolymers from ethylene and 1-hexene
_____________________________________________________________________________

Average chemical composition of the copolymers, acronyms and references:

_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Ethylene/1-hexene copolymer
10.6 wt% 1-hexene
16.1 wt% 1-hexene
20.6 wt% 1-hexene
35.0 wt% 1-hexene
35.0 wt% 1-hexene

E-H/11w
E-H/16w
E-H/21w
E-H/35w(1)
E-H/35w(2)

2000CH3
99KIN
2000CH2
2000CH3
2000CH3

_____________________________________________________________________________

Characterization:

_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol
g/mol
g/mol
_____________________________________________________________________________
Copolymer (B)

E-H/11w
E-H/16w
E-H/21w
E-H/35w(1)
E-H/35w(2)

52600
60000
51300
48100
112100

80000
129000
126000
103000
139000

_____________________________________________________________________________

2001 by CRC Press LLC

Experimental HPPE data:

_____________________________________________________________________________
copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/MPa

E-H/11w
ethene

0.148
413.15
154.5

copolymer (B):
solvent (A):

wB
T/K
P/MPa

0.148
433.25
146.0

C2H4

99KIN
74-85-1

0.148
453.15
138.9

E-H/16w
ethene

cloud-points

0.150
393.15
156.0

0.150
413.15
144.3

copolymer (B):
solvent (A):
Type of data:

2000CH3
74-85-1

cloud-points

0.148
393.25
168.0

Type of data:

C2H4

0.150
433.15
137.3

0.150
453.15
129.1

E-H/35w(1)
ethene

0.150
473.15
123.1

0.150
493.15
118.6

2000CH3
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.050
393.15
136.3

0.050
403.15
132.6

0.050
413.15
129.6

0.050
423.15
127.0

0.050
433.15
124.9

0.050
443.15
122.9

0.050
453.15
121.0

0.100
393.15
134.8

0.100
403.15
131.4

wB
T/K
P/MPa

0.100
413.15
128.3

0.100
423.15
125.8

0.100
433.15
123.7

0.100
443.15
121.8

0.100
453.15
120.8

0.150
393.15
129.4

0.150
403.15
126.1

0.150
413.15
123.6

0.150
423.15
121.5

wB
T/K
P/MPa

0.150
433.15
119.8

0.150
443.15
118.7

0.150
453.15
119.4

copolymer (B):
solvent (A):
Type of data:

E-H/11w
propane

2000CH3
74-98-6

C3H8

cloud-points

wB
T/K
P/MPa

0.010
363.15
50.3

0.010
373.25
50.0

wB
T/K
P/MPa

0.148
413.15
50.4

0.148
453.15
51.1

2001 by CRC Press LLC

0.010
413.15
49.9

0.010
453.15
50.7

0.051
363.15
51.0

0.051
373.15
50.4

0.051
413.15
50.4

0.051
453.15
50.4

0.148
373.25
50.6

copolymer (B):
solvent (A):
Type of data:

E-H/21w
propane

2000CH2
74-98-6

C3H8

cloud-points

T/K = 453.15
wB
P/bar

0.018
446.0

0.031
454.0

0.055
456.0

wB
P/bar

0.108
471.0

0.114
466.0

0.148
459.0

copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/MPa

E-H/35w(1)
propane

0.150
343.15
38.1

copolymer (B):
solvent (A):

wB
T/K
P/MPa

0.009
313.25
39.0

wB
T/K
P/MPa

0.152
453.15
43.7

0.075
468.0

0.079
475.0

0.089
478.0

0.098
470.0

0.100
474.0

2000CH3
74-98-6

C3H8

cloud-points

0.150
313.15
37.3

Type of data:

0.066
459.0

0.150
363.05
39.1

0.150
373.05
39.7

E-H/35w(2)
propane

0.150
413.15
42.3

0.150
453.15
44.6

2000CH3
74-98-6

C3H8

cloud-points
0.009
353.25
36.8

0.009
368.25
37.6

0.009
373.15
37.9

0.009
413.15
40.6

0.009
453.15
42.9

0.152
353.25
37.8

0.152
373.15
39.2

0.152
413.15
41.5

_____________________________________________________________________________
Copolymers from ethylene and methyl acrylate
_____________________________________________________________________________
Average chemical composition of the copolymers, acronyms and references:

_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Ethylene/methyl acrylate copolymer
25.0 wt% methyl acrylate
58.0 wt% methyl acrylate
68.0 wt% methyl acrylate

E-MA/25w
E-MA/58w
E-MA/68w

96MUE
96MUE
96MUE

_____________________________________________________________________________

2001 by CRC Press LLC

Characterization:

_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol
g/mol
g/mol
_____________________________________________________________________________
Copolymer (B)

E-MA/25w
E-MA/58w
E-MA/68w

17000
33000
42000

75400
108900
110000

synthesized in the laboratory


synthesized in the laboratory
synthesized in the laboratory

_____________________________________________________________________________
Experimental HPPE data:

_____________________________________________________________________________
copolymer (B):
solvent (A):
Type of data:

E-MA/25w
ethene

96MUE
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.010
522.65
113.7

0.010
498.15
119.8

0.010
473.85
123.6

0.010
448.55
128.8

0.010
424.05
133.0

0.050
523.95
115.9

0.050
498.85
119.4

0.050
472.75
123.2

0.050
449.15
127.5

wB
T/K
P/MPa

0.050
423.95
134.2

0.050
404.15
140.0

0.100
525.05
117.3

0.100
498.35
117.4

0.100
474.35
120.2

0.100
448.65
124.6

0.100
424.95
129.2

0.113
523.15
117.2

0.113
498.35
119.0

wB
T/K
P/MPa

0.113
473.55
122.7

0.113
448.85
125.5

0.113
423.45
131.2

0.149
522.85
116.7

0.149
498.55
118.8

0.149
473.25
121.2

0.149
448.45
125.0

0.149
423.05
130.2

0.207
523.95
109.4

wB
T/K
P/MPa

0.207
497.85
112.2

0.207
473.05
115.5

0.207
448.85
119.5

0.207
424.15
124.1

copolymer (B):
solvent (A):
Type of data:

E-MA/58w
ethene

96MUE
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.010
523.75
125.8

0.010
498.35
133.7

0.010
473.75
140.6

0.010
448.05
149.7

0.010
423.55
161.3

0.050
522.95
124.9

0.050
498.65
130.8

0.050
473.95
138.2

0.050
449.05
148.5

wB
T/K
P/MPa

0.050
423.95
163.1

0.050
404.05
178.8

0.101
524.65
123.0

0.101
499.15
128.4

0.101
473.25
135.6

0.101
448.45
145.0

0.101
424.05
162.0

0.150
524.05
122.7

0.150
498.95
127.8

wB
T/K
P/MPa

0.150
473.45
132.3

0.150
448.95
140.6

0.150
423.55
150.6

0.200
523.75
117.3

0.200
498.45
122.1

0.200
473.85
128.2

0.200
448.45
136.2

2001 by CRC Press LLC

copolymer (B):
solvent (A):
Type of data:

E-MA/68w
ethene

96MUE
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.011
523.85
136.5

0.011
498.95
145.5

0.011
473.55
157.8

0.011
448.45
165.2

0.011
423.75
206.4

0.050
523.25
136.1

0.050
498.35
145.2

0.050
473.15
157.7

0.050
448.85
174.4

wB
T/K
P/MPa

0.050
423.85
201.3

0.050
403.65
234.3

0.101
523.65
133.6

0.101
498.25
142.0

0.101
473.25
153.0

0.101
448.25
167.4

0.101
423.15
189.3

0.150
523.35
133.9

0.150
498.15
141.0

wB
T/K
P/MPa

0.150
473.05
151.8

0.150
448.95
164.9

0.150
424.35
184.1

0.192
523.45
132.0

0.192
497.95
139.9

0.192
472.65
150.0

0.192
448.85
163.2

0.192
423.45
181.9

_____________________________________________________________________________
Copolymers from ethylene and 1-octene
_____________________________________________________________________________
Average chemical composition of the copolymers, acronyms and references:

_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Ethylene/1-octene copolymer
13.9 wt% 1-octene
25.8 wt% 1-octene
38.7 wt% 1-octene

E-O/14w
E-O/26w
E-O/39w

2000CH1
2000CH1
2000CH1

_____________________________________________________________________________
Characterization:

_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol
g/mol
g/mol
_____________________________________________________________________________
Copolymer (B)

E-O/14w
E-O/26w
E-O/39w

51200
54800
83300

83000
115000
120000

4 hexyl branches/100 ethyl units


8 hexyl branches/100 ethyl units
13.6 hexyl branches/100 ethyl units

_____________________________________________________________________________

2001 by CRC Press LLC

Experimental HPPE data:

_____________________________________________________________________________

copolymer (B):
solvent (A):
Type of data:

wB
T/K
P/MPa

E-O/14w
propane

cloud-points

0.050
453.15
53.4

0.050
413.15
52.8

copolymer (B):
solvent (A):
Type of data:

wB
T/K
P/MPa

0.050
393.15
52.8

0.050
373.15
53.2

E-O/26w
propane

0.050
368.15
53.5

0.050
363.15
53.7

C3H8

2000CH1
74-98-6

C3H8

2000CH1
74-98-6

cloud-points

0.049
453.15
48.5

0.049
413.15
47.1

copolymer (B):
solvent (A):
Type of data:

2000CH1
74-98-6

C3H8

0.049
373.15
46.3

E-O/39w
propane

cloud-points

wB
T/K
P/MPa

0.010
453.15
38.6

0.010
413.15
36.0

0.010
373.15
33.2

0.010
343.15
34.8

wB
T/K
P/MPa

0.049
333.15
33.6

0.100
453.15
40.4

0.100
413.15
37.9

0.100
373.15
35.5

2001 by CRC Press LLC

0.010
333.15
37.8

0.049
453.15
40.8

0.049
413.15
38.4

0.049
373.15
35.6

0.049
343.15
33.7

_____________________________________________________________________________
Copolymers from ethylene and propylene
_____________________________________________________________________________
Average chemical composition of the copolymers, acronyms and references:

_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Ethylene/propylene copolymer
50.0 mol% propene
50.0 mol% propene
50.0 mol% propene
50.0 mol% propene
50.0 mol% propene
50.0 mol% propene
50.0 mol% propene
50.0 mol% propene
50.0 mol% propene
50.0 mol% propene
50.0 mol% propene
50.0 mol% propene

E-P/50x(1)
E-P/50x(1)
E-P/50x(1)
E-P/50x(2)
E-P/50x(2)
E-P/50x(2)
E-P/50x(2)
E-P/50x(3)
E-P/50x(3)
E-P/50x(4)
E-P/50x(4)
E-P/50x(4)

92CH1
93GRE
94GR1
92CH1
93GRE
94GR1
94GR2
92CH1
92CH2
92CH1
93GRE
94GR1

Ethylene/propylene/isoprene terpolymer
28.2 mol% propene, 43.6 mol% isoprene
36.7 mol% propene, 26.6 mol% isoprene

E-P-IP/28x
E-P-IP/37x

96ALB
96ALB

_____________________________________________________________________________
Characterization:

_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol
g/mol
_____________________________________________________________________________

Copolymer (B)

E-P/50x(1)

782

790

E-P/50x(2)

5460

5900

E-P/50x(3)

25200

26000

E-P/50x(4)

87700

96400

E-P-IP/28x

7650

13620

E-P-IP/37x

7690

13690

alternating ethylene/propylene units from


complete hydrogenation of polyisoprene
alternating ethylene/propylene units from
complete hydrogenation of polyisoprene
alternating ethylene/propylene units from
complete hydrogenation of polyisoprene
alternating ethylene/propylene units from
complete hydrogenation of polyisoprene
alternating ethylene/propylene units from
partial hydrogenation of polyisoprene
alternating ethylene/propylene units from
partial hydrogenation of polyisoprene

_____________________________________________________________________________

2001 by CRC Press LLC

Experimental HPPE data:

_____________________________________________________________________________

copolymer (B):
solvent (A):
Type of data:

E-P/50x(1)
1-butene

92CH1
106-98-9

C4H8

cloud-points

wB = 0.151
T/K
P/bar

355.05
11.5

T/K
P/bar

473.15
90.8

373.15
16.4

copolymer (B):
solvent (A):
Type of data:

398.15
27.1

421.65
39.8

E-P/50x(2)
1-butene

424.05
42.5

426.35
44.8

428.15
46.5

432.95
51.7

444.45
63.4

92CH1
106-98-9

C4H8

cloud-points

wB = 0.157
T/K
P/bar

376.15
21.3

378.85
27.2

382.65
35.5

397.95
66.7

423.15
110.0

447.95
146.0

473.15
172.5

Comments: a lower critical endpoint is found at 373.15 K

copolymer (B):
solvent (A):
Type of data:

E-P/50x(3)
1-butene

92CH1
106-98-9

C4H8

cloud-points

wB = 0.160
T/K
P/bar

346.35
12.3

348.35
15.2

350.35
20.5

355.15
29.0

T/K
P/bar

416.35
137.3

423.15
149.0

448.35
183.0

473.35
213.4

361.35
40.2

Comments: a lower critical endpoint is found at 345.15 K

2001 by CRC Press LLC

361.85
38.2

367.45
50.3

373.15
61.2

398.15
108.0

copolymer (B):
solvent (A):
Type of data:

E-P/50x(4)
1-butene

92CH1
106-98-9

C4H8

cloud-points

wB = 0.152
T/K
P/bar

334.45
8.4

T/K
P/bar

473.15
240.5

336.05
13.1

339.55
19.5

343.75
28.4

355.15
54.0

373.15
90.8

398.15
137.3

423.75
177.3

448.15
210.1

Comments: a lower critical endpoint is found at 333.15 K

copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/bar

E-P/50x(1)
ethene

cloud-points

0.156
293.15
571.5

0.156
323.15
555.0

copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/bar

0.156
323.15
1018.6

0.152
475.15
689.6

93GRE, 94GR1
74-85-1

C2H4

0.156
325.65
1001.1

0.158
348.15
941.9

E-P/50x(4)
ethene

0.158
373.15
897.9

C2H4

0.157
398.15
899.9

0.158
448.15
899.1

0.158
468.15
892.8

0.158
473.15
900.0

93GRE, 94GR1
74-85-1

cloud-points

0.038
353.15
1722.5

0.038
373.15
1569.0

copolymer (B):
solvent (A):
Type of data:

0.152
423.15
600.9

E-P/50x(2)
ethene

copolymer (B):
solvent (A):

wB
T/K
P/bar

0.156
363.15
550.0

cloud-points

0.156
308.15
1080.1

Type of data:

93GRE, 94GR1
74-85-1

C2H4

0.038
398.15
1389.0

E-P/50x(3)
1-hexene

0.038
423.15
1235.5

0.038
473.15
1132.7

C6H12

92CH1, 92CH2
592-41-6

cloud-points
continue

2001 by CRC Press LLC

continue
wB = 0.160
T/K
P/bar

427.15
7.2
(VLE

447.95
12.7
VLE

467.85
17.2
VLE

473.15
23.5
LLE

477.95
29.4
LLE

478.65
31.6
LLE

473.15
19.3
VLLE

477.95
20.0
VLLE

478.55
20.4
VLLE)

Comments: a lower critical endpoint is found at 472.15 K

copolymer (B):
solvent (A):
Type of data:

E-P/50x(4)
1-hexene

92CH1
592-41-6

C6H12

cloud-points

wB = 0.150
T/K
P/bar

416.95
8.3
(VLE

453.15
14.0
VLE

459.35
18.3
LLE

454.95
28.5
LLE

474.45
43.3
LLE

463.95
17.3
VLLE)

Comments: a lower critical endpoint is found at 457.15 K

copolymer (B):
solvent (A):
Type of data:

E-P/50x(1)
propene

92CH1
115-07-1

C3H6

cloud-points

wB = 0.172
T/K
P/bar

319.45
19.0
(VLE

343.35
30.2
VLE

350.55
34.4
VLE

352.15
37.7
LLE

T/K
P/bar

473.35
180.0
(LLE

352.15
35.9
VLLE

353.75
36.9
VLLE

355.05
38.3
VLLE)

355.05
43.0
LLE

373.35
73.0
LLE

397.95
113.0
LLE

423.15
144.0
LLE

447.95
170.0
LLE)

Comments: a lower critical endpoint is found at 351.1 K

copolymer (B):
solvent (A):
Type of data:

E-P/50x(2)
propene

92CH1
115-07-1

C3H6

cloud-points

wB = 0.155
T/K
P/bar

272.65
5.5

298.15
64.0

325.15
126.0

356.15
190.5

373.15
224.4

Comments: a lower critical endpoint is found at 272.6 K

2001 by CRC Press LLC

398.95
267.0

423.35
296.0

447.95
325.0

472.75
344.0

copolymer (B):
solvent (A):
Type of data:

E-P/50x(2)
propene

cloud-points

wB
T/K
P/bar

0.018
373.15
179.5

0.073
373.75
202.8

wB
T/K
P/bar

0.216
423.15
293.0

0.329
423.15
267.1

copolymer (B):
solvent (A):
Type of data:

93GRE, 94GR1, 94GR2


115-07-1

C3H6

0.150
373.15
212.5

0.216
373.35
209.8

E-P/50x(3)
propene

0.281
373.45
200.2

0.392
373.15
189.1

0.018
423.15
248.6

0.073
423.15
273.7

0.150
423.15
295.0

92CH1
115-07-1

C3H6

cloud-points

wB = 0.151
T/K
P/bar

323.55
273.0

355.55
312.0

copolymer (B):
solvent (A):
Type of data:

373.55
332.0

398.05
361.2

E-P/50x(4)
propene

423.55
388.0

448.15
412.0

92CH1
115-07-1

C3H6

cloud-points

wB = 0.158
T/K
P/bar

264.15
354.0

265.85
347.0

271.15
337.0

274.15
331.0

277.95
325.5

280.35
322.5

285.25
316.7

287.05
315.0

293.55
311.0

T/K
P/bar

303.05
310.6

317.15
319.5

322.55
322.3

331.15
330.0

354.65
352.0

373.05
371.0

397.75
396.4

423.35
423.0

447.95
442.3

T/K
P/bar

473.55
461.0

copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/bar

0.008
373.15
393.1

wB
T/K
P/bar

0.231
423.15
393.0

E-P/50x(4)
propene

93GRE, 94GR1, 94GR2


115-07-1

C3H6

cloud-points

2001 by CRC Press LLC

0.045
373.15
363.0

0.088
373.15
371.3

0.158
373.15
371.2

0.231
373.15
343.0

0.008
423.15
402.1

0.045
423.15
413.8

0.088
423.15
423.0

0.158
423.15
423.1

copolymer (B):
solvent (A):
Type of data:

E-P-IP/28x
dimethyl ether

96ALB
115-10-6

C2H6O

cloud-points

wB = 0.0536
T/K
P/bar

424.75
216.6

383.25
133.0

347.55
46.2

329.95
12.2

Comments: a lower critical endpoint is found at 329.95 K

copolymer (B):
solvent (A):
Type of data:

E-P-IP/37x
dimethyl ether

96ALB
115-10-6

C2H6O

cloud-points

wB = 0.0524
T/K
P/bar

423.45
208.9

411.95
186.1

410.65
184.4

384.35
132.9

362.35
85.5

348.65
53.5

328.15
11.9

Comments: a lower critical endpoint is found at 328.15 K

copolymer (B):
solvent (A):
Type of data:

E-P-IP/37x
ethane

96ALB
74-84-0

C2H6

cloud-points

wB = 0.0722
T/K
P/bar

423.65
818.1

414.15
824.2

copolymer (B):
solvent (A):
Type of data:

393.75
869.4

392.85
874.3

E-P-IP/37x
ethene

383.05
918.7

C2H4

cloud-points

wB = 0.0843
T/K
P/bar

423.75
1249.1

2001 by CRC Press LLC

423.15
1250.5

421.65
1256.2

409.15
1293.2

394.35
1352.9

382.25
923.0

373.75
964.9

364.85
1005.4

362.25
1038.7

96ALB
74-85-1

copolymer (B):
solvent (A):
Type of data:

E-P-IP/37x
propane

96ALB
74-98-6

C3H8

cloud-points

wB = 0.0528
T/K
P/bar

422.75
377.8

T/K
P/bar

327.25
472.3

422.05
378.3

copolymer (B):
solvent (A):
Type of data:

390.05
370.2

389.85
370.2

E-P-IP/37x
propene

388.75
366.6

388.45
369.5

363.95
398.0

347.75
423.0

333.65
453.0

96ALB
115-07-1

C3H6

cloud-points

wB = 0.0478
T/K
P/bar

424.25
357.5

390.45
320.7

363.65
301.1

339.05
304.5

335.85
305.0

310.95
337.5

_____________________________________________________________________________
Copolymers from ethylene and vinyl acetate
_____________________________________________________________________________
Average chemical composition of the copolymers, acronyms and references:

_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Ethylene/vinyl acetate copolymer
7.5 wt% vinyl acetate
7.5 wt% vinyl acetate
10.9 wt% vinyl acetate
12.7 wt% vinyl acetate
12.7 wt% vinyl acetate
17.5 wt% vinyl acetate
26.0 wt% vinyl acetate
27.3 wt% vinyl acetate
27.3 wt% vinyl acetate
27.5 wt% vinyl acetate
27.5 wt% vinyl acetate
29.0 wt% vinyl acetate

E-VA/08w
E-VA/08w
E-VA/11w
E-VA/13w
E-VA/13w
E-VA/18w
E-VA/26w
E-VA/27w
E-VA/27w
E-VA/28w(1)
E-VA/28w(2)
E-VA/29w

82RAE
84WAG
91NIE
82RAE
84WAG
91NIE
91NIE
82RAE
84WAG
91NIE
99KIN
91FIN

_____________________________________________________________________________
continue

2001 by CRC Press LLC

continue

_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
31.4 wt% vinyl acetate
31.4 wt% vinyl acetate
31.8 wt% vinyl acetate
31.8 wt% vinyl acetate
32.1 wt% vinyl acetate
32.3 wt% vinyl acetate
32.3 wt% vinyl acetate
32.5 wt% vinyl acetate
33.0 wt% vinyl acetate
33.0 wt% vinyl acetate
33.2 wt% vinyl acetate
33.2 wt% vinyl acetate
33.4 wt% vinyl acetate
34.2 wt% vinyl acetate
42.7 wt% vinyl acetate
42.7 wt% vinyl acetate
58.0 wt% vinyl acetate

E-VA/31w
E-VA/31w
E-VA/32w(1)
E-VA/32w(1)
E-VA/32w(2)
E-VA/32w(3)
E-VA/32w(3)
E-VA/33w(1)
E-VA/33w(2)
E-VA/33w(2)
E-VA/33w(3)
E-VA/33w(3)
E-VA/33w(4)
E-VA/34w
E-VA/43w
E-VA/43w
E-VA/58w

83RAE
84WAG
82RAE
84WAG
84WAG
83RAE
84WAG
91NIE
83RAE
84WAG
83RAE
84WAG
84WAG
91FIN
82RAE
84WAG
91NIE

_____________________________________________________________________________
Characterization:

_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol
g/mol
g/mol
_____________________________________________________________________________

Copolymer (B)

E-VA/08w
E-VA/11w
E-VA/13w
E-VA/18w
E-VA/26w
E-VA/27w
E-VA/28w(1)
E-VA/28w(2)
E-VA/29w
E-VA/31w
E-VA/32w(1)
E-VA/32w(2)
E-VA/32w(3)
E-VA/33w(1)
E-VA/33w(2)
E-VA/33w(3)
E-VA/33w(4)
E-VA/34w
E-VA/43w
E-VA/58w

20400
29300
19700
33400
33600
13700
35000
61900
2180
27500
16200
21800
15500
13000
5430
15000
9590
13100
19800
35000

145000
161600
120000
137700
231000
60800
126500
167000
5680
60300
45800
46400
40800
22100
8220
28300
16900
41300
44000

Leuna-Werke, Germany
Exxon Chemical Company
Leuna-Werke, Germany
Exxon Chemical Company
Exxon Chemical Company
Leuna-Werke, Germany
Exxon Chemical Company
Leuna-Werke, Germany
Leuna-Werke, Germany
Leuna-Werke, Germany
Leuna-Werke, Germany
Leuna-Werke, Germany
Exxon Chemical Company
Leuna-Werke, Germany
Leuna-Werke, Germany
Leuna-Werke, Germany
Leuna-Werke, Germany
Leuna-Werke, Germany
Exxon Chemical Company

_____________________________________________________________________________

2001 by CRC Press LLC

Experimental HPPE data:

_____________________________________________________________________________
copolymer (B):
solvent (A):
Type of data:

E-VA/08w
ethene

82RAE
74-85-1

C2H4

cloud-points

T/K = 433.15
wB
P/MPa

0.05
140.3

0.10
139.3

copolymer (B):
solvent (A):
Type of data:

0.15
137.3

0.20
131.2

E-VA/08w
ethene

0.30
121.0

84WAG
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.05
393.15
155.0

0.10
393.15
154.5

0.15
393.15
149.5

0.20
393.15
144.9

0.30
393.15
133.2

0.05
413.15
146.4

0.10
413.15
144.9

0.15
413.15
141.9

0.20
413.15
136.8

wB
T/K
P/MPa

0.30
413.15
126.1

0.05
433.15
140.7

0.10
433.15
139.3

0.15
433.15
137.9

0.20
433.15
131.2

0.30
433.15
121.0

0.05
453.15
135.3

0.10
453.15
134.8

0.15
453.15
133.2

wB
T/K
P/MPa

0.20
453.15
127.2

0.30
453.15
116.0

0.05
473.15
130.7

0.10
473.15
129.7

0.15
473.15
126.7

0.20
473.15
122.6

0.30
473.15
113.0

copolymer (B):
solvent (A):
Type of data:

E-VA/11w
ethene

C2H4

91NIE
74-85-1

coexistence data

T/K = 403.15
The total feed concentration of the copolymer in the homogeneous system is: wB = 0.151

_____________________________________________________________________________
P/
wA
MPa
bottom phase top phase
_____________________________________________________________________________
88.6
108.8
125.5
136.2
141.0

0.449
0.567
0.674
0.768
0.849

0.991
0.983
0.968
0.949
(cloud point)

_____________________________________________________________________________

2001 by CRC Press LLC

copolymer (B):
solvent (A):
Type of data:

E-VA/11w
ethene

91NIE
74-85-1

C2H4

coexistence data

T/K = 433.15
The total feed concentration of the copolymer in the homogeneous system is: wB = 0.155

_____________________________________________________________________________
P/
wA
MPa
bottom phase top phase
_____________________________________________________________________________
94.8
104.9
115.2
128.2
131.0

0.501
0.568
0.652
0.782
0.845

0.992
0.985
0.975
0.952
(cloud point)

_____________________________________________________________________________
copolymer (B):
solvent (A):
Type of data:

E-VA/13w
ethene

82RAE
74-85-1

C2H4

cloud-points

T/K = 433.15
wB
P/MPa

0.05
132.4

0.10
128.5

copolymer (B):
solvent (A):
Type of data:

0.15
125.0

0.20
121.6

E-VA/13w
ethene

0.30
114.7

84WAG
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.05
393.15
146.6

0.075
393.15
145.1

0.10
393.15
143.3

0.15
393.15
138.9

0.20
393.15
133.9

0.30
393.15
125.5

0.05
413.15
137.8

0.075
413.15
137.3

0.10
413.15
134.8

wB
T/K
P/MPa

0.15
413.15
130.4

0.20
413.15
127.0

0.30
413.15
119.6

0.05
433.15
132.4

0.075
433.15
130.4

0.10
433.15
128.5

0.15
433.15
125.0

0.20
433.15
121.6

0.30
433.15
114.7

wB
T/K
P/MPa

0.05
453.15
127.5

0.075
453.15
125.5

0.10
453.15
124.0

0.15
453.15
120.6

0.20
453.15
117.7

0.30
453.15
109.8

0.05
473.15
122.6

0.075
473.15
121.1

0.10
473.15
119.6

wB
T/K
P/MPa

0.15
473.15
116.7

0.20
473.15
113.8

0.30
473.15
105.5

2001 by CRC Press LLC

copolymer (B):
solvent (A):
Type of data:

E-VA/18w
ethene

91NIE
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.030
373.65
158.6

0.030
403.15
143.5

0.030
433.15
133.0

0.081
363.15
156.2

0.081
393.15
141.4

0.081
423.15
131.8

0.081
453.15
124.5

0.211
388.15
136.5

0.211
403.15
130.5

wB
T/K
P/MPa

0.211
433.15
122.8

0.211
448.15
119.6

0.344
398.65
125.5

0.344
403.15
117.5

0.344
433.15
111.4

0.344
453.15
108.2

0.462
373.15
104.2

0.462
433.15
95.0

0.462
463.15
93.5

wB
T/K
P/MPa

0.585
393.15
78.2

0.585
433.15
77.2

0.585
453.15
76.8

copolymer (B):
solvent (A):
Type of data:

E-VA/18w
ethene

C2H4

91NIE
74-85-1

coexistence data

T/K = 403.15
The total feed concentration of the copolymer in the homogeneous system is: wB = 0.145

_____________________________________________________________________________
Fractionation during demixing
Demixing
wA
pressure
bottom phase top phase
bottom phase
top phase
_____________________________________________________________________________
Mn/
M w/
Mn/
M w/
M z/
P/
MPa
g/mol g/mol
g/mol g/mol g/mol
_____________________________________________________________________________
48.7
100.1
118.7
134.1

0.276
0.9992
0.543
0.989
0.680
0.980
0.855 (cloud point)

33400

7833 15338
11676 23830
137700 (feed sample)

30553
42441

_____________________________________________________________________________
copolymer (B):
solvent (A):
Type of data:

E-VA/18w
ethene

C2H4

91NIE
74-85-1

coexistence data

T/K = 433.15
continue

2001 by CRC Press LLC

continue
The total feed concentration of the copolymer in the homogeneous system is: wB = 0.133

_____________________________________________________________________________
P/
wA
MPa
bottom phase top phase
_____________________________________________________________________________
43.1
47.8
75.5
77.5
89.7
103.5
107.9
113.8
121.0
123.8
126.1

0.280
0.999
0.410
0.497
0.584
0.623
0.679
0.757
0.792
0.867

0.995
0.993
0.984
0.985
0.972
0.948
0.940
(cloud point)

_____________________________________________________________________________
copolymer (B):
solvent (A):
Type of data:

E-VA/18w
ethene

91NIE
74-85-1

C2H4

coexistence data

T/K = 463.15
The total feed concentration of the copolymer in the homogeneous system is: wB = 0.138

_____________________________________________________________________________
P/
wA
MPa
bottom phase top phase
_____________________________________________________________________________
48.1
97.4
108.7
122.4

0.252
0.542
0.650
0.862

0.9994
0.9905
0.9792
(cloud point)

_____________________________________________________________________________
copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/MPa

E-VA/26w
ethene

91NIE
74-85-1

C2H4

cloud-points

0.040
373.15
146.6

0.040
403.15
139.8

0.040
463.15
125.5

0.067
393.15
139.7

0.067
433.15
129.0

0.101
393.15
138.5

0.101
433.15
128.0

0.101
453.15
123.8

0.157
373.15
143.5
continue

2001 by CRC Press LLC

continue
wB
T/K
P/MPa

0.157
393.15
136.5

0.157
433.15
126.2

0.157
453.15
122.5

0.262
393.15
130.2

0.262
413.15
125.4

0.262
433.15
121.2

0.262
453.15
117.0

0.360
403.15
115.5

0.360
418.15
113.0

wB
T/K
P/MPa

0.360
453.15
108.2

0.408
393.15
110.6

0.408
413.15
107.5

0.408
433.15
105.2

0.408
453.15
102.8

0.480
373.15
99.2

0.480
393.15
96.5

0.480
433.15
94.0

0.480
449.15
93.8

copolymer (B):
solvent (A):
Type of data:

E-VA/27w
ethene

82RAE
74-85-1

C2H4

cloud-points

T/K = 433.15
wB
P/MPa

0.05
121.0

0.10
120.0

copolymer (B):
solvent (A):
Type of data:

0.15
118.0

0.20
115.5

E-VA/27w
ethene

0.30
109.0

84WAG
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.05
393.15
128.5

0.10
393.15
127.5

0.15
393.15
125.5

0.20
393.15
123.0

0.30
393.15
116.5

0.05
413.15
125.5

0.10
413.15
124.0

0.15
413.15
122.0

0.20
413.15
119.0

wB
T/K
P/MPa

0.30
413.15
112.0

0.05
433.15
121.0

0.10
433.15
120.0

0.15
433.15
118.0

0.20
433.15
115.5

0.30
433.15
109.0

0.05
453.15
118.5

0.10
453.15
117.0

0.15
453.15
115.0

wB
T/K
P/MPa

0.20
453.15
112.0

0.30
453.15
105.0

0.05
473.15
115.5

0.10
473.15
113.5

0.15
473.15
111.5

0.20
473.15
109.0

0.30
473.15
102.5

copolymer (B):
solvent (A):
Type of data:

E-VA/28w(1)
ethene

C2H4

91NIE
74-85-1

coexistence data

T/K = 433.15
The total feed concentration of the copolymer in the homogeneous system is: wB = 0.138
continue

2001 by CRC Press LLC

continue

_____________________________________________________________________________
P/
wA
MPa
bottom phase top phase
_____________________________________________________________________________
70.8
80.0
80.8
92.8
104.0
104.2
113.8
114.2
119.0
120.5
123.8
124.7

0.998
0.996
0.450
0.551

0.987
0.981

0.600
0.693
0.964
0.945
0.936

0.745
0.792
0.850

(cloud point)

_____________________________________________________________________________

copolymer (B):
solvent (A):
Type of data:

E-VA/28w(2)
ethene

99KIN
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.030
393.15
121.6

0.060
393.15
128.7

0.100
393.15
128.3

0.150
393.15
125.9

0.200
393.15
121.4

0.230
393.15
118.0

0.240
393.15
116.9

0.250
393.15
115.7

0.270
393.15
113.4

wB
T/K
P/MPa

0.300
393.15
111.4

0.350
393.15
110.4

0.030
413.15
117.5

0.060
413.15
124.0

0.100
413.15
123.6

0.150
413.15
121.5

0.200
413.15
117.4

0.230
413.15
114.5

0.240
413.15
113.4

wB
T/K
P/MPa

0.250
413.15
112.3

0.270
413.15
110.2

0.300
413.15
108.0

0.350
413.15
107.0

0.030
433.15
113.7

0.060
433.15
119.5

0.100
433.15
119.2

0.150
433.15
117.4

0.200
433.15
113.6

wB
T/K
P/MPa

0.230
433.15
110.7

0.240
433.15
109.8

0.250
433.15
109.2

0.270
433.15
107.3

0.300
433.15
105.4

0.350
433.15
104.4

0.030
453.15
110.5

0.060
453.15
116.3

0.100
453.15
116.0

wB
T/K
P/MPa

0.150
453.15
113.9

0.200
453.15
110.5

0.230
453.15
108.1

0.240
453.15
107.1

0.250
453.15
106.4

0.270
453.15
104.7

0.300
453.15
102.9

0.350
453.15
101.9

0.030
473.15
108.1

wB
T/K
P/MPa

0.060
473.15
113.0

0.100
473.15
112.9

0.150
473.15
111.2

0.200
473.15
108.0

0.230
473.15
105.9

0.240
473.15
104.9

0.250
473.15
104.2

0.270
473.15
102.1

0.300
473.15
100.8
continue

2001 by CRC Press LLC

continue
wB
T/K
P/MPa

0.350
473.15
99.8

0.030
493.15
105.7

0.060
493.15
110.4

wB
T/K
P/MPa

0.270
493.15
100.0

0.300
493.15
98.8

0.350
493.15
97.8

copolymer (B):
solvent (A):
Type of data:

0.100
493.15
110.3

E-VA/29w
ethene

0.150
493.15
108.5

0.200
493.15
105.7

0.230
493.15
103.7

0.240
493.15
102.8

0.250
493.15
101.9

91FIN
74-85-1

C2H4

gas solubility

T/K = 443.15
wA
P/MPa

0.0116
1.991

wA
P/MPa

0.1619
28.143

0.0184
3.041

copolymer (B):
solvent (A):
Type of data:

0.0657
5.882

E-VA/29w
ethene

0.0538
8.972

0.0777
12.864

0.0884
14.415

0.1005
16.768

0.1207
20.788

C2H4

0.1430
24.318

91FIN
74-85-1

coexistence data

T/K = 443.15
The total feed concentration of the copolymer in the homogeneous system is: wB = 0.250

_____________________________________________________________________________
P/
wA
MPa
bottom phase top phase
_____________________________________________________________________________
48.06
52.08
55.12
67.77
80.71
81.49
90.12

0.2719
0.9710
0.3199
0.4045
0.5468
0.5211
0.7401

0.9364
0.8985
0.8930
0.7584

_____________________________________________________________________________

2001 by CRC Press LLC

copolymer (B):
solvent (A):
Type of data:

E-VA/29w
vinyl acetate

91FIN
108-05-4

C4H6O2

gas solubility

T/K = 413.15
wA
P/MPa

0.042
0.152

wA
P/MPa

0.299
0.464

0.077
0.169

copolymer (B):
solvent (A):
Type of data:

0.079
0.186

0.114
0.273

E-VA/29w
vinyl acetate

0.115
0.288

0.205
0.371

0.245
0.405

0.237
0.435

0.318
0.444

91FIN
108-05-4

C4H6O2

gas solubility

T/K = 443.15
wA
P/MPa

0.028
0.125

0.030
0.144

0.047
0.165

wA
P/MPa

0.322
0.886

0.456
1.02

0.684
1.14

copolymer (B):
solvent (A):
Type of data:

0.050
0.166

E-VA/29w
vinyl acetate

0.065
0.185

0.071
0.265

0.116
0.494

0.127
0.557

0.129
0.567

91FIN
108-05-4

C4H6O2

gas solubility

T/K = 473.15
wA
P/MPa

0.024
0.179

0.037
0.211

copolymer (B):
solvent (A):
Type of data:

0.039
0.234

0.055
0.425

E-VA/31w
ethene

0.056
0.495

0.086
0.543

0.122
0.788

0.155
0.935

83RAE
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.014
393.15
122.6

0.04
393.15
124.0

0.07
393.15
123.1

0.10
393.15
121.6

0.20
393.15
118.7

0.25
393.15
115.2

0.30
393.15
114.2

0.05
433.15
117.9

0.10
433.15
115.1

wB
T/K
P/MPa

0.20
433.15
112.0

0.30
433.15
108.3

0.014
473.15
111.3

0.04
473.15
113.3

0.07
473.15
110.3

0.10
473.15
107.4

0.20
473.15
106.4

0.25
473.15
103.9

0.30
473.15
102.5

2001 by CRC Press LLC

copolymer (B):
solvent (A):
Type of data:

E-VA/31w
ethene

84WAG
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.014
393.15
122.6

0.04
393.15
124.0

0.07
393.15
123.1

0.10
393.15
121.6

0.15
393.15
122.1

0.20
393.15
119.7

0.25
393.15
115.2

0.30
393.15
114.2

0.014
413.15
119.2

wB
T/K
P/MPa

0.04
413.15
121.6

0.07
413.15
118.7

0.10
413.15
118.1

0.15
413.15
118.7

0.20
413.15
115.2

0.25
413.15
112.8

0.30
413.15
110.3

0.014
433.15
116.2

0.04
433.15
118.2

wB
T/K
P/MPa

0.07
433.15
115.7

0.10
433.15
114.5

0.15
433.15
114.5

0.20
433.15
110.8

0.25
433.15
110.3

0.30
433.15
108.4

0.014
453.15
114.2

0.04
453.15
115.2

0.07
453.15
112.8

wB
T/K
P/MPa

0.10
453.15
111.8

0.15
453.15
111.8

0.20
453.15
108.8

0.25
453.15
108.8

0.30
453.15
106.4

0.014
473.15
111.3

0.04
473.15
113.3

0.07
473.15
110.3

0.10
473.15
107.4

wB
T/K
P/MPa

0.15
473.15
108.4

0.20
473.15
106.4

0.25
473.15
105.9

0.30
473.15
102.5

copolymer (B):
solvent (A):
Type of data:

E-VA/32w(1)
ethene

82RAE
74-85-1

C2H4

cloud-points

T/K = 433.15
wB
P/MPa

0.05
119.7

0.10
119.5

copolymer (B):
solvent (A):
Type of data:

0.15
117.5

0.20
115.5

E-VA/32w(1)
ethene

0.30
111.5

84WAG
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.05
393.15
126.8

0.10
393.15
126.0

0.15
393.15
125.8

0.20
393.15
124.5

0.30
393.15
119.5

0.05
413.15
123.0

0.10
413.15
122.2

0.15
413.15
121.0

0.20
413.15
120.0

wB
T/K
P/MPa

0.30
413.15
115.5

0.05
433.15
119.7

0.10
433.15
119.5

0.15
433.15
117.5

0.20
433.15
115.5

0.30
433.15
111.5

0.05
453.15
116.0

0.10
453.15
115.7

0.15
453.15
114.0

wB
T/K
P/MPa

0.20
453.15
112.0

0.30
453.15
108.0

0.05
473.15
113.5

0.10
473.15
112.5

0.15
473.15
111.0

0.20
473.15
109.2

0.30
473.15
105.5

2001 by CRC Press LLC

copolymer (B):
solvent (A):
Type of data:

E-VA/32w(2)
ethene

84WAG
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.12
393.15
121.1

0.16
393.15
120.6

0.20
393.15
118.7

0.25
393.15
116.2

0.30
393.15
112.3

0.0075
413.15
114.2

0.12
413.15
117.2

0.16
413.15
117.2

0.20
413.15
114.7

wB
T/K
P/MPa

0.25
413.15
113.7

0.30
413.15
108.8

0.0075
433.15
111.3

0.04
433.15
114.2

0.08
433.15
113.7

0.12
433.15
114.7

0.16
433.15
113.7

0.20
433.15
111.8

0.25
433.15
110.3

wB
T/K
P/MPa

0.30
433.15
106.9

0.0075
453.15
110.9

0.04
453.15
112.3

0.08
453.15
110.8

0.12
453.15
111.8

0.16
453.15
110.8

0.20
453.15
109.8

0.25
453.15
107.4

0.30
453.15
103.9

wB
T/K
P/MPa

0.0075
473.15
108.4

0.04
473.15
109.8

0.08
473.15
108.4

0.12
473.15
108.8

0.16
473.15
107.9

0.20
473.15
105.9

0.25
473.15
104.9

0.30
473.15
102.0

copolymer (B):
solvent (A):
Type of data:

E-VA/32w(3)
ethene

cloud-points

wB
T/K
P/MPa

0.009
393.15
118.7

0.04
393.15
120.1

0.08
393.15
118.2

0.12
393.15
117.4

0.20
393.15
114.9

wB
T/K
P/MPa

0.08
473.15
107.9

0.12
473.15
106.9

0.20
473.15
105.9

0.25
473.15
102.7

0.30
473.15
99.1

copolymer (B):
solvent (A):
Type of data:

83RAE
74-85-1

C2H4

E-VA/32w(3)
ethene

0.25
393.15
111.8

0.30
393.15
105.9

0.009
473.15
107.9

0.04
473.15
109.8

84WAG
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.009
393.15
118.7

0.04
393.15
120.1

0.08
393.15
118.2

0.12
393.15
117.4

0.20
393.15
114.9

0.25
393.15
111.8

0.304
393.15
105.9

0.009
413.15
116.2

0.04
413.15
118.2

wB
T/K
P/MPa

0.08
413.15
115.2

0.12
413.15
114.9

0.20
413.15
112.3

0.25
413.15
108.4

0.304
413.15
104.5

0.009
433.15
112.3

0.04
433.15
115.2

0.08
433.15
112.8

0.12
433.15
112.5

wB
T/K
P/MPa

0.20
433.15
110.3

0.25
433.15
106.4

0.304
433.15
103.2

0.009
453.15
110.8

0.04
453.15
112.8

0.08
453.15
110.3

0.12
453.15
108.9

0.20
453.15
107.9

0.25
453.15
104.5

wB
T/K
P/MPa

0.304
453.15
100.2

0.009
473.15
107.9

0.04
473.15
109.8

0.08
473.15
107.9

0.12
473.15
106.9

0.20
473.15
105.9

0.25
473.15
102.7

0.30
473.15
99.1

2001 by CRC Press LLC

copolymer (B):
solvent (A):
Type of data:

E-VA/33w(1)
ethene

91NIE
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.068
383.15
118.2

0.068
393.15
115.8

0.068
433.15
108.5

0.068
453.15
105.7

0.157
383.15
116.5

0.157
433.15
107.0

0.178
373.15
116.0

0.178
403.15
110.0

0.178
453.15
103.2

wB
T/K
P/MPa

0.300
393.15
107.5

0.300
403.15
106.0

0.300
433.15
102.3

0.393
353.15
107.4

0.393
373.15
103.5

0.393
403.15
99.2

0.393
433.15
96.4

0.393
453.15
95.0

0.439
373.15
98.0

wB
T/K
P/MPa

0.439
433.15
92.2

copolymer (B):
solvent (A):
Type of data:

E-VA/33w(2)
ethene

cloud-points

wB
T/K
P/MPa

0.014
393.15
92.7

0.04
393.15
98.6

0.08
393.15
100.0

0.12
393.15
99.0

0.20
393.15
98.6

wB
T/K
P/MPa

0.08
473.15
93.2

0.12
473.15
91.2

0.20
473.15
90.7

0.25
473.15
88.7

0.32
473.15
86.8

copolymer (B):
solvent (A):
Type of data:

83RAE
74-85-1

C2H4

E-VA/33w(2)
ethene

0.25
393.15
96.6

0.32
393.15
94.3

0.014
473.15
86.8

0.04
473.15
93.6

84WAG
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.014
393.15
92.7

0.04
393.15
98.6

0.08
393.15
100.0

0.12
393.15
99.0

0.16
393.15
98.6

0.20
393.15
99.0

0.25
393.15
96.6

0.32
393.15
94.2

0.014
413.15
90.2

wB
T/K
P/MPa

0.04
413.15
97.1

0.08
413.15
98.1

0.12
413.15
96.8

0.16
413.15
97.1

0.20
413.15
96.9

0.25
413.15
95.1

0.32
413.15
93.2

0.014
433.15
88.7

0.04
433.15
96.1

wB
T/K
P/MPa

0.08
433.15
96.1

0.12
433.15
94.6

0.16
433.15
95.1

0.20
433.15
94.3

0.25
433.15
92.7

0.32
433.15
90.2

0.014
453.15
87.8

0.04
453.15
95.1

0.08
453.15
94.6

wB
T/K
P/MPa

0.12
453.15
92.7

0.16
453.15
93.2

0.20
453.15
92.7

0.25
453.15
90.4

0.32
453.15
88.7

0.014
473.15
86.8

0.04
473.15
93.6

0.08
473.15
93.2

0.12
473.15
91.2

wB
T/K
P/MPa

0.16
473.15
91.2

0.20
473.15
90.7

0.25
473.15
88.7

0.32
473.15
80.8

2001 by CRC Press LLC

copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/MPa

E-VA/33w(3)
ethene

83RAE
74-85-1

C2H4

84WAG
74-85-1

cloud-points

0.05
433.15
111.2

0.10
433.15
111.0

copolymer (B):
solvent (A):
Type of data:

C2H4

0.20
433.15
108.4

0.30
433.15
104.4

E-VA/33w(3)
ethene

cloud-points

wB
T/K
P/MPa

0.007
393.15
114.2

0.03
393.15
116.2

0.08
393.15
118.2

0.12
393.15
116.7

0.16
393.15
116.7

0.20
393.15
115.2

0.25
393.15
113.3

0.30
393.15
110.8

0.007
413.15
110.8

wB
T/K
P/MPa

0.03
413.15
113.3

0.08
413.15
114.9

0.12
413.15
112.8

0.16
413.15
112.8

0.20
413.15
112.3

0.25
413.15
109.8

0.30
413.15
106.7

0.007
433.15
108.4

0.03
433.15
110.8

wB
T/K
P/MPa

0.08
433.15
111.8

0.12
433.15
109.3

0.16
433.15
108.8

0.20
433.15
108.4

0.25
433.15
107.4

0.30
433.15
104.1

0.007
453.15
105.9

0.03
453.15
108.4

0.08
453.15
108.4

wB
T/K
P/MPa

0.12
453.15
106.9

0.16
453.15
106.9

0.20
453.15
105.9

0.25
453.15
103.9

0.30
453.15
100.8

0.007
473.15
104.4

0.03
473.15
105.9

0.08
473.15
106.4

0.12
473.15
104.4

wB
T/K
P/MPa

0.16
473.15
104.4

0.20
473.15
103.0

0.25
473.15
101.0

0.30
473.15
98.6

copolymer (B):
solvent (A):
Type of data:

E-VA/33w(4)
ethene

84WAG
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.0105
393.15
114.2

0.04
393.15
114.7

0.08
393.15
110.8

0.12
393.15
110.3

0.16
393.15
110.3

0.20
393.15
107.8

0.25
393.15
107.8

0.30
393.15
106.4

0.0105
413.15
111.0

wB
T/K
P/MPa

0.04
413.15
111.8

0.08
413.15
108.4

0.12
413.15
107.4

0.16
413.15
105.9

0.20
413.15
103.9

0.25
413.15
104.2

0.30
413.15
103.5

0.0105
433.15
108.4

0.04
433.15
108.8

wB
T/K
P/MPa

0.08
433.15
105.4

0.12
433.15
104.4

0.16
433.15
102.5

0.20
433.15
102.0

0.25
433.15
102.0

0.30
433.15
100.5

0.0105
453.15
106.9

0.04
453.15
106.4

0.08
453.15
103.0
continue

2001 by CRC Press LLC

continue
wB
T/K
P/MPa

0.12
453.15
101.5

0.16
453.15
100.5

0.20
453.15
100.1

0.25
453.15
100.1

wB
T/K
P/MPa

0.16
473.15
98.5

0.20
473.15
98.0

0.25
473.15
97.6

0.30
473.15
96.6

copolymer (B):
solvent (A):
Type of data:

E-VA/34w
ethene

0.30
453.15
98.5

0.0105
473.15
104.4

0.04
473.15
104.4

0.08
473.15
101.0

0.12
473.15
99.5

91FIN
74-85-1

C2H4

gas solubility

T/K = 473.15
wA
P/MPa

0.0135
2.695

0.0264
4.683

wA
P/MPa

0.1091
22.361

0.1323
29.520

copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/MPa

0.0337
6.551

E-VA/43w
ethene

0.0373
6.779

0.0462
8.847

0.0577
11.356

0.0652
14.006

0.0752
16.135

83RAE
74-85-1

C2H4

cloud-points

0.05
433.15
114.5

0.10
433.15
112.0

copolymer (B):
solvent (A):
Type of data:

0.0336
6.464

0.15
433.15
109.3

0.20
433.15
107.5

E-VA/43w
ethene

0.30
433.15
106.2

84WAG
74-85-1

C2H4

cloud-points

wB
T/K
P/MPa

0.05
393.15
121.3

0.10
393.15
118.6

0.15
393.15
116.5

0.20
393.15
114.1

0.30
393.15
112.4

0.05
413.15
117.2

0.10
413.15
115.5

0.15
413.15
112.7

0.20
413.15
110.3

wB
T/K
P/MPa

0.30
413.15
109.6

0.05
433.15
114.5

0.10
433.15
112.0

0.15
433.15
109.8

0.20
433.15
107.5

0.30
433.15
106.2

0.05
453.15
111.3

0.10
453.15
108.9

0.15
453.15
106.9

wB
T/K
P/MPa

0.20
453.15
105.5

0.30
453.15
103.4

0.05
473.15
108.6

0.10
473.15
106.8

0.15
473.15
103.4

0.20
473.15
102.7

0.30
473.15
101.0

2001 by CRC Press LLC

copolymer (B):
solvent (A):
Type of data:

E-VA/58w
ethene

91NIE
74-85-1

C2H4

coexistence data

T/K = 463.15
The total feed concentration of the copolymer in the homogeneous system is: wB = 0.157

_____________________________________________________________________________
P/
wA
MPa
bottom phase top phase
_____________________________________________________________________________
93.5
133.0
139.5
151.6
156.2
160.2
164.5
170.0
171.5
174.5
175.7

0.376
0.980
0.560
0.602
0.972
0.630
0.964
0.942
0.718
0.843

0.920
(cloud point)

_____________________________________________________________________________

_____________________________________________________________________________
Copolymers from ethylene oxide and propylene oxide
_____________________________________________________________________________
Average chemical composition of the copolymers, acronyms and references:

_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(propylene oxide)
diblock copolymer
8.6 mol% ethylene oxide
10.0 mol% ethylene oxide

EO-b-PO/09x
EO-b-PO/10x

98ONE
98ONE

_____________________________________________________________________________
continue

2001 by CRC Press LLC

continue

_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(propylene oxide)b-poly(ethylene oxide) triblock copolymer
11.8 mol% ethylene oxide
12.6 mol% ethylene oxide
13.7 mol% ethylene oxide
24.8 mol% ethylene oxide
24.8 mol% ethylene oxide
36.2 mol% ethylene oxide

EO-PO-EO/11x
EO-PO-EO/13x
EO-PO-EO/14x
EO-PO-EO/25x(1)
EO-PO-EO/25x(2)
EO-PO-EO/36x

98ONE
98ONE
98ONE
98ONE
98ONE
98ONE

Poly(propylene oxide)-b-poly(ethylene oxide)b-poly(propylene oxide) triblock copolymer


24.7 mol% ethylene oxide
24.8 mol% ethylene oxide
46.7 mol% ethylene oxide
56.9 mol% ethylene oxide

PO-EO-PO/25x(1)
PO-EO-PO/25x(2)
PO-EO-PO/47x
PO-EO-PO/57x

98ONE
98ONE
98ONE
98ONE

_____________________________________________________________________________

Characterization:

_____________________________________________________________________________
Further information
Mn/
g/mol
_____________________________________________________________________________
Copolymer (B)

EO-b-PO/09x
EO-b-PO/10x
EO-PO-EO/11x
EO-PO-EO/13x
EO-PO-EO/14x
EO-PO-EO/25x(1)
EO-PO-EO/25x(2)
EO-PO-EO/36x
PO-EO-PO/25x(1)
PO-EO-PO/25x(2)
PO-EO-PO/47x
PO-EO-PO/57x

1988 (= 132 + 1856)


566 (=

44 + 522)

1050 (= 50 + 950 + 50)


2944 (= 147 + 2650 + 147)
2210 (= 120 + 1970 + 120)
2460 (= 245 + 1970 + 245)
3738 (= 374 + 2990 + 374)
1844 (= 277 + 1290 + 277)
3125 (= 1250 + 625 + 1250)
2125 (= 850 + 425 + 850)
2833 (= 850 + 1133 + 850)
2000 (= 500 + 1000 + 500)

Jeffamine M2000, hydroxyl terminated EO,


NH2 terminated PO
Jeffamine M600, hydroxyl terminated EO,
NH2 terminated PO
Pluronic L31, hydroxyl terminated
Pluronic L81, hydroxyl terminated
Pluronic L61, hydroxyl terminated
Pluronic L62, hydroxyl terminated
Pluronic L92, hydroxyl terminated
Pluronic L43, hydroxyl terminated
Pluronic 25R2, hydroxyl terminated
Pluronic 17R2, hydroxyl terminated
Pluronic 17R4, hydroxyl terminated
Pluronic 10R5, hydroxyl terminated

_____________________________________________________________________________

2001 by CRC Press LLC

Experimental HPPE data:

_____________________________________________________________________________
copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/MPa

CO2

98ONE
124-38-9

CO2

98ONE
124-38-9

CO2

98ONE
124-38-9

CO2

98ONE
124-38-9

0.007
308.15
27.58

Type of data:

EO-PO-EO/11x
carbon dioxide

cloud-points

0.030
308.15
27.58

copolymer (B):
solvent (A):
Type of data:

EO-PO-EO/13x
carbon dioxide

cloud-points

0.002
308.15
27.58

copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/MPa

EO-b-PO/10x
carbon dioxide

cloud-points

copolymer (B):
solvent (A):

wB
T/K
P/MPa

98ONE
124-38-9

0.001
308.15
27.58

Type of data:

wB
T/K
P/MPa

CO2

cloud-points

copolymer (B):
solvent (A):

wB
T/K
P/MPa

EO-b-PO/09x
carbon dioxide

EO-PO-EO/14x
carbon dioxide

cloud-points

0.008
308.15
27.58

2001 by CRC Press LLC

copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/MPa

CO2

98ONE
124-38-9

CO2

98ONE
124-38-9

CO2

98ONE
124-38-9

CO2

98ONE
124-38-9

0.001
308.15
27.58

Type of data:

EO-PO-EO/36x
carbon dioxide

cloud-points

0.003
308.15
27.58

copolymer (B):
solvent (A):
Type of data:

PO-EO-PO/25x(1)
carbon dioxide

cloud-points

0.001
308.15
27.58

copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/MPa

EO-PO-EO/25x(2)
carbon dioxide

cloud-points

copolymer (B):
solvent (A):

wB
T/K
P/MPa

98ONE
124-38-9

0.002
308.15
27.58

Type of data:

wB
T/K
P/MPa

CO2

cloud-points

copolymer (B):
solvent (A):

wB
T/K
P/MPa

EO-PO-EO/25x(1)
carbon dioxide

PO-EO-PO/25x(2)
carbon dioxide

cloud-points

0.007
308.15
27.58

2001 by CRC Press LLC

copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/MPa

CO2

98ONE
124-38-9

CO2

98ONE
124-38-9

cloud-points

0.001
308.15
27.58

copolymer (B):
solvent (A):
Type of data:
wB
T/K
P/MPa

PO-EO-PO/47x
carbon dioxide

PO-EO-PO/57x
carbon dioxide

cloud-points

0.003
308.15
27.58

4.2. Table of systems where binary HPPE data were published only
in graphical form as phase diagrams or related figures
_____________________________________________________________________________
Copolymer (B)
Solvent/gas (A)
Ref.
_____________________________________________________________________________
Ethylene/acrylic acid copolymer
n-butane
n-butane
1-butene
1-butene
1-butene
1-butene
dimethyl ether
dimethyl ether
dimethyl ether
ethene
ethene
ethene
propane
propane
propene
propene
propene

94LE1
96LE3
94LE1
93HA2
94LE2
96LE3
94LE1
96LE1
96LE3
92LUF
93HA2
97LEE
94LE1
96LE1
93HA2
94LE1
96LE1

_____________________________________________________________________________

2001 by CRC Press LLC

Copolymer (B)
Solvent/gas (A)
Ref.
_____________________________________________________________________________
Ethylene/1-butene copolymer
n-heptane
propane
propane

96DEL
95CHE
98HAN

_____________________________________________________________________________
Ethylene/butyl acrylate copolymer
ethene

96BYU

_____________________________________________________________________________
Ethylene/1-hexene copolymer
n-heptane
2-methylpropane
propane
propane

96DEL
99PAN
98HAN
99PAN

_____________________________________________________________________________
Ethylene/methacrylic acid copolymer
n-butane
1-butene
dimethyl ether
ethene
propane

97LEE
97LEE
97LEE
97LEE
97LEE

_____________________________________________________________________________
Ethylene/methyl acrylate copolymer
n-butane
n-butane
n-butane
n-butane
n-butane
1-butene
1-butene
carbon dioxide
chlorodifluoromethane
chlorodifluoromethane
chlorodifluoromethane
dimethyl ether
ethane
ethane
ethane
ethane
ethene
ethene
ethene
ethene

93PRA
94LOS
94LE2
96LE1
96LE3
93PRA
96LE1
99LOR
91MEI
93HA1
93PRA
96LE3
92HAS
93HA2
94LOS
96LE3
92HAS
93HA2
96BYU
96LE3

_____________________________________________________________________________

2001 by CRC Press LLC

Copolymer (B)
Solvent/gas (A)
Ref.
_____________________________________________________________________________
Ethylene/methyl acrylate copolymer
n-hexane
methanol
propane
propane
propane
propane
propane
propene
propene
propene

94LOS
96LE3
91MEI
92HAS
93HA1
93HA2
94LOS
92HAS
93HA2
96LE3

_____________________________________________________________________________
Ethylene/4-methyl-1-pentene copolymer
n-heptane

96DEL

_____________________________________________________________________________
Ethylene/1-octene copolymer
cyclohexane
n-heptane
n-hexane
2-methylpentane
propane
propane

96DEL
96DEL
96DEL
96DEL
97WHA
98HAN

_____________________________________________________________________________
Ethylene/propylene copolymer
1-butene
ethene
n-heptane
propane
propane
propene
propene

93CHE
97HAN
96DEL
97WHA
98HAN
93CHE
97HAN

_____________________________________________________________________________
Ethylene/vinyl acetate copolymer
ethene
ethene
ethene

82WOH
96FOL
2000KIN

_____________________________________________________________________________
Methyl methacrylate/2-hydroxyethyl methacrylate
copolymer
carbon dioxide

97LEP

_____________________________________________________________________________

2001 by CRC Press LLC

Copolymer (B)
Solvent/gas (A)
Ref.
_____________________________________________________________________________
Poly(ethylene oxide)-b-poly(propylene oxide)b-poly(ethylene oxide) triblock copolymer
carbon dioxide

98ONE

_____________________________________________________________________________
Tetrafluoroethylene/hexafluoropropylene copolymer
carbon dioxide
carbon dioxide
carbon dioxide
carbon dioxide
chlorotrifluoromethane
hexafluoroethane
hexafluoropropene
octafluoropropane
sulfur hexafluoride
sulfur hexafluoride
sulfur hexafluoride
tetrafluoromethane
tetrafluoromethane
trifluoromethane

96MER
96RIN
98MCH
99MER
96MER
96MER
96MER
96MER
96MER
98MCH
99MER
96MER
98MCH
99MER

_____________________________________________________________________________
Tetrafluoroethylene/2,2-bis(trifluoromethyl)4,5-difluoro-1,3-dioxole copolymer
carbon dioxide

2000DIN

_____________________________________________________________________________
Vinylidene fluoride/hexafluoropropylene copolymer
carbon dioxide
carbon dioxide
carbon dioxide
1-chloro-1,1-difluoroethane
chlorodifluoromethane
chlorotrifluoromethane
chlorotrifluoromethane
1,1-difluoroethane
difluoromethane
hexafluoropropene
pentafluoroethane
1,1,1,2-tetrafluoroethane
trifluoromethane
trifluoromethane

96RIN
97MER
2000DIN
2000DIN
2000DIN
97MER
2000DIN
2000DIN
2000DIN
97MER
2000DIN
2000DIN
97MER
2000DIN

_____________________________________________________________________________

2001 by CRC Press LLC

4.3. Experimental data of quasiternary solutions containing at least


one copolymer

_____________________________________________________________________________
Copolymers from ethylene and acrylic acid
_____________________________________________________________________________
Average chemical composition of the copolymers, acronyms and references:

_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Ethylene/acrylic acid copolymer
3.0 wt% acrylic acid
6.0 wt% acrylic acid
7.3 wt% acrylic acid

E-AA/03w
E-AA/06w
E-AA/07w

92WIN
92WIN
92WIN

_____________________________________________________________________________
Characterization:

_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol
g/mol
_____________________________________________________________________________
Copolymer (B)

E-AA/03w
E-AA/06w
E-AA/07w

37500
30000
25000

183000
150000
126000

synthesized in the laboratory


synthesized in the laboratory
synthesized in the laboratory

_____________________________________________________________________________
Experimental HPPE data:

_____________________________________________________________________________
copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-AA/03w
acrylic acid
ethene

C3H4O2
C2H4

cloud-points

T/K = 413.15
wA
wB
wC
P/MPa

0.007
0.135
0.858
164.4

2001 by CRC Press LLC

0.014
0.135
0.851
157.1

0.026
0.135
0.839
152.9

0.043
0.135
0.822
148.0

0.068
0.135
0.797
142.7

0.095
0.135
0.770
138.2

92WIN
79-10-7
74-85-1

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-AA/03w
acrylic acid
ethene

C3H4O2
C2H4

92WIN
79-10-7
74-85-1

cloud-points

T/K = 433.15
wA
wB
wC
P/MPa

0.007
0.135
0.858
150.6

0.014
0.135
0.851
146.2

copolymer (B):
solvent (A):
solvent (C):
Type of data:

0.026
0.135
0.839
143.2

0.043
0.135
0.822
139.4

E-AA/03w
acrylic acid
ethene

0.068
0.135
0.797
134.1

0.095
0.135
0.770
130.5

C3H4O2
C2H4

92WIN
79-10-7
74-85-1

cloud-points

T/K = 453.15
wA
wB
wC
P/MPa

0.007
0.135
0.858
141.3

0.014
0.135
0.851
138.2

copolymer (B):
solvent (A):
solvent (C):
Type of data:

0.026
0.135
0.839
135.8

0.043
0.135
0.822
132.7

E-AA/03w
acrylic acid
ethene

0.068
0.135
0.797
128.4

0.095
0.135
0.770
124.7

C3H4O2
C2H4

92WIN
79-10-7
74-85-1

cloud-points

T/K = 473.15
wA
wB
wC
P/MPa

0.007
0.135
0.858
133.8

0.014
0.135
0.851
131.7

copolymer (B):
solvent (A):
solvent (C):
Type of data:

0.026
0.135
0.839
129.7

E-AA/06w
acrylic acid
ethene

0.043
0.135
0.822
127.5

0.068
0.135
0.797
123.7

0.095
0.135
0.770
120.5

C3H4O2
C2H4

92WIN
79-10-7
74-85-1

cloud-points

T/K = 413.15
continue

2001 by CRC Press LLC

continue
wA
wB
wC
P/MPa

0.005
0.135
0.860
195.1

0.017
0.135
0.848
175.5

copolymer (B):
solvent (A):
solvent (C):
Type of data:

0.026
0.135
0.839
166.0

0.043
0.135
0.822
157.5

E-AA/06w
acrylic acid
ethene

0.068
0.135
0.797
150.4

0.104
0.135
0.761
144.0

92WIN
79-10-7
74-85-1

C3H4O2
C2H4

cloud-points

T/K = 433.15
wA
wB
wC
P/MPa

0.005
0.135
0.860
173.4

0.014
0.135
0.851
163.2

copolymer (B):
solvent (A):
solvent (C):
Type of data:

0.017
0.135
0.848
169.4

0.026
0.135
0.839
154.5

E-AA/06w
acrylic acid
ethene

0.043
0.135
0.822
147.2

0.068
0.135
0.797
141.2

0.104
0.135
0.761
135.1

92WIN
79-10-7
74-85-1

C3H4O2
C2H4

cloud-points

T/K = 453.15
wA
wB
wC
P/MPa

0.005
0.135
0.860
155.2

0.014
0.135
0.851
149.1

copolymer (B):
solvent (A):
solvent (C):
Type of data:

0.017
0.135
0.848
147.5

0.026
0.135
0.839
144.5

E-AA/06w
acrylic acid
ethene

0.043
0.135
0.822
139.1

0.068
0.135
0.797
134.1

0.104
0.135
0.761
130.0

92WIN
79-10-7
74-85-1

C3H4O2
C2H4

cloud-points

T/K = 473.15
wA
wB
wC
P/MPa

0.005
0.135
0.860
143.1

2001 by CRC Press LLC

0.014
0.135
0.851
140.5

0.017
0.135
0.848
139.2

0.026
0.135
0.839
137.5

0.043
0.135
0.822
133.3

0.068
0.135
0.797
128.5

0.104
0.135
0.761
124.6

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-AA/07w
acrylic acid
ethene

C3H4O2
C2H4

92WIN
79-10-7
74-85-1

cloud-points

T/K = 413.15
wA
wB
wC
P/MPa

0.007
0.135
0.858
210.3

0.014
0.135
0.851
189.5

copolymer (B):
solvent (A):
solvent (C):
Type of data:

0.023
0.135
0.842
174.4

0.051
0.135
0.814
157.6

E-AA/07w
acrylic acid
ethene

0.074
0.135
0.791
152.8

0.113
0.135
0.752
150.3

C3H4O2
C2H4

92WIN
79-10-7
74-85-1

cloud-points

T/K = 433.15
wA
wB
wC
P/MPa

0.007
0.135
0.858
180.1

0.014
0.135
0.851
169.3

copolymer (B):
solvent (A):
solvent (C):
Type of data:

0.023
0.135
0.842
160.2

0.051
0.135
0.814
147.3

E-AA/07w
acrylic acid
ethene

0.074
0.135
0.791
144.0

0.113
0.135
0.752
142.4

C3H4O2
C2H4

92WIN
79-10-7
74-85-1

cloud-points

T/K = 453.15
wA
wB
wC
P/MPa

0.007
0.135
0.858
162.4

0.014
0.135
0.851
155.3

copolymer (B):
solvent (A):
solvent (C):
Type of data:

0.023
0.135
0.842
149.0

E-AA/07w
acrylic acid
ethene

0.051
0.135
0.814
139.5

0.074
0.135
0.791
137.3

0.113
0.135
0.752
136.5

C3H4O2
C2H4

92WIN
79-10-7
74-85-1

cloud-points

T/K = 473.15
continue

2001 by CRC Press LLC

continue
wA
wB
wC
P/MPa

0.007
0.135
0.858
148.5

0.014
0.135
0.851
144.7

0.023
0.135
0.842
140.5

0.051
0.135
0.814
134.1

0.074
0.135
0.791
131.9

0.113
0.135
0.752
130.5

_____________________________________________________________________________
Copolymers from ethylene and 1-hexene
_____________________________________________________________________________
Average chemical composition of the copolymers, acronyms and references:

_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Ethylene/1-hexene copolymer
10.6 wt% 1-hexene
16.1 wt% 1-hexene
35.0 wt% 1-hexene

E-H/11w
E-H/16w
E-H/35w

2000CH3
99KIN
2000CH3

_____________________________________________________________________________
Characterization:

_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol
g/mol
_____________________________________________________________________________
Copolymer (B)

E-H/11w
E-H/16w
E-H/35w

52600
60000
48100

80000
129000
103000

_____________________________________________________________________________
Experimental HPPE data:

_____________________________________________________________________________
copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-H/16w
ethene
n-butane

C2H4
C4H10

99KIN
74-85-1
106-97-8

cloud-points
continue

2001 by CRC Press LLC

continue
wA
wB
wC
T/K
P/MPa

0.800
0.150
0.050
393.15
145.0

0.800
0.150
0.050
413.15
135.3

0.800
0.150
0.050
433.15
127.3

0.800
0.150
0.050
453.15
121.2

0.800
0.150
0.050
473.15
116.6

0.800
0.150
0.050
493.15
113.0

0.750
0.150
0.100
393.15
134.0

0.750
0.150
0.100
413.15
125.9

0.750
0.150
0.100
433.15
119.1

wA
wB
wC
T/K
P/MPa

0.750
0.150
0.100
453.15
113.6

0.750
0.150
0.100
473.15
109.6

0.750
0.150
0.100
493.15
106.2

0.700
0.150
0.150
393.15
125.4

0.700
0.150
0.150
413.15
117.8

0.700
0.150
0.150
433.15
111.7

0.700
0.150
0.150
453.15
107.1

0.700
0.150
0.150
473.15
103.7

0.700
0.150
0.150
493.15
101.0

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-H/16w
ethene
ethane

99KIN
74-85-1
74-84-0

C2H4
C2H6

cloud-points

wA
wB
wC
T/K
P/MPa

0.800
0.150
0.050
393.15
151.7

0.800
0.150
0.050
413.15
140.7

0.800
0.150
0.050
433.15
133.4

0.800
0.150
0.050
453.15
126.3

0.800
0.150
0.050
473.15
120.8

0.800
0.150
0.050
493.15
116.5

0.750
0.150
0.100
393.15
147.1

0.750
0.150
0.100
413.15
136.8

0.750
0.150
0.100
433.15
129.1

wA
wB
wC
T/K
P/MPa

0.750
0.150
0.100
453.15
123.0

0.750
0.150
0.100
473.15
118.1

0.750
0.150
0.100
493.15
114.3

0.700
0.150
0.150
393.15
143.2

0.700
0.150
0.150
413.15
133.5

0.700
0.150
0.150
433.15
125.5

0.700
0.150
0.150
453.15
120.0

0.700
0.150
0.150
473.15
116.0

0.700
0.150
0.150
493.15
112.0

copolymer (B):
solvent (A):
solvent (C):
Type of data:
wA
wB
wC
T/K
P/MPa

0.840
0.150
0.010
393.15
195.0

wA
wB
wC
T/K
P/MPa

0.830
0.150
0.020
493.15
176.8

E-H/16w
ethene
helium

99KIN
74-85-1
7440-59-7

C2H4
He

cloud-points

2001 by CRC Press LLC

0.840
0.150
0.010
413.15
178.6

0.840
0.150
0.010
433.15
165.8

0.840
0.150
0.010
453.15
155.4

0.840
0.150
0.010
473.15
148.2

0.840
0.150
0.010
493.15
143.0

0.830
0.150
0.020
433.15
214.6

0.830
0.150
0.020
453.15
200.7

0.830
0.150
0.020
473.15
188.3

copolymer (B):
solvent (A):
solvent (C):
Type of data:
wA
wB
wC
T/K
P/MPa

E-H/11w
ethene
1-hexene

cloud-points

0.4255
0.1490
0.4255
393.15
65.4

0.4255
0.1490
0.4255
423.15
66.5

copolymer (B):
solvent (A):
solvent (C):
Type of data:

2000CH3
74-85-1
592-41-6

C2H4
C6H12

0.4255 0.2755
0.1490 0.1390
0.4255 0.5855
453.35 393.25
65.1
44.2

E-H/16w
ethene
1-hexene

0.2755
0.1390
0.5855
423.15
45.1

0.2755
0.1390
0.5855
453.25
44.6

99KIN
74-85-1
592-41-6

C2H4
C6H12

cloud-points

wA
wB
wC
T/K
P/MPa

0.6375
0.1500
0.2125
393.15
118.2

0.6375
0.1500
0.2125
413.15
103.2

0.6375
0.1500
0.2125
433.15
99.2

0.6375
0.1500
0.2125
453.15
95.7

0.6375
0.1500
0.2125
473.15
93.3

0.6375
0.1500
0.2125
493.15
91.4

0.4250
0.1500
0.4250
393.15
59.0

0.4250
0.1500
0.4250
413.15
59.0

0.4250
0.1500
0.4250
433.15
59.1

wA
wB
wC
T/K
P/MPa

0.4250
0.1500
0.4250
453.15
59.0

0.4250
0.1500
0.4250
473.15
59.1

0.4250
0.1500
0.4250
493.15
59.1

0.2125
0.1500
0.6375
393.15
25.6

0.2125
0.1500
0.6375
413.15
27.0

0.2125
0.1500
0.6375
433.15
28.3

0.2125
0.1500
0.6375
453.15
30.3

0.2125
0.1500
0.6375
473.15
32.3

0.2125
0.1500
0.6375
493.15
34.6

copolymer (B):
solvent (A):
solvent (C):
Type of data:
wA
wB
wC
T/K
P/MPa

C2H4
C6H12

2000CH3
74-85-1
592-41-6

cloud-points

0.4558
0.1400
0.4042
393.15
55.7

0.4558
0.1400
0.4042
413.15
55.7

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-H/35w
ethene
1-hexene

0.4558 0.4558
0.1400 0.1400
0.4042 0.4042
433.15 453.15
56.2
57.7

E-H/16w
ethene
methane

C2H4
CH4

99KIN
74-85-1
74-82-8

cloud-points
continue

2001 by CRC Press LLC

continue
wA
wB
wC
T/K
P/MPa

0.800
0.150
0.050
393.15
169.0

0.800
0.150
0.050
413.15
156.7

0.800
0.150
0.050
433.15
147.1

0.800
0.150
0.050
453.15
139.4

0.800
0.150
0.050
473.15
132.4

0.800
0.150
0.050
493.15
126.4

0.750
0.150
0.100
393.15
186.5

0.750
0.150
0.100
413.15
170.5

0.750
0.150
0.100
433.15
157.8

wA
wB
wC
T/K
P/MPa

0.750
0.150
0.100
453.15
149.0

0.750
0.150
0.100
473.15
142.0

0.750
0.150
0.100
493.15
137.5

0.700
0.150
0.150
393.15
202.0

0.700
0.150
0.150
413.15
186.9

0.700
0.150
0.150
433.15
174.0

0.700
0.150
0.150
453.15
162.8

0.700
0.150
0.150
473.15
153.7

0.700
0.150
0.150
493.15
149.1

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-H/16w
ethene
propane

99KIN
74-85-1
74-98-6

C2H4
C3H8

cloud-points

wA
wB
wC
T/K
P/MPa

0.800
0.150
0.050
393.15
148.5

0.800
0.150
0.050
413.15
136.0

0.800
0.150
0.050
433.15
128.1

0.800
0.150
0.050
453.15
122.1

0.800
0.150
0.050
473.15
117.4

0.800
0.150
0.050
493.15
113.6

0.750
0.150
0.100
393.15
138.3

0.750
0.150
0.100
413.15
129.3

0.750
0.150
0.100
433.15
123.3

wA
wB
wC
T/K
P/MPa

0.750
0.150
0.100
453.15
117.1

0.750
0.150
0.100
473.15
113.3

0.750
0.150
0.100
493.15
110.0

0.700
0.150
0.150
393.15
130.3

0.700
0.150
0.150
413.15
122.1

0.700
0.150
0.150
433.15
116.0

0.700
0.150
0.150
453.15
111.8

0.700
0.150
0.150
473.15
108.9

0.700
0.150
0.150
493.15
106.6

copolymer (B):
solvent (A):
solvent (C):
solvent (D):
Type of data:

E-H/16w
ethene
1-hexene
n-butane

99KIN
74-85-1
592-41-6
106-97-8

C2H4
C6H12
C4H10

cloud-points

wA
wB
wC
wD
T/K
P/MPa

0.6000
0.1500
0.2000
0.0500
393.15
99.9

0.6000
0.1500
0.2000
0.0500
413.15
95.8

0.6000
0.1500
0.2000
0.0500
433.15
91.6

0.6000
0.1500
0.2000
0.0500
453.15
89.7

0.6000
0.1500
0.2000
0.0500
473.15
87.7

0.6000
0.1500
0.2000
0.0500
493.15
86.0

0.5625
0.1500
0.1875
0.1000
393.15
90.5

0.5625
0.1500
0.1875
0.1000
413.15
87.2

0.5625
0.1500
0.1875
0.1000
433.15
84.6

wA
wB

0.5625
0.1500

0.5625
0.1500

0.5625
0.1500

0.5250
0.1500

0.5250
0.1500

0.5250
0.1500

0.5250
0.1500

0.5250
0.1500

0.5250
0.1500
continue

2001 by CRC Press LLC

continue
wC
wD
T/K
P/MPa

0.1875
0.1000
453.15
82.6

0.1875
0.1000
473.15
81.1

copolymer (B):
solvent (A):
solvent (C):
solvent (D):
Type of data:

0.1875
0.1000
493.15
79.9

0.1750
0.1500
393.15
85.5

E-H/16w
ethene
1-hexene
n-butane

0.1750
0.1500
413.15
83.1

0.1750
0.1500
433.15
81.1

0.1750
0.1500
453.15
79.5

0.1750
0.1500
473.15
78.2

0.1750
0.1500
493.15
77.2

99KIN
74-85-1
592-41-6
106-97-8

C2H4
C6H12
C4H10

cloud-points

wA
wB
wC
wD
T/K
P/MPa

0.4000
0.1500
0.4000
0.0500
393.15
57.0

0.4000
0.1500
0.4000
0.0500
413.15
57.1

0.4000
0.1500
0.4000
0.0500
433.15
57.2

0.4000
0.1500
0.4000
0.0500
453.15
57.3

0.4000
0.1500
0.4000
0.0500
473.15
57.3

0.4000
0.1500
0.4000
0.0500
493.15
57.4

0.3750
0.1500
0.3750
0.1000
393.15
55.6

0.3750
0.1500
0.3750
0.1000
413.15
55.6

0.3750
0.1500
0.3750
0.1000
433.15
55.7

wA
wB
wC
wD
T/K
P/MPa

0.3750
0.1500
0.3750
0.1000
453.15
55.8

0.3750
0.1500
0.3750
0.1000
473.15
55.9

0.3750
0.1500
0.3750
0.1000
493.15
56.1

0.3500
0.1500
0.3500
0.1500
393.15
54.9

0.3500
0.1500
0.3500
0.1500
413.15
54.9

0.3500
0.1500
0.3500
0.1500
433.15
55.1

0.3500
0.1500
0.3500
0.1500
453.15
55.4

0.3500
0.1500
0.3500
0.1500
473.15
55.6

0.3500
0.1500
0.3500
0.1500
493.15
55.6

copolymer (B):
solvent (A):
solvent (C):
solvent (D):
Type of data:

E-H/16w
ethene
1-hexene
n-butane

99KIN
74-85-1
592-41-6
106-97-8

C2H4
C6H12
C4H10

cloud-points

wA
wB
wC
wD
T/K
P/MPa

0.2000
0.1500
0.6000
0.0500
393.15
25.1

0.2000
0.1500
0.6000
0.0500
413.15
26.6

0.2000
0.1500
0.6000
0.0500
433.15
27.7

0.2000
0.1500
0.6000
0.0500
453.15
29.7

0.2000
0.1500
0.6000
0.0500
473.15
32.0

0.2000
0.1500
0.6000
0.0500
493.15
34.0

0.1875
0.1500
0.5625
0.1000
393.15
23.7

0.1875
0.1500
0.5625
0.1000
413.15
25.1

0.1785
0.1500
0.5625
0.1000
433.15
26.6

wA
wB
wC
wD
T/K
P/MPa

0.1875
0.1500
0.5625
0.1000
453.15
28.6

0.1875
0.1500
0.5625
0.1000
473.15
30.8

0.1875
0.1500
0.5625
0.1000
493.15
33.1

0.1750
0.1500
0.5250
0.1500
393.15
23.4

0.1750
0.1500
0.5250
0.1500
413.15
24.9

0.1750
0.1500
0.5250
0.1500
433.15
26.5

0.1750
0.1500
0.5250
0.1500
453.15
28.4

0.1750
0.1500
0.5250
0.1500
473.15
30.6

0.1750
0.1500
0.5250
0.1500
493.15
32.8

2001 by CRC Press LLC

copolymer (B):
solvent (A):
solvent (C):
solvent (D):
Type of data:

E-H/16w
ethene
1-hexene
helium

cloud-points

wA
wB
wC
wD
T/K
P/MPa

0.6300
0.1500
0.2100
0.0100
393.15
150.3

0.6300
0.1500
0.2100
0.0100
413.15
139.9

0.6300
0.1500
0.2100
0.0100
433.15
131.5

wA
wB
wC
wD
T/K
P/MPa

0.6225
0.1500
0.2075
0.0200
453.15
161.4

0.6225
0.1500
0.2075
0.0200
473.15
152.5

0.6225
0.1500
0.2075
0.0200
493.15
147.7

copolymer (B):
solvent (A):
solvent (C):
solvent (D):
Type of data:

99KIN
74-85-1
592-41-6
7440-59-7

C2H4
C6H12
He

0.6300
0.1500
0.2100
0.0100
453.15
125.1

E-H/16w
ethene
1-hexene
helium

0.6300
0.1500
0.2100
0.0100
473.15
119.9

0.6300
0.1500
0.2100
0.0100
493.15
115.5

0.6225
0.1500
0.2075
0.0200
393.15
200.5

0.6225
0.1500
0.2075
0.0200
413.15
185.5

0.6225
0.1500
0.2075
0.0200
433.15
172.6

99KIN
74-85-1
592-41-6
7440-59-7

C2H4
C6H12
He

cloud-points

wA
wB
wC
wD
T/K
P/MPa

0.4200
0.1500
0.4200
0.0100
393.15
100.0

0.4200
0.1500
0.4200
0.0100
413.15
95.1

0.4200
0.1500
0.4200
0.0100
433.15
91.2

0.4200
0.1500
0.4200
0.0100
453.15
88.2

0.4200
0.1500
0.4200
0.0100
473.15
86.1

0.4200
0.1500
0.4200
0.0100
493.15
84.4

0.4150
0.1500
0.4150
0.0200
393.15
149.7

0.4150
0.1500
0.4150
0.0200
413.15
139.0

0.4150
0.1500
0.4150
0.0200
433.15
130.5

wA
wB
wC
wD
T/K
P/MPa

0.4150
0.1500
0.4150
0.0200
453.15
123.6

0.4150
0.1500
0.4150
0.0200
473.15
118.2

0.4150
0.1500
0.4150
0.0200
493.15
113.6

0.4100
0.1500
0.4100
0.0300
393.15
209.9

0.4100
0.1500
0.4100
0.0300
413.15
189.9

0.4100
0.1500
0.4100
0.0300
433.15
172.9

0.4100
0.1500
0.4100
0.0300
453.15
161.6

0.4100
0.1500
0.4100
0.0300
473.15
153.8

0.4100
0.1500
0.4100
0.0300
493.15
148.4

copolymer (B):
solvent (A):
solvent (C):
solvent (D):
Type of data:

E-H/16w
ethene
1-hexene
helium

C2H4
C6H12
He

99KIN
74-85-1
592-41-6
7440-59-7

cloud-points
continue

2001 by CRC Press LLC

continue
wA
wB
wC
wD
T/K
P/MPa

0.2100
0.1500
0.6300
0.0100
393.15
54.4

0.2100
0.1500
0.6300
0.0100
413.15
54.6

0.2100
0.1500
0.6300
0.0100
433.15
54.5

0.2100
0.1500
0.6300
0.0100
453.15
54.3

0.2100
0.1500
0.6300
0.0100
473.15
54.0

0.2100
0.1500
0.6300
0.0100
493.15
54.0

0.2075
0.1500
0.6225
0.0200
393.15
93.3

0.2075
0.1500
0.6225
0.0200
413.15
88.8

0.2075
0.1500
0.6225
0.0200
433.15
85.1

wA
wB
wC
wD
T/K
P/MPa

0.2075
0.1500
0.6225
0.0200
453.15
82.1

0.2075
0.1500
0.6225
0.0200
473.15
79.8

0.2075
0.1500
0.6225
0.0200
493.15
78.0

0.2050
0.1500
0.6150
0.0300
393.15
134.5

0.2050
0.1500
0.6150
0.0300
413.15
127.1

0.2050
0.1500
0.6150
0.0300
433.15
121.7

0.2050
0.1500
0.6150
0.0300
453.15
117.1

0.2050
0.1500
0.6150
0.0300
473.15
113.3

0.2050
0.1500
0.6150
0.0300
493.15
110.2

copolymer (B):
solvent (A):
solvent (C):
solvent (D):
Type of data:

E-H/16w
ethene
1-hexene
methane

99KIN
74-85-1
592-41-6
74-82-8

C2H4
C6H12
CH4

cloud-points

wA
wB
wC
wD
T/K
P/MPa

0.6000
0.1500
0.2000
0.0500
393.15
123.0

0.6000
0.1500
0.2000
0.0500
413.15
117.5

0.6000
0.1500
0.2000
0.0500
433.15
112.4

0.6000
0.1500
0.2000
0.0500
453.15
108.1

0.6000
0.1500
0.2000
0.0500
473.15
104.7

0.6000
0.1500
0.2000
0.0500
493.15
102.0

0.5625
0.1500
0.1875
0.1000
393.15
137.2

0.5625
0.1500
0.1875
0.1000
413.15
129.7

0.5625
0.1500
0.1875
0.1000
433.15
124.2

wA
wB
wC
wD
T/K
P/MPa

0.5625
0.1500
0.1875
0.1000
453.15
119.6

0.5625
0.1500
0.1875
0.1000
473.15
115.8

0.5625
0.1500
0.1875
0.1000
493.15
112.8

0.5250
0.1500
0.1750
0.1500
393.15
151.9

0.5250
0.1500
0.1750
0.1500
413.15
144.0

0.5250
0.1500
0.1750
0.1500
433.15
137.1

0.5250
0.1500
0.1750
0.1500
453.15
131.4

0.5250
0.1500
0.1750
0.1500
473.15
127.0

0.5250
0.1500
0.1750
0.1500
493.15
123.4

copolymer (B):
solvent (A):
solvent (C):
solvent (D):
Type of data:
wA
wB
wC
wD
T/K
P/MPa

E-H/16w
ethene
1-hexene
methane

99KIN
74-85-1
592-41-6
74-82-8

C2H4
C6H12
CH4

cloud-points

0.4000
0.1500
0.4000
0.0500
393.15
83.0

0.4000
0.1500
0.4000
0.0500
413.15
80.9

0.4000
0.1500
0.4000
0.0500
433.15
79.0

0.4000
0.1500
0.4000
0.0500
453.15
77.4

0.4000
0.1500
0.4000
0.0500
473.15
76.0

0.4000
0.1500
0.4000
0.0500
493.15
74.8

0.3750
0.1500
0.3750
0.1000
393.15
100.5

0.3750
0.1500
0.3750
0.1000
413.15
97.1

0.3750
0.1500
0.3750
0.1000
433.15
94.0
continue

2001 by CRC Press LLC

continue
wA
wB
wC
wD
T/K
P/MPa

0.3750
0.1500
0.3750
0.1000
453.15
91.3

0.3750
0.1500
0.3750
0.1000
473.15
89.1

copolymer (B):
solvent (A):
solvent (C):
solvent (D):
Type of data:

0.3750
0.1500
0.3750
0.1000
493.15
87.2

0.3500
0.1500
0.3500
0.1500
393.15
121.6

E-H/16w
ethene
1-hexene
methane

0.3500
0.1500
0.3500
0.1500
413.15
115.2

0.3500
0.1500
0.3500
0.1500
433.15
109.6

0.3500
0.1500
0.3500
0.1500
453.15
105.4

0.3500
0.1500
0.3500
0.1500
473.15
101.9

0.3500
0.1500
0.3500
0.1500
493.15
99.0

99KIN
74-85-1
592-41-6
74-82-8

C2H4
C6H12
CH4

cloud-points

wA
wB
wC
wD
T/K
P/MPa

0.2000
0.1500
0.6000
0.0500
393.15
40.9

0.2000
0.1500
0.6000
0.0500
413.15
42.5

0.2000
0.1500
0.6000
0.0500
433.15
44.0

0.2000
0.1500
0.6000
0.0500
453.15
45.5

0.2000
0.1500
0.6000
0.0500
473.15
46.9

0.2000
0.1500
0.6000
0.0500
493.15
48.3

0.1875
0.1500
0.5625
0.1000
393.15
58.6

0.1875
0.1500
0.5625
0.1000
413.15
58.8

0.1785
0.1500
0.5625
0.1000
433.15
59.1

wA
wB
wC
wD
T/K
P/MPa

0.1875
0.1500
0.5625
0.1000
453.15
59.2

0.1875
0.1500
0.5625
0.1000
473.15
59.4

0.1875
0.1500
0.5625
0.1000
493.15
59.5

0.1750
0.1500
0.5250
0.1500
393.15
82.5

0.1750
0.1500
0.5250
0.1500
413.15
81.0

0.1750
0.1500
0.5250
0.1500
433.15
79.6

0.1750
0.1500
0.5250
0.1500
453.15
78.5

0.1750
0.1500
0.5250
0.1500
473.15
77.4

0.1750
0.1500
0.5250
0.1500
493.15
76.6

_____________________________________________________________________________
Copolymers from ethylene and propylene
_____________________________________________________________________________
Average chemical composition of the copolymers, acronyms and references:

_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Ethylene/propylene copolymer
50.0 mol% ethylene

E-P/50x

92CH2

_____________________________________________________________________________

2001 by CRC Press LLC

Characterization:

_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol
g/mol
_____________________________________________________________________________
Copolymer (B)

E-P/50x

25200

26000

alternating ethylene/propylene units from


complete hydrogenation of polyisoprene

_____________________________________________________________________________
Experimental HPPE data:

_____________________________________________________________________________

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-P/50x
ethene
1-butene

92CH2
74-85-1
106-98-9

C2H4
C4H8

cloud-points

wA
wB
wC
T/K
P/bar

0.074
0.187
0.739
355.35
144.0

0.074
0.187
0.739
373.45
177.0

0.074
0.187
0.739
398.15
215.3

0.074
0.187
0.739
423.15
250.3

0.074
0.187
0.739
448.15
278.0

0.074
0.187
0.739
473.55
303.0

0.117
0.162
0.721
355.35
200.4

wA
wB
wC
T/K
P/bar

0.117
0.162
0.721
423.15
296.8

0.117
0.162
0.721
447.95
322.0

0.117
0.162
0.721
473.45
344.5

0.234
0.154
0.612
355.35
318.5

0.234
0.154
0.612
373.55
340.2

0.234
0.154
0.612
398.15
365.0

0.234
0.154
0.612
423.25
389.0

copolymer (B):
solvent (A):
solvent (C):

E-P/50x
ethene
1-hexene

Type of data:

cloud-points

wA = 0.122

wB = 0.158

0.117
0.162
0.721
373.35
232.0

0.117
0.162
0.721
398.25
266.4

92CH2
74-85-1
592-41-6

C2H4
C6H12

wC = 0.820

T/K
P/bar

299.65
16.9
(VLE

323.15
23.0
VLE

353.45
32.1
VLE

373.65
38.5
VLE

384.05
41.2
VLE

397.15
44.0
VLE

405.75
58.0
LLE

413.15
68.0
LLE

422.15
85.0
LLE)

T/K
P/bar

424.75
89.2
(LLE

433.45
100.0
LLE

447.65
124.0
LLE

463.65
138.0
LLE

468.55
144.0
LLE

473.35
148.0
LLE

424.75
53.1
VLLE

433.45
54.1
VLLE

447.65
59.8
VLLE)
continue

2001 by CRC Press LLC

continue
T/K
P/bar

468.15
63.2
(VLLE)

copolymer (B):
solvent (A):
solvent (C):

E-P/50x
ethene
1-hexene

Type of data:

cloud-points

wA = 0.243

wB = 0.150

92CH2
74-85-1
592-41-6

C2H4
C6H12

wC = 0.607

T/K
P/bar

300.65
28.0
(VLE

306.15
31.7
VLE

314.15
43.0
LLE

321.85
56.5
LLE

353.75
114.0
LLE

371.95
144.0
LLE

395.85
179.0
LLE

425.55
222.0
LLE

T/K
P/bar

472.55
266.0
(LLE

315.95
35.0
VLLE

323.35
39.2
VLLE

341.15
47.0
VLLE

353.75
55.6
VLLE

371.95
63.4
VLLE

395.85
73.0
VLLE

424.15
81.2
VLLE)

copolymer (B):
solvent (A):
solvent (C):

E-P/50x
ethene
1-hexene

Type of data:

cloud-points

wA = 0.355

wB = 0.153

447.85
246.0
LLE)

92CH2
74-85-1
592-41-6

C2H4
C6H12

wC = 0.492

T/K
P/bar

251.15
187.0
(LLE

264.65
176.0
LLE

271.15
175.0
LLE

282.75
182.5
LLE

295.45
194.7
LLE

311.65
216.5
LLE

324.65
233.0
LLE

355.45
269.0
LLE

373.45
290.0
LLE)

T/K
P/bar

398.15
320.5
(LLE

423.95
348.0
LLE

449.15
370.0
LLE

473.45
384.0
LLE

258.85
17.2
VLLE

282.75
30.0
VLLE

295.45
36.5
VLLE

311.65
45.8
VLLE

324.65
55.0
VLLE)

T/K
P/bar

355.45
75.5
(VLLE

373.45
85.0
VLLE

398.15
91.8
VLLE)

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-P/50x
ethene
1-hexene

C2H4
C6H12

92CH2
74-85-1
592-41-6

cloud-points
continue

2001 by CRC Press LLC

continue
wA = 0.504

wB = 0.149

wC = 0.347

T/K
P/bar

296.05
488.0
(LLE

310.85
464.0
LLE

325.75
456.0
LLE

343.25
452.0
LLE

358.85
459.0
LLE

374.85
468.0
LLE

397.25
479.0
LLE

T/K
P/bar

469.65
511.0
(LLE

295.65
48.6
VLLE

311.15
59.4
VLLE

325.95
70.0
VLLE

343.25
79.0
VLLE

358.85
88.6
VLLE

374.85
92.0
VLLE)

424.15
492.0
LLE

446.55
502.0
LLE)

_____________________________________________________________________________
Copolymers from ethylene and vinyl acetate
_____________________________________________________________________________
Average chemical composition of the copolymers, acronyms and references:

_____________________________________________________________________________
Copolymer (B)
Acronym
Ref.
_____________________________________________________________________________
Ethylene/vinyl acetate copolymer
10.9 wt% vinyl acetate
17.5 wt% vinyl acetate
26.0 wt% vinyl acetate
27.5 wt% vinyl acetate
27.5 wt% vinyl acetate
32.3 wt% vinyl acetate
32.5 wt% vinyl acetate
34.2 wt% vinyl acetate
58.0 wt% vinyl acetate

E-VA/11w
E-VA/18w
E-VA/26w
E-VA/28w(1)
E-VA/28w(2)
E-VA/32w
E-VA/33w
E-VA/34w
E-VA/58w

91NIE
91NIE
91NIE
91NIE
99KIN
84WOH
91NIE
91FIN
91NIE

_____________________________________________________________________________
Characterization:

_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol
g/mol
_____________________________________________________________________________
Copolymer (B)

E-VA/11w
E-VA/18w
E-VA/26w
E-VA/28w(1)

29300
33400
33600
35000

161600
137700
231000
126500

Exxon Chemical Company


Exxon Chemical Company
Exxon Chemical Company
Exxon Chemical Company

_____________________________________________________________________________
continue

2001 by CRC Press LLC

continue

_____________________________________________________________________________
M w/
M /
Further information
Mn/
g/mol g/mol
g/mol
_____________________________________________________________________________
Copolymer (B)

E-VA/28w(2)
E-VA/32w
E-VA/33w
E-VA/34w
E-VA/58w

61900
15500
15000
13100
35000

167000
40800
28300
41300

Leuna-Werke, Germany
Leuna-Werke, Germany
Leuna-Werke, Germany
Exxon Chemical Company

_____________________________________________________________________________
Experimental HPPE data:

_____________________________________________________________________________
copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/11w
ethene
vinyl acetate

91NIE
74-85-1
108-05-4

C2H4
C4H6O2

coexistence data

T/K = 403.15
The total feed concentration of the homogeneous system before demixing is:
wA = 0.590; wB = 0.153; wC = 0.257

_____________________________________________________________________________
wB
wC
wA
wB
wC
P/
wA
MPa
bottom phase
top phase
_____________________________________________________________________________
56.5
75.5
87.8
100.2
104.1

0.311

0.542

0.147

0.450
0.546
0.590

0.352
0.212
0.153

0.683 0.016
0.198
0.678 0.023
0.242
0.660 0.048
0.257 (cloud point)

0.301
0.299
0.292

_____________________________________________________________________________
copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/11w
ethene
vinyl acetate

C2H4
C4H6O2

91NIE
74-85-1
108-05-4

coexistence data

T/K = 403.15
continue

2001 by CRC Press LLC

continue
The total feed concentration of the homogeneous system before demixing is:
wA = 0.347; wB = 0.157; wC = 0.496

_____________________________________________________________________________
wB
wC
wA
wB
wC
P/
wA
MPa
bottom phase
top phase
_____________________________________________________________________________
58.5
68.0
72.7

0.322
0.347

0.215
0.157

0.387 0.037
0.463
0.380 0.056
0.496 (cloud point)

0.576
0.564

_____________________________________________________________________________
copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/11w
ethene
vinyl acetate

91NIE
74-85-1
108-05-4

C2H4
C4H6O2

coexistence data

T/K = 433.15
The total feed concentration of the homogeneous system before demixing is:
wA = 0.254; wB = 0.155; wC = 0.591

_____________________________________________________________________________
wB
wC
wA
wB
wC
P/
wA
MPa
bottom phase
top phase
_____________________________________________________________________________
48.7
53.4

0.231
0.254

0.230
0.155

0.539
0.277 0.050
0.591 (cloud point)

0.673

_____________________________________________________________________________
copolymer (B):
solvent (A):
solvent (C):
Type of data:
wA
wB
wC
T/K
P/MPa

E-VA/18w
ethene
vinyl acetate

91NIE
74-85-1
108-05-4

C2H4
C4H6O2

cloud-points

0.422
0.159
0.419
373.15
75.3

0.422
0.159
0.419
403.15
69.8

0.422
0.159
0.419
433.15
68.0

0.217
0.156
0.627
373.15
45.8

0.217
0.156
0.627
403.15
38.3

0.217
0.156
0.627
433.15
39.0

0.120
0.298
0.582
378.15
21.4

0.120
0.298
0.582
388.15
19.5

0.120
0.298
0.582
403.15
18.0
continue

2001 by CRC Press LLC

continue
wA
wB
wC
T/K
P/MPa

0.120
0298
0.582
423.15
19.4

0.120
0.298
0.582
433.15
20.5

copolymer (B):
solvent (A):
solvent (C):
Type of data:

0.120
0.298
0.582
443.15
22.2

E-VA/18w
ethene
vinyl acetate

91NIE
74-85-1
108-05-4

C2H4
C4H6O2

coexistence data

T/K = 433.15
The total feed concentration of the homogeneous system before demixing is:
wA = 0.217; wB = 0.156; wC = 0.627

_____________________________________________________________________________
wB
wC
wA
wB
wC
P/
wA
MPa
bottom phase
top phase
_____________________________________________________________________________
27.5
33.5
39.0

0.160
0.188
0.217

0.360
0.276
0.156

0.480
0.251 0.041
0.536
0.242 0.061
0.627 (cloud point)

0.708
0.697

_____________________________________________________________________________
copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/18w
ethene
vinyl acetate

91NIE
74-85-1
108-05-4

C2H4
C4H6O2

coexistence data

T/K = 433.15
The total feed concentration of the homogeneous system before demixing is:
wA = 0.343; wB = 0.136; wC = 0.521

_____________________________________________________________________________
wB
wC
wA
wB
wC
P/
wA
MPa
bottom phase
top phase
_____________________________________________________________________________
19.9
43.0
57.3

0.256
0.343

0.361
0.136

0.4042 0.0004
0.383
0.3936 0.0127
0.521 (cloud point)

0.5954
0.5937

_____________________________________________________________________________

2001 by CRC Press LLC

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/18w
ethene
vinyl acetate

C2H4
C4H6O2

91NIE
74-85-1
108-05-4

coexistence data

T/K = 433.15
The total feed concentration of the homogeneous system before demixing is:
wA = 0.442; wB = 0.159; wC = 0.419

_____________________________________________________________________________
P/
wA
wB
wC
wA
wB
wC
MPa
bottom phase
top phase
_____________________________________________________________________________
37.7
50.0
61.9
68.0

0.221
0.288
0.365
0.422

0.532
0.404
0.272
0.159

0.247
0.498 0.025
0.308
0.487 0.038
0.363
0.476 0.062
0.419 (cloud point)

0.477
0.475
0.462

_____________________________________________________________________________

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/18w
ethene
vinyl acetate

C2H4
C4H6O2

91NIE
74-85-1
108-05-4

coexistence data

T/K = 433.15
The total feed concentration of the homogeneous system before demixing is:
wA = 0.645; wB = 0.158; wC = 0.197

_____________________________________________________________________________
wB
wC
wA
wB
wC
P/
wA
MPa
bottom phase
top phase
_____________________________________________________________________________
30.4
43.7
66.6
86.0
97.2

0.176
0.244
0.370
0.513
0.645

0.760
0.670
0.506
0.325
0.158

0.064
0.779 0.0008
0.086
0.766 0.0009
0.124
0.754 0.0130
0.162
0.736 0.0290
0.197 (cloud point)

0.221
0.233
0.233
0.235

_____________________________________________________________________________

2001 by CRC Press LLC

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/18w
ethene
vinyl acetate

91NIE
74-85-1
108-05-4

C2H4
C4H6O2

coexistence data

T/K = 463.15
The total feed concentration of the homogeneous system before demixing is:
wA = 0.460; wB = 0.135; wC = 0.405

_____________________________________________________________________________
P/
wA
wB
wC
wA
wB
wC
MPa
bottom phase
top phase
_____________________________________________________________________________
47.3
58.8
70.7

0.273
0.346
0.460

0.506
0.363
0.135

0.221
0.582 0.012
0.291
0.546 0.051
0.405 (cloud point)

0.406
0.403

_____________________________________________________________________________
Fractionation during demixing

_____________________________________________________________________________
Demixing
pressure

molar mass averages


bottom phase
top phase

_____________________________________________________________________________
M w/
M z/
Mn/
M w/
M z/
P/
Mn/
MPa
g/mol
g/mol
g/mol
g/mol
g/mol g/mol
_____________________________________________________________________________
47.3
58.8
70.7

5611
11958
33400

13634
26057

27447
44198

137700 (feed sample)

_____________________________________________________________________________
copolymer (B):
solvent (A):
solvent (C):
Type of data:
wA
wB
wC
T/K
P/MPa

E-VA/26w
ethene
vinyl acetate

91NIE
74-85-1
108-05-4

C2H4
C4H6O2

cloud-points

0.317
0.360
0.323
363.15
52.3

0.317
0.360
0.323
373.15
53.1

0.317
0.360
0.323
393.15
54.0

0.317
0.360
0.323
413.15
55.2

0.317
0.360
0.323
438.15
57.2

0.317
0.360
0.323
453.15
58.5

0.340
0.322
0.338
383.15
62.4

0.340
0.322
0.338
433.15
64.5

0.413
0.207
0.380
403.15
75.4
continue

2001 by CRC Press LLC

continue
wA
wB
wC
T/K
P/MPa

0.413
0.207
0.380
433.15
75.1

0.505
0.257
0.238
363.15
88.3

0.505
0.257
0.238
383.15
86.1

0.505
0.257
0.238
403.15
83.7

wA
wB
wC
T/K
P/MPa

0.631
0.187
0.182
443.15
96.5

0.795
0.105
0.100
383.15
122.0

0.795
0.105
0.100
403.15
118.5

0.795
0.105
0.100
433.15
113.0

copolymer (B):
solvent (A):
solvent (C):
Type of data:
wA
wB
wC
T/K
P/MPa

E-VA/28w(1)
ethene
vinyl acetate

0.505
0.257
0.238
453.15
81.8

0.631
0.187
0.182
363.15
106.8

0.631
0.187
0.182
383.15
102.8

0.631
0.187
0.182
403.15
100.0

91NIE
74-85-1
108-05-4

C2H4
C4H6O2

cloud-points

0.594
0.148
0.258
398.15
90.2

0.594
0.148
0.258
403.15
86.4

copolymer (B):
solvent (A):
solvent (C):
Type of data:

0.505
0.257
0.238
438.15
82.0

0.594
0.148
0.258
433.15
84.6

0.200
0.152
0.648
401.15
26.1

0.200
0.152
0.648
413.15
27.2

E-VA/28w(1)
ethene
vinyl acetate

0.200
0.152
0.648
433.15
29.0

91NIE
74-85-1
108-05-4

C2H4
C4H6O2

coexistence data

T/K = 403.15
The total feed concentration of the homogeneous system before demixing is:
wA = 0.353; wB = 0.159; wC = 0.488

_____________________________________________________________________________
wB
wC
wA
wB
wC
P/
wA
MPa
bottom phase
top phase
_____________________________________________________________________________
30.7
31.2
39.1
39.7
46.7
49.5

0.016

0.569

0.220

0.446

0.334

0.415

0.349
0.224
0.159

0.409 0.025
0.396
0.457
0.403 0.044
0.488 (cloud point)

0.563

0.255
0.319
0.353

0.553

_____________________________________________________________________________

2001 by CRC Press LLC

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/28w(1)
ethene
vinyl acetate

91NIE
74-85-1
108-05-4

C2H4
C4H6O2

coexistence data

T/K = 433.15
The total feed concentration of the homogeneous system before demixing is:
wA = 0.594; wB = 0.148; wC = 0.258

_____________________________________________________________________________
P/
wA
wB
wC
wA
wB
wC
MPa
bottom phase
top phase
_____________________________________________________________________________
35.5
48.2
56.6
67.0
78.6
84.6

0.204
0.273
0.322
0.392
0.500
0.594

0.702
0.613
0.551
0.447
0.290
0.148

0.094
0.114
0.709
0.127
0.705
0.161
0.692
0.210
0.677
0.258 (cloud point)

0.008
0.013
0.020
0.040

0.283
0.282
0.288
0.283

_____________________________________________________________________________
copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/28w(1)
ethene
vinyl acetate

91NIE
74-85-1
108-05-4

C2H4
C4H6O2

coexistence data

T/K = 433.15
The total feed concentration of the homogeneous system before demixing is:
wA = 0.349; wB = 0.152; wC = 0.499

_____________________________________________________________________________
wB
wC
wA
wB
wC
P/
wA
MPa
bottom phase
top phase
_____________________________________________________________________________
27.8
35.8
46.2
51.0

0.176
0.221
0.289
0.349

0.529
0.439
0.308
0.152

0.295
0.419 0.012
0.340
0.413 0.021
0.403
0.402 0.051
0.499 (cloud point)

0.567
0.566
0.547

_____________________________________________________________________________

2001 by CRC Press LLC

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/28w(1)
ethene
vinyl acetate

91NIE
74-85-1
108-05-4

C2H4
C4H6O2

coexistence data

T/K = 433.15
The total feed concentration of the homogeneous system before demixing is:
wA = 0.200; wB = 0.152; wC = 0.648

_____________________________________________________________________________
wB
wC
wA
wB
wC
P/
wA
MPa
bottom phase
top phase
_____________________________________________________________________________
14.5
19.5
26.0
29.0

0.140
0.154
0.181
0.200

0.400
0.356
0.233
0.152

0.460
0.238 0.014
0.490
0.231 0.031
0.586
0.228 0.051
0.648 (cloud point)

0.748
0.738
0.721

_____________________________________________________________________________
copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/28w(2)
ethene
carbon dioxide

99KIN
74-85-1
124-38-9

C2H4
CO2

cloud-points

wA
wB
wC
T/K
P/MPa

0.800
0.150
0.050
393.15
127.7

0.800
0.150
0.050
413.15
123.0

0.800
0.150
0.050
433.15
119.2

0.800
0.150
0.050
453.15
115.9

0.800
0.150
0.050
473.15
113.0

0.800
0.150
0.050
493.15
110.2

0.750
0.150
0.100
393.15
128.5

0.750
0.150
0.100
413.15
123.8

0.750
0.150
0.100
433.15
120.1

wA
wB
wC
T/K
P/MPa

0.750
0.150
0.100
453.15
117.0

0.750
0.150
0.100
473.15
113.9

0.750
0.150
0.100
493.15
111.2

0.700
0.150
0.150
393.15
130.3

0.700
0.150
0.150
413.15
125.7

0.700
0.150
0.150
433.15
121.8

0.700
0.150
0.150
453.15
118.9

0.700
0.150
0.150
473.15
115.8

0.700
0.150
0.150
493.15
113.1

copolymer (B):
solvent (A):
solvent (C):
Type of data:
wA
wB
wC
T/K
P/MPa

E-VA/28w(2)
ethene
ethane

99KIN
74-85-1
74-84-0

C2H4
C2H6

cloud-points

0.800
0.150
0.050
393.15
125.6

0.800
0.150
0.050
413.15
121.2

0.800
0.150
0.050
433.15
117.2

0.800
0.150
0.050
453.15
113.9

0.800
0.150
0.050
473.15
110.8

0.800
0.150
0.050
493.15
108.0

0.750
0.150
0.100
393.15
126.0

0.750
0.150
0.100
413.15
121.5

0.750
0.150
0.100
433.15
117.3
continue

2001 by CRC Press LLC

continue
wA
wB
wC
T/K
P/MPa

0.750
0.150
0.100
453.15
114.0

0.750
0.150
0.100
473.15
111.3

copolymer (B):
solvent (A):
solvent (C):
Type of data:

0.750
0.150
0.100
493.15
108.4

0.700
0.150
0.150
393.15
124.8

E-VA/28w(2)
ethene
helium

0.700
0.150
0.150
413.15
120.0

0.700
0.150
0.150
433.15
115.8

0.700
0.150
0.150
453.15
112.4

0.700
0.150
0.150
473.15
109.7

0.700
0.150
0.150
493.15
107.5

99KIN
74-85-1
7440-59-7

C2H4
He

cloud-points

wA
wB
wC
T/K
P/MPa

0.955
0.035
0.010
393.15
163.6

0.955
0.035
0.010
413.15
156.1

0.955
0.035
0.010
433.15
149.2

0.955
0.035
0.010
453.15
142.8

0.955
0.035
0.010
473.15
137.5

0.955
0.035
0.010
493.15
132.7

0.920
0.070
0.010
393.15
168.1

0.920
0.070
0.010
413.15
159.3

0.920
0.070
0.010
433.15
151.5

wA
wB
wC
T/K
P/MPa

0.920
0.070
0.010
453.15
145.4

0.920
0.070
0.010
473.15
139.9

0.920
0.070
0.010
493.15
135.3

0.870
0.120
0.010
393.15
165.2

0.870
0.120
0.010
413.15
157.6

0.870
0.120
0.010
433.15
150.7

0.870
0.120
0.010
453.15
144.6

0.870
0.120
0.010
473.15
139.2

0.870
0.120
0.010
493.15
134.5

wA
wB
wC
T/K
P/MPa

0.840
0.150
0.010
393.15
163.8

0.840
0.150
0.010
413.15
156.2

0.840
0.150
0.010
433.15
149.4

0.840
0.150
0.010
453.15
143.3

0.840
0.150
0.010
473.15
137.9

0.840
0.150
0.010
493.15
133.3

0.790
0.200
0.010
393.15
163.2

0.790
0.200
0.010
413.15
155.7

0.790
0.200
0.010
433.15
148.8

wA
wB
wC
T/K
P/MPa

0.790
0.200
0.010
453.15
142.5

0.790
0.200
0.010
473.15
137.5

0.790
0.200
0.010
493.15
132.6

0.640
0.350
0.010
393.15
158.7

0.640
0.350
0.010
413.15
150.1

0.640
0.350
0.010
433.15
142.7

0.640
0.350
0.010
453.15
137.4

0.640
0.350
0.010
473.15
132.5

0.640
0.350
0.010
493.15
128.4

copolymer (B):
solvent (A):
solvent (C):
Type of data:
wA
wB
wC
T/K
P/MPa

E-VA/28w(2)
ethene
nitrogen

99KIN
74-85-1
7727-37-9

C2H4
N2

cloud-points

0.800
0.150
0.050
393.15
146.5

0.800
0.150
0.050
413.15
140.5

0.800
0.150
0.050
433.15
135.8

0.800
0.150
0.050
453.15
130.5

0.800
0.150
0.050
473.15
125.4

0.800
0.150
0.050
493.15
120.5

0.750
0.150
0.100
393.15
172.5

0.750
0.150
0.100
413.15
164.7

0.750
0.150
0.100
433.15
155.6
continue

2001 by CRC Press LLC

continue
wA
wB
wC
T/K
P/MPa

0.750
0.150
0.100
453.15
148.8

0.750
0.150
0.100
473.15
142.5

copolymer (B):
solvent (A):
solvent (C):
Type of data:

0.750
0.150
0.100
493.15
137.5

0.700
0.150
0.150
393.15
193.0

E-VA/28w(2)
ethene
propane

0.700
0.150
0.150
413.15
184.8

0.700
0.150
0.150
433.15
176.8

0.700
0.150
0.150
453.15
168.9

0.700
0.150
0.150
473.15
161.4

0.700
0.150
0.150
493.15
154.4

99KIN
74-85-1
74-98-6

C2H4
C3H8

cloud-points

wA
wB
wC
T/K
P/MPa

0.800
0.150
0.050
393.15
122.0

0.800
0.150
0.050
413.15
117.7

0.800
0.150
0.050
433.15
113.6

0.800
0.150
0.050
453.15
110.5

0.800
0.150
0.050
473.15
107.6

0.800
0.150
0.050
493.15
104.9

0.750
0.150
0.100
393.15
116.3

0.750
0.150
0.100
413.15
112.4

0.750
0.150
0.100
433.15
109.0

wA
wB
wC
T/K
P/MPa

0.750
0.150
0.100
453.15
105.8

0.750
0.150
0.100
473.15
103.4

0.750
0.150
0.100
493.15
100.8

0.700
0.150
0.150
393.15
112.9

0.700
0.150
0.150
413.15
109.2

0.700
0.150
0.150
433.15
105.9

0.700
0.150
0.150
453.15
103.0

0.700
0.150
0.150
473.15
100.4

0.700
0.150
0.150
493.15
98.0

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/28w(2)
ethene
vinyl acetate

99KIN
74-85-1
108-05-4

C2H4
C4H6O2

cloud-points

wA
wB
wC
T/K
P/MPa

0.6715
0.1500
0.1785
393.15
99.5

0.6715
0.1500
0.1785
413.15
97.5

0.6715
0.1500
0.1785
433.15
95.5

0.6715
0.1500
0.1785
453.15
94.1

0.6715
0.1500
0.1785
473.15
92.7

0.6715
0.1500
0.1785
493.15
91.5

0.6375
0.1500
0.2125
393.15
94.3

0.6375
0.1500
0.2125
413.15
92.6

0.6375
0.1500
0.2125
433.15
91.1

wA
wB
wC
T/K
P/MPa

0.6375
0.1500
0.2125
453.15
89.8

0.6375
0.1500
0.2125
473.15
88.6

0.6375
0.1500
0.2125
493.15
87.5

0.4250
0.1500
0.4250
393.15
60.7

0.4250
0.1500
0.4250
413.15
61.1

0.4250
0.1500
0.4250
433.15
61.6

0.4250
0.1500
0.4250
453.15
62.0

0.4250
0.1500
0.4250
473.15
62.4

0.4250
0.1500
0.4250
493.15
62.7

wA
wB
wC
T/K
P/MPa

0.2125
0.1500
0.6375
393.15
26.7

0.2125
0.1500
0.6375
413.15
28.9

0.2125
0.1500
0.6375
433.15
30.9

0.2125
0.1500
0.6375
453.15
33.1

0.2125
0.1500
0.6375
473.15
34.8

0.2125
0.1500
0.6375
493.15
37.6

0.0850
0.1500
0.7650
393.15
4.8

0.0850
0.1500
0.7650
413.15
7.1

0.0850
0.1500
0.7650
433.15
9.8
continue

2001 by CRC Press LLC

continue
wA
wB
wC
T/K
P/MPa

0.0850
0.1500
0.7650
453.15
13.2

0.0850
0.1500
0.7650
473.15
17.5

copolymer (B):
solvent (A):
solvent (C):
Type of data:

0.0850
0.1500
0.7650
493.15
19.5

E-VA/28w(2)
ethene
vinyl acetate

99KIN
74-85-1
108-05-4

C2H4
C4H6O2

cloud-points

wA
wB
wC
T/K
P/MPa

0.4250
0.1500
0.4250
348.15
48.7

0.4250
0.1500
0.4250
353.15
47.5

0.4250
0.1500
0.4250
358.15
46.8

0.4250
0.1500
0.4250
368.15
46.7

0.4250
0.1500
0.4250
383.15
47.5

0.4250
0.1500
0.4250
393.15
48.0

0.4250
0.1500
0.4250
423.15
50.8

0.3060
0.1500
0.5440
348.15
42.2

0.3060
0.1500
0.5440
353.15
41.4

wA
wB
wC
T/K
P/MPa

0.3060
0.1500
0.5440
358.15
41.0

0.3060
0.1500
0.5440
368.15
40.9

0.3060
0.1500
0.5440
373.15
41.0

0.3060
0.1500
0.5440
383.15
41.1

0.3060
0.1500
0.5440
393.15
41.5

0.3060
0.1500
0.5440
403.15
42.0

0.3060
0.1500
0.5440
423.15
43.9

0.3060
0.1500
0.5440
443.15
45.3

0.3060
0.1500
0.5440
463.15
46.9

wA
wB
wC
T/K
P/MPa

0.0850
0.1500
0.7650
341.15
4.8

0.0850
0.1500
0.7650
343.15
3.5

0.0850
0.1500
0.7650
348.15
2.9

0.0850
0.1500
0.7650
353.15
2.8

0.0850
0.1500
0.7650
358.15
2.7

0.0850
0.1500
0.7650
368.15
3.0

0.0850
0.1500
0.7650
373.15
3.4

0.0850
0.1500
0.7650
383.15
4.0

0.0850
0.1500
0.7650
403.15
5.7

wA
wB
wC
T/K
P/MPa

0.0850
0.1500
0.7650
423.15
8.6

0.0850
0.1500
0.7650
443.15
11.0

0.0850
0.1500
0.7650
463.15
15.5

copolymer (B):
solvent (A):
solvent (C):
Type of data:
wA
wB
wC
T/K
P/MPa

E-VA/28w(2)
ethene
vinyl acetate

99KIN
74-85-1
108-05-4

C2H4
C4H6O2

cloud-points

0.4825
0.0350
0.4825
393.15
59.0

0.4825
0.0350
0.4825
413.15
59.9

0.4825
0.0350
0.4825
433.15
60.6

0.4825
0.0350
0.4825
453.15
61.2

0.4825
0.0350
0.4825
473.15
61.6

0.4825
0.0350
0.4825
493.15
61.9

0.4600
0.0800
0.4600
393.15
61.9

0.4600
0.0800
0.4600
413.15
62.3

0.4600
0.0800
0.4600
433.15
62.9
continue

2001 by CRC Press LLC

continue
wA
wB
wC
T/K
P/MPa

0.4600
0.0800
0.4600
453.15
63.3

0.4600
0.0800
0.4600
473.15
63.8

0.4600
0.0800
0.4600
493.15
64.1

0.4250
0.1500
0.4250
393.15
60.7

0.4250
0.1500
0.4250
413.15
61.1

0.4250
0.1500
0.4250
433.15
61.6

wA
wB
wC
T/K
P/MPa

0.3750
0.2500
0.3750
393.15
53.8

0.3750
0.2500
0.3750
413.15
54.9

0.3750
0.2500
0.3750
433.15
56.0

0.3750
0.2500
0.3750
453.15
56.9

0.3750
0.2500
0.3750
473.15
58.0

0.3750
0.2500
0.3750
493.15
58.9

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/28w(2)
ethene
vinyl acetate

0.4250
0.1500
0.4250
453.15
62.0

0.4250
0.1500
0.4250
473.15
62.4

0.4250
0.1500
0.4250
493.15
62.7

99KIN
74-85-1
108-05-4

C2H4
C4H6O2

cloud-points

wA
wB
wC
T/K
P/MPa

0.3450
0.3100
0.3450
393.15
47.5

0.3450
0.3100
0.3450
413.15
49.2

0.3450
0.3100
0.3450
433.15
50.7

0.3450
0.3100
0.3450
453.15
52.1

0.3450
0.3100
0.3450
473.15
53.5

0.3450
0.3100
0.3450
493.15
54.7

0.3400
0.3200
0.3400
393.15
49.0

0.3400
0.3200
0.3400
413.15
50.4

0.3400
0.3200
0.3400
433.15
51.8

wA
wB
wC
T/K
P/MPa

0.3400
0.3200
0.3400
453.15
53.2

0.3400
0.3200
0.3400
473.15
54.5

0.3400
0.3200
0.3400
493.15
55.7

0.3250
0.3500
0.3250
393.15
48.6

0.3250
0.3500
0.3250
413.15
50.1

0.3250
0.3500
0.3250
433.15
51.6

0.3250
0.3500
0.3250
453.15
53.0

0.3250
0.3500
0.3250
473.15
54.3

0.3250
0.3500
0.3250
493.15
55.5

wA
wB
wC
T/K
P/MPa

0.2750
0.4500
0.2750
393.15
42.8

0.2750
0.4500
0.2750
413.15
44.6

0.2750
0.4500
0.2750
433.15
46.2

0.2750
0.4500
0.2750
453.15
47.7

0.2750
0.4500
0.2750
473.15
49.1

0.2750
0.4500
0.2750
493.15
50.3

copolymer (B):
solvent (A):
solvent (C):
solvent (D):
Type of data:
wA
wB
wC
wD
T/K
P/MPa

E-VA/28w(2)
ethene
vinyl acetate
carbon dioxide

99KIN
74-85-1
108-05-4
124-38-9

C2H4
C4H6O2
CO2

cloud-points

0.6000
0.1500
0.2000
0.0500
393.15
97.9

0.6000
0.1500
0.2000
0.0500
413.15
96.0

0.6000
0.1500
0.2000
0.0500
433.15
94.3

0.6000
0.1500
0.2000
0.0500
453.15
92.6

0.6000
0.1500
0.2000
0.0500
473.15
91.1

0.6000
0.1500
0.2000
0.0500
493.15
90.0

0.5625
0.1500
0.1875
0.1000
393.15
101.5

0.5625
0.1500
0.1875
0.1000
413.15
99.4

0.5625
0.1500
0.1875
0.1000
433.15
97.3
continue

2001 by CRC Press LLC

continue
wA
wB
wC
wD
T/K
P/MPa

0.5625
0.1500
0.1875
0.1000
453.15
95.7

0.5625
0.1500
0.1875
0.1000
473.15
94.2

copolymer (B):
solvent (A):
solvent (C):
solvent (D):
Type of data:

0.5625
0.1500
0.1875
0.1000
493.15
92.9

0.5250
0.1500
0.1750
0.1500
393.15
105.1

E-VA/28w(2)
ethene
vinyl acetate
carbon dioxide

0.5250
0.1500
0.1750
0.1500
413.15
102.4

0.5250
0.1500
0.1750
0.1500
433.15
100.1

0.5250
0.1500
0.1750
0.1500
453.15
97.7

0.5250
0.1500
0.1750
0.1500
473.15
95.9

0.5250
0.1500
0.1750
0.1500
493.15
94.3

99KIN
74-85-1
108-05-4
124-38-9

C2H4
C4H6O2
CO2

cloud-points

wA
wB
wC
wD
T/K
P/MPa

0.400
0.150
0.400
0.050
393.15
64.9

0.400
0.150
0.400
0.050
413.15
65.1

0.400
0.150
0.400
0.050
433.15
65.3

0.400
0.150
0.400
0.050
453.15
65.5

0.400
0.150
0.400
0.050
473.15
65.7

0.400
0.150
0.400
0.050
493.15
65.8

0.375
0.150
0.375
0.100
393.15
69.6

0.375
0.150
0.375
0.100
413.15
69.6

0.375
0.150
0.375
0.100
433.15
69.5

wA
wB
wC
wD
T/K
P/MPa

0.375
0.150
0.375
0.100
453.15
69.5

0.375
0.150
0.375
0.100
473.15
69.4

0.375
0.150
0.375
0.100
493.15
69.3

0.350
0.150
0.350
0.150
393.15
74.9

0.350
0.150
0.350
0.150
413.15
74.6

0.350
0.150
0.350
0.150
433.15
74.3

0.350
0.150
0.350
0.150
453.15
74.1

0.350
0.150
0.350
0.150
473.15
73.7

0.350
0.150
0.350
0.150
493.15
73.5

copolymer (B):
solvent (A):
solvent (C):
solvent (D):
Type of data:

E-VA/28w(2)
ethene
vinyl acetate
carbon dioxide

99KIN
74-85-1
108-05-4
124-38-9

C2H4
C4H6O2
CO2

cloud-points

wA
wB
wC
wD
T/K
P/MPa

0.2000
0.1500
0.6000
0.0500
393.15
32.5

0.2000
0.1500
0.6000
0.0500
413.15
34.4

0.2000
0.1500
0.6000
0.0500
433.15
36.1

0.2000
0.1500
0.6000
0.0500
453.15
38.0

0.2000
0.1500
0.6000
0.0500
473.15
39.4

0.2000
0.1500
0.6000
0.0500
493.15
40.9

0.1875
0.1500
0.5625
0.1000
393.15
38.9

0.1875
0.1500
0.5625
0.1000
413.15
40.3

0.1875
0.1500
0.5625
0.1000
433.15
41.8

wA
wB
wC
wD
T/K
P/MPa

0.1875
0.1500
0.5625
0.1000
453.15
43.1

0.1875
0.1500
0.5625
0.1000
473.15
44.2

0.1875
0.1500
0.5625
0.1000
493.15
45.2

0.1750
0.1500
0.5250
0.1500
393.15
45.2

0.1750
0.1500
0.5250
0.1500
413.15
46.1

0.1750
0.1500
0.5250
0.1500
433.15
47.2

0.1750
0.1500
0.5250
0.1500
453.15
48.3

0.1750
0.1500
0.5250
0.1500
473.15
48.9

0.1750
0.1500
0.5250
0.1500
493.15
49.6

2001 by CRC Press LLC

copolymer (B):
solvent (A):
solvent (C):
solvent (D):
Type of data:

E-VA/28w(2)
ethene
vinyl acetate
helium

99KIN
74-85-1
108-05-4
7440-59-7

C2H4
C4H6O2
He

cloud-points

wA
wB
wC
wD
T/K
P/MPa

0.8300
0.1500
0.0000
0.0200
393.15
209.4

0.8300
0.1500
0.0000
0.0200
413.15
197.5

0.8300
0.1500
0.0000
0.0200
433.15
185.4

0.8300
0.1500
0.0000
0.0200
453.15
174.8

0.8300
0.1500
0.0000
0.0200
473.15
165.9

0.8300
0.1500
0.0000
0.0200
493.15
158.5

0.6300
0.1500
0.2100
0.0100
393.15
139.1

0.6300
0.1500
0.2100
0.0100
413.15
133.4

0.6300
0.1500
0.2100
0.0100
433.15
127.4

wA
wB
wC
wD
T/K
P/MPa

0.6300
0.1500
0.2100
0.0100
453.15
122.6

0.6300
0.1500
0.2100
0.0100
473.15
118.7

0.6300
0.1500
0.2100
0.0100
493.15
116.3

0.6225
0.1500
0.2075
0.0200
393.15
186.5

0.6225
0.1500
0.2075
0.0200
413.15
176.6

0.6225
0.1500
0.2075
0.0200
433.15
166.4

0.6225
0.1500
0.2075
0.0200
453.15
157.7

0.6225
0.1500
0.2075
0.0200
473.15
151.3

0.6225
0.1500
0.0750
0.0200
493.15
147.1

copolymer (B):
solvent (A):
solvent (C):
solvent (D):
Type of data:

E-VA/28w(2)
ethene
vinyl acetate
helium

99KIN
74-85-1
108-05-4
7440-59-7

C2H4
C4H6O2
He

cloud-points

wA
wB
wC
wD
T/K
P/MPa

0.420
0.150
0.420
0.010
393.15
99.2

0.420
0.150
0.420
0.010
413.15
96.8

0.420
0.150
0.420
0.010
433.15
95.0

0.420
0.150
0.420
0.010
453.15
93.0

0.420
0.150
0.420
0.010
473.15
91.3

0.420
0.150
0.420
0.010
493.15
89.9

0.415
0.150
0.415
0.020
393.15
148.0

0.415
0.150
0.415
0.020
413.15
139.6

0.415
0.150
0.415
0.020
433.15
132.0

wA
wB
wC
wD
T/K
P/MPa

0.415
0.150
0.415
0.020
453.15
126.8

0.415
0.150
0.415
0.020
473.15
121.7

0.415
0.150
0.415
0.020
493.15
117.3

0.410
0.150
0.410
0.030
393.15
215.6

0.410
0.150
0.410
0.030
413.15
201.1

0.410
0.150
0.410
0.030
433.15
185.4

0.410
0.150
0.410
0.030
453.15
173.2

0.410
0.150
0.410
0.030
473.15
163.1

0.410
0.150
0.410
0.030
493.15
153.5

copolymer (B):
solvent (A):
solvent (C):
solvent (D):
Type of data:

E-VA/28w(2)
ethene
vinyl acetate
helium

C2H4
C4H6O2
He

99KIN
74-85-1
108-05-4
7440-59-7

cloud-points
continue

2001 by CRC Press LLC

continue
wA
wB
wC
wD
T/K
P/MPa

0.2100
0.1500
0.6300
0.0100
393.15
69.4

0.2100
0.1500
0.6300
0.0100
413.15
67.1

0.2100
0.1500
0.6300
0.0100
433.15
65.1

0.2100
0.1500
0.6300
0.0100
453.15
63.7

0.2100
0.1500
0.6300
0.0100
473.15
62.9

0.2100
0.1500
0.6300
0.0100
493.15
62.8

0.2075
0.1500
0.6225
0.0200
393.15
117.3

0.2075
0.1500
0.6225
0.0200
413.15
109.4

0.2075
0.1500
0.6225
0.0200
433.15
102.8

wA
wB
wC
wD
T/K
P/MPa

0.2075
0.1500
0.6225
0.0200
453.15
97.6

0.2075
0.1500
0.6225
0.0200
473.15
94.0

0.2075
0.1500
0.6225
0.0200
493.15
91.8

0.2050
0.1500
0.6150
0.0300
393.15
165.0

0.2050
0.1500
0.6150
0.0300
413.15
151.9

0.2050
0.1500
0.6150
0.0300
433.15
140.6

0.2050
0.1500
0.6150
0.0300
453.15
131.5

0.2050
0.1500
0.6150
0.0300
473.15
124.9

0.2050
0.1500
0.6150
0.0300
493.15
120.6

copolymer (B):
solvent (A):
solvent (C):
solvent (C):
Type of data:

E-VA/28w(2)
ethene
vinyl acetate
nitrogen

99KIN
74-85-1
108-05-4
7727-37-9

C2H4
C4H6O2
N2

cloud-points

wA
wB
wC
wD
T/K
P/MPa

0.6000
0.1500
0.2000
0.0500
393.15
115.4

0.6000
0.1500
0.2000
0.0500
413.15
112.5

0.6000
0.1500
0.2000
0.0500
433.15
110.0

0.6000
0.1500
0.2000
0.0500
453.15
108.0

0.6000
0.1500
0.2000
0.0500
473.15
105.4

0.6000
0.1500
0.2000
0.0500
493.15
103.0

0.5625
0.1500
0.1875
0.1000
393.15
142.2

0.5625
0.1500
0.1875
0.1000
413.15
136.6

0.5625
0.1500
0.1875
0.1000
433.15
131.1

wA
wB
wC
wD
T/K
P/MPa

0.5625
0.1500
0.1875
0.1000
453.15
125.5

0.5625
0.1500
0.1875
0.1000
473.15
120.6

0.5625
0.1500
0.1875
0.1000
493.15
116.1

0.5250
0.1500
0.1750
0.1500
393.15
170.0

0.5250
0.1500
0.1750
0.1500
413.15
160.9

0.5250
0.1500
0.1750
0.1500
433.15
153.2

0.5250
0.1500
0.1750
0.1500
453.15
146.2

0.5250
0.1500
0.1750
0.1500
473.15
139.8

0.5250
0.1500
0.1750
0.1500
493.15
133.9

copolymer (B):
solvent (A):
solvent (C):
solvent (C):
Type of data:
wA
wB
wC
wD
T/K
P/MPa

E-VA/28w(2)
ethene
vinyl acetate
nitrogen

99KIN
74-85-1
108-05-4
7727-37-9

C2H4
C4H6O2
N2

cloud-points

0.400
0.150
0.400
0.050
393.15
84.1

0.400
0.150
0.400
0.050
413.15
82.5

0.400
0.150
0.400
0.050
433.15
81.3

0.400
0.150
0.400
0.050
453.15
79.7

0.400
0.150
0.400
0.050
473.15
78.5

0.400
0.150
0.400
0.050
493.15
77.3

0.375
0.150
0.375
0.100
393.15
107.0

0.375
0.150
0.375
0.100
413.15
104.0

0.375
0.150
0.375
0.100
433.15
101.1
continue

2001 by CRC Press LLC

continue
wA
wB
wC
wD
T/K
P/MPa

0.375
0.150
0.375
0.100
453.15
98.4

0.375
0.150
0.375
0.100
473.15
96.1

copolymer (B):
solvent (A):
solvent (C):
solvent (C):
Type of data:

0.375
0.150
0.375
0.100
493.15
93.9

0.350
0.150
0.350
0.150
393.15
130.8

E-VA/28w(2)
ethene
vinyl acetate
nitrogen

0.350
0.150
0.350
0.150
413.15
126.1

0.350
0.150
0.350
0.150
433.15
122.0

0.350
0.150
0.350
0.150
453.15
118.6

0.350
0.150
0.350
0.150
473.15
115.5

0.350
0.150
0.350
0.150
493.15
112.5

99KIN
74-85-1
108-05-4
7727-37-9

C2H4
C4H6O2
N2

cloud-points

wA
wB
wC
wD
T/K
P/MPa

0.2000
0.1500
0.6000
0.0500
393.15
48.4

0.2000
0.1500
0.6000
0.0500
413.15
49.0

0.2000
0.1500
0.6000
0.0500
433.15
49.4

0.2000
0.1500
0.6000
0.0500
453.15
49.6

0.2000
0.1500
0.6000
0.0500
473.15
50.2

0.2000
0.1500
0.6000
0.0500
493.15
50.7

0.1875
0.1500
0.5625
0.1000
393.15
73.6

0.1875
0.1500
0.5625
0.1000
413.15
72.2

0.1875
0.1500
0.5625
0.1000
433.15
70.9

wA
wB
wC
wD
T/K
P/MPa

0.1875
0.1500
0.5625
0.1000
453.15
70.0

0.1875
0.1500
0.5625
0.1000
473.15
69.3

0.1875
0.1500
0.5625
0.1000
493.15
68.7

0.1750
0.1500
0.5250
0.1500
393.15
99.8

0.1750
0.1500
0.5250
0.1500
413.15
97.7

0.1750
0.1500
0.5250
0.1500
433.15
95.8

0.1750
0.1500
0.5250
0.1500
453.15
94.1

0.1750
0.1500
0.5250
0.1500
473.15
92.6

0.1750
0.1500
0.5250
0.1500
493.15
91.3

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/32w
ethene
vinyl acetate

84WOH
74-85-1
108-05-4

C2H4
C4H6O2

cloud-points

Comments: the feed (total) monomer weight fraction ratio wA/wC = 64/36 was kept constant
wB
T/K
P/MPa

0.05
393.15
80.4

0.10
393.15
77.8

0.15
393.15
75.8

0.20
393.15
73.3

0.30
393.15
71.3

0.05
413.15
78.3

0.10
413.15
76.8

0.15
413.15
75.0

0.20
413.15
72.3

wB
T/K
P/MPa

0.30
413.15
70.3

0.05
433.15
76.8

0.10
433.15
76.0

0.15
433.15
74.0

0.20
433.15
70.3

0.30
433.15
68.8

0.05
453.15
76.3

0.10
453.15
74.8

0.15
453.15
73.3

wB
T/K
P/MPa

0.20
453.15
68.8

0.30
453.15
67.8

2001 by CRC Press LLC

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/33w
ethene
vinyl acetate

91NIE
74-85-1
108-05-4

C2H4
C4H6O2

cloud-points

wA
wB
wC
T/K
P/MPa

0.761
0.073
0.166
348.15
65.8

0.761
0.073
0.166
373.15
65.4

0.761
0.073
0.166
403.15
65.8

0.761
0.073
0.166
433.15
66.8

0.761
0.073
0.166
453.15
67.8

0.657
0.136
0.207
373.15
84.9

0.657
0.136
0.207
403.15
82.9

0.657
0.136
0.207
433.15
81.4

0.657
0.136
0.207
453.15
80.6

wA
wB
wC
T/K
P/MPa

0.505
0.184
0.311
358.15
98.1

0.505
0.184
0.311
383.15
94.6

0.505
0.184
0.311
438.15
90.2

0.361
0.246
0.393
373.15
53.4

0.361
0.246
0.393
403.15
55.6

0.361
0.246
0.393
433.15
58.5

0.430
0.273
0.297
373.15
63.1

0.430
0.273
0.297
433.15
64.3

0.521
0.084
0.395
373.15
61.7

wA
wB
wC
T/K
P/MPa

0.521
0.084
0.395
433.15
64.1

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/34w
ethene
vinyl acetate

91FIN
74-85-1
108-05-4

C2H4
C4H6O2

coexistence data

T/K = 473.15
The total feed concentration of the homogeneous system before demixing is:
wA = 0.4395; wB = 0.2500; wC = 0.2565

_____________________________________________________________________________
wB
wC
wA
wB
wC
P/
wA
MPa
bottom phase
top phase
_____________________________________________________________________________
28.15
29.32
31.28
32.54
36.19
38.05
50.12
51.40

0.1554
0.1640
0.1720
0.1863
0.1968
0.2118
0.2594
0.2736

0.7016
0.6923
0.7010
0.6719
0.6550
0.6400
0.6017
0.5415

0.1489
0.1515
0.1498
0.1600
0.1507
0.1557
0.1591
0.1870

0.6095
0.6801
0.6573

0.0700
0.0090
0.0307

0.3299
0.3305
0.3314

0.6211
0.6653
0.6590

0.0314
0.0381
0.0266

0.3279
0.3331
0.3318

_____________________________________________________________________________
continue

2001 by CRC Press LLC

continue

_____________________________________________________________________________
P/
wA
wB
wC
wA
wB
wC
MPa
bottom phase
top phase
_____________________________________________________________________________
52.54
59.01
64.90
66.94
71.00

0.3404
0.3348
0.3782
0.4114
0.4675

0.4725
0.4848
0.4188
0.3811
0.3011

0.2066
0.2051
0.2262
0.2295
0.2425

0.6541
0.6361
0.6550
0.6427
0.6232

0.0300
0.0552
0.0692
0.0483
0.0734

0.3441
0.3302
0.3210
0.3296
0.3230

_____________________________________________________________________________
copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/34w
ethene
vinyl acetate

91FIN
74-85-1
108-05-4

C2H4
C4H6O2

coexistence data

T/K = 473.15
The total feed concentration of the homogeneous system before demixing is:
wA = 0.4125; wB = 0.2500; wC = 0.3375

_____________________________________________________________________________
wB
wC
wA
wB
wC
P/
wA
MPa
bottom phase
top phase
_____________________________________________________________________________
20.11
20.70
20.99
21.09
21.68
21.68
29.32
30.70
36.58
38.35
42.77
44.63
48.16
49.15
50.81
51.60
56.99
60.43

0.1116
0.1193
0.1171
0.1166
0.1191
0.1204
0.1650
0.1742
0.2132
0.2273
0.2487
0.2630
0.2846
0.3009
0.3188
0.3308
0.3618
0.3881

0.7008
0.6861
0.6957
0.6876
0.6864
0.6815
0.6410
0.6255
0.5672
0.5445
0.6113
0.4983
0.4441
0.4163
0.3966
0.3757
0.3357
0.2553

0.1876
0.1947
0.1872
0.1959
0.1944
0.1981
0.2009
0.2047
0.2132
0.2405
0.2400
0.2387
0.2714
0.2828
0.2846
0.2935
0.3025
0.3567

0.5426
0.5672
0.5395
0.5397
0.5416
0.5366
0.5621
0.5571
0.5274
0.5283
0.5705
0.5659
0.5340
0.5317
0.5334
0.4975
0.5201
0.5047

0.0392
0.0000
0.0169
0.0303
0.0299
0.0214
0.0232
0.0330
0.0362
0.0414
0.0215
0.0281
0.0547
0.0330
0.0512
0.0870
0.0696
0.0974

0.4182
0.4328
0.4436
0.4299
0.4284
0.4420
0.4292
0.4217
0.4432
0.4431
0.4070
0.4060
0.4112
0.4350
0.4154
0.4155
0.4102
0.3979

_____________________________________________________________________________

2001 by CRC Press LLC

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/58w
ethene
vinyl acetate

91NIE
74-85-1
108-05-4

C2H4
C4H6O2

coexistence data

T/K = 393.15
The total feed concentration of the homogeneous system before demixing is:
wA = 0.167; wB = 0.219; wC = 0.614

_____________________________________________________________________________
P/
wA
wB
wC
wA
wB
wC
MPa
bottom phase
top phase
_____________________________________________________________________________
8.3
8.65
9.6
11.0
11.65
12.1

0.231

0.013

0.756

0.227

0.021

0.752

0.217 0.050
0.614 (cloud point)

0.733

0.128
0.130
0.151

0.350
0.337
0.286

0.522
0.533
0.563

0.167

0.219

_____________________________________________________________________________
Comments: some three-phase demixing data below 8 MPa can be found in the original source 91NIE

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/58w
ethene
vinyl acetate

91NIE
74-85-1
108-05-4

C2H4
C4H6O2

coexistence data

T/K = 393.15
The total feed concentration of the homogeneous system before demixing is:
wA = 0.251; wB = 0.200; wC = 0.549

_____________________________________________________________________________
wB
wC
wA
wB
wC
P/
wA
MPa
bottom phase
top phase
_____________________________________________________________________________
9.85

0.112

0.489

0.399

0.330

0.004

0.666

_____________________________________________________________________________
continue

2001 by CRC Press LLC

continue

_____________________________________________________________________________
P/
wA
wB
wC
wA
wB
wC
MPa
bottom phase
top phase
_____________________________________________________________________________
13.9
17.4
20.0
24.9
25.2
27.1
27.7
28.1

0.132
0.150
0.164
0.200

0.487
0.441
0.415
0.328

0.381
0.409
0.421
0.472

0.346
0.343
0.336

0.004
0.007
0.009

0.645
0.650
0.650

0.224

0.272

0.504

0.319

0.037

0.644

0.251

0.200

0.311 0.061
0.549 (cloud point)

0.628

_____________________________________________________________________________
Comments: some three-phase demixing data below 10 MPa can be found in the original source 91NIE

copolymer (B):
solvent (A):
solvent (C):
Type of data:

E-VA/58w
ethene
vinyl acetate

91NIE
74-85-1
108-05-4

C2H4
C4H6O2

cloud-points

wA
wB
wC
T/K
P/MPa

0.096
0.200
0.704
363.15
4.2

0.096
0.200
0.704
393.15
5.3

0.096
0.200
0.704
423.15
6.8

0.148
0.214
0.638
393.15
7.9

0.152
0.214
0.642
363.15
6.3

wA
wB
wC
T/K
P/MPa

0.196
0.198
0.606
423.15
23.3

0.299
0.203
0.498
363.15
36.0

0.401
0.204
0.405
363.15
65.0

0.401
0.204
0.405
393.15
64.5

0.401
0.204
0.405
423.15
64.2

2001 by CRC Press LLC

0.152
0.214
0.642
393.15
8.4

0.160
0.205
0.635
393.15
9.8

0.196
0.198
0.606
363.15
12.0

0.196
0.198
0.606
393.15
18.0

4.4. Table of systems where ternary HPPE data were published only
in graphical form as phase diagrams or related figures

_____________________________________________________________________________
Copolymer (B)
Second and third component
Ref.
_____________________________________________________________________________
Ethylene/acrylic acid copolymer
n-butane and dimethyl ether
n-butane and ethanol
n-butane and ethanol

96LE2
96LE1
96LE2

_____________________________________________________________________________
Ethylene/ethyl acrylate copolymer
1-butene and polyethylene

98LEE

_____________________________________________________________________________
Ethylene/2-ethylhexyl acrylate copolymer
ethene and 2-ethylhexyl acrylate

96BUB

_____________________________________________________________________________
Ethylene/1-hexene copolymer
ethene and n-butane
ethene and carbon dioxide
ethene and 1-hexene
ethene and nitrogen
2-methylpropane and 1-hexene

2000KIN
2000KIN
2000KIN
2000KIN
99PAN

_____________________________________________________________________________
Ethylene/methacrylic acid copolymer
n-butane and dimethyl ether
n-butane and ethanol

97LEE
97LEE

_____________________________________________________________________________
Ethylene/methyl acrylate copolymer
n-butane and ethylene/
methyl acrylate copolymer
n-butane and ethylene/
vinyl alcohol copolymer
1-butene and ethylene/
methyl acrylate copolymer
chlorodifluoromethane and ethanol
chlorodifluoromethane and ethanol
chlorodifluoromethane and 2-propanone
chlorodifluoromethane and 2-propanone
ethene and methyl acrylate
propane and 1-butanol

98LEE
98LEE
98LEE
92MEI
93HA1
92MEI
93HA1
87LUF
94LOS

_____________________________________________________________________________

2001 by CRC Press LLC

Copolymer (B)
Second and third component
Ref.
_____________________________________________________________________________
Ethylene/methyl acrylate copolymer
propane and ethanol
propane and ethanol
propane and ethanol
propane and ethanol
propane and n-hexane
propane and 1-hexene
propane and methanol
propane and 1-propanol
propane and 2-propanone
propane and 2-propanone
propane and 2-propanone

92MEI
93HA1
93HA2
94LOS
94LOS
94LOS
94LOS
94LOS
92MEI
93HA1
93HA2

_____________________________________________________________________________
Ethylene/propylene copolymer
carbon dioxide and C6-fraction solvent
ethene and C6-fraction solvent
ethene and 1-butene
ethene and n-hexane
ethene and 1-hexene
methane and C6-fraction solvent
propene and C6-fraction solvent
propene and C6-fraction solvent
propene and 2-methylbutane

85MCH
85MCH
93CHE
85MCC
93CHE
85MCH
85MCH
86IRA
86IRA

_____________________________________________________________________________
Ethylene/vinyl acetate copolymer
ethene and n-butane
ethene and carbon dioxide
ethene and nitrogen
ethene and vinyl acetate
ethene and vinyl acetate
ethene and vinyl acetate
ethene and vinyl acetate
ethene and vinyl acetate

2000KIN
2000KIN
2000KIN
80RAE
83WOH
92FIN
96FOL
2000KIN

_____________________________________________________________________________
Ethylene/vinyl alcohol copolymer
n-butane and ethylene/
methyl acrylate copolymer

98LEE

_____________________________________________________________________________
Tetrafluoroethylene/hexafluoropropylene copolymer
carbon dioxide and sulfur hexafluoride
carbon dioxide and trifluoromethane
trifluoromethane and sulfur hexafluoride

99MER
99MER
99MER

_____________________________________________________________________________

2001 by CRC Press LLC

4.5. References
80RAE
82RAE

82WOH

83RAE

83WOH
84WAG
84WOH

85MCC
85MCH
86IRA
87LUF
91FIN
91MEI

91NIE

92CH1
92CH2
92FIN

92HAS

92LUF
92MEI
92WIN

Raetzsch, M., Findeisen, R., and Sernov, V.S., Untersuchungen zum Phasenverhalten von
Monomer-Polymer-Systemen unter hohem Druck, Z. Phys. Chemie, Leipzig, 261, 995, 1980.
Raetzsch, M.T., Wagner, P., Wohlfarth, C., and Heise, D., High-pressure phase equilibrium
studies in mixtures of ethylene and (ethylene-vinyl acetate) copolymers. Part I. Dependence
on vinyl acetate content of copolymers (Ger.), Acta Polym., 33, 463, 1982.
Wohlfarth, C., Wagner, P., Raetzsch, M.T., and Westmeier, S., High-pressure phase
equilibrium studies in mixtures of ethylene and (ethylene-vinyl acetate) copolymers. Part II.
Temperature effect (Ger.), Acta Polym., 33, 468, 1982.
Raetzsch, M.T., Wagner, P., Wohlfarth, C., and Gleditzsch, S., Studies of phase equilibriums in mixtures of ethylene and ethylene-vinyl acetate copolymers at high pressures. Part
III. Dependence on the molar weight distribution (Ger.), Acta Polym., 34, 340, 1983.
Wohlfarth, C. and Rtzsch, M.T., Calculation of high-pressure phase equilibria in mixtures
of ethylene, vinyl acetate, and ethylene-vinyl acetate copolymers, Acta Polym., 34, 255, 1983.
Wagner, P., Zum Phasengleichgewicht im System Ethylen + Ethylen-VinylacetatCopolymer unter hohem Druck, PhD-Thesis, TH Leuna-Merseburg, 1984.
Wohlfarth, Ch., Wagner, P., Glindemann, D., Voelkner, M., and Rtzsch, M.T., Highpressure phase equilibrium in the system ethylene + vinyl acetate + (ethylene-vinyl acetate)
copolymers (Ger.), Acta Polym., 35, 498, 1984.
McClellan, A.K. and McHugh, M.A., Separating polymer solutions using high pressure
lower critical solution temperature (LCST) phenomena, Polym. Eng. Sci., 25, 1088, 1985.
McHugh, M.A. and Guckes, T.L., Separating polymer solutions with supercritical fluids,
Macromolecules, 18, 674, 1985.
Irani, C.A. and Cozewith, C., Lower critical solution temperature behavior of ethylene
propylene copolymers in multicomponent solvents, J. Appl. Polym. Sci., 31, 1879, 1986.
Luft, G. and Subramanian, N.S., Phase behavior of mixtures of ethylene, methyl acrylate,
and copolymers under high pressures, Ind. Eng. Chem. Res., 26, 750, 1987.
Finck, U., Phasengleichgewichte in Monomer + Copolymer - Systemen, Diploma paper,
TH Leuna-Merseburg, 1991.
Meilchen, M.A., Hasch, B.M., and McHugh, M.A., Effect of copolymer composition on the
phase behavior of mixtures of poly(ethylene-co-methyl acrylate) with propane and chlorodifluoromethane, Macromolecules, 24, 4874, 1991.
Nieszporek, B., Untersuchungen zum Phasenverhalten quasibinrer und quasiternrer
Mischungen aus Polyethylen, Ethylen-Vinylacetat-Copolymeren, Ethylen und Vinylacetat
unter Druck, PhD-Thesis, TH Darmstadt, 1991.
Chen, S.-J. and Radosz, M., Density-tuned polyolefin phase equilibria 1, Macromolecules,
25, 3089, 1992.
Chen, S.-J., Economou, I.G., Radosz, M., Density-tuned polyolefin phase equilibria 2,
Macromolecules, 25, 4987, 1992.
Finck, U., Wohlfarth, Ch., and Heuer, T., Calculation of high pressure phase equilibria of
mixtures of ethylene, vinyl acetate and an (ethylene-vinyl acetate) copolymer, Ber.
Bunsenges. Phys. Chem., 96, 179, 1992.
Hasch, B.A., Meilchen, M.A., Lee, S.-H., and McHugh, M.A., High-pressure phase
behavior of mixtures of poly(ethylene-co-methyl acrylate) with low-molecular weight
hydrocarbons, J. Polym. Sci., Part B: Polym. Phys., 30, 1365, 1992.
Luft, G. and Wind, R.W., Phasenverhalten von Mischungen aus Ethylen und EthylenAcrylsure-Copolymeren unter hohem Druck, Chem.-Ing.-Techn., 64, 1114, 1992.
Meilchen, M.A., Hasch, B.M., Lee, S.-H., and McHugh, M.A., Poly(ethylene-co-methyl
acrylate)-solvent-cosolvent phase behaviour at high pressures, Polymer, 33, 1922, 1992.
Wind, R.W., Untersuchungen zum Phasenverhalten von Mischungen aus Ethylen, Acrylsure
und Ethylen-Acrylsure-Copolymer unter hohem Druck, PhD-Thesis, TH Darmstadt, 1992.

2001 by CRC Press LLC

93CHE
93GRE

93HA1
93HA2
93PRA
94GR1
94GR2

94LE1
94LE2
94LOS

95CHE
96ALB

96BUB

96BYU

96DEL
96FOL

96LE1
96LE2
96LE3

96MER

96MUE

Chen, S.-J., Economou, I.G., and Radosz, M., Phase behavior of LCST and UCST solutions
of branchy copolymers. Experiment and SAFT modelling, Fluid Phase Equil., 83, 391, 1993
Gregg, C.J., Chen, S.-J., Stein, F.P., and Radosz, M., Phase behavior of binary ethylenepropylene copolymer solutions in sub- and supercritical ethylene and propylene, Fluid
Phase Equil., 83, 375, 1993.
Hasch, B.M., Meilchen, M.A., Lee, S.-H., and McHugh, M.A., Cosolvency effects on
copolymer solutions at high pressure, J. Polym. Sci., Part B: Polym. Phys., 31, 429, 1993.
Hasch, B.M., Lee, S.-H., and McHugh, M.A., The effect of copolymer architecture on
solution behavior, Fluid Phase Equil., 83, 341, 1993.
Pratt, J.A., Lee, S.-H., and McHugh, M.A., Supercritical fluid fractionation of copolymers
based on chemical composition and molecular weight, J. Appl. Polym. Sci., 49, 953, 1993.
Gregg, C.J., Phase equilibria of supercritical fluid solutions of associating polymers in
nonpolar and polar fluids, PhD-Thesis, Lehigh University, Bethlehem, 1994.
Gregg, C.J., Stein, F.P., Morgan, C.K., and Radosz, M., A variable-volume optical pressurevolume-temperature cell for high-pressure cloud points, densities, and IR-spectra, applicable
to supercritical fluid solutions of polymers up to 2 kbar, J. Chem. Eng. Data, 39, 219, 1994.
Lee, S.-H., LoStracco, M.A., Hasch, B.M., and McHugh, M.A., Solubility of poly(ethyleneco-acrylic acid) in low molecular weight hydrocarbons, J. Phys. Chem., 98, 4055, 1994.
Lee, S.-H., LoStracco, A., and McHugh, M.A., High pressure, molecular weight-dependent
behavior of (co)polymer-solvent mixtures, Macromolecules, 27, 4652, 1994.
LoStracco, M.A., Lee, S.-H., and McHugh, M.A., Comparison of the effect of density and
hydrogen bonding on the cloud point behavior of poly(ethylene-co-methyl acrylate)propane-cosolvent mixtures, Polymer, 35, 3272, 1994.
Chen, S., Banaszak, M., and Radosz, M., Phase behavior of poly(ethylene-1-butene) in
subcritical and supercritical propane, Macromolecules, 28, 1812, 1995.
Albrecht, K.L., Stein, F.P., Han, S.J., Gregg, C.J., and Radosz, M., Phase equilibria of
saturated and unsaturated polyisoprene in sub- and supercritical ethane, ethylene, propane,
propylene, and dimethyl ether, Fluid Phase Equil., 117, 84, 1996.
Buback, M., Busch, M., Dietzsch, H., Droege, T., and Lovis, K., Cloud-point curves in
ethylene-acrylate-poly(ethylene-co-acrylate) systems, in High Pressure Chemical Engineering, von Rohr, Ph.R., Trepp, Ch., Eds., Elsevier Sci. B.V., 1996, 175.
Byun, H.-S., Hasch, B.M., McHugh, M.A., Maehling, F.-O., Busch, M., and Buback, M.,
Poly(ethylene-co-butyl acrylate). Phase behavior in ethylene compared to the poly(ethyleneco-methyl acrylate)-ethylene system and aspects of copolymerization kinetics at high
pressures, Macromolecules, 29, 1625, 1996.
DeLoos, Th.W., de Graaf, L.J., and de Swaan Arons, J., Liquid-liquid phase separation in
linear low density polyethylene - solvent systems, Fluid Phase Equil., 117, 40, 1996.
Folie, B., Gregg, C., Luft, G., and Radosz, M., Phase equilibria of poly(ethylene-co-vinyl
acetate) copolymers in subcritical and supercritical ethylene and ethylene - vinyl acetate
mixtures, Fluid Phase Equil., 120, 11, 1996.
Lee, S.-H., Hasch, B.M., and McHugh, M.A., Calculating copolymer solution behavior with
statistical associating fluid theory, Fluid Phase Equil., 117, 61, 1996.
Lee, S.-H., LoStracco, M.A., and McHugh, M.A., Cosolvent effect on the phase behavior of
poly(ethylene-co-acrylic acid) - butane mixtures, Macromolecules, 29, 1349, 1996.
Lee, S.-H. and McHugh, M.A., Influence of chain architecture on high-pressure co-polymer
solution behavior: Experiments and modeling, in High Pressure Chemical Engineering, von
Rohr, Ph.R., Trepp, Ch., Eds., Elsevier Sci. B.V., 1996, 11.
Mertdogan, C.A., Byun, H.-S., McHugh, M.A., and Tuminello, W.H., Solubility of poly
(tetrafluoroethylene-co-19 mol% hexafluoropropylene) in supercritical CO2 and halogenated
supercritical solvents, Macromolecules, 29, 6548, 1996.
Mueller, C., Untersuchungen zum Phasenverhalten von quasibinren Gemischen aus
Ethylen und Ethylen-Copolymeren, PhD-Thesis, Univ. Karlsruhe (TH), 1996.

2001 by CRC Press LLC

96RIN
97HAN

97LEE
97LEP

97MER

97WHA
98HAN

98LEE
98MCH

98ONE

99KIN
99LOR

99MER

99PAN
2000CH1

2000CH2

2000CH3

2000DIN

2000KIN

Rindfleisch, F., DiNoia, T.P., and McHugh, M.A., Solubility of polymers and copolymers
in supercritical CO2, J. Phys. Chem., 100, 15581, 1996.
Han, S.J., Gregg, C.J., and Radosz, M., How the solute polydispersity affects the cloudpoint and coexistence pressures in propylene and ethylene solutions of alternating
poly(ethylene-co-propylene), Ind. Eng. Chem. Res., 36, 5520, 1997.
Lee, S.-H. and McHugh, M.A., Phase behaviour studies with poly(ethylene-co-methacrylic
acid) at high pressures, Polymer, 38, 1317, 1997.
Lepilleur, C., Beckman, E.J., Schonemann, H., and Krukonis, V.J., Effect of molecular
architecture on the phase behavior of fluoroether-functional graft copolymers in
supercritical CO2, Fluid Phase Equil., 134, 285, 1997.
Mertdogan, C.A., DiNoia, T.P., and McHugh, M.A., Impact of backbone architecture on the
solubility of fluoropolymers in supercritical CO2 and halogenated supercritical solvents,
Macromolecules, 30, 7511, 1997.
Whaley, P.D., Winter, H.H., and Ehrlich, P., Phase equilibria of polypropylene with
compressed propane and related systems. 2, Macromolecules, 30, 4887, 1997.
Han, S.J., Lohse, D.J., Radosz, M., and Sperling, L.H., Short chain branching effect on the
cloud-point pressures of ethylene copolymers in subcritical and supercritical propane,
Macromolecules, 31, 2533, 1998.
Lee, S.-H. and McHugh, M.A., Phase behavior of copolymer-copolymer-solvent mixtures at
high pressures, Polymer, 39, 5447, 1998.
McHugh, M.A., Mertdogan, C.A., DiNoia, T.P., Anolick, C., Tuminello, W.H., and
Wheland, R., Impact of melting temperature on poly(tetrafluoroethylene-co-hexafluoropropylene) solubility in supercritical fluid solvents, Macromolecules, 31, 2252, 1998.
O'Neill, M.L., Cao, Q., Fang, C.M., Johnston, K.P., Wilkinson, S.P., Smith, C.D.,
Kerschner, J.L., and Jureller, S.H., Solubility of homopolymers and copolymers in carbon
dioxide, Ind. Eng. Chem. Res., 37, 3067, 1998.
Kinzl, M., Einfluss der Zugabe von Inertkomponenten auf die Phasengleichgewichte von
Copolymerlsungen in berkritischem Ethen, PhD-Thesis, TH Darmstadt, 1999.
Lora, M., Rindfleisch, F., and McHugh, M.A., Influence of the alkyl tail on the solubility of
poly(alkyl acrylates) in ethylene and CO2 at high pressures: Experiments and modeling, J.
Appl. Polym. Sci., 73, 1979, 1999.
Mertdogan, C.A., McHugh, M.A., and Tuminello, W.H., Cosolvency effect of SF6 on the
solubility of poly(tetrafluoroethylene-co-19 mol% hexafluoropropylene) in supercritical CO2
and CHF3, J. Appl. Polym. Sci., 74, 2039, 1999.
Pan, C. and Radosz, M., Phase behavior of poly(ethylene-co-hexene-1) solutions in
isobutane and propane, Ind. Eng. Chem. Res., 38, 2842, 1999.
Chan, K.C., Adidharma, H., and Radosz, M., Fluid-liquid and fluid-solid transitions of
poly(ethylene-co-octene-1) in sub- and supercritical propane solutions, Ind. Eng. Chem.
Res., 39, 3069, 2000.
Chan, A.K.C., Russo, P.S., and Radosz, M., Fluid-liquid equilibria in poly(ethylene-cohexene-1) + propane: a light-scattering probe of cloud-point pressure and critical polymer
concentration, Fluid Phase Equil., 173, 149, 2000.
Chan, A.K.C. and Radosz, M., Fluid-liquid and fluid-solid phase behavior of poly(ethyleneco-hexene-1) solutions in sub- and supercritical propane, ethylene, and ethylene + hexene-1,
Macromolecules, 33, 6800, 2000.
DiNoia, T.P., Conway, S.E., Lim, J.S., McHugh, M.A., Solubility of vinylidene fluoride
polymers in supercritical CO2 and halogenated solvents, J. Polym. Sci., Part B: Polym.
Phys., 38, 2832, 2000
Kinzl, M., Luft, G., Adidharma, H., and Radosz, M., SAFT modeling of inert-gas effects on
the cloud-point pressures in ethylene copolymerization systems: Poly(ethylene-co-vinyl
acetate) + vinyl acetate + ethylene and poly(ethylene-co-hex-1-ene) + 1-hexene + ethylene
with carbon dioxide, nitrogen, or butane, Ind. Eng. Chem. Res., 39, 541, 2000.

2001 by CRC Press LLC