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1
ANSWERS, HINTS & SOLUTIONS
CRT IV
(Paper2)
Q.
No.
PHYSICS CHEMISTRY MATHEMATICS
1.
C A, B, C D
2.
C A, C C
3.
D C A
4.
B A, B, D B
5.
B B, C, D A, C
6.
C A, C A, C, D
7.
C A, B A, B, D
8.
C A, B, C B, D
9.
C B B
10.
A D C
11.
B B B
12.
B B D
13.
C B A
14.
B D B
15.
A A D
16.
C B C
17.
C C B
18.
D A C
19.
C D D
20.
B C C
A
L
L
I
N
D
I
A
T
E
S
T
S
E
R
I
E
S
FI I TJEE JEE(Advanced)2014
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AITSCRTIV(Paper2)PCM(S)JEE(Advanced)/14
FI I TJEE Ltd., FI ITJ EE House, 29A, Kal u Sarai , Sarvapri ya Vi har, New Del hi 110016, Ph 46106000, 26569493, Fax 26513942
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2
P P h hy ys si i c cs s PART I
2. T sin u =mg/2
T' =T cos u
=
mg mg
cot
2 2tan
u =
u
T si n
T cos
T
T
3.
2
1
mv pt
2
= (P =const)
v =
2Pt
m
a =
dv 2P 1
dt m
2 t
=
F =ma =
mP 1
2t v
5.
1 2 3 4 5
F F F F F F = + + + +
2 5 2 4
F F and F F = =
1 3 2 1
F F 2F cos30 2F cos60 = + +
F
3
=
2
2
Gm
4a
; F
2
=
2
2
Gm
3a
; F
1
=
2
2
Gm
a
m
m m
m
m m
F1
F2
F3
F4
F5
F =
2
2
Gm 5 1
4 a
3
 
+

\ .
=me
2
a
e =
3
Gm 5 1
a 4 3
 
+

\ .
T =2t
( )
3
4 3a
Gm 5 3 4 +
6. ( ) ( )
d
g L x gL xu
dt
+ =
7.
x
p
v 5 = ,
y
p
v 5 =
5 2 =7.1 m/s approx.
8.
6
P 4
1600 10
v
4 10
=4 m/s
6
Q 4
1600 10
v
2 10
=8 m/s
( )
2 2
A B A Q P
1
P P v v gh
2
= =
AITSCRTIV(Paper2)PCM(S)JEE(Advanced)/14
FI I TJEE Ltd., FI ITJ EE House, 29A, Kal u Sarai , Sarvapri ya Vi har, New Del hi 110016, Ph 46106000, 26569493, Fax 26513942
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3
1112. Let the point of suspension is origin(O), then C.M. lies on
vertical line when it is in equilibrium position.
x
cm
=
m(0) m(L / 2) m(L)
3m
+ +
=L/2 and
y
cm
=
m( L / 2) m( L) m( L / 2) 2L
3m 3
+ +
=
tan u =
L /2
2L /3
= u =tan
1
(3/4) or 37
0
d
2
=
2 2
2L L
3 2
   
+
 
\ . \ .
d =
5L
6
u
/2
m
5/6
2/3
/2
y
x
O
Moment of inertia I =Mk
2
=
2 2 2 2
m
4m
12 4 2 3
 
+ +

\ .
=3m
2
(Assume full square and calculate moment of inertia about origin and subtract the moment of
inertia of fourth rod.)
Time period of a physical pendulum =2t
I
mgd
=2t
6
5g
sec
1314. F =qvB sin u =qvB (u =90)
So, B =
F
qv
=
20
19 3
3.2 10
1.6 10 4 10
=5 10
7
T
Now,
p q 7 0
I I
5 10
2 5 2
(
+ =
(
t
I =4 amp.
If the distance of point R from third current carrying current is X, then
B
R
=0
7 0
2 2.5
5 10 0
4
+ =
t
so x = 1 m
16. P(2tr)dr =2trq
dv
dr
2t(r+dr) q
dv
dr
P(2tr)dr = 2t q
dv
dr
 

\ .
dr
P(2tr) = 2t q
0
2
2v r
R
 

\ .
P =
0
2
2 v
R
q
AITSCRTIV(Paper2)PCM(S)JEE(Advanced)/14
FI I TJEE Ltd., FI ITJ EE House, 29A, Kal u Sarai , Sarvapri ya Vi har, New Del hi 110016, Ph 46106000, 26569493, Fax 26513942
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4
C Ch he em mi i s st tr r y y PART I I
SECTION A
8. (D) is incorrect, since Gabriel method is used to prepare 1
o
aliphatic amines.
10. Bottles 1, 2, 3, 4 have Pb(NO
3
)
2
, HCl, Na
2
CO
3
and CuSO
4
.
When mixing:
Bottle 1 +Bottle 2 PbCl
2
Bottle 1 +Bottle 3 PbCO
3
Bottle 1 +Bottle 4 PbSO
4
Bottle 2 +Bottle 3 CO
2
Bottle 2 +Bottle 4 No visible reaction
Bottle 3 +Bottle 4 CuCO
3
12.
2 2
N O
2 3
Li Li O Li N
+
A
+
2
H O
LiOH
2
Li N
A
+ 
2
H O
3
LiOH NH + 
Solution for the Q. No. 15 & 16
OH
NO
2
( ) A
2 5
C H I
OC
2
H
5
NO
2
( ) B
Sn HCl +
OC
2
H
5
NH
2
( ) C
2
Ac OH AcOH +
OC
2
H
5
N H C
O
Me
( ) D
( ) A
OSO
2
Ph
NO
2
NaF/DMSO
F
NO
2
( ) E
( ) F
20. (P 2) oxalic acid dehydrate, loses H
2
O when treated at 105
o
C.
(Q 3) when heated at 200
o
C or when refluxed with H
2
SO
4
at 90
o
C, it decomposes into CO
2
, CO,
HCOOH and H
2
O.
(R 4) malonic acid on heating with P
2
O
5
loses H
2
O and forms carbon suboxide.
(S 1) oxalic acid is oxidised by KMnO
4
to CO
2
.
AITSCRTIV(Paper2)PCM(S)JEE(Advanced)/14
FI I TJEE Ltd., FI ITJ EE House, 29A, Kal u Sarai , Sarvapri ya Vi har, New Del hi 110016, Ph 46106000, 26569493, Fax 26513942
websi te: www.fi i tjee.com
5
M Ma at th he em ma at ti i c cs s PART I I I
HINTS AND SOLUTION
1. Put x
2
=t
( )
2 2 2
t t t 2 t
1
I e te e 2t e dt
2
(
= + +
}
2. We have
a b
k
2 3
= = and
2
8
sec A
5
=
2
5
cos A
8
=
2 2 2
5
c 10k , k
2
=
4. ( )
( )
1 1
1 2 3
1 2
tan tan
a 1 b
tan 1
1 b a
1 tan tan
u u
+
u + u + u = = =
u u
[
7.
( )
x if x [1, 2)
f x
x if x (2, )
e
=
e
8. Clearly, A =(2 cos 60, 2 sin 60)
B =(2 cos 60, 2 sin 60)
Tangent at A is x(2 cos 60) +y(2 sin 60) =4
and tangent at B is x(2 cos 60) +y(2 sin 60) =4
30
2
B
60
2
A
( ) P 3, 1
2
x x'
9. Since, parabola is above xaxis
D =a
2
4 s 0
Thus, a
max
=2
10. Equation of tangent at (0, 1) to the parabola is y 1 =a(x 0)
11.12. az bz c 0 + + = ..... (1)
az bz c 0 + + = ..... (2)
Eliminating z from (1) and (2)
( )
2 2
b a z ca bc =
Adding (1) and (2)
( ) ( ) ( )
a b z a b z c c 0 + + + + + =
This is of form Az Az B 0 + + =
13.14 Here,
2x 2x
A
2x 2x
e 1 e 1 1
e
2
e 1 e 1
(
+
= (
+ (
So, f(x) =e
2x
+1; g(x) =e
2x
1
AITSCRTIV(Paper2)PCM(S)JEE(Advanced)/14
FI I TJEE Ltd., FI ITJ EE House, 29A, Kal u Sarai , Sarvapri ya Vi har, New Del hi 110016, Ph 46106000, 26569493, Fax 26513942
websi te: www.fi i tjee.com
6
15.16.
( ) ( )
/ 2
0
f x sinx cost f t dt sinx
t
=
}
f(x) P sin x =sin x
or f(x) =(P +1) sin x
Where
( )
/ 2
0
P cost f t dt
t
=
}
=
( )
/ 2
0
cost P 1 sint dt
t
+
}
=
( )
/ 2
0
P 1
sin2t dt
2
t
+
}
( )
P 1
P
2
+
= P
2
=
( )
f x 1 sinx 2
2
 
= + =

\ .
sin x =2
e [1, 3]
/ 2
0
2
sinx dx 3
2
t
=
}
4
3
=
20. (P) 2(F(x) f(x)) =f
2
(x)
f(x) f'(x) =f(x) f'(x)
( )
( )
( ) ( )
f x 1
f ' x 1
1 f x 1 f x
= =
+ +
f(x) is an increasing function
(Q) 21 s f(5) f(2) s 28
(R)
2
x 2
y
2x 3x 6
+
=
+ +
1 1
y ,
13 3
(
e
(
(S) y =e
x
cos x
y
1
=e
x
sin x e
x
cos x =e
x
sin x y
y
2
=e
x
cos x +e
x
sin x y
1
y
4
+4y =0
k =2
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